Rapid industrialization in China has caused significant environmental challenges,particularly heavy metal pollution from mine tailings.Toxic heavy metals such as lead(Pb),cadmium(Cd),and mercury(Hg)are released during...Rapid industrialization in China has caused significant environmental challenges,particularly heavy metal pollution from mine tailings.Toxic heavy metals such as lead(Pb),cadmium(Cd),and mercury(Hg)are released during the processing of mining wastewater and leaching of mine tailings.Owing to their excellent physicochemical properties,cementitious materials are widely used for the solidification/stabilization of heavy metals,immobilizing heavy metals via two distinct mechanisms.Physically,their favorable characteristics,including high mechanical strength,low porosity,and durable matrix,create effective barriers.Chemically,the alkaline environment facilitates the precipitation of metal hydroxides/carbonates.Conversely,hydration products(calcium silicate hydrate gels and ettringite)contribute to immobilization through adsorption and physical encapsulation.This study systematically investigated the migration mechanisms of heavy metal contaminants in mine tailings;further,it elucidated the multifaceted immobilization pathways of cementitious materials,which involve synergistic adsorption,precipitation,and encapsulation by hydration products combined with homocrystalline substitution.A comprehensive analysis indicated that cementitious materials significantly reduced the mobility and bioavailability of heavy metals.Nonetheless,their long-term stability and potential environmental impact require further investigation.This study aims to provide theoretical support for environmental management and sustainable resource utilization,and to explore the broader application potential of cementitious technology for heavy metal stabilization,thereby establishing a theoretical foundation for future research on heavy metals in low-cement solidified/stabilized tailings.展开更多
Unconfined Compressive Strength(UCS)is a key parameter for the assessment of the stability and performance of stabilized soils,yet traditional laboratory testing is both time and resource intensive.In this study,an in...Unconfined Compressive Strength(UCS)is a key parameter for the assessment of the stability and performance of stabilized soils,yet traditional laboratory testing is both time and resource intensive.In this study,an interpretable machine learning approach to UCS prediction is presented,pairing five models(Random Forest(RF),Gradient Boosting(GB),Extreme Gradient Boosting(XGB),CatBoost,and K-Nearest Neighbors(KNN))with SHapley Additive exPlanations(SHAP)for enhanced interpretability and to guide feature removal.A complete dataset of 12 geotechnical and chemical parameters,i.e.,Atterberg limits,compaction properties,stabilizer chemistry,dosage,curing time,was used to train and test the models.R2,RMSE,MSE,and MAE were used to assess performance.Initial results with all 12 features indicated that boosting-based models(GB,XGB,CatBoost)exhibited the highest predictive accuracy(R^(2)=0.93)with satisfactory generalization on test data,followed by RF and KNN.SHAP analysis consistently picked CaO content,curing time,stabilizer dosage,and compaction parameters as the most important features,aligning with established soil stabilization mechanisms.Models were then re-trained on the top 8 and top 5 SHAP-ranked features.Interestingly,GB,XGB,and CatBoost maintained comparable accuracy with reduced input sets,while RF was moderately sensitive and KNN was somewhat better owing to reduced dimensionality.The findings confirm that feature reduction through SHAP enables cost-effective UCS prediction through the reduction of laboratory test requirements without significant accuracy loss.The suggested hybrid approach offers an explainable,interpretable,and cost-effective tool for geotechnical engineering practice.展开更多
This paper deals with the singular chemotaxis-Navier-Stokes system with indirect signal consumption n_(t)+u·▽v=△n-Х▽·(n/v▽u);v_(t)+u·▽v=△v-uw;w_(t)+u·▽w=△w-w+n;u_(t)+(u·▽)u=△u-▽P+...This paper deals with the singular chemotaxis-Navier-Stokes system with indirect signal consumption n_(t)+u·▽v=△n-Х▽·(n/v▽u);v_(t)+u·▽v=△v-uw;w_(t)+u·▽w=△w-w+n;u_(t)+(u·▽)u=△u-▽P+n▽Ф;▽·u=0,x∈Ω,t>0 in a bounded and smooth domainΩ⊂ℝ2 with no-flux/no-flux/no-flux/no-slip boundary conditions,whereΦ∈W2,∞(Ω).A recent literature[Dai F,Liu B.J Differential Equations,2023,369:115–155]has proved that for all reasonably regular initial data,the associated initial-boundary value problem possesses a global classical solution,but qualitative information on the behavior of solution has never been touched so far.In stark contrast to the positive effect of indirect signal consumption mechanism on the global solvability of system,the analysis of asymptotic behavior of solution to the system with indirect signal consumption is essentially complicated than that with direct signal consumption because the favorable coupled structure between cells and signal is broken down by the indirect signal consumption mechanism.The present study shows that the global classical solution exponentially stabilizes toward the corresponding spatially homogeneous equilibria under a smallness condition on the initial cell mass.In comparison to the previously known result concerning the uniform convergence of solution to the system with direct signal consumption,our result inter alia provides a more in-depth understanding on the asymptotic behavior of solution.展开更多
