The coupling of water and fertilizer is the only way for high yield, efficiency, sugar on sugarcane. On sugarcane production, the spatial and temporal controlling technology of fertigation is an important direction of...The coupling of water and fertilizer is the only way for high yield, efficiency, sugar on sugarcane. On sugarcane production, the spatial and temporal controlling technology of fertigation is an important direction of the sustainable and healthy development of ecological agriculture in cane area of China. This paper reviews main achievements and advances on the coupling effect of water and fertilizer on sugarcane from time and space at home or abroad in recent years, analyzes the application prospects of the temporal and spatial coupling effect of water and fertilizer on sugarcane and puts forward some problems which need further research in future.展开更多
In ultra-short laser pulses,small changes in dispersion properties before the final focusing mirror can lead to severe pulse distortions around the focus and therefore to very different pulse properties at the point o...In ultra-short laser pulses,small changes in dispersion properties before the final focusing mirror can lead to severe pulse distortions around the focus and therefore to very different pulse properties at the point of laser±matter interaction,yielding unexpected interaction results.The mapping between far-and near-field laser properties intricately depends on the spatial and angular dispersion properties as well as the focal geometry.For a focused Gaussian laser pulse under the influence of angular,spatial and group-delay dispersion,we derive analytical expressions for its pulse-front tilt,duration and width from a fully analytic expression for its electric field in the time±space domain obtained with scalar diffraction theory.This expression is not only valid in and near the focus but also along the entire propagation distance from the focusing mirror to the focus.Expressions relating angular,spatial and group-delay dispersion before focusing at an off-axis parabola,where they are well measurable,to the respective values in the pulse’s focus are obtained by a ray tracing approach.Together,these formulas are used to show in example setups that the pulse-front tilts of lasers with small initial dispersion can become several tens of degrees larger in the vicinity of the focus while being small directly in the focus.The formulas derived here provide the analytical foundation for observations previously made in numerical experiments.By numerically simulating Gaussian pulse propagation and measuring properties of the pulse at distances several Rayleigh lengths off the focus,we verify the analytic expressions.展开更多
The coupling reactions of methanol and long-chain alkanes(n-dodecane,n-tetradecane and n-hexadecane)over CHA-type molecular sieves were studied in a fixed bed reactor.Over SAPO-34 and SSZ-13,it was found that the indu...The coupling reactions of methanol and long-chain alkanes(n-dodecane,n-tetradecane and n-hexadecane)over CHA-type molecular sieves were studied in a fixed bed reactor.Over SAPO-34 and SSZ-13,it was found that the induction period of methanol conversion was shortened by the introduction of long-chain alkanes.However,the addition of long-chain alkanes had little influence on the product distribution.Polymethylbenzenes and the derivatives were the main retained species on spent SSZ-13 catalyst,while adamantanes were the main retained species on SAPO-34.This indicates that coking species formation was mainly related to the further transformation of long-chain alkane/methanol coupling products at acid sites of the molecular sieve.These findings provide valuable information of long chain alkanes conversion and methanol reaction behavior of induction period over small pore CHA molecular sieves.展开更多
Wire arc additive manufacturing(WAAM)has emerged as a promising approach for fabricating large-scale components.However,conventional WAAM still faces challenges in optimizing microstructural evolution,minimizing addit...Wire arc additive manufacturing(WAAM)has emerged as a promising approach for fabricating large-scale components.However,conventional WAAM still faces challenges in optimizing microstructural evolution,minimizing additive-induced defects,and alleviating residual stress and deformation,all of which are critical for enhancing the mechanical performance of the manufactured parts.Integrating interlayer friction stir processing(FSP)into WAAM significantly enhances the quality of deposited materials.However,numerical simulation research focusing on elucidating the associated thermomechanical coupling mechanisms remains insufficient.A comprehensive numerical model was developed to simulate the thermomechanical coupling behavior in friction stir-assisted WAAM.The influence of post-deposition FSP on the coupled thermomechanical response of the WAAM process was analyzed quantitatively.Moreover,the residual stress distribution and deformation behavior under both single-layer and multilayer deposition conditions were investigated.Thermal analysis of different deposition layers in WAAM and friction stir-assisted WAAM was conducted.Results show that subsequent layer deposition induces partial remelting of the previously solidified layer,whereas FSP does not cause such remelting.Furthermore,thermal stress and deformation analysis confirm that interlayer FSP effectively mitigates residual stresses and distortion in WAAM components,thereby improving their structural integrity and mechanical properties.展开更多
Transition metal-catalyzed C—C coupling reactions are a core strategy for the construction of carbon-carbon bonds in organic synthesis.Their development has not only promoted the synthesis of drugs,materials,and natu...Transition metal-catalyzed C—C coupling reactions are a core strategy for the construction of carbon-carbon bonds in organic synthesis.Their development has not only promoted the synthesis of drugs,materials,and natural products,but also promoted the development of new synthetic methods,and has also made breakthroughs in mechanism innovation and catalyst design.On this basis,a copper-catalyzed radical reaction between ketones is reported,enabling the synthesis of 2-carbonyl-1,4-diones.The method exhibits excellent applicability to multiple structural types of ketones,including aliphatic ketones with diverse substituents,aromatic ketones,and various simple ketones not limited to acetone,with wide applications,easy implementation,low catalyst toxicity,and low cost,cost-effective,and the product is easy to separate and purify.展开更多
This study aims to promote the optimization and upgrading of the economic structure in rural areas of China by focusing on the coupling coordination mechanism between digital economy–agriculture integration and rural...This study aims to promote the optimization and upgrading of the economic structure in rural areas of China by focusing on the coupling coordination mechanism between digital economy–agriculture integration and rural revitalization.By examining panel data from 30 Chinese provinces,autonomous regions,and municipalities between 2011 and 2022,the research constructs a weight-based evaluation system that integrates subjective and objective methods and a coupling coordination model to reveal its dynamic evolution patterns.Key findings indicate that digital economy–agriculture integration and rural revitalization achieve cross-coupling through critical activities.The impact of digital-agriculture integration on advancing rural revitalization lags by 2–3 years.Although the coupling development degree between the two systems continues to improve,it remains at the stage of primary coordination.Regional disparities are significant,showing a gradient pattern of“high degree of coupling development in the east and low degree of coupling development in the west.”展开更多
