Analyzed the support instable mode of sliding,tripping,and so on,and believed the key point of the support stability control of fully mechanized coal caving face with steep coal seams was to maintain that the seam tru...Analyzed the support instable mode of sliding,tripping,and so on,and believed the key point of the support stability control of fully mechanized coal caving face with steep coal seams was to maintain that the seam true angle was less than the hydraulic support instability critical angle.Through the layout of oblique face,the improvement of support setting load,the control of mining height and nonskid platform,the group support system of end face,the advance optimization of conveyor and support,and the other control tech- nical measures,the true angle of the seam is reduced and the instable critical angle of the support is increased,the hydraulic support stability of fully mechanized coal caving face with steep coal seams is effectively controlled.展开更多
Considering the situation that it is difficult to control the stability of narrow coal pillar in gob-side entry driving under unstable overlying strata, the finite difference numerical simulation method was adopted to...Considering the situation that it is difficult to control the stability of narrow coal pillar in gob-side entry driving under unstable overlying strata, the finite difference numerical simulation method was adopted to analyze the inner stress distribution and its evolution regularity, as well as the deformation characteristics of narrow coal pillar in gob-side entry driving, in the whole process from entry driving of last working face to the present working face mining. A new method of narrow coal pillar control based on the triune coupling support technique (TCST), which includes that high-strength prestressed thread steel bolt is used to strain the coal on the goaf side, and that short bolt to control the integrity of global displacement zone in coal pillar on the entry side, and that long grouting cable to fix anchor point to constrain the bed separation between global displacement zone and fixed zone, is thereby generated and applied to the field production. The result indicates that after entry excavating along the gob under unstable overlying strata, the supporting structure left on the gob side of narrow coal pillar is basically invalid to maintain the coal-pillar stability, and the large deformation of the pillar on the gob side is evident. Except for the significant dynamic pressure appearing in the coal mining of last working face and overlying strata stabilizing process, the stress variation inside the coal pillar in other stages are rather steady, however, the stress expansion is obvious and the coal pillar continues to deform. Once the gob-side entry driving is completed, a global displacement zone on the entry side appears in the shallow part of the pillar, whereas, a relatively steady fixed zone staying almost still in gob-side entry driving and present working face mining is found in the deep part of the pillar. The application of TCST can not only avoid the failure of pillar supporting structure, but exert the supporting capacity of the bolting structure left in the pillar of last sublevel entry, thus to jointly maintain the stability of coal pillar.展开更多
Magneli phase titanium sub-oxide conductive ceramic Tin O2n-1 was used as the support for Pt due to its excellent resistance to electrochemical oxidation, and Pt/Tin O2n-1 composites were prepared by the impregnation-...Magneli phase titanium sub-oxide conductive ceramic Tin O2n-1 was used as the support for Pt due to its excellent resistance to electrochemical oxidation, and Pt/Tin O2n-1 composites were prepared by the impregnation-reduction method. The electrochemical stability of Tin O2n-1 was investigated and the results show almost no change in the redox region after oxidation for 20 h at 1.2 V(vs NHE) in 0.5 mol/L H2SO4 aqueous solution. The catalytic activity and stability of the Pt/Tin O2n-1 toward the oxygen reduction reaction(ORR) in 0.5 mol/L H2SO4 solution were investigated through the accelerated aging tests(AAT), and the morphology of the catalysts before and after the AAT was observed by transmission electron microscopy. At the potential of 0.55 V(vs SCE), the specific kinetic current density of the ORR on the Pt/Tin O2n-1 is about 1.5 times that of the Pt/C. The LSV curves for the Pt/C shift negatively obviously with the half-wave potential shifting about 0.02 V after 8000 cycles AAT, while no obvious change takes place for the LSV curves for the Pt/Tin O2n-1. The Pt particles supported on the carbon aggregate obviously, while the morphology of the Pt supported on Tin O2n-1 remains almost unchanged, which contributes to the electrochemical surface area loss of Pt/C being about 2times that of the Pt/Tin O2n-1. The superior catalytic stability of Pt/Tin O2n-1 toward the ORR could be attributed to the excellent stability of the Tin O2n-1 and the electronic interaction between the metals and the support.展开更多
