Minimizing the thermal expansion coefficient(TEC)mismatch between the cathode and electrolyte in solid oxide fuel cells is crucial for achieving stable,durable operation and high performance.Recently,materials with ne...Minimizing the thermal expansion coefficient(TEC)mismatch between the cathode and electrolyte in solid oxide fuel cells is crucial for achieving stable,durable operation and high performance.Recently,materials with negative thermal expansion(NTE)have at-tracted significant attention as effective additives for tailoring the thermomechanical properties of electrodes and enhancing cell durability.In this work,for the first time,single-phase NTE perovskite Sm_(0.85)Zn_(0.15)MnO_(3−δ)(SZM15)was successfully synthesized via the sol-gel method,eliminating the unwanted ZnO phase typically observed in materials obtained through the conventional solid-state reaction route.The sol-gel approach proved highly advantageous,offering low cost,robustness,excellent chemical homogeneity,precise compositional control,and high phase purity.After optimization of synthesis parameters,a negative TEC of approximately−6.5×10^(−6)K^(−1)was achieved in the 400-850℃range.SZM15 was then incorporated as an additive(10wt%-50wt%)into a SmBa0.5Sr0.5CoCuO_(5+δ)(SBSCCO)cathode to tune the thermomechanical properties with a La_(0.8)Sr_(0.2)Ga_(0.8)Mg_(0.2)O_(3−δ)(LSGM)electrolyte,achieving a minimal TEC mismatch of only 1%.Notably,the SBSCCO+10wt%SZM15 composite cathode exhibited the lowest polarization resistance of 0.019Ω·cm^(2)at 900℃,showing approximately 70%lower than that of the pristine cathode.Excellent long-term stability after 100 h of operation was achieved.In addition,a high peak power density of 680 mW·cm^(−2)was achieved in a Ni-YSZ(yttria-stabilized zirconia)|YSZ|Ce_(0.9)Gd_(0.1)O_(2−δ)(GDC10)|SBSCCO+10wt%SZM15 anode-supported fuel cell at 850℃,highlighting the effectiveness of incorporating NTE materials as a promising strategy for regulating the thermomechanical properties and improving the long-term stability of intermediate temperature solid oxide fuel cells(IT-SOFCs).展开更多
Prticle-in-cell（PIC） simulations demonstrated that,when the relativistic magnetron with diffraction output（MDO） is applied with a 410 kV voltage pulse,or when the relativistic magnetron with radial output is appli...Prticle-in-cell（PIC） simulations demonstrated that,when the relativistic magnetron with diffraction output（MDO） is applied with a 410 kV voltage pulse,or when the relativistic magnetron with radial output is applied with a 350 kV voltage pulse,electrons emitted from the cathode with high energy will strike the anode block wall.The emitted secondary electrons and backscattered electrons affect the interaction between electrons and RF fields induced by the operating modes,which decreases the output power in the radial output relativistic magnetron by about 15%（10%for the axial output relativistic magnetron）,decreases the anode current by about 5%（5%for the axial output relativistic magnetron）,and leads to a decrease of electronic efficiency by 8%（6%for the axial output relativistic magnetron）.The peak value of the current formed by secondary and backscattered current equals nearly half of the amplitude of the anode current,which may help the growth of parasitic modes when the applied magnetic field is near the critical magnetic field separating neighboring modes.Thus,mode competition becomes more serious.展开更多
Lithium metal batteries (LMBs) show great potential in delivering high energy density (>500 Wh/kg) with cycling [1]. The cycling life of LMBs is mainly improved by regulating the composition and structure of solid/...Lithium metal batteries (LMBs) show great potential in delivering high energy density (>500 Wh/kg) with cycling [1]. The cycling life of LMBs is mainly improved by regulating the composition and structure of solid/cathode electrolyte interphase(SEI/CEI) with electrolytes [2]. However, both Li anode and transition metal oxide cathode have high interfacial reactivity at extreme voltages, which highly needs compatible electrolytes.Recently, localized high-concentration electrolytes (LHCEs) have promisingly stabilized the dual electrodes of high-voltage LMBs[3].展开更多
基金supported by the research project within the program“Excellence Initiative-Research University”for the AGH University of Krakow(IDUB AGH,Action 21)Kun Zheng acknowledges financial support from AGH University of Krakow(No.16.16.210.476).
