A novel method of ultra-trace Cd（Ⅱ） preconcentration with nanometer-size TiO2 colloid and determination by graphite furnace atomic adsorption spectrometry（GFAAS） with slurry sampling was first advanced in this pa...A novel method of ultra-trace Cd（Ⅱ） preconcentration with nanometer-size TiO2 colloid and determination by graphite furnace atomic adsorption spectrometry（GFAAS） with slurry sampling was first advanced in this paper. The adsorption efficiency of nanometer-size TiO2 colloid for ultra-trace Cd（Ⅱ） could reach above 96% in a short time when the pH value was between 5 and 6. Other problems were also studied, such as adsorption capacity, nanometer-size TiO2 colloid dosage, effect of coexistent ions. The detection limit（3σ） and the relative standard deviation （R.S.D） of this method were 4.46.103 μg/L and 1.30%（n=7）, respectively. The method was successfully applied to the analysis of environmental samples with recoveries between 93.8% and 96.4%.展开更多
Ultrasonic aided slurry sampling hydride generation atomic fluorescence spectrometry （USS-HG-AFS） was developed for the determination of Hg in soil samples from a sewage-irrigated farm. 500 mg grounded soil was susp...Ultrasonic aided slurry sampling hydride generation atomic fluorescence spectrometry （USS-HG-AFS） was developed for the determination of Hg in soil samples from a sewage-irrigated farm. 500 mg grounded soil was suspended in agar solution by an ultrasound water bath before the HG-AFS determination. The results for the reference material of soil （serial number GBW-07411） agreed satisfactorily with the certified values. Results obtained by the developed procedure compared well with those after traditional acid digestion of samples. The detection limit are 6.7ngL-1 for Hg respectively, with average relative standard deviation values of 6.4% for analysis of a series of soil samples of different origin. The recoveries of the anatytes varied in the range from 95 to 107%. This observation has stimulated interest in fast, accurate and sensitive analytical methods for determination of metals in soil.展开更多
文摘A novel method of ultra-trace Cd（Ⅱ） preconcentration with nanometer-size TiO2 colloid and determination by graphite furnace atomic adsorption spectrometry（GFAAS） with slurry sampling was first advanced in this paper. The adsorption efficiency of nanometer-size TiO2 colloid for ultra-trace Cd（Ⅱ） could reach above 96% in a short time when the pH value was between 5 and 6. Other problems were also studied, such as adsorption capacity, nanometer-size TiO2 colloid dosage, effect of coexistent ions. The detection limit（3σ） and the relative standard deviation （R.S.D） of this method were 4.46.103 μg/L and 1.30%（n=7）, respectively. The method was successfully applied to the analysis of environmental samples with recoveries between 93.8% and 96.4%.
文摘Ultrasonic aided slurry sampling hydride generation atomic fluorescence spectrometry （USS-HG-AFS） was developed for the determination of Hg in soil samples from a sewage-irrigated farm. 500 mg grounded soil was suspended in agar solution by an ultrasound water bath before the HG-AFS determination. The results for the reference material of soil （serial number GBW-07411） agreed satisfactorily with the certified values. Results obtained by the developed procedure compared well with those after traditional acid digestion of samples. The detection limit are 6.7ngL-1 for Hg respectively, with average relative standard deviation values of 6.4% for analysis of a series of soil samples of different origin. The recoveries of the anatytes varied in the range from 95 to 107%. This observation has stimulated interest in fast, accurate and sensitive analytical methods for determination of metals in soil.