The working condition of the hydraulic support in working face can be divided into three kinds of situations in the following： roof fall and col,lapse with cavity, advancing support and supporting. Took single suppor...The working condition of the hydraulic support in working face can be divided into three kinds of situations in the following： roof fall and col,lapse with cavity, advancing support and supporting. Took single support with four-pole in Iongwall face to the dip as research object, control method was studied to avoid support instability in three situations mentioned above. Based on these researches, the major factors of influencing on support stability and its controlling measures were put forward. According to specific conditions of working face 1215（3）, which is fully-mechanized and Iongwall face to the dip with great mining height in Zhangji Coal Mine, Huainan Mining Group, the effective measures was taken to control supports stability..展开更多
Co-precipitation method was selected for the preparation of Ni/Al_2O_3, Ni/ZrO_2 and Ni/CeO_2 catalysts, and their performances in methanation were investigated in this study. The structure and surface properties of t...Co-precipitation method was selected for the preparation of Ni/Al_2O_3, Ni/ZrO_2 and Ni/CeO_2 catalysts, and their performances in methanation were investigated in this study. The structure and surface properties of these catalysts were characterized by BET, XRD, H_2-TPD, TEM and H_2-TPR. The results showed that the catalytic activity at low temperature followed the order: Ni/Al_2O_3>Ni/ZrO_2>Ni/CeO_2. Ni/Al_2O_3 catalyst presented the best catalytic performance with the highest CH_4 selectivity of 94.5%. The characterization results indicated that the dispersion of the active component Ni was the main factor affecting the catalytic activity and the one with higher dispersion gave better performance.展开更多
HZSM-5, Al_2O_3, TiO_2 and SiO_2 supported CeO_2-ZrO_2-CrO_x catalysts were prepared by deposition-precipitation method and tested for deep catalytic oxidation of 1,2-dichloroethane（DCE）, as one of the common chlori...HZSM-5, Al_2O_3, TiO_2 and SiO_2 supported CeO_2-ZrO_2-CrO_x catalysts were prepared by deposition-precipitation method and tested for deep catalytic oxidation of 1,2-dichloroethane（DCE）, as one of the common chlorinated organic pollutants. All the catalysts were characterized by means of N_2 adsorption-desorption, X-ray photoelectron spectroscopy（XPS）, ammonia-temperatureprogrammed desorption（NH_3-TPD） and hydrogen temperature-programmed reduction（H2-TPR）. The characterization results revealed that there was strongly synergistic effect between the oxidizability of CZCr species and the acidity of supports, which obviously promoted the catalytic activity for DCE degradation. 20% CZCr/HZSM-5 showed the highest activity and good durability during the long-term continuous test. The catalytic activity decreased in the order： 20%CZCr/HZSM-5〉CZCr〉20%CZCr/TiO_2〉20%CZCr/Al_2O_3〉20%CZCr/SiO_2.展开更多
Based on nonlinear Mohr-Coulomb failure criterion, the analytical solutions of stability number and supporting force on twin shallow tunnels were derived using upper bound theorem of limit analysis. The optimized solu...Based on nonlinear Mohr-Coulomb failure criterion, the analytical solutions of stability number and supporting force on twin shallow tunnels were derived using upper bound theorem of limit analysis. The optimized solutions were obtained by the technique of sequential quadratic programming. When nonlinear coefficient equals 1 and internal friction angle equals 0, the nonlinear Mohr-Coulomb failure criterion degenerates into linear failure criterion. The calculated results of stability number in this work were compared with previous results, and the agreement verifies the effectiveness of the present method. Under the condition of nonlinear Mohr-Coulomb failure criterion, the results show that the supporting force on twin shallow tunnels obviously increases when the nonlinear coefficient, burial depth, ground load or pore water pressure coefficients increase. When the clear distance is 0.5to 1.0 times the diameter of tunnel, the supporting force of twin shallow tunnels reaches its maximum value, which means that the tunnels are the easiest to collapse. While the clear distance increases to 3.5 times the diameter of tunnel, the calculation for twin shallow tunnels can be carried out by the method for independent single shallow tunnel. Therefore, 3.5 times the diameter of tunnel serves as a critical value to determine whether twin shallow tunnels influence each other. In designing twin shallow tunnels,appropriate clear distance value must be selected according to its change rules and actual topographic conditions, meanwhile, the influences of nonlinear failure criterion of soil materials and pore water must be completely considered. During the excavation process, supporting system should be intensified at the positions of larger burial depth or ground load to avoid collapses.展开更多