Superconducting elect rides have attracted growing attention for their potential to achieve high superconducting transition temperatures(T_(C))under pressure.However,many known elect rides are chemically reactive and ...Superconducting elect rides have attracted growing attention for their potential to achieve high superconducting transition temperatures(T_(C))under pressure.However,many known elect rides are chemically reactive and unstable,making high-quality single-crystal growth,characterization,and measurements difficult,and most do not exhibit superconductivity at ambient pressure.In contrast,La_(3) In stands out for its ambient-pressure superconductivity(T_(C)∼9.4 K)and the availability of high-quality single crystals.Here,we investigate its low-energy electronic structure using angle-resolved photoemission spectroscopy and first-principles calculations.The bands near the Fermi energy(E_(F))are mainly derived from La 5d and In 5p orbitals.A saddle point is directly observed at the Brillouin zone(BZ)boundary,while a three-dimensional Van Hove singularity crosses E_(F) at the BZ corner.First-principles calculations further reveal topological Dirac surface states within the bulk energy gap above E_(F).The coexistence of a high density of states and in-gap topological surface states near𝐸F suggests that La3In offers a promising platform for tuning superconductivity and exploring possible topological superconducting phases through doping or external pressure.展开更多
The robust stability and robust stabilization problems for discrete singular systems with interval time-varying delay and linear fractional uncertainty are discussed. A new delay-dependent criterion is established for...The robust stability and robust stabilization problems for discrete singular systems with interval time-varying delay and linear fractional uncertainty are discussed. A new delay-dependent criterion is established for the nominal discrete singular delay systems to be regular, causal and stable by employing the linear matrix inequality （LMI） approach. It is shown that the newly proposed criterion can provide less conservative results than some existing ones. Then, with this criterion, the problems of robust stability and robust stabilization for uncertain discrete singular delay systems are solved, and the delay-dependent LMI conditions are obtained. Finally, numerical examples are given to illustrate the effectiveness of the proposed approach.展开更多
In this paper, delay-dependent stability analysis and robust stabilization for uncertain singular time-delay systems are addressed. By using Jensen integral inequality, an improved delay-dependent criterion of admissi...In this paper, delay-dependent stability analysis and robust stabilization for uncertain singular time-delay systems are addressed. By using Jensen integral inequality, an improved delay-dependent criterion of admissibility for singular time-delay systems is proposed in terms of linear matrix inequality （LMI）. Our new proposed criterion is less conservative and the numerical complexity is smaller than the existing ones. Based on this criterion, a state feedback controller is designed to ensure that the uncertain singular time-delay system is admissible. Finally, three numerical examples are employed to illustrate the effectiveness of the proposed method.展开更多
Stability analysis and stabilization for discrete-time singular delay systems are addressed,respectively.Firstly,a sufficient condition for regularity,causality and stability for discrete-time singular delay systems i...Stability analysis and stabilization for discrete-time singular delay systems are addressed,respectively.Firstly,a sufficient condition for regularity,causality and stability for discrete-time singular delay systems is derived.Then,by applying the skill of matrix theory,the state feedback controller is designed to guarantee the closed-loop discrete-time singular delay systems to be regular,casual and stable.Finally,numerical examples are given to demonstrate the effectiveness of the proposed method.展开更多
This paper investigates the problem of delay-dependent robust stabilization for uncertain singular systems with discrete and distributed delays in terms of linear matrix inequality （LMI） approach. Based on a delay-d...This paper investigates the problem of delay-dependent robust stabilization for uncertain singular systems with discrete and distributed delays in terms of linear matrix inequality （LMI） approach. Based on a delay-dependent stability condition for the nominal system, a state feedback controller is designed, which guarantees the resultant closed- loop system to be robustly stable. An explicit expression for the desired controller is also given by solving a set of matrix inequalities. Some numerical examples are provided to illustrate the less conservativeness of the proposed methods.展开更多
The design of a functional observer and reduced-order observer with internal delay for linear singular timedelay systems with unknown inputs is discussed. The sufficient conditions of the existence of observers, which...The design of a functional observer and reduced-order observer with internal delay for linear singular timedelay systems with unknown inputs is discussed. The sufficient conditions of the existence of observers, which are normal linear time-delay systems, and the corresponding design steps are presented via linear matrix inequality（LMI）. Moreover, the observer-based feedback stabilizing controller is obtained. Three examples are given to show the effectiveness of the proposed methods.展开更多
