The amino poly-siloxane was modified with self-made polyether silicones by the crafts of emulsion polymerization. We studied the emulsifier, the dosage of emulsifier initiator, polyether/silane coupling agent, pH valu...The amino poly-siloxane was modified with self-made polyether silicones by the crafts of emulsion polymerization. We studied the emulsifier, the dosage of emulsifier initiator, polyether/silane coupling agent, pH value. There are some results of the research indicated in the following. First, there are many factors for the hydrophilic amino-silicone softener both on the polymerization process and the performance, such as the proportion and amount of emulsifier, initiator dosage, the mass ratio of the polyether and hydrogen silicone oil, the choice of silicone coupling agent, and the ratio and dosage of polyether silicones silane coupling agent. Second, the amount of hydrogen of the hydrogen silicones and the choice of catalyst are the key points on the synthesis of polyether silicones. The amount of hydrogen should be low and the catalyst must be economical and efficient and its introduction should be small and times, other more the holding time is not too long. The next one is that, in the process of hydrolysis of silane coupling agent, we need some acid to adjust pH value, or they will be broken down. The most important one but not the last is that the epoxy group can improve the products low-temperature supple and the persistence of the finishing fabric, furthermore it can reduce yellowing and has a good stability of the inorganic salt, however, it will be destroyed if the reaction temperature for epoxy is too high. What’s more, it is very economical and environmental that the process of emulsion is simple and with less emulsifier.展开更多
Chemical softener (Cepreton UN) is used to soften the cellulosic fiber (cotton) in the textile industries to make clothes better to touch. Therefore, this study investigated the effects of Cepreton UN on both physical...Chemical softener (Cepreton UN) is used to soften the cellulosic fiber (cotton) in the textile industries to make clothes better to touch. Therefore, this study investigated the effects of Cepreton UN on both physical (length, aspect ratio, contact angle, and moisture regain) and mechanical (load at break, elongation at break, tensile stress, young’s modulus, and tenacity) properties of the lignocellulosic canola (HYREAR 3) fibers extracted from narrow, medium, and wide stems. ANOVA showed that fiber diameter had strong effects on elongation at break, load at break, tensile stress, young’s modulus, and aspect ratio for all fibers. Corrgram values showed that tensile stress, young’s modulus, and aspect ratio were negatively correlated to fiber diameter whereas load at break and tenacity were mostly positively correlated to fiber diameter. The fibers were treated with 2% and 10% Cepreton UN and compared with control fibers. In most cases, the fiber diameter was decreased in both 2% and 10% treated medium stem fibers. The mean values of elongation at break, load at break, tenacity, and contact angle were decreased for 10% and increased for 2% and the mean values of tensile stress, young’s modulus, and aspect ratio were decreased for 2% and increased for 10% treated medium stem fibers. Moisture regain (%) mostly decreased for 2%, and increased for 10% treated fibers. Low pH (4.5) had an almost similar effect on fibers as 2% Cepreton UN. Overall, 2% Cepreton UN treatment is found to be better than 10% to make canola fibers less stiff and low pH was found to be an alternative softener treatment strategy.展开更多
Ascorbate(Asc),commonly known as vitamin C,is a vital molecule for plant growth,development,and stress resilience.It is also known to play a crucial role in various physiological processes,including photosynthesis,cel...Ascorbate(Asc),commonly known as vitamin C,is a vital molecule for plant growth,development,and stress resilience.It is also known to play a crucial role in various physiological processes,including photosynthesis,cell division,and differentiation.This article thoroughly explores the processes governing the metabolism of Asc in plants and its roles in physiological functions.It lays down a robust theoretical groundwork for delving into Asc production,transportation,functions,and its potential applications in stress alleviation and horticulture.Furthermore,recent studies indicate that Asc plays a role in regulating fruit development and affecting postharvest storage characteristics,thereby influencing fruit ripening and resilience to stress.Hence,there is a growing importance in studying the synthesis and utilization of Asc in plants.Although the critical role of Asc in controlling plant redox signals has been extensively studied,the precise mechanisms by which it manages cellular redox homeostasis to maintain the equilibrium between reactive oxygen scavenging and cell redox signaling remain elusive.This gap in knowledge presents fresh opportunities to explore how the production of Asc in plants is regulated and how plants react to environmental stressors.Furthermore,this article delves into the potential for a comprehensive investigation into the essential function of Asc in fruits,the development of Asc-rich fruits,and the enhancement of postharvest storage properties.展开更多
Irradiating hard rocks by a high-power laser can reduce localized hardness in the rocks;however,continuous lasers produce a large amount of melt that inhibits further heat absorption.Pulsed lasers allow rocks to absor...Irradiating hard rocks by a high-power laser can reduce localized hardness in the rocks;however,continuous lasers produce a large amount of melt that inhibits further heat absorption.Pulsed lasers allow rocks to absorb and dissipate energy and avoid melt formation.In this study,200 W nanosecond pulsed laser was used to irradiate granite.The effects of laser parameters on the thermal cracking morphology,temperature field,warming pattern,and Leeb hardness of the granite surface were analyzed.The optimal laser parameters for softening granite were determined by performing objective optimization in MATLAB using granite's melting point as the reference.Nanoindentation techniques were employed to assess the softening characteristics of the granite surface along the longitudinal direction.The results showed that three main forms of thermal damage occurred on the granite surface:oxidative decomposition,spalling,and melting.The damage state was affected by the average laser power,with the pulse width and repetition frequency affecting surface damage differently.Appropriate laser parameters effectively controlled the melt damage on the granite surface,and irradiation with nanosecond pulsed lasers effectively reduced surface hardness.However,excessive power can generate large amounts of hard melts and weaken the softening effect.展开更多
In the field of rock engineering,the influence of water is a dynamic process that exhibits varying effects over time and across different locations.To further understand how water influences the mechanical properties ...In the field of rock engineering,the influence of water is a dynamic process that exhibits varying effects over time and across different locations.To further understand how water influences the mechanical properties and acoustic emission(AE)behavior of rocks,this study conducted uniaxial compression experiments on sandstones with varying degrees of wetting under both natural conditions and water-chemical environments.In addition,the study combined AE equipment with digital image correlation(DIC)to monitor the entire failure process.Using the sliding window algorithm,the variation in the variance of AE characteristic parameters during the process of sandstone loading to failure is analyzed from the perspective of critical slowing down.This analysis enables the effective identification of the early warning signal before failure.The experimental findings suggest that an increase in wetting height results in a gradual decrease in peak stress,accompanied by a concomitant increase in the percentage of shear cracks.The characteristic parameters,including energy,amplitude,and ringing count,all exhibit critical slowing phenomena.The waveform of AE characteristic parameters of the same sample is similar,and the mutation time of the precursor signal is roughly the same.All signals appear in the irreversible plastic deformation stage of microcrack initiation.The integration of critical slowing down theory and the b-value early warning method facilitates a more comprehensive evaluation of the stability of rock mass,thereby significantly enhancing the efficiency and safety of disaster prevention measures.展开更多
