As a natural biopolymer material,silk fibroin with unique mechanical properties can be used in the preparation of biocomposite hydrogels for strain sensors.But,the electromechanical properties of bio-composite hydroge...As a natural biopolymer material,silk fibroin with unique mechanical properties can be used in the preparation of biocomposite hydrogels for strain sensors.But,the electromechanical properties of bio-composite hydrogel strain sensors are still insufficient,such as the deterioration of electrical signals and low sensitivity,which need to develop a hydrogel with a stable transmission network for electric con-duction.Herein,a silk fibroin biocomposite hydrogel is prepared by incorporating tannic acid and MXene nanosheets into a polyacrylamide and silk fibroin double network.The electromechanical properties of hydrogels are improved by optimizing the proportion of material components.As a result,the double network structure and supramolecular interaction enhance the stretchability of hydrogels(692% fracture strain).The hydrogel also exhibits good biocompatibility and conductivity(0.85 S/m),which shows the application prospect in wearable sensors.The wireless strain sensor assembled by this biocomposite hy-drogel presents good portability and sensing performance,such as high sensitivity(gauge factor=6.04),wide working range(500% strain),and outstanding stability(1000 cycles at 100%strain).The results in-dicate that the hydrogel strain sensor can be used to monitor human body movement.The biocomposite hydrogel is expected to be applied in the field of wearable strain sensors,and this study can provide a new way for the design of flexible electronic materials.展开更多
With the rapid development of wearable electronic skin technology, flexible strain sensors have shown great application prospects in the fields of human motion and physiological signal detection, medical diagnostics, ...With the rapid development of wearable electronic skin technology, flexible strain sensors have shown great application prospects in the fields of human motion and physiological signal detection, medical diagnostics, and human-computer interaction owing to their outstanding sensing performance. This paper reports a strain sensor with synergistic conductive network, consisting of stable carbon nanotube dispersion (CNT) layer and brittle MXene layer by dip-coating and electrostatic self-assembly method, and breathable three-dimensional (3D) flexible substrate of thermoplastic polyurethane (TPU) fibrous membrane prepared through electrospinning technology. The MXene/CNT@PDA-TPU (MC@p-TPU) flexible strain sensor had excellent air permeability, wide operating range (0–450 %), high sensitivity (Gauge Factor, GFmax = 8089.7), ultra-low detection limit (0.05 %), rapid response and recovery times (40 ms/60 ms), and excellent cycle stability and durability (10,000 cycles). Given its superior strain sensing capabilities, this sensor can be applied in physiological signals detection, human motion pattern recognition, and driving exoskeleton robots. In addition, MC@p-TPU fibrous membrane also exhibited excellent photothermal conversion performance and can be used as a wearable photo-heater, which has far-reaching application potential in the photothermal therapy of human joint diseases.展开更多
The ZrO2 (9mol% Y2O3) coating was prepared evenly on the surface of MgO partially stabilized zirconia (Mg-PSZ) tube (oxygen sensor probe) by dipping the green Mg-PSZ tube in a ZrO2 (9mol% Y2O3) slurry and then co-fir...The ZrO2 (9mol% Y2O3) coating was prepared evenly on the surface of MgO partially stabilized zirconia (Mg-PSZ) tube (oxygen sensor probe) by dipping the green Mg-PSZ tube in a ZrO2 (9mol% Y2O3) slurry and then co-firing at 1750°C for 8 h. The double-cell method was employed to measure the electronic conductivity parameter and exam the reproducibility of the coated Mg- PSZ tube. The experimental results indicate that the good thermal shock resistance of the Mg-PSZ tube can be retained when the coating thickness is not more than 3.4 μm. The ZrO2 (9mol% Y2O3) coating reduces the electronic conductivity parameter remarka- bly, probably due to the lower electronic conductivity of Y2O,-stabilized ZrO2 than that of MgO-stabilized ZrO2. Moreover, the ZrO2 (9mol% Y2O3) coating can improve the reproducibility and accuracy of the Mg-PSZ tube significantly in the low oxygen measure- ment. The smooth surface feature and lower electronic conductivity of the coated Mg-PSZ tube should be responsible for this im- provement.展开更多
Polyvinyl alcohol(PVA)hydrogels doped with cyclohexane-1,2,3,4,5,6-hexacarboxylic acid(CHA)were successfully prepared during drying and swelling.Structural and morphological characterizations suggest the carboxyl and ...Polyvinyl alcohol(PVA)hydrogels doped with cyclohexane-1,2,3,4,5,6-hexacarboxylic acid(CHA)were successfully prepared during drying and swelling.Structural and morphological characterizations suggest the carboxyl and hydroxyl groups in the material undergo esterification during the preparation of the material,which contributes to the high transparency with 90%transmittance in the 400 to 800 nm range and robust mechanical properties of the material with a tensile strength at a break of 27.55 MPa.It is noteworthy that the bending and torsion angles exhibit a strong linear correlation with electrical resistance,enabling the monitoring of the bending motion state of each human body segment.展开更多