Multilayer complex dynamical networks,characterized by the intricate topological connections and diverse hierarchical structures,present significant challenges in determining complete structural configurations due to ...Multilayer complex dynamical networks,characterized by the intricate topological connections and diverse hierarchical structures,present significant challenges in determining complete structural configurations due to the unique functional attributes and interaction patterns inherent to different layers.This paper addresses the critical question of whether structural information from a known layer can be used to reconstruct the unknown intralayer structure of a target layer within general weighted output-coupling multilayer networks.Building upon the generalized synchronization principle,we propose an innovative reconstruction method that incorporates two essential components in the design of structure observers,the cross-layer coupling modulator and the structural divergence term.A key advantage of the proposed reconstruction method lies in its flexibility to freely designate both the unknown target layer and the known reference layer from the general weighted output-coupling multilayer network.The reduced dependency on full-state observability enables more deployment in engineering applications with partial measurements.Numerical simulations are conducted to validate the effectiveness of the proposed structure reconstruction method.展开更多
Traffic flow prediction constitutes a fundamental component of Intelligent Transportation Systems(ITS),playing a pivotal role in mitigating congestion,enhancing route optimization,and improving the utilization efficie...Traffic flow prediction constitutes a fundamental component of Intelligent Transportation Systems(ITS),playing a pivotal role in mitigating congestion,enhancing route optimization,and improving the utilization efficiency of roadway infrastructure.However,existingmethods struggle in complex traffic scenarios due to static spatio-temporal embedding,restricted multi-scale temporal modeling,and weak representation of local spatial interactions.This study proposes Bi-STAT+,an enhanced bidirectional spatio-temporal attention framework to address existing limitations through three principal contributions:(1)an adaptive spatio-temporal embedding module that dynamically adjusts embeddings to capture complex traffic variations;(2)frequency-domain analysis in the temporal dimension for simultaneous high-frequency details and low-frequency trend extraction;and(3)an agent attention mechanism in the spatial dimension that enhances local feature extraction through dynamic weight allocation.Extensive experiments were performed on four distinct datasets,including two publicly benchmark datasets(PEMS04 and PEMS08)and two private datasets collected from Baotou and Chengdu,China.The results demonstrate that Bi-STAT+consistently outperforms existing methods in terms of MAE,RMSE,and MAPE,while maintaining strong robustness against missing data and noise.Furthermore,the results highlight that prediction accuracy improves significantly with higher sampling rates,providing crucial insights for optimizing real-world deployment scenarios.展开更多
The pseudo-two-dimensional(P2D)model plays an important role in exploring physicochemical mechanisms,predicting the state of health,and improving the fast charge capability for Li-ion batteries(LIBs).However,the fast ...The pseudo-two-dimensional(P2D)model plays an important role in exploring physicochemical mechanisms,predicting the state of health,and improving the fast charge capability for Li-ion batteries(LIBs).However,the fast charge leads to the lithium concentration gradient in the solid and electrolyte phases and the non-uniform electrochemical reaction at the solid/electrolyte interface.In order to decouple charge transfer reactions in LIBs under dynamic conditions,understanding the spatio-temporal resolution of the P2D model is urgently required.Till now,the study of this aspect is still insufficient.This work studies the spatio-temporal resolution for dynamic/static electrochemical impedance spectroscopy(DEIS/SEIS)on multiple scales.In detail,DEIS and SEIS with spatio-temporal resolutions are used to decouple charge transfer reactions in LIBs based on the numerical solution of the P2D model in the frequency domain.The calculated results indicate that decoupling solid diffusion requires a high spatial resolution along the r-direction in particles,decoupling electrolyte diffusion and interfacial transfer reaction requires a high spatial resolution along the x-direction,and decoupling charge transfer reactions in LIBs at an extremely low state of charge(SOC)requires an extremely high temporal resolution along the t-direction.Finally,the optimal range of spatio-temporal resolutions for DEIS/SEIS is derived,and the method to decouple charge transfer reactions with spatio-temporal resolutions is developed.展开更多
A series of new chiral amide ligands were prepared from natural amino acids and applied to the copper-catalyzed asymmetric oxidative homocoupling reaction of 3-hydroxy-2-naphthoates.By optimizing the reaction conditio...A series of new chiral amide ligands were prepared from natural amino acids and applied to the copper-catalyzed asymmetric oxidative homocoupling reaction of 3-hydroxy-2-naphthoates.By optimizing the reaction conditions,it was found that when using L3(5 mol%)as the ligand,CuCl(5 mol%)as the catalyst,dichloromethane as the solvent,2,2,6,6-tetramethylpiperidine 1-oxyl(TEMPO)/O2 as the oxidant,and under the reaction condition of 40℃,this method exhibited good substrate tolerance.Under these conditions,a series of chiral 1,1'-bi-2-naphthol(BINOL)derivatives were synthesized with yields of 45%~90%and enantioselectivities ranging from 50∶50 to 97∶3.展开更多
The F_(1)-ATPase and V_(1)-ATPase are rotary biomotors.Alignment of their amino acid sequences,which originate from bovine heart mitochondria(1BMF)and Enterococcus hirae(3VR6),respectively,demonstrates that the segmen...The F_(1)-ATPase and V_(1)-ATPase are rotary biomotors.Alignment of their amino acid sequences,which originate from bovine heart mitochondria(1BMF)and Enterococcus hirae(3VR6),respectively,demonstrates that the segment forming the ATP catalytic pocket is highly conserved.Single-molecule experiments,however,have revealed subtle differences in efficiency between the F_(1) and V_(1) motors.Here,we perform both atomistic and coarse-grained molecular dynamics simulations to investigate the mechanochemical coupling and coordination in F_(1) and V_(1) ATPase.Our results show that the correlation between conformational changes in F_(1) is stronger than that in V_(1),indicating that the mechanochemical coupling in F_(1) is tighter than in V_(1).Moreover,the unidirectional rotation of F_(1) is more processive than that of V_(1),which accounts for the higher efficiency observed in F_(1) and explains the occasional backward steps detected in single-molecule experiments on V_(1).展开更多
