The efficiency and stability of catalysts for photocatalytic hydrogen evolution(PHE)are largely governed by the charge transfer behaviors across the heterojunction interfaces.In this study,CuO,a typical semiconductor ...The efficiency and stability of catalysts for photocatalytic hydrogen evolution(PHE)are largely governed by the charge transfer behaviors across the heterojunction interfaces.In this study,CuO,a typical semiconductor featuring a broad spectral absorption range,is successfully employed as the electron acceptor to combine with CdS for constructing a S-scheme heterojunction.The optimized photocatalyst(CdSCuO2∶1)delivers an exceptional hydrogen evolution rate of 18.89 mmol/(g·h),4.15-fold higher compared with bare CdS.X-ray photoelectron spectroscopy(XPS)and ultraviolet-visible diffuse reflection absorption spectroscopy(UV-vis DRS)confirmed the S-scheme band structure of the composites.Moreover,the surface photovoltage(SPV)and electron paramagnetic resonance(EPR)indicated that the photogenerated electrons and photogenerated holes of CdS-CuO2∶1 were respectively transferred to the conduction band(CB)of CdS with a higher reduction potential and the valence band(VB)of CuO with a higher oxidation potential under illumination,as expected for the S-scheme mechanism.Density-functional-theory calculations of the electron density difference(EDD)disclose an interfacial electric field oriented from CdS to CuO.This built-in field suppresses charge recombination and accelerates carrier migration,rationalizing the markedly enhanced PHE activity.This study offers a novel strategy for designing S-scheme heterojunctions with high light harvesting and charge utilization toward sustainable solar-tohydrogen conversion.展开更多
Serbisütherapy(ST)is a distinctive external treatment modality within traditional Mongolian medicine(TMM),historically developed within a nomadic cultural framework.This study presents a comprehensive philologica...Serbisütherapy(ST)is a distinctive external treatment modality within traditional Mongolian medicine(TMM),historically developed within a nomadic cultural framework.This study presents a comprehensive philological and historical analysis of ST,tracing its evolution from early battlefield applications to contemporary clinical use.By critically examining classical Mongolian medical texts alongside modern case studies,we aim to systematize ST’s therapeutic methods,indications,and limitations,while exploring its mechanisms of action through both traditional theory and modern biomedical perspectives.ST has undergone significant transformation,shifting from whole-body cavity immersion in the 13th century to targeted,organ-specific applications in modern practice.Its four primary methods–Covering,Mounted,Organ Placement,and Suction–demonstrate efficacy in treating cold-natured diseases,musculoskeletal disorders,gynecological conditions,and certain emergencies.ST embodies the core principles of TMM,particularly the balance of the“Three Roots”and the correction of cold-induced pathologies through heat.Despite challenges related to standardization,cultural translation,and regulatory acceptance,ST holds translational potential for integrative medicine.Future research should prioritize mechanistic validation,clinical standardization,and the development of biocompatible thermal technologies to bridge traditional practice with modern healthcare systems.展开更多
Exploring the spatial evolution patterns of land use in creative urban tourism complexes provides theoretical and decision-making support to foster creative tourism projects.This study focuses on the Hangzhou Leisure ...Exploring the spatial evolution patterns of land use in creative urban tourism complexes provides theoretical and decision-making support to foster creative tourism projects.This study focuses on the Hangzhou Leisure Expo Garden as a case study,utilizing a land use change index model to analyze the spatial evolution characteristics and dynamic processes of creative urban tourism complexes,as well as to explore their spatial differentiation mechanisms.The analysis indicates that Hangzhou Leisure Expo Garden,initially a derelict industrial area dominated by production and residential land use,has evolved into a creative urban tourism complex with tourism comprehensive service land at its core,going through the pattern evolution processes of“constrained sprawl,”“intensive expansion,”and“random integration.”From the perspective of tourism human-land relationships,the formation of land use evolution patterns in creative urban tourism complexes results from various stakeholders(government,tourism enterprises,residents,tourists,etc.),as humanistic factors,continuously adapting to specific urban spaces,which are considered as geographical elements and have locational advantages and are oriented towards economic and social values.Based on the acquisition of stakeholder interests,the transformation of resource-disadvantaged areas into tourism advantage areas is facilitated,thereby achieving the re-creation of tourism creative space and promoting intensive spatial growth.展开更多
Rural industrial development and ecological civilization transformation are crucial to China's comprehensive advancement of rural revitalization. However, many regions still face the issue of a conflict between ec...Rural industrial development and ecological civilization transformation are crucial to China's comprehensive advancement of rural revitalization. However, many regions still face the issue of a conflict between economic development and ecological protection. Symbiosis theory provides a new perspective for understanding the interactive relationship of rural industry and ecology(RIE). Jiangxi Province, one of China's first national pilot zones for ecological conservation, exemplifies rural areas' typical challenges in balancing industrial development and ecological protection, and has been selected as the study area. By integrating the characteristics of RIE with symbiosis theory, a comprehensive RIE assessment framework was constructed. The comprehensive model, spatial autocorrelation method, and symbiosis theory model were employed to address the spatio-temporal evolution characteristics of RIE, reveal the symbiotic relationship(SR) and the symbiosis types of RIE, and explore the path of symbiotic development between RIE. Results indicated that:(1) Since 2015, RIE has shown an upward trend, with regional differences in ecological development levels gradually shrinking. Significant spatial correlation and agglomeration characteristics exist, but a coordinated regional development pattern has not yet emerged.(2) Overall, the symbiosis degree(SD) between RIE showed a positive trend with narrowing gaps, the symbiosis coefficient(SC) of industry to ecology converged to 0.5 under a positive asymmetric mutualism(PAM) mode, suggesting that their relationship tended to be coordinated. Specifically, rural ecology grew increasingly influential on industry in most counties.(3) Rural areas were classified into different types led by industry-dominated PAM, and various optimization paths were proposed. Future efforts should promote the equalization of the interaction forces between RIE according to local conditions.展开更多
The utilization of iron coke provides a green pathway for low-carbon ironmaking.To uncover the influence mechanism of iron ore on the behavior and kinetics of iron coke gasification,the effect of iron ore on the micro...The utilization of iron coke provides a green pathway for low-carbon ironmaking.To uncover the influence mechanism of iron ore on the behavior and kinetics of iron coke gasification,the effect of iron ore on the microstructure of iron coke was investigated.Furthermore,a comparative study of the gasification reactions between iron coke and coke was conducted through non-isothermal thermogravimetric method.The findings indicate that compared to coke,iron coke exhibits an augmentation in micropores and specific surface area,and the micropores further extend and interconnect.This provides more adsorption sites for CO_(2) molecules during the gasification process,resulting in a reduction in the initial gasification temperature of iron coke.Accelerating the heating rate in non-isothermal gasification can enhance the reactivity of iron coke.The metallic iron reduced from iron ore is embedded in the carbon matrix,reducing the orderliness of the carbon structure,which is primarily responsible for the heightened reactivity of the carbon atoms.The kinetic study indicates that the random pore model can effectively represent the gasification process of iron coke due to its rich pore structure.Moreover,as the proportion of iron ore increases,the activation energy for the carbon gasification gradually decreases,from 246.2 kJ/mol for coke to 192.5 kJ/mol for iron coke 15wt%.展开更多
Gradient magnetic heterointerfaces have injected infinite vitality in optimizing impedance matching,adjusting dielectric/magnetic resonance and promoting electromagnetic(EM)wave absorption,but still exist a significan...Gradient magnetic heterointerfaces have injected infinite vitality in optimizing impedance matching,adjusting dielectric/magnetic resonance and promoting electromagnetic(EM)wave absorption,but still exist a significant challenging in regulating local phase evolution.Herein,accordion-shaped Co/Co_(3)O_(4)@N-doped carbon nanosheets(Co/Co_(3)O_(4)@NC)with gradient magnetic heterointerfaces have been fabricated via the cooperative high-temperature carbonization and lowtemperature oxidation process.The results indicate that the surface epitaxial growth of crystal Co_(3)O_(4) domains on local Co nanoparticles realizes the adjustment of magnetic-heteroatomic components,which are beneficial for optimizing impedance matching and interfacial polarization.Moreover,gradient magnetic heterointerfaces simultaneously realize magnetic coupling,and long-range magnetic diffraction.Specifically,the synthesized Co/Co_(3)O_(4)@NC absorbents display the strong electromagnetic wave attenuation capability of−53.5 dB at a thickness of 3.0 mm with an effective absorption bandwidth of 5.36 GHz,both are superior to those of single magnetic domains embedded in carbon matrix.This design concept provides us an inspiration in optimizing interfacial polarization,regulating magnetic coupling and promoting electromagnetic wave absorption.展开更多
