As the size of transistors shrinks and power density increases,thermal simulation has become an indispensable part of the device design procedure.However,existing works for advanced technology transistors use simplifi...As the size of transistors shrinks and power density increases,thermal simulation has become an indispensable part of the device design procedure.However,existing works for advanced technology transistors use simplified empirical models to calculate effective thermal conductivity in the simulations.In this work,we present a dataset of size-dependent effective thermal conductivity with electron and phonon properties extracted from ab initio computations.Absolute in-plane and cross-plane thermal conductivity data of eight semiconducting materials(Si,Ge,GaN,AlN,4H-SiC,GaAs,InAs,BAs)and four metallic materials(Al,W,TiN,Ti)with the characteristic length ranging from 5 nm to 50 nm have been provided.Besides the absolute value,normalized effective thermal conductivity is also given,in case it needs to be used with updated bulk thermal conductivity in the future.展开更多
The size-dependent effect on the biaxial and shear nonlinear buckling analysis of an isotropic and orthotropic micro-plate based on the surface stress, the modified couple stress theory (MCST), and the nonlocal elas...The size-dependent effect on the biaxial and shear nonlinear buckling analysis of an isotropic and orthotropic micro-plate based on the surface stress, the modified couple stress theory (MCST), and the nonlocal elasticity theories using the differential quadrature method (DQM) is presented. Main advantages of the MCST over the classical theory (CT) are the inclusion of the asymmetric couple stress tensor and the consideration of only one material length scale parameter. Based on the nonlinear von Karman assumption, the governing equations of equilibrium for the micro-classical plate consid- ering midplane displacements are derived based on the minimum principle of potential energy. Using the DQM, the biaxial and shear critical buckling loads of the micro-plate for various boundary conditions are obtained. Accuracy of the obtained results is validated by comparing the solutions with those reported in the literature. A parametric study is conducted to show the effects of the aspect ratio, the side-to-thickness ratio, Eringen's nonlocal parameter, the material length scale parameter, Young's modulus of the surface layer, the surface residual stress, the polymer matrix coefficients, and various boundary conditions on the dimensionless uniaxial, biaxial, and shear critical buckling loads. The results indicate that the critical buckling loads are strongly sensitive to Eringen's nonlocal parameter, the material length scale parameter, and the surface residual stress effects, while the effect of Young's modulus of the surface layer on the critical buckling load is negligible. Also, considering the size dependent effect causes the increase in the stiffness of the orthotropic micro-plate. The results show that the critical biaxial buckling load increases with an increase in G12/E2 and vice versa for E1/E2. It is shown that the nonlinear biaxial buckling ratio decreases as the aspect ratio increases and vice versa for the buckling amplitude. Because of the most lightweight micro-composite materials with high strength/weight and stiffness/weight ratios, it is anticipated that the results of the present work are useful in experimental characterization of the mechanical properties of micro-composite plates in the aircraft industry and other engineering applications.展开更多
This study investigates the surface effects on the operation of double-ended dislocation sources in single-crystal micropillars under compression.A comprehensive theoretical framework is formulated to derive the stres...This study investigates the surface effects on the operation of double-ended dislocation sources in single-crystal micropillars under compression.A comprehensive theoretical framework is formulated to derive the stress field of the source segment and the corresponding Peach-Koehler(PK)forces acting on this segment near the free surfaces.An analytical formulation is then developed to compare the source strength with and without the influence of the surface stress.The results reveal that the surface effects on the dislocation source strength are highly sensitive to the interplay between the source length and its distance from the free surface.These surface effects can either enhance or reduce the critical stress required for the source operation by up to 50%,leading to significant fluctuations in yield strength,as commonly observed in discrete dislocation dynamics simulations and experimental studies.These findings provide different interpretations for the size-dependent and stochastic yield stress behavior in face-centered cubic(FCC)micropillars.展开更多
Summary: The contribution of particles to cardiovascular mortality and morbidity has been enlightened by epidemiologic and experimental studies. However, adverse biological effects of the particles with different siz...Summary: The contribution of particles to cardiovascular mortality and morbidity has been enlightened by epidemiologic and experimental studies. However, adverse biological effects of the particles with different sizes on cardiovascular cells have not been well recognized. In this study, sub-cultured human umbilical vein endothelial cells (HUVECs) were exposed to increasing concentrations of pure quartz particles (DQ) of three sizes (DQPM1, 〈1 μm; DQPM3-5, 3-5 μm; DQPM5, 5 μm) and carbon black particles of two sizes (CB0.1, 〈0.1 μm; CB 1, 〈 1 μm) for 24 h. Cytotoxicity was estimated by measuring the activity of lactate dehydrogenase (LDH) and cell viability. Nitric oxide (NO) generation and cyto- kines (TNF-α and IL-1β) releases were analyzed by using NO assay and enzyme-linked immunoabsorbent assay (ELISA), respectively. It was found that both particles induced adverse biological effects on HUVECs in a dose-dependent manner. The size of particle directly influenced the biological activity. For quartz, the smaller particles induced stronger cytotoxicity and higher levels of cytokine responses than those particles of big size. For carbon black particles, CB0.1 was more capable of inducing adverse responses on HUVECs than CB 1 only at lower particle concentrations, in contrast to those at higher concentrations. Meanwhile, our data also revealed that quartz particles performed stronger cell damage and produced higher levels of TNF-α than carbon black particles, even if particles size was similar. In conclusion, particle size as well as particle composition should be both considered in assessing vascular endothelial cells injury and inflammation responses induced by particles.展开更多