The deactivation behavior by crystallite growth of nickel nanoparticles on various supports（carbon nanofibers, zirconia, Si C, α-Al2O3 and γ-Al2O3） was investigated in the aqueous phase reforming of ethylene glyco...The deactivation behavior by crystallite growth of nickel nanoparticles on various supports（carbon nanofibers, zirconia, Si C, α-Al2O3 and γ-Al2O3） was investigated in the aqueous phase reforming of ethylene glycol. Supported Ni catalysts of ~10 wt% were prepared by impregnation of carbon nanofibers（CNF）,Zr O2, SiC, γ-Al2O3 and α-Al2O3. The extent of the Ni nanoparticle growth on various support materials follows the order CNF ~ ZrO2〉 SiC 〉 γ-Al2O3〉〉 α-Al2O3 which sequence, however, was determined by the initial Ni particle size. Based on the observed nickel leaching and the specific growth characteristics; the particle size distribution and the effect of loading on the growth rate, Ostwald ripening is suggested to be the main mechanism contributing to nickel particle growth. Remarkably, initially smaller Ni particles（~12 nm） supported on α-Al2O3 were found to outgrow Ni particles with initially larger size（~20 nm）. It is put forward that the higher susceptibility with respect to oxidation of the smaller Ni nanoparticles and differences in initial particle size distribution are responsible for this behavior.展开更多
A series of plane-strain physical model experiments are carried out to study the spatiotemporal evolution rule of rocks fracture surrounding gob-side roadway, which is subjected to the pressure induced by the mining p...A series of plane-strain physical model experiments are carried out to study the spatiotemporal evolution rule of rocks fracture surrounding gob-side roadway, which is subjected to the pressure induced by the mining process. The digital photogrammetry technology and large deformation analysis method are applied to measure the deformation and fracture of surrounding rocks. The experimental results indicate that the deformation and fracture of coal pillars are the cause to the instability and failure of the surrounding rocks. The spatiotemporal evolution rule of the rock deformation and fracture surrounding gob-side roadway is obtained. The coal pillar and the roof near coal pillar should be strengthened in support design. The engineering application results also can provide a useful guide that the combined support with wire meshes, beam, anchor bolt and cable is an effective method.展开更多
Mass movements are very common problems in the eastern Black Sea region of Turkey due to its climate conditions, geological, and geomorphological characteristics. High slope angle, weathering, dense rainfalls, and ant...Mass movements are very common problems in the eastern Black Sea region of Turkey due to its climate conditions, geological, and geomorphological characteristics. High slope angle, weathering, dense rainfalls, and anthropogenic impacts are generally reported as the most important triggering factors in the region. Following the portal slope excavations in the entrance section of Cankurtaran tunnel, located in the region, where the highly weathered andesitic tuff crops out, a circular toe failure occurred. The main target of the present study is to investigate the causes and occurrence mechanism of this failure and to determine the feasible remedial measures against it using finite element method(FEM) in four stages. These stages are slope stability analyses for pre-and postexcavation cases, and remediation design assessments for slope and tunnel. The results of the FEM-SSR analyses indicated that the insufficient initial support design and weathering of the andesitic tuffs are the main factors that caused the portal failure. After installing a rock retaining wall with jet grout columns and reinforced slope benching applications, the factor of safety increased from 0.83 to 2.80. In addition toslope stability evaluation, the Rock Mass Rating(RMR), Rock Mass Quality(Q) and New Austrian Tunneling Method(NATM) systems were also utilized as empirical methods to characterize the tunnel ground and to determine the tunnel support design. The performance of the suggested empirical support design, induced stress distributions and deformations were analyzed by means of numerical modelling. Finally, it was concluded that the recommended stabilization technique was essential for the dynamic long-term stability and prevents the effects of failure. Additionally, the FEM method gives useful and reasonably reliable results in evaluating the stability of cut slopes and tunnels excavated both in continuous and discontinuous rock masses.展开更多
In order to investigate the effects of probe support on the stall characteristics of micro compressors, an experiment was carried out on a large-scale low-speed research compressor according to the principle of geomet...In order to investigate the effects of probe support on the stall characteristics of micro compressors, an experiment was carried out on a large-scale low-speed research compressor according to the principle of geometric similarity. A cylindrical probe support intruding to 50% blade span was mounted at 50% chord upstream from the rotor blade leading edge. The static pressure rise characteristic of the compressor is measured, with and without the probe support respectively. The dynamic compressor behavior from pre-stall to full stall was also measured. The results indicate that the stability margin of the compressor is lowered after installing the probe support. The stall inception is aroused by modal wave disturbances. The disturbances developed into two stall cells smoothly before installing the probe support, while the disturbances first developed into a single stall cell then splitting into two stall cells after installing the probe support. The presence of probe support lowers the initial intensity of the rotating stall of the compressor, while it doesn't alter the intensity of the rotation stall after the compressor enters into full stall.展开更多
