The mixed-alkali-metal borates NaK(B_(5)O_(8))(OH)·H2O(1),NaK_(6)[(B_(4)O_(5))(OH)_(4)]3(OH)·C_(2)H_(5)OH(2)and Na_(0.33)K_(1.67)(B_(4)O_(5))(OH)_(4)·3H_(2)O(3)have been solvothermally synthesized using...The mixed-alkali-metal borates NaK(B_(5)O_(8))(OH)·H2O(1),NaK_(6)[(B_(4)O_(5))(OH)_(4)]3(OH)·C_(2)H_(5)OH(2)and Na_(0.33)K_(1.67)(B_(4)O_(5))(OH)_(4)·3H_(2)O(3)have been solvothermally synthesized using various polar organic solvents.Compounds 1 and 2 crystallize in the centrosymmetric space groups P1¯and R3¯c,respectively.展开更多
基金financially supported by the National Natural Science Foundation of China(no.51432006,50925207,and 51172100)the Ministry of Science and Technology of China(no.2011DFG52970)+1 种基金the Ministry of Education of China for the Changjiang Innovation Research Team(no.IRT13R24)the Ministry of Education and the State Administration of Foreign Experts Affairs for the 111 Project(no.B13025).M.G.H.and C.Z.thank the Australian Research Council for support.
文摘The mixed-alkali-metal borates NaK(B_(5)O_(8))(OH)·H2O(1),NaK_(6)[(B_(4)O_(5))(OH)_(4)]3(OH)·C_(2)H_(5)OH(2)and Na_(0.33)K_(1.67)(B_(4)O_(5))(OH)_(4)·3H_(2)O(3)have been solvothermally synthesized using various polar organic solvents.Compounds 1 and 2 crystallize in the centrosymmetric space groups P1¯and R3¯c,respectively.