In this paper,the work hardening and softening behavior of AZ31 magnesium alloy sheets by hard plate accumulative roll bonding(HP-ARB)process in a specific temperature range was studied for the first time,and the cycl...In this paper,the work hardening and softening behavior of AZ31 magnesium alloy sheets by hard plate accumulative roll bonding(HP-ARB)process in a specific temperature range was studied for the first time,and the cyclic stress relaxation test,EBSD,TEM and other characterization methods were used.When the rolling temperature is 350℃,the grain size of magnesium sheets is refined to 4.32(±0.36)μm on average,and it shows an excellent combination of strength and plasticity.The tensile strength reaches 307(±8.52)MPa and the elongation is 12.73(±0.84)%.At this time,the curve of work hardening rate decreases smoothly and the degree of hardening is the lowest,and the amplitude of stress drop △σ_(p) in work softening test is the smallest with the increase of cycle times,which shows that the well coordination between work hardening and softening behavior has been achieved.Research has found that the combined effect of grain boundary strengthening and fine grain strengthening enhances the yield and tensile strength of magnesium sheets after three passes HP-ARB process at 350℃.This is attributed to the high degree of dislocation slip opening in the pyramidal surfaceand<c+a>,which not only coordinates the c-axis strain of the entire grain,but also promotes the slip transfer of dislocations in the fine-grained region,significantly improving the elongation of the sheets.This study provides a new idea for the forming and manufacturing of high performance magnesium alloy sheets.展开更多
To obtain the Ti_(p)with different aspect ratios,the Ti_(p)/Mg-5Zn-0.3Ca composite prepared by semi-solid stir casting was subjected to extrusion at 220℃,180℃,and 140℃,respectively.Then,the effect of the Ti_(p)’s ...To obtain the Ti_(p)with different aspect ratios,the Ti_(p)/Mg-5Zn-0.3Ca composite prepared by semi-solid stir casting was subjected to extrusion at 220℃,180℃,and 140℃,respectively.Then,the effect of the Ti_(p)’s aspect ratio on the microstructure,mechanical properties,work hardening and softening behaviors of Ti_(p)/Mg-5Zn-0.3Ca composites was investigated.The results indicated that the Ti_(p)could be elongated obviously after low-temperature extrusion,and the aspect ratio of which would reach to 13.7:1 as the extrusion temperature deceased to 140℃.Then the“Ti/Mg”layer-like structure was formed in the Ti_(p)/Mg-5Zn-0.3Ca composite.Accompanied with the elongation of Ti_(p),the dynamic recrystallized grains and dynamic precipitates were both refined significantly,however,the dynamic recrystallization rate changed a little.The elongated Ti_(p)endowed the Ti_(p)/Mg-5Zn-0.3Ca composites with better matching of strength and toughness without the sacrifice of elongation and bending strain.Both the work hardening rate and softening rate of Ti_(p)/Mg-5Zn-0.3Ca composites increased with the increasing aspect ratio of Ti_(p).The formation of“Ti/Mg”layer-like structure contributed to the redistribution of strain from large aggregations to a network-like distribution,which effectively suppresses the initiation and propagation of micro-cracks,thus enhancing the plasticity of the Ti_(p)/Mg-5Zn-0.3Ca composites.展开更多
Large interfacial strains in particles are crucial for promoting bonding in cold spraying(CS),initiated either by adiabatic shear instability(ASI)due to softening prevailing over strain hardening or by hydrostatic pla...Large interfacial strains in particles are crucial for promoting bonding in cold spraying(CS),initiated either by adiabatic shear instability(ASI)due to softening prevailing over strain hardening or by hydrostatic plasticity,which is claimed to promote bonding even without ASI.A thorough microstructural analysis is vital to fully understand the bonding mechanisms at play during microparticle impacts and throughout the CS process.In this study,the HEA CoCrFeMnNi,known for its relatively high strain hardening and resistance to softening,was selected to investigate the microstructure characteristics and bonding mech-anisms in CS.This study used characterization techniques covering a range of length scales,including electron channeling contrast imaging(ECCI),electron backscatter diffraction(EBSD),and high-resolution transmission microscopy(HR-TEM),to explore the microstructure characteristics of bonding and overall structure development of CoCrFeMnNi microparticles after impact in CS.HR-TEM lamellae were prepared using focused ion beam milling.Additionally,the effects of deformation field variables on microstructure development were determined through finite element modeling(FEM)of microparticle impacts.The ECCI,EBSD,and HR-TEM analyses revealed an interplay between dislocation-driven processes and twinning,leading to the development of four distinct deformation microstructures.Significant grain refinement occurs at the interface through continuous dynamic recrystallization(CDRX)due to high strain and temperature rise from adiabatic deformation,signs of softening,and ASI.Near the interface,a necklace-like structure of refined grains forms around grain boundaries,along with elongated grains,resulting from the coexistence of dynamic recovery and discontinuous dynamic recrystallization(DDRX)due to lower temperature rise and strain.Towards the particle or substrate interior,concurrent twinning and dislocation-mediated mechanisms refine the structure,forming straight,curved,and intersected twins.At the top of the particles,only deformed grains with a low dislocation density are observed.Our results showed that DRX induces microstructure softening in highly strained interface areas,facilitating atomic bonding in CoCrFeMnNi.HR-TEM investigation confirms the formation of atomic bonds between particles and substrate,with a gradual change in crystal lattice orientation from the particle to the substrate and the occurrence of some misfit dislocations and vacancies at the interface.Finally,the findings of this research suggest that softening and ASI,even in materials resistant to softening,are required to establish bonding in CS.展开更多
With the generation of both localised thermal and vibration in incremental sheet forming(ISF)by novel tool designs,rotational vibration assisted ISF(RV-ISF)can achieve significant force reduction and material softenin...With the generation of both localised thermal and vibration in incremental sheet forming(ISF)by novel tool designs,rotational vibration assisted ISF(RV-ISF)can achieve significant force reduction and material softening.However,the combined thermal and vibration softening in RV-ISF is unclear.By evaluating the similarities and differences of friction stir ISF(FS-ISF)and RV-ISF,this study develops a novel approach to decouple and quantify the thermal and vibration softening effects in RV-ISF of AZ31B-H24,providing new insights into underlying thermal and vibration softening mechanism.Experimental results reveal that in RV-ISF of AZ31B-H24 the thermal softening due to frictional heating dominates with 45∼65%of softening,while the vibration effect only contributes up to 15%of softening,from the conventional ISF,depending on the tool designs and tool rotational speed.The double-offset tool(T2)produces greater vibration softening than the three-groove tool(T3)owing to the higher vibration amplitude of the T2 tool.An increase in tool rotational speed primarily enhances thermal softening with only marginal changes to the vibration effect.Microstructural analysis suggests that with average grain size of 0.94μm at the top layer,RV-ISF with T3 and 3000 rpm is more effective for microstructure refinement than that by FS-ISF,especially on the tool-sheet contact surface,which confirms the occurrence of surface shearing.This refinement is a result of the reduced recrystallisation degree,71.8%at the top bottom layer.Compared with FS-ISF,RV-ISF can lead to not only higher geometrically necessary dislocation density,but also higher fraction of low-angle grain boundaries,indicating that softening mechanism due to localised vibration effect is resulted from the enhanced rearrangement and annihilation of dislocations.These findings contribute to new understanding of the thermal and vibration softening effects in RV-ISF of AZ31B-H24 and offer a theoretical foundation for the tool design and process optimisation.展开更多
In order to obtain a lower frequency band gap,this paper proposes a novel locally resonant meta-beam incorporating a softening nonlinear factor.An improved camroller structure is designed in this meta-beam to achieve ...In order to obtain a lower frequency band gap,this paper proposes a novel locally resonant meta-beam incorporating a softening nonlinear factor.An improved camroller structure is designed in this meta-beam to achieve the softening nonlinear stiffness of the local oscillators.Firstly,based on Hamilton's principle and the Galerkin method,the control equations for the coupled system are established.The theoretical band gap boundary is then derived with the modal analysis method.The theoretical results reveal that the band gap of the meta-beam shifts towards lower frequencies due to the presence of a softening nonlinear factor,distinguishing it from both linear metamaterials and those with hardening nonlinear characteristics.Then,the vibration attenuation characteristics of a finite size meta-beam are investigated through numerical calculation,and are verified by the theoretical results.Furthermore,parameter studies indicate that the reasonable design of the local oscillator parameters based on lightweight principles helps to achieve further broadband and efficient vibration reduction in the low-frequency region.Finally,a prototype of the meta-beam is fabricated and assembled,and the formations of the low-frequency band gap and the amplitude-induced band gap phenomenon are verified through experiments.展开更多