At present,the catalysts commercially used for the oxygen reduction reaction of the cathode of proton exchange membrane fuel cells(PEMFCs)are carbon-supported platinum-based catalysts.However,the carbon supports are s...At present,the catalysts commercially used for the oxygen reduction reaction of the cathode of proton exchange membrane fuel cells(PEMFCs)are carbon-supported platinum-based catalysts.However,the carbon supports are susceptible to corrosion under harsh working conditions,which greatly shortens the life of the catalysts.Highly stable carbon supports are urgently required for high-performance PEMFCs.In this work,we developed structure-stable and highly graphitized three-dimensional network carbon nanofibers(CNF)derived from polyaniline by heat treatment at 1200℃.The CNF-1200-based catalyst(PtNi/CNF-1200)loaded with PtNi nanoparticles showed excellent stability.After 5000 cycles from 1.0 to 1.5 V in oxygen saturated 0.1 M HClO_(4) electrolyte,the losses in the half-wave potential and mass activity were only 5 mV and 15%,respectively,far lower than those of commercial Pt/C.The high graphitization degree of CNF-1200 promotes the corrosion resistance of the catalyst.In addition,nitrogen doping effectively facilitates the catalyst–support interaction,stabilizes the highly dispersed PtNi nanoparticles,and improves the stability and activity of PtNi/CNF-1200.展开更多
基金the National Natrual Science Foundation of China(50504014)
文摘Analyzed the support instable mode of sliding,tripping,and so on,and believed the key point of the support stability control of fully mechanized coal caving face with steep coal seams was to maintain that the seam true angle was less than the hydraulic support instability critical angle.Through the layout of oblique face,the improvement of support setting load,the control of mining height and nonskid platform,the group support system of end face,the advance optimization of conveyor and support,and the other control tech- nical measures,the true angle of the seam is reduced and the instable critical angle of the support is increased,the hydraulic support stability of fully mechanized coal caving face with steep coal seams is effectively controlled.
基金supports from the National High Technology Research and Development Program of China (No. 2012AA062101)the Program for New Century Excellent Talents in University of Ministry of Education of China (No. NCET-10-0770)+1 种基金the Program Granted for Scientific Innovation Research of College Graduate in Jiangsu Province (No. CXZZ11-0309)the Priority Academic Program Development of Jiangsu Higher Education Institutions (No. SZBF2011-6-B35)
文摘Considering the situation that it is difficult to control the stability of narrow coal pillar in gob-side entry driving under unstable overlying strata, the finite difference numerical simulation method was adopted to analyze the inner stress distribution and its evolution regularity, as well as the deformation characteristics of narrow coal pillar in gob-side entry driving, in the whole process from entry driving of last working face to the present working face mining. A new method of narrow coal pillar control based on the triune coupling support technique (TCST), which includes that high-strength prestressed thread steel bolt is used to strain the coal on the goaf side, and that short bolt to control the integrity of global displacement zone in coal pillar on the entry side, and that long grouting cable to fix anchor point to constrain the bed separation between global displacement zone and fixed zone, is thereby generated and applied to the field production. The result indicates that after entry excavating along the gob under unstable overlying strata, the supporting structure left on the gob side of narrow coal pillar is basically invalid to maintain the coal-pillar stability, and the large deformation of the pillar on the gob side is evident. Except for the significant dynamic pressure appearing in the coal mining of last working face and overlying strata stabilizing process, the stress variation inside the coal pillar in other stages are rather steady, however, the stress expansion is obvious and the coal pillar continues to deform. Once the gob-side entry driving is completed, a global displacement zone on the entry side appears in the shallow part of the pillar, whereas, a relatively steady fixed zone staying almost still in gob-side entry driving and present working face mining is found in the deep part of the pillar. The application of TCST can not only avoid the failure of pillar supporting structure, but exert the supporting capacity of the bolting structure left in the pillar of last sublevel entry, thus to jointly maintain the stability of coal pillar.