The coupling effects among the flow field,temperature distribution and structural deformation in a turbine cannot be ignored,particularly during flight cycles when the turbine experiences varied operational states.Rel...The coupling effects among the flow field,temperature distribution and structural deformation in a turbine cannot be ignored,particularly during flight cycles when the turbine experiences varied operational states.Relying solely on steady-state solutions cannot predict the detrimental effects caused by hysteresis.Consequently,this paper employs a quasi-steady-state fluid-thermalstructure multidisciplinary coupling solution method,integrating transient solid heat conduction with steady-state flow field and static structural deformation solutions.After conducting a numerical simulation of a three-dimensional,five-stage,low-pressure turbine air system,the following conclusions are drawn:when boundary conditions attain high-power states through processes that are numerically identical but in opposite directions,slight variations in solid deformation significantly impact the flow field;when boundary conditions attain high-power states through processes that are directionally consistent but have different numerical values,the influence of the boundary condition change rate on the flow field surpasses that of solid deformation.In terms of turbine design parameters,a large difference in stage-reaction between adjacent stages at the lower radius of the turbine can lead to significant changes in the disc cavity flow field during flight cycles.The difference in the stage-reaction of 0.23 at 10%blade height in adjacent stages may induce severe gas ingress in the stator disc cavity.Thus,it is crucial to minimize this difference and to appropriately extend the duration of the deceleration phase to ensure the turbine's safe operation.展开更多
Based on the Smit-Suhl formula,we propose a universal approach for solving the magnon-magnon coupling problem in bilayer coupled systems(e.g.,antiferromagnets).This method requires only the energy expression,enabling ...Based on the Smit-Suhl formula,we propose a universal approach for solving the magnon-magnon coupling problem in bilayer coupled systems(e.g.,antiferromagnets).This method requires only the energy expression,enabling the automatic derivation of analytical expressions for the eigenmatrix elements via symbolic computation,eliminating the need for tedious manual calculations.Using this approach,we investigate the impact of magnetic hysteresis on magnon-magnon coupling in a system with interlayer Dzyaloshinskii-Moriya interaction(DMI).The magnetic hysteresis leads to an asymmetric magnetic field dependence of the resonance frequency and alters the number of degeneracy points between the pure optical and acoustic modes.Moreover,it can result in the coupling strength at the gap of the f–H phase diagram being nearly vanishing,contrary to the conventionally expected maximum.These results deepen the understanding of the effect of interlayer DMI on magnon–magnon coupling and the proposed universal method significantly streamlines the solving process of magnon–magnon coupling problems.展开更多
This study presents an implicit multiphysics coupling method integrating Computational Fluid Dynamics(CFD),the Multiphase Particle-in-Cell(MPPIC)model,and the Finite Element Method(FEM),implemented with OpenFOAM,Calcu...This study presents an implicit multiphysics coupling method integrating Computational Fluid Dynamics(CFD),the Multiphase Particle-in-Cell(MPPIC)model,and the Finite Element Method(FEM),implemented with OpenFOAM,CalculiX,and preCICE to simulate fluid-particle-structure interactions with large deformations.Mesh motion in the fluid field is handled using the radial basis function(RBF)method.The particle phase is modeled by MPPIC,where fluid-particle interaction is described through momentum exchange,and inter-particle collisions are characterized by collision stress.The structural field is solved by nonlinear FEM to capture large deformations induced by geometric nonlinearity.Coupling among fields is realized through a partitioned,parallel,and non-intrusive iterative strategy,ensuring stable transfer and convergence of interface forces and displacements.Notably,the influence of particles on the structure is not direct but mediated by the fluid,while structural motion directly affects particle dynamics.The results demonstrate that the proposed approach effectively captures multiphysics interaction processes and provides a valuable reference for numerical modeling of coupled fluid-particle-structure systems.展开更多
Global-and meso-scale dipolarizations are well-known features of Earth’s magnetosphere,but their coupling remains poorly understood.Here,using a new approach that combines two-dimentional(2D)ionospheric field-aligned...Global-and meso-scale dipolarizations are well-known features of Earth’s magnetosphere,but their coupling remains poorly understood.Here,using a new approach that combines two-dimentional(2D)ionospheric field-aligned current(FAC)maps with coordinated observations from a network of magnetospheric satellites,we directly show that individual global-scale dipolarizations can expand from the nightside to,or even into,the dayside.These expansions are enduring(20–30 minutes),slow(2–4 deg/min),and global in extent(up to 12 h in local time),consistent with previous statistical inferences but now explicitly observed.The expanding FACs form a two-sheet current system as described by the Boström II model.In contrast,meso-scale dipolarizations are bursty(a few minutes),fast(several tens deg/min),and localized(several hours in local time),as evidenced by auroral expansions and satellite data.They are associated with the line-current system as described by the Boström I model(i.e.,the substorm current wedge).Notably,meso-scale dipolarizations often emerge near the expanding edge of a global-scale dipolarization,suggesting a dynamic coupling between the two scales.These observations provide a complementary scenario to the simulation-based interpretation that global-scale dipolarizations result from the accumulation of meso-scale dipolarizations.Here,meso-scale dipolarizations appear far less frequently than in simulations and occur around the edge of global-scale dipolarizations.This result implies that meso-scale dipolarizations may be sporadically triggered during the azimuthal expansion of global-scale dipolarizations.展开更多
