Cementing carbonate reservoirs is generally a difficult task.The so-called thixotropic cement slurry has gained considerable attention in this regard as it can help tofix some notable problems.More precisely,it can ea...Cementing carbonate reservoirs is generally a difficult task.The so-called thixotropic cement slurry has gained considerable attention in this regard as it can help tofix some notable problems.More precisely,it can easilyfill the leakage layer;moreover,its gelling strength can grow rapidly when pumping stops,thereby increasing the resistance to gas channeling,effectively preventing this undesired phenomenon in many cases.High-temperature thixotropic cement slurry systems,however,are still in an early stage of development and additional research is needed to make them a viable option.In the present study,using a self-developed composite high-temperature thixotropic additive as a basis,it is shown that the compressive strength can be adjusted by tuning the proportion of silica sand,the high-temperature retarder,fluid loss additive and dispersant(compatible with the thixotropic additive).According to the tests,the developed high-temperature thixotropic cement slurry system has a 14 d compressive strength of 29.73 MPa at 150°C,and a thickening time of 330 min when the dosage of retarder is 2%.At the same time,the rheological property,water loss,permeability,water separation rate,and settlement stability of the cement slurry system meet the requirements of cementing construction.展开更多
The kinetics of liquid-phase hydrogenation of benzene in misch metai nickel-five (MINi5) and benzene slurry system was studied by investigating the influences of the reaction temperature, pressure, alloy concentration...The kinetics of liquid-phase hydrogenation of benzene in misch metai nickel-five (MINi5) and benzene slurry system was studied by investigating the influences of the reaction temperature, pressure, alloy concentration and stirring speed on the mass transfer-reaction processes inside the slurry. The results show that the whole process is controlled by the reaction at the surface of the catalyst. The mass transfer resistance at gas-liquid interface and that from the bulk liquid phase to the surface of the catalyst particles are negligible. The apparent reaction rate is zero order for benzene concentration and first order for hydrogen concentration in the liquid phase. The kinetic modei obtained fits the experimental data very well. The apparent activation energy of the hydrogen absorption reaction of MINi5-C6H6 slurry system is 42.16kJ·mol-1.展开更多
The bubble formation dynamics and size manipulation in the slurry of polystyrene microspheres in the microfluidic T-junction were visually investigated by a high-speed camera.Based on the evolution of the bubble neck ...The bubble formation dynamics and size manipulation in the slurry of polystyrene microspheres in the microfluidic T-junction were visually investigated by a high-speed camera.Based on the evolution of the bubble neck with time,the formation process of bubbles is divided into three stages:filling,squeezing and pinch-off.The particle concentration has an obvious effect on the squeezing stage,while less impact on the filling and pinch-off stages.In the squeezing stage,the evolution of the dimensionless minimum neck width of bubbles with time could be described by a power-law relationship.The increase of the particle concentration or continuous phase flow rate could lead to the increase of body flow of the continuous phase and the enhancement of the squeezing force acted on the bubble neck,correspondingly,the power-law index a in the squeezing stage enlarges.Moreover,the bubble size increases with the increase of the gas phase flow rate and the decrease of the particle concentration and continuous phase flow rate.However,the effect of the particle concentration on the bubble size weakens with the increase of the continuous phase flow rate.In addition,a new prediction correlation of the bubble size for the slurry system in a T-shape microchannel was proposed with good prediction accuracy.展开更多
The casing deformation prevention technology based on the optimization of cement slurry is proposed to reduce the casing deformation of shale oil and gas wells during hydraulic fracturing. In this paper, the fracture ...The casing deformation prevention technology based on the optimization of cement slurry is proposed to reduce the casing deformation of shale oil and gas wells during hydraulic fracturing. In this paper, the fracture mechanism of hollow particles in cement sheath was firstly analyzed by discrete element method, and the effect of hollow particles in cement on casing deformation was investigated by laboratory experiment method. Finally, field test was carried out to verify the improvement effect of the casing deformation based on cement slurry modification. The results show that the formation displacement can be absorbed effectively by hollow particles inside the cement transferring the excessive deformation away from casing. The particles in the uncemented state provide deformation space during formation slipping. The casing with diameter of 139.7 mm could be passed through by bridge plug with the diameter of 99 mm when the mass ratio of particle/cement reaches 1:4. According to the field test feedback, the method based on optimization of cement slurry can effectively reduce the risk of casing deformation, and the recommended range of hollow microbeads content in the cement slurry is between 15% and 25%.展开更多
With the development of cementing slurry technology,cementing self-healing has become one of the most effective technologies to prevent and treat oil and gas channeling and improve long-term sealing capacity of cement...With the development of cementing slurry technology,cementing self-healing has become one of the most effective technologies to prevent and treat oil and gas channeling and improve long-term sealing capacity of cement sheath.To solve the technical problem of annulus oil and gas channeling caused by the long-term sealing failure of cement sheath,this paper researches and develops a kind of viscosity-soluble type biomimetic self-healing cement slurry system from the perspective of chemical biomimetics,based on the technical idea of“prevention before blocking”.Then,the engineering performance of this biomimetic self-healing cement slurry system and the mechanical property of self-healing set cement are evaluated respectively.In addition,the mechanical recovery capacity and permeability reducing rate of the self-healing set cement conserved with methane are evaluated by creating fractures through splitting.Finally,the healing mechanisms of the self-healing cement are analyzed by means of SEM microscopic test and infrared spectrography.And the following research results are obtained.First,the set cement has excellent mechanical property.When the compressive strength decreases by 15%,the elastic modulus of set cement decreases by 41%,showing good toughness to play the role of“first prevention”.Second,when meeting hydrocarbon,the damaged set cement is excited to generate a kind of viscosity-soluble type gelatinous ester substance,which re-bonds the skeleton of the set cement.When the self-healing set cement is conserved with methane,its compressive strength recovery rate is up to 94.5%,bending strength recovery rate is 58.6%,gas log permeability drops by 99%,and liquid log permeability drops by 100%,so as to realize“blocking later”.In conclusion,the viscosity-soluble type biomimetic self-healing cement slurry system can effectively achieve cementing integrity and long-term sealing integrity through self-healing after the damage of cement sheath,which provides a strong technical support for preventing the production safety hazard of sustained casing pressure in oil and gas wells and is beneficial to solve the technical problem of annulus oil and gas channeling caused by long-term sealing failure of cement sheath.展开更多