Rubbery waste at the end of the cycle often constitutes a threat for the environment because of their encumbrance and low biodeterioration.The purpose of the research presented is to develop the rubber fine powder as ...Rubbery waste at the end of the cycle often constitutes a threat for the environment because of their encumbrance and low biodeterioration.The purpose of the research presented is to develop the rubber fine powder as a pavement.It is interested primarily in the behavior of two types of bitumen 40/50 modified by the addition of two varieties of rubber fine powders of different grading,resulting from the crushing of the rubbery products intended for the clothes industry of soles of shoes.The objective of the experimentation is to study the influence of the added polymer on the physical properties of the ordinary road bitumen with the incorporation of the fine powder.The experimental approach is carried out using the two tests of characterization of the bitumen i.e.the softening point test and the penetration test which remain the most used to define and classify the road bitumen.It will be noted however,that the experimental investigation which is based on several tests according to the type and the content of fine powders,leads on a whole of interesting correlations.展开更多
In clinical dermatology,approximately 15%of patients suffer from nail disorders.Different nail diseases may present with similar clinical manifestations.When clinical diagnosis based on symptoms,dermoscopy,and fungal ...In clinical dermatology,approximately 15%of patients suffer from nail disorders.Different nail diseases may present with similar clinical manifestations.When clinical diagnosis based on symptoms,dermoscopy,and fungal tests is inconclusive,nail biopsy becomes the most critical diagnostic tool.Nail specimens are highly rigid,brittle,and adhere poorly to slide glass,making sectioning challenging and posing significant difficulties for pathology technicians.Limited literature exists on nail histology processing techniques.This paper reviews and consolidates the available literature on nail paraffin sectioning techniques,aiming to provide insights and methods for pathology technicians.展开更多
While the deformation behavior of rare-earth magnesium alloys at high temperatures has been extensively studied,the deformation mechanisms under moderate-to-low temperatures and high strain rates remain insufficiently...While the deformation behavior of rare-earth magnesium alloys at high temperatures has been extensively studied,the deformation mechanisms under moderate-to-low temperatures and high strain rates remain insufficiently understood.To address this gap,hot compression tests were conducted on a Mg-11Gd-3Y-0.5Zr(wt.%)alloy over a temperature range of 150℃–450℃under strain rates of 10^(-3) s^(-1)(low strain rate(LSR))and 10 s^(-1)(high strain rate(HSR))to explore the strain rate-temperature coupling effects during hot deformation.The results revealed an anomalous increase in peak stress at 150℃–250℃as the strain rate decreased,attributed to the combined effects of nano-precipitates,dislocation cell structures,and serrated flow induced by dynamic strain aging.At higher temperatures,strain rate influences softening pathways:under HSR at 450℃,the effect of twinning shifts from strengthening to facilitating dynamic recrystallization(DRX),resulting in substantial grain refinement(-4 μm,81%area fraction at a strain of 0.6).In contrast,at LSR,softening is dominated by dynamic recovery at 350℃,with limited DRX(-4 μm grains,10%area fraction at a strain of 0.6)occurs at 400℃.These findings clarify the dual role of twinning and its interaction with rate-temperature conditions,providing valuable insights into optimizing the hot processing of rare-earth magnesium alloys.展开更多
Multimodal ultrasonic vibration(UV)assisted micro-forming has been widely investigated for its advantages of further reducing forming loads and improving forming quality.However,the influence mechanism of different UV...Multimodal ultrasonic vibration(UV)assisted micro-forming has been widely investigated for its advantages of further reducing forming loads and improving forming quality.However,the influence mechanism of different UV modes on microstructure evolution and mechanical properties was still unclear.Mul-timodal UV assisted micro-compression tests on T2 copper with different grains and sample sizes were conducted in this study.The microstructure evolution for different UV modes was observed by EBSD.The results showed that the true stress reduction caused by UV was increased sequentially with tool ultrasonic vibration(TV),mold ultrasonic vibration(MV)and compound ultrasonic vibration(CV).The region of grain deformation was shifted along the direction of UV,and the MV promoted the uniform distribution of deformation stress.The grain refinement,fiber streamline density,grain deformation and rotation degree were further enhanced under CV,due to the synergistic effect of TV and MV.Additionally,a coupled theoretical model considering both acoustic softening effect and size effect was proposed for describing the mechanical properties.And a physical model of dislocation motion in different UV modes was developed for describing the microstructure evolution.The maximum error between the theoretical and experimental results was only 2.39%.This study provides a theoretical basis for the optimization of UV assisted micro-forming process.展开更多
This study proposed a new and more flexible S-shaped rock damage evolution model from a phenomenological perspective based on an improved Logistic function to describe the characteristics of the rock strain softening ...This study proposed a new and more flexible S-shaped rock damage evolution model from a phenomenological perspective based on an improved Logistic function to describe the characteristics of the rock strain softening and damage process.Simultaneously,it established a constitutive model capable of describing the entire process of rock pre-peak compaction and post-peak strain softening deformation,considering the nonlinear effects of the initial compaction stage of rocks,combined with damage mechanics theory and effective medium theory.In addition,this research verified the rationality of the constructed damage constitutive model using results from uniaxial and conventional triaxial compression tests on Miluo granite,yellow sandstone,mudstone,and glutenite.The results indicate that based on the improved Logistic function,the theoretical damage model accurately describes the entire evolution of damage characteristics during rock compression deformation,from maintenance through gradual onset,accelerated development to deceleration and termination,in a simple and unified expression.At the same time,the constructed constitutive model can accurately simulate the stress-strain process of different rock types under uniaxial and conventional triaxial compression,and the theoretical model curve closely aligns with experimental data.Compared to existing constitutive models,the proposed model has significant advantages.The damage model parameters a,r and β have clear physical meanings and interact competitively,where the three parameters collectively determine the shape of the theoretical stress−strain curve.展开更多
When tunnelling through low-permeability saturated ground,the pore pressure decreases in the vicinity of the cavity.In certain instances of deep tunnels crossing weak rocks,the pore pressure may even become negative.A...When tunnelling through low-permeability saturated ground,the pore pressure decreases in the vicinity of the cavity.In certain instances of deep tunnels crossing weak rocks,the pore pressure may even become negative.All existing analytical solutions for the undrained ground response curve(GRC)in the literature assume that the ground fully retains its saturation,in which case the development of negative pore pressures has a stabilising effect e it results in increased effective stresses,and thus shearing resistance,which in turn leads to reduced deformations and plastification.In practice,however,negative pore pressures can induce partial or complete ground desaturation,which may even invalidate the premise of undrained conditions and lead to considerably increased deformations and plastification.In such cases,existing solutions are unsafe for design.The present paper aims to address this shortcoming,by presenting a novel analytical solution for the undrained GRC which incorporates the effect of the excavation-induced desaturation.The solution is derived under the assumption that the ground desaturates completely and immediately under negative pore pressures,which provides the upper bound of deformations and plastification for cases of partial desaturation.The rock is considered to be a linear elastic,brittle-plastic material,obeying a non-associated Mohr-Coulomb(MC)yield criterion.Nevertheless,the solution is also applicable to perfectly plastic rocks via a simple modification of the input parameters.Although the solution is in general semi-analytical,simple closed-form expressions are obtained in the special case of non-dilatant rocks.These expressions are also applicable to rocks exhibiting limited dilatancy,which is usually the case.An application example,based on the planned deep geological repository for radioactive waste in Switzerland,demonstrates the significant practical value and usefulness of the novel solution and underscores its necessity in cases where existing solutions that disregard desaturation are rendered thoroughly unsafe for design.展开更多
