The aim of this research is to develop a novel non-leaching antimicrobial waterborne polyurethane(WPU)leather coating material with covalently attached quaternary phosphonium salt(QPS).The structure of the QPS-bearing...The aim of this research is to develop a novel non-leaching antimicrobial waterborne polyurethane(WPU)leather coating material with covalently attached quaternary phosphonium salt(QPS).The structure of the QPS-bearing WPU has been identified,and their thermal stability,mechanical property,and antimicrobial performance have been investigated.The results reveal that the incorporation of QPS slightly reduces the thermal stability of WPU material but would not affects its usability as leather coating.Despite the presence of hydrophobic benzene in QPS structure,the strong hydration of its cationic groups leads to the increased surface contact angle(SCA)and water absorption rate(WAR)of the films,suggesting that the water resistance of the films needs to be improved for the purpose of leather coatings.Antibacterial tests demonstrate that when the QPS content is 20 wt%,QPS-bearing WPU shows effective antimicrobial activity against bacteria.The WPU containing QPS prepared in this study is a non-leaching antimicrobial material and has great potential application as leather coating.展开更多
Genuine leather is often coated before making daily necessities such as shoes,clothing,bags,sofas,car seats,etc.,so as to impart leather products various colours,higher wear resistance and water resistance and so on.H...Genuine leather is often coated before making daily necessities such as shoes,clothing,bags,sofas,car seats,etc.,so as to impart leather products various colours,higher wear resistance and water resistance and so on.However,the coating of these products is often damaged in daily use which will decrease its aesthetic effect and practicability.Therefore,how to improve the scratch resistance of leather coatings has been puzzling people all the time.It is a common knowledge that animals and plants can repair the injured biological tissues by himself.According to this principle,here,we prepared a type of self-healing water-borne polyurethane with disulfide bond in the main chain by using HEDS as chain extender,and the self-healing system was triggered by the disulfide bonds with the help of shape memory function of waterborne Polyurethane,self-healing experiments how that the damaged of leather coating can be repaired fully at 60℃ for 12 h.展开更多
基金Innovation Team Program of Science and Technology(2017TD0010)Key research and development project(2018GZ031518)of Sichuan Province+1 种基金China Postdoctoral Science Foundation(2018 M631083,2019 T120842)postdoctoral research and development Foundation of Sichuan University(2019SCU12060)are gratefully acknowledged.
文摘The aim of this research is to develop a novel non-leaching antimicrobial waterborne polyurethane(WPU)leather coating material with covalently attached quaternary phosphonium salt(QPS).The structure of the QPS-bearing WPU has been identified,and their thermal stability,mechanical property,and antimicrobial performance have been investigated.The results reveal that the incorporation of QPS slightly reduces the thermal stability of WPU material but would not affects its usability as leather coating.Despite the presence of hydrophobic benzene in QPS structure,the strong hydration of its cationic groups leads to the increased surface contact angle(SCA)and water absorption rate(WAR)of the films,suggesting that the water resistance of the films needs to be improved for the purpose of leather coatings.Antibacterial tests demonstrate that when the QPS content is 20 wt%,QPS-bearing WPU shows effective antimicrobial activity against bacteria.The WPU containing QPS prepared in this study is a non-leaching antimicrobial material and has great potential application as leather coating.
基金supported by the National Key Research and Development Program of China(Project No:2017YFB0308600).
文摘Genuine leather is often coated before making daily necessities such as shoes,clothing,bags,sofas,car seats,etc.,so as to impart leather products various colours,higher wear resistance and water resistance and so on.However,the coating of these products is often damaged in daily use which will decrease its aesthetic effect and practicability.Therefore,how to improve the scratch resistance of leather coatings has been puzzling people all the time.It is a common knowledge that animals and plants can repair the injured biological tissues by himself.According to this principle,here,we prepared a type of self-healing water-borne polyurethane with disulfide bond in the main chain by using HEDS as chain extender,and the self-healing system was triggered by the disulfide bonds with the help of shape memory function of waterborne Polyurethane,self-healing experiments how that the damaged of leather coating can be repaired fully at 60℃ for 12 h.