Electrolytic Zn-MnO_(2)batteries arepromising candidates for safe and sustainable energystorage owing to their high voltage,environmentalbenignity,and cost-effectiveness.However,practicalapplications are hindered by t...Electrolytic Zn-MnO_(2)batteries arepromising candidates for safe and sustainable energystorage owing to their high voltage,environmentalbenignity,and cost-effectiveness.However,practicalapplications are hindered by the poor conductivity andthe irreversible dissolution of conventionalε-MnO_(2)deposits.Herein,we report a scalable semisolid slurryelectrode architecture that enables stable MnO_(2)deposition/dissolution using a three-dimensional percolatingnetwork of carbon nanotubes(CNTs)as both conductivematrix and deposition host.The slurry systempromotes the formation of highly conductiveγ-MnO_(2)owing to enhanced charge transfer kinetics,enablingoverall dissolution rather than the localized separationtypically seen in traditional electrodes.The Zn-MnO_(2)slurry cell exhibits a reversible areal capacity approaching 60 mAh cm^(-2).Moreover,theflowable nature of the slurry allows electrochemically inactive MnO_(2)formed during dissolution to be reconnected and reactivated by CNTs inthe rheological network,ensuring deep utilization and cycling stability.This work establishes a slurry electrode strategy to improve electrolyticMnO_(2)reactions and offers a viable pathway toward renewable aqueous batteries for grid-scale applications.展开更多
Pressurized bentonite slurry is applied on a tunnel face to form a filter cake to stabilize the tunnel face when the slurryshield excavates through the sandy soil. Failure of the tunnel face may be caused by a high pe...Pressurized bentonite slurry is applied on a tunnel face to form a filter cake to stabilize the tunnel face when the slurryshield excavates through the sandy soil. Failure of the tunnel face may be caused by a high permeable filter cake, which commonlyhas a long penetration distance of slurry in sands. A column system with a height of 680 mm and a diameter of 300 mm was de-veloped to model pressurized slurry infiltration in sands. Pressure transducers were installed to estimate the hydraulic conductivityof the filter cake during slurry infiltration. The electrical conductivity of the leachate of collected samples was measured. Resultsshow that the majority of fine particles in slurry are within the range 100-300 mm into the sand specimen. The time for forming animpermeable filter cake is about 300 s, which indicates the impermeable filter cake is hard to form during the excavation.展开更多
A novel vacuum ice slurry producing system with jet-pumps was proposed to deal with the problems of high energy consumption and ice blockage.In this novel system,one steam driven by a jet-pump was used to create vacuu...A novel vacuum ice slurry producing system with jet-pumps was proposed to deal with the problems of high energy consumption and ice blockage.In this novel system,one steam driven by a jet-pump was used to create vacuum in a hermetic vessel where water was sprayed through a nozzle to produce ice slurry,while the other steam was used to provide enough cold energy to make the left vapor in the hermetic vessel condense.Mathematical models of this novel system were established and theoretical simulation on the performance characteristics was also implemented based on the MATLAB program.Results show that the novel system is feasible and practicable,and the system performance is affected by many factors,such as the temperature of the generators,condensing temperature,evaporation temperature,and the cooling load of the refrigerator sub-system.The findings are helpful to improve the performance of ice slurry producing system.展开更多
Development of a technology that can reduce the odor of liquid swine manure during agitation and land application could prove beneficial to the swine industry. The purpose of this study was to evaluate a commercial oz...Development of a technology that can reduce the odor of liquid swine manure during agitation and land application could prove beneficial to the swine industry. The purpose of this study was to evaluate a commercial ozone treatment system for swine slurry under production scale conditions. The facility used for this study was a curtain sided finishing building housing 500 grow–finish market hogs located over a manure pit measuring 12.2 m wide × 25.9 m long × 2.4 m deep with a total pit capacity of 770,142 l, containing 577,607 l. The system evaluated exposes air to ultra-violet light creating O3. The O3 is then injected into slurry at a rate of 851.6 l/min. treating 51,097 l/h. In this study the entire pit contents were treated every 11.3 h. At 0, 24, 48, and 96 h two slurry samples were collected with a 3.05 m probe and six air sample bags were collected via a vacuum pump. No significant differences were detected in slurry samples between time periods. Mean slurry values were 13.6 ± 4.6% solids dry wt., 850 ± 70 mg/l settable solids, 54,200 ± 4384 mg/l total suspended solids, 61,050 ± 12,657 mg/l chemical oxygen demand, 0.86 ± 0.14%N, 0.49 ± 0.27%P, 0.45 ± 0.01%K and dissolved oxygen below detection limits. Ammonia concentrations decreased (P = 0.004) from 0 to 96 h. Odor panelists analyzed air samples for intensity at recognition (IR), offensiveness at recognition (OR), intensity at full strength (IFS) and offensiveness at full strength (OFS). Panelists found OR, IFS and OFS were reduced (P < 0.01) at 48 h and 96 h compared to 0 h and IR was reduced (P < 0.04) at 24 h and 48 h and not at 96 h but trended lower (P = 0.12) at 96 h. The system evaluated significantly improved air quality within the building suggesting that odor emanating from swine buildings and odor generated during land application of slurry should be reduced.展开更多
In the present study, the ice slurry refrigeration system with pre-cooling heat exchanger (ISSH) is studied experimentally to achieve the system performance, ice crystal formation time and the temperature of ice cryst...In the present study, the ice slurry refrigeration system with pre-cooling heat exchanger (ISSH) is studied experimentally to achieve the system performance, ice crystal formation time and the temperature of ice crystal formation. The operating parameters considered in this paper include the concentration of salt solution, suction pressure, discharge pressure and Energy Efficiency Ratio (EER). The result shows that the temperature of critical time of ice crystal formation decreases with the increasing concentration of salt solution and that the ice crystal formation time increases with the increasing concentration of salt solution. In the same concentration of salt solution, the ice crystal formation temperature of ISSH is lower than that of basic ice slurry refrigeration system (BISS), and the ice crystal formation time of ISSH is shorter than that of BISS. On the whole, the EER of ice slurry refrigeration system with pre-cooling heat exchanger is higher than that of basic ice slurry refrigeration system.展开更多
Utilizing phosphorus tailings as the raw material for foam concrete is a key approach to achieving sustainable and efficient resource utilization.During the preparation of phosphorus tailings-based foam concrete,slurr...Utilizing phosphorus tailings as the raw material for foam concrete is a key approach to achieving sustainable and efficient resource utilization.During the preparation of phosphorus tailings-based foam concrete,slurry performance is critical to the successful production.Phosphorus tailings,cement and microsilica were used to prepare foam concrete slurry in this study.A rheometer was employed as a test tool to measure the variation of linear viscoelastic zone(LVR),viscosity,and yield stress of the slurries with different cement contents.The results indicate that the phosphorus tailings-cement-microsilica slurry exhibits shear-thinning properties,which aligns well with the Herschel-Bulkley model,showing a high degree of correlation.As the cement content increases,the energy storage modulus of the slurry rises,and the LVR length shows a nonlinear trend.The LVR reaches its maximum length of 0.04%when the cement content is 6 mass%or 8 mass%.The increment of the cement content leads to a more intricate internal network structure,which hinders the reconstruction rate of the flocculated structure after high-shear deformation.展开更多