The problems of robust stability and stabilization via memoryless state feedback for a class of discrete-time switched singular systems with time-varying delays and linear fractional uncertainties are investigated.By ...The problems of robust stability and stabilization via memoryless state feedback for a class of discrete-time switched singular systems with time-varying delays and linear fractional uncertainties are investigated.By constructing a novel switched Lyapunov-Krasovskii functional,a delay-dependent criterion for the unforced system to be regular,causal and uniformly asymptotically stable is established in terms of linear matrix inequalities（LMIs）.An explicit expression for the desired memoryless state feedback stabilization controller is also given.The merits of the proposed criteria lie in their less conservativeness and relative simplicity,which are achieved by considering additionally useful terms（ignored in previous methods） when estimating the upper bound of the forward difference of the Lyapunov-Krasovskii functional and by avoiding utilizing any model augmentation transformation.Some numerical examples are provided to illustrate the validity of the proposed methods.展开更多
Based on input-output approach, the robust stability and stabilization problems for uncertain singular systems with time-varying delays are investigated. The parameter uncertainties are assumed to be norm-bounded and ...Based on input-output approach, the robust stability and stabilization problems for uncertain singular systems with time-varying delays are investigated. The parameter uncertainties are assumed to be norm-bounded and the time-varying delays include both discrete delay and distributed delay. By introducing a new input-output model, the time-delay system is embedded in a family of systems with a forward system without time delay and a dynamical feedback uncertainty. A sufficient and necessary condition, which guarantees the system regular, impulse-free and stable for all admissible uncertainties, is obtained. Based on the strict linear matrix inequality, the desired robust state feedback controller is also obtained. Finally, a numerical example is provided to demonstrate the application of the proposed method.展开更多
This paper addresses the robust admissibility problem in singular fractional-order continuous time systems. It is based on new admissibility conditions of singular fractional-order systems expressed in a set of strict...This paper addresses the robust admissibility problem in singular fractional-order continuous time systems. It is based on new admissibility conditions of singular fractional-order systems expressed in a set of strict linear matrix inequalities(LMIs). Then, a static output feedback controller is designed for the uncertain closed-loop system to be admissible. Numerical examples are given to illustrate the proposed methods.展开更多
This paper deals with the delay-dependent stabilization problem for singular systems with Markovian jump parameters and time delays.A delay-dependent condition is established for the considered system to be regular,im...This paper deals with the delay-dependent stabilization problem for singular systems with Markovian jump parameters and time delays.A delay-dependent condition is established for the considered system to be regular,impulse free and stochastically stable.Based on the condition,a design algorithm of the desired state feedback controller which guarantees the resultant closed-loop system to be regular,impulse free and stochastically stable is proposed in terms of a set of strict linear matrix inequalities(LMIs).Numerical examples show the effectiveness of the proposed methods.展开更多
The investigations of physical attributes of oceans,including parameters such as heat flow and bathymetry,have garnered substantial attention and are particularly valuable for examining Earth’s thermal structures and...The investigations of physical attributes of oceans,including parameters such as heat flow and bathymetry,have garnered substantial attention and are particularly valuable for examining Earth’s thermal structures and dynamic processes.Nevertheless,classical plate cooling models exhibit disparities when predicting observed heat flow and seafloor depth for extremely young and old lithospheres.Furthermore,a comprehensive analysis of global heat flow predictions and regional ocean heat flow or bathymetry data with physical models has been lacking.In this study,we employed power-law models derived from the singularity theory of fractal density to meticulously fit the latest ocean heat flow and bathymetry.Notably,power-law models offer distinct advantages over traditional plate cooling models,showcasing robust self-similarity,scale invariance,or scaling properties,and providing a better fit to observed data.The outcomes of our singularity analysis concerning heat flow and bathymetry across diverse oceanic regions exhibit a degree of consistency with the global ocean spreading rate model.In addition,we applied the similarity method to predict a higher resolution(0.1°×0.1°)global heat flow map based on the most recent heat flow data and geological/geophysical observables refined through linear correlation analysis.Regions displaying significant disparities between predicted and observed heat flow are closely linked to hydrothermal vent fields and active structures.Finally,combining the actual bathymetry and predicted heat flow with the power-law models allows for the quantitative and comprehensive detection of anomalous regions of ocean subsidence and heat flow,which deviate from traditional plate cooling models.The anomalous regions of subsidence and heat flow show different degrees of anisotropy,providing new ideas and clues for further analysis of ocean topography or hydrothermal circulation of mid-ocean ridges.展开更多