High concentrations of PM_(2.5) are universally considered as a main cause for haze formation. Therefore, it is important to identify the spatial heterogeneity and influencing factors of PM_(2.5) concentrations for re...High concentrations of PM_(2.5) are universally considered as a main cause for haze formation. Therefore, it is important to identify the spatial heterogeneity and influencing factors of PM_(2.5) concentrations for regional air quality control and management. In this study, PM_(2.5) data from 2000 to 2015 was determined from an inversion of NASA atmospheric remote sensing images. Using geo-statistics, geographic detectors, and geo-spatial analysis methods, the spatio-temporal evolution patterns and driving factors of PM_(2.5) concentration in China were evaluated. The main results are as follows.(1) In general, the average concentration of PM_(2.5) in China increased quickly and reached its peak value in 2006; subsequently, concentrations remained between 21.84 and 35.08 μg/m3.(2) PM_(2.5) is strikingly heterogeneous in China, with higher concentrations in the north and east than in the south and west. In particular, areas with relatively high PM_(2.5) concentrations are primarily in four regions, the Huang-Huai-Hai Plain, Lower Yangtze River Delta Plain, Sichuan Basin, and Taklimakan Desert. Among them, Beijing-Tianjin-Hebei Region has the highest concentration of PM_(2.5).(3) The center of gravity of PM_(2.5) has generally moved northeastward, which indicates an increasingly serious haze in eastern China. High-value PM_(2.5) concentrations have moved eastward, while low-value PM_(2.5) has moved westward.(4) Spatial autocorrelation analysis indicates a significantly positive spatial correlation. The "High-High" PM_(2.5) agglomeration areas are distributed in the Huang-Huai-Hai Plain, Fenhe-Weihe River Basin, Sichuan Basin, and Jianghan Plain regions. The "Low-Low" PM_(2.5) agglomeration areas include Inner Mongolia and Heilongjiang, north of the Great Wall, Qinghai-Tibet Plateau, and Taiwan, Hainan, and Fujian and other southeast coastal cities and islands.(5) Geographic detection analysis indicates that both natural and anthropogenic factors account for spatial variations in PM_(2.5) concentration. Geographical location, population density, automobile quantity, industrial discharge, and straw burning are the main driving forces of PM_(2.5) concentration in China.展开更多
Binary composites(ZIF-67/rGO)were synthesized by one-step precipitation method using cobalt nitrate hexahydrate as metal source,2-methylimidazole as organic ligand,and reduced graphene oxide(rGO)as carbon carrier.Then...Binary composites(ZIF-67/rGO)were synthesized by one-step precipitation method using cobalt nitrate hexahydrate as metal source,2-methylimidazole as organic ligand,and reduced graphene oxide(rGO)as carbon carrier.Then Ru3+was introduced for ion exchange,and the porous Ru-doped Co_(3)O_(4)/rGO(Ru-Co_(3)O_(4)/rGO)composite electrocatalyst was prepared by annealing.The phase structure,morphology,and valence state of the catalyst were analyzed by X-ray powder diffraction(XRD),scanning electron microscope(SEM),transmission electron microscopy(TEM),and X-ray photoelectron spectroscopy(XPS).In 1 mol·L^(-1)KOH,the oxygen evolution reaction(OER)performance of the catalyst was measured by linear sweep voltammetry,cyclic voltammetry,and chronoamperometry.The results show that the combination of Ru doping and rGO provides a fast channel for collaborative electron transfer.At the same time,rGO as a carbon carrier can improve the electrical conductivity of Ru-Co_(3)O_(4)particles,and the uniformly dispersed nanoparticles enable the reactants to diffuse freely on the catalyst.The results showed that the electrochemical performance of Ru-Co_(3)O_(4)/rGO was much better than that of Co_(3)O_(4)/rGO,and the overpotential of Ru-Co_(3)O_(4)/rGO was 363.5 mV at the current density of 50 mA·cm^(-2).展开更多
Brazing filler metals are widely applied,which serve as an industrial adhesive in the joining of dissimilar structures.With the continuous emergence of new structures and materials,the demand for novel brazing filler ...Brazing filler metals are widely applied,which serve as an industrial adhesive in the joining of dissimilar structures.With the continuous emergence of new structures and materials,the demand for novel brazing filler metals is ever-increasing.It is of great significance to investigate the optimized composition design methods and to establish systematic design guidelines for brazing filler metals.This study elucidated the fundamental rules for the composition design of brazing filler metals from a three-dimensional perspective encompassing the basic properties of applied brazing filler metals,formability and processability,and overall cost.The basic properties of brazing filler metals refer to their mechanical properties,physicochemical properties,electromagnetic properties,corrosion resistance,and the wettability and fluidity during brazing.The formability and processability of brazing filler metals include the processes of smelting and casting,extrusion,rolling,drawing and ring-making,as well as the processes of granulation,powder production,and the molding of amorphous and microcrystalline structures.The cost of brazing filler metals corresponds to the sum of materials value and manufacturing cost.Improving the comprehensive properties of brazing filler metals requires a comprehensive and systematic consideration of design indicators.Highlighting the unique characteristics of brazing filler metals should focus on relevant technical indicators.Binary or ternary eutectic structures can effectively enhance the flow spreading ability of brazing filler metals,and solid solution structures contribute to the formability.By employing the proposed design guidelines,typical Ag based,Cu based,Zn based brazing filler metals,and Sn based solders were designed and successfully applied in major scientific and engineering projects.展开更多
Ecological land(Eco-land) is a basic resource for human beings to survive, and eco-land use is a strategy, a way to manage the land resource. So, ecologically-sustainable land use is essential for human beings to surv...Ecological land(Eco-land) is a basic resource for human beings to survive, and eco-land use is a strategy, a way to manage the land resource. So, ecologically-sustainable land use is essential for human beings to survive. This paper investigates the spatiotemporal characteristics and mechanisms of urban-rural eco-land using a new and innovative integration way based on eco-land change data in China's Loess Plateau(LP) prefecture level cities and explores factors of eco-land change. The spatial difference characteristic of eco-land among different level cities in the LP is that: small cities > big cities > middle cities. From 2009 to 2016, the eco-land in the LP from the perspective of urban-rural areas has changed significantly. Significant differences of urban-rural eco-land were identified among various urban growth types, and all the cities in the LP were further classified into four types based on eco-land change trend, with type A and B cities identified as the vital zone and major zone. Taking the eco-fragile region Loess Plateau(LP) as an example, our results demonstrated that the migrants to cities in LP could relieve ecological pressures and promote restoration of ecological vegetation. We have demonstrated that urbanization and the influence of government policy can be discerned through the quantification of the spatial-temporal change of eco-land and suggest that combining both urban and rural eco-land can support more effective land use decisions and provide theoretical basis for the practical application of urban planning, policy-making and sustainable development. What's more, governments should strive to population mobility and restore vegetation to sustain this fragile ecological environment.展开更多
The building of the ocean power strategy and the implementation of the blue agriculture plan urgently need to strengthen the sustainable development of marine fishery.Taking vulnerability as the starting point, this p...The building of the ocean power strategy and the implementation of the blue agriculture plan urgently need to strengthen the sustainable development of marine fishery.Taking vulnerability as the starting point, this paper constructs the vulnerability index system of marine fishery industry ecosystem from the aspects of sensitivity and response capacity, and combines the entropy method with the Topsis to comprehensively analyze the spatio-temporal evolution characteristics of vulnerability of marine fishery industry ecosystem in the Bohai Rim Region from 2001 to 2015.The results show that: 1) In the time dimension, from 2001 to 2015, the vulnerability of the marine fishery industry ecosystem in the Bohai Rim Region shows a fluctuant and degressive trend;2) In the spatial dimension, the spatial distribution of the marine fishery industry ecosystem vulnerability in the Bohai Rim Region presents the gradient characteristics which shows high vulnerability in the east and low vulnerability in the west.According to the evolution track of the system’s vulnerability level, the vulnerability of the marine fishery industry ecosystem is divided into ‘declining’ and ‘stable’ types of evolutionary structures;3) The development of marine fishery in the Bohai Rim Region needs to be derived from the marine fishery’s ecological environment and the industrial development mode and structure, which can improve the marine environment remediation efforts, optimize the marine fishery industry structure, vigorously focus on pelagic fishery, and enhance the introduction of marine fishery’s science and technology talents, etc.Then, the marine fishery’s development in the Bohai Rim Region will be moving in the green, circular and sustainable direction.展开更多