基金Project(21406273)supported by the National Natural Science Foundation of China
文摘Magneli phase titanium sub-oxide conductive ceramic Tin O2n-1 was used as the support for Pt due to its excellent resistance to electrochemical oxidation, and Pt/Tin O2n-1 composites were prepared by the impregnation-reduction method. The electrochemical stability of Tin O2n-1 was investigated and the results show almost no change in the redox region after oxidation for 20 h at 1.2 V(vs NHE) in 0.5 mol/L H2SO4 aqueous solution. The catalytic activity and stability of the Pt/Tin O2n-1 toward the oxygen reduction reaction(ORR) in 0.5 mol/L H2SO4 solution were investigated through the accelerated aging tests(AAT), and the morphology of the catalysts before and after the AAT was observed by transmission electron microscopy. At the potential of 0.55 V(vs SCE), the specific kinetic current density of the ORR on the Pt/Tin O2n-1 is about 1.5 times that of the Pt/C. The LSV curves for the Pt/C shift negatively obviously with the half-wave potential shifting about 0.02 V after 8000 cycles AAT, while no obvious change takes place for the LSV curves for the Pt/Tin O2n-1. The Pt particles supported on the carbon aggregate obviously, while the morphology of the Pt supported on Tin O2n-1 remains almost unchanged, which contributes to the electrochemical surface area loss of Pt/C being about 2times that of the Pt/Tin O2n-1. The superior catalytic stability of Pt/Tin O2n-1 toward the ORR could be attributed to the excellent stability of the Tin O2n-1 and the electronic interaction between the metals and the support.
文摘The working condition of the hydraulic support in working face can be divided into three kinds of situations in the following： roof fall and col,lapse with cavity, advancing support and supporting. Took single support with four-pole in Iongwall face to the dip as research object, control method was studied to avoid support instability in three situations mentioned above. Based on these researches, the major factors of influencing on support stability and its controlling measures were put forward. According to specific conditions of working face 1215（3）, which is fully-mechanized and Iongwall face to the dip with great mining height in Zhangji Coal Mine, Huainan Mining Group, the effective measures was taken to control supports stability..
基金financial support from the National Science and Technology Supporting Plan through contract (2015BAD15B06)the National Natural Science Foundation of China (51661145011)
文摘Co-precipitation method was selected for the preparation of Ni/Al_2O_3, Ni/ZrO_2 and Ni/CeO_2 catalysts, and their performances in methanation were investigated in this study. The structure and surface properties of these catalysts were characterized by BET, XRD, H_2-TPD, TEM and H_2-TPR. The results showed that the catalytic activity at low temperature followed the order: Ni/Al_2O_3>Ni/ZrO_2>Ni/CeO_2. Ni/Al_2O_3 catalyst presented the best catalytic performance with the highest CH_4 selectivity of 94.5%. The characterization results indicated that the dispersion of the active component Ni was the main factor affecting the catalytic activity and the one with higher dispersion gave better performance.
基金Project supports from National Nature Science Foundation of China(21177110)
文摘HZSM-5, Al_2O_3, TiO_2 and SiO_2 supported CeO_2-ZrO_2-CrO_x catalysts were prepared by deposition-precipitation method and tested for deep catalytic oxidation of 1,2-dichloroethane（DCE）, as one of the common chlorinated organic pollutants. All the catalysts were characterized by means of N_2 adsorption-desorption, X-ray photoelectron spectroscopy（XPS）, ammonia-temperatureprogrammed desorption（NH_3-TPD） and hydrogen temperature-programmed reduction（H2-TPR）. The characterization results revealed that there was strongly synergistic effect between the oxidizability of CZCr species and the acidity of supports, which obviously promoted the catalytic activity for DCE degradation. 20% CZCr/HZSM-5 showed the highest activity and good durability during the long-term continuous test. The catalytic activity decreased in the order： 20%CZCr/HZSM-5〉CZCr〉20%CZCr/TiO_2〉20%CZCr/Al_2O_3〉20%CZCr/SiO_2.