The present work aims to stabilize the room temperature allotropic transition of ammonium nitrate(AN)particles utilizing a microencapsulation technique,which involves solvent/non-solvent in which nitrocellulose(NC)has...The present work aims to stabilize the room temperature allotropic transition of ammonium nitrate(AN)particles utilizing a microencapsulation technique,which involves solvent/non-solvent in which nitrocellulose(NC)has been employed as a coating agent.The SEM micrographs revealed distinct features of both pure AN and NC,contrasting with the irregular granular surface topography of the coated AN particles,demonstrating the adherence of NC on the AN surface.Structural analysis via infrared spectroscopy(IR)demonstrated a successful association of AN and NC,with slight shifts observed in IR bands indicating interfacial interactions.Powder X-ray Diffraction(PXRD)analysis further elucidated the structural changes induced by the coating process,revealing that the NC coating altered the crystallization pattern of its pure form.Thermal analysis demonstrates distinct profiles for pure and coated AN,for which the coated sample exhibits a temperature increase and an enthalpy decrease of the room temperature allotropic transition by 6℃,and 36%,respectively.Furthermore,the presence of NC coating alters the intermolecular forces within the composite system,leading to a reduction in melting enthalpy of coated AN by~39%compared to pure AN.The thermal decomposition analysis shows a two-step thermolysis process for coated AN,with a significant increase in the released heat by about 78%accompanied by an increase in the activation barrier of NC and AN thermolysis,demonstrating a stabilized reactivity of the AN-NC particles.These findings highlight the synergistic effect of NC coating on AN particles,which contributed to a structural and reactive stabilization of both AN and NC,proving the potential application of NC-coated AN as a strategically advantageous oxidizer in composite solid propellant formulations.展开更多
Weathering steel exhibits excellent corrosion resistance and is widely used in bridges,towers,railways,highways,and other engineering projects that are exposed to the atmosphere for long periods of time.However,before...Weathering steel exhibits excellent corrosion resistance and is widely used in bridges,towers,railways,highways,and other engineering projects that are exposed to the atmosphere for long periods of time.However,before the formation of stable rust layers,weathering steel is prone to liquid rust sagging and spattering,leading to environmental pollution and city appearance concerns.These factors limit the application and development of weathering steel.In this study,a rapid and environmentally friendly method was de-veloped by introducing alloying elements,specifically investigating the role of Sn in the rapid stabilization of rust layers in marine atmo-spheric environments.The rust layer formed on weathering low-alloy steel exposed to prolonged outdoor conditions and laboratory im-mersion experiments was explored using electron probe micro-analyzer(EPMA),micro-Raman,X-ray photoelectron spectroscopy(XPS),and electrochemical measurements.Results showed an optimal synergistic effect between Sn and Cr,which facilitated the accelerated densification of the rust layer.This beneficial effect enhanced the capability of the rust layer to resist Cl^(-)erosion and improved the protec-tion performance of the rust layer.展开更多
Although perovskite solar cells(PSCs) demonstrate outstanding power conversion efficiency(PCE), their practical applications are still limited by stability issues caused by various problems such as poor crystal qualit...Although perovskite solar cells(PSCs) demonstrate outstanding power conversion efficiency(PCE), their practical applications are still limited by stability issues caused by various problems such as poor crystal quality triggered structural instability. Herein, to address the structural instability of perovskites, we introduced a polymer additive, poly-L-lysine hydrobromide(PLL), into the perovskite precursor to promote perovskite crystal growth, thereby constructing a stable crystal structure. The results show that the introduction of PLL modulates the colloidal aggregation state in the precursor solution, provides longer time for growth of perovskite and successfully realizes the formation of large-sized perovskite films with high crystallinity. More importantly, owing to its hydrophobic long-chain structure and the widespread distribution of C=O and NH on the chain, PLL firmly locks the perovskite crystals, enhancing their structural stability while blocking the intrusion of external factors such as water molecules, significantly enhances the overall stability of the device. The results show that the PLL-based PSC has negligible hysteresis and its PCE is improved from 22.20% to 23.66%. while the PLL-modified perovskite films and devices demonstrate excellent thermal and environmental stability. These findings highlight PLL as a promising additive for optimizing perovskite crystallization, offering guidance for fabricating efficient and stable photovoltaic devices.展开更多
基金supported by the National Natural Science Foundation of China(No.52374121)the Henan Province Science and Technology Research and Development Joint Fund,China(No.235200810016)the National Key Research and Development Program,China(No.2023YFC2907203).