The design of cost-effective and efficient metal-free carbon-based catalysts for the hydrogen evolution reaction(HER)is of great significance for increasing the production of clean hydrogen by the electrolysis of alka...The design of cost-effective and efficient metal-free carbon-based catalysts for the hydrogen evolution reaction(HER)is of great significance for increasing the production of clean hydrogen by the electrolysis of alkaline water.Precise control of the electronic structure by heteroatom doping has proven to be efficient for increasing catalytic activity.Nevertheless,both the structural characteristics and the underlying mechanism are not well understood,especially for doping with two different atoms,thus limiting the use of these catalysts.We report the production of phosphorus and nitrogen co-doped hollow carbon nanospheres(HCNs)by the copolymerization of pyrrole and aniline at a Triton X-100 micelle-interface,followed by doping with phytic acid and carbonization.The unique pore structure and defect-rich framework of the HCNs expose numerous active sites.Crucially,the combined effect of graphitic nitrogen and phosphorus-carbon bonds modulate the local electronic structure of adjacent C atoms and facilitates electron transfer.As a res-ult,the HCN carbonized at 1100°C exhibited superior HER activity and an outstanding stability(70 h at a current density of 10 mA cm^(−2))in alkaline water,because of the large number of graphitic nitrogen and phosphorus-carbon bonds.展开更多
Sulfur-doped iron-cobalt tannate nanorods(S-FeCoTA)derived from metal-organic frameworks(MOFs)as electrocatalysts were synthesized via a one-step hydrothermal method.The optimized S-FeCoTA was interlaced by loose nano...Sulfur-doped iron-cobalt tannate nanorods(S-FeCoTA)derived from metal-organic frameworks(MOFs)as electrocatalysts were synthesized via a one-step hydrothermal method.The optimized S-FeCoTA was interlaced by loose nanorods,which had many voids.The S-FeCoTA catalysts exhibited excellent electrochemical oxygen evolution reaction(OER)performance with a low overpotential of 273 mV at 10 mA·cm^(-2)and a small Tafel slope of 36 mV·dec^(-1)in 1 mol·L^(-1)KOH.The potential remained at 1.48 V(vs RHE)at 10 mA·cm^(-2)under continuous testing for 15 h,implying that S-FeCoTA had good stability.The Faraday efficiency of S-FeCoTA was 94%.The outstanding OER activity of S-FeCoTA is attributed to the synergistic effects among S,Fe,and Co,thus promoting electron transfer,reducing the reaction kinetic barrier,and enhancing the OER performance.展开更多
To study the mechanism of rockburst and its spatio-temporal evolution criterion,a rockburst simulation experiment was performed on granite specimens,each with a prefabricated circular hole,under different lateral load...To study the mechanism of rockburst and its spatio-temporal evolution criterion,a rockburst simulation experiment was performed on granite specimens,each with a prefabricated circular hole,under different lateral loads.Using micro camera,acoustic emission(AE)system,and infrared thermal imager,the AE characteristics and thermal radiation temperature migration were studied during the rockburst process.Then,the failure mode and damage evolution of the surrounding rock were analyzed.The results demonstrate that increasing the lateral load can first increase and then reduce the bearing capacity of the hole.In this experiment,the hole failure process could be divided into four periods:quiet,particle ejection,stability failure and collapse.Correspondingly,the AE signals evolved from a calm stage,to have intermittent appearance;then,they were continuous with a sudden increase,and finally increased dramatically.The failure of the surrounding rock was mainly tensile failure,while shear failure tended to first increase and then decrease.Meanwhile,damage to the hole increased gradually during the particle ejection period,whereas damage to the rockburst mainly occurred in the stability failure period.The thermal radiation temperature migration exhibited warming in shallow parts,inward expansion,cooling in the shallow parts with free surface heating,inward expansion,a sudden rise in temperature of the rockburst pits,and finally specimen failure.The initial reinforcement support should fully contribute to surface support.Furthermore,an appropriate tensile capacity and good energy absorption capacity should be established in support systems for high-stress roadways.展开更多
Cities are important carriers of green innovation.The foundation for accelerating China's ecological civilization construction and fostering regionally coordinated and sustainable development is quantitative analy...Cities are important carriers of green innovation.The foundation for accelerating China's ecological civilization construction and fostering regionally coordinated and sustainable development is quantitative analysis of the spatial evolution pattern and influencing factors of urban green innovation,as well as revealing the development differences between regions.This study's research object includes 284 Chinese cities that are at the prefecture level or above,excluding Xizang,Hong Kong,Macao,and Taiwan of China due to incomplete data.The spatial evolution characteristics of urban green innovation in China between 2005 and 2021 are comprehensively described using the gravity center model and boxplot analysis.The factors that affect urban green innovation are examined using the spatial Durbin model(SDM).The findings indicate that:1)over the period of the study,the gravity center of urban green innovation in China has always been distributed in the Henan-Anhui border region,showing a migration characteristic of‘initially shifting northeast,subsequently southeast',and the migration speed has gradually increased.2)Although there are also noticeable disparities in east-west,the north-south gap is the main cause of the shift in China's urban green innovation gravity center.The primary areas of urban green innovation in China are the cities with green innovation levels higher than the median.3)The main influencing factor of urban green innovation is the industrial structure level.The effect of the financial development level,the government intervention level,and the openness to the outside world degree on urban green innovation is weakened in turn.The environmental regulation degree is not truly influencing urban green innovation.The impact of various factors on green innovation across cities of different sizes,exhibiting heterogeneity.This study is conducive to broadening the academic community's comprehension of the spatial evolution characteristics of urban green innovation and offering a theoretical framework for developing policies for the all-encompassing green transformation of social and economic growth.展开更多
Several physical mechanisms of earthquake nucleation,such as pre-slip,cascade triggering,aseismic slip,and fluid-driven models,have been proposed.However,it is still not clear which model plays the most important role...Several physical mechanisms of earthquake nucleation,such as pre-slip,cascade triggering,aseismic slip,and fluid-driven models,have been proposed.However,it is still not clear which model plays the most important role in driving foreshocks and mainshock nucleation for given cases.In this study,we focus on the relationship between an intensive earthquake swarm that started beneath the Noto Peninsula in Central Japan since November 2020 and the nucleation of the 2024 M 7.6 Noto Hanto earthquake.We relocate earthquakes listed in the standard Japan Meteorological Agency(JMA)catalog since 2018 with the double-different relocation method.Relocated seismicity revealed that the 2024 M 7.6 mainshock likely ruptured a thrust fault above a parallel fault where the M 6.5 Suzu earthquake occurred in May 2023.We find possible along-strike and along-dip expansion of seismicity in the first few months at the beginning of the swarm sequence,while no obvious migration pattern in the last few days before the M 7.6 mainshock was observed.Several smaller events occurred in between the M 5.5 and M 4.6 foreshocks that occurred about 4min and 2 min before the M 7.6 mainshock.The Coulomb stress changes from the M 5.5 foreshock were negative at the hypocenter of the M 7.6 mainshock,which is inconsistent with a simple cascade triggering model.Moreover,an M 5.9 foreshock was identified in the JMA catalog 14 s before the mainshock.Results from backprojection of high-frequency teleseismic P waves show a prolonged initial rupture process near the mainshock hypocenter lasting for~25 s,before propagating bilaterally outward.Our results suggest a complex evolution process linking the earthquake swarm to the nucleation of the M 7.6 mainshock at a region of complex structures associated with the bend of a mapped large-scale reverse fault.A combination of fluid migration,aseismic slip and elastic stress triggering likely work in concert to drive both the prolonged earthquake swarm and the nucleation of the M 7.6 mainshock.展开更多