With several favorable properties,including flexibility,biocompatibility,and conductivity,conductive hydrogels are one of the most promising flexible sensing materials and are expected to be used in areas such as wear...With several favorable properties,including flexibility,biocompatibility,and conductivity,conductive hydrogels are one of the most promising flexible sensing materials and are expected to be used in areas such as wearable devices,health monitoring,and electronic skin.However,water in hydrogels freezes at sub-zero temperatures,which greatly affects the performance of hydrogels at low temperatures.Therefore,it remains a challenge to prepare conductive hydrogels that can maintain their performance at low temperatures.In this work,we developed a series of polyoxometalate-based anti-freezing hydrogels with high conductivity by constructing a semi-interpenetrating network using polyacrylamide and sodium alginate,and then introducing H_(3)PW_(12)O_(40)(HPW)and glycerol into it via a facile soaking strategy.Among the obtained anti-freezing hydrogels,PSWG-50%hydrogel has the proton conductivity of 0.325 S·cm^(−1) at room temperature and can maintain high proton conductivity over a wide temperature range from−20 to 65℃.Based on these advantages,PSWG-50%hydrogel has been used in flexible sensors to monitor human movement,such as limb bending.Whether in mild or cold environments,PSWG-50%hydrogel shows great potential in the field of flexible sensor.展开更多
The accurate measurement of volume fraction of oil-water two-phase flow on line is important in the oil field.This paper presents a new coaxial conductivity sensor for measuring the volume fraction of oil-water two-ph...The accurate measurement of volume fraction of oil-water two-phase flow on line is important in the oil field.This paper presents a new coaxial conductivity sensor for measuring the volume fraction of oil-water two-phase flow.This structure may get the more uniform sensitivity field and the vertical installation may get the more axial symmetry of the flow field,which improve the measurement accuracy.In order to minimize the influence of the edge effect,guard electrodes were designed.An anti-edge effect degree Ae was defined to optimize the length of the guard electrode.Different models of effective conductivity of two materials were used in calculating the oil volume fraction of oil-water two-phase flow.The experimental results indicate that Maxwell model is the best model under the condition of oil volume fraction less than 50%and the mean value of the calculation results using Maxwell model and Bruggeman model possesses higher accuracy in the range of oil volume fraction(50%-70%).The experimental results show that the sensor obtains similar measurement performance in both vertical upward and downward flow conditions.The accuracy of the sensor system is 2%when the oil volume fraction less than 50%,and the accuracy is about 5%when the oil volume fraction between 50%and 70%.展开更多
Flexible electronic technology has laid the foundation for complex human-computer interaction system,and has attracted great attention in the field of human motion detection and soft robotics.Graphene has received an ...Flexible electronic technology has laid the foundation for complex human-computer interaction system,and has attracted great attention in the field of human motion detection and soft robotics.Graphene has received an extensive attention due to its excellent electrical conductivity;however,how to use it to fabricate wearable flexible sensors with complex structures remains challenging.In this study,we studied the rheological behavior of graphene/polydimethylsiloxane ink and proposed an optimal graphene ratio,which makes the ink have an good printability and conductivity at the same time.Then,based on the theory of Peano fractal layout,we proposed a two-dimensional structure that can withstand multi-directional tension by replacing the traditional arris structure with the arc structure.After that,we manufactured circular arc fractal structure sensor by adjusting ink composition and printing structure through direct ink writing method.Finally,we evaluated the detection performance and repeatability of the sensor.This method provides a simple and effective solution for fabricating wearable flexible sensors and exhibits the potential to fabricate 3D complex flexible electronic devices.展开更多
The development of analytical methods for antibiotic detection has become crucial for public health.In this research,a novel and simple electrochemical sensor for sensitive detection of cefadroxil(CFL)antibiotic was d...The development of analytical methods for antibiotic detection has become crucial for public health.In this research,a novel and simple electrochemical sensor for sensitive detection of cefadroxil(CFL)antibiotic was developed.The glassy carbon electrode(GCE)was coated with cheap conductive carbon black VXC-72R that was decorated with tetrabutylammonium tetrafluoroborate(TBABF_(4)),to construct the electrochemical sensor TBABF_(4)/VXC-72R/GCE.It was found that CFL exhibited a reduction peak at approximately 0.22 V on TBABF_(4)/VXC-72R/GCE.TBABF_(4)/VXC-72R/GCE showed a linear response to CFL in a concentration range of 0.3-10.0μmol/L,with a detection limit of 0.2μmol/L(a signal-to-noise ratio of 3).TBABF_(4)/VXC-72R/GCE showed good reproducibility,high storage stability and anti-interference performance.Analytical applications for CFL detection in real lake water,pharmaceutical tablet and fetal bovine serum samples were achieved.展开更多
The hydrothermal synthesis of In_(2)O_(3)and CeO_(2)–In_(2)O_(3)is investigated as well as the properties of sensor layers based on these compounds.During the synthesis of In_(2)O_(3),intermediate products In(OH)_(3)...The hydrothermal synthesis of In_(2)O_(3)and CeO_(2)–In_(2)O_(3)is investigated as well as the properties of sensor layers based on these compounds.During the synthesis of In_(2)O_(3),intermediate products In(OH)_(3)and InOOH are formed,which are the precursors of stable cubic(c-In_(2)O_(3))and metastable rhombohedral(rh-In_(2)O_(3))phases,respectively.A transition from c-In_(2)O_(3)to rh-In_(2)O_(3)is observed with the addition of CeO_(2).The introduction of cerium into rh-In_(2)O_(3)results in a decrease in the sensor response to hydrogen,while it increases in composites based on c-In_(2)O_(3).The data on the sensor activity of the composites correlate with XPS results in which CeO_(2)causes a decrease in the concentrations of chemisorbed oxygen and oxygen vacancies in rh-In_(2)O_(3).The reverse situation is observed in composites based on c-In_(2)O_(3).Compared to In_(2)O_(3)and CeO_(2)–In_(2)O_(3)obtained by other methods,the synthesized composites demonstrate maximum response to H_(2)at low temperatures by 70–100℃,and have short response time(0.2–0.5 s),short recovery time(6–7 s),and long-term stability.A model is proposed for the dependence of sensitivity on the direction of electron transfer between In_(2)O_(3)and CeO_(2).展开更多