The hot deformation behavior of 2707 hyper duplex stainless steel(HDSS)was investigated through a hot compression test at 950℃ to 1,250℃ at strain rates of 0.01 s^(-1) to 10 s^(-1).Observations from the flow stress ...The hot deformation behavior of 2707 hyper duplex stainless steel(HDSS)was investigated through a hot compression test at 950℃ to 1,250℃ at strain rates of 0.01 s^(-1) to 10 s^(-1).Observations from the flow stress curves reveal a balance between work hardening and dynamic recovery at the beginning of the deformation and subsequently demonstrate various softening mechanisms with the increase of strain.At high strain rates,dynamic recovery is the prevailing mechanism,whereas,at medium and low strain rates,dynamic recrystallization becomes dominant.The constitutive equation was constructed,and the deformation activation energy was calculated to be 645.46 kJ·mol^(-1).The hot processing map was drawn based on the dynamic material model at a strain of 0.8.The results indicate that the hot workability of 2707 HDSS decreases due to its high alloying content.The microstructure evolution of 2707 HDSS at 1,050℃ was identified by means of electron backscatter diffraction and transmission electron microscopy.The results demonstrate that the ferrite completes dynamic recrystallization at the strain rate of 1 s^(-1).The softening process of austenite is influenced by ferrite and mainly experiences dynamic recovery.The austenite located at the α/γ phase boundaries tends to undergo dynamic recrystallization.展开更多
In the framework of elastoplastic theory,by introducing dissipative plastic energy(instead of cumulative plastic strain)and dissipative plastic energy rate(instead of cumulative plastic strain rate)into the ratchettin...In the framework of elastoplastic theory,by introducing dissipative plastic energy(instead of cumulative plastic strain)and dissipative plastic energy rate(instead of cumulative plastic strain rate)into the ratchetting parameter evolution equation and isotropic evolution rules respectively,a cyclic elastoplastic constitutive model based on dissipative plastic energy is established.This model,termed the WDP model,describes the physical meaning and evolution rule of the unclosed stress–strain hysteresis loop using an energy method.A comparison of numerical implementation results with experimental data demonstrates the capability of the WDP model to predict the cyclic deformation of EA4T steel,effectively capturing the cyclic softening characteristics and ratchetting behaviors of axle steel EA4T.展开更多
Existing creep constitutive models rarely incorporate studies on the coupling mechanism between creep damage and rock strain softening/hardening.This study analyzed the strain softening and hardening behaviors of argi...Existing creep constitutive models rarely incorporate studies on the coupling mechanism between creep damage and rock strain softening/hardening.This study analyzed the strain softening and hardening behaviors of argillaceous sandstone and sandy mudstone during load-induced failure based on the plastic increment theory.These behaviors were then coupled with an improved Burgers creep model to establish a coupled creep-damage and plastic softening/hardening model.Finally,the validity and engineering applicability of the proposed model were verified through FLAC~(3D)numerical simulations.The numerical simulation results of standard cylindrical specimens show that the established coupling model can effectively reflect the unloading creep deformation law and failure characteristics of argillaceous sandstone and sandy mudstone.Taking the diversion tunnel of a hydropower station in Northwest China as an example for engineering application,the coupled creep-damage and plastic softening/hardening model is introduced into FLAC~(3D)to carry out numerical simulation calculation of the tunnel under excavation and unsupported creep conditions.The results show that the uncoordinated deformation of the upper and lower walls of the surrounding rock of the tunnel is more prominent.When the buried depth of the tunnel increases to 80 m,the monitoring point C in the sandy mudstone area of the upper wall shows nonlinear accelerated deformation under unsupported creep conditions,and the maximum displacement in the horizontal direction reaches 44.5 mm,and the maximum displacement in the vertical direction reaches 53.5 mm.The coupled creep-damage and plastic softening/hardening model established in the research results can well describe the whole process of uncoordinated deformation and failure in the unloading creep process of soft-hard interbedded rock mass.展开更多
Multi-pass hot processing methods are commonly used in magnesium(Mg)alloys to overcome the poor workability due to limited slip systems,which generally involve complicated post-deformation softening and hardening beha...Multi-pass hot processing methods are commonly used in magnesium(Mg)alloys to overcome the poor workability due to limited slip systems,which generally involve complicated post-deformation softening and hardening behaviors.In this work,to reveal post-deformation softening and hardening mechanisms of a Mg-2Y-1Zn alloy,double-stage hot compression tests and microstructural observations were conducted.The results showed that the softening fraction of Mg-2Y-1Zn alloy showed a non-linear dependence on deformation conditions and could be general coupled by Z parameter.Due to the formation and cross-overlapping of twins and kinks,only static recovery(SRV)occurred during holding process at 300℃/0.001 s^(-1) which led to the least static softening:5.52% after 10 s of holding.For samples at 400℃/0.001s^(-1),the enhanced post-deformation softening,which is 11.93% after 10 s of holding,was attributed to static recrystallization(SRX)followed continuous dynamic recrystallization(CDRX)happened during first deformation stage as well as SRV influenced by the LPSO phases.Under deformation condition of 400℃/0.1 s^(-1),the coupled meta-dynamic recrystallization(MDRX)and SRX resulted in serious stress relaxation,which is 42.83% after 10 s of holding,and caused hardening phenomenon at reloading stage.The 18R-LPSO and 14H-LPSO phases synchronously worked on deformation behaviors and limited the growth of recrystallized grains.Further,a simplified static softening kinetics model was established based on Johnson-Mehl-Avrami-Kolmogorov equation and employed to rationalize experimental data.展开更多
文摘The amino poly-siloxane was modified with self-made polyether silicones by the crafts of emulsion polymerization. We studied the emulsifier, the dosage of emulsifier initiator, polyether/silane coupling agent, pH value. There are some results of the research indicated in the following. First, there are many factors for the hydrophilic amino-silicone softener both on the polymerization process and the performance, such as the proportion and amount of emulsifier, initiator dosage, the mass ratio of the polyether and hydrogen silicone oil, the choice of silicone coupling agent, and the ratio and dosage of polyether silicones silane coupling agent. Second, the amount of hydrogen of the hydrogen silicones and the choice of catalyst are the key points on the synthesis of polyether silicones. The amount of hydrogen should be low and the catalyst must be economical and efficient and its introduction should be small and times, other more the holding time is not too long. The next one is that, in the process of hydrolysis of silane coupling agent, we need some acid to adjust pH value, or they will be broken down. The most important one but not the last is that the epoxy group can improve the products low-temperature supple and the persistence of the finishing fabric, furthermore it can reduce yellowing and has a good stability of the inorganic salt, however, it will be destroyed if the reaction temperature for epoxy is too high. What’s more, it is very economical and environmental that the process of emulsion is simple and with less emulsifier.
