Poly(3-hexylthiophene)(P3HT)is one of the most promising hole-transporting materials in the pursuit of efficient and stable perovskite solar cells due to its outstanding stability and low cost.However,the intrinsic lo...Poly(3-hexylthiophene)(P3HT)is one of the most promising hole-transporting materials in the pursuit of efficient and stable perovskite solar cells due to its outstanding stability and low cost.However,the intrinsic low carrier density of P3 HT and poor contact between the P3HT/perovskite interface always lead to a low performance of the solar cell,while conventional chemical doping always makes the films unstable and limits the scalability.In this work,for the first time,we simultaneously enhanced the hole transporting properties of P3HT film and the interface of perovskite by doping it with a judiciously designed oxidized small molecule organic semiconductor.The organic salt not only can promote the lamellar crystallinity of P3HT to obtain better charge transport properties,but also reduce the defects of perovskite.As a result,we achieved champion efficiencies of 23.0%for small-area solar cells and 18.8%for larger-area modules(48.0 cm^(2)).This efficiency is the highest value for P3HT-based perovskite modules.Moreover,the solar cells show excellent operational stability,retaining over 95%of their initial efficiencies after1200 h of continuous operation.展开更多
Currently,perovskite solar cells have achieved commendable progresses in power conversion efficiency(PCE)and operational stability.However,some conventional laboratory-scale fabrication methods become challenging when...Currently,perovskite solar cells have achieved commendable progresses in power conversion efficiency(PCE)and operational stability.However,some conventional laboratory-scale fabrication methods become challenging when scaling up material syntheses or device production.Particularly,the prolonged high-temperature annealing process for the crystallization of perovskites requires a substantial amount of energy consumption and impact the modules’throughput.Here,we report a modified near-infrared annealing(NIRA)process,which involves the excess PbI_(2)engineered crystallization,efficiently reduces the preparation time for perovskite active layer to within 20 s compared to dozens of min in conventional hot plate annealing(HPA)process.The study showed that the incorporated PbI_(2)promoted the consistent nucleation of the perovskite film,leading to the subsequent rapid and homogeneous crystallization at the NIRA stage.Thus,highly crystalized perovskite film was realized with even better crystallization performance than conventional HPA-based film.Ultimately,efficient perovskite solar modules of 36 and 100 cm^(2)were readily fabricated with the optimal PCEs of 22.03%and 20.18%,respectively.This study demonstrates,for the first time,the successful achievement of homogeneous and high-quality crystallization in large-area perovskite films through rapid NIRA processing.This approach not only significantly reduces energy consumption during production,but also substantially shortens the manufacturing cycle,paving a new path toward the commercial-scale application of perovskite solar modules.展开更多
The fabrication of efficient and stable flexible perovskite solar modules(F-PSMs)using poly[bis(4-phenyl)(2,4,6-trimethylphenyl)amine](PTAA)remains a significant challenge due to its hydrophobic properties and the mis...The fabrication of efficient and stable flexible perovskite solar modules(F-PSMs)using poly[bis(4-phenyl)(2,4,6-trimethylphenyl)amine](PTAA)remains a significant challenge due to its hydrophobic properties and the mismatch in interface energy-level alignment.Here,we introduced[2-(3,6-dimethoxy-9H-carba zol-9-yl)ethyl]phosphonic acid(MeO-2PACz)to modify the PTAA layer,which effectively suppressed surface potential fluctuations and aligned energy levels at the interface of PTAA/perovskite.Additionally,MeO-2PACz enhanced the hydrophilicity of PTAA,facilitating the fabrication of dense,uniform,and pinhole-free perovskite films on large-area flexible substrates.As a result,we achieved an F-PSM with a power conversion efficiency(PCE)of 16.6% and an aperture area of 64 cm^(2),which is the highest reported value among F-PSMs with an active area exceeding 35 cm^(2)based on PTAA.Moreover,the encapsulated module demonstrated outstanding long-term operational stability,retaining 90.2% of its initial efficiency after 1000 bending cycles(5 mm radius),87.2% after 1000 h of continuous illumination,and 80.3% under combined thermal and humid conditions(85℃ and 85% relative humidity),representing one of the most stable F-PSMs reported to date.展开更多
A considerable efficiency gap exists between large-area perovskite solar modules and small-area perovskite solar cells.The control of forming uniform and large-area film and perovskite crystallization is still the mai...A considerable efficiency gap exists between large-area perovskite solar modules and small-area perovskite solar cells.The control of forming uniform and large-area film and perovskite crystallization is still the main obstacle restricting the efficiency of PSMs.In this work,we adopted a solid-liquid two-step film formation technique,which involved the evaporation of a lead iodide film and blade coating of an organic ammonium halide solution to prepare perovskite films.This method possesses the advantages of integrating vapor deposition and solution methods,which could apply to substrates with different roughness and avoid using toxic solvents to achieve a more uniform,large-area perovskite film.Furthermore,modification of the NiO_(x)/perovskite buried interface and introduction of Urea additives were utilized to reduce interface recombination and regulate perovskite crystallization.As a result,a large-area perovskite film possessing larger grains,fewer pinholes,and reduced defects could be achieved.The inverted PSM with an active area of 61.56 cm^(2)(10×10 cm^(2)substrate)achieved a champion power conversion efficiency of 20.56%and significantly improved stability.This method suggests an innovative approach to resolving the uniformity issue associated with large-area film fabrication.展开更多
Effective perovskite crystallization control strategies for flexible substrates with scalable processing techniques have rarely been reported and remain an important challenge.In this study,3-mercaptobenzoic acid(3-MB...Effective perovskite crystallization control strategies for flexible substrates with scalable processing techniques have rarely been reported and remain an important challenge.In this study,3-mercaptobenzoic acid(3-MBA)was introduced into the perovskite precursor to modulate the crystallization dynamics,facilitating rapid nucleation while slowing down crystal growth.This approach enabled the formation of uniform,dense large-area perovskite films on flexible substrates.Consequently,a 12 cm^(2) flexible perovskite solar module achieved a power conversion efficiency(PCE)of 16.43%.Additionally,the module exhibited enhanced mechanical stability under various bending radii and improved light stability,marking a substantial advance toward the practical application of flexible perovskite solar modules.展开更多
