Microwave digestion-inductively coupled plasma mass spectrometry(ICP-MS)was used to analyze the sources of lead in farmland soil and rice in the Jiulongjiang River Basin.The results suggested that the source of lead i...Microwave digestion-inductively coupled plasma mass spectrometry(ICP-MS)was used to analyze the sources of lead in farmland soil and rice in the Jiulongjiang River Basin.The results suggested that the source of lead in rice was differ from that in soil.There were four main sources of lead in farmland soil:natural source,agricultural source,industrial source and fossil fuel source,among which natural source,agricultural source and industrial source contributed more.There were four main sources of lead in rice:natural,agricultural,industrial and fossil fuel sources,and more importantly,fossil fuel sources.The comparison of lead isotope composition with potential sources(^(206)Pb/^(207)Pb,^(208)Pb/^(206)Pb,^(208)Pb/^(207)Pb)can provide a scientific basis for the identification and treatment of heavy metal lead pollution sources in farmland soil and rice in the Jiulong River Basin.展开更多
Analyzing the sources of nitrogen and phosphorus pollution in atmospheric deposition is crucial for protecting the surfacewater environment in vulnerable areas.This study focused on the Dahekou Reservoir,Shayuan Distr...Analyzing the sources of nitrogen and phosphorus pollution in atmospheric deposition is crucial for protecting the surfacewater environment in vulnerable areas.This study focused on the Dahekou Reservoir,Shayuan District,Xilin Gol League,Inner Mongolia,China.It established 12 monitoring sites,conducted one-year monitoring,and collected 144 samples.The concentrations of nitrogen,phosphorus,and water-soluble ions in atmospheric wet sedimentation were measured.This study identified atmospheric precipitation types,revealed seasonal variations in nitrogen and phosphorus concentrations,assessed the contribution of atmosphericwet sedimentation to reservoirwater quality.Utilizing the airmass backward trajectory(HYSPLIT)model and PMF model,themain pollution sources were analyzed.The results were as follows.1)During the observation period,the atmospheric precipitation types were nitric acid rain in spring,sulfuric acid rain in winter,and mixed acid rain in summer and autumn.2)The monthly concentrations of nitrogen and phosphorus of various forms varied significantly,with NH_(4)^(+)-N peaking in spring,NO_(3)^(-)-N and DOP in autumn,and DIP and DON in summer.Annual pollution loads of atmospheric nitrogen and phosphorus precipitation into the reservoir were 35.77 and 4.17 t/a,respectively,severely impacting reservoir water quality.3)Precipitation was negatively correlated with TN concentration,particularly with the NO_(3)^(-)-N/TN ratio,and positively correlated with TP and DIP concen-trations.4)The analysis of pollution sources indicated that the sources of atmospheric nitrogen and phosphorus wet deposition pollution in the study area included agricultural,anthropogenic,dust,and coal sources,with contribution rates of 32.4%,25.6%,21.0%,and 21.0%,respectively.展开更多
Carbonyl compounds play a pivotal role in the formation of secondary pollutants such as O_(3) and SOA,signifi-cantly impacting air quality and human health.This study extended the observation period compared to previo...Carbonyl compounds play a pivotal role in the formation of secondary pollutants such as O_(3) and SOA,signifi-cantly impacting air quality and human health.This study extended the observation period compared to previous research,providing a long-term perspective on carbonyl compound variations and their environmental implica-tions.Atmospheric observations were conducted at Beijing(BJ)and Xianghe(XH)during the summer and winter months of 2018,2019,and 2023 to study the sources and impacts of carbonyl compounds in typical urban areas and peri‑urban areas.Notably,concentrations in the summer of 2023 increased compared to 2018 and 2019.The predominant carbonyl compounds—formaldehyde,acetaldehyde,and acetone—accounted for over 60%of the total.The mean values of OFP in BJ ranged from 18.55 to 58.61μg/m3,lower than those in XH(29.82 to 65.48μg/m3),with formaldehyde and acetaldehyde contributing over 80%of the total.SOAP exhibited a similar pattern,with values in XH(69.21 to 508.55μg/m3)significantly exceeding those in BJ(34.47 to 159.78μg/m3).The PMF model highlighted vehicle exhaust,secondary pollution,and biomass combustion as major sources of carbonyl compounds,emphasizing differences in source contributions between the two regions.This study’s com-parative analysis over different years and locations provides new insights into the dynamic changes in carbonyl compounds and their environmental importance.These results not only reinforce the importance of carbonyl compounds regulation but also offer a valuable reference for evaluating and refining emission control strategies during this period.展开更多
基金Supported by Natural Science Foundation of Fujian Province(2023J011667)Natural Science Foundation of Xiamen(3502Z202374084).