Al-Mg-Si-Sc alloys with different Mg/Si ratio(<1.73 in wt.% vs>1.73 in wt.%) and different grain size(coarse grains vs ultrafine grains) were prepared, which allowed to investigate the grain size-dependent Mg/Si...Al-Mg-Si-Sc alloys with different Mg/Si ratio(<1.73 in wt.% vs>1.73 in wt.%) and different grain size(coarse grains vs ultrafine grains) were prepared, which allowed to investigate the grain size-dependent Mg/Si ratio effect on the microstructural evolution and concomitantly on the hardness and electrical conductivity when subjected to aging at 200℃. In the coarse-grained Al-Mg-Sc-Sc alloys, the β" precipitation within the grain interior and also the precipitation hardening were highly dependent on the Mg/Si ratio,while the electrical conductivity was slightly affected by the Mg/Si ratio. A promoted β" precipitation was found in the case of Si excess(Mg/Si ratio <1.73), much greater than in the case of Mg excess(Mg/Si ratio>1.73). While in the ultrafine-grained Al-Mg-Si-Sc alloys, the electrical conductivity rather than the hardness was more sensitive to the Mg/Si ratio. The alloy with Si excess displayed electrical conductivity much higher than its counterpart with Mg excess. This is rationalized by the grain boundary precipitation promoted by Si, which reduced the solute atoms and precipitates within the grain interior. Age softening was found in the ultrafine-grained alloy with Si excess, but the ultrafine-grained alloy with Mg excess held the hardness almost unchanged during the aging. The hardness-conductivity correlation is comprehensively discussed by considering the coupling effect of Mg/Si ratio and grain size. A strategy to simultaneously increase the hardness/strength and electrical conductivity is proposed for the Al-Mg-SiSc alloys, based on present understanding of the predominant factors on strengthening and conductivity,respectively.展开更多
A size-dependent continuum-based model is developed for the functionally graded(FG)Timoshenko micro-beams with viscoelastic properties,in which material parameters vary according to the power law along its axial direc...A size-dependent continuum-based model is developed for the functionally graded(FG)Timoshenko micro-beams with viscoelastic properties,in which material parameters vary according to the power law along its axial direction.The size effect is incorporated by employing the modified couple stress theory and Kelvin-Voigt viscoelastic model,so that viscous components are included in the stress and the deviatoric segments of the symmetric couple stress tensors.The components of strain,curvature,stress and couple stress are formulated by combining them with the Timoshenko beam theory.Based on the Hamilton principle,the governing differential equations and boundary conditions for the micro-beam are expressed with arbitrary beam section shape and arbitrary type of loads.The size effect,FG effect,Poisson effect,and the influence of the beam section shape on the mechanical behaviors of viscoelastic FG micro-beams are investigated by taking the simply supported micro-beam subjected to point load as an example.Results show that the size effect on deflection,normal stress and couple stress are obvious when the size of the micro-beam is small enough,and the FG effects are obvious when the size of the micro-beam is large enough.Moreover,the Poisson ratio influences the size effect significantly and the beam section shape is also an important factor influencing the mechanical behavior of the micro-beam.展开更多
The non-Hermitian systems with the non-Hermitian skin effect(NHSE)are very sensitive to the imposed boundary conditions and lattice sizes,which lead to size-dependent non-Hermitian skin effects.Here,we report the expe...The non-Hermitian systems with the non-Hermitian skin effect(NHSE)are very sensitive to the imposed boundary conditions and lattice sizes,which lead to size-dependent non-Hermitian skin effects.Here,we report the experimental observation of NHSE with different boundary conditions and different lattice sizes in the unidirectional hopping model based on a circuit platform.The circuit admittance spectra and corresponding eigenstates are very sensitive to the presence of the boundary.Meanwhile,our experimental results show how the lattice sizes and boundary terms together affect the strength of NHSE.Therefore,our electric circuit provides a good platform to observe size-dependent boundary effects in non-Hermitian systems.展开更多
Metastable high entropy alloys(HEAs) and amorphous metallic glasses(MGs), with the chemical disordered character, are intensively studied due to their excellent performance. Here, we introduce Cu to separately constra...Metastable high entropy alloys(HEAs) and amorphous metallic glasses(MGs), with the chemical disordered character, are intensively studied due to their excellent performance. Here, we introduce Cu to separately constrain these two metastable materials and comparatively investigate their deformation behaviors and mechanical properties of Cu/HEA Fe Co Cr Ni and Cu/MG Cu Zr nanolaminated micropillars in terms of intrinsic layer thickness h and extrinsic pillar diameter D. The metastable HEA layers, as the hard phase in Cu/HEA micropillars, are stable and dominate the deformation, while transformation(crystallization) occurs in MG which plays a minor role in deformation of Cu/MG micropillars. The h-controlled deformation mode transits from the D-independent homogenous-like deformation at large h to the Ddependent shear banding at small h in both Cu/HEA and Cu/MG micropillars. Although both Cu/HEA and Cu/MG micropillars exhibit a maximum strain hardening capability controlled by h, the former manifests much lower hardening capability compared with the latter. The intrinsic size h and extrinsic size D have a strong coupling effect on the strength of Cu/HEA and Cu/MG micropillars. The strength of strength of Cu/HEA micropillars exhibits the D-dependent transition from "smaller is stronger" to "smaller is weaker"with increasing h. By contrast, the strength of Cu/MG micropillars exhibits the transition from bulk-like D-independent behavior at large h to small volume D-dependent behavior(smaller is stronger) at small h.展开更多
Electrochemical ozone production(EOP) via water electrolysis represents an attractive method for the generation of high-purity O3. Herein, the X-PtZn/Zn-N-C electrocatalysts show a strong structural sensitive behavior...Electrochemical ozone production(EOP) via water electrolysis represents an attractive method for the generation of high-purity O3. Herein, the X-PtZn/Zn-N-C electrocatalysts show a strong structural sensitive behavior depends on the size of the PtZn nanoparticles and their EOP activity exhibits a volcano-type dependence for the O3 performance in neutral media. The 7.7-PtZn/Zn-N-C exhibits EOP current efficiency of 4.2%, and shows the prominent performance in the production of gaseous O3 with a value of 1647 ppb at 30 min, which is almost 4-fold compared to 2.2-Pt Zn/Zn-N-C. Based on the experiments and theoretical calculations, the performance of the EOP process was determined by the nanoparticle size-effect and the synergistic effect between the PtZn nanoparticles and atomically dispersed Zn-N-C. Furthermore, the fivemembered cyclic structure of O3 can be stabilized between the PtZn nanoparticle and the Zn-N-C support,indicating that O3 is produced at the interface.展开更多