The multipath application of green resources needs to be realised under the carbon neutrality goal.Worldwide,biomass is a resource in urgent need of treatment.In this paper,corn stover biomass(YM)or biochar with diffe...The multipath application of green resources needs to be realised under the carbon neutrality goal.Worldwide,biomass is a resource in urgent need of treatment.In this paper,corn stover biomass(YM)or biochar with different particle sizes(YMF or YMX)was added during the preparation of coal-water slurry to investigate its effect on the performance of coal-water slurry and the micro-mechanism.The results showed that the fixed viscosity concentration of coal-water slurry(CYWS)with YM was only 47.42%,and the flowability was 49.9 mm,which made the slurry performance poor.The fixed viscosity concentration of coal-water slurry(CFWS)blended with YMF and coal-water slurry(CXWS)blended with YMX increased by 10.41%and 14.24%,respectively,compared with CYWS.Meanwhile,CXWS had the lowest thixotropy and yield stress,with a yield stress of only 16.13 Pa,which was 77.31 Pa lower than that of CYWS.This indicates that YMX treated by charring and milling is more favorable to be blended with coal to prepare coal-water slurry.This is due to the enhanced hydrophilicity and electronegativity of YMX.The enhanced hydrophilicity reduces the tendency to form three-dimensional networks in coal-water slurry,while the enhanced electronegativity improves the electrostatic repulsion between particles,which is beneficial to the dispersion of particles.In the subsequent EDLVO analyses,the same idea was proved.展开更多
To fundamentally alleviate the excavation chamber clogging during slurry tunnel boring machine(TBM)advancing in hard rock,large-diameter short screw conveyor was adopted to slurry TBM of Qingdao Jiaozhou Bay Second Un...To fundamentally alleviate the excavation chamber clogging during slurry tunnel boring machine(TBM)advancing in hard rock,large-diameter short screw conveyor was adopted to slurry TBM of Qingdao Jiaozhou Bay Second Undersea Tunnel.To evaluate the discharging performance of short screw conveyor in different cases,the full-scale transient slurry-rock two-phase model for a short screw conveyor actively discharging rocks was established using computational fluid dynamics-discrete element method(CFD-DEM)coupling approach.In the fluid domain of coupling model,the sliding mesh technology was utilized to describe the rotations of the atmospheric composite cutterhead and the short screw conveyor.In the particle domain of coupling model,the dynamic particle factories were established to produce rock particles with the rotation of the cutterhead.And the accuracy and reliability of the CFD-DEM simulation results were validated via the field test and model test.Furthermore,a comprehensive parameter analysis was conducted to examine the effects of TBM operating parameters,the geometric design of screw conveyor and the size of rocks on the discharging performance of short screw conveyor.Accordingly,a reasonable rotational speed of screw conveyor was suggested and applied to Jiaozhou Bay Second Undersea Tunnel project.The findings in this paper could provide valuable references for addressing the excavation chamber clogging during ultra-large-diameter slurry TBM tunneling in hard rock for similar future.展开更多
In this work,the influences of surface layer slurry at different temperatures(10℃,14℃,18℃,22℃)on wax patterns deformation,shrinkage,slurry coating characteristics,and the surface quality of the casting were invest...In this work,the influences of surface layer slurry at different temperatures(10℃,14℃,18℃,22℃)on wax patterns deformation,shrinkage,slurry coating characteristics,and the surface quality of the casting were investigated by using a single factor variable method.The surface morphologies of the shell molds produced by different temperatures of the surface(first)layer slurries were observed via electron microscopy.Furthermore,the microscopic composition of these shell molds was obtained by EDS,and the osmotic effect of the slurry on the wax patterns at different temperatures was also assessed by the PZ-200 Contact Angle detector.The forming reasons for the surface cracks and holes of thick and large ZTC4 titanium alloy by investment casting were analyzed.The experimental results show that the surface of the shell molds prepared by the surface layer slurry with a low temperature exhibits noticeable damage,which is mainly due to the poor coating performance and the serious expansion and contraction of wax pattern at low temperatures.The second layer shell material(SiO_(2),Al_(2)O_(3))immerses into the crack area of the surface layer,contacts and reacts with the molten titanium to form surface cracks and holes in the castings.With the increase of the temperature of surface layer slurry,the damage to the shell surface tends to weaken,and the composition of the shell molds'surface becomes more uniform with less impurities.The results show that the surface layer slurry at 22℃is evenly coated on the surface of the wax patterns with appropriate thickness,and there is no surface shell mold rupture caused by sliding slurry after sand leaching.The surface layer slurry temperature is consistent with the wax pattern temperature and the workshop temperature,so there is no damage of the surface layer shell caused by expansion and contraction.Therefore,the shell mold prepared by the surface layer slurry at this temperature has good integrity,isolating the contact between the low inert shell material and the titanium liquid effectively,and the ZTC4 titanium alloy cylinder casting prepared by this shell mold is smooth,without cracks and holes.展开更多
Investment casting shell moulds are widely applied to cast alloys, but how to efficiently form a hierarchical porous structure inside the wall is an innovation and challenge. In this research, porous shell moulds with...Investment casting shell moulds are widely applied to cast alloys, but how to efficiently form a hierarchical porous structure inside the wall is an innovation and challenge. In this research, porous shell moulds with three infill patterns(rectilinear, grid, and honeycomb) were prepared using bauxite slurry and slurry extrusionbased additive manufacturing technology, and the effects of infill patterns on the properties were evaluated. The hierarchical pores inside the wall are composed of the macropores formed by infills and the micropores among bauxite particles. Different infill patterns result in changes in distribution and shape of pores, thereby affecting the properties of the shell moulds. The honeycomb pattern has more comprehensive advantages compared to the other two infill patterns. The samples prepared with the honeycomb pattern exhibit the highest bending strength(11.62 MPa) and porosity(41.6%), as well as good heat-transfer ability, with an average shrinkage rate within 2.0%. This work provides an attractive feasibility for fabricating shell moulds with hierarchical porous walls.展开更多