This paper uses data for the period 1950-2050 compiled by the United Nations Population Division together with methods including spatial autocorrelation analysis, hie- rarchical cluster analysis and the standard devia...This paper uses data for the period 1950-2050 compiled by the United Nations Population Division together with methods including spatial autocorrelation analysis, hie- rarchical cluster analysis and the standard deviational ellipse, to analyze the spatio-temporal evolution of population and urbanization in the 75 countries located along the routes of the Silk Road Economic Belt and the 21st-century Maritime Silk Road, to identify future popula- tion growth and urbanization hotspots. The results reveal the following： First, in 2015, the majority of Belt and Road countries in Europe, South Asia and Southeast Asia had high population densities, whereas most countries in Central Asia, North Africa and West Asia, as well as Russia and Mongolia, had low population densities; the majority of countries in South Asia, Southeast Asia, Central Asia, West Asia and North Africa had rapid population growth, whereas many countries in Europe had negative population growth; and five Belt and Road countries are in the initial stage of urbanization, 44 countries are in the acceleration stage of urbanization, and 26 are in the terminal stage of urbanization. Second, in the century from 1950 to 2050, the mean center of the study area＇s population is consistently located in the border region between India and China. Prior to 2000, the trajectory of the mean center was from northwest to southeast, but from 2000 it is on a southward trajectory, as the population of the study area becomes more concentrated. Future population growth hotspots are predicted to be in South Asia, West Asia and Southeast Asia, and hotspot countries for the period 2015-2030 include India, China, Pakistan and Indonesia, though China will move into nega- tive population growth after 2030. Third, the overall urban population of Belt and Road coun- tries increased from 22% in 1950 to 49% in 2015, and it is expected to gradually catch up with the world average, reaching 64% in 2050. The different levels of urbanization in different countries display significant spatial dependency, and in the hundred-year period under con-sideration, this dependency increases before eventually weakening. Fourth, between 2015 and 2030, urban population hotspots will include Thailand, China, Laos and Albania, while Kuwait, Cyprus, Qatar and Estonia will be urban ＂coldspots.＂ Fifth, there were 293 cities with populations over 1 million located along the Belt and Road in 2015, but that number Js ex- pected to increase to 377 by 2030. Of those, 43 will be in China, with many of the others located in India, Indonesia and the eastern Mediterranean.展开更多
Titanium(Ti)and its alloys are frequently utilized as critical components in a variety of engineering ap-plications because of their high specific strength and excellent corrosion resistance.Compared to conven-tional ...Titanium(Ti)and its alloys are frequently utilized as critical components in a variety of engineering ap-plications because of their high specific strength and excellent corrosion resistance.Compared to conven-tional surface strengthening technologies,laser shock peening(LSP)has increasingly attracted attention from researchers and industries,since it significantly improves the surface strength,biocompatibility,fa-tigue resistance,and anti-corrosion ability of Ti and its alloys.Despite numerous studies that have been carried out to elucidate the effects of LSP on microstructural evolution and mechanical properties of Ti and its alloys in recent years,a comprehensive review of recent advancements in the field of Ti and its alloys subjected to LSP is still lacking.In this review,the standard LSP and the novel process designs of LSP assisted by thermal,cryogenic,electropulsing and magnetic fields are discussed and compared.Microstructural evolution,with focuses on the dislocation dynamics,deformation twinning,grain refine-ment and surface amorphization,during LSP processing of Ti alloys is reviewed.Furthermore,the en-hanced engineering performance of the L SP-processed(L SPed)Ti alloys,including surface hardness,wear resistance,fatigue life and corrosion resistance are summarized.Finally,this review concludes by present-ing an overview of the current challenges encountered in this field and offering insights into anticipated future trends.展开更多
The characterization techniques were employed like transmission electron microscope,X-ray diffraction and microstructural characterization to investigate microstructural evolution and impact of precipitate-phase preci...The characterization techniques were employed like transmission electron microscope,X-ray diffraction and microstructural characterization to investigate microstructural evolution and impact of precipitate-phase precipitation on strength and toughness of a self-developed 32Si_(2)CrNi_(2)MoVNb steel during the quenching and tempering process.Research outputs indicated that the steel microstructure under the quenching state could be composed of martensite with a high dislocation density,a small amount of residual austenite,and many dispersed spherical MC carbides.In details,after tempering at 200℃,fine needle-shapedε-carbides would precipitate,which may improve yield strength and toughness of the steel.However,as compared to that after tempering at 200℃,the average length of needle-shapedε-carbides was found to increase to 144.1±4 from 134.1±3 nm after tempering at 340℃.As a result,the yield strength may increase to 1505±40 MPa,and the impact absorption energy(V-notch)may also decrease.Moreover,after tempering at 450℃,thoseε-carbides in the steel may transform into coarse rod-shaped cementite,and dislocation recoveries at such high tempering temperature may lead to decrease of strength and toughness of the steel.Finally,the following properties could be obtained:a yield strength of 1440±35 MPa,an ultimate tensile strength of 1864±50 MPa and an impact absorption energy of 45.9±4 J,by means of rational composition design and microstructural control.展开更多
In today's world, the innovation of science and technology has become the key support for improving comprehensive national strength and changing the mode of social production and lifestyle. The country that posses...In today's world, the innovation of science and technology has become the key support for improving comprehensive national strength and changing the mode of social production and lifestyle. The country that possesses world-class scientific and technological innovation cities maximizes the attraction of global innovation factors and wins a strategic initiative in international competition. Based on the urban zip code geodatabase, an evaluation system of urban innovation with the perspective of innovation outputs, and the spatial evolutionary mode, concerning the structure of innovation space of Shanghai and Beijing from 1991 to 2014, was developed. The results of the research indicated that the zip code geodatabase provided a new perspective for studying the evolving spatial structure of urban innovation. The resulting evaluation of the spatial structure of urban innovation using the urban zip code geodatabase established by connecting random edge points, was relatively effective. The study illustrates the value of this methodology. During the study period, the spatial structure of innovation of Shanghai and Beijing demonstrated many common features: with the increase in urban space units participating in innovation year by year, the overall gap of regional innovation outputs has narrowed, and the trend towards spatial agglomeration has strengthened. The evolving spatial structure of innovation of Shanghai and Beijing demonstrated differences between the common features during the 25 years as well: in the trend towards the suburbanization of innovation resources, the spatial structure of innovation of Shanghai evolved from a single-core to a multi-core structure. A radiation effect related to traffic arteries as spatial diffusion corridors was prominent. Accordingly, a spatial correlation effect of its innovation outputs also indicated a hollowness in the city center; the spatial structure of innovation of Beijing had a single-core oriented structure all the way. Together with the tendency for innovation resources to be agglomerated in the city center, the spatial correlation effect of innovation outputs reflected the characteristics of the evolutionary feature where "rural area encircles cities". The innovation spatial structure of Shanghai and Beijing have intrinsic consistency with the spatial structure of their respective regions(Yangtze River Delta urban agglomeration and Beijing-Tianjin-Hebei metropolitan region), which suggested that the principle of proportional and disproportional distribution of a city-scale pattern of technological and innovational activities is closely related to its regional innovation pattern.展开更多
文摘The efficiency and stability of catalysts for photocatalytic hydrogen evolution(PHE)are largely governed by the charge transfer behaviors across the heterojunction interfaces.In this study,CuO,a typical semiconductor featuring a broad spectral absorption range,is successfully employed as the electron acceptor to combine with CdS for constructing a S-scheme heterojunction.The optimized photocatalyst(CdSCuO2∶1)delivers an exceptional hydrogen evolution rate of 18.89 mmol/(g·h),4.15-fold higher compared with bare CdS.X-ray photoelectron spectroscopy(XPS)and ultraviolet-visible diffuse reflection absorption spectroscopy(UV-vis DRS)confirmed the S-scheme band structure of the composites.Moreover,the surface photovoltage(SPV)and electron paramagnetic resonance(EPR)indicated that the photogenerated electrons and photogenerated holes of CdS-CuO2∶1 were respectively transferred to the conduction band(CB)of CdS with a higher reduction potential and the valence band(VB)of CuO with a higher oxidation potential under illumination,as expected for the S-scheme mechanism.Density-functional-theory calculations of the electron density difference(EDD)disclose an interfacial electric field oriented from CdS to CuO.This built-in field suppresses charge recombination and accelerates carrier migration,rationalizing the markedly enhanced PHE activity.This study offers a novel strategy for designing S-scheme heterojunctions with high light harvesting and charge utilization toward sustainable solar-tohydrogen conversion.