Piezoelectric superlattice is a potential component for nanoelectromechanical systems. Due to the strong nonlocal effect such as flexoelectric effect at interfaces, classical piezoelectric theory is unable to accurate...Piezoelectric superlattice is a potential component for nanoelectromechanical systems. Due to the strong nonlocal effect such as flexoelectric effect at interfaces, classical piezoelectric theory is unable to accurately describe the electromechanical response of piezoelectric superlattice at nanoscale scale. Based on the previous nonlocal thermodynamics theory with flexoelectric effect Liu et al. (2016), the size- dependent electromechanical properties of piezoelectric superlattices made of BaTiO3 (BTO) and PbTiO3 (PRO) layers are investigated systematically in the present work. Giant strain gradient is found near the interface between BTO and PTO layers, which leads to the significant enhancement of polarization in the superlattice due to the flexoelectric effect. For the piezoelectric BTO-PTO superlattices with different unit- cell sizes, the thickness of interface with nontrivial strain gradient is almost constant. The influence of strain gradient at the interface becomes significant when the size of superlattice decreases, As a result, a strong size dependence of electromechanical properties is predicted for the piezoelectric BTO-PTO superlattices, In particular, for the superlattices with a specific thickness ratio of BTO and PTO layers, the piezoelectric response can be several times larger than that of bulk structure. The present work demonstrates a practical wast to design the piezoelectric superlattices with high piezoelectric coefficient by using the nonlocal effect at nanoscale.展开更多
The incomplete understanding of nanoscale surface interactions arising from underlying atomistic long-range forces limits our ability to simulate and design their performance. In this paper, the surface elasticity is ...The incomplete understanding of nanoscale surface interactions arising from underlying atomistic long-range forces limits our ability to simulate and design their performance. In this paper, the surface elasticity is constructed from underlying atomistic nonlocal interactions in spherical nanoparticles. By introducing an intrinsic length scale,we quantify the surface region thickness, and demonstrate the progressive elastic modulus transition caused by asymmetric atomistic nonlocal interactions. The universal surface scaling law, relating the intrinsic length scale to the particle dimensions, is established, and a surface-dominated criterion is developed for quantifying the transition to the surfacedominated behaviors. The model is thoroughly validated through the molecular static simulations and experimental data with the material-specific intrinsic length constants.展开更多
In this study,the thermodynamic behaviors of the intrinsic frequency and buckling temperature of rectangular plates of functionally graded materials(FGMs)are explored based on the modified couple stress theory(MCST)an...In this study,the thermodynamic behaviors of the intrinsic frequency and buckling temperature of rectangular plates of functionally graded materials(FGMs)are explored based on the modified couple stress theory(MCST)and the novel dual powerlaw scale distribution theory.The effects of linear,homogeneous,and non-homogeneous temperature fields on the frequency and buckling temperature of FGM microplates are evaluated in detail.The results show that the porosity greatly affects the mechanical properties of FGM plates,reducing their frequency and flexural temperature compared with non-porous plates.Different temperature profiles alter plate frequencies and buckling temperatures.The presence and pattern of scale effect parameters are also shown to be crucial for the mechanical response of FGM plates.The present research aims to provide precise guidelines for the micro-electro-mechanical system(MEMS)fabrication by elucidating the complex interplay between thermal,material,and structural factors that affect the performance of FGM plates in advanced applications.展开更多
This paper examined how microstructure influences the homogenized thermal conductivity of cellular structures and revealed a surface-induced size-dependent effect.This effect is linked to the porous microstructural fe...This paper examined how microstructure influences the homogenized thermal conductivity of cellular structures and revealed a surface-induced size-dependent effect.This effect is linked to the porous microstructural features of cellular structures,which stems from the degree of porosity and the distri-bution of the pores.Unlike the phonon-driven surface effect at the nanoscale,the macro-scale surface mechanism in thermal cellular structures is found to be the microstructure-induced changes in the heat conduction path based on fully resolved 3D numerical simulations.The surface region is determined by the microstructure,characterized by the intrinsic length.With the coupling between extrinsic and intrinsic length scales under the surface mechanism,a surface-enriched multiscale method was devel-oped to accurately capture the complex size-dependent thermal conductivity.The principle of scale separation required by classical multiscale methods is not necessary to be satisfied by the proposed multiscale method.The significant potential of the surface-enriched multiscale method was demon-strated through simulations of the effective thermal conductivity of a thin-walled metamaterial struc-ture.The surface-enriched multiscale method offers higher accuracy compared with the classical multiscale method and superior efficiency over high-fidelity finite element methods.展开更多
Herein,3‑aminopropyltriethoxysilane(APTES)was used to modify F‑containing silica slag(SS)by simple grafting and served as a multifunctional barrier layer.The amino group(—NH2)in the amino‑modified SS(NH2‑SS)forms lig...Herein,3‑aminopropyltriethoxysilane(APTES)was used to modify F‑containing silica slag(SS)by simple grafting and served as a multifunctional barrier layer.The amino group(—NH2)in the amino‑modified SS(NH2‑SS)forms ligand bonds or hydrogen bonds with sulfur ions in lithium polysulfides(LiPSs),thus inhibiting the shuttle effect.Electrochemical analyses demonstrated that lithium‑sulfur(Li‑S)batteries employing the NH2‑SS interlayer exhibited discharge specific capacities of 1048 and 789 mAh·g^(-1) at 0.2C and 2C,respectively,and even at 4C,the initial discharge specific capacity remained at 590 mAh·g^(-1),outperforming the Li‑S battery with unmodified SS as the interlayer.展开更多
In this paper,a fractional-order kinematic model is utilized to capture the size-dependent static bending and free vibration responses of piezoelectric nanobeams.The general nonlocal strains in the Euler-Bernoulli pie...In this paper,a fractional-order kinematic model is utilized to capture the size-dependent static bending and free vibration responses of piezoelectric nanobeams.The general nonlocal strains in the Euler-Bernoulli piezoelectric beam are defined by a frame-invariant and dimensionally consistent Riesz-Caputo fractional-order derivatives.The strain energy,the work done by external loads,and the kinetic energy based on the fractional-order kinematic model are derived and expressed in explicit forms.The boundary conditions for the nonlocal Euler-Bernoulli beam are derived through variational principles.Furthermore,a finite element model for the fractional-order system is developed in order to obtain the numerical solutions to the integro-differential equations.The effects of the fractional order and the vibration order on the static bending and vibration responses of the Euler-Bernoulli piezoelectric beams are investigated numerically.The results from the present model are validated against the existing results in the literature,and it is demonstrated that they are theoretically consistent.Although this fractional finite element method(FEM)is presented in the context of a one-dimensional(1D)beam,it can be extended to higher dimensional fractional-order boundary value problems.展开更多