文摘Rapid industrialization in China has caused significant environmental challenges,particularly heavy metal pollution from mine tailings.Toxic heavy metals such as lead(Pb),cadmium(Cd),and mercury(Hg)are released during the processing of mining wastewater and leaching of mine tailings.Owing to their excellent physicochemical properties,cementitious materials are widely used for the solidification/stabilization of heavy metals,immobilizing heavy metals via two distinct mechanisms.Physically,their favorable characteristics,including high mechanical strength,low porosity,and durable matrix,create effective barriers.Chemically,the alkaline environment facilitates the precipitation of metal hydroxides/carbonates.Conversely,hydration products(calcium silicate hydrate gels and ettringite)contribute to immobilization through adsorption and physical encapsulation.This study systematically investigated the migration mechanisms of heavy metal contaminants in mine tailings;further,it elucidated the multifaceted immobilization pathways of cementitious materials,which involve synergistic adsorption,precipitation,and encapsulation by hydration products combined with homocrystalline substitution.A comprehensive analysis indicated that cementitious materials significantly reduced the mobility and bioavailability of heavy metals.Nonetheless,their long-term stability and potential environmental impact require further investigation.This study aims to provide theoretical support for environmental management and sustainable resource utilization,and to explore the broader application potential of cementitious technology for heavy metal stabilization,thereby establishing a theoretical foundation for future research on heavy metals in low-cement solidified/stabilized tailings.
文摘Unconfined Compressive Strength(UCS)is a key parameter for the assessment of the stability and performance of stabilized soils,yet traditional laboratory testing is both time and resource intensive.In this study,an interpretable machine learning approach to UCS prediction is presented,pairing five models(Random Forest(RF),Gradient Boosting(GB),Extreme Gradient Boosting(XGB),CatBoost,and K-Nearest Neighbors(KNN))with SHapley Additive exPlanations(SHAP)for enhanced interpretability and to guide feature removal.A complete dataset of 12 geotechnical and chemical parameters,i.e.,Atterberg limits,compaction properties,stabilizer chemistry,dosage,curing time,was used to train and test the models.R2,RMSE,MSE,and MAE were used to assess performance.Initial results with all 12 features indicated that boosting-based models(GB,XGB,CatBoost)exhibited the highest predictive accuracy(R^(2)=0.93)with satisfactory generalization on test data,followed by RF and KNN.SHAP analysis consistently picked CaO content,curing time,stabilizer dosage,and compaction parameters as the most important features,aligning with established soil stabilization mechanisms.Models were then re-trained on the top 8 and top 5 SHAP-ranked features.Interestingly,GB,XGB,and CatBoost maintained comparable accuracy with reduced input sets,while RF was moderately sensitive and KNN was somewhat better owing to reduced dimensionality.The findings confirm that feature reduction through SHAP enables cost-effective UCS prediction through the reduction of laboratory test requirements without significant accuracy loss.The suggested hybrid approach offers an explainable,interpretable,and cost-effective tool for geotechnical engineering practice.
文摘This paper deals with the singular chemotaxis-Navier-Stokes system with indirect signal consumption n_(t)+u·▽v=△n-Х▽·(n/v▽u);v_(t)+u·▽v=△v-uw;w_(t)+u·▽w=△w-w+n;u_(t)+(u·▽)u=△u-▽P+n▽Ф;▽·u=0,x∈Ω,t>0 in a bounded and smooth domainΩ⊂ℝ2 with no-flux/no-flux/no-flux/no-slip boundary conditions,whereΦ∈W2,∞(Ω).A recent literature[Dai F,Liu B.J Differential Equations,2023,369:115–155]has proved that for all reasonably regular initial data,the associated initial-boundary value problem possesses a global classical solution,but qualitative information on the behavior of solution has never been touched so far.In stark contrast to the positive effect of indirect signal consumption mechanism on the global solvability of system,the analysis of asymptotic behavior of solution to the system with indirect signal consumption is essentially complicated than that with direct signal consumption because the favorable coupled structure between cells and signal is broken down by the indirect signal consumption mechanism.The present study shows that the global classical solution exponentially stabilizes toward the corresponding spatially homogeneous equilibria under a smallness condition on the initial cell mass.In comparison to the previously known result concerning the uniform convergence of solution to the system with direct signal consumption,our result inter alia provides a more in-depth understanding on the asymptotic behavior of solution.