文摘Chemical softener (Cepreton UN) is used to soften the cellulosic fiber (cotton) in the textile industries to make clothes better to touch. Therefore, this study investigated the effects of Cepreton UN on both physical (length, aspect ratio, contact angle, and moisture regain) and mechanical (load at break, elongation at break, tensile stress, young’s modulus, and tenacity) properties of the lignocellulosic canola (HYREAR 3) fibers extracted from narrow, medium, and wide stems. ANOVA showed that fiber diameter had strong effects on elongation at break, load at break, tensile stress, young’s modulus, and aspect ratio for all fibers. Corrgram values showed that tensile stress, young’s modulus, and aspect ratio were negatively correlated to fiber diameter whereas load at break and tenacity were mostly positively correlated to fiber diameter. The fibers were treated with 2% and 10% Cepreton UN and compared with control fibers. In most cases, the fiber diameter was decreased in both 2% and 10% treated medium stem fibers. The mean values of elongation at break, load at break, tenacity, and contact angle were decreased for 10% and increased for 2% and the mean values of tensile stress, young’s modulus, and aspect ratio were decreased for 2% and increased for 10% treated medium stem fibers. Moisture regain (%) mostly decreased for 2%, and increased for 10% treated fibers. Low pH (4.5) had an almost similar effect on fibers as 2% Cepreton UN. Overall, 2% Cepreton UN treatment is found to be better than 10% to make canola fibers less stiff and low pH was found to be an alternative softener treatment strategy.
基金supported by the Lendület/Momentum Programme of the Hungarian Academy of Sciencesthe National Research, Development, and Innovation Office, Hungary (Grant Nos. LP2024/21 and K146791)+2 种基金Bayers fellowship program MEDHA and Department of Botany, University of Calicutthe financial assistance provided in the form of Junior Research Fellowship from the University Grants Commission (UGC), Indiathe financial assistance provided by the Council for Scientific and Industrial Research(CSIR), India
文摘Ascorbate(Asc),commonly known as vitamin C,is a vital molecule for plant growth,development,and stress resilience.It is also known to play a crucial role in various physiological processes,including photosynthesis,cell division,and differentiation.This article thoroughly explores the processes governing the metabolism of Asc in plants and its roles in physiological functions.It lays down a robust theoretical groundwork for delving into Asc production,transportation,functions,and its potential applications in stress alleviation and horticulture.Furthermore,recent studies indicate that Asc plays a role in regulating fruit development and affecting postharvest storage characteristics,thereby influencing fruit ripening and resilience to stress.Hence,there is a growing importance in studying the synthesis and utilization of Asc in plants.Although the critical role of Asc in controlling plant redox signals has been extensively studied,the precise mechanisms by which it manages cellular redox homeostasis to maintain the equilibrium between reactive oxygen scavenging and cell redox signaling remain elusive.This gap in knowledge presents fresh opportunities to explore how the production of Asc in plants is regulated and how plants react to environmental stressors.Furthermore,this article delves into the potential for a comprehensive investigation into the essential function of Asc in fruits,the development of Asc-rich fruits,and the enhancement of postharvest storage properties.
基金Project(52378425)supported by the National Natural Science Foundation of ChinaProject(1053320221044)supported by the Fundamental Research Funds for the Central Universities,China。
文摘Irradiating hard rocks by a high-power laser can reduce localized hardness in the rocks;however,continuous lasers produce a large amount of melt that inhibits further heat absorption.Pulsed lasers allow rocks to absorb and dissipate energy and avoid melt formation.In this study,200 W nanosecond pulsed laser was used to irradiate granite.The effects of laser parameters on the thermal cracking morphology,temperature field,warming pattern,and Leeb hardness of the granite surface were analyzed.The optimal laser parameters for softening granite were determined by performing objective optimization in MATLAB using granite's melting point as the reference.Nanoindentation techniques were employed to assess the softening characteristics of the granite surface along the longitudinal direction.The results showed that three main forms of thermal damage occurred on the granite surface:oxidative decomposition,spalling,and melting.The damage state was affected by the average laser power,with the pulse width and repetition frequency affecting surface damage differently.Appropriate laser parameters effectively controlled the melt damage on the granite surface,and irradiation with nanosecond pulsed lasers effectively reduced surface hardness.However,excessive power can generate large amounts of hard melts and weaken the softening effect.
基金support from the National Natural Science Foundation of China(Grant Nos.52104207 and 52374214)the Shandong Provincial Youth Innovation Team Development Program for Higher Education Institutions(Grant No.2023KJ305).
文摘In the field of rock engineering,the influence of water is a dynamic process that exhibits varying effects over time and across different locations.To further understand how water influences the mechanical properties and acoustic emission(AE)behavior of rocks,this study conducted uniaxial compression experiments on sandstones with varying degrees of wetting under both natural conditions and water-chemical environments.In addition,the study combined AE equipment with digital image correlation(DIC)to monitor the entire failure process.Using the sliding window algorithm,the variation in the variance of AE characteristic parameters during the process of sandstone loading to failure is analyzed from the perspective of critical slowing down.This analysis enables the effective identification of the early warning signal before failure.The experimental findings suggest that an increase in wetting height results in a gradual decrease in peak stress,accompanied by a concomitant increase in the percentage of shear cracks.The characteristic parameters,including energy,amplitude,and ringing count,all exhibit critical slowing phenomena.The waveform of AE characteristic parameters of the same sample is similar,and the mutation time of the precursor signal is roughly the same.All signals appear in the irreversible plastic deformation stage of microcrack initiation.The integration of critical slowing down theory and the b-value early warning method facilitates a more comprehensive evaluation of the stability of rock mass,thereby significantly enhancing the efficiency and safety of disaster prevention measures.