The complexity of application environment stimulates the development of wearable devices based on functional hydrogels.Among all the promising performances,self-healing and self-adhesion properties are ideal for hydro...The complexity of application environment stimulates the development of wearable devices based on functional hydrogels.Among all the promising performances,self-healing and self-adhesion properties are ideal for hydrogel sensors,which can guarantee good accuracy,comfort and long service life.However,it is still a challenge to achieve simultaneous self-healing and self-adhesion in different environments(in the air,underwater and at low temperatures).Herein,a feasible new strategy was successfully carried out to prepare a starch-based composite conductive organohydrogel based on the reversible borate ester bonds formed by complexing starch/polyvinyl alcohol(PVA)/tea polyphenol(TP)with borax,and multiple hydrogen-bond interactions among PVA,starch,TP and ethylene glycol(EG).Silver nanoparticles(Ag-NPs),reduced and stabilized by TP,and MWCNTs(multi-walled carbon nanotubes)were introduced into the cross-linking networks to endow the resulting PBSTCE organohydrogel with considerable antibacterial property and conductivity,respectively.The organohydrogel possessed rapid self-healing(HE(self-healing efficiency)=96.07%in 90 s,both in the air and underwater,also at-20℃),considerable self-adhesion(both in the air and underwater,also at-20℃),remarkable stretchability(814%of elongation),anti-freezing(-20℃)and moisture-retention abilities,antibacterial activity,sensitive pH/sugar-responsiveness,and plasticity.The strain sensor formed by the PBSTCE organohydrogel can not only effectively record large-scale human motions(e.g.finger/wrist/elbow bending,walking,etc.),but also accurately capture subtle motion changes(e.g.breathing,chewing,swallowing,speaking,smiling and frowning).Moreover,the self-healed organohydrogel sensor also exhibited almost invariable mechanical,electrical and sensing behaviors.This work demonstrates a feasible strategy to construct multifunctional starch-based organohy-drogels,and promotes their efficient,stable and eco-friendly application as flexible wearable devices.展开更多
The design and fabrication of conductive hydrogels with high stretchability,compressibility,self-healing properties and good adhesion remains a significant challenge.We have fabricated composite hydrogels by random po...The design and fabrication of conductive hydrogels with high stretchability,compressibility,self-healing properties and good adhesion remains a significant challenge.We have fabricated composite hydrogels by random polymerization of acrylic acid(AA)and dopamine(DA)in the presence of multi-walled carbon nanotubes(MWCNTs).The π-π interaction between DA and MWCNTs makes MWCNTs stably and homogenously dispersed in water.The fabricated PAA-PDA/CNT composite hydrogels possess relatively high mechanical strength(maximum Youngzs modulus:800 kPa)and can be stretched to 1280%strain and compressed to 80%strain.The multiple hydrogen bonding formed between functional groups of PAA-PDA and MWCNTs can effectively dissipate energy and quickly achieve self-healing.The composite hydrogels also show good adhesion and can easily adhere to various inorganic or organic surfaces.In addition,the hydrogel reveals stable strain sensitivity and can be used as skin sensors.展开更多
Methane is an explosive gas in coalmines and needs to be monitored by methane sensors.Conductivetype methane sensors are small,simple and stable,and they are very promising for mining safety or home safety application...Methane is an explosive gas in coalmines and needs to be monitored by methane sensors.Conductivetype methane sensors are small,simple and stable,and they are very promising for mining safety or home safety applications.They can even be employed in mining Internet of things if the power consumption can be lowered down to few milliwatts.Many researches of nanomaterialsbased conductive-type methane sensors have been reported recently.This review intends to present a comprehensive and critical summary on the recent progresses in the nanomaterials-based conductive-type methane sensors field.Many excellent methane-sensitive nanomaterials will be present,such as SnO2,ZnO,TiO2,WO3,carbon nanotubes,graphene,rare earth metal-based perovskite oxides and their hybrids.Particular attention is given to the synthetic methods of the nanomaterials,sensing mechanisms of the nanomaterials and the relationship between the sensing performance and the structures and components of the nanomaterials.Finally,the future trends and perspectives of nanomaterials-based conductive-type methane sensors are proposed.展开更多