Chitosan(CTS)was grafted onto the surface of amino‑functionalized silver chloride silicon dioxide(AgCl@SiO_(2)‑NH_(2))cores to obtain AgCl@SiO_(2)/CTS hybrid nanoparticles.The as‑obtained AgCl@SiO_(2)/CTS nanoparticle...Chitosan(CTS)was grafted onto the surface of amino‑functionalized silver chloride silicon dioxide(AgCl@SiO_(2)‑NH_(2))cores to obtain AgCl@SiO_(2)/CTS hybrid nanoparticles.The as‑obtained AgCl@SiO_(2)/CTS nanoparticles were chlorinated by NaClO solution to get AgCl@SiO_(2)/CTS‑based chloramine nano‑hybrid materials,denoted as AgCl@SiO_(2)/CTS‑Cl.A transmission electron microscope was used to observe the morphology of the as‑prepared samples AgCl@SiO_(2)/CTS and AgCl@SiO_(2)/CTS‑Cl.At the same time,an X‑ray diffractometer and an infrared spectroscope were utilized to characterize their crystal and chemical structures.Besides,ζpotentials were measured to elucidate the surface modification of AgCl nanoparticles by—NH_(2),the antibacterial mechanism of AgCl@SiO_(2)/CTS‑Cl was investigated by scanning electron microscopy,and Escherichia coli(E.coli)and Staphylococcus aureus(S.aureus)were used as the to‑be‑tested strains to evaluate the antimicrobial activity of samples AgCl@SiO_(2)/CTS and AgCl@SiO_(2)/CTS‑Cl.Findings demonstrate that sample AgCl@SiO_(2)/CTS exhibits a chain‑like structure ascribed to the interaction between—NH_(2),and each AgCl@SiO_(2)/CTS hybrid nanoparticle contains several AgCl cores.In the meantime,sample AgCl@SiO_(2)/CTS‑Cl exhibits excellent antibacterial activity against E.coli and S.aureus,which is attributed to the synergistic antibacterial effect of Ag^(+)and Cl^(-).Sample AgCl@SiO_(2)/CTS‑Cl with a dosage of 640.00μg·mL^(-1) could completely kill the two kinds of tested bacteria in 12 h of incubation;it retains a high antibacterial efficiency even after 10 cycles of antibacterial tests.展开更多
Rechargeable Zn/Sn-air batteries have received considerable attention as promising energy storage devices.However,the electrochemical performance of these batteries is significantly constrained by the sluggish electro...Rechargeable Zn/Sn-air batteries have received considerable attention as promising energy storage devices.However,the electrochemical performance of these batteries is significantly constrained by the sluggish electrocatalytic reaction kinetics at the cathode.The integration of light energy into Zn/Sn-air batteries is a promising strategy for enhancing their performance.However,the photothermal and photoelectric effects generate heat in the battery under prolonged solar irradiation,leading to air cathode instability.This paper presents the first design and synthesis of Ni_(2)-1,5-diamino-4,8-dihydroxyanthraquinone(Ni_(2)DDA),an electronically conductiveπ-d conjugated metal-organic framework(MOF).Ni_(2)DDA exhibits both photoelectric and photothermal effects,with an optical band gap of~1.14 eV.Under illumination,Ni_(2)DDA achieves excellent oxygen evolution reaction performance(with an overpotential of 245 mV vs.reversible hydrogen electrode at 10 mA cm^(−2))and photothermal stability.These properties result from the synergy between the photoelectric and photothermal effects of Ni_(2)DDA.Upon integration into Zn/Sn-air batteries,Ni_(2)DDA ensures excellent cycling stability under light and exhibits remarkable performance in high-temperature environments up to 80℃.This study experimentally confirms the stable operation of photo-assisted Zn/Sn-air batteries under high-temperature conditions for the first time and provides novel insights into the application of electronically conductive MOFs in photoelectrocatalysis and photothermal catalysis.展开更多
Beam-tracking simulations have been extensively utilized in the study of collective beam instabilities in circular accelerators.Traditionally,many simulation codes have relied on central processing unit(CPU)-based met...Beam-tracking simulations have been extensively utilized in the study of collective beam instabilities in circular accelerators.Traditionally,many simulation codes have relied on central processing unit(CPU)-based methods,tracking on a single CPU core,or parallelizing the computation across multiple cores via the message passing interface(MPI).Although these approaches work well for single-bunch tracking,scaling them to multiple bunches significantly increases the computational load,which often necessitates the use of a dedicated multi-CPU cluster.To address this challenge,alternative methods leveraging General-Purpose computing on Graphics Processing Units(GPGPU)have been proposed,enabling tracking studies on a standalone desktop personal computer(PC).However,frequent CPU-GPU interactions,including data transfers and synchronization operations during tracking,can introduce communication overheads,potentially reducing the overall effectiveness of GPU-based computations.In this study,we propose a novel approach that eliminates this overhead by performing the entire tracking simulation process exclusively on the GPU,thereby enabling the simultaneous processing of all bunches and their macro-particles.Specifically,we introduce MBTRACK2-CUDA,a Compute Unified Device Architecture(CUDA)ported version of MBTRACK2,which facilitates efficient tracking of single-and multi-bunch collective effects by leveraging the full GPU-resident computation.展开更多
The dried fruit of Forsythia suspensa(Oleaceae),also known as Forsythia,is a traditional Chinese medicinal herb known for its heat-clearing and detoxifying properties.It is used to disperse nodules,reduce swelling,rem...The dried fruit of Forsythia suspensa(Oleaceae),also known as Forsythia,is a traditional Chinese medicinal herb known for its heat-clearing and detoxifying properties.It is used to disperse nodules,reduce swelling,remove toxins,clear heat,and alleviate wind-heat syndromes.It also has hepatoprotective,anti-inflammatory,antiviral,antibacterial,anticancer,antioxidant,antiaging,and anti-obesity effects,as well as potential therapeutic effects on Alzheimer’s disease and diabetic nephropathy.It is used to treat scrofula,mastitis,wind-heat common cold,and other ailments.The review summarizes the chemical constituents and pharmacological effects of F.suspensa,aiming to provide a scientific foundation for its future development,research,and clinical utilization.展开更多
This paper extends the one-dimensional(1D)nonlocal strain gradient integral model(NStraGIM)to the two-dimensional(2D)Kirchhoff axisymmetric nanoplates,based on nonlocal strain gradient integral relations formulated al...This paper extends the one-dimensional(1D)nonlocal strain gradient integral model(NStraGIM)to the two-dimensional(2D)Kirchhoff axisymmetric nanoplates,based on nonlocal strain gradient integral relations formulated along both the radial and circumferential directions.By transforming the proposed integral constitutive equations into the equivalent differential forms,complemented by the corresponding constitutive boundary conditions(CBCs),a well-posed mathematical formulation is established for analyzing the axisymmetric bending and buckling of annular/circular functionally graded(FG)sandwich nanoplates.The boundary conditions at the inner edge of a solid nanoplate are derived by L'H?spital's rule.The numerical solution is obtained by the generalized differential quadrature method(GDQM).The accuracy of the proposed model is validated through comparison with the data from the existing literature.A parameter study is conducted to demonstrate the effects of FG sandwich parameters,size parameters,and nonlocal gradient parameters.展开更多
基金Project supported by the National Key R&D Project from Ministry of Science and Technology of China(Grant No.2022YFA1203100)the National Natural Science Foundation of China(Grant No.52122606)the funding from Shanghai Polytechnic University.