In this paper,a theoretical model is established for locally resonant plates with general resonators,and the corresponding governing equation is derived.The model provides a mathematical demonstration of the locally r...In this paper,a theoretical model is established for locally resonant plates with general resonators,and the corresponding governing equation is derived.The model provides a mathematical demonstration of the locally resonant effect,which contains two parts:the first part is induced by translation coupling,and the second part is induced by rotation coupling.The second part cannot be reflected by most existing theoretical models.The analytical solutions of the dynamic response are compared with the direct numerical simulation(DNS)results for two locally resonant plates with different resonator types,thereby validating the general applicability of the present model.The rotation coupling effect leads to the frequency-dependent effective rotational inertia density and anisotropic dispersion relation of the locally resonant plate,as well as the enhancement of the structural vibration suppression ability.展开更多
An efficient scheme is applied to generate a nonisospectral Botie-Pempinelli-Tu(BPT)integrable hierarchy under the case whereλ_(t)=n∑j=0 k_(j)(t)λ^(-j).Based on an expanding higherdimensional Lie algebra,we obtain ...An efficient scheme is applied to generate a nonisospectral Botie-Pempinelli-Tu(BPT)integrable hierarchy under the case whereλ_(t)=n∑j=0 k_(j)(t)λ^(-j).Based on an expanding higherdimensional Lie algebra,we obtain a nonisospectral BPT integrable coupling hieararchy.It follws that some new nonisospectral nonlinear systems are obtained by reducing these two nonisospectral BPT hierarchies.Actually,these nonisospectral integrable models that we obtained can enrich the existing integrable models and possibly describe new nonlinear phenomena.展开更多
The strong electron-phonon coupling in organic photovoltaic materials significantly impedes exciton transport and promotes charge recombination,thereby exerting a detrimental effect on the overall performance of organ...The strong electron-phonon coupling in organic photovoltaic materials significantly impedes exciton transport and promotes charge recombination,thereby exerting a detrimental effect on the overall performance of organic solar cells(OSCs).Mitigating electron-phonon coupling is therefore essential for developing high-performance OSCs.In this work,we introduce two solid additives,1-bromo-3-chloronaphthalene(BCN-1)and 1-chloro-3-bromonaphthalene(BCN-2),into the bulk heterojunction active layer to address this fundamental challenge.We demonstrate that BCN-2 effectively suppresses high-frequency lattice vibrations,which minimizes electron-phonon scattering and thereby promotes efficient and long-range exciton diffusion.As a result,the BCN-2 processed devices exhibit prolonged exciton lifetime and superior charge carrier mobility compared to the control devices.These synergistic improvements in photophysical properties such as charge transport,contribute to a remarkable power conversion efficiency of 19.72%in the PM6:L8-BO-based OSCs.This work underscores the suppression of electron-phonon coupling as a critical and general strategy for advancing the performance of organic photovoltaic devices.展开更多
This study proposes a novel forecasting framework that simultaneously captures the strong periodicity and irregular meteorological fluctuations inherent in solar radiation time series.Existing approaches typically def...This study proposes a novel forecasting framework that simultaneously captures the strong periodicity and irregular meteorological fluctuations inherent in solar radiation time series.Existing approaches typically define inter-regional correlations using either simple correlation coefficients or distance-based measures when applying spatio-temporal graph neural networks(STGNNs).However,such definitions are prone to generating spurious correlations due to the dominance of periodic structures.To address this limitation,we adopt the Elastic-Band Transform(EBT)to decompose solar radiation into periodic and amplitude-modulated components,which are then modeled independently with separate graph neural networks.The periodic component,characterized by strong nationwide correlations,is learned with a relatively simple architecture,whereas the amplitude-modulated component is modeled with more complex STGNNs that capture climatological similarities between regions.The predictions from the two components are subsequently recombined to yield final forecasts that integrate both periodic patterns and aperiodic variability.The proposed framework is validated with multiple STGNN architectures,and experimental results demonstrate improved predictive accuracy and interpretability compared to conventional methods.展开更多
With the rapid advancement of electromagnetic launch technology,enhancing the structural stability and thermal resistance of armatures has become essential for improving the overall efficiency and reliability of railg...With the rapid advancement of electromagnetic launch technology,enhancing the structural stability and thermal resistance of armatures has become essential for improving the overall efficiency and reliability of railgun systems.Traditional aluminum alloy armatures often suffer from severe ablation,deformation,and uneven current distribution under high pulsed currents,which limit their performance and service life.To address these challenges,this study employs the Johnson–Cook constitutive model and the finite element method to develop armature models of aluminum matrix composites with varying heterogeneous graphene volume fractions.The temperature,stress,and strain of the armatures during operation were analyzed to investigate the effects of different graphene volume fractions on the deformation and damage behavior of aluminum matrix composite armatures under the multi-field coupling of electromagnetic,thermal,and structural interactions.The results indicate that,compared to the 6061 aluminum alloy matrix,the graphene-reinforced aluminum matrix composite armature significantly suppresses ablation damage at the tail and throat edges.The incorporation of graphene notably reduces the temperature rise during the armature emission process,increases the muzzle velocity under identical current excitation,and mitigates directional deformation of the armature.The 1 wt.% graphene-reinforced aluminum matrix composite armature demonstrates better agreement with experimental results at a strain rate of 2000 s^(-1),while simultaneously improving stress-strain response,reducing temperature rise,and improving velocity performance.展开更多
基金Supported by Open Fund of Key Laboratory of Plant Nutrition and Fertilizer,Ministry of Agriculture(2013-1)Guangxi Natural Science Foundation for Youths(2011GXNSFB018026)+2 种基金Guangxi Scientific Research and Technological Development Program(14125008-2-15)Scientific and Technological Development Fund for Youths of Guangxi Academy of Agricultural Sciences(2013YQ18,2013YF06)the State Key Program of National Natural Science of China(U1033004-06)~~
文摘The coupling of water and fertilizer is the only way for high yield, efficiency, sugar on sugarcane. On sugarcane production, the spatial and temporal controlling technology of fertigation is an important direction of the sustainable and healthy development of ecological agriculture in cane area of China. This paper reviews main achievements and advances on the coupling effect of water and fertilizer on sugarcane from time and space at home or abroad in recent years, analyzes the application prospects of the temporal and spatial coupling effect of water and fertilizer on sugarcane and puts forward some problems which need further research in future.