基金supported by The China Ethnic Medicine Association Research Grant(No.2023MY055-81)Science and Technology Program of the Joint Fund of Scientific Research for the Public Hospitals of Inner Mongolia Academy of Medical Sciences(2023GLLHD177,2023GLLH0174)Inner Mongolia Autonomous Region Regional Medical Center for Specialized Care(2025).
文摘Serbisütherapy(ST)is a distinctive external treatment modality within traditional Mongolian medicine(TMM),historically developed within a nomadic cultural framework.This study presents a comprehensive philological and historical analysis of ST,tracing its evolution from early battlefield applications to contemporary clinical use.By critically examining classical Mongolian medical texts alongside modern case studies,we aim to systematize ST’s therapeutic methods,indications,and limitations,while exploring its mechanisms of action through both traditional theory and modern biomedical perspectives.ST has undergone significant transformation,shifting from whole-body cavity immersion in the 13th century to targeted,organ-specific applications in modern practice.Its four primary methods–Covering,Mounted,Organ Placement,and Suction–demonstrate efficacy in treating cold-natured diseases,musculoskeletal disorders,gynecological conditions,and certain emergencies.ST embodies the core principles of TMM,particularly the balance of the“Three Roots”and the correction of cold-induced pathologies through heat.Despite challenges related to standardization,cultural translation,and regulatory acceptance,ST holds translational potential for integrative medicine.Future research should prioritize mechanistic validation,clinical standardization,and the development of biocompatible thermal technologies to bridge traditional practice with modern healthcare systems.
文摘Exploring the spatial evolution patterns of land use in creative urban tourism complexes provides theoretical and decision-making support to foster creative tourism projects.This study focuses on the Hangzhou Leisure Expo Garden as a case study,utilizing a land use change index model to analyze the spatial evolution characteristics and dynamic processes of creative urban tourism complexes,as well as to explore their spatial differentiation mechanisms.The analysis indicates that Hangzhou Leisure Expo Garden,initially a derelict industrial area dominated by production and residential land use,has evolved into a creative urban tourism complex with tourism comprehensive service land at its core,going through the pattern evolution processes of“constrained sprawl,”“intensive expansion,”and“random integration.”From the perspective of tourism human-land relationships,the formation of land use evolution patterns in creative urban tourism complexes results from various stakeholders(government,tourism enterprises,residents,tourists,etc.),as humanistic factors,continuously adapting to specific urban spaces,which are considered as geographical elements and have locational advantages and are oriented towards economic and social values.Based on the acquisition of stakeholder interests,the transformation of resource-disadvantaged areas into tourism advantage areas is facilitated,thereby achieving the re-creation of tourism creative space and promoting intensive spatial growth.
基金supported by the National Natural Science Foundation of China (No.42361050,42201232)Humanities and Social Sciences Research Project of Jiangxi Colleges and Universities (No.JC24211)+1 种基金Science and Technology Research Project of Jiangxi Provincial Department of Education (No.GJJ2200553)Jiangxi provincial Social Science Foundation of China (No.23JL11)。
文摘Rural industrial development and ecological civilization transformation are crucial to China's comprehensive advancement of rural revitalization. However, many regions still face the issue of a conflict between economic development and ecological protection. Symbiosis theory provides a new perspective for understanding the interactive relationship of rural industry and ecology(RIE). Jiangxi Province, one of China's first national pilot zones for ecological conservation, exemplifies rural areas' typical challenges in balancing industrial development and ecological protection, and has been selected as the study area. By integrating the characteristics of RIE with symbiosis theory, a comprehensive RIE assessment framework was constructed. The comprehensive model, spatial autocorrelation method, and symbiosis theory model were employed to address the spatio-temporal evolution characteristics of RIE, reveal the symbiotic relationship(SR) and the symbiosis types of RIE, and explore the path of symbiotic development between RIE. Results indicated that:(1) Since 2015, RIE has shown an upward trend, with regional differences in ecological development levels gradually shrinking. Significant spatial correlation and agglomeration characteristics exist, but a coordinated regional development pattern has not yet emerged.(2) Overall, the symbiosis degree(SD) between RIE showed a positive trend with narrowing gaps, the symbiosis coefficient(SC) of industry to ecology converged to 0.5 under a positive asymmetric mutualism(PAM) mode, suggesting that their relationship tended to be coordinated. Specifically, rural ecology grew increasingly influential on industry in most counties.(3) Rural areas were classified into different types led by industry-dominated PAM, and various optimization paths were proposed. Future efforts should promote the equalization of the interaction forces between RIE according to local conditions.
基金financially supported by the National Science Foundation of China(Nos.51974212 and 52274316)the China Baowu Low Carbon Metallurgy Innovation Foundation(No.BWLCF202116)+1 种基金the Science and Technology Major Project of Wuhan(No.2023020302020572)the Foundation of Key Laboratory for Ferrous Metallurgy and Resources Utilization of Ministry of Education(No.FMRUlab23-04)。
文摘The utilization of iron coke provides a green pathway for low-carbon ironmaking.To uncover the influence mechanism of iron ore on the behavior and kinetics of iron coke gasification,the effect of iron ore on the microstructure of iron coke was investigated.Furthermore,a comparative study of the gasification reactions between iron coke and coke was conducted through non-isothermal thermogravimetric method.The findings indicate that compared to coke,iron coke exhibits an augmentation in micropores and specific surface area,and the micropores further extend and interconnect.This provides more adsorption sites for CO_(2) molecules during the gasification process,resulting in a reduction in the initial gasification temperature of iron coke.Accelerating the heating rate in non-isothermal gasification can enhance the reactivity of iron coke.The metallic iron reduced from iron ore is embedded in the carbon matrix,reducing the orderliness of the carbon structure,which is primarily responsible for the heightened reactivity of the carbon atoms.The kinetic study indicates that the random pore model can effectively represent the gasification process of iron coke due to its rich pore structure.Moreover,as the proportion of iron ore increases,the activation energy for the carbon gasification gradually decreases,from 246.2 kJ/mol for coke to 192.5 kJ/mol for iron coke 15wt%.
基金financially supported by the National Natural Science Foundation of China(52373271)Science,Technology and Innovation Commission of Shenzhen Municipality under Grant(KCXFZ20201221173004012)+1 种基金National Key Research and Development Program of Shaanxi Province(No.2023-YBNY-271)Open Testing Foundation of the Analytical&Testing Center of Northwestern Polytechnical University(2023T019).