基金supported by the Natural Science Foundation of Heilongjiang Province(No.JQ2022E004).
文摘In this paper,the work hardening and softening behavior of AZ31 magnesium alloy sheets by hard plate accumulative roll bonding(HP-ARB)process in a specific temperature range was studied for the first time,and the cyclic stress relaxation test,EBSD,TEM and other characterization methods were used.When the rolling temperature is 350℃,the grain size of magnesium sheets is refined to 4.32(±0.36)μm on average,and it shows an excellent combination of strength and plasticity.The tensile strength reaches 307(±8.52)MPa and the elongation is 12.73(±0.84)%.At this time,the curve of work hardening rate decreases smoothly and the degree of hardening is the lowest,and the amplitude of stress drop △σ_(p) in work softening test is the smallest with the increase of cycle times,which shows that the well coordination between work hardening and softening behavior has been achieved.Research has found that the combined effect of grain boundary strengthening and fine grain strengthening enhances the yield and tensile strength of magnesium sheets after three passes HP-ARB process at 350℃.This is attributed to the high degree of dislocation slip opening in the pyramidal surfaceand<c+a>,which not only coordinates the c-axis strain of the entire grain,but also promotes the slip transfer of dislocations in the fine-grained region,significantly improving the elongation of the sheets.This study provides a new idea for the forming and manufacturing of high performance magnesium alloy sheets.
基金supported by the“National Natural Science Foundation of China”(Grants.52271109 and 52001223)Support from the“National Key Research and Development Program for Young Scientists”(Grant.2021YFB3703300)+1 种基金the Major Special Plan for Science and Technology in Shanxi Province(202201050201012)the Special Fund Project for Guiding Local Science and Technology Development by the Central Government(Grant.YDZJSX2021B019)。
文摘To obtain the Ti_(p)with different aspect ratios,the Ti_(p)/Mg-5Zn-0.3Ca composite prepared by semi-solid stir casting was subjected to extrusion at 220℃,180℃,and 140℃,respectively.Then,the effect of the Ti_(p)’s aspect ratio on the microstructure,mechanical properties,work hardening and softening behaviors of Ti_(p)/Mg-5Zn-0.3Ca composites was investigated.The results indicated that the Ti_(p)could be elongated obviously after low-temperature extrusion,and the aspect ratio of which would reach to 13.7:1 as the extrusion temperature deceased to 140℃.Then the“Ti/Mg”layer-like structure was formed in the Ti_(p)/Mg-5Zn-0.3Ca composite.Accompanied with the elongation of Ti_(p),the dynamic recrystallized grains and dynamic precipitates were both refined significantly,however,the dynamic recrystallization rate changed a little.The elongated Ti_(p)endowed the Ti_(p)/Mg-5Zn-0.3Ca composites with better matching of strength and toughness without the sacrifice of elongation and bending strain.Both the work hardening rate and softening rate of Ti_(p)/Mg-5Zn-0.3Ca composites increased with the increasing aspect ratio of Ti_(p).The formation of“Ti/Mg”layer-like structure contributed to the redistribution of strain from large aggregations to a network-like distribution,which effectively suppresses the initiation and propagation of micro-cracks,thus enhancing the plasticity of the Ti_(p)/Mg-5Zn-0.3Ca composites.
文摘Large interfacial strains in particles are crucial for promoting bonding in cold spraying(CS),initiated either by adiabatic shear instability(ASI)due to softening prevailing over strain hardening or by hydrostatic plasticity,which is claimed to promote bonding even without ASI.A thorough microstructural analysis is vital to fully understand the bonding mechanisms at play during microparticle impacts and throughout the CS process.In this study,the HEA CoCrFeMnNi,known for its relatively high strain hardening and resistance to softening,was selected to investigate the microstructure characteristics and bonding mech-anisms in CS.This study used characterization techniques covering a range of length scales,including electron channeling contrast imaging(ECCI),electron backscatter diffraction(EBSD),and high-resolution transmission microscopy(HR-TEM),to explore the microstructure characteristics of bonding and overall structure development of CoCrFeMnNi microparticles after impact in CS.HR-TEM lamellae were prepared using focused ion beam milling.Additionally,the effects of deformation field variables on microstructure development were determined through finite element modeling(FEM)of microparticle impacts.The ECCI,EBSD,and HR-TEM analyses revealed an interplay between dislocation-driven processes and twinning,leading to the development of four distinct deformation microstructures.Significant grain refinement occurs at the interface through continuous dynamic recrystallization(CDRX)due to high strain and temperature rise from adiabatic deformation,signs of softening,and ASI.Near the interface,a necklace-like structure of refined grains forms around grain boundaries,along with elongated grains,resulting from the coexistence of dynamic recovery and discontinuous dynamic recrystallization(DDRX)due to lower temperature rise and strain.Towards the particle or substrate interior,concurrent twinning and dislocation-mediated mechanisms refine the structure,forming straight,curved,and intersected twins.At the top of the particles,only deformed grains with a low dislocation density are observed.Our results showed that DRX induces microstructure softening in highly strained interface areas,facilitating atomic bonding in CoCrFeMnNi.HR-TEM investigation confirms the formation of atomic bonds between particles and substrate,with a gradual change in crystal lattice orientation from the particle to the substrate and the occurrence of some misfit dislocations and vacancies at the interface.Finally,the findings of this research suggest that softening and ASI,even in materials resistant to softening,are required to establish bonding in CS.
基金the financial support received from the UK Engineering and Physical Sciences Research Council(EPSRC)through project grants EP/W010089/1 and EP/T005254/1.
文摘With the generation of both localised thermal and vibration in incremental sheet forming(ISF)by novel tool designs,rotational vibration assisted ISF(RV-ISF)can achieve significant force reduction and material softening.However,the combined thermal and vibration softening in RV-ISF is unclear.By evaluating the similarities and differences of friction stir ISF(FS-ISF)and RV-ISF,this study develops a novel approach to decouple and quantify the thermal and vibration softening effects in RV-ISF of AZ31B-H24,providing new insights into underlying thermal and vibration softening mechanism.Experimental results reveal that in RV-ISF of AZ31B-H24 the thermal softening due to frictional heating dominates with 45∼65%of softening,while the vibration effect only contributes up to 15%of softening,from the conventional ISF,depending on the tool designs and tool rotational speed.The double-offset tool(T2)produces greater vibration softening than the three-groove tool(T3)owing to the higher vibration amplitude of the T2 tool.An increase in tool rotational speed primarily enhances thermal softening with only marginal changes to the vibration effect.Microstructural analysis suggests that with average grain size of 0.94μm at the top layer,RV-ISF with T3 and 3000 rpm is more effective for microstructure refinement than that by FS-ISF,especially on the tool-sheet contact surface,which confirms the occurrence of surface shearing.This refinement is a result of the reduced recrystallisation degree,71.8%at the top bottom layer.Compared with FS-ISF,RV-ISF can lead to not only higher geometrically necessary dislocation density,but also higher fraction of low-angle grain boundaries,indicating that softening mechanism due to localised vibration effect is resulted from the enhanced rearrangement and annihilation of dislocations.These findings contribute to new understanding of the thermal and vibration softening effects in RV-ISF of AZ31B-H24 and offer a theoretical foundation for the tool design and process optimisation.