基金supported by the National Natural Science Foundation of China(Grant Nos.12222413,12174443,12274459,and 12404266)the National Key R&D Program of China(Grant Nos.2023YFA1406500,2022YFA1403800,and 2022YFA1403103)+3 种基金the Natural Science Foundation of Shanghai (Grant No.23ZR1482200)the Natural Science Foundation of Ningbo (Grant No.2024J019)the Science Research Project of Hebei Education Department (Grant No.BJ2025060)the funding of Ningbo Yongjiang Talent Program。
文摘Superconducting elect rides have attracted growing attention for their potential to achieve high superconducting transition temperatures(T_(C))under pressure.However,many known elect rides are chemically reactive and unstable,making high-quality single-crystal growth,characterization,and measurements difficult,and most do not exhibit superconductivity at ambient pressure.In contrast,La_(3) In stands out for its ambient-pressure superconductivity(T_(C)∼9.4 K)and the availability of high-quality single crystals.Here,we investigate its low-energy electronic structure using angle-resolved photoemission spectroscopy and first-principles calculations.The bands near the Fermi energy(E_(F))are mainly derived from La 5d and In 5p orbitals.A saddle point is directly observed at the Brillouin zone(BZ)boundary,while a three-dimensional Van Hove singularity crosses E_(F) at the BZ corner.First-principles calculations further reveal topological Dirac surface states within the bulk energy gap above E_(F).The coexistence of a high density of states and in-gap topological surface states near𝐸F suggests that La3In offers a promising platform for tuning superconductivity and exploring possible topological superconducting phases through doping or external pressure.
基金supported by Research Foundation of Education Bureau of Shannxi Province, PRC(No.2010JK400)
文摘The robust stability and robust stabilization problems for discrete singular systems with interval time-varying delay and linear fractional uncertainty are discussed. A new delay-dependent criterion is established for the nominal discrete singular delay systems to be regular, causal and stable by employing the linear matrix inequality （LMI） approach. It is shown that the newly proposed criterion can provide less conservative results than some existing ones. Then, with this criterion, the problems of robust stability and robust stabilization for uncertain discrete singular delay systems are solved, and the delay-dependent LMI conditions are obtained. Finally, numerical examples are given to illustrate the effectiveness of the proposed approach.
基金supported by National Natural Science Foundation of China (No.60904009,No.60974004)
文摘In this paper, delay-dependent stability analysis and robust stabilization for uncertain singular time-delay systems are addressed. By using Jensen integral inequality, an improved delay-dependent criterion of admissibility for singular time-delay systems is proposed in terms of linear matrix inequality （LMI）. Our new proposed criterion is less conservative and the numerical complexity is smaller than the existing ones. Based on this criterion, a state feedback controller is designed to ensure that the uncertain singular time-delay system is admissible. Finally, three numerical examples are employed to illustrate the effectiveness of the proposed method.
基金supported by the National Natural Science Foundation of China (6090400960974004)
文摘Stability analysis and stabilization for discrete-time singular delay systems are addressed,respectively.Firstly,a sufficient condition for regularity,causality and stability for discrete-time singular delay systems is derived.Then,by applying the skill of matrix theory,the state feedback controller is designed to guarantee the closed-loop discrete-time singular delay systems to be regular,casual and stable.Finally,numerical examples are given to demonstrate the effectiveness of the proposed method.
基金the National Natural Science Foundation of China (No.60503027)
文摘This paper investigates the problem of delay-dependent robust stabilization for uncertain singular systems with discrete and distributed delays in terms of linear matrix inequality （LMI） approach. Based on a delay-dependent stability condition for the nominal system, a state feedback controller is designed, which guarantees the resultant closed- loop system to be robustly stable. An explicit expression for the desired controller is also given by solving a set of matrix inequalities. Some numerical examples are provided to illustrate the less conservativeness of the proposed methods.