Tin dioxide(SnO_(2))has been demonstrated as one of the promising electron transport layers for high-efficiency perovskite solar cells(PSCs).However,scalable fabrication of SnO_(2) films with uniform coverage,desirabl...Tin dioxide(SnO_(2))has been demonstrated as one of the promising electron transport layers for high-efficiency perovskite solar cells(PSCs).However,scalable fabrication of SnO_(2) films with uniform coverage,desirable thickness and a low defect density in perovskite solar mod-ules(PSMs)is still challenging.Here,we report preparation of high-quality large-area SnO_(2) films by chemical bath depo-sition(CBD)with the addition of KMnO_(4).The strong oxidiz-ing nature of KMnO_(4) promotes the conversion from Sn(II)to Sn(VI),leading to reduced trap defects and a higher carrier mobility of SnO_(2).In addition,K ions diffuse into the per-ovskite film resulting in larger grain sizes,passivated grain boundaries,and reduced hysteresis of PSCs.Furthermore,Mn ion doping improves both the crystallinity and the phase stability of the perovskite film.Such a multifunctional interface engineering strategy enabled us to achieve a power conversion efficiency(PCE)of 21.70% with less hysteresis for lab-scale PSCs.Using this method,we also fabricated 5×5 and 10×10 cm^(2) PSMs,which showed PCEs of 15.62% and 11.80%(active area PCEs are 17.26%and 13.72%),respectively.For the encapsulated 5×5 cm^(2) PSM,we obtained a T80 operation lifetime(the lifespan during which the solar module PCE drops to 80%of its initial value)exceeding 1000 h in ambient condition.展开更多
Most thin-film photovoltaic modules are constructed on soda-lime glass(SLG)substrates containing alkali oxides,such as Na_(2)O.Na may diffuse from SLG into a module's active layers through P1 lines,an area between...Most thin-film photovoltaic modules are constructed on soda-lime glass(SLG)substrates containing alkali oxides,such as Na_(2)O.Na may diffuse from SLG into a module's active layers through P1 lines,an area between a module's constituent cells where the substrate-side charge transport layer(CTL)is in direct contact with SLG.Na diffusion from SLG is known to cause several important effects inⅡ-Ⅵand chalcogenide solar modules,but it has not been studied in perovskite solar modules(PSMs).In this work,we use complementary microscopy and spectroscopy techniques to show that Na diffusion occurs in the fabrication process of PSMs.Na diffuses vertically inside P1 lines and then laterally from P1 lines into the active area for up to 360 pm.We propose that this process is driven by the high temperatures the devices are exposed to during CTL and perovskite annealing.The diffused Na preferentially binds with Br,forming Br-poor,l-rich perovskite and a species rich in Na and Br(Na-Br)close to P1 lines.Na-Br passivates defect sites,reducing non-radiative recombination in the perovskite and boosting its luminescence by up to 5×.Na-Br is observed to be stable after 12 weeks of device storage,suggesting long-lasting effects of Na diffusion.Our results not only point to a potential avenue to increase PSM performance but also highlight the possibility of unabated Na diffusion throughout a module's lifetime,especially if accelerated by the electric field and elevated temperatures achievable during device operation.展开更多
The stability issue has been acknowledged as the bottleneck in the practical application of perovskite photovoltaics,while the stabilized interface between the perovskites and charge transport layers dominates their s...The stability issue has been acknowledged as the bottleneck in the practical application of perovskite photovoltaics,while the stabilized interface between the perovskites and charge transport layers dominates their stability performance under different stresses.Here,we developed a high-performance sulfurized zinc-titanium mixed oxide(ZTO-S)electron transport layer(ETL)to fabricate large-area efficient and long-term 85℃/85%RH stable perovskite solar modules.The scalably prepared ZTO-S using the facile spray coating method demonstrates excellent electron mobility close to that of Zn O,in addition to promoting the uniform crystallization of perovskite film across the entire module via the interaction between surface S and Pb^(2+).Furthermore,this novel coordination stabilized the interface and reduced the interfacial non-radiative recombination defects within the devices,yielding an efficient and stable performance for the modules.High efficiency of 21.73%and 17.50%was achieved for blade-coated 36 cm^(2)and 100 cm^(2)perovskite solar modules,respectively.In addition,the encapsulated module(36 cm^(2))shows an attractive humidity and heat stability(85℃/85%RH)performance with a maintained 93.5%of the initial PCE over 1000 h.展开更多
The persistency of passivation and scalable uniformity are vital issues that limit the improvement of performance and stability of large-area perovskite solar modules(PSMs).Here,we design a bilayer interface engineeri...The persistency of passivation and scalable uniformity are vital issues that limit the improvement of performance and stability of large-area perovskite solar modules(PSMs).Here,we design a bilayer interface engineering strategy that takes advantage of the stability and passivation ability of low-dimensional perovskite and the dipole layer.Introducing phenethylammonium iodide(PEAI)can form 2D/3D heterojunctions on the perovskite surface and effectively passivate defects of perovskite film.Interestingly,the upper piperazinium iodide(PI)layer can still form surface dipoles on the 2D/3D perovskite surface to optimize energy-level alignment.Moreover,the bilayer interface engineering enables large-area perovskite films with uniform surface morphology,lower trap-state density and stability against environmental stress factors.The final devices achieved a small-area PCE of 25.20% and a large-area(1 cm^(2))PCE of 23.96%.A perovskite mini-module(5×5 cm^(2) with an active area of 14.28 cm^(2))could also be fabricated to achieve a PCE of 23.19%,ranking it among the highest for inverted PSMs.Additionally,the device could retain over 93% of its initial efficiency after MPP tracking at 45℃ for 1280 h.This study successfully demonstrates a bilayer interface engineering with respective functions,offering valuable insights for producing efficient and stable large-area PSCs.展开更多
Perovskite solar cells have shown great potential in the field of underwater solar cells due to their excellent optoelectronic properties;however,their underwater performance and stability still hinder their practical...Perovskite solar cells have shown great potential in the field of underwater solar cells due to their excellent optoelectronic properties;however,their underwater performance and stability still hinder their practical use.In this research,a 1H,1H,2H,2H-heptadecafluorodecyl acrylate(HFDA)anti-reflection coating(ARC)was introduced as a high-transparent material for encapsulating perovskite solar modules(PSMs).Optical characterization results revealed that HFDA can effectively reduce reflection of light below 800 nm,aiding in the absorption of light within this wavelength range by underwater solar cells.Thus,a remarkable efficiency of 14.65%was achieved even at a water depth of 50 cm.And,the concentration of Pb^(2+)for HFDA-encapsulated film is significantly reduced from 186 to 16.5 ppb after being immersed in water for 347 h.Interestingly,the encapsulated PSMs still remained above 80%of their initial efficiency after continuous underwater illumination for 400 h.Furthermore,being exposed to air,the encapsulated PSMs maintained 94%of their original efficiency after 1000 h light illumination.This highly transparent ARC shows great potentials in enhancing the stability of perovskite devices,applicable not only to underwater cells but also extendable to land-based photovoltaic devices.展开更多