基金Center for Advanced Systems Understanding(CASUS)。
文摘In ultra-short laser pulses,small changes in dispersion properties before the final focusing mirror can lead to severe pulse distortions around the focus and therefore to very different pulse properties at the point of laser±matter interaction,yielding unexpected interaction results.The mapping between far-and near-field laser properties intricately depends on the spatial and angular dispersion properties as well as the focal geometry.For a focused Gaussian laser pulse under the influence of angular,spatial and group-delay dispersion,we derive analytical expressions for its pulse-front tilt,duration and width from a fully analytic expression for its electric field in the time±space domain obtained with scalar diffraction theory.This expression is not only valid in and near the focus but also along the entire propagation distance from the focusing mirror to the focus.Expressions relating angular,spatial and group-delay dispersion before focusing at an off-axis parabola,where they are well measurable,to the respective values in the pulse’s focus are obtained by a ray tracing approach.Together,these formulas are used to show in example setups that the pulse-front tilts of lasers with small initial dispersion can become several tens of degrees larger in the vicinity of the focus while being small directly in the focus.The formulas derived here provide the analytical foundation for observations previously made in numerical experiments.By numerically simulating Gaussian pulse propagation and measuring properties of the pulse at distances several Rayleigh lengths off the focus,we verify the analytic expressions.
基金Supported by National Natural Science Foundation of China(21991093)。
文摘The coupling reactions of methanol and long-chain alkanes(n-dodecane,n-tetradecane and n-hexadecane)over CHA-type molecular sieves were studied in a fixed bed reactor.Over SAPO-34 and SSZ-13,it was found that the induction period of methanol conversion was shortened by the introduction of long-chain alkanes.However,the addition of long-chain alkanes had little influence on the product distribution.Polymethylbenzenes and the derivatives were the main retained species on spent SSZ-13 catalyst,while adamantanes were the main retained species on SAPO-34.This indicates that coking species formation was mainly related to the further transformation of long-chain alkane/methanol coupling products at acid sites of the molecular sieve.These findings provide valuable information of long chain alkanes conversion and methanol reaction behavior of induction period over small pore CHA molecular sieves.
基金National Key Research and Development Program of China(2022YFB4600902)Shandong Provincial Science Foundation for Outstanding Young Scholars(ZR2024YQ020)。
文摘Wire arc additive manufacturing(WAAM)has emerged as a promising approach for fabricating large-scale components.However,conventional WAAM still faces challenges in optimizing microstructural evolution,minimizing additive-induced defects,and alleviating residual stress and deformation,all of which are critical for enhancing the mechanical performance of the manufactured parts.Integrating interlayer friction stir processing(FSP)into WAAM significantly enhances the quality of deposited materials.However,numerical simulation research focusing on elucidating the associated thermomechanical coupling mechanisms remains insufficient.A comprehensive numerical model was developed to simulate the thermomechanical coupling behavior in friction stir-assisted WAAM.The influence of post-deposition FSP on the coupled thermomechanical response of the WAAM process was analyzed quantitatively.Moreover,the residual stress distribution and deformation behavior under both single-layer and multilayer deposition conditions were investigated.Thermal analysis of different deposition layers in WAAM and friction stir-assisted WAAM was conducted.Results show that subsequent layer deposition induces partial remelting of the previously solidified layer,whereas FSP does not cause such remelting.Furthermore,thermal stress and deformation analysis confirm that interlayer FSP effectively mitigates residual stresses and distortion in WAAM components,thereby improving their structural integrity and mechanical properties.
基金Project supported by the Basic Research Support Program for Outstanding Young Teachers in Provincial Undergraduate Colleges and Universities in Heilongjiang Province(No.YQJH2024096)the Heilongjiang Province Natural Joint Guidance Cultivation Project(No.PL2024H198)。
文摘Transition metal-catalyzed C—C coupling reactions are a core strategy for the construction of carbon-carbon bonds in organic synthesis.Their development has not only promoted the synthesis of drugs,materials,and natural products,but also promoted the development of new synthetic methods,and has also made breakthroughs in mechanism innovation and catalyst design.On this basis,a copper-catalyzed radical reaction between ketones is reported,enabling the synthesis of 2-carbonyl-1,4-diones.The method exhibits excellent applicability to multiple structural types of ketones,including aliphatic ketones with diverse substituents,aromatic ketones,and various simple ketones not limited to acetone,with wide applications,easy implementation,low catalyst toxicity,and low cost,cost-effective,and the product is easy to separate and purify.
基金Youth project under the National Social Science Foundation of China(15CJY054)key project in Philosophy and Social Sciences funded by the Chongqing Municipal Education Commission(22SKGH091)。
文摘This study aims to promote the optimization and upgrading of the economic structure in rural areas of China by focusing on the coupling coordination mechanism between digital economy–agriculture integration and rural revitalization.By examining panel data from 30 Chinese provinces,autonomous regions,and municipalities between 2011 and 2022,the research constructs a weight-based evaluation system that integrates subjective and objective methods and a coupling coordination model to reveal its dynamic evolution patterns.Key findings indicate that digital economy–agriculture integration and rural revitalization achieve cross-coupling through critical activities.The impact of digital-agriculture integration on advancing rural revitalization lags by 2–3 years.Although the coupling development degree between the two systems continues to improve,it remains at the stage of primary coordination.Regional disparities are significant,showing a gradient pattern of“high degree of coupling development in the east and low degree of coupling development in the west.”