Traditional pyrometallurgical and hydrometallurgical methods to extract bismuth from sulfide ores face problems such as high cost,low-concentration SO_(2)generation,and long process time.In this study,the cyclone tech...Traditional pyrometallurgical and hydrometallurgical methods to extract bismuth from sulfide ores face problems such as high cost,low-concentration SO_(2)generation,and long process time.In this study,the cyclone technology and slurry electrolysis method were combined.The bismuth sulfide ore was dissolved directly at the anode,while the high purity bismuth was deposited efficiently at the cathode under the advantages of the two methods.The short process and high-efficiency extraction of bismuth sulfide ore were realized,and the pollution of low-concentration SO_(2)was avoided.Then,the effects of several crucial experimental conditions(current density,reaction time,temperature,pH,liquid-solid ratio,and circulation flow rate)on the leaching efficiency and recovery efficiency of bismuth were investigated.The leaching and electrowinning mechanisms during the recovery process were also analyzed according to the research results of this paper to better understand the cyclone slurry electrolysis process.The experimental results showed that 95.19%bismuth was leached into the acid solution in the anode area under optimal conditions,and the recovery efficiency and purity of bismuth on the cathode reached 91.13%and 99.26%,respectively,which were better than those by the traditional hydrometallurgy recovery process.展开更多
This study investigates the leaching and purification processes for dunite slurry,a common mining waste material,and the carbonation processes for the mineralization of CO_(2) with Mg^(2+).Results indicate that HCl is...This study investigates the leaching and purification processes for dunite slurry,a common mining waste material,and the carbonation processes for the mineralization of CO_(2) with Mg^(2+).Results indicate that HCl is a promising leaching agent,and pH and temperature are major factors in controlling the efficiency of the leaching process,with leaching efficiencies of 82%achieved after 4 h using 2 M HCl solution at 75℃.The removal of other ions like Fe^(3+),Fe^(2+),and Al^(3+)through the purification of the leachate using ammonium hydroxide was also proven to be effective,completely removing iron and aluminum from the leachate from starting concentrations of 3.10 and 0.40 g/L,respectively.The carbonation of magnesium at room temperature was investigated with both purified leachate and pure MgCl_(2) aqueous solution.Nesquehonite crystals began to form after 1.5 h with a conversion of Mg^(2+)to nesquehonite of approximately 5%.The produced crystals possess a needle-like shape,which could be modified using the biopolymers pectin and xanthan.Pectin had a limited influence on the length of the crystals,reducing the needle length with increasing pectin concentration.Xanthan,on the other hand,shortened and widened the needle-like structure into a column shape as more xanthan was added.This study demonstrates the potential for this process to utilize mining wastes and sequester CO_(2),producing useful mineral products in the process.展开更多
Erosion in slurry pumps presents a persistent challenge in industrial applications.This study examines the erosion of the static components of a 150ZJ-C42 centrifugal slurry pump,currently in operation at a beneficiat...Erosion in slurry pumps presents a persistent challenge in industrial applications.This study examines the erosion of the static components of a 150ZJ-C42 centrifugal slurry pump,currently in operation at a beneficiation plant,under varying particle conditions.Utilizing high-precision three-dimensional reverse engineering,the pump’s flow passage geometry was reconstructed to facilitate detailed erosion analysis.Focusing on the front and rear baffles of the pump chamber,as well as the volute,erosion patterns were analyzed for different particle volume concentrations and sizes.The results reveal that the highest erosion damage consistently occurs near the volute tongue,with wear being most severe in regions adjacent to the partition plate near the rear cover.Erosion damage intensity in this area correlates positively with particle diameter.Notably,the average erosion rate in the volute surpasses that of the front and rear chamber liners,reaching a value as high as 6.03×10^(-7)kg·m^(-2)·s^(-1)at a particle concentration of 9%and diameter of 0.1 mm,adversely impacting pump stability.For the pump chamber baffles,increased erosion is observed at a particle diameter of 0.05 mm under constant volume concentration conditions,while higher particle concentrations exacerbate localized erosion.展开更多
The lanthanum-cerium-based slurry(LC-slurry)is extensively utilized in the chemical mechanical polishing(CMP)of TFT-LCD glass substrates,optical lenses,and other glass products.Sodium hexametaphosphate(SHMP),as a disp...The lanthanum-cerium-based slurry(LC-slurry)is extensively utilized in the chemical mechanical polishing(CMP)of TFT-LCD glass substrates,optical lenses,and other glass products.Sodium hexametaphosphate(SHMP),as a dispersant,is commonly employed to enhance the dispersion properties of LCslurry for improved polishing performance.However,the tendency of sedimentation to form a compacted sediment layer,which is challenging to redisperse,increases storage difficulty and polishing equipment failure risk,thereby limiting its utilization in CMP.In the present study,sodium carboxymethylcellulose(CMC-Na),a long-chain organic polymer,was employed to enhance the redispersibility of LC-slurry containing SHMP.A comprehensive investigation was conducted on the influence of CMC-Na dosage and slurry pH on dispersibility,redispersibility and polishing performance.Additionally,an analysis was carried out to elucidate the underlying mechanism behind the effect of CMC-Na.The study demonstrates that the LC-slurry,containing 250 ppm SHMP and 500 ppm CMC-Na,exhibits excellent dispersibility and redispersibility.Further polishing tests demonstrate that compared to the LC-slurry containing only SHMP,utilizing the slurry containing both SHMP and CMC-Na at various pH for polishing thin film transistor liquid crystal display(TFT-LCD)glass substrates results in a reduction of both material removal rate(MRR)and surface roughness(Sa).Specifically,when adjusting the slurry to a pH range of 5-6,the MRR can reach up to 330 nm/min,which closely approximates the MRR achieved by LC-slurry containing only 250 ppm SHMP at corresponding pH values.Meanwhile,after polishing,the surface roughness of the glass substrate measures approximately 0.47 nm.展开更多
Bauxite tailing(BT)slurry has been generated and accumulated in large quantities,posing a threat to the green and sustainable development of the alumina industry.The regression equation between the actual water conten...Bauxite tailing(BT)slurry has been generated and accumulated in large quantities,posing a threat to the green and sustainable development of the alumina industry.The regression equation between the actual water content and mud water separation rate was established to achieve efficient resource utilization,and the feasibility of foam lightweight soil(FLS)prepared from BT was investigated.The effects of industrial waste residues(fly ash and slag powder)on the properties of FLS were studied.Meanwhile,the micro-mechanisms were revealed by XRD,SEM-EDS,and TG-DSC.The results revealed that fly ash reduced the workability and compressive strength of FLS.Slag powder can significantly enhance the compressive strength of FLS,which increased by 18.60%-23.26%,17.07%-58.54% and 12.12%-52.12%,respectively.Besides,slag powder can improve the long-term water stability performance and enhance carbonation resistance.XRD and thermal analyses showed that adding fly ash decreased the hydration degree of FLS,leading to a decrease in the hydration products.Slag powder improved the pore structure and compacted the skeleton structure of FLS.This study would provide an effective way to realize the resource utilization of BT,fly ash,and slag powder,with certain socio-economic and environmental benefits.展开更多
基金funded by the National Natural Science Foundation of China(51974355).