文摘Minimizing the thermal expansion coefficient(TEC)mismatch between the cathode and electrolyte in solid oxide fuel cells is crucial for achieving stable,durable operation and high performance.Recently,materials with negative thermal expansion(NTE)have at-tracted significant attention as effective additives for tailoring the thermomechanical properties of electrodes and enhancing cell durability.In this work,for the first time,single-phase NTE perovskite Sm_(0.85)Zn_(0.15)MnO_(3−δ)(SZM15)was successfully synthesized via the sol-gel method,eliminating the unwanted ZnO phase typically observed in materials obtained through the conventional solid-state reaction route.The sol-gel approach proved highly advantageous,offering low cost,robustness,excellent chemical homogeneity,precise compositional control,and high phase purity.After optimization of synthesis parameters,a negative TEC of approximately−6.5×10^(−6)K^(−1)was achieved in the 400-850℃range.SZM15 was then incorporated as an additive(10wt%-50wt%)into a SmBa0.5Sr0.5CoCuO_(5+δ)(SBSCCO)cathode to tune the thermomechanical properties with a La_(0.8)Sr_(0.2)Ga_(0.8)Mg_(0.2)O_(3−δ)(LSGM)electrolyte,achieving a minimal TEC mismatch of only 1%.Notably,the SBSCCO+10wt%SZM15 composite cathode exhibited the lowest polarization resistance of 0.019Ω·cm^(2)at 900℃,showing approximately 70%lower than that of the pristine cathode.Excellent long-term stability after 100 h of operation was achieved.In addition,a high peak power density of 680 mW·cm^(−2)was achieved in a Ni-YSZ(yttria-stabilized zirconia)|YSZ|Ce_(0.9)Gd_(0.1)O_(2−δ)(GDC10)|SBSCCO+10wt%SZM15 anode-supported fuel cell at 850℃,highlighting the effectiveness of incorporating NTE materials as a promising strategy for regulating the thermomechanical properties and improving the long-term stability of intermediate temperature solid oxide fuel cells(IT-SOFCs).
基金supported by National Natural Science Foundation of China(No.61302010)the Foundation of Science and Technology on High Power Microwave Laboratory,Central University Foundation(2013KW07)Work at the University of New Mexico in USA was supportedby ONR Grant N00014-13-1-0565
文摘Prticle-in-cell（PIC） simulations demonstrated that,when the relativistic magnetron with diffraction output（MDO） is applied with a 410 kV voltage pulse,or when the relativistic magnetron with radial output is applied with a 350 kV voltage pulse,electrons emitted from the cathode with high energy will strike the anode block wall.The emitted secondary electrons and backscattered electrons affect the interaction between electrons and RF fields induced by the operating modes,which decreases the output power in the radial output relativistic magnetron by about 15%（10%for the axial output relativistic magnetron）,decreases the anode current by about 5%（5%for the axial output relativistic magnetron）,and leads to a decrease of electronic efficiency by 8%（6%for the axial output relativistic magnetron）.The peak value of the current formed by secondary and backscattered current equals nearly half of the amplitude of the anode current,which may help the growth of parasitic modes when the applied magnetic field is near the critical magnetic field separating neighboring modes.Thus,mode competition becomes more serious.
文摘Lithium metal batteries (LMBs) show great potential in delivering high energy density (>500 Wh/kg) with cycling [1]. The cycling life of LMBs is mainly improved by regulating the composition and structure of solid/cathode electrolyte interphase(SEI/CEI) with electrolytes [2]. However, both Li anode and transition metal oxide cathode have high interfacial reactivity at extreme voltages, which highly needs compatible electrolytes.Recently, localized high-concentration electrolytes (LHCEs) have promisingly stabilized the dual electrodes of high-voltage LMBs[3].