The advancement of sophisticated smart windows exhibiting superior thermoregulation capabilities in both solar spectrum and long-wave infrared range maintains a prominent objective for researchers in this field.In thi...The advancement of sophisticated smart windows exhibiting superior thermoregulation capabilities in both solar spectrum and long-wave infrared range maintains a prominent objective for researchers in this field.In this study,a Janus window is proposed and prepared based on polymer-stabilized liquid-crystal films/thermochromic materials.It can achieve switchable front long-wave infrared emissivity(ε_(Front))and solar modulation ability(ΔT_(sol))through dynamic flipping,making it suitable for different seasonal energy-saving requirements.Outdoor experiments show that under daytime illumination,the indoor temperature decreases by 8℃,and the nighttime temperature drops by 5℃.MATLAB simulation calculations indicate that the daytime cooling power is 93 W m^(-2),while the nighttime cooling power reaches 142 W m^(-2).Interestingly,by modifying the conductive layer,it can effectively shield electromagnetic radiation(within the X-band frequency range(8.2-12.4)GHz).Energy simulation reveals the substantial superiority of this device in energy savings compared with single-layer polymer-stabilized liquid crystal,poly(N-isopropyl acrylamide),and normal glass when applied in different climate zones.This research presents a compelling opportunity for the development of sophisticated smart windows characterized by exceptional thermoregulation capabilities.展开更多
Quantum dots(QDs)can modulate the solar spectrum through the down-conversion mechanism to better match the spectral response of solar cells.Following previous work,this paper first tested the response of QD solar cell...Quantum dots(QDs)can modulate the solar spectrum through the down-conversion mechanism to better match the spectral response of solar cells.Following previous work,this paper first tested the response of QD solar cells to specific monochromatic light,and found that QDs can effectively improve the photoelectric conversion efficiency(PCE)in the ultraviolet(UV)band by comparison.Then the photoelectric properties of the QD solar cells are tested under the air-mass 1.5(AM1.5)and air-mass 0(AM0)spectra.The experimental results show that because the absorption band of QDs is in the UV region,the space solar cells in the AM0 spectrum can obtain better PCE after coating QDs.The research results show the technical route of space solar cells with down-conversion mechanism,and put forward an important direction for the application of space solar photovoltaic(PV)technology,and have a good application prospect.展开更多
Organometal halide perovskites have exhibited a bright future as photovoltaic semiconductor in next generation solar cells due to their unique and promising physicochemical properties.Over the past few years,we have w...Organometal halide perovskites have exhibited a bright future as photovoltaic semiconductor in next generation solar cells due to their unique and promising physicochemical properties.Over the past few years,we have witnessed a tremendous progress of efficiency record evolution of perovskite solar cells(PSCs).Up to now,the highest efficiency record of PSCs has reached 22.1%;however,it was achieved at a very small device area of<0.1 cm^(2).With the device area increasing to mini-module scale,the efficiency record dropped dramatically.The inherent causes are mainly ascribed to inadequate quality control of large-area perovskite thin films and insufficient optimization of solar module design.In current stage of PSCs research and development,to overcome these two obstacles is in urgent need before this new technology could realize scale-up industrialization.Herein,we present an overview of recently developed strategies for preparing large-area perovskite thin films and perovskite solar modules(PSMs).At last,cost analysis and future application directions of PSMs have also been discussed.展开更多
Commercialization of perovskite solar cells(PSCs) requires the development of high-efficiency devices with none current density-voltage(J-V) hysteresis. Here, electron transport layers(ETLs) with gradual change in wor...Commercialization of perovskite solar cells(PSCs) requires the development of high-efficiency devices with none current density-voltage(J-V) hysteresis. Here, electron transport layers(ETLs) with gradual change in work function(WF) are successfully fabricated and employed as an ideal model to investigate the energy barriers, charge transfer and recombination kinetics at ETL/perovskite interface. The energy barrier for electron injection existing at ETL/perovskite is directly assessed by surface photovoltage microscopy, and the results demonstrate the tunable barriers have significant impact on the J-V hysteresis and performance of PSCs. By work function engineering of ETL, PSCs exhibit PCEs over 21% with negligible hysteresis. These results provide a critical understanding of the origin reason for hysteresis effect in planar PSCs, and clear reveal that the J-V hysteresis can be effectively suppressed by carefully tuning the interface features in PSCs. By extending this strategy to a modified formamidinium-cesium-rubidium(FA-Cs-Rb) perovskite system, the PCEs are further boosted to 24.18%. Moreover, 5 cm × 5 cm perovskite mini-modules are also fabricated with an impressive efficiency of 20.07%, demonstrating compatibility and effectiveness of our strategy on upscaled devices.展开更多
Perovskite crystal facets greatly impact the performance and stability of their corresponding photovoltaic devices.Compared to the(001)facet,the(011)facet yields better photoelectric properties,including higher conduc...Perovskite crystal facets greatly impact the performance and stability of their corresponding photovoltaic devices.Compared to the(001)facet,the(011)facet yields better photoelectric properties,including higher conductivity and enhanced charge carrier mobility.Thus,achieving(011)facet-exposed films is a promising way to improve device performance.However,the growth of(011)facets is energetically unfavorable in FAPbI_(3) perovskites due to the influence of methylammonium chloride additive.Here,1-butyl-4-methylpyridinium chloride([4MBP]Cl)was used to expose(011)facets.The[4MBP]^(+)cation selectively decreases the surface energy of the(011)facet enabling the growth of the(011)plane.The[4MBP]^(+)cation causes the perovskite nuclei to rotate by 45°such that(011)crystal facets stack along the out-of-plane direction.The(011)facet has excellent charge transport properties and can achieve better-matched energy level alignment.In addition,[4MBP]Cl increases the activation energy barrier for ion migration,suppressing decomposition of the perovskite.As a result,a small-size device(0.06 cm2)and a module(29.0 cm2)based on exposure of the(011)facet achieved power conversion efficiencies of 25.24%and 21.12%,respectively.展开更多
Highly efficient organic solar cells(OSCs)are normally produced using the halogenated solvents chloroform or chlorobenzene,which present challenges for scalable manufacturing due to their toxicity,narrow processing wi...Highly efficient organic solar cells(OSCs)are normally produced using the halogenated solvents chloroform or chlorobenzene,which present challenges for scalable manufacturing due to their toxicity,narrow processing window and low boiling point.Herein,we develop a novel high-speed doctor-blading technique that significantly reduces the required concentration,facilitating the use of eco-friendly,non-halogenated solvents as alternatives to chloroform or chlorobenzene.By utilizing two widely used high-boiling,non-halogenated green solvents-o-xylene(o-XY)and toluene(Tol)-in the fabrication of PM 6:L 8-BO,we achieve power conversion efficiencies(PCEs)of 18.20%and 17.36%,respectively.Additionally,a module fabricated with o-XY demonstrates a notable PCE of 16.07%.In-situ testing and morphological analysis reveal that the o-XY coating process extends the liquid-to-solid transition stage to 6 s,significantly longer than the 1.7 s observed with Tol processing.This prolonged transition phase is crucial for improving the crystallinity of the thin film,reducing defect-mediated recombination,and enhancing carrier mobility,which collectively contribute to superior PCEs.展开更多