文摘Cementing carbonate reservoirs is generally a difficult task.The so-called thixotropic cement slurry has gained considerable attention in this regard as it can help tofix some notable problems.More precisely,it can easilyfill the leakage layer;moreover,its gelling strength can grow rapidly when pumping stops,thereby increasing the resistance to gas channeling,effectively preventing this undesired phenomenon in many cases.High-temperature thixotropic cement slurry systems,however,are still in an early stage of development and additional research is needed to make them a viable option.In the present study,using a self-developed composite high-temperature thixotropic additive as a basis,it is shown that the compressive strength can be adjusted by tuning the proportion of silica sand,the high-temperature retarder,fluid loss additive and dispersant(compatible with the thixotropic additive).According to the tests,the developed high-temperature thixotropic cement slurry system has a 14 d compressive strength of 29.73 MPa at 150°C,and a thickening time of 330 min when the dosage of retarder is 2%.At the same time,the rheological property,water loss,permeability,water separation rate,and settlement stability of the cement slurry system meet the requirements of cementing construction.
基金State Key Project of Basic Research of China(TG2000026406)National Natural Science Foundation of China(No.50071053)
文摘The kinetics of liquid-phase hydrogenation of benzene in misch metai nickel-five (MINi5) and benzene slurry system was studied by investigating the influences of the reaction temperature, pressure, alloy concentration and stirring speed on the mass transfer-reaction processes inside the slurry. The results show that the whole process is controlled by the reaction at the surface of the catalyst. The mass transfer resistance at gas-liquid interface and that from the bulk liquid phase to the surface of the catalyst particles are negligible. The apparent reaction rate is zero order for benzene concentration and first order for hydrogen concentration in the liquid phase. The kinetic modei obtained fits the experimental data very well. The apparent activation energy of the hydrogen absorption reaction of MINi5-C6H6 slurry system is 42.16kJ·mol-1.
基金supported by the National Natural Science Foundation of China(21978197 and 21776200)。
文摘The bubble formation dynamics and size manipulation in the slurry of polystyrene microspheres in the microfluidic T-junction were visually investigated by a high-speed camera.Based on the evolution of the bubble neck with time,the formation process of bubbles is divided into three stages:filling,squeezing and pinch-off.The particle concentration has an obvious effect on the squeezing stage,while less impact on the filling and pinch-off stages.In the squeezing stage,the evolution of the dimensionless minimum neck width of bubbles with time could be described by a power-law relationship.The increase of the particle concentration or continuous phase flow rate could lead to the increase of body flow of the continuous phase and the enhancement of the squeezing force acted on the bubble neck,correspondingly,the power-law index a in the squeezing stage enlarges.Moreover,the bubble size increases with the increase of the gas phase flow rate and the decrease of the particle concentration and continuous phase flow rate.However,the effect of the particle concentration on the bubble size weakens with the increase of the continuous phase flow rate.In addition,a new prediction correlation of the bubble size for the slurry system in a T-shape microchannel was proposed with good prediction accuracy.
基金the supports of project funded by China Postdoctoral Science Foundation(2023M743886)Project of Shale Gas Evaluation and Exploitation Key Laboratory of Sichuan Province(YSK2023004)youth project funded by Shaanxi Province Natural Science Basic Research Program(2024JC-YBQN-0522)。
文摘The casing deformation prevention technology based on the optimization of cement slurry is proposed to reduce the casing deformation of shale oil and gas wells during hydraulic fracturing. In this paper, the fracture mechanism of hollow particles in cement sheath was firstly analyzed by discrete element method, and the effect of hollow particles in cement on casing deformation was investigated by laboratory experiment method. Finally, field test was carried out to verify the improvement effect of the casing deformation based on cement slurry modification. The results show that the formation displacement can be absorbed effectively by hollow particles inside the cement transferring the excessive deformation away from casing. The particles in the uncemented state provide deformation space during formation slipping. The casing with diameter of 139.7 mm could be passed through by bridge plug with the diameter of 99 mm when the mass ratio of particle/cement reaches 1:4. According to the field test feedback, the method based on optimization of cement slurry can effectively reduce the risk of casing deformation, and the recommended range of hollow microbeads content in the cement slurry is between 15% and 25%.
基金supported by Scientific Research and Technology Development Project of PetroChina Southwest Oil&Gasfield Company“Evaluation method of self-healing slurry”(No.20220302-02).
文摘With the development of cementing slurry technology,cementing self-healing has become one of the most effective technologies to prevent and treat oil and gas channeling and improve long-term sealing capacity of cement sheath.To solve the technical problem of annulus oil and gas channeling caused by the long-term sealing failure of cement sheath,this paper researches and develops a kind of viscosity-soluble type biomimetic self-healing cement slurry system from the perspective of chemical biomimetics,based on the technical idea of“prevention before blocking”.Then,the engineering performance of this biomimetic self-healing cement slurry system and the mechanical property of self-healing set cement are evaluated respectively.In addition,the mechanical recovery capacity and permeability reducing rate of the self-healing set cement conserved with methane are evaluated by creating fractures through splitting.Finally,the healing mechanisms of the self-healing cement are analyzed by means of SEM microscopic test and infrared spectrography.And the following research results are obtained.First,the set cement has excellent mechanical property.When the compressive strength decreases by 15%,the elastic modulus of set cement decreases by 41%,showing good toughness to play the role of“first prevention”.Second,when meeting hydrocarbon,the damaged set cement is excited to generate a kind of viscosity-soluble type gelatinous ester substance,which re-bonds the skeleton of the set cement.When the self-healing set cement is conserved with methane,its compressive strength recovery rate is up to 94.5%,bending strength recovery rate is 58.6%,gas log permeability drops by 99%,and liquid log permeability drops by 100%,so as to realize“blocking later”.In conclusion,the viscosity-soluble type biomimetic self-healing cement slurry system can effectively achieve cementing integrity and long-term sealing integrity through self-healing after the damage of cement sheath,which provides a strong technical support for preventing the production safety hazard of sustained casing pressure in oil and gas wells and is beneficial to solve the technical problem of annulus oil and gas channeling caused by long-term sealing failure of cement sheath.
基金supported by the National Natural Science Foundation of China(No.22109181,U24A2060,22279023,and 22309031)the National Key R&D Program of China(2024YFE0101100)+6 种基金the Hunan Provincial Science and Technology Plan Projects of China(No.2017TP1001)the Hunan Provincial Natural Science Foundation of China(No.2025JJ40011)the Fundamental Research Funds for the Central Universities(20720250005)the Science and Technology Commission of Shanghai Municipality(25DZ3002901,2024ZDSYS02,25PY2600100)the Shanghai Pilot Program for Basic Research-Fudan University 21TQ1400100(25TQ012)the AI for Science Foundation of Fudan University(FudanX24A1035)the National Research Foundation,Singapore,under its Singapore-China Joint Flagship Project(Clean Energy).