Oil-gas-water three-phase flow in the pipe is commonly encountered in the petroleum and nature gas industry. Its flow patterns are complex and always changeable, so it’s difficult to be measured and is becoming one o...Oil-gas-water three-phase flow in the pipe is commonly encountered in the petroleum and nature gas industry. Its flow patterns are complex and always changeable, so it’s difficult to be measured and is becoming one of the most important subjects. Moreover, most of the oil fields in China are in such a high water fraction period that measures must be taken to meet the needs of the actual production. A conductance sensor which is widely used in the measurements of oil-water two-phase flow is used to measure the flow rate of the three-phase flow based on the research of the characteristics and the correlation theory, and a new technical solution which is suitable for measuring the oil-gas-water three-phase flow is established. A series of tests demonstrate that it’s feasible to use the conductance sensor in the measurements of oil- gas-water three-phase flow.展开更多
High density polyethylene filled with condutuctive carbon black was prepared by conventional meltmixing method. The effect of unidirectional pressure on the conductivity was studied. Wide angle X-ray diffraction （ WA...High density polyethylene filled with condutuctive carbon black was prepared by conventional meltmixing method. The effect of unidirectional pressure on the conductivity was studied. Wide angle X-ray diffraction （ WAXD ） was used to slum： the influence of pressure on the aggregate structure of the polymer filled with carbon black （CB） fillers. A model on the basis of the formation and destruction of conductive networks was proposed to explain the change in the conductivity with the application of pressure.展开更多
In this study,we proposed a self-healing conductive hydrogel based on polysaccharides and Li+to serve as flexible sensors.At first,the oxidized sodium alginate(OSA)was obtained through the oxidation reaction of sodium...In this study,we proposed a self-healing conductive hydrogel based on polysaccharides and Li+to serve as flexible sensors.At first,the oxidized sodium alginate(OSA)was obtained through the oxidation reaction of sodium alginate(SA).Then OSA,carboxymethyl chitosan(CMC),and agarose(AGO)were dissolved in LiCl solution,respectively.Finally,the hydrogel was obtained through heating,mixing,and cooling processes.Because of the Schiff base structure and hydrogen bonding,the hydrogel demonstrates good mechanical and self-healing properties.The presence of Li+provides good conductivity for the hydrogel.In addition,we demonstrated the application of the hydrogel as the flexible sensors.It can perceive the process of pressing Morse code with the index finger as a pressure sensor and monitor sliding movement of the thumb as the strain sensor to browse the web with the mobile phone.Thus,the selfhealing conductive hydrogel may have potential applications in flexible wearable sensors.展开更多
Compression force sensors are indispensable to tactile sensors in humanoid robots. We are investigating the application of low-cost electrically conducting rubber sheets to force sensors, of which the biggest problem ...Compression force sensors are indispensable to tactile sensors in humanoid robots. We are investigating the application of low-cost electrically conducting rubber sheets to force sensors, of which the biggest problem is its poor reproducibility. We have found that the deposition of aluminum by a vacuum evaporation method shows such an excellent characteristic that the sensor can be used in a wide range under 10.33 N/cm2. In this article, we investigated time response of the sensors and also studied how the radiation heating during the vacuum evaporation process for Al deposition affected their sensing property. We found that the radiation heating induces deterioration from the point of view of standard deviation of the output voltage of the sensors at a transient region. We convince that a low-temperature Al deposition method should be developed to form electrodes on the electrical conducting rubber sensors.展开更多
Tactile sensors are believed to be a key element in order to realize robotic fingers to catch a fragile object without damage. Force sensitive conductive rubber is a low-cost material and then attractive for the appli...Tactile sensors are believed to be a key element in order to realize robotic fingers to catch a fragile object without damage. Force sensitive conductive rubber is a low-cost material and then attractive for the application to tactile sensors. We have studied the effect of electrodes attached to the rubber sheets. We have tried four kinds of electrodes: vacuum deposited Al, adhesive Cu tape, Al thin film sheet and silver paste. It can be concluded that vacuum deposited Al has the highest potential from the practical point of view;it has the widest dynamic range and good precision at the same time.展开更多
Wearable and stretchable strain sensors have potential values in the fields of human motion and health monitoring,flexible electronics,and soft robotic skin.The wearable and stretchable strain sensors can be directly ...Wearable and stretchable strain sensors have potential values in the fields of human motion and health monitoring,flexible electronics,and soft robotic skin.The wearable and stretchable strain sensors can be directly attached to human skin,providing visualized detection for human motions and personal healthcare.Conductive polymer composites(CPC)composed of conductive fillers and flexible polymers have the advantages of high stretchability,good flexibility,superior durability,which can be used to prepare flexible strain sensors with large working strain and outstanding sensitivity.This review has put forward a comprehensive summary on the fabrication methods,advanced mechanisms and strain sensing abilities of CPC strain sensors reported in recent years,especially the sensors with superior performance.Finally,the structural design,bionic function,integration technology and further application of CPC strain sensors are prospected.展开更多