In the 21st century, the deployment of ground-based Solar Photovoltaic (PV) Modules has seen exponential growth, driven by increasing demands for green, clean, and renewable energy sources. However, their usage is con...In the 21st century, the deployment of ground-based Solar Photovoltaic (PV) Modules has seen exponential growth, driven by increasing demands for green, clean, and renewable energy sources. However, their usage is constrained by certain limitations. Notably, the efficiency of solar PV modules on the ground peaks at a maximum of 25%, and there are concerns regarding their long-term reliability, with an expected lifespan of approximately 25 years without failures. This study focuses on analyzing the thermal efficiency of PV Modules. We have investigated the temperature profile of PV Modules under varying environmental conditions, such as air velocity and ambient temperature, utilizing Computational Fluid Dynamics (CFD). This analysis is crucial as the efficiency of PV Modules is significantly impacted by changes in the temperature differential relative to the environment. Furthermore, the study highlights the effect of airflow over solar panels on their temperature. It is found that a decrease in the temperature of the PV Module increases Open Circuit Voltage, underlining the importance of thermal management in optimizing solar panel performance.展开更多
This project adopts an advanced microcontroller as the core control unit,which accurately commands the servo drive,realizes the real-time light chasing and charging function of the solar panel,and effectively manages ...This project adopts an advanced microcontroller as the core control unit,which accurately commands the servo drive,realizes the real-time light chasing and charging function of the solar panel,and effectively manages the power supply system of the street light.At the same time,the system is able to continuously monitor the operation status of the servo within the range of 0°to 180°to ensure that it is trouble-free and not offline.The hardware system construction consists of five modules:a power module,solar panel module,servo module,street light module,and Organic Light-Emitting Diode(OLED)display module.Each module works together to support the stable operation of the whole system.The system workflow is to accurately determine the direction of the light source by collecting real-time light intensity data through four precision photoresistors.Subsequently,the microcontroller intelligently controls the helm module based on these data to drive the solar panel to rotate within a range of 180°to accurately track the sun’s orientation.The street light provides two lighting modes,automatic and manual,to meet the needs of different scenarios.During the daytime,the solar panels work actively to monitor and collect solar energy efficiently in real-time,meanwhile,when night falls,the solar panels switch to standby mode and the streetlights light up automatically,illuminating the road ahead for pedestrians.Compared with the traditional solar street lights on the market,the intelligent solar light chasing road system introduced in this project has significant advantages.Its unique light-chasing algorithm enables the solar panel to continuously track the light source from sunrise to sunset,thus significantly improving the charging efficiency.Compared with traditional street lights,the biggest advantage of this project is the proposed light-chasing algorithm,which can always charge from sunrise until sunset,making the charging efficiency increase by 38%to 47%.The charging efficiency is 20%to 38%higher than that of traditional street lamps.Simultaneously,the biggest advantage of this project is that the power storage capacity is higher than 35%of the traditional solar street light.Bringing users a more durable and stable lighting experience.展开更多
The booming growth of organic-inorganic hybrid lead halide perovskite solar cells have made this promising photovoltaic technology to leap towards commercialization.One of the most important issues for the evolution f...The booming growth of organic-inorganic hybrid lead halide perovskite solar cells have made this promising photovoltaic technology to leap towards commercialization.One of the most important issues for the evolution from research to practical application of this technology is to achieve high-throughput manufacturing of large-scale perovskite solar modules.In particular,realization of scalable fabrication of large-area perovskite films is one of the essential steps.During the past ten years,a great number of approaches have been developed to deposit high quality perovskite films,to which additives are introduced during the fabrication process of perovskite layers in terms of the perovskite grain growth control,defect reduction,stability enhancement,etc.Herein,we first review the recent progress on additives during the fabrication of large area perovskite films for large scale perovskite solar cells and modules.We then focus on a comprehensive and in-depth understanding of the roles of additives for perovskite grain growth control,defects reduction,and stability enhancement.Further advancement of the scalable fabrication of high-quality perovskite films and solar cells using additives to further develop large area,stable perovskite solar cells are discussed.展开更多
Perovskite solar cells(PSCs)have undergone a dramatic increase in laboratory-scale effi ciency to more than 25%,which is comparable to Si-based single-junction solar cell effi ciency.However,the effi ciency of PSCs dr...Perovskite solar cells(PSCs)have undergone a dramatic increase in laboratory-scale effi ciency to more than 25%,which is comparable to Si-based single-junction solar cell effi ciency.However,the effi ciency of PSCs drops from laboratory-scale to large-scale perovskite solar modules(PSMs)because of the poor quality of perovskite fi lms,and the increased resistance of large-area PSMs obstructs practical PSC applications.An in-depth understanding of the fabricating processes is vital for precisely controlling the quality of large-area perovskite fi lms,and a suitable structural design for PSMs plays an impor-tant role in minimizing energy loss.In this review,we discuss several solution-based deposition techniques for large-area perovskite fi lms and the eff ects of operating conditions on the fi lms.Furthermore,diff erent structural designs for PSMs are presented,including the processing technologies and device architectures.展开更多
基金financially supported by the National Natural Science Foundation of China(52472248 and 22075221)the Key Research and Development Project of Shanxi Province(202202060301003 and 202202060301015)the Innovation Program of Wuhan-Shuguang Project(2023010201020367)。
文摘Poly(3-hexylthiophene)(P3HT)is one of the most promising hole-transporting materials in the pursuit of efficient and stable perovskite solar cells due to its outstanding stability and low cost.However,the intrinsic low carrier density of P3 HT and poor contact between the P3HT/perovskite interface always lead to a low performance of the solar cell,while conventional chemical doping always makes the films unstable and limits the scalability.In this work,for the first time,we simultaneously enhanced the hole transporting properties of P3HT film and the interface of perovskite by doping it with a judiciously designed oxidized small molecule organic semiconductor.The organic salt not only can promote the lamellar crystallinity of P3HT to obtain better charge transport properties,but also reduce the defects of perovskite.As a result,we achieved champion efficiencies of 23.0%for small-area solar cells and 18.8%for larger-area modules(48.0 cm^(2)).This efficiency is the highest value for P3HT-based perovskite modules.Moreover,the solar cells show excellent operational stability,retaining over 95%of their initial efficiencies after1200 h of continuous operation.
基金supported by China Huaneng Group Key R&D Program(HNKJ22-H104)the Science and Technology Programs of Fujian Province(2022H0005)+1 种基金the Fundamental Research Funds for the Central Universities(20720240067)Technology Projects of Innovation Laboratory for Sciences and Technologies of Energy Materials of Fujian Province(RD2020020101 and RD2022040601).