文摘Electrolytic Zn-MnO_(2)batteries arepromising candidates for safe and sustainable energystorage owing to their high voltage,environmentalbenignity,and cost-effectiveness.However,practicalapplications are hindered by the poor conductivity andthe irreversible dissolution of conventionalε-MnO_(2)deposits.Herein,we report a scalable semisolid slurryelectrode architecture that enables stable MnO_(2)deposition/dissolution using a three-dimensional percolatingnetwork of carbon nanotubes(CNTs)as both conductivematrix and deposition host.The slurry systempromotes the formation of highly conductiveγ-MnO_(2)owing to enhanced charge transfer kinetics,enablingoverall dissolution rather than the localized separationtypically seen in traditional electrodes.The Zn-MnO_(2)slurry cell exhibits a reversible areal capacity approaching 60 mAh cm^(-2).Moreover,theflowable nature of the slurry allows electrochemically inactive MnO_(2)formed during dissolution to be reconnected and reactivated by CNTs inthe rheological network,ensuring deep utilization and cycling stability.This work establishes a slurry electrode strategy to improve electrolyticMnO_(2)reactions and offers a viable pathway toward renewable aqueous batteries for grid-scale applications.
基金supported by the National Natural Science Foundation of China(Nos.51225804,U1234204,and 41472244)the Doctoral Fund of the Ministry of Education of China(No.20120101110027)+1 种基金the Research Fund from the China Railway Corporation(No.2014G003-B)the Zhejiang Provincial Communication Department(No.2014H07),China
文摘Pressurized bentonite slurry is applied on a tunnel face to form a filter cake to stabilize the tunnel face when the slurryshield excavates through the sandy soil. Failure of the tunnel face may be caused by a high permeable filter cake, which commonlyhas a long penetration distance of slurry in sands. A column system with a height of 680 mm and a diameter of 300 mm was de-veloped to model pressurized slurry infiltration in sands. Pressure transducers were installed to estimate the hydraulic conductivityof the filter cake during slurry infiltration. The electrical conductivity of the leachate of collected samples was measured. Resultsshow that the majority of fine particles in slurry are within the range 100-300 mm into the sand specimen. The time for forming animpermeable filter cake is about 300 s, which indicates the impermeable filter cake is hard to form during the excavation.
基金Project(51376198)supported by the National Natural Science Foundation of ChinaProject(11JJ22029)supported by the Hunan Provincial Natural Science Foundation of China
文摘A novel vacuum ice slurry producing system with jet-pumps was proposed to deal with the problems of high energy consumption and ice blockage.In this novel system,one steam driven by a jet-pump was used to create vacuum in a hermetic vessel where water was sprayed through a nozzle to produce ice slurry,while the other steam was used to provide enough cold energy to make the left vapor in the hermetic vessel condense.Mathematical models of this novel system were established and theoretical simulation on the performance characteristics was also implemented based on the MATLAB program.Results show that the novel system is feasible and practicable,and the system performance is affected by many factors,such as the temperature of the generators,condensing temperature,evaporation temperature,and the cooling load of the refrigerator sub-system.The findings are helpful to improve the performance of ice slurry producing system.
文摘Development of a technology that can reduce the odor of liquid swine manure during agitation and land application could prove beneficial to the swine industry. The purpose of this study was to evaluate a commercial ozone treatment system for swine slurry under production scale conditions. The facility used for this study was a curtain sided finishing building housing 500 grow–finish market hogs located over a manure pit measuring 12.2 m wide × 25.9 m long × 2.4 m deep with a total pit capacity of 770,142 l, containing 577,607 l. The system evaluated exposes air to ultra-violet light creating O3. The O3 is then injected into slurry at a rate of 851.6 l/min. treating 51,097 l/h. In this study the entire pit contents were treated every 11.3 h. At 0, 24, 48, and 96 h two slurry samples were collected with a 3.05 m probe and six air sample bags were collected via a vacuum pump. No significant differences were detected in slurry samples between time periods. Mean slurry values were 13.6 ± 4.6% solids dry wt., 850 ± 70 mg/l settable solids, 54,200 ± 4384 mg/l total suspended solids, 61,050 ± 12,657 mg/l chemical oxygen demand, 0.86 ± 0.14%N, 0.49 ± 0.27%P, 0.45 ± 0.01%K and dissolved oxygen below detection limits. Ammonia concentrations decreased (P = 0.004) from 0 to 96 h. Odor panelists analyzed air samples for intensity at recognition (IR), offensiveness at recognition (OR), intensity at full strength (IFS) and offensiveness at full strength (OFS). Panelists found OR, IFS and OFS were reduced (P < 0.01) at 48 h and 96 h compared to 0 h and IR was reduced (P < 0.04) at 24 h and 48 h and not at 96 h but trended lower (P = 0.12) at 96 h. The system evaluated significantly improved air quality within the building suggesting that odor emanating from swine buildings and odor generated during land application of slurry should be reduced.
文摘In the present study, the ice slurry refrigeration system with pre-cooling heat exchanger (ISSH) is studied experimentally to achieve the system performance, ice crystal formation time and the temperature of ice crystal formation. The operating parameters considered in this paper include the concentration of salt solution, suction pressure, discharge pressure and Energy Efficiency Ratio (EER). The result shows that the temperature of critical time of ice crystal formation decreases with the increasing concentration of salt solution and that the ice crystal formation time increases with the increasing concentration of salt solution. In the same concentration of salt solution, the ice crystal formation temperature of ISSH is lower than that of basic ice slurry refrigeration system (BISS), and the ice crystal formation time of ISSH is shorter than that of BISS. On the whole, the EER of ice slurry refrigeration system with pre-cooling heat exchanger is higher than that of basic ice slurry refrigeration system.
基金Hubei Provincial Key Research Program Project(2023BCB099).
文摘Utilizing phosphorus tailings as the raw material for foam concrete is a key approach to achieving sustainable and efficient resource utilization.During the preparation of phosphorus tailings-based foam concrete,slurry performance is critical to the successful production.Phosphorus tailings,cement and microsilica were used to prepare foam concrete slurry in this study.A rheometer was employed as a test tool to measure the variation of linear viscoelastic zone(LVR),viscosity,and yield stress of the slurries with different cement contents.The results indicate that the phosphorus tailings-cement-microsilica slurry exhibits shear-thinning properties,which aligns well with the Herschel-Bulkley model,showing a high degree of correlation.As the cement content increases,the energy storage modulus of the slurry rises,and the LVR length shows a nonlinear trend.The LVR reaches its maximum length of 0.04%when the cement content is 6 mass%or 8 mass%.The increment of the cement content leads to a more intricate internal network structure,which hinders the reconstruction rate of the flocculated structure after high-shear deformation.