基金supported by the National Natural Science Foundation of China(Nos.12172014,U224126412332001)。
文摘In order to obtain a lower frequency band gap,this paper proposes a novel locally resonant meta-beam incorporating a softening nonlinear factor.An improved camroller structure is designed in this meta-beam to achieve the softening nonlinear stiffness of the local oscillators.Firstly,based on Hamilton's principle and the Galerkin method,the control equations for the coupled system are established.The theoretical band gap boundary is then derived with the modal analysis method.The theoretical results reveal that the band gap of the meta-beam shifts towards lower frequencies due to the presence of a softening nonlinear factor,distinguishing it from both linear metamaterials and those with hardening nonlinear characteristics.Then,the vibration attenuation characteristics of a finite size meta-beam are investigated through numerical calculation,and are verified by the theoretical results.Furthermore,parameter studies indicate that the reasonable design of the local oscillator parameters based on lightweight principles helps to achieve further broadband and efficient vibration reduction in the low-frequency region.Finally,a prototype of the meta-beam is fabricated and assembled,and the formations of the low-frequency band gap and the amplitude-induced band gap phenomenon are verified through experiments.
文摘Rubbery waste at the end of the cycle often constitutes a threat for the environment because of their encumbrance and low biodeterioration.The purpose of the research presented is to develop the rubber fine powder as a pavement.It is interested primarily in the behavior of two types of bitumen 40/50 modified by the addition of two varieties of rubber fine powders of different grading,resulting from the crushing of the rubbery products intended for the clothes industry of soles of shoes.The objective of the experimentation is to study the influence of the added polymer on the physical properties of the ordinary road bitumen with the incorporation of the fine powder.The experimental approach is carried out using the two tests of characterization of the bitumen i.e.the softening point test and the penetration test which remain the most used to define and classify the road bitumen.It will be noted however,that the experimental investigation which is based on several tests according to the type and the content of fine powders,leads on a whole of interesting correlations.
文摘In clinical dermatology,approximately 15%of patients suffer from nail disorders.Different nail diseases may present with similar clinical manifestations.When clinical diagnosis based on symptoms,dermoscopy,and fungal tests is inconclusive,nail biopsy becomes the most critical diagnostic tool.Nail specimens are highly rigid,brittle,and adhere poorly to slide glass,making sectioning challenging and posing significant difficulties for pathology technicians.Limited literature exists on nail histology processing techniques.This paper reviews and consolidates the available literature on nail paraffin sectioning techniques,aiming to provide insights and methods for pathology technicians.
基金financially supported by the National Natural Science Foundation of China (grants 52301146 and 52275308)the Fundamental Research Funds for the Central Universities (grant 2023JG007)China Postdoctoral Science Foundation (grant 8206300226)。
文摘While the deformation behavior of rare-earth magnesium alloys at high temperatures has been extensively studied,the deformation mechanisms under moderate-to-low temperatures and high strain rates remain insufficiently understood.To address this gap,hot compression tests were conducted on a Mg-11Gd-3Y-0.5Zr(wt.%)alloy over a temperature range of 150℃–450℃under strain rates of 10^(-3) s^(-1)(low strain rate(LSR))and 10 s^(-1)(high strain rate(HSR))to explore the strain rate-temperature coupling effects during hot deformation.The results revealed an anomalous increase in peak stress at 150℃–250℃as the strain rate decreased,attributed to the combined effects of nano-precipitates,dislocation cell structures,and serrated flow induced by dynamic strain aging.At higher temperatures,strain rate influences softening pathways:under HSR at 450℃,the effect of twinning shifts from strengthening to facilitating dynamic recrystallization(DRX),resulting in substantial grain refinement(-4 μm,81%area fraction at a strain of 0.6).In contrast,at LSR,softening is dominated by dynamic recovery at 350℃,with limited DRX(-4 μm grains,10%area fraction at a strain of 0.6)occurs at 400℃.These findings clarify the dual role of twinning and its interaction with rate-temperature conditions,providing valuable insights into optimizing the hot processing of rare-earth magnesium alloys.
基金supported by the National Key Research and Development Program(No.2022YFB4602502)the Guangdong Basic and Applied Basic Research Foundation(No.2021A1515011991)+2 种基金the Key Research and Development Program Fund of Hubei Province(No.2022BAA057)the state Key Lab-oratory of Solidification Processing in NPU(No.SKLSP202325)the China Scholarship Council Visiting PhD Program(No.202306410136).
文摘Multimodal ultrasonic vibration(UV)assisted micro-forming has been widely investigated for its advantages of further reducing forming loads and improving forming quality.However,the influence mechanism of different UV modes on microstructure evolution and mechanical properties was still unclear.Mul-timodal UV assisted micro-compression tests on T2 copper with different grains and sample sizes were conducted in this study.The microstructure evolution for different UV modes was observed by EBSD.The results showed that the true stress reduction caused by UV was increased sequentially with tool ultrasonic vibration(TV),mold ultrasonic vibration(MV)and compound ultrasonic vibration(CV).The region of grain deformation was shifted along the direction of UV,and the MV promoted the uniform distribution of deformation stress.The grain refinement,fiber streamline density,grain deformation and rotation degree were further enhanced under CV,due to the synergistic effect of TV and MV.Additionally,a coupled theoretical model considering both acoustic softening effect and size effect was proposed for describing the mechanical properties.And a physical model of dislocation motion in different UV modes was developed for describing the microstructure evolution.The maximum error between the theoretical and experimental results was only 2.39%.This study provides a theoretical basis for the optimization of UV assisted micro-forming process.
基金Project(52074299)supported by the National Natural Science Foundation of ChinaProjects(2023JCCXSB02,BBJ2024083)supported by the Fundamental Research Funds for the Central Universities,China。
文摘This study proposed a new and more flexible S-shaped rock damage evolution model from a phenomenological perspective based on an improved Logistic function to describe the characteristics of the rock strain softening and damage process.Simultaneously,it established a constitutive model capable of describing the entire process of rock pre-peak compaction and post-peak strain softening deformation,considering the nonlinear effects of the initial compaction stage of rocks,combined with damage mechanics theory and effective medium theory.In addition,this research verified the rationality of the constructed damage constitutive model using results from uniaxial and conventional triaxial compression tests on Miluo granite,yellow sandstone,mudstone,and glutenite.The results indicate that based on the improved Logistic function,the theoretical damage model accurately describes the entire evolution of damage characteristics during rock compression deformation,from maintenance through gradual onset,accelerated development to deceleration and termination,in a simple and unified expression.At the same time,the constructed constitutive model can accurately simulate the stress-strain process of different rock types under uniaxial and conventional triaxial compression,and the theoretical model curve closely aligns with experimental data.Compared to existing constitutive models,the proposed model has significant advantages.The damage model parameters a,r and β have clear physical meanings and interact competitively,where the three parameters collectively determine the shape of the theoretical stress−strain curve.
