Chemical absorption with amine-based solvents was treated as a promising route approach for carbon dioxide(CO_(2))capture from industrial flue gases.The heat-stable salts(HSS)degraded from amine species is unavoidable...Chemical absorption with amine-based solvents was treated as a promising route approach for carbon dioxide(CO_(2))capture from industrial flue gases.The heat-stable salts(HSS)degraded from amine species is unavoidable and detrimental for CO_(2)capture.To solve this problem,17 porous materials,including anion-exchange resins,macroporous adsorption resins,and activated carbon,were selected for the purification of the hazardous HSS to regenerate the biphasic solvents.The purification performance was thoroughly assessed through experimental tests that examined the effects of various factors,including temperature,flow rate,and pH.Among the materials tested,the macroporous adsorption resin(NKA-9)demonstrated the highest purification efficiency,achieving an adsorption efficiency 92.0%for NO_(3)^(-),and an overall efficiency of 51%for HSS removal.The experimental tests showed that pH was the most significant factor.The decreasing pH value was detrimental to HSS purification.Additionally,a multi-step purification process combining anion exchange resin,activated carbon,and macroporous adsorption resin was evaluated.The multi-stage process effectively removes 82.98%HSS and 62.44%Fe^(3+)ions.The presented work holds significant importance for controlling the HSS concentration in amine-based solvent and maintaining the long-term efficient operation of CO_(2)capture process.展开更多
基金the National Key Research and Development Program of China(No.2023YFC3707004)the Liaoning Province Natural Science Foundation Project of China(No.2023-MS-321)+2 种基金the Liaoning Province International Cooperation Project,China(No.2023030491-JH2/107)the Tsinghua University Open Fund,China(No.KY-2024126)the Northeast Geological Science and Technology Innovation Center,China(Nos.QCJJ2023-46 and QCJJ2023-50).
文摘Chemical absorption with amine-based solvents was treated as a promising route approach for carbon dioxide(CO_(2))capture from industrial flue gases.The heat-stable salts(HSS)degraded from amine species is unavoidable and detrimental for CO_(2)capture.To solve this problem,17 porous materials,including anion-exchange resins,macroporous adsorption resins,and activated carbon,were selected for the purification of the hazardous HSS to regenerate the biphasic solvents.The purification performance was thoroughly assessed through experimental tests that examined the effects of various factors,including temperature,flow rate,and pH.Among the materials tested,the macroporous adsorption resin(NKA-9)demonstrated the highest purification efficiency,achieving an adsorption efficiency 92.0%for NO_(3)^(-),and an overall efficiency of 51%for HSS removal.The experimental tests showed that pH was the most significant factor.The decreasing pH value was detrimental to HSS purification.Additionally,a multi-step purification process combining anion exchange resin,activated carbon,and macroporous adsorption resin was evaluated.The multi-stage process effectively removes 82.98%HSS and 62.44%Fe^(3+)ions.The presented work holds significant importance for controlling the HSS concentration in amine-based solvent and maintaining the long-term efficient operation of CO_(2)capture process.