基金Project(2013CB036004)supported by the National Basic Research Program of ChinaProject(51378510)supported by the NationalNatural Science Foundation of ChinaProject(CX2013B077)supported by Hunan Provincial Innovation Foundation for Postgraduate,China
文摘Based on nonlinear Mohr-Coulomb failure criterion, the analytical solutions of stability number and supporting force on twin shallow tunnels were derived using upper bound theorem of limit analysis. The optimized solutions were obtained by the technique of sequential quadratic programming. When nonlinear coefficient equals 1 and internal friction angle equals 0, the nonlinear Mohr-Coulomb failure criterion degenerates into linear failure criterion. The calculated results of stability number in this work were compared with previous results, and the agreement verifies the effectiveness of the present method. Under the condition of nonlinear Mohr-Coulomb failure criterion, the results show that the supporting force on twin shallow tunnels obviously increases when the nonlinear coefficient, burial depth, ground load or pore water pressure coefficients increase. When the clear distance is 0.5to 1.0 times the diameter of tunnel, the supporting force of twin shallow tunnels reaches its maximum value, which means that the tunnels are the easiest to collapse. While the clear distance increases to 3.5 times the diameter of tunnel, the calculation for twin shallow tunnels can be carried out by the method for independent single shallow tunnel. Therefore, 3.5 times the diameter of tunnel serves as a critical value to determine whether twin shallow tunnels influence each other. In designing twin shallow tunnels,appropriate clear distance value must be selected according to its change rules and actual topographic conditions, meanwhile, the influences of nonlinear failure criterion of soil materials and pore water must be completely considered. During the excavation process, supporting system should be intensified at the positions of larger burial depth or ground load to avoid collapses.
基金the support of the Smart Mix Program of The Netherlands Ministry of Economic Affairs, Agriculture and Innovation and The Netherlands Ministry of Education, Culture and Science (Grant no. 053.70.011)
文摘The deactivation behavior by crystallite growth of nickel nanoparticles on various supports（carbon nanofibers, zirconia, Si C, α-Al2O3 and γ-Al2O3） was investigated in the aqueous phase reforming of ethylene glycol. Supported Ni catalysts of ~10 wt% were prepared by impregnation of carbon nanofibers（CNF）,Zr O2, SiC, γ-Al2O3 and α-Al2O3. The extent of the Ni nanoparticle growth on various support materials follows the order CNF ~ ZrO2〉 SiC 〉 γ-Al2O3〉〉 α-Al2O3 which sequence, however, was determined by the initial Ni particle size. Based on the observed nickel leaching and the specific growth characteristics; the particle size distribution and the effect of loading on the growth rate, Ostwald ripening is suggested to be the main mechanism contributing to nickel particle growth. Remarkably, initially smaller Ni particles（~12 nm） supported on α-Al2O3 were found to outgrow Ni particles with initially larger size（~20 nm）. It is put forward that the higher susceptibility with respect to oxidation of the smaller Ni nanoparticles and differences in initial particle size distribution are responsible for this behavior.
基金supported by the National Natural Science Foundation of China (No. 51174197)the Major State Basic Research Development Program of China (No. 2014CB046905)+1 种基金State Key Laboratory for Geo Mechanics and Deep Underground Engineering (CUMT) (No. SKLGDUEK1503)the ‘Qing Lan’ Project of Jiangsu Province
文摘A series of plane-strain physical model experiments are carried out to study the spatiotemporal evolution rule of rocks fracture surrounding gob-side roadway, which is subjected to the pressure induced by the mining process. The digital photogrammetry technology and large deformation analysis method are applied to measure the deformation and fracture of surrounding rocks. The experimental results indicate that the deformation and fracture of coal pillars are the cause to the instability and failure of the surrounding rocks. The spatiotemporal evolution rule of the rock deformation and fracture surrounding gob-side roadway is obtained. The coal pillar and the roof near coal pillar should be strengthened in support design. The engineering application results also can provide a useful guide that the combined support with wire meshes, beam, anchor bolt and cable is an effective method.