基金the National Natural Science Foundation of China (No. 50477042)the Ph.D. Programs Foundation of Ministry of Education of China (No. 20040422052 )the National Natural Science Foundation of Shandong Province (No.Z2004G04)
文摘The design of a functional observer and reduced-order observer with internal delay for linear singular timedelay systems with unknown inputs is discussed. The sufficient conditions of the existence of observers, which are normal linear time-delay systems, and the corresponding design steps are presented via linear matrix inequality（LMI）. Moreover, the observer-based feedback stabilizing controller is obtained. Three examples are given to show the effectiveness of the proposed methods.
基金supported by the National Natural Science Foundation of China(6090402060835001)the Jiangsu Planned Projects for Postdoctoral Research Funds(0802010C)
文摘The problems of robust stability and stabilization via memoryless state feedback for a class of discrete-time switched singular systems with time-varying delays and linear fractional uncertainties are investigated.By constructing a novel switched Lyapunov-Krasovskii functional,a delay-dependent criterion for the unforced system to be regular,causal and uniformly asymptotically stable is established in terms of linear matrix inequalities（LMIs）.An explicit expression for the desired memoryless state feedback stabilization controller is also given.The merits of the proposed criteria lie in their less conservativeness and relative simplicity,which are achieved by considering additionally useful terms（ignored in previous methods） when estimating the upper bound of the forward difference of the Lyapunov-Krasovskii functional and by avoiding utilizing any model augmentation transformation.Some numerical examples are provided to illustrate the validity of the proposed methods.
基金Project supported by the Key Program of the National NaturalScience Foundation of China (No. 60434020)the National Natural Science Foundation of China (No. 60604003)
文摘Based on input-output approach, the robust stability and stabilization problems for uncertain singular systems with time-varying delays are investigated. The parameter uncertainties are assumed to be norm-bounded and the time-varying delays include both discrete delay and distributed delay. By introducing a new input-output model, the time-delay system is embedded in a family of systems with a forward system without time delay and a dynamical feedback uncertainty. A sufficient and necessary condition, which guarantees the system regular, impulse-free and stable for all admissible uncertainties, is obtained. Based on the strict linear matrix inequality, the desired robust state feedback controller is also obtained. Finally, a numerical example is provided to demonstrate the application of the proposed method.
文摘This paper addresses the robust admissibility problem in singular fractional-order continuous time systems. It is based on new admissibility conditions of singular fractional-order systems expressed in a set of strict linear matrix inequalities(LMIs). Then, a static output feedback controller is designed for the uncertain closed-loop system to be admissible. Numerical examples are given to illustrate the proposed methods.
基金supported by the National Creative Research Groups Science Foundation of China(No.60721062)the National High Technology Research and Development Program of China(863 Program)(2006AA04 Z182)the National Natural Science Foundation of China(No.60736021)
文摘This paper deals with the delay-dependent stabilization problem for singular systems with Markovian jump parameters and time delays.A delay-dependent condition is established for the considered system to be regular,impulse free and stochastically stable.Based on the condition,a design algorithm of the desired state feedback controller which guarantees the resultant closed-loop system to be regular,impulse free and stochastically stable is proposed in terms of a set of strict linear matrix inequalities(LMIs).Numerical examples show the effectiveness of the proposed methods.
基金supported by the Guangdong Province Introduced Innovative R&D Team of Big Data-Mathematical Earth Sciences and Extreme Geological Events Team(grant number 2021ZT09H399)the National Natural Science Foundation of China(grant number 42430111,42050103).
文摘The investigations of physical attributes of oceans,including parameters such as heat flow and bathymetry,have garnered substantial attention and are particularly valuable for examining Earth’s thermal structures and dynamic processes.Nevertheless,classical plate cooling models exhibit disparities when predicting observed heat flow and seafloor depth for extremely young and old lithospheres.Furthermore,a comprehensive analysis of global heat flow predictions and regional ocean heat flow or bathymetry data with physical models has been lacking.In this study,we employed power-law models derived from the singularity theory of fractal density to meticulously fit the latest ocean heat flow and bathymetry.Notably,power-law models offer distinct advantages over traditional plate cooling models,showcasing robust self-similarity,scale invariance,or scaling properties,and providing a better fit to observed data.The outcomes of our singularity analysis concerning heat flow and bathymetry across diverse oceanic regions exhibit a degree of consistency with the global ocean spreading rate model.In addition,we applied the similarity method to predict a higher resolution(0.1°×0.1°)global heat flow map based on the most recent heat flow data and geological/geophysical observables refined through linear correlation analysis.Regions displaying significant disparities between predicted and observed heat flow are closely linked to hydrothermal vent fields and active structures.Finally,combining the actual bathymetry and predicted heat flow with the power-law models allows for the quantitative and comprehensive detection of anomalous regions of ocean subsidence and heat flow,which deviate from traditional plate cooling models.The anomalous regions of subsidence and heat flow show different degrees of anisotropy,providing new ideas and clues for further analysis of ocean topography or hydrothermal circulation of mid-ocean ridges.