文摘Currently,perovskite solar cells have achieved commendable progresses in power conversion efficiency(PCE)and operational stability.However,some conventional laboratory-scale fabrication methods become challenging when scaling up material syntheses or device production.Particularly,the prolonged high-temperature annealing process for the crystallization of perovskites requires a substantial amount of energy consumption and impact the modules’throughput.Here,we report a modified near-infrared annealing(NIRA)process,which involves the excess PbI_(2)engineered crystallization,efficiently reduces the preparation time for perovskite active layer to within 20 s compared to dozens of min in conventional hot plate annealing(HPA)process.The study showed that the incorporated PbI_(2)promoted the consistent nucleation of the perovskite film,leading to the subsequent rapid and homogeneous crystallization at the NIRA stage.Thus,highly crystalized perovskite film was realized with even better crystallization performance than conventional HPA-based film.Ultimately,efficient perovskite solar modules of 36 and 100 cm^(2)were readily fabricated with the optimal PCEs of 22.03%and 20.18%,respectively.This study demonstrates,for the first time,the successful achievement of homogeneous and high-quality crystallization in large-area perovskite films through rapid NIRA processing.This approach not only significantly reduces energy consumption during production,but also substantially shortens the manufacturing cycle,paving a new path toward the commercial-scale application of perovskite solar modules.
基金financially supported by the Key Fund of Tianjin Natural Science Foundation,China Project of Tianjin Natural Science Foundation(24JCZDJC00510)the National Natural Science Foundation of China,China(22475147)the Fundamental Research Funds for the Central Universities,China。
文摘The fabrication of efficient and stable flexible perovskite solar modules(F-PSMs)using poly[bis(4-phenyl)(2,4,6-trimethylphenyl)amine](PTAA)remains a significant challenge due to its hydrophobic properties and the mismatch in interface energy-level alignment.Here,we introduced[2-(3,6-dimethoxy-9H-carba zol-9-yl)ethyl]phosphonic acid(MeO-2PACz)to modify the PTAA layer,which effectively suppressed surface potential fluctuations and aligned energy levels at the interface of PTAA/perovskite.Additionally,MeO-2PACz enhanced the hydrophilicity of PTAA,facilitating the fabrication of dense,uniform,and pinhole-free perovskite films on large-area flexible substrates.As a result,we achieved an F-PSM with a power conversion efficiency(PCE)of 16.6% and an aperture area of 64 cm^(2),which is the highest reported value among F-PSMs with an active area exceeding 35 cm^(2)based on PTAA.Moreover,the encapsulated module demonstrated outstanding long-term operational stability,retaining 90.2% of its initial efficiency after 1000 bending cycles(5 mm radius),87.2% after 1000 h of continuous illumination,and 80.3% under combined thermal and humid conditions(85℃ and 85% relative humidity),representing one of the most stable F-PSMs reported to date.
基金the financial support from Shanxi Province Science and Technology Department(20201101012,202101060301016)the support from the APRC Grant of the City University of Hong Kong(9380086)+5 种基金the TCFS Grant(GHP/018/20SZ)MRP Grant(MRP/040/21X)from the Innovation and Technology Commission of Hong Kongthe Green Tech Fund(202020164)from the Environment and Ecology Bureau of Hong Kongthe GRF grants(11307621,11316422)from the Research Grants Council of Hong KongGuangdong Major Project of Basic and Applied Basic Research(2019B030302007)Guangdong-Hong Kong-Macao Joint Laboratory of Optoelectronic and Magnetic Functional Materials(2019B121205002).
文摘A considerable efficiency gap exists between large-area perovskite solar modules and small-area perovskite solar cells.The control of forming uniform and large-area film and perovskite crystallization is still the main obstacle restricting the efficiency of PSMs.In this work,we adopted a solid-liquid two-step film formation technique,which involved the evaporation of a lead iodide film and blade coating of an organic ammonium halide solution to prepare perovskite films.This method possesses the advantages of integrating vapor deposition and solution methods,which could apply to substrates with different roughness and avoid using toxic solvents to achieve a more uniform,large-area perovskite film.Furthermore,modification of the NiO_(x)/perovskite buried interface and introduction of Urea additives were utilized to reduce interface recombination and regulate perovskite crystallization.As a result,a large-area perovskite film possessing larger grains,fewer pinholes,and reduced defects could be achieved.The inverted PSM with an active area of 61.56 cm^(2)(10×10 cm^(2)substrate)achieved a champion power conversion efficiency of 20.56%and significantly improved stability.This method suggests an innovative approach to resolving the uniformity issue associated with large-area film fabrication.
基金financially supported by the National Natural Science Foundation of China(52203237)the Fundamental Research Funds for the Central Universities.
文摘Effective perovskite crystallization control strategies for flexible substrates with scalable processing techniques have rarely been reported and remain an important challenge.In this study,3-mercaptobenzoic acid(3-MBA)was introduced into the perovskite precursor to modulate the crystallization dynamics,facilitating rapid nucleation while slowing down crystal growth.This approach enabled the formation of uniform,dense large-area perovskite films on flexible substrates.Consequently,a 12 cm^(2) flexible perovskite solar module achieved a power conversion efficiency(PCE)of 16.43%.Additionally,the module exhibited enhanced mechanical stability under various bending radii and improved light stability,marking a substantial advance toward the practical application of flexible perovskite solar modules.
基金supported by funding from the Energy Materials and Surface Sciences Unit of the Okinawa Institute of Science and Technology Graduate Universitythe OIST R&D Cluster Research Program,the OIST Proof of Concept(POC)ProgramJST A-STEP Grant Number JPMJTM20HS,Japan。
文摘Tin dioxide(SnO_(2))has been demonstrated as one of the promising electron transport layers for high-efficiency perovskite solar cells(PSCs).However,scalable fabrication of SnO_(2) films with uniform coverage,desirable thickness and a low defect density in perovskite solar mod-ules(PSMs)is still challenging.Here,we report preparation of high-quality large-area SnO_(2) films by chemical bath depo-sition(CBD)with the addition of KMnO_(4).The strong oxidiz-ing nature of KMnO_(4) promotes the conversion from Sn(II)to Sn(VI),leading to reduced trap defects and a higher carrier mobility of SnO_(2).In addition,K ions diffuse into the per-ovskite film resulting in larger grain sizes,passivated grain boundaries,and reduced hysteresis of PSCs.Furthermore,Mn ion doping improves both the crystallinity and the phase stability of the perovskite film.Such a multifunctional interface engineering strategy enabled us to achieve a power conversion efficiency(PCE)of 21.70% with less hysteresis for lab-scale PSCs.Using this method,we also fabricated 5×5 and 10×10 cm^(2) PSMs,which showed PCEs of 15.62% and 11.80%(active area PCEs are 17.26%and 13.72%),respectively.For the encapsulated 5×5 cm^(2) PSM,we obtained a T80 operation lifetime(the lifespan during which the solar module PCE drops to 80%of its initial value)exceeding 1000 h in ambient condition.