文摘As the size of transistors shrinks and power density increases,thermal simulation has become an indispensable part of the device design procedure.However,existing works for advanced technology transistors use simplified empirical models to calculate effective thermal conductivity in the simulations.In this work,we present a dataset of size-dependent effective thermal conductivity with electron and phonon properties extracted from ab initio computations.Absolute in-plane and cross-plane thermal conductivity data of eight semiconducting materials(Si,Ge,GaN,AlN,4H-SiC,GaAs,InAs,BAs)and four metallic materials(Al,W,TiN,Ti)with the characteristic length ranging from 5 nm to 50 nm have been provided.Besides the absolute value,normalized effective thermal conductivity is also given,in case it needs to be used with updated bulk thermal conductivity in the future.
基金supported by the Iranian Nanotechnology Development Committee and the University of Kashan(No.363452/10)
文摘The size-dependent effect on the biaxial and shear nonlinear buckling analysis of an isotropic and orthotropic micro-plate based on the surface stress, the modified couple stress theory (MCST), and the nonlocal elasticity theories using the differential quadrature method (DQM) is presented. Main advantages of the MCST over the classical theory (CT) are the inclusion of the asymmetric couple stress tensor and the consideration of only one material length scale parameter. Based on the nonlinear von Karman assumption, the governing equations of equilibrium for the micro-classical plate consid- ering midplane displacements are derived based on the minimum principle of potential energy. Using the DQM, the biaxial and shear critical buckling loads of the micro-plate for various boundary conditions are obtained. Accuracy of the obtained results is validated by comparing the solutions with those reported in the literature. A parametric study is conducted to show the effects of the aspect ratio, the side-to-thickness ratio, Eringen's nonlocal parameter, the material length scale parameter, Young's modulus of the surface layer, the surface residual stress, the polymer matrix coefficients, and various boundary conditions on the dimensionless uniaxial, biaxial, and shear critical buckling loads. The results indicate that the critical buckling loads are strongly sensitive to Eringen's nonlocal parameter, the material length scale parameter, and the surface residual stress effects, while the effect of Young's modulus of the surface layer on the critical buckling load is negligible. Also, considering the size dependent effect causes the increase in the stiffness of the orthotropic micro-plate. The results show that the critical biaxial buckling load increases with an increase in G12/E2 and vice versa for E1/E2. It is shown that the nonlinear biaxial buckling ratio decreases as the aspect ratio increases and vice versa for the buckling amplitude. Because of the most lightweight micro-composite materials with high strength/weight and stiffness/weight ratios, it is anticipated that the results of the present work are useful in experimental characterization of the mechanical properties of micro-composite plates in the aircraft industry and other engineering applications.
基金supported by the Henan International Science and Technology Cooperation Program(No.242102521055)the Japan Science and Technology Agency(No.JPMJCR2092)the Japan Society for the Promotion of Science(Nos.JP24H00283,JP24K21575,and JP22K18754)。
文摘This study investigates the surface effects on the operation of double-ended dislocation sources in single-crystal micropillars under compression.A comprehensive theoretical framework is formulated to derive the stress field of the source segment and the corresponding Peach-Koehler(PK)forces acting on this segment near the free surfaces.An analytical formulation is then developed to compare the source strength with and without the influence of the surface stress.The results reveal that the surface effects on the dislocation source strength are highly sensitive to the interplay between the source length and its distance from the free surface.These surface effects can either enhance or reduce the critical stress required for the source operation by up to 50%,leading to significant fluctuations in yield strength,as commonly observed in discrete dislocation dynamics simulations and experimental studies.These findings provide different interpretations for the size-dependent and stochastic yield stress behavior in face-centered cubic(FCC)micropillars.
基金supported by grants from the National Basic Research Program of China(No.2011CB503804)the National Natural Science Foundation of China(No.81372967)
文摘Summary: The contribution of particles to cardiovascular mortality and morbidity has been enlightened by epidemiologic and experimental studies. However, adverse biological effects of the particles with different sizes on cardiovascular cells have not been well recognized. In this study, sub-cultured human umbilical vein endothelial cells (HUVECs) were exposed to increasing concentrations of pure quartz particles (DQ) of three sizes (DQPM1, 〈1 μm; DQPM3-5, 3-5 μm; DQPM5, 5 μm) and carbon black particles of two sizes (CB0.1, 〈0.1 μm; CB 1, 〈 1 μm) for 24 h. Cytotoxicity was estimated by measuring the activity of lactate dehydrogenase (LDH) and cell viability. Nitric oxide (NO) generation and cyto- kines (TNF-α and IL-1β) releases were analyzed by using NO assay and enzyme-linked immunoabsorbent assay (ELISA), respectively. It was found that both particles induced adverse biological effects on HUVECs in a dose-dependent manner. The size of particle directly influenced the biological activity. For quartz, the smaller particles induced stronger cytotoxicity and higher levels of cytokine responses than those particles of big size. For carbon black particles, CB0.1 was more capable of inducing adverse responses on HUVECs than CB 1 only at lower particle concentrations, in contrast to those at higher concentrations. Meanwhile, our data also revealed that quartz particles performed stronger cell damage and produced higher levels of TNF-α than carbon black particles, even if particles size was similar. In conclusion, particle size as well as particle composition should be both considered in assessing vascular endothelial cells injury and inflammation responses induced by particles.