文摘The present work aims to stabilize the room temperature allotropic transition of ammonium nitrate(AN)particles utilizing a microencapsulation technique,which involves solvent/non-solvent in which nitrocellulose(NC)has been employed as a coating agent.The SEM micrographs revealed distinct features of both pure AN and NC,contrasting with the irregular granular surface topography of the coated AN particles,demonstrating the adherence of NC on the AN surface.Structural analysis via infrared spectroscopy(IR)demonstrated a successful association of AN and NC,with slight shifts observed in IR bands indicating interfacial interactions.Powder X-ray Diffraction(PXRD)analysis further elucidated the structural changes induced by the coating process,revealing that the NC coating altered the crystallization pattern of its pure form.Thermal analysis demonstrates distinct profiles for pure and coated AN,for which the coated sample exhibits a temperature increase and an enthalpy decrease of the room temperature allotropic transition by 6℃,and 36%,respectively.Furthermore,the presence of NC coating alters the intermolecular forces within the composite system,leading to a reduction in melting enthalpy of coated AN by~39%compared to pure AN.The thermal decomposition analysis shows a two-step thermolysis process for coated AN,with a significant increase in the released heat by about 78%accompanied by an increase in the activation barrier of NC and AN thermolysis,demonstrating a stabilized reactivity of the AN-NC particles.These findings highlight the synergistic effect of NC coating on AN particles,which contributed to a structural and reactive stabilization of both AN and NC,proving the potential application of NC-coated AN as a strategically advantageous oxidizer in composite solid propellant formulations.
基金support of the National Natural Science Foundation of China(No.52171063).
文摘Weathering steel exhibits excellent corrosion resistance and is widely used in bridges,towers,railways,highways,and other engineering projects that are exposed to the atmosphere for long periods of time.However,before the formation of stable rust layers,weathering steel is prone to liquid rust sagging and spattering,leading to environmental pollution and city appearance concerns.These factors limit the application and development of weathering steel.In this study,a rapid and environmentally friendly method was de-veloped by introducing alloying elements,specifically investigating the role of Sn in the rapid stabilization of rust layers in marine atmo-spheric environments.The rust layer formed on weathering low-alloy steel exposed to prolonged outdoor conditions and laboratory im-mersion experiments was explored using electron probe micro-analyzer(EPMA),micro-Raman,X-ray photoelectron spectroscopy(XPS),and electrochemical measurements.Results showed an optimal synergistic effect between Sn and Cr,which facilitated the accelerated densification of the rust layer.This beneficial effect enhanced the capability of the rust layer to resist Cl^(-)erosion and improved the protec-tion performance of the rust layer.
基金the financial support from the National Key R&D Program of China (No. 2021YFB3800102)the National Natural Science Foundation of China (Nos. 52102196 and 52302324)CASHIPS Director's Fund (Nos. YZJJ-GGZX-2022-01 and YZJJ202304-CX)。
文摘Although perovskite solar cells(PSCs) demonstrate outstanding power conversion efficiency(PCE), their practical applications are still limited by stability issues caused by various problems such as poor crystal quality triggered structural instability. Herein, to address the structural instability of perovskites, we introduced a polymer additive, poly-L-lysine hydrobromide(PLL), into the perovskite precursor to promote perovskite crystal growth, thereby constructing a stable crystal structure. The results show that the introduction of PLL modulates the colloidal aggregation state in the precursor solution, provides longer time for growth of perovskite and successfully realizes the formation of large-sized perovskite films with high crystallinity. More importantly, owing to its hydrophobic long-chain structure and the widespread distribution of C=O and NH on the chain, PLL firmly locks the perovskite crystals, enhancing their structural stability while blocking the intrusion of external factors such as water molecules, significantly enhances the overall stability of the device. The results show that the PLL-based PSC has negligible hysteresis and its PCE is improved from 22.20% to 23.66%. while the PLL-modified perovskite films and devices demonstrate excellent thermal and environmental stability. These findings highlight PLL as a promising additive for optimizing perovskite crystallization, offering guidance for fabricating efficient and stable photovoltaic devices.