基金Project supported by the National Natural Science Foun-dation of China(Grant No.62373197)the Natural Science Foundation of the Higher Education Institutions of Jiangsu Province,China(Grant No.23KJB120010)+1 种基金the Industry-University-Research Cooperation Project of Jiangsu Province,China(Grant No.BY20251038)the Cultivation and In-cubation Project of the College of Automation,Nanjing Uni-versity of Posts and Telecommunications.
文摘Multilayer complex dynamical networks,characterized by the intricate topological connections and diverse hierarchical structures,present significant challenges in determining complete structural configurations due to the unique functional attributes and interaction patterns inherent to different layers.This paper addresses the critical question of whether structural information from a known layer can be used to reconstruct the unknown intralayer structure of a target layer within general weighted output-coupling multilayer networks.Building upon the generalized synchronization principle,we propose an innovative reconstruction method that incorporates two essential components in the design of structure observers,the cross-layer coupling modulator and the structural divergence term.A key advantage of the proposed reconstruction method lies in its flexibility to freely designate both the unknown target layer and the known reference layer from the general weighted output-coupling multilayer network.The reduced dependency on full-state observability enables more deployment in engineering applications with partial measurements.Numerical simulations are conducted to validate the effectiveness of the proposed structure reconstruction method.
基金partly supported by the Youth Foundation of the Inner Mongolia Natural Science Foundation[grant number 2024QN06017 and 2025MS06022]the Basic Scientific Research Business Fee Project for Universities in Inner Mongolia[grant numbers 2023XKJX019 and 2023XKJX024]the Central Guidance on Local Science and Technology Development Fund through[grant number 2024ZY0084].
文摘Traffic flow prediction constitutes a fundamental component of Intelligent Transportation Systems(ITS),playing a pivotal role in mitigating congestion,enhancing route optimization,and improving the utilization efficiency of roadway infrastructure.However,existingmethods struggle in complex traffic scenarios due to static spatio-temporal embedding,restricted multi-scale temporal modeling,and weak representation of local spatial interactions.This study proposes Bi-STAT+,an enhanced bidirectional spatio-temporal attention framework to address existing limitations through three principal contributions:(1)an adaptive spatio-temporal embedding module that dynamically adjusts embeddings to capture complex traffic variations;(2)frequency-domain analysis in the temporal dimension for simultaneous high-frequency details and low-frequency trend extraction;and(3)an agent attention mechanism in the spatial dimension that enhances local feature extraction through dynamic weight allocation.Extensive experiments were performed on four distinct datasets,including two publicly benchmark datasets(PEMS04 and PEMS08)and two private datasets collected from Baotou and Chengdu,China.The results demonstrate that Bi-STAT+consistently outperforms existing methods in terms of MAE,RMSE,and MAPE,while maintaining strong robustness against missing data and noise.Furthermore,the results highlight that prediction accuracy improves significantly with higher sampling rates,providing crucial insights for optimizing real-world deployment scenarios.
基金supported by the National Natural Science Foundation of China(Nos.22479092 and 22078190)。
文摘The pseudo-two-dimensional(P2D)model plays an important role in exploring physicochemical mechanisms,predicting the state of health,and improving the fast charge capability for Li-ion batteries(LIBs).However,the fast charge leads to the lithium concentration gradient in the solid and electrolyte phases and the non-uniform electrochemical reaction at the solid/electrolyte interface.In order to decouple charge transfer reactions in LIBs under dynamic conditions,understanding the spatio-temporal resolution of the P2D model is urgently required.Till now,the study of this aspect is still insufficient.This work studies the spatio-temporal resolution for dynamic/static electrochemical impedance spectroscopy(DEIS/SEIS)on multiple scales.In detail,DEIS and SEIS with spatio-temporal resolutions are used to decouple charge transfer reactions in LIBs based on the numerical solution of the P2D model in the frequency domain.The calculated results indicate that decoupling solid diffusion requires a high spatial resolution along the r-direction in particles,decoupling electrolyte diffusion and interfacial transfer reaction requires a high spatial resolution along the x-direction,and decoupling charge transfer reactions in LIBs at an extremely low state of charge(SOC)requires an extremely high temporal resolution along the t-direction.Finally,the optimal range of spatio-temporal resolutions for DEIS/SEIS is derived,and the method to decouple charge transfer reactions with spatio-temporal resolutions is developed.
文摘A series of new chiral amide ligands were prepared from natural amino acids and applied to the copper-catalyzed asymmetric oxidative homocoupling reaction of 3-hydroxy-2-naphthoates.By optimizing the reaction conditions,it was found that when using L3(5 mol%)as the ligand,CuCl(5 mol%)as the catalyst,dichloromethane as the solvent,2,2,6,6-tetramethylpiperidine 1-oxyl(TEMPO)/O2 as the oxidant,and under the reaction condition of 40℃,this method exhibited good substrate tolerance.Under these conditions,a series of chiral 1,1'-bi-2-naphthol(BINOL)derivatives were synthesized with yields of 45%~90%and enantioselectivities ranging from 50∶50 to 97∶3.
基金supported by the National Natural Science Foundation of China(Grant Nos.22193032 and 32401033)the Research Fund of Wenzhou Institute,Chinese Academy of Sciences(Grant Nos.WIUCASQD2020009,WIUCASQD2023005,XSZD2024004,2021HZSY0061,and WIUCASICTP2022)。
文摘The F_(1)-ATPase and V_(1)-ATPase are rotary biomotors.Alignment of their amino acid sequences,which originate from bovine heart mitochondria(1BMF)and Enterococcus hirae(3VR6),respectively,demonstrates that the segment forming the ATP catalytic pocket is highly conserved.Single-molecule experiments,however,have revealed subtle differences in efficiency between the F_(1) and V_(1) motors.Here,we perform both atomistic and coarse-grained molecular dynamics simulations to investigate the mechanochemical coupling and coordination in F_(1) and V_(1) ATPase.Our results show that the correlation between conformational changes in F_(1) is stronger than that in V_(1),indicating that the mechanochemical coupling in F_(1) is tighter than in V_(1).Moreover,the unidirectional rotation of F_(1) is more processive than that of V_(1),which accounts for the higher efficiency observed in F_(1) and explains the occasional backward steps detected in single-molecule experiments on V_(1).