基金support from the Scientific Research Foundation for the Introduction of Talent,Anhui University of Science and Technology(2023yjrc90)the Fundamental Research Funds of the AUST(2024JBQN0015)the Open Research Fund Program of Anhui Provincial Institute of Modern Coal Processing Technology,Anhui University of Science and Technology(MTY202302).
文摘The multipath application of green resources needs to be realised under the carbon neutrality goal.Worldwide,biomass is a resource in urgent need of treatment.In this paper,corn stover biomass(YM)or biochar with different particle sizes(YMF or YMX)was added during the preparation of coal-water slurry to investigate its effect on the performance of coal-water slurry and the micro-mechanism.The results showed that the fixed viscosity concentration of coal-water slurry(CYWS)with YM was only 47.42%,and the flowability was 49.9 mm,which made the slurry performance poor.The fixed viscosity concentration of coal-water slurry(CFWS)blended with YMF and coal-water slurry(CXWS)blended with YMX increased by 10.41%and 14.24%,respectively,compared with CYWS.Meanwhile,CXWS had the lowest thixotropy and yield stress,with a yield stress of only 16.13 Pa,which was 77.31 Pa lower than that of CYWS.This indicates that YMX treated by charring and milling is more favorable to be blended with coal to prepare coal-water slurry.This is due to the enhanced hydrophilicity and electronegativity of YMX.The enhanced hydrophilicity reduces the tendency to form three-dimensional networks in coal-water slurry,while the enhanced electronegativity improves the electrostatic repulsion between particles,which is beneficial to the dispersion of particles.In the subsequent EDLVO analyses,the same idea was proved.
基金supported by the Fundamental Research Funds for the Central Universities(Grant No.2023YJS053)the National Natural Science Foundation of China(Grant No.52278386).
文摘To fundamentally alleviate the excavation chamber clogging during slurry tunnel boring machine(TBM)advancing in hard rock,large-diameter short screw conveyor was adopted to slurry TBM of Qingdao Jiaozhou Bay Second Undersea Tunnel.To evaluate the discharging performance of short screw conveyor in different cases,the full-scale transient slurry-rock two-phase model for a short screw conveyor actively discharging rocks was established using computational fluid dynamics-discrete element method(CFD-DEM)coupling approach.In the fluid domain of coupling model,the sliding mesh technology was utilized to describe the rotations of the atmospheric composite cutterhead and the short screw conveyor.In the particle domain of coupling model,the dynamic particle factories were established to produce rock particles with the rotation of the cutterhead.And the accuracy and reliability of the CFD-DEM simulation results were validated via the field test and model test.Furthermore,a comprehensive parameter analysis was conducted to examine the effects of TBM operating parameters,the geometric design of screw conveyor and the size of rocks on the discharging performance of short screw conveyor.Accordingly,a reasonable rotational speed of screw conveyor was suggested and applied to Jiaozhou Bay Second Undersea Tunnel project.The findings in this paper could provide valuable references for addressing the excavation chamber clogging during ultra-large-diameter slurry TBM tunneling in hard rock for similar future.
文摘In this work,the influences of surface layer slurry at different temperatures(10℃,14℃,18℃,22℃)on wax patterns deformation,shrinkage,slurry coating characteristics,and the surface quality of the casting were investigated by using a single factor variable method.The surface morphologies of the shell molds produced by different temperatures of the surface(first)layer slurries were observed via electron microscopy.Furthermore,the microscopic composition of these shell molds was obtained by EDS,and the osmotic effect of the slurry on the wax patterns at different temperatures was also assessed by the PZ-200 Contact Angle detector.The forming reasons for the surface cracks and holes of thick and large ZTC4 titanium alloy by investment casting were analyzed.The experimental results show that the surface of the shell molds prepared by the surface layer slurry with a low temperature exhibits noticeable damage,which is mainly due to the poor coating performance and the serious expansion and contraction of wax pattern at low temperatures.The second layer shell material(SiO_(2),Al_(2)O_(3))immerses into the crack area of the surface layer,contacts and reacts with the molten titanium to form surface cracks and holes in the castings.With the increase of the temperature of surface layer slurry,the damage to the shell surface tends to weaken,and the composition of the shell molds'surface becomes more uniform with less impurities.The results show that the surface layer slurry at 22℃is evenly coated on the surface of the wax patterns with appropriate thickness,and there is no surface shell mold rupture caused by sliding slurry after sand leaching.The surface layer slurry temperature is consistent with the wax pattern temperature and the workshop temperature,so there is no damage of the surface layer shell caused by expansion and contraction.Therefore,the shell mold prepared by the surface layer slurry at this temperature has good integrity,isolating the contact between the low inert shell material and the titanium liquid effectively,and the ZTC4 titanium alloy cylinder casting prepared by this shell mold is smooth,without cracks and holes.
基金financially supported by the National Natural Science Foundation of China (No. 52062029)the Key Science and Technology Project of Gansu Province (No. 18YF1GA064)the Natural Science Foundation of Gansu Provence (No. 25JRRA094)。
文摘Investment casting shell moulds are widely applied to cast alloys, but how to efficiently form a hierarchical porous structure inside the wall is an innovation and challenge. In this research, porous shell moulds with three infill patterns(rectilinear, grid, and honeycomb) were prepared using bauxite slurry and slurry extrusionbased additive manufacturing technology, and the effects of infill patterns on the properties were evaluated. The hierarchical pores inside the wall are composed of the macropores formed by infills and the micropores among bauxite particles. Different infill patterns result in changes in distribution and shape of pores, thereby affecting the properties of the shell moulds. The honeycomb pattern has more comprehensive advantages compared to the other two infill patterns. The samples prepared with the honeycomb pattern exhibit the highest bending strength(11.62 MPa) and porosity(41.6%), as well as good heat-transfer ability, with an average shrinkage rate within 2.0%. This work provides an attractive feasibility for fabricating shell moulds with hierarchical porous walls.
基金Projects(52104355,52074363,52374364)supported by the National Natural Science Foundation of ChinaProject(2023YFC2907904)supported by the National Key R&D Program of China。
文摘Traditional pyrometallurgical and hydrometallurgical methods to extract bismuth from sulfide ores face problems such as high cost,low-concentration SO_(2)generation,and long process time.In this study,the cyclone technology and slurry electrolysis method were combined.The bismuth sulfide ore was dissolved directly at the anode,while the high purity bismuth was deposited efficiently at the cathode under the advantages of the two methods.The short process and high-efficiency extraction of bismuth sulfide ore were realized,and the pollution of low-concentration SO_(2)was avoided.Then,the effects of several crucial experimental conditions(current density,reaction time,temperature,pH,liquid-solid ratio,and circulation flow rate)on the leaching efficiency and recovery efficiency of bismuth were investigated.The leaching and electrowinning mechanisms during the recovery process were also analyzed according to the research results of this paper to better understand the cyclone slurry electrolysis process.The experimental results showed that 95.19%bismuth was leached into the acid solution in the anode area under optimal conditions,and the recovery efficiency and purity of bismuth on the cathode reached 91.13%and 99.26%,respectively,which were better than those by the traditional hydrometallurgy recovery process.