For advanced conductive hydrogels,adaptable mechanical properties and high conductivity are essential requirements for practical application,e.g.,soft electronic devices.Here,a straightforward strategy to develop a me...For advanced conductive hydrogels,adaptable mechanical properties and high conductivity are essential requirements for practical application,e.g.,soft electronic devices.Here,a straightforward strategy to develop a mechanically robust hydrogel with high conductivity by constructing complicated 3D structures composed of covalently cross-linked polymer network and two nanofillers with distinguishing dimensions is reported.The combination of one-dimensional quaternized cellulose nanofibrils(QACNF)and two-dimensional MXene nanosheets not only provides prominent and tunable mechanical properties modulated by materials composition,but results in electronically conductive path with high conductivity(1281 mS m^(-1)).Owing to the uniform interconnectivity of network structure attributed to the strong macro-molecular interaction and nano-reinforced effect,the resultant hydrogel exhibits a balanced mechanical feature,i.e.,high tensile strength(449 kPa),remarkable stretchability(>1700%),and ultra-high toughness(5.46 MJ m^(-3)),outperforming those of virgin one.Additionally,the enhanced conductive characteristic with the aid of QACNF enables hydrogels with impressive electromechanical behavior,containing high sensitivity(maximum gauge factor:2.24),wide working range(0-1465%),and fast response performance(response time:141 ms,recover time:140 ms).Benefiting from the excellent mechanical performance,a flexible strain sensor based on such conductive hydrogel can deliver an appealing sensing performance of monitoring multi-scale deformations,from large and monotonous mechanical deformation to tiny and complex physiological motions(e.g.,joint movement and signature/vocal recognition).Together,the hydrogel material in this work opens up opportunities in the design and fabrication of advanced gel-based materials for emerging wearable electronics.展开更多
Compressive force sensors or pressure sensors are indispensable to tactile sensors in humanoid robots. It is investigated that low-cost electro-conducting rubber sheets are applied to the force sensor, of which the bi...Compressive force sensors or pressure sensors are indispensable to tactile sensors in humanoid robots. It is investigated that low-cost electro-conducting rubber sheets are applied to the force sensor, of which the biggest problem is its poor reproducibility. It was found that the aluminum deposition by a vacuum evaporation method shows excellent characteristics but suffers deterioration by a radiation heating effect. The aluminum electrode was deposited by a sputtering method, known to have an advantage of a low-temperature method, and the reproducibility of the output was improved.展开更多
基金supported by the National Key Re-search and Development Program of China(No.2021YFA0715700)the National Natural Science Foundation of China(No.52003212).
文摘As a natural biopolymer material,silk fibroin with unique mechanical properties can be used in the preparation of biocomposite hydrogels for strain sensors.But,the electromechanical properties of bio-composite hydrogel strain sensors are still insufficient,such as the deterioration of electrical signals and low sensitivity,which need to develop a hydrogel with a stable transmission network for electric con-duction.Herein,a silk fibroin biocomposite hydrogel is prepared by incorporating tannic acid and MXene nanosheets into a polyacrylamide and silk fibroin double network.The electromechanical properties of hydrogels are improved by optimizing the proportion of material components.As a result,the double network structure and supramolecular interaction enhance the stretchability of hydrogels(692% fracture strain).The hydrogel also exhibits good biocompatibility and conductivity(0.85 S/m),which shows the application prospect in wearable sensors.The wireless strain sensor assembled by this biocomposite hy-drogel presents good portability and sensing performance,such as high sensitivity(gauge factor=6.04),wide working range(500% strain),and outstanding stability(1000 cycles at 100%strain).The results in-dicate that the hydrogel strain sensor can be used to monitor human body movement.The biocomposite hydrogel is expected to be applied in the field of wearable strain sensors,and this study can provide a new way for the design of flexible electronic materials.
基金supported by the National Natural Science Foundation of China(Nos.52373093 and 12072325)the Outstanding Youth Fund of Henan Province(No.242300421062)+1 种基金National Key R&D Program of China(No.2019YFA0706802)the 111 project(No.D18023).
文摘With the rapid development of wearable electronic skin technology, flexible strain sensors have shown great application prospects in the fields of human motion and physiological signal detection, medical diagnostics, and human-computer interaction owing to their outstanding sensing performance. This paper reports a strain sensor with synergistic conductive network, consisting of stable carbon nanotube dispersion (CNT) layer and brittle MXene layer by dip-coating and electrostatic self-assembly method, and breathable three-dimensional (3D) flexible substrate of thermoplastic polyurethane (TPU) fibrous membrane prepared through electrospinning technology. The MXene/CNT@PDA-TPU (MC@p-TPU) flexible strain sensor had excellent air permeability, wide operating range (0–450 %), high sensitivity (Gauge Factor, GFmax = 8089.7), ultra-low detection limit (0.05 %), rapid response and recovery times (40 ms/60 ms), and excellent cycle stability and durability (10,000 cycles). Given its superior strain sensing capabilities, this sensor can be applied in physiological signals detection, human motion pattern recognition, and driving exoskeleton robots. In addition, MC@p-TPU fibrous membrane also exhibited excellent photothermal conversion performance and can be used as a wearable photo-heater, which has far-reaching application potential in the photothermal therapy of human joint diseases.