文摘Mass movements are very common problems in the eastern Black Sea region of Turkey due to its climate conditions, geological, and geomorphological characteristics. High slope angle, weathering, dense rainfalls, and anthropogenic impacts are generally reported as the most important triggering factors in the region. Following the portal slope excavations in the entrance section of Cankurtaran tunnel, located in the region, where the highly weathered andesitic tuff crops out, a circular toe failure occurred. The main target of the present study is to investigate the causes and occurrence mechanism of this failure and to determine the feasible remedial measures against it using finite element method(FEM) in four stages. These stages are slope stability analyses for pre-and postexcavation cases, and remediation design assessments for slope and tunnel. The results of the FEM-SSR analyses indicated that the insufficient initial support design and weathering of the andesitic tuffs are the main factors that caused the portal failure. After installing a rock retaining wall with jet grout columns and reinforced slope benching applications, the factor of safety increased from 0.83 to 2.80. In addition toslope stability evaluation, the Rock Mass Rating(RMR), Rock Mass Quality(Q) and New Austrian Tunneling Method(NATM) systems were also utilized as empirical methods to characterize the tunnel ground and to determine the tunnel support design. The performance of the suggested empirical support design, induced stress distributions and deformations were analyzed by means of numerical modelling. Finally, it was concluded that the recommended stabilization technique was essential for the dynamic long-term stability and prevents the effects of failure. Additionally, the FEM method gives useful and reasonably reliable results in evaluating the stability of cut slopes and tunnels excavated both in continuous and discontinuous rock masses.
基金funded by the National Natural Science Foundation of China(Grant No.51161130525 and 51136003)the 111 Project,No.B07009
文摘In order to investigate the effects of probe support on the stall characteristics of micro compressors, an experiment was carried out on a large-scale low-speed research compressor according to the principle of geometric similarity. A cylindrical probe support intruding to 50% blade span was mounted at 50% chord upstream from the rotor blade leading edge. The static pressure rise characteristic of the compressor is measured, with and without the probe support respectively. The dynamic compressor behavior from pre-stall to full stall was also measured. The results indicate that the stability margin of the compressor is lowered after installing the probe support. The stall inception is aroused by modal wave disturbances. The disturbances developed into two stall cells smoothly before installing the probe support, while the disturbances first developed into a single stall cell then splitting into two stall cells after installing the probe support. The presence of probe support lowers the initial intensity of the rotating stall of the compressor, while it doesn't alter the intensity of the rotation stall after the compressor enters into full stall.
基金The work was supported by the National Natural Science Foundation of China(No.92061125,22209186)Beijing Natural Science Foundation(No.Z200012)+1 种基金Jiangxi Natural Science Foundation(No.20212ACB213009,20223BBG74004)Youth Innovation Promotion Association,CAS(No.2023343).
文摘At present,the catalysts commercially used for the oxygen reduction reaction of the cathode of proton exchange membrane fuel cells(PEMFCs)are carbon-supported platinum-based catalysts.However,the carbon supports are susceptible to corrosion under harsh working conditions,which greatly shortens the life of the catalysts.Highly stable carbon supports are urgently required for high-performance PEMFCs.In this work,we developed structure-stable and highly graphitized three-dimensional network carbon nanofibers(CNF)derived from polyaniline by heat treatment at 1200℃.The CNF-1200-based catalyst(PtNi/CNF-1200)loaded with PtNi nanoparticles showed excellent stability.After 5000 cycles from 1.0 to 1.5 V in oxygen saturated 0.1 M HClO_(4) electrolyte,the losses in the half-wave potential and mass activity were only 5 mV and 15%,respectively,far lower than those of commercial Pt/C.The high graphitization degree of CNF-1200 promotes the corrosion resistance of the catalyst.In addition,nitrogen doping effectively facilitates the catalyst–support interaction,stabilizes the highly dispersed PtNi nanoparticles,and improves the stability and activity of PtNi/CNF-1200.