基金supported by the National Science and Tech-nology Major Project,China(No.J2019-II-0012-0032)。
文摘The coupling effects among the flow field,temperature distribution and structural deformation in a turbine cannot be ignored,particularly during flight cycles when the turbine experiences varied operational states.Relying solely on steady-state solutions cannot predict the detrimental effects caused by hysteresis.Consequently,this paper employs a quasi-steady-state fluid-thermalstructure multidisciplinary coupling solution method,integrating transient solid heat conduction with steady-state flow field and static structural deformation solutions.After conducting a numerical simulation of a three-dimensional,five-stage,low-pressure turbine air system,the following conclusions are drawn:when boundary conditions attain high-power states through processes that are numerically identical but in opposite directions,slight variations in solid deformation significantly impact the flow field;when boundary conditions attain high-power states through processes that are directionally consistent but have different numerical values,the influence of the boundary condition change rate on the flow field surpasses that of solid deformation.In terms of turbine design parameters,a large difference in stage-reaction between adjacent stages at the lower radius of the turbine can lead to significant changes in the disc cavity flow field during flight cycles.The difference in the stage-reaction of 0.23 at 10%blade height in adjacent stages may induce severe gas ingress in the stator disc cavity.Thus,it is crucial to minimize this difference and to appropriately extend the duration of the deceleration phase to ensure the turbine's safe operation.
基金supported by the National Key Research and Development Program of China (MOST)(Grant No.2022YFA1402800)the Chinese Academy of Sciences (CAS) Presidents International Fellowship Initiative (PIFI)(Grant No.2025PG0006)+3 种基金the National Natural Science Foundation of China (NSFC)(Grant Nos.51831012,12274437,and 52161160334)the CAS Project for Young Scientists in Basic Research (Grant No.YSBR-084)the CAS Youth Interdisciplinary Teamthe China Postdoctoral Science Foundation (Grant No.2025M773402)。
文摘Based on the Smit-Suhl formula,we propose a universal approach for solving the magnon-magnon coupling problem in bilayer coupled systems(e.g.,antiferromagnets).This method requires only the energy expression,enabling the automatic derivation of analytical expressions for the eigenmatrix elements via symbolic computation,eliminating the need for tedious manual calculations.Using this approach,we investigate the impact of magnetic hysteresis on magnon-magnon coupling in a system with interlayer Dzyaloshinskii-Moriya interaction(DMI).The magnetic hysteresis leads to an asymmetric magnetic field dependence of the resonance frequency and alters the number of degeneracy points between the pure optical and acoustic modes.Moreover,it can result in the coupling strength at the gap of the f–H phase diagram being nearly vanishing,contrary to the conventionally expected maximum.These results deepen the understanding of the effect of interlayer DMI on magnon–magnon coupling and the proposed universal method significantly streamlines the solving process of magnon–magnon coupling problems.
基金supported in part by the Mining Hydraulic Technology and Equipment Engineering Research Center,Liaoning Technical University,Fuxin,China(Grant No.MHTE23-R04)the Fundamental Research Funds for the Central Universities(ID N25BSS068).
文摘This study presents an implicit multiphysics coupling method integrating Computational Fluid Dynamics(CFD),the Multiphase Particle-in-Cell(MPPIC)model,and the Finite Element Method(FEM),implemented with OpenFOAM,CalculiX,and preCICE to simulate fluid-particle-structure interactions with large deformations.Mesh motion in the fluid field is handled using the radial basis function(RBF)method.The particle phase is modeled by MPPIC,where fluid-particle interaction is described through momentum exchange,and inter-particle collisions are characterized by collision stress.The structural field is solved by nonlinear FEM to capture large deformations induced by geometric nonlinearity.Coupling among fields is realized through a partitioned,parallel,and non-intrusive iterative strategy,ensuring stable transfer and convergence of interface forces and displacements.Notably,the influence of particles on the structure is not direct but mediated by the fluid,while structural motion directly affects particle dynamics.The results demonstrate that the proposed approach effectively captures multiphysics interaction processes and provides a valuable reference for numerical modeling of coupled fluid-particle-structure systems.
基金NASA(National Aeronautics and Space Administration)grant 81NSSC19K0306NASA prime contract NAS5-01072+6 种基金AFOSR(Air Force Office of Scientific Research)grant FA9559-16-1-0364NSF(National Science Foundation)grant AGS-2055192NASA grants 80NSSC20K1314,80NSSC20K1316,and 80NSSC21K1407NASA Contract NAS5-02099NASA grants:80NSSC18K1220 and 80NSSC18K0570NASA contracts 80GSFC17C0018,and NAS5-02099NASA award 80NSSC18K122。
文摘Global-and meso-scale dipolarizations are well-known features of Earth’s magnetosphere,but their coupling remains poorly understood.Here,using a new approach that combines two-dimentional(2D)ionospheric field-aligned current(FAC)maps with coordinated observations from a network of magnetospheric satellites,we directly show that individual global-scale dipolarizations can expand from the nightside to,or even into,the dayside.These expansions are enduring(20–30 minutes),slow(2–4 deg/min),and global in extent(up to 12 h in local time),consistent with previous statistical inferences but now explicitly observed.The expanding FACs form a two-sheet current system as described by the Boström II model.In contrast,meso-scale dipolarizations are bursty(a few minutes),fast(several tens deg/min),and localized(several hours in local time),as evidenced by auroral expansions and satellite data.They are associated with the line-current system as described by the Boström I model(i.e.,the substorm current wedge).Notably,meso-scale dipolarizations often emerge near the expanding edge of a global-scale dipolarization,suggesting a dynamic coupling between the two scales.These observations provide a complementary scenario to the simulation-based interpretation that global-scale dipolarizations result from the accumulation of meso-scale dipolarizations.Here,meso-scale dipolarizations appear far less frequently than in simulations and occur around the edge of global-scale dipolarizations.This result implies that meso-scale dipolarizations may be sporadically triggered during the azimuthal expansion of global-scale dipolarizations.