文摘The ZrO2 (9mol% Y2O3) coating was prepared evenly on the surface of MgO partially stabilized zirconia (Mg-PSZ) tube (oxygen sensor probe) by dipping the green Mg-PSZ tube in a ZrO2 (9mol% Y2O3) slurry and then co-firing at 1750°C for 8 h. The double-cell method was employed to measure the electronic conductivity parameter and exam the reproducibility of the coated Mg- PSZ tube. The experimental results indicate that the good thermal shock resistance of the Mg-PSZ tube can be retained when the coating thickness is not more than 3.4 μm. The ZrO2 (9mol% Y2O3) coating reduces the electronic conductivity parameter remarka- bly, probably due to the lower electronic conductivity of Y2O,-stabilized ZrO2 than that of MgO-stabilized ZrO2. Moreover, the ZrO2 (9mol% Y2O3) coating can improve the reproducibility and accuracy of the Mg-PSZ tube significantly in the low oxygen measure- ment. The smooth surface feature and lower electronic conductivity of the coated Mg-PSZ tube should be responsible for this im- provement.
基金Funded by the National Natural Science Foundation of China(No.22005151)the Natural Science Foundation of Nanjing University of Posts and Telecommunications(No.NY220127)。
文摘Polyvinyl alcohol(PVA)hydrogels doped with cyclohexane-1,2,3,4,5,6-hexacarboxylic acid(CHA)were successfully prepared during drying and swelling.Structural and morphological characterizations suggest the carboxyl and hydroxyl groups in the material undergo esterification during the preparation of the material,which contributes to the high transparency with 90%transmittance in the 400 to 800 nm range and robust mechanical properties of the material with a tensile strength at a break of 27.55 MPa.It is noteworthy that the bending and torsion angles exhibit a strong linear correlation with electrical resistance,enabling the monitoring of the bending motion state of each human body segment.
基金supported by the National Natural Science Foundation of China(22071019,21872021 and 21671033).
文摘With several favorable properties,including flexibility,biocompatibility,and conductivity,conductive hydrogels are one of the most promising flexible sensing materials and are expected to be used in areas such as wearable devices,health monitoring,and electronic skin.However,water in hydrogels freezes at sub-zero temperatures,which greatly affects the performance of hydrogels at low temperatures.Therefore,it remains a challenge to prepare conductive hydrogels that can maintain their performance at low temperatures.In this work,we developed a series of polyoxometalate-based anti-freezing hydrogels with high conductivity by constructing a semi-interpenetrating network using polyacrylamide and sodium alginate,and then introducing H_(3)PW_(12)O_(40)(HPW)and glycerol into it via a facile soaking strategy.Among the obtained anti-freezing hydrogels,PSWG-50%hydrogel has the proton conductivity of 0.325 S·cm^(−1) at room temperature and can maintain high proton conductivity over a wide temperature range from−20 to 65℃.Based on these advantages,PSWG-50%hydrogel has been used in flexible sensors to monitor human movement,such as limb bending.Whether in mild or cold environments,PSWG-50%hydrogel shows great potential in the field of flexible sensor.
基金supported by National Natural Science Foundation of China(Grant No.61072101)Program for New Century Excellent Talents in University(Grant No.NCET-10-0621)the Independent Innovation Foundation of Tianjin University
文摘The accurate measurement of volume fraction of oil-water two-phase flow on line is important in the oil field.This paper presents a new coaxial conductivity sensor for measuring the volume fraction of oil-water two-phase flow.This structure may get the more uniform sensitivity field and the vertical installation may get the more axial symmetry of the flow field,which improve the measurement accuracy.In order to minimize the influence of the edge effect,guard electrodes were designed.An anti-edge effect degree Ae was defined to optimize the length of the guard electrode.Different models of effective conductivity of two materials were used in calculating the oil volume fraction of oil-water two-phase flow.The experimental results indicate that Maxwell model is the best model under the condition of oil volume fraction less than 50%and the mean value of the calculation results using Maxwell model and Bruggeman model possesses higher accuracy in the range of oil volume fraction(50%-70%).The experimental results show that the sensor obtains similar measurement performance in both vertical upward and downward flow conditions.The accuracy of the sensor system is 2%when the oil volume fraction less than 50%,and the accuracy is about 5%when the oil volume fraction between 50%and 70%.
基金the National Key Research and Development Program of China(No.2020YFB1313100)the Strategic Priority Research Program of the Chinese Academy of Sciences(No.XDA16020803)+2 种基金the National Natural Science Foundation of China(Nos.51875557 and 52205319)the Research Equipment Development Program of the Chinese Academy of Sciences(No.YJKYYQ20190045)the Foundation of State Key Laboratory of Robotics(Nos.2021-Z01,2022-Z04 and 2023-Z01)。
文摘Flexible electronic technology has laid the foundation for complex human-computer interaction system,and has attracted great attention in the field of human motion detection and soft robotics.Graphene has received an extensive attention due to its excellent electrical conductivity;however,how to use it to fabricate wearable flexible sensors with complex structures remains challenging.In this study,we studied the rheological behavior of graphene/polydimethylsiloxane ink and proposed an optimal graphene ratio,which makes the ink have an good printability and conductivity at the same time.Then,based on the theory of Peano fractal layout,we proposed a two-dimensional structure that can withstand multi-directional tension by replacing the traditional arris structure with the arc structure.After that,we manufactured circular arc fractal structure sensor by adjusting ink composition and printing structure through direct ink writing method.Finally,we evaluated the detection performance and repeatability of the sensor.This method provides a simple and effective solution for fabricating wearable flexible sensors and exhibits the potential to fabricate 3D complex flexible electronic devices.