基金the Jardine Foundation and Cambridge Trust for a doctoral scholarshipthe European Union(EU)Horizon 2020 research and innovation program under grant No.764047(ESPResSo)+12 种基金funding from the European Union's Horizon 2020 research and innovation programme under grant agreement No.823717-ESTEEM3.J.F.Oacknowledges funding from the Engineering and Physical Sciences Research Council(EPSRC)Nano Doctoral Training Centre(EP/L015978/1)J.F.O.,G.K.,and R.A.O.acknowledge Attolight and EPSRC(EP/R025193/1)for funding and supporting the SEM-CL systemE.M.T.thanks the EU Horizon 2020 research and innovation program under the Marie Skłodowska-Curie grant agreement no.841265.S.D.S.E.M.T.acknowledge funding from the EPSRC(EP/R023980/1)the EPSRC Centre for Advanced Materials for Integrated Energy Systems(CAM-IES,EP/P007767/1)Cambridge Royce facilities grant(EP/P024947/1)S.D.S.acknowledges funding from the Royal Society and Tata Group(UF150033)from the European Research Council under the EU Horizon 2020 research and innovation program under grant No.756962(HYPERION)W.L.and J.L.M.-D.acknowledge support from the EPSRC(EP/L011700/1,EP/N004272/1)the Leverhulme Trust(RPG-2015-017)the Royal Academy of Engineering Chair in Emerging Technologies(CiET1819_24)We wish to acknowledge the support of the Henry Royce Institute(HRI)for F.U.K.through the Royce PhD Equipment Access Scheme enabling access to the NanoSIMS facility at Manchester.The NanoSIMS was funded by UK Research Partnership Investment Funding(UKRPIF)Manchester RPIF Round 2.This work was supported by the HRI,funded through EPSRC grants EP/R00661X/1,EP/S019367/1,EP/P025021/1,and EP/P025498/1
文摘Most thin-film photovoltaic modules are constructed on soda-lime glass(SLG)substrates containing alkali oxides,such as Na_(2)O.Na may diffuse from SLG into a module's active layers through P1 lines,an area between a module's constituent cells where the substrate-side charge transport layer(CTL)is in direct contact with SLG.Na diffusion from SLG is known to cause several important effects inⅡ-Ⅵand chalcogenide solar modules,but it has not been studied in perovskite solar modules(PSMs).In this work,we use complementary microscopy and spectroscopy techniques to show that Na diffusion occurs in the fabrication process of PSMs.Na diffuses vertically inside P1 lines and then laterally from P1 lines into the active area for up to 360 pm.We propose that this process is driven by the high temperatures the devices are exposed to during CTL and perovskite annealing.The diffused Na preferentially binds with Br,forming Br-poor,l-rich perovskite and a species rich in Na and Br(Na-Br)close to P1 lines.Na-Br passivates defect sites,reducing non-radiative recombination in the perovskite and boosting its luminescence by up to 5×.Na-Br is observed to be stable after 12 weeks of device storage,suggesting long-lasting effects of Na diffusion.Our results not only point to a potential avenue to increase PSM performance but also highlight the possibility of unabated Na diffusion throughout a module's lifetime,especially if accelerated by the electric field and elevated temperatures achievable during device operation.
基金financially supported by the National Key R&D Program of China(2021YFB3401604)the Natural Science Foundation of Jiangxi Province(20202ACB214008)+3 种基金the Science and Technology Programs of Fujian Province(2022H0005)the Key Scientific and Technological Program of Xiamen(3502Z20211002)the Open Fund of the State Key Laboratory of Integrated Optoelectronics(IOSKL2020KF12)the Science and Technology Projects of Innovation Laboratory for Sciences and Technologies of Energy Materials of Fujian Province(RD2020020101)。
文摘The stability issue has been acknowledged as the bottleneck in the practical application of perovskite photovoltaics,while the stabilized interface between the perovskites and charge transport layers dominates their stability performance under different stresses.Here,we developed a high-performance sulfurized zinc-titanium mixed oxide(ZTO-S)electron transport layer(ETL)to fabricate large-area efficient and long-term 85℃/85%RH stable perovskite solar modules.The scalably prepared ZTO-S using the facile spray coating method demonstrates excellent electron mobility close to that of Zn O,in addition to promoting the uniform crystallization of perovskite film across the entire module via the interaction between surface S and Pb^(2+).Furthermore,this novel coordination stabilized the interface and reduced the interfacial non-radiative recombination defects within the devices,yielding an efficient and stable performance for the modules.High efficiency of 21.73%and 17.50%was achieved for blade-coated 36 cm^(2)and 100 cm^(2)perovskite solar modules,respectively.In addition,the encapsulated module(36 cm^(2))shows an attractive humidity and heat stability(85℃/85%RH)performance with a maintained 93.5%of the initial PCE over 1000 h.
基金the APRC Grant of the City University of Hong Kong(9380086)the TCFS Grant(GHP/018/20SZ)and MRP Grant(MRP/040/21X)from the Innovation and Technology Commission of Hong Kong+3 种基金the Green Tech Fund(202020164)from the Environment and Ecology Bureau of Hong Kongthe GRF grants(11307621,11316422)from the Research Grants Council of Hong KongGuangdong Major Project of Basic and Applied Basic Research(2019B030302007)Guangdong-Hong Kong-Macao Joint Laboratory of Optoelectronic and Magnetic Functional Materials(2019B121205002).
文摘The persistency of passivation and scalable uniformity are vital issues that limit the improvement of performance and stability of large-area perovskite solar modules(PSMs).Here,we design a bilayer interface engineering strategy that takes advantage of the stability and passivation ability of low-dimensional perovskite and the dipole layer.Introducing phenethylammonium iodide(PEAI)can form 2D/3D heterojunctions on the perovskite surface and effectively passivate defects of perovskite film.Interestingly,the upper piperazinium iodide(PI)layer can still form surface dipoles on the 2D/3D perovskite surface to optimize energy-level alignment.Moreover,the bilayer interface engineering enables large-area perovskite films with uniform surface morphology,lower trap-state density and stability against environmental stress factors.The final devices achieved a small-area PCE of 25.20% and a large-area(1 cm^(2))PCE of 23.96%.A perovskite mini-module(5×5 cm^(2) with an active area of 14.28 cm^(2))could also be fabricated to achieve a PCE of 23.19%,ranking it among the highest for inverted PSMs.Additionally,the device could retain over 93% of its initial efficiency after MPP tracking at 45℃ for 1280 h.This study successfully demonstrates a bilayer interface engineering with respective functions,offering valuable insights for producing efficient and stable large-area PSCs.
基金supported by the National Natural Science Foundation of China(Nos.62104028 and 62174021)the Creative Research Groups of the National Natural Science Foundation of Sichuan Province(No.2023NSFSC1973)+2 种基金the Natural Science Foundation of Sichuan Province(No.2022NSFSC0899)the Guang Dong Basic and Applied Basic Research Foundation(No.2023A1515110067)the China Postdoctoral Science Foundation(No.2021M700689).
