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Isotope Shifts of Nitrogen around 800 nm 被引量:1
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作者 白皎 汪海玲 +1 位作者 倪雪 邓伦华 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2016年第5期527-532,I0001,共7页
The Doppler-limited absorption spectra of ^14N and ^15N atoms were measured around 800 nm using concentration modulation spectroscopy to study their isotope shifts. The nitrogen atoms were generated by discharging mol... The Doppler-limited absorption spectra of ^14N and ^15N atoms were measured around 800 nm using concentration modulation spectroscopy to study their isotope shifts. The nitrogen atoms were generated by discharging molecular nitrogen buffered with helium in a homemade discharge tube. The isotope shifts of four multiplets (3s^4PJ→3p^4D^oJ, 3s^4PJ→3p^4P^oJ, 3s^2DJ→5s^2P^oJ, and 3p^2P^oJ→5s^2D^oJ) were measured and their J-dependent specific mass shifts were observed and discussed. 展开更多
关键词 Doppler-limited absorption spectra Isotope shifts specific mass shifts J-dependence
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Theoretical Calculation on Isotope Shifts of N(I)
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作者 Yan Zhang Qing-ning Lin +2 位作者 Tao Yang Jian-ping Yin Hai-ling Wang 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2020年第6期686-690,I0002,共6页
The special mass shift coefficient and field parameter factor of four multiples,3s^4P→3p4P°,3s^4P→3p^4D°,3s^2D→5p^2D°,and 3s^2P→3p^2P°,of ^14N and ^15N were studied using the multi-configuratio... The special mass shift coefficient and field parameter factor of four multiples,3s^4P→3p4P°,3s^4P→3p^4D°,3s^2D→5p^2D°,and 3s^2P→3p^2P°,of ^14N and ^15N were studied using the multi-configuration Dirac-Hartree-Fock method and the relativistic configuration interaction approach.The normal mass shifts,special mass shifts,field shifts,and isotope shifts of N(I)were derived from the theoretical calculated normal mass shift parameter,special mass shift parameter and field parameter factor,and compared with the reported experimental measurements and theoretical results. 展开更多
关键词 Multi-configuration Dirac-Hartree-Fock Relativistic configuration interaction Isotope shifts specific mass shifts
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