基金Research Foundation from National Innovation Center of Advanced Dyeing&Finishing Technology,China(No.2022GCJJ10)。
文摘The development of analytical methods for antibiotic detection has become crucial for public health.In this research,a novel and simple electrochemical sensor for sensitive detection of cefadroxil(CFL)antibiotic was developed.The glassy carbon electrode(GCE)was coated with cheap conductive carbon black VXC-72R that was decorated with tetrabutylammonium tetrafluoroborate(TBABF_(4)),to construct the electrochemical sensor TBABF_(4)/VXC-72R/GCE.It was found that CFL exhibited a reduction peak at approximately 0.22 V on TBABF_(4)/VXC-72R/GCE.TBABF_(4)/VXC-72R/GCE showed a linear response to CFL in a concentration range of 0.3-10.0μmol/L,with a detection limit of 0.2μmol/L(a signal-to-noise ratio of 3).TBABF_(4)/VXC-72R/GCE showed good reproducibility,high storage stability and anti-interference performance.Analytical applications for CFL detection in real lake water,pharmaceutical tablet and fetal bovine serum samples were achieved.
基金supported by the Russian Science Foundation(grant No.22-19-00037),https://rscf.ru/project/22-19-00037/.
文摘The hydrothermal synthesis of In_(2)O_(3)and CeO_(2)–In_(2)O_(3)is investigated as well as the properties of sensor layers based on these compounds.During the synthesis of In_(2)O_(3),intermediate products In(OH)_(3)and InOOH are formed,which are the precursors of stable cubic(c-In_(2)O_(3))and metastable rhombohedral(rh-In_(2)O_(3))phases,respectively.A transition from c-In_(2)O_(3)to rh-In_(2)O_(3)is observed with the addition of CeO_(2).The introduction of cerium into rh-In_(2)O_(3)results in a decrease in the sensor response to hydrogen,while it increases in composites based on c-In_(2)O_(3).The data on the sensor activity of the composites correlate with XPS results in which CeO_(2)causes a decrease in the concentrations of chemisorbed oxygen and oxygen vacancies in rh-In_(2)O_(3).The reverse situation is observed in composites based on c-In_(2)O_(3).Compared to In_(2)O_(3)and CeO_(2)–In_(2)O_(3)obtained by other methods,the synthesized composites demonstrate maximum response to H_(2)at low temperatures by 70–100℃,and have short response time(0.2–0.5 s),short recovery time(6–7 s),and long-term stability.A model is proposed for the dependence of sensitivity on the direction of electron transfer between In_(2)O_(3)and CeO_(2).
基金This work is financed by the National Natural Science Founda-tion of China(No.21978180).We appreciate the valuable help of Dr.Jinwei Zhang from the College of Biomass Science and Engineering of Sichuan University and Hui Wang from the Analytical&Testing Center of Sichuan University.We thank eceshi(www.eceshi.com)for the great help in SEM analysis.
文摘The complexity of application environment stimulates the development of wearable devices based on functional hydrogels.Among all the promising performances,self-healing and self-adhesion properties are ideal for hydrogel sensors,which can guarantee good accuracy,comfort and long service life.However,it is still a challenge to achieve simultaneous self-healing and self-adhesion in different environments(in the air,underwater and at low temperatures).Herein,a feasible new strategy was successfully carried out to prepare a starch-based composite conductive organohydrogel based on the reversible borate ester bonds formed by complexing starch/polyvinyl alcohol(PVA)/tea polyphenol(TP)with borax,and multiple hydrogen-bond interactions among PVA,starch,TP and ethylene glycol(EG).Silver nanoparticles(Ag-NPs),reduced and stabilized by TP,and MWCNTs(multi-walled carbon nanotubes)were introduced into the cross-linking networks to endow the resulting PBSTCE organohydrogel with considerable antibacterial property and conductivity,respectively.The organohydrogel possessed rapid self-healing(HE(self-healing efficiency)=96.07%in 90 s,both in the air and underwater,also at-20℃),considerable self-adhesion(both in the air and underwater,also at-20℃),remarkable stretchability(814%of elongation),anti-freezing(-20℃)and moisture-retention abilities,antibacterial activity,sensitive pH/sugar-responsiveness,and plasticity.The strain sensor formed by the PBSTCE organohydrogel can not only effectively record large-scale human motions(e.g.finger/wrist/elbow bending,walking,etc.),but also accurately capture subtle motion changes(e.g.breathing,chewing,swallowing,speaking,smiling and frowning).Moreover,the self-healed organohydrogel sensor also exhibited almost invariable mechanical,electrical and sensing behaviors.This work demonstrates a feasible strategy to construct multifunctional starch-based organohy-drogels,and promotes their efficient,stable and eco-friendly application as flexible wearable devices.
基金the Introduction and Cultivation Plan of Young Innovative Talents in Colleges and Universities of Shandong Province,the Shandong Key R&D Program(No.2019GSF109050)Research Leader Foundation of"20 Policies of Colleges and Universities"of Jinan City(No.2018GXRC027)the National Natural Science Foundation of China(No.31670590).