文摘Perovskite solar cells have shown great potential in the field of underwater solar cells due to their excellent optoelectronic properties;however,their underwater performance and stability still hinder their practical use.In this research,a 1H,1H,2H,2H-heptadecafluorodecyl acrylate(HFDA)anti-reflection coating(ARC)was introduced as a high-transparent material for encapsulating perovskite solar modules(PSMs).Optical characterization results revealed that HFDA can effectively reduce reflection of light below 800 nm,aiding in the absorption of light within this wavelength range by underwater solar cells.Thus,a remarkable efficiency of 14.65%was achieved even at a water depth of 50 cm.And,the concentration of Pb^(2+)for HFDA-encapsulated film is significantly reduced from 186 to 16.5 ppb after being immersed in water for 347 h.Interestingly,the encapsulated PSMs still remained above 80%of their initial efficiency after continuous underwater illumination for 400 h.Furthermore,being exposed to air,the encapsulated PSMs maintained 94%of their original efficiency after 1000 h light illumination.This highly transparent ARC shows great potentials in enhancing the stability of perovskite devices,applicable not only to underwater cells but also extendable to land-based photovoltaic devices.
基金supported by the National Natural Science Foundation of China(52372279,52103071,52203322,52473289,52303220)the Interdisciplinary Research Project for Young Teachers of USTB(Fundamental Research Funds for the Central Universities in China,FRF-IDRY-GD22-001)。
文摘The advancement of sophisticated smart windows exhibiting superior thermoregulation capabilities in both solar spectrum and long-wave infrared range maintains a prominent objective for researchers in this field.In this study,a Janus window is proposed and prepared based on polymer-stabilized liquid-crystal films/thermochromic materials.It can achieve switchable front long-wave infrared emissivity(ε_(Front))and solar modulation ability(ΔT_(sol))through dynamic flipping,making it suitable for different seasonal energy-saving requirements.Outdoor experiments show that under daytime illumination,the indoor temperature decreases by 8℃,and the nighttime temperature drops by 5℃.MATLAB simulation calculations indicate that the daytime cooling power is 93 W m^(-2),while the nighttime cooling power reaches 142 W m^(-2).Interestingly,by modifying the conductive layer,it can effectively shield electromagnetic radiation(within the X-band frequency range(8.2-12.4)GHz).Energy simulation reveals the substantial superiority of this device in energy savings compared with single-layer polymer-stabilized liquid crystal,poly(N-isopropyl acrylamide),and normal glass when applied in different climate zones.This research presents a compelling opportunity for the development of sophisticated smart windows characterized by exceptional thermoregulation capabilities.
基金supported by the Science&Technology Development Fund of Tianjin Education Commission for Higher Education(No.2022KJ133).
文摘Quantum dots(QDs)can modulate the solar spectrum through the down-conversion mechanism to better match the spectral response of solar cells.Following previous work,this paper first tested the response of QD solar cells to specific monochromatic light,and found that QDs can effectively improve the photoelectric conversion efficiency(PCE)in the ultraviolet(UV)band by comparison.Then the photoelectric properties of the QD solar cells are tested under the air-mass 1.5(AM1.5)and air-mass 0(AM0)spectra.The experimental results show that because the absorption band of QDs is in the UV region,the space solar cells in the AM0 spectrum can obtain better PCE after coating QDs.The research results show the technical route of space solar cells with down-conversion mechanism,and put forward an important direction for the application of space solar photovoltaic(PV)technology,and have a good application prospect.
基金This work was financially supported by the National Natural Science Foundation of China(51672094,51661135023)the National Key R&D Program of China(2016YFC0205002)+1 种基金the Selfdetermined and Innovative Research Funds of HUST(2016JCTD111)the open research funds of Engineering Research Center of Nano-Geo Materials of Ministry of Education,China University of Geosciences(NGM2017KF013).
文摘Organometal halide perovskites have exhibited a bright future as photovoltaic semiconductor in next generation solar cells due to their unique and promising physicochemical properties.Over the past few years,we have witnessed a tremendous progress of efficiency record evolution of perovskite solar cells(PSCs).Up to now,the highest efficiency record of PSCs has reached 22.1%;however,it was achieved at a very small device area of<0.1 cm^(2).With the device area increasing to mini-module scale,the efficiency record dropped dramatically.The inherent causes are mainly ascribed to inadequate quality control of large-area perovskite thin films and insufficient optimization of solar module design.In current stage of PSCs research and development,to overcome these two obstacles is in urgent need before this new technology could realize scale-up industrialization.Herein,we present an overview of recently developed strategies for preparing large-area perovskite thin films and perovskite solar modules(PSMs).At last,cost analysis and future application directions of PSMs have also been discussed.
基金supported by the National Natural Science Foundation of China (Grant No. NSFC62004182)the Career Development Grant of Institute of Chemical Materials (Grant No. STB-2021-10)the Sichuan Science and Technology Program (Grant No. 2022JDRC0021)。
文摘Commercialization of perovskite solar cells(PSCs) requires the development of high-efficiency devices with none current density-voltage(J-V) hysteresis. Here, electron transport layers(ETLs) with gradual change in work function(WF) are successfully fabricated and employed as an ideal model to investigate the energy barriers, charge transfer and recombination kinetics at ETL/perovskite interface. The energy barrier for electron injection existing at ETL/perovskite is directly assessed by surface photovoltage microscopy, and the results demonstrate the tunable barriers have significant impact on the J-V hysteresis and performance of PSCs. By work function engineering of ETL, PSCs exhibit PCEs over 21% with negligible hysteresis. These results provide a critical understanding of the origin reason for hysteresis effect in planar PSCs, and clear reveal that the J-V hysteresis can be effectively suppressed by carefully tuning the interface features in PSCs. By extending this strategy to a modified formamidinium-cesium-rubidium(FA-Cs-Rb) perovskite system, the PCEs are further boosted to 24.18%. Moreover, 5 cm × 5 cm perovskite mini-modules are also fabricated with an impressive efficiency of 20.07%, demonstrating compatibility and effectiveness of our strategy on upscaled devices.
基金This work was funded by the European Union’s Horizon 2020 program,through a FET Proactive research and innovation action under grant agreement No.101084124(DIAMOND)supported by the 111 Project(B16016),and the Project of Scientific and Technological Support Program in Jiang Su Province(BE2022026-2)+2 种基金K.Z.thanks to the China Scholarship Council(no.202206730056)X.F.Z.thanks to the China Scholarship Council(no.202206730058)R.W.acknowledges the grant(LD22E020002)by the Natural Science Foundation of Zhejiang Province of China.