基金financially supported by the National Natural Science Foundation of China (No. 51771147)
文摘Al-Mg-Si-Sc alloys with different Mg/Si ratio(<1.73 in wt.% vs>1.73 in wt.%) and different grain size(coarse grains vs ultrafine grains) were prepared, which allowed to investigate the grain size-dependent Mg/Si ratio effect on the microstructural evolution and concomitantly on the hardness and electrical conductivity when subjected to aging at 200℃. In the coarse-grained Al-Mg-Sc-Sc alloys, the β" precipitation within the grain interior and also the precipitation hardening were highly dependent on the Mg/Si ratio,while the electrical conductivity was slightly affected by the Mg/Si ratio. A promoted β" precipitation was found in the case of Si excess(Mg/Si ratio <1.73), much greater than in the case of Mg excess(Mg/Si ratio>1.73). While in the ultrafine-grained Al-Mg-Si-Sc alloys, the electrical conductivity rather than the hardness was more sensitive to the Mg/Si ratio. The alloy with Si excess displayed electrical conductivity much higher than its counterpart with Mg excess. This is rationalized by the grain boundary precipitation promoted by Si, which reduced the solute atoms and precipitates within the grain interior. Age softening was found in the ultrafine-grained alloy with Si excess, but the ultrafine-grained alloy with Mg excess held the hardness almost unchanged during the aging. The hardness-conductivity correlation is comprehensively discussed by considering the coupling effect of Mg/Si ratio and grain size. A strategy to simultaneously increase the hardness/strength and electrical conductivity is proposed for the Al-Mg-SiSc alloys, based on present understanding of the predominant factors on strengthening and conductivity,respectively.
基金The National Science and Technology Major Project(No.2017ZX05009-003)the National Key Research and Development Program of China(No.2017YFC0307604)the Talent Foundation of China University of Petroleum(No.Y1215042)。
文摘A size-dependent continuum-based model is developed for the functionally graded(FG)Timoshenko micro-beams with viscoelastic properties,in which material parameters vary according to the power law along its axial direction.The size effect is incorporated by employing the modified couple stress theory and Kelvin-Voigt viscoelastic model,so that viscous components are included in the stress and the deviatoric segments of the symmetric couple stress tensors.The components of strain,curvature,stress and couple stress are formulated by combining them with the Timoshenko beam theory.Based on the Hamilton principle,the governing differential equations and boundary conditions for the micro-beam are expressed with arbitrary beam section shape and arbitrary type of loads.The size effect,FG effect,Poisson effect,and the influence of the beam section shape on the mechanical behaviors of viscoelastic FG micro-beams are investigated by taking the simply supported micro-beam subjected to point load as an example.Results show that the size effect on deflection,normal stress and couple stress are obvious when the size of the micro-beam is small enough,and the FG effects are obvious when the size of the micro-beam is large enough.Moreover,the Poisson ratio influences the size effect significantly and the beam section shape is also an important factor influencing the mechanical behavior of the micro-beam.
基金the State Key Development Program for Basic Research of China(Grant No.2017YFA0304300)the Key-Area Research and Development Program of Guangdong Province,China(Grant No.2020B0303030001)+1 种基金the National Natural Science Foundation of China(Grant No.T2121001)the Strategic Priority Research Program of Chinese Academy of Sciences(Grant No.XDB28000000).
文摘The non-Hermitian systems with the non-Hermitian skin effect(NHSE)are very sensitive to the imposed boundary conditions and lattice sizes,which lead to size-dependent non-Hermitian skin effects.Here,we report the experimental observation of NHSE with different boundary conditions and different lattice sizes in the unidirectional hopping model based on a circuit platform.The circuit admittance spectra and corresponding eigenstates are very sensitive to the presence of the boundary.Meanwhile,our experimental results show how the lattice sizes and boundary terms together affect the strength of NHSE.Therefore,our electric circuit provides a good platform to observe size-dependent boundary effects in non-Hermitian systems.
基金supported by the National Natural Science Foundation of China (Grant Nos.51722104,51625103,51790482,and 51761135031)the National Key Research and Development Program of China (2017YFA0700701)+3 种基金the 111 Project 2.0 of China(BP2018008)the Fok Ying-Tong Education Foundation (161096)the Fundamental Research Funds for the Central Universitiessupported by the Fundamental Research Funds for the Central Universities (xzy022019071)。
文摘Metastable high entropy alloys(HEAs) and amorphous metallic glasses(MGs), with the chemical disordered character, are intensively studied due to their excellent performance. Here, we introduce Cu to separately constrain these two metastable materials and comparatively investigate their deformation behaviors and mechanical properties of Cu/HEA Fe Co Cr Ni and Cu/MG Cu Zr nanolaminated micropillars in terms of intrinsic layer thickness h and extrinsic pillar diameter D. The metastable HEA layers, as the hard phase in Cu/HEA micropillars, are stable and dominate the deformation, while transformation(crystallization) occurs in MG which plays a minor role in deformation of Cu/MG micropillars. The h-controlled deformation mode transits from the D-independent homogenous-like deformation at large h to the Ddependent shear banding at small h in both Cu/HEA and Cu/MG micropillars. Although both Cu/HEA and Cu/MG micropillars exhibit a maximum strain hardening capability controlled by h, the former manifests much lower hardening capability compared with the latter. The intrinsic size h and extrinsic size D have a strong coupling effect on the strength of Cu/HEA and Cu/MG micropillars. The strength of strength of Cu/HEA micropillars exhibits the D-dependent transition from "smaller is stronger" to "smaller is weaker"with increasing h. By contrast, the strength of Cu/MG micropillars exhibits the transition from bulk-like D-independent behavior at large h to small volume D-dependent behavior(smaller is stronger) at small h.
基金financial support from the National Natural Science Foundation of China (NSFC-21776251, 21625604, 21671172 and 91934302)。
文摘Electrochemical ozone production(EOP) via water electrolysis represents an attractive method for the generation of high-purity O3. Herein, the X-PtZn/Zn-N-C electrocatalysts show a strong structural sensitive behavior depends on the size of the PtZn nanoparticles and their EOP activity exhibits a volcano-type dependence for the O3 performance in neutral media. The 7.7-PtZn/Zn-N-C exhibits EOP current efficiency of 4.2%, and shows the prominent performance in the production of gaseous O3 with a value of 1647 ppb at 30 min, which is almost 4-fold compared to 2.2-Pt Zn/Zn-N-C. Based on the experiments and theoretical calculations, the performance of the EOP process was determined by the nanoparticle size-effect and the synergistic effect between the PtZn nanoparticles and atomically dispersed Zn-N-C. Furthermore, the fivemembered cyclic structure of O3 can be stabilized between the PtZn nanoparticle and the Zn-N-C support,indicating that O3 is produced at the interface.