文摘The design and fabrication of conductive hydrogels with high stretchability,compressibility,self-healing properties and good adhesion remains a significant challenge.We have fabricated composite hydrogels by random polymerization of acrylic acid(AA)and dopamine(DA)in the presence of multi-walled carbon nanotubes(MWCNTs).The π-π interaction between DA and MWCNTs makes MWCNTs stably and homogenously dispersed in water.The fabricated PAA-PDA/CNT composite hydrogels possess relatively high mechanical strength(maximum Youngzs modulus:800 kPa)and can be stretched to 1280%strain and compressed to 80%strain.The multiple hydrogen bonding formed between functional groups of PAA-PDA and MWCNTs can effectively dissipate energy and quickly achieve self-healing.The composite hydrogels also show good adhesion and can easily adhere to various inorganic or organic surfaces.In addition,the hydrogel reveals stable strain sensitivity and can be used as skin sensors.
基金financially supported by the Fundamental Research Funds for the Central Universities(No.2020QN69)。
文摘Methane is an explosive gas in coalmines and needs to be monitored by methane sensors.Conductivetype methane sensors are small,simple and stable,and they are very promising for mining safety or home safety applications.They can even be employed in mining Internet of things if the power consumption can be lowered down to few milliwatts.Many researches of nanomaterialsbased conductive-type methane sensors have been reported recently.This review intends to present a comprehensive and critical summary on the recent progresses in the nanomaterials-based conductive-type methane sensors field.Many excellent methane-sensitive nanomaterials will be present,such as SnO2,ZnO,TiO2,WO3,carbon nanotubes,graphene,rare earth metal-based perovskite oxides and their hybrids.Particular attention is given to the synthetic methods of the nanomaterials,sensing mechanisms of the nanomaterials and the relationship between the sensing performance and the structures and components of the nanomaterials.Finally,the future trends and perspectives of nanomaterials-based conductive-type methane sensors are proposed.
文摘Oil-gas-water three-phase flow in the pipe is commonly encountered in the petroleum and nature gas industry. Its flow patterns are complex and always changeable, so it’s difficult to be measured and is becoming one of the most important subjects. Moreover, most of the oil fields in China are in such a high water fraction period that measures must be taken to meet the needs of the actual production. A conductance sensor which is widely used in the measurements of oil-water two-phase flow is used to measure the flow rate of the three-phase flow based on the research of the characteristics and the correlation theory, and a new technical solution which is suitable for measuring the oil-gas-water three-phase flow is established. A series of tests demonstrate that it’s feasible to use the conductance sensor in the measurements of oil- gas-water three-phase flow.
文摘High density polyethylene filled with condutuctive carbon black was prepared by conventional meltmixing method. The effect of unidirectional pressure on the conductivity was studied. Wide angle X-ray diffraction （ WAXD ） was used to slum： the influence of pressure on the aggregate structure of the polymer filled with carbon black （CB） fillers. A model on the basis of the formation and destruction of conductive networks was proposed to explain the change in the conductivity with the application of pressure.
基金support from National Natural Science Foundation of China(51873009)Beijing Natural Science Foundation(2192042).
文摘In this study,we proposed a self-healing conductive hydrogel based on polysaccharides and Li+to serve as flexible sensors.At first,the oxidized sodium alginate(OSA)was obtained through the oxidation reaction of sodium alginate(SA).Then OSA,carboxymethyl chitosan(CMC),and agarose(AGO)were dissolved in LiCl solution,respectively.Finally,the hydrogel was obtained through heating,mixing,and cooling processes.Because of the Schiff base structure and hydrogen bonding,the hydrogel demonstrates good mechanical and self-healing properties.The presence of Li+provides good conductivity for the hydrogel.In addition,we demonstrated the application of the hydrogel as the flexible sensors.It can perceive the process of pressing Morse code with the index finger as a pressure sensor and monitor sliding movement of the thumb as the strain sensor to browse the web with the mobile phone.Thus,the selfhealing conductive hydrogel may have potential applications in flexible wearable sensors.
文摘Compression force sensors are indispensable to tactile sensors in humanoid robots. We are investigating the application of low-cost electrically conducting rubber sheets to force sensors, of which the biggest problem is its poor reproducibility. We have found that the deposition of aluminum by a vacuum evaporation method shows such an excellent characteristic that the sensor can be used in a wide range under 10.33 N/cm2. In this article, we investigated time response of the sensors and also studied how the radiation heating during the vacuum evaporation process for Al deposition affected their sensing property. We found that the radiation heating induces deterioration from the point of view of standard deviation of the output voltage of the sensors at a transient region. We convince that a low-temperature Al deposition method should be developed to form electrodes on the electrical conducting rubber sensors.
文摘Tactile sensors are believed to be a key element in order to realize robotic fingers to catch a fragile object without damage. Force sensitive conductive rubber is a low-cost material and then attractive for the application to tactile sensors. We have studied the effect of electrodes attached to the rubber sheets. We have tried four kinds of electrodes: vacuum deposited Al, adhesive Cu tape, Al thin film sheet and silver paste. It can be concluded that vacuum deposited Al has the