文摘Perovskite crystal facets greatly impact the performance and stability of their corresponding photovoltaic devices.Compared to the(001)facet,the(011)facet yields better photoelectric properties,including higher conductivity and enhanced charge carrier mobility.Thus,achieving(011)facet-exposed films is a promising way to improve device performance.However,the growth of(011)facets is energetically unfavorable in FAPbI_(3) perovskites due to the influence of methylammonium chloride additive.Here,1-butyl-4-methylpyridinium chloride([4MBP]Cl)was used to expose(011)facets.The[4MBP]^(+)cation selectively decreases the surface energy of the(011)facet enabling the growth of the(011)plane.The[4MBP]^(+)cation causes the perovskite nuclei to rotate by 45°such that(011)crystal facets stack along the out-of-plane direction.The(011)facet has excellent charge transport properties and can achieve better-matched energy level alignment.In addition,[4MBP]Cl increases the activation energy barrier for ion migration,suppressing decomposition of the perovskite.As a result,a small-size device(0.06 cm2)and a module(29.0 cm2)based on exposure of the(011)facet achieved power conversion efficiencies of 25.24%and 21.12%,respectively.
基金Project(2022YFB3803300)supported by the National Key Research and Development Program of ChinaProjects(U23A20138,52173192)supported by the National Natural Science Foundation of China+1 种基金Project(GZC20233148)supported by the Postdoctoral Fellowship Program of CPSF,ChinaProject(140050043)supported by the Central South University Postdoctoral Research Funding,China。
文摘Highly efficient organic solar cells(OSCs)are normally produced using the halogenated solvents chloroform or chlorobenzene,which present challenges for scalable manufacturing due to their toxicity,narrow processing window and low boiling point.Herein,we develop a novel high-speed doctor-blading technique that significantly reduces the required concentration,facilitating the use of eco-friendly,non-halogenated solvents as alternatives to chloroform or chlorobenzene.By utilizing two widely used high-boiling,non-halogenated green solvents-o-xylene(o-XY)and toluene(Tol)-in the fabrication of PM 6:L 8-BO,we achieve power conversion efficiencies(PCEs)of 18.20%and 17.36%,respectively.Additionally,a module fabricated with o-XY demonstrates a notable PCE of 16.07%.In-situ testing and morphological analysis reveal that the o-XY coating process extends the liquid-to-solid transition stage to 6 s,significantly longer than the 1.7 s observed with Tol processing.This prolonged transition phase is crucial for improving the crystallinity of the thin film,reducing defect-mediated recombination,and enhancing carrier mobility,which collectively contribute to superior PCEs.
文摘In the 21st century, the deployment of ground-based Solar Photovoltaic (PV) Modules has seen exponential growth, driven by increasing demands for green, clean, and renewable energy sources. However, their usage is constrained by certain limitations. Notably, the efficiency of solar PV modules on the ground peaks at a maximum of 25%, and there are concerns regarding their long-term reliability, with an expected lifespan of approximately 25 years without failures. This study focuses on analyzing the thermal efficiency of PV Modules. We have investigated the temperature profile of PV Modules under varying environmental conditions, such as air velocity and ambient temperature, utilizing Computational Fluid Dynamics (CFD). This analysis is crucial as the efficiency of PV Modules is significantly impacted by changes in the temperature differential relative to the environment. Furthermore, the study highlights the effect of airflow over solar panels on their temperature. It is found that a decrease in the temperature of the PV Module increases Open Circuit Voltage, underlining the importance of thermal management in optimizing solar panel performance.
文摘This project adopts an advanced microcontroller as the core control unit,which accurately commands the servo drive,realizes the real-time light chasing and charging function of the solar panel,and effectively manages the power supply system of the street light.At the same time,the system is able to continuously monitor the operation status of the servo within the range of 0°to 180°to ensure that it is trouble-free and not offline.The hardware system construction consists of five modules:a power module,solar panel module,servo module,street light module,and Organic Light-Emitting Diode(OLED)display module.Each module works together to support the stable operation of the whole system.The system workflow is to accurately determine the direction of the light source by collecting real-time light intensity data through four precision photoresistors.Subsequently,the microcontroller intelligently controls the helm module based on these data to drive the solar panel to rotate within a range of 180°to accurately track the sun’s orientation.The street light provides two lighting modes,automatic and manual,to meet the needs of different scenarios.During the daytime,the solar panels work actively to monitor and collect solar energy efficiently in real-time,meanwhile,when night falls,the solar panels switch to standby mode and the streetlights light up automatically,illuminating the road ahead for pedestrians.Compared with the traditional solar street lights on the market,the intelligent solar light chasing road system introduced in this project has significant advantages.Its unique light-chasing algorithm enables the solar panel to continuously track the light source from sunrise to sunset,thus significantly improving the charging efficiency.Compared with traditional street lights,the biggest advantage of this project is the proposed light-chasing algorithm,which can always charge from sunrise until sunset,making the charging efficiency increase by 38%to 47%.The charging efficiency is 20%to 38%higher than that of traditional street lamps.Simultaneously,the biggest advantage of this project is that the power storage capacity is higher than 35%of the traditional solar street light.Bringing users a more durable and stable lighting experience.
基金supported by the Energy Materials and Surface Sciences Unit of the Okinawa Institute of Science and Technology Graduate Universitythe OIST R&D Cluster Research Program+1 种基金the OIST Proof of Concept(POC)ProgramJSPS KAKENHI Grant Number JP18K05266。
文摘The booming growth of organic-inorganic hybrid lead halide perovskite solar cells have made this promising photovoltaic technology to leap towards commercialization.One of the most important issues for the evolution from research to practical application of this technology is to achieve high-throughput manufacturing of large-scale perovskite solar modules.In particular,realization of scalable fabrication of large-area perovskite films is one of the essential steps.During the past ten years,a great number of approaches have been developed to deposit high quality perovskite films,to which additives are introduced during the fabrication process of perovskite layers in terms of the perovskite grain growth control,defect reduction,stability enhancement,etc.Herein,we first review the recent progress on additives during the fabrication of large area perovskite films for large scale perovskite solar cells and modules.We then focus on a comprehensive and in-depth understanding of the roles of additives for perovskite grain growth control,defects reduction,and stability enhancement.Further advancement of the scalable fabrication of high-quality perovskite films and solar cells using additives to further develop large area,stable perovskite solar cells are discussed.
基金supported by the National Key Research and Development Program of China(No.2017YFE0127100)the National Natural Science Foundation of China(No.22025505)the Program of Shanghai Academic/Technology Research Leader(No.20XD1422200).
文摘Perovskite solar cells(PSCs)have undergone a dramatic increase in laboratory-scale effi ciency to more than 25%,which is comparable to Si-based single-junction solar cell effi ciency.However,the effi ciency of PSCs drops from laboratory-scale to large-scale perovskite solar modules(PSMs)because of the poor quality of perovskite fi lms,and the increased resistance of large-area PSMs obstructs practical PSC applications.An in-depth understanding of the fabricating processes is vital for precisely controlling the quality of large-area perovskite fi lms,and a suitable structural design for PSMs plays an impor-tant role in minimizing energy loss.In this review,we discuss several solution-based deposition techniques for large-area perovskite fi lms and the eff ects of operating conditions on the fi lms.Furthermore,diff erent structural designs for PSMs are presented,including the processing technologies and device architectures.