基金Project supported by the National Natural Science Foundation of China(No.12472062)。
文摘In this paper,a theoretical model is established for locally resonant plates with general resonators,and the corresponding governing equation is derived.The model provides a mathematical demonstration of the locally resonant effect,which contains two parts:the first part is induced by translation coupling,and the second part is induced by rotation coupling.The second part cannot be reflected by most existing theoretical models.The analytical solutions of the dynamic response are compared with the direct numerical simulation(DNS)results for two locally resonant plates with different resonator types,thereby validating the general applicability of the present model.The rotation coupling effect leads to the frequency-dependent effective rotational inertia density and anisotropic dispersion relation of the locally resonant plate,as well as the enhancement of the structural vibration suppression ability.
基金Supported by the National Natural Science Foundation of China(11971475)。
文摘An efficient scheme is applied to generate a nonisospectral Botie-Pempinelli-Tu(BPT)integrable hierarchy under the case whereλ_(t)=n∑j=0 k_(j)(t)λ^(-j).Based on an expanding higherdimensional Lie algebra,we obtain a nonisospectral BPT integrable coupling hieararchy.It follws that some new nonisospectral nonlinear systems are obtained by reducing these two nonisospectral BPT hierarchies.Actually,these nonisospectral integrable models that we obtained can enrich the existing integrable models and possibly describe new nonlinear phenomena.
基金supported by the NSFC(52522314,52473200,52450063,52120105006,51925306)the National Key R&D Program of China(2018FYA 0305800)+2 种基金the Key Research Program of Chinese Academy of Sciences(XDPB08-2)the Youth Innovation Promotion Asso-ciation of Chinese Academy of Sciences(2022165)the Fundamental Research Funds for the Central Universities(E3ET1803).
文摘The strong electron-phonon coupling in organic photovoltaic materials significantly impedes exciton transport and promotes charge recombination,thereby exerting a detrimental effect on the overall performance of organic solar cells(OSCs).Mitigating electron-phonon coupling is therefore essential for developing high-performance OSCs.In this work,we introduce two solid additives,1-bromo-3-chloronaphthalene(BCN-1)and 1-chloro-3-bromonaphthalene(BCN-2),into the bulk heterojunction active layer to address this fundamental challenge.We demonstrate that BCN-2 effectively suppresses high-frequency lattice vibrations,which minimizes electron-phonon scattering and thereby promotes efficient and long-range exciton diffusion.As a result,the BCN-2 processed devices exhibit prolonged exciton lifetime and superior charge carrier mobility compared to the control devices.These synergistic improvements in photophysical properties such as charge transport,contribute to a remarkable power conversion efficiency of 19.72%in the PM6:L8-BO-based OSCs.This work underscores the suppression of electron-phonon coupling as a critical and general strategy for advancing the performance of organic photovoltaic devices.
基金supported by Basic Science Research Program through the National Research Foundation of Korea(NRF)funded by the Ministry of Education(RS-2023-00249743).
文摘This study proposes a novel forecasting framework that simultaneously captures the strong periodicity and irregular meteorological fluctuations inherent in solar radiation time series.Existing approaches typically define inter-regional correlations using either simple correlation coefficients or distance-based measures when applying spatio-temporal graph neural networks(STGNNs).However,such definitions are prone to generating spurious correlations due to the dominance of periodic structures.To address this limitation,we adopt the Elastic-Band Transform(EBT)to decompose solar radiation into periodic and amplitude-modulated components,which are then modeled independently with separate graph neural networks.The periodic component,characterized by strong nationwide correlations,is learned with a relatively simple architecture,whereas the amplitude-modulated component is modeled with more complex STGNNs that capture climatological similarities between regions.The predictions from the two components are subsequently recombined to yield final forecasts that integrate both periodic patterns and aperiodic variability.The proposed framework is validated with multiple STGNN architectures,and experimental results demonstrate improved predictive accuracy and interpretability compared to conventional methods.
基金funded Basic Research Projects of Higher Education Institutions in Liaoning Province(JYTZD20230004)Future Industry Frontier Technology Project in Liaoning Province in 2025(2025JH2/101330141)Key Research and Development Program of Liaoning Province in 2025.
文摘With the rapid advancement of electromagnetic launch technology,enhancing the structural stability and thermal resistance of armatures has become essential for improving the overall efficiency and reliability of railgun systems.Traditional aluminum alloy armatures often suffer from severe ablation,deformation,and uneven current distribution under high pulsed currents,which limit their performance and service life.To address these challenges,this study employs the Johnson–Cook constitutive model and the finite element method to develop armature models of aluminum matrix composites with varying heterogeneous graphene volume fractions.The temperature,stress,and strain of the armatures during operation were analyzed to investigate the effects of different graphene volume fractions on the deformation and damage behavior of aluminum matrix composite armatures under the multi-field coupling of electromagnetic,thermal,and structural interactions.The results indicate that,compared to the 6061 aluminum alloy matrix,the graphene-reinforced aluminum matrix composite armature significantly suppresses ablation damage at the tail and throat edges.The incorporation of graphene notably reduces the temperature rise during the armature emission process,increases the muzzle velocity under identical current excitation,and mitigates directional deformation of the armature.The 1 wt.% graphene-reinforced aluminum matrix composite armature demonstrates better agreement with experimental results at a strain rate of 2000 s^(-1),while simultaneously improving stress-strain response,reducing temperature rise,and improving velocity performance.