基金financial support from the National Natural Science Foundation of China(11472242,11672264,and 11621062)the Zhejiang Provincial Natural Science Foundation(LZ17A020001)the Fundamental Research Funds for the Central Universities
文摘Piezoelectric superlattice is a potential component for nanoelectromechanical systems. Due to the strong nonlocal effect such as flexoelectric effect at interfaces, classical piezoelectric theory is unable to accurately describe the electromechanical response of piezoelectric superlattice at nanoscale scale. Based on the previous nonlocal thermodynamics theory with flexoelectric effect Liu et al. (2016), the size- dependent electromechanical properties of piezoelectric superlattices made of BaTiO3 (BTO) and PbTiO3 (PRO) layers are investigated systematically in the present work. Giant strain gradient is found near the interface between BTO and PTO layers, which leads to the significant enhancement of polarization in the superlattice due to the flexoelectric effect. For the piezoelectric BTO-PTO superlattices with different unit- cell sizes, the thickness of interface with nontrivial strain gradient is almost constant. The influence of strain gradient at the interface becomes significant when the size of superlattice decreases, As a result, a strong size dependence of electromechanical properties is predicted for the piezoelectric BTO-PTO superlattices, In particular, for the superlattices with a specific thickness ratio of BTO and PTO layers, the piezoelectric response can be several times larger than that of bulk structure. The present work demonstrates a practical wast to design the piezoelectric superlattices with high piezoelectric coefficient by using the nonlocal effect at nanoscale.
基金Project supported by the National Natural Science Foundation of China (No.52175095)。
文摘The incomplete understanding of nanoscale surface interactions arising from underlying atomistic long-range forces limits our ability to simulate and design their performance. In this paper, the surface elasticity is constructed from underlying atomistic nonlocal interactions in spherical nanoparticles. By introducing an intrinsic length scale,we quantify the surface region thickness, and demonstrate the progressive elastic modulus transition caused by asymmetric atomistic nonlocal interactions. The universal surface scaling law, relating the intrinsic length scale to the particle dimensions, is established, and a surface-dominated criterion is developed for quantifying the transition to the surfacedominated behaviors. The model is thoroughly validated through the molecular static simulations and experimental data with the material-specific intrinsic length constants.
基金Project supported by the National Key Research and Development Program of China(No.2022YFB3207100)Hubei Provincial Strategic Scientist Training Plan(No.2022EJD009)the Fundamental Research Funds for the Central Universities of China(No.2042023kf1041)。
文摘In this study,the thermodynamic behaviors of the intrinsic frequency and buckling temperature of rectangular plates of functionally graded materials(FGMs)are explored based on the modified couple stress theory(MCST)and the novel dual powerlaw scale distribution theory.The effects of linear,homogeneous,and non-homogeneous temperature fields on the frequency and buckling temperature of FGM microplates are evaluated in detail.The results show that the porosity greatly affects the mechanical properties of FGM plates,reducing their frequency and flexural temperature compared with non-porous plates.Different temperature profiles alter plate frequencies and buckling temperatures.The presence and pattern of scale effect parameters are also shown to be crucial for the mechanical response of FGM plates.The present research aims to provide precise guidelines for the micro-electro-mechanical system(MEMS)fabrication by elucidating the complex interplay between thermal,material,and structural factors that affect the performance of FGM plates in advanced applications.
基金supported by the National Key Research and Development Program of China(Grant No.2021YFB1714600)the National Natural Science Foundation of China(Grant No.52175095)the Young Top-Notch Talent Cultivation Program of Hubei Province of China.
文摘This paper examined how microstructure influences the homogenized thermal conductivity of cellular structures and revealed a surface-induced size-dependent effect.This effect is linked to the porous microstructural features of cellular structures,which stems from the degree of porosity and the distri-bution of the pores.Unlike the phonon-driven surface effect at the nanoscale,the macro-scale surface mechanism in thermal cellular structures is found to be the microstructure-induced changes in the heat conduction path based on fully resolved 3D numerical simulations.The surface region is determined by the microstructure,characterized by the intrinsic length.With the coupling between extrinsic and intrinsic length scales under the surface mechanism,a surface-enriched multiscale method was devel-oped to accurately capture the complex size-dependent thermal conductivity.The principle of scale separation required by classical multiscale methods is not necessary to be satisfied by the proposed multiscale method.The significant potential of the surface-enriched multiscale method was demon-strated through simulations of the effective thermal conductivity of a thin-walled metamaterial struc-ture.The surface-enriched multiscale method offers higher accuracy compared with the classical multiscale method and superior efficiency over high-fidelity finite element methods.
文摘Herein,3‑aminopropyltriethoxysilane(APTES)was used to modify F‑containing silica slag(SS)by simple grafting and served as a multifunctional barrier layer.The amino group(—NH2)in the amino‑modified SS(NH2‑SS)forms ligand bonds or hydrogen bonds with sulfur ions in lithium polysulfides(LiPSs),thus inhibiting the shuttle effect.Electrochemical analyses demonstrated that lithium‑sulfur(Li‑S)batteries employing the NH2‑SS interlayer exhibited discharge specific capacities of 1048 and 789 mAh·g^(-1) at 0.2C and 2C,respectively,and even at 4C,the initial discharge specific capacity remained at 590 mAh·g^(-1),outperforming the Li‑S battery with unmodified SS as the interlayer.
基金Project supported by the National Natural Science Foundation of China(No.12172169)。
文摘In this paper,a fractional-order kinematic model is utilized to capture the size-dependent static bending and free vibration responses of piezoelectric nanobeams.The general nonlocal strains in the Euler-Bernoulli piezoelectric beam are defined by a frame-invariant and dimensionally consistent Riesz-Caputo fractional-order derivatives.The strain energy,the work done by external loads,and the kinetic energy based on the fractional-order kinematic model are derived and expressed in explicit forms.The boundary conditions for the nonlocal Euler-Bernoulli beam are derived through variational principles.Furthermore,a finite element model for the fractional-order system is developed in order to obtain the numerical solutions to the integro-differential equations.The effects of the fractional order and the vibration order on the static bending and vibration responses of the Euler-Bernoulli piezoelectric beams are investigated numerically.The results from the present model are validated against the existing results in the literature,and it is demonstrated that they are theoretically consistent.Although this fractional finite element method(FEM)is presented in the context of a one-dimensional(1D)beam,it can be extended to higher dimensional fractional-order boundary value problems.