基金supported by Fonds Wetenschappelijk Onderzoek-Vlaanderen(FWO).D.M.acknowledges support from FWO in the form of strategic basic research fellowships(File number:1S13924N).
文摘This study investigates the leaching and purification processes for dunite slurry,a common mining waste material,and the carbonation processes for the mineralization of CO_(2) with Mg^(2+).Results indicate that HCl is a promising leaching agent,and pH and temperature are major factors in controlling the efficiency of the leaching process,with leaching efficiencies of 82%achieved after 4 h using 2 M HCl solution at 75℃.The removal of other ions like Fe^(3+),Fe^(2+),and Al^(3+)through the purification of the leachate using ammonium hydroxide was also proven to be effective,completely removing iron and aluminum from the leachate from starting concentrations of 3.10 and 0.40 g/L,respectively.The carbonation of magnesium at room temperature was investigated with both purified leachate and pure MgCl_(2) aqueous solution.Nesquehonite crystals began to form after 1.5 h with a conversion of Mg^(2+)to nesquehonite of approximately 5%.The produced crystals possess a needle-like shape,which could be modified using the biopolymers pectin and xanthan.Pectin had a limited influence on the length of the crystals,reducing the needle length with increasing pectin concentration.Xanthan,on the other hand,shortened and widened the needle-like structure into a column shape as more xanthan was added.This study demonstrates the potential for this process to utilize mining wastes and sequester CO_(2),producing useful mineral products in the process.
基金The authors gratefully acknowledge the filnancial support of the National Natural Science Foundation of China(Grant No.52369018)the Major Training Program of University Research and Innovation Platform of Gansu Provincial Department of Education(No.2024CXPT-09)+1 种基金the Administration of Central Funds Guiding the Local Science and Technology Development,China(Grant No.23ZYQA0320)the Double First-Class Key Program of Gansu Provincial Department of Education,Grant No.GCJ2022-38.
文摘Erosion in slurry pumps presents a persistent challenge in industrial applications.This study examines the erosion of the static components of a 150ZJ-C42 centrifugal slurry pump,currently in operation at a beneficiation plant,under varying particle conditions.Utilizing high-precision three-dimensional reverse engineering,the pump’s flow passage geometry was reconstructed to facilitate detailed erosion analysis.Focusing on the front and rear baffles of the pump chamber,as well as the volute,erosion patterns were analyzed for different particle volume concentrations and sizes.The results reveal that the highest erosion damage consistently occurs near the volute tongue,with wear being most severe in regions adjacent to the partition plate near the rear cover.Erosion damage intensity in this area correlates positively with particle diameter.Notably,the average erosion rate in the volute surpasses that of the front and rear chamber liners,reaching a value as high as 6.03×10^(-7)kg·m^(-2)·s^(-1)at a particle concentration of 9%and diameter of 0.1 mm,adversely impacting pump stability.For the pump chamber baffles,increased erosion is observed at a particle diameter of 0.05 mm under constant volume concentration conditions,while higher particle concentrations exacerbate localized erosion.
基金supported by the National Key Research and Development Program(2021YFB3501103)Guiding Local Funding Projects for Scientific and Technological Development by Central Government in Hebei(216Z1402G)Youth Fund of GRINM Group Co.,Ltd.
文摘The lanthanum-cerium-based slurry(LC-slurry)is extensively utilized in the chemical mechanical polishing(CMP)of TFT-LCD glass substrates,optical lenses,and other glass products.Sodium hexametaphosphate(SHMP),as a dispersant,is commonly employed to enhance the dispersion properties of LCslurry for improved polishing performance.However,the tendency of sedimentation to form a compacted sediment layer,which is challenging to redisperse,increases storage difficulty and polishing equipment failure risk,thereby limiting its utilization in CMP.In the present study,sodium carboxymethylcellulose(CMC-Na),a long-chain organic polymer,was employed to enhance the redispersibility of LC-slurry containing SHMP.A comprehensive investigation was conducted on the influence of CMC-Na dosage and slurry pH on dispersibility,redispersibility and polishing performance.Additionally,an analysis was carried out to elucidate the underlying mechanism behind the effect of CMC-Na.The study demonstrates that the LC-slurry,containing 250 ppm SHMP and 500 ppm CMC-Na,exhibits excellent dispersibility and redispersibility.Further polishing tests demonstrate that compared to the LC-slurry containing only SHMP,utilizing the slurry containing both SHMP and CMC-Na at various pH for polishing thin film transistor liquid crystal display(TFT-LCD)glass substrates results in a reduction of both material removal rate(MRR)and surface roughness(Sa).Specifically,when adjusting the slurry to a pH range of 5-6,the MRR can reach up to 330 nm/min,which closely approximates the MRR achieved by LC-slurry containing only 250 ppm SHMP at corresponding pH values.Meanwhile,after polishing,the surface roughness of the glass substrate measures approximately 0.47 nm.
基金Project(5206800)supported by the National Natural Science Foundation of ChinaProject(2024JJA160096)supported by the Natural Science Foundation of Guangxi Province,China。
文摘Bauxite tailing(BT)slurry has been generated and accumulated in large quantities,posing a threat to the green and sustainable development of the alumina industry.The regression equation between the actual water content and mud water separation rate was established to achieve efficient resource utilization,and the feasibility of foam lightweight soil(FLS)prepared from BT was investigated.The effects of industrial waste residues(fly ash and slag powder)on the properties of FLS were studied.Meanwhile,the micro-mechanisms were revealed by XRD,SEM-EDS,and TG-DSC.The results revealed that fly ash reduced the workability and compressive strength of FLS.Slag powder can significantly enhance the compressive strength of FLS,which increased by 18.60%-23.26%,17.07%-58.54% and 12.12%-52.12%,respectively.Besides,slag powder can improve the long-term water stability performance and enhance carbonation resistance.XRD and thermal analyses showed that adding fly ash decreased the hydration degree of FLS,leading to a decrease in the hydration products.Slag powder improved the pore structure and compacted the skeleton structure of FLS.This study would provide an effective way to realize the resource utilization of BT,fly ash,and slag powder,with certain socio-economic and environmental benefits.
