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Numerical investigation on the spewing mechanism of earth pressure balance shield in a high-pressure water-rich sand stratum 被引量:1
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作者 Zhiyong Yang Weiqiang Qi +4 位作者 Yanjie Ding Yusheng Jiang Xinkang Yang Xing Yang Xiaokang Shao 《Deep Underground Science and Engineering》 2023年第1期74-87,共14页
The spewing of a screw conveyor easily occurs from the earth pressure balance(called EPB)shield in a water-rich sand stratum.This may lead to the collapse of the tunnel face and even serious subsidence of the ground s... The spewing of a screw conveyor easily occurs from the earth pressure balance(called EPB)shield in a water-rich sand stratum.This may lead to the collapse of the tunnel face and even serious subsidence of the ground surface.To understand the spewing mechanism of the shield screw conveyor and explore the critical hydraulic condition of soil spewing in a shield–soil chamber,a simplified theoretical model for the spewing of the screw conveyor was developed based on the equation of groundwater flow in the screw conveyor under turbulent state.Thus,coupling Darcy's law with Brinkman's equation,this model was implemented within the COMSOL Multiphysics framework.The underground water flow in the shield screw conveyor was simulated so as to obtain its velocity and flow rate.Numerical simulations show that the water pressure distribution is concentrated in the lower part of the soil chamber after the groundwater enters the soil chamber.When the groundwater enters the screw conveyor,its pressure gradually decreases along the direction of the screw conveyor.When the water flow reaches the stratum–shield interface,the flow velocity changes markedly:first increases and concentrates at the entrance of the lower soil chamber,plummets and stabilizes gradually,and increases again at the exit.The soil chamber and screw conveyor are significantly depressurized.It is also found that the soil permeability coefficient can be reduced to k<2.6×10^(−4)cm/s through appropriate soil improvement,which can effectively prevent the occurrence of spewing disasters. 展开更多
关键词 EPB shield multiphysical coupling permeability coefficient screw conveyor spewing
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RuO_2-IrO_2-TiO_2析氧催化剂的制备工艺 被引量:1
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作者 赵丽娟 刘志祥 +1 位作者 张萍 毛宗强 《电池》 CAS CSCD 北大核心 2010年第1期19-22,共4页
以Ti N、RuCl3和H2IrCl6为原料,用真空浸渍-热分解法制备了RuO2-IrO2-Ti O2,研究了煅烧温度和n(Ru+Ir)∶n(Ti)对产物的影响。XRD分析表明:Ti N在高温煅烧时氧化生成金红石型Ti O2,RuO2、IrO2和Ti O2以固溶体的形式存在。CV、阳极极化曲... 以Ti N、RuCl3和H2IrCl6为原料,用真空浸渍-热分解法制备了RuO2-IrO2-Ti O2,研究了煅烧温度和n(Ru+Ir)∶n(Ti)对产物的影响。XRD分析表明:Ti N在高温煅烧时氧化生成金红石型Ti O2,RuO2、IrO2和Ti O2以固溶体的形式存在。CV、阳极极化曲线和EIS测试表明:RuO2-IrO2-Ti O2的最佳煅烧温度为400℃,随着n(Ru+Ir)∶n(Ti)的提高,催化剂的活性增强;在相同电位下,RuO2-IrO2-Ti O2的电流密度大于IrO2,可用作固体聚合物电解质(SPE)水电解催化剂。 展开更多
关键词 TIN RuO2-IrO2-TiO2 制备工艺 固体聚合物电解水制氢(SPEWE) 催化剂
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A novel approach for analyzing the migration behavior of fatliquors within leather
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作者 Ruibin Li Chen Yang +1 位作者 Yuanqing Liu Yue Yu 《Collagen and Leather》 2025年第4期82-91,共10页
Fatliquor migration within the leather matrix may lead to the formation of fatty spew,oil patches and fogging,posing challenges to the production of high-quality leather.Currently,it lacks a straightforward and effect... Fatliquor migration within the leather matrix may lead to the formation of fatty spew,oil patches and fogging,posing challenges to the production of high-quality leather.Currently,it lacks a straightforward and effective method for analyzing fatliquor migration behavior.This investigation introduces a novel approach for analyzing fatliquor migration by measuring its spreading area on collagen fiber membranes.By applying 300 mg of fatliquor onto 0.5 mm square membranes(10 cm×10 cm),distinct oil spots were observed,enabling analysis of migration behavior.Using stearic acid as a standard reference compound effectively minimized the influence of different leather sections on fatliquor migration.Fatliquors with low molecular weight,low melting point and high aliphatic ester content exhibited obvious migration potential.Organic-tanned leathers and sulfated fatliquors displayed weak interactions,resulting in easy fatliquor migration within the leather.Conversely,metal-tanned leathers and phosphorylated fatliquors demonstrated strong interactions,effectively hindering migration.This research provides valuable practical and theoretical insights for developing effective strategies to prevent and control fatliquor migration in leather production. 展开更多
关键词 Fatliquors Migration behavior Fatty spew FOGGING Fiber membrane LEATHER
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