文摘Gradient magnetic heterointerfaces have injected infinite vitality in optimizing impedance matching,adjusting dielectric/magnetic resonance and promoting electromagnetic(EM)wave absorption,but still exist a significant challenging in regulating local phase evolution.Herein,accordion-shaped Co/Co_(3)O_(4)@N-doped carbon nanosheets(Co/Co_(3)O_(4)@NC)with gradient magnetic heterointerfaces have been fabricated via the cooperative high-temperature carbonization and lowtemperature oxidation process.The results indicate that the surface epitaxial growth of crystal Co_(3)O_(4) domains on local Co nanoparticles realizes the adjustment of magnetic-heteroatomic components,which are beneficial for optimizing impedance matching and interfacial polarization.Moreover,gradient magnetic heterointerfaces simultaneously realize magnetic coupling,and long-range magnetic diffraction.Specifically,the synthesized Co/Co_(3)O_(4)@NC absorbents display the strong electromagnetic wave attenuation capability of−53.5 dB at a thickness of 3.0 mm with an effective absorption bandwidth of 5.36 GHz,both are superior to those of single magnetic domains embedded in carbon matrix.This design concept provides us an inspiration in optimizing interfacial polarization,regulating magnetic coupling and promoting electromagnetic wave absorption.
基金The Strategic Priority Research Program of the Chinese Academy of Sciences,No.XDA19040401China Postdoctoral Science Foundation,No.2016M600121+1 种基金National Natural Science Foundation of China,No.41701173,No.41501137The State Key Laboratory of Resources and Environmental Information System
文摘High concentrations of PM_(2.5) are universally considered as a main cause for haze formation. Therefore, it is important to identify the spatial heterogeneity and influencing factors of PM_(2.5) concentrations for regional air quality control and management. In this study, PM_(2.5) data from 2000 to 2015 was determined from an inversion of NASA atmospheric remote sensing images. Using geo-statistics, geographic detectors, and geo-spatial analysis methods, the spatio-temporal evolution patterns and driving factors of PM_(2.5) concentration in China were evaluated. The main results are as follows.(1) In general, the average concentration of PM_(2.5) in China increased quickly and reached its peak value in 2006; subsequently, concentrations remained between 21.84 and 35.08 μg/m3.(2) PM_(2.5) is strikingly heterogeneous in China, with higher concentrations in the north and east than in the south and west. In particular, areas with relatively high PM_(2.5) concentrations are primarily in four regions, the Huang-Huai-Hai Plain, Lower Yangtze River Delta Plain, Sichuan Basin, and Taklimakan Desert. Among them, Beijing-Tianjin-Hebei Region has the highest concentration of PM_(2.5).(3) The center of gravity of PM_(2.5) has generally moved northeastward, which indicates an increasingly serious haze in eastern China. High-value PM_(2.5) concentrations have moved eastward, while low-value PM_(2.5) has moved westward.(4) Spatial autocorrelation analysis indicates a significantly positive spatial correlation. The "High-High" PM_(2.5) agglomeration areas are distributed in the Huang-Huai-Hai Plain, Fenhe-Weihe River Basin, Sichuan Basin, and Jianghan Plain regions. The "Low-Low" PM_(2.5) agglomeration areas include Inner Mongolia and Heilongjiang, north of the Great Wall, Qinghai-Tibet Plateau, and Taiwan, Hainan, and Fujian and other southeast coastal cities and islands.(5) Geographic detection analysis indicates that both natural and anthropogenic factors account for spatial variations in PM_(2.5) concentration. Geographical location, population density, automobile quantity, industrial discharge, and straw burning are the main driving forces of PM_(2.5) concentration in China.
文摘Binary composites(ZIF-67/rGO)were synthesized by one-step precipitation method using cobalt nitrate hexahydrate as metal source,2-methylimidazole as organic ligand,and reduced graphene oxide(rGO)as carbon carrier.Then Ru3+was introduced for ion exchange,and the porous Ru-doped Co_(3)O_(4)/rGO(Ru-Co_(3)O_(4)/rGO)composite electrocatalyst was prepared by annealing.The phase structure,morphology,and valence state of the catalyst were analyzed by X-ray powder diffraction(XRD),scanning electron microscope(SEM),transmission electron microscopy(TEM),and X-ray photoelectron spectroscopy(XPS).In 1 mol·L^(-1)KOH,the oxygen evolution reaction(OER)performance of the catalyst was measured by linear sweep voltammetry,cyclic voltammetry,and chronoamperometry.The results show that the combination of Ru doping and rGO provides a fast channel for collaborative electron transfer.At the same time,rGO as a carbon carrier can improve the electrical conductivity of Ru-Co_(3)O_(4)particles,and the uniformly dispersed nanoparticles enable the reactants to diffuse freely on the catalyst.The results showed that the electrochemical performance of Ru-Co_(3)O_(4)/rGO was much better than that of Co_(3)O_(4)/rGO,and the overpotential of Ru-Co_(3)O_(4)/rGO was 363.5 mV at the current density of 50 mA·cm^(-2).
基金National Natural Science Foundation of China(U22A20191)。
文摘Brazing filler metals are widely applied,which serve as an industrial adhesive in the joining of dissimilar structures.With the continuous emergence of new structures and materials,the demand for novel brazing filler metals is ever-increasing.It is of great significance to investigate the optimized composition design methods and to establish systematic design guidelines for brazing filler metals.This study elucidated the fundamental rules for the composition design of brazing filler metals from a three-dimensional perspective encompassing the basic properties of applied brazing filler metals,formability and processability,and overall cost.The basic properties of brazing filler metals refer to their mechanical properties,physicochemical properties,electromagnetic properties,corrosion resistance,and the wettability and fluidity during brazing.The formability and processability of brazing filler metals include the processes of smelting and casting,extrusion,rolling,drawing and ring-making,as well as the processes of granulation,powder production,and the molding of amorphous and microcrystalline structures.The cost of brazing filler metals corresponds to the sum of materials value and manufacturing cost.Improving the comprehensive properties of brazing filler metals requires a comprehensive and systematic consideration of design indicators.Highlighting the unique characteristics of brazing filler metals should focus on relevant technical indicators.Binary or ternary eutectic structures can effectively enhance the flow spreading ability of brazing filler metals,and solid solution structures contribute to the formability.By employing the proposed design guidelines,typical Ag based,Cu based,Zn based brazing filler metals,and Sn based solders were designed and successfully applied in major scientific and engineering projects.
基金funded by the National Key Research and Development Program of China (Grant No.2017YFC0504701)National Natural Science Foundation of China (Grant Nos.41130748 and 41471143)the National Social Science Foundation of China (Grant No 15ZDA021)
文摘Ecological land(Eco-land) is a basic resource for human beings to survive, and eco-land use is a strategy, a way to manage the land resource. So, ecologically-sustainable land use is essential for human beings to survive. This paper investigates the spatiotemporal characteristics and mechanisms of urban-rural eco-land using a new and innovative integration way based on eco-land change data in China's Loess Plateau(LP) prefecture level cities and explores factors of eco-land change. The spatial difference characteristic of eco-land among different level cities in the LP is that: small cities > big cities > middle cities. From 2009 to 2016, the eco-land in the LP from the perspective of urban-rural areas has changed significantly. Significant differences of urban-rural eco-land were identified among various urban growth types, and all the cities in the LP were further classified into four types based on eco-land change trend, with type A and B cities identified as the vital zone and major zone. Taking the eco-fragile region Loess Plateau(LP) as an example, our results demonstrated that the migrants to cities in LP could relieve ecological pressures and promote restoration of ecological vegetation. We have demonstrated that urbanization and the influence of government policy can be discerned through the quantification of the spatial-temporal change of eco-land and suggest that combining both urban and rural eco-land can support more effective land use decisions and provide theoretical basis for the practical application of urban planning, policy-making and sustainable development. What's more, governments should strive to population mobility and restore vegetation to sustain this fragile ecological environment.
基金Under the auspices of the National Natural Science Foundation of China(No.41201114,41976207)Finance Department of Liaoning Province(No.18C021)
文摘The building of the ocean power strategy and the implementation of the blue agriculture plan urgently need to strengthen the sustainable development of marine fishery.Taking vulnerability as the starting point, this paper constructs the vulnerability index system of marine fishery industry ecosystem from the aspects of sensitivity and response capacity, and combines the entropy method with the Topsis to comprehensively analyze the spatio-temporal evolution characteristics of vulnerability of marine fishery industry ecosystem in the Bohai Rim Region from 2001 to 2015.The results show that: 1) In the time dimension, from 2001 to 2015, the vulnerability of the marine fishery industry ecosystem in the Bohai Rim Region shows a fluctuant and degressive trend;2) In the spatial dimension, the spatial distribution of the marine fishery industry ecosystem vulnerability in the Bohai Rim Region presents the gradient characteristics which shows high vulnerability in the east and low vulnerability in the west.According to the evolution track of the system’s vulnerability level, the vulnerability of the marine fishery industry ecosystem is divided into ‘declining’ and ‘stable’ types of evolutionary structures;3) The development of marine fishery in the Bohai Rim Region needs to be derived from the marine fishery’s ecological environment and the industrial development mode and structure, which can improve the marine environment remediation efforts, optimize the marine fishery industry structure, vigorously focus on pelagic fishery, and enhance the introduction of marine fishery’s science and technology talents, etc.Then, the marine fishery’s development in the Bohai Rim Region will be moving in the green, circular and sustainable direction.
基金financially supported by the project of the National Natural Science Foundation of China(52322203)the Key Research and Development Program of Shaanxi Province(2024GHZDXM-21)。
文摘The design of cost-effective and efficient metal-free carbon-based catalysts for the hydrogen evolution reaction(HER)is of great significance for increasing the production of clean hydrogen by the electrolysis of alkaline water.Precise control of the electronic structure by heteroatom doping has proven to be efficient for increasing catalytic activity.Nevertheless,both the structural characteristics and the underlying mechanism are not well understood,especially for doping with two different atoms,thus limiting the use of these catalysts.We report the production of phosphorus and nitrogen co-doped hollow carbon nanospheres(HCNs)by the copolymerization of pyrrole and aniline at a Triton X-100 micelle-interface,followed by doping with phytic acid and carbonization.The unique pore structure and defect-rich framework of the HCNs expose numerous active sites.Crucially,the combined effect of graphitic nitrogen and phosphorus-carbon bonds modulate the local electronic structure of adjacent C atoms and facilitates electron transfer.As a res-ult,the HCN carbonized at 1100°C exhibited superior HER activity and an outstanding stability(70 h at a current density of 10 mA cm^(−2))in alkaline water,because of the large number of graphitic nitrogen and phosphorus-carbon bonds.
文摘Sulfur-doped iron-cobalt tannate nanorods(S-FeCoTA)derived from metal-organic frameworks(MOFs)as electrocatalysts were synthesized via a one-step hydrothermal method.The optimized S-FeCoTA was interlaced by loose nanorods,which had many voids.The S-FeCoTA catalysts exhibited excellent electrochemical oxygen evolution reaction(OER)performance with a low overpotential of 273 mV at 10 mA·cm^(-2)and a small Tafel slope of 36 mV·dec^(-1)in 1 mol·L^(-1)KOH.The potential remained at 1.48 V(vs RHE)at 10 mA·cm^(-2)under continuous testing for 15 h,implying that S-FeCoTA had good stability.The Faraday efficiency of S-FeCoTA was 94%.The outstanding OER activity of S-FeCoTA is attributed to the synergistic effects among S,Fe,and Co,thus promoting electron transfer,reducing the reaction kinetic barrier,and enhancing the OER performance.
基金Project(2017YFC0603003)supported by the National Key Research and Development Project of ChinaProjects(51974009,51674008)supported by the National Natural Science Foundation of China+3 种基金Project(201904a07020010)supported by the Key Research and Development Program of Anhui Province,ChinaProject(2018D187)supported by the Leading Talent Project of Anhui“Special Support Program”,Anhui Provincial Academic and Technology Leaders Research Activities Funding,ChinaProject(gxbjZD2016051)supported by the Excellence Talent Training Program of High School,ChinaProject(2019CX2008)supported by the Graduate Innovation Fund of Anhui University of Science and Technology,China。
文摘To study the mechanism of rockburst and its spatio-temporal evolution criterion,a rockburst simulation experiment was performed on granite specimens,each with a prefabricated circular hole,under different lateral loads.Using micro camera,acoustic emission(AE)system,and infrared thermal imager,the AE characteristics and thermal radiation temperature migration were studied during the rockburst process.Then,the failure mode and damage evolution of the surrounding rock were analyzed.The results demonstrate that increasing the lateral load can first increase and then reduce the bearing capacity of the hole.In this experiment,the hole failure process could be divided into four periods:quiet,particle ejection,stability failure and collapse.Correspondingly,the AE signals evolved from a calm stage,to have intermittent appearance;then,they were continuous with a sudden increase,and finally increased dramatically.The failure of the surrounding rock was mainly tensile failure,while shear failure tended to first increase and then decrease.Meanwhile,damage to the hole increased gradually during the particle ejection period,whereas damage to the rockburst mainly occurred in the stability failure period.The thermal radiation temperature migration exhibited warming in shallow parts,inward expansion,cooling in the shallow parts with free surface heating,inward expansion,a sudden rise in temperature of the rockburst pits,and finally specimen failure.The initial reinforcement support should fully contribute to surface support.Furthermore,an appropriate tensile capacity and good energy absorption capacity should be established in support systems for high-stress roadways.
基金Under the auspices of National Natural Science Foundation of China(No.42371192)Natural Science Foundation of Hunan Province(No.2023JJ30100)Social Science Foundation of Hunan Province(No.23ZDAJ023,23YBA133)。
文摘Cities are important carriers of green innovation.The foundation for accelerating China's ecological civilization construction and fostering regionally coordinated and sustainable development is quantitative analysis of the spatial evolution pattern and influencing factors of urban green innovation,as well as revealing the development differences between regions.This study's research object includes 284 Chinese cities that are at the prefecture level or above,excluding Xizang,Hong Kong,Macao,and Taiwan of China due to incomplete data.The spatial evolution characteristics of urban green innovation in China between 2005 and 2021 are comprehensively described using the gravity center model and boxplot analysis.The factors that affect urban green innovation are examined using the spatial Durbin model(SDM).The findings indicate that:1)over the period of the study,the gravity center of urban green innovation in China has always been distributed in the Henan-Anhui border region,showing a migration characteristic of‘initially shifting northeast,subsequently southeast',and the migration speed has gradually increased.2)Although there are also noticeable disparities in east-west,the north-south gap is the main cause of the shift in China's urban green innovation gravity center.The primary areas of urban green innovation in China are the cities with green innovation levels higher than the median.3)The main influencing factor of urban green innovation is the industrial structure level.The effect of the financial development level,the government intervention level,and the openness to the outside world degree on urban green innovation is weakened in turn.The environmental regulation degree is not truly influencing urban green innovation.The impact of various factors on green innovation across cities of different sizes,exhibiting heterogeneity.This study is conducive to broadening the academic community's comprehension of the spatial evolution characteristics of urban green innovation and offering a theoretical framework for developing policies for the all-encompassing green transformation of social and economic growth.
基金partially supported by U.S.National Science Foundation grants EAR1925965 and RISE-2425889support from the European Research Council under the European Union Horizon 2020 research and innovation program(grant agreement no.742335,FIMAGE)。
文摘Several physical mechanisms of earthquake nucleation,such as pre-slip,cascade triggering,aseismic slip,and fluid-driven models,have been proposed.However,it is still not clear which model plays the most important role in driving foreshocks and mainshock nucleation for given cases.In this study,we focus on the relationship between an intensive earthquake swarm that started beneath the Noto Peninsula in Central Japan since November 2020 and the nucleation of the 2024 M 7.6 Noto Hanto earthquake.We relocate earthquakes listed in the standard Japan Meteorological Agency(JMA)catalog since 2018 with the double-different relocation method.Relocated seismicity revealed that the 2024 M 7.6 mainshock likely ruptured a thrust fault above a parallel fault where the M 6.5 Suzu earthquake occurred in May 2023.We find possible along-strike and along-dip expansion of seismicity in the first few months at the beginning of the swarm sequence,while no obvious migration pattern in the last few days before the M 7.6 mainshock was observed.Several smaller events occurred in between the M 5.5 and M 4.6 foreshocks that occurred about 4min and 2 min before the M 7.6 mainshock.The Coulomb stress changes from the M 5.5 foreshock were negative at the hypocenter of the M 7.6 mainshock,which is inconsistent with a simple cascade triggering model.Moreover,an M 5.9 foreshock was identified in the JMA catalog 14 s before the mainshock.Results from backprojection of high-frequency teleseismic P waves show a prolonged initial rupture process near the mainshock hypocenter lasting for~25 s,before propagating bilaterally outward.Our results suggest a complex evolution process linking the earthquake swarm to the nucleation of the M 7.6 mainshock at a region of complex structures associated with the bend of a mapped large-scale reverse fault.A combination of fluid migration,aseismic slip and elastic stress triggering likely work in concert to drive both the prolonged earthquake swarm and the nucleation of the M 7.6 mainshock.
基金The Strategic Priority Research Program of the CAS,Pan-Third Pole Environment Study for a Green Silk Road(Pan-TPE),No.XDA20040400Key Deployment Project of the CAS,No.ZDRW-ZS-2016-6-2
文摘This paper uses data for the period 1950-2050 compiled by the United Nations Population Division together with methods including spatial autocorrelation analysis, hie- rarchical cluster analysis and the standard deviational ellipse, to analyze the spatio-temporal evolution of population and urbanization in the 75 countries located along the routes of the Silk Road Economic Belt and the 21st-century Maritime Silk Road, to identify future popula- tion growth and urbanization hotspots. The results reveal the following： First, in 2015, the majority of Belt and Road countries in Europe, South Asia and Southeast Asia had high population densities, whereas most countries in Central Asia, North Africa and West Asia, as well as Russia and Mongolia, had low population densities; the majority of countries in South Asia, Southeast Asia, Central Asia, West Asia and North Africa had rapid population growth, whereas many countries in Europe had negative population growth; and five Belt and Road countries are in the initial stage of urbanization, 44 countries are in the acceleration stage of urbanization, and 26 are in the terminal stage of urbanization. Second, in the century from 1950 to 2050, the mean center of the study area＇s population is consistently located in the border region between India and China. Prior to 2000, the trajectory of the mean center was from northwest to southeast, but from 2000 it is on a southward trajectory, as the population of the study area becomes more concentrated. Future population growth hotspots are predicted to be in South Asia, West Asia and Southeast Asia, and hotspot countries for the period 2015-2030 include India, China, Pakistan and Indonesia, though China will move into nega- tive population growth after 2030. Third, the overall urban population of Belt and Road coun- tries increased from 22% in 1950 to 49% in 2015, and it is expected to gradually catch up with the world average, reaching 64% in 2050. The different levels of urbanization in different countries display significant spatial dependency, and in the hundred-year period under con-sideration, this dependency increases before eventually weakening. Fourth, between 2015 and 2030, urban population hotspots will include Thailand, China, Laos and Albania, while Kuwait, Cyprus, Qatar and Estonia will be urban ＂coldspots.＂ Fifth, there were 293 cities with populations over 1 million located along the Belt and Road in 2015, but that number Js ex- pected to increase to 377 by 2030. Of those, 43 will be in China, with many of the others located in India, Indonesia and the eastern Mediterranean.
基金supported by the National Key R&D Plan of China(No.2022YFB3705603)the National Natural Science Foundation of China(No.52101046)+1 种基金the Excellent Youth Overseas Project of National Science and Natural Foundation of China,the Baowu Special Metallurgy Cooperation Limited(No.22H010101336)the Medicine-Engineering Interdisciplinary Project of Shanghai Jiao Tong University(No.YG2022QN076).
文摘Titanium(Ti)and its alloys are frequently utilized as critical components in a variety of engineering ap-plications because of their high specific strength and excellent corrosion resistance.Compared to conven-tional surface strengthening technologies,laser shock peening(LSP)has increasingly attracted attention from researchers and industries,since it significantly improves the surface strength,biocompatibility,fa-tigue resistance,and anti-corrosion ability of Ti and its alloys.Despite numerous studies that have been carried out to elucidate the effects of LSP on microstructural evolution and mechanical properties of Ti and its alloys in recent years,a comprehensive review of recent advancements in the field of Ti and its alloys subjected to LSP is still lacking.In this review,the standard LSP and the novel process designs of LSP assisted by thermal,cryogenic,electropulsing and magnetic fields are discussed and compared.Microstructural evolution,with focuses on the dislocation dynamics,deformation twinning,grain refine-ment and surface amorphization,during LSP processing of Ti alloys is reviewed.Furthermore,the en-hanced engineering performance of the L SP-processed(L SPed)Ti alloys,including surface hardness,wear resistance,fatigue life and corrosion resistance are summarized.Finally,this review concludes by present-ing an overview of the current challenges encountered in this field and offering insights into anticipated future trends.
基金the National Natural Science Foundation of China(Key Program)(52031004).
文摘The characterization techniques were employed like transmission electron microscope,X-ray diffraction and microstructural characterization to investigate microstructural evolution and impact of precipitate-phase precipitation on strength and toughness of a self-developed 32Si_(2)CrNi_(2)MoVNb steel during the quenching and tempering process.Research outputs indicated that the steel microstructure under the quenching state could be composed of martensite with a high dislocation density,a small amount of residual austenite,and many dispersed spherical MC carbides.In details,after tempering at 200℃,fine needle-shapedε-carbides would precipitate,which may improve yield strength and toughness of the steel.However,as compared to that after tempering at 200℃,the average length of needle-shapedε-carbides was found to increase to 144.1±4 from 134.1±3 nm after tempering at 340℃.As a result,the yield strength may increase to 1505±40 MPa,and the impact absorption energy(V-notch)may also decrease.Moreover,after tempering at 450℃,thoseε-carbides in the steel may transform into coarse rod-shaped cementite,and dislocation recoveries at such high tempering temperature may lead to decrease of strength and toughness of the steel.Finally,the following properties could be obtained:a yield strength of 1440±35 MPa,an ultimate tensile strength of 1864±50 MPa and an impact absorption energy of 45.9±4 J,by means of rational composition design and microstructural control.
基金National Natural Science Foundation of China,No.41471108,No.41501141
文摘In today's world, the innovation of science and technology has become the key support for improving comprehensive national strength and changing the mode of social production and lifestyle. The country that possesses world-class scientific and technological innovation cities maximizes the attraction of global innovation factors and wins a strategic initiative in international competition. Based on the urban zip code geodatabase, an evaluation system of urban innovation with the perspective of innovation outputs, and the spatial evolutionary mode, concerning the structure of innovation space of Shanghai and Beijing from 1991 to 2014, was developed. The results of the research indicated that the zip code geodatabase provided a new perspective for studying the evolving spatial structure of urban innovation. The resulting evaluation of the spatial structure of urban innovation using the urban zip code geodatabase established by connecting random edge points, was relatively effective. The study illustrates the value of this methodology. During the study period, the spatial structure of innovation of Shanghai and Beijing demonstrated many common features: with the increase in urban space units participating in innovation year by year, the overall gap of regional innovation outputs has narrowed, and the trend towards spatial agglomeration has strengthened. The evolving spatial structure of innovation of Shanghai and Beijing demonstrated differences between the common features during the 25 years as well: in the trend towards the suburbanization of innovation resources, the spatial structure of innovation of Shanghai evolved from a single-core to a multi-core structure. A radiation effect related to traffic arteries as spatial diffusion corridors was prominent. Accordingly, a spatial correlation effect of its innovation outputs also indicated a hollowness in the city center; the spatial structure of innovation of Beijing had a single-core oriented structure all the way. Together with the tendency for innovation resources to be agglomerated in the city center, the spatial correlation effect of innovation outputs reflected the characteristics of the evolutionary feature where "rural area encircles cities". The innovation spatial structure of Shanghai and Beijing have intrinsic consistency with the spatial structure of their respective regions(Yangtze River Delta urban agglomeration and Beijing-Tianjin-Hebei metropolitan region), which suggested that the principle of proportional and disproportional distribution of a city-scale pattern of technological and innovational activities is closely related to its regional innovation pattern.