文摘When tunnelling through low-permeability saturated ground,the pore pressure decreases in the vicinity of the cavity.In certain instances of deep tunnels crossing weak rocks,the pore pressure may even become negative.All existing analytical solutions for the undrained ground response curve(GRC)in the literature assume that the ground fully retains its saturation,in which case the development of negative pore pressures has a stabilising effect e it results in increased effective stresses,and thus shearing resistance,which in turn leads to reduced deformations and plastification.In practice,however,negative pore pressures can induce partial or complete ground desaturation,which may even invalidate the premise of undrained conditions and lead to considerably increased deformations and plastification.In such cases,existing solutions are unsafe for design.The present paper aims to address this shortcoming,by presenting a novel analytical solution for the undrained GRC which incorporates the effect of the excavation-induced desaturation.The solution is derived under the assumption that the ground desaturates completely and immediately under negative pore pressures,which provides the upper bound of deformations and plastification for cases of partial desaturation.The rock is considered to be a linear elastic,brittle-plastic material,obeying a non-associated Mohr-Coulomb(MC)yield criterion.Nevertheless,the solution is also applicable to perfectly plastic rocks via a simple modification of the input parameters.Although the solution is in general semi-analytical,simple closed-form expressions are obtained in the special case of non-dilatant rocks.These expressions are also applicable to rocks exhibiting limited dilatancy,which is usually the case.An application example,based on the planned deep geological repository for radioactive waste in Switzerland,demonstrates the significant practical value and usefulness of the novel solution and underscores its necessity in cases where existing solutions that disregard desaturation are rendered thoroughly unsafe for design.
基金funded by the Major Science and Technology Program of Luoyang,China(Grant No.2101005A)Provincial and Ministerial Co-construction of Collaborative Innovation Center for Non-ferrous Metal New Materials and Advanced Processing Technology.
文摘The hot deformation behavior of 2707 hyper duplex stainless steel(HDSS)was investigated through a hot compression test at 950℃ to 1,250℃ at strain rates of 0.01 s^(-1) to 10 s^(-1).Observations from the flow stress curves reveal a balance between work hardening and dynamic recovery at the beginning of the deformation and subsequently demonstrate various softening mechanisms with the increase of strain.At high strain rates,dynamic recovery is the prevailing mechanism,whereas,at medium and low strain rates,dynamic recrystallization becomes dominant.The constitutive equation was constructed,and the deformation activation energy was calculated to be 645.46 kJ·mol^(-1).The hot processing map was drawn based on the dynamic material model at a strain of 0.8.The results indicate that the hot workability of 2707 HDSS decreases due to its high alloying content.The microstructure evolution of 2707 HDSS at 1,050℃ was identified by means of electron backscatter diffraction and transmission electron microscopy.The results demonstrate that the ferrite completes dynamic recrystallization at the strain rate of 1 s^(-1).The softening process of austenite is influenced by ferrite and mainly experiences dynamic recovery.The austenite located at the α/γ phase boundaries tends to undergo dynamic recrystallization.
基金supported by the Science&Technology Development Fund of Tianjin Education Commission for Higher Education(No.2023KJ250).
文摘In the framework of elastoplastic theory,by introducing dissipative plastic energy(instead of cumulative plastic strain)and dissipative plastic energy rate(instead of cumulative plastic strain rate)into the ratchetting parameter evolution equation and isotropic evolution rules respectively,a cyclic elastoplastic constitutive model based on dissipative plastic energy is established.This model,termed the WDP model,describes the physical meaning and evolution rule of the unclosed stress–strain hysteresis loop using an energy method.A comparison of numerical implementation results with experimental data demonstrates the capability of the WDP model to predict the cyclic deformation of EA4T steel,effectively capturing the cyclic softening characteristics and ratchetting behaviors of axle steel EA4T.
基金funded by the Natural Science Foundation of China(Grant No.U22A20600)。
文摘Existing creep constitutive models rarely incorporate studies on the coupling mechanism between creep damage and rock strain softening/hardening.This study analyzed the strain softening and hardening behaviors of argillaceous sandstone and sandy mudstone during load-induced failure based on the plastic increment theory.These behaviors were then coupled with an improved Burgers creep model to establish a coupled creep-damage and plastic softening/hardening model.Finally,the validity and engineering applicability of the proposed model were verified through FLAC~(3D)numerical simulations.The numerical simulation results of standard cylindrical specimens show that the established coupling model can effectively reflect the unloading creep deformation law and failure characteristics of argillaceous sandstone and sandy mudstone.Taking the diversion tunnel of a hydropower station in Northwest China as an example for engineering application,the coupled creep-damage and plastic softening/hardening model is introduced into FLAC~(3D)to carry out numerical simulation calculation of the tunnel under excavation and unsupported creep conditions.The results show that the uncoordinated deformation of the upper and lower walls of the surrounding rock of the tunnel is more prominent.When the buried depth of the tunnel increases to 80 m,the monitoring point C in the sandy mudstone area of the upper wall shows nonlinear accelerated deformation under unsupported creep conditions,and the maximum displacement in the horizontal direction reaches 44.5 mm,and the maximum displacement in the vertical direction reaches 53.5 mm.The coupled creep-damage and plastic softening/hardening model established in the research results can well describe the whole process of uncoordinated deformation and failure in the unloading creep process of soft-hard interbedded rock mass.
基金supported by the National Natural Science Foundation of China(52174361,52074114)Science and Technology Innovation Program of Hunan Province(2023RC3106)+2 种基金Open Fund of the China Spallation Neutron Source Songshan Lake Science City(KFKT2023B13)Graduate Training and Innovation Practice Base of Hunan Province,China Scholarship Council(202106130051)Postgraduate Scientific Research Innovation Project of Hunan Province(QL20220100,QL20230094).
文摘Multi-pass hot processing methods are commonly used in magnesium(Mg)alloys to overcome the poor workability due to limited slip systems,which generally involve complicated post-deformation softening and hardening behaviors.In this work,to reveal post-deformation softening and hardening mechanisms of a Mg-2Y-1Zn alloy,double-stage hot compression tests and microstructural observations were conducted.The results showed that the softening fraction of Mg-2Y-1Zn alloy showed a non-linear dependence on deformation conditions and could be general coupled by Z parameter.Due to the formation and cross-overlapping of twins and kinks,only static recovery(SRV)occurred during holding process at 300℃/0.001 s^(-1) which led to the least static softening:5.52% after 10 s of holding.For samples at 400℃/0.001s^(-1),the enhanced post-deformation softening,which is 11.93% after 10 s of holding,was attributed to static recrystallization(SRX)followed continuous dynamic recrystallization(CDRX)happened during first deformation stage as well as SRV influenced by the LPSO phases.Under deformation condition of 400℃/0.1 s^(-1),the coupled meta-dynamic recrystallization(MDRX)and SRX resulted in serious stress relaxation,which is 42.83% after 10 s of holding,and caused hardening phenomenon at reloading stage.The 18R-LPSO and 14H-LPSO phases synchronously worked on deformation behaviors and limited the growth of recrystallized grains.Further,a simplified static softening kinetics model was established based on Johnson-Mehl-Avrami-Kolmogorov equation and employed to rationalize experimental data.