文摘Chitosan(CTS)was grafted onto the surface of amino‑functionalized silver chloride silicon dioxide(AgCl@SiO_(2)‑NH_(2))cores to obtain AgCl@SiO_(2)/CTS hybrid nanoparticles.The as‑obtained AgCl@SiO_(2)/CTS nanoparticles were chlorinated by NaClO solution to get AgCl@SiO_(2)/CTS‑based chloramine nano‑hybrid materials,denoted as AgCl@SiO_(2)/CTS‑Cl.A transmission electron microscope was used to observe the morphology of the as‑prepared samples AgCl@SiO_(2)/CTS and AgCl@SiO_(2)/CTS‑Cl.At the same time,an X‑ray diffractometer and an infrared spectroscope were utilized to characterize their crystal and chemical structures.Besides,ζpotentials were measured to elucidate the surface modification of AgCl nanoparticles by—NH_(2),the antibacterial mechanism of AgCl@SiO_(2)/CTS‑Cl was investigated by scanning electron microscopy,and Escherichia coli(E.coli)and Staphylococcus aureus(S.aureus)were used as the to‑be‑tested strains to evaluate the antimicrobial activity of samples AgCl@SiO_(2)/CTS and AgCl@SiO_(2)/CTS‑Cl.Findings demonstrate that sample AgCl@SiO_(2)/CTS exhibits a chain‑like structure ascribed to the interaction between—NH_(2),and each AgCl@SiO_(2)/CTS hybrid nanoparticle contains several AgCl cores.In the meantime,sample AgCl@SiO_(2)/CTS‑Cl exhibits excellent antibacterial activity against E.coli and S.aureus,which is attributed to the synergistic antibacterial effect of Ag^(+)and Cl^(-).Sample AgCl@SiO_(2)/CTS‑Cl with a dosage of 640.00μg·mL^(-1) could completely kill the two kinds of tested bacteria in 12 h of incubation;it retains a high antibacterial efficiency even after 10 cycles of antibacterial tests.
基金supported by the National Natural Science Foundation of China(No.62464010)Spring City Plan-Special Program for Young Talents(K202005007)+2 种基金Yunnan Talents Support Plan for Young Talents(XDYC-QNRC-2022-0482)Yunnan Local Colleges Applied Basic Research Projects(202101BA070001-138)Frontier Research Team of Kunming University 2023.
文摘Rechargeable Zn/Sn-air batteries have received considerable attention as promising energy storage devices.However,the electrochemical performance of these batteries is significantly constrained by the sluggish electrocatalytic reaction kinetics at the cathode.The integration of light energy into Zn/Sn-air batteries is a promising strategy for enhancing their performance.However,the photothermal and photoelectric effects generate heat in the battery under prolonged solar irradiation,leading to air cathode instability.This paper presents the first design and synthesis of Ni_(2)-1,5-diamino-4,8-dihydroxyanthraquinone(Ni_(2)DDA),an electronically conductiveπ-d conjugated metal-organic framework(MOF).Ni_(2)DDA exhibits both photoelectric and photothermal effects,with an optical band gap of~1.14 eV.Under illumination,Ni_(2)DDA achieves excellent oxygen evolution reaction performance(with an overpotential of 245 mV vs.reversible hydrogen electrode at 10 mA cm^(−2))and photothermal stability.These properties result from the synergy between the photoelectric and photothermal effects of Ni_(2)DDA.Upon integration into Zn/Sn-air batteries,Ni_(2)DDA ensures excellent cycling stability under light and exhibits remarkable performance in high-temperature environments up to 80℃.This study experimentally confirms the stable operation of photo-assisted Zn/Sn-air batteries under high-temperature conditions for the first time and provides novel insights into the application of electronically conductive MOFs in photoelectrocatalysis and photothermal catalysis.
基金supported by the National Research Foundation of Korea(NRF)funded by the Ministry of Science and ICT(MSIT)(No.RS-2022-00143178)the Ministry of Education(MOE)(Nos.2022R1A6A3A13053896 and 2022R1F1A1074616),Republic of Korea.
文摘Beam-tracking simulations have been extensively utilized in the study of collective beam instabilities in circular accelerators.Traditionally,many simulation codes have relied on central processing unit(CPU)-based methods,tracking on a single CPU core,or parallelizing the computation across multiple cores via the message passing interface(MPI).Although these approaches work well for single-bunch tracking,scaling them to multiple bunches significantly increases the computational load,which often necessitates the use of a dedicated multi-CPU cluster.To address this challenge,alternative methods leveraging General-Purpose computing on Graphics Processing Units(GPGPU)have been proposed,enabling tracking studies on a standalone desktop personal computer(PC).However,frequent CPU-GPU interactions,including data transfers and synchronization operations during tracking,can introduce communication overheads,potentially reducing the overall effectiveness of GPU-based computations.In this study,we propose a novel approach that eliminates this overhead by performing the entire tracking simulation process exclusively on the GPU,thereby enabling the simultaneous processing of all bunches and their macro-particles.Specifically,we introduce MBTRACK2-CUDA,a Compute Unified Device Architecture(CUDA)ported version of MBTRACK2,which facilitates efficient tracking of single-and multi-bunch collective effects by leveraging the full GPU-resident computation.
文摘The dried fruit of Forsythia suspensa(Oleaceae),also known as Forsythia,is a traditional Chinese medicinal herb known for its heat-clearing and detoxifying properties.It is used to disperse nodules,reduce swelling,remove toxins,clear heat,and alleviate wind-heat syndromes.It also has hepatoprotective,anti-inflammatory,antiviral,antibacterial,anticancer,antioxidant,antiaging,and anti-obesity effects,as well as potential therapeutic effects on Alzheimer’s disease and diabetic nephropathy.It is used to treat scrofula,mastitis,wind-heat common cold,and other ailments.The review summarizes the chemical constituents and pharmacological effects of F.suspensa,aiming to provide a scientific foundation for its future development,research,and clinical utilization.
基金Project supported by the National Natural Science Foundation of China(No.12172169)the Priority Academic Program Development of Jiangsu Higher Education Institutions。
文摘This paper extends the one-dimensional(1D)nonlocal strain gradient integral model(NStraGIM)to the two-dimensional(2D)Kirchhoff axisymmetric nanoplates,based on nonlocal strain gradient integral relations formulated along both the radial and circumferential directions.By transforming the proposed integral constitutive equations into the equivalent differential forms,complemented by the corresponding constitutive boundary conditions(CBCs),a well-posed mathematical formulation is established for analyzing the axisymmetric bending and buckling of annular/circular functionally graded(FG)sandwich nanoplates.The boundary conditions at the inner edge of a solid nanoplate are derived by L'H?spital's rule.The numerical solution is obtained by the generalized differential quadrature method(GDQM).The accuracy of the proposed model is validated through comparison with the data from the existing literature.A parameter study is conducted to demonstrate the effects of FG sandwich parameters,size parameters,and nonlocal gradient parameters.