文摘Microwave digestion-inductively coupled plasma mass spectrometry(ICP-MS)was used to analyze the sources of lead in farmland soil and rice in the Jiulongjiang River Basin.The results suggested that the source of lead in rice was differ from that in soil.There were four main sources of lead in farmland soil:natural source,agricultural source,industrial source and fossil fuel source,among which natural source,agricultural source and industrial source contributed more.There were four main sources of lead in rice:natural,agricultural,industrial and fossil fuel sources,and more importantly,fossil fuel sources.The comparison of lead isotope composition with potential sources(^(206)Pb/^(207)Pb,^(208)Pb/^(206)Pb,^(208)Pb/^(207)Pb)can provide a scientific basis for the identification and treatment of heavy metal lead pollution sources in farmland soil and rice in the Jiulong River Basin.
基金supported by Inner Mongolia Autonomous Region Department of Education Science and Technology Talent Project(No.NJYT22040)Inner Mongolia Agricultural University Young Teachers'Scientific Research Ability Promotion Project(No.BR220102)+4 种基金the National Natural Science Foundation of China(No.52260029)the National Key R&D Program(No.2019YFC0409204)Inner Mongolia Natural Science Foundation(No.2021MS04013)the Science and Technology Project of Inner Mongolia Autonomous Region(No.2023YFHH0060)Inner Mongolia AutonomousRegion Science and Technology Leading TalentTeam(No.2022LJRC0007).
文摘Analyzing the sources of nitrogen and phosphorus pollution in atmospheric deposition is crucial for protecting the surfacewater environment in vulnerable areas.This study focused on the Dahekou Reservoir,Shayuan District,Xilin Gol League,Inner Mongolia,China.It established 12 monitoring sites,conducted one-year monitoring,and collected 144 samples.The concentrations of nitrogen,phosphorus,and water-soluble ions in atmospheric wet sedimentation were measured.This study identified atmospheric precipitation types,revealed seasonal variations in nitrogen and phosphorus concentrations,assessed the contribution of atmosphericwet sedimentation to reservoirwater quality.Utilizing the airmass backward trajectory(HYSPLIT)model and PMF model,themain pollution sources were analyzed.The results were as follows.1)During the observation period,the atmospheric precipitation types were nitric acid rain in spring,sulfuric acid rain in winter,and mixed acid rain in summer and autumn.2)The monthly concentrations of nitrogen and phosphorus of various forms varied significantly,with NH_(4)^(+)-N peaking in spring,NO_(3)^(-)-N and DOP in autumn,and DIP and DON in summer.Annual pollution loads of atmospheric nitrogen and phosphorus precipitation into the reservoir were 35.77 and 4.17 t/a,respectively,severely impacting reservoir water quality.3)Precipitation was negatively correlated with TN concentration,particularly with the NO_(3)^(-)-N/TN ratio,and positively correlated with TP and DIP concen-trations.4)The analysis of pollution sources indicated that the sources of atmospheric nitrogen and phosphorus wet deposition pollution in the study area included agricultural,anthropogenic,dust,and coal sources,with contribution rates of 32.4%,25.6%,21.0%,and 21.0%,respectively.
基金supported by the National Natural Science Foundation of China(Nos.41905108 and 42130704).
文摘Carbonyl compounds play a pivotal role in the formation of secondary pollutants such as O_(3) and SOA,signifi-cantly impacting air quality and human health.This study extended the observation period compared to previous research,providing a long-term perspective on carbonyl compound variations and their environmental implica-tions.Atmospheric observations were conducted at Beijing(BJ)and Xianghe(XH)during the summer and winter months of 2018,2019,and 2023 to study the sources and impacts of carbonyl compounds in typical urban areas and peri‑urban areas.Notably,concentrations in the summer of 2023 increased compared to 2018 and 2019.The predominant carbonyl compounds—formaldehyde,acetaldehyde,and acetone—accounted for over 60%of the total.The mean values of OFP in BJ ranged from 18.55 to 58.61μg/m3,lower than those in XH(29.82 to 65.48μg/m3),with formaldehyde and acetaldehyde contributing over 80%of the total.SOAP exhibited a similar pattern,with values in XH(69.21 to 508.55μg/m3)significantly exceeding those in BJ(34.47 to 159.78μg/m3).The PMF model highlighted vehicle exhaust,secondary pollution,and biomass combustion as major sources of carbonyl compounds,emphasizing differences in source contributions between the two regions.This study’s com-parative analysis over different years and locations provides new insights into the dynamic changes in carbonyl compounds and their environmental importance.These results not only reinforce the importance of carbonyl compounds regulation but also offer a valuable reference for evaluating and refining emission control strategies during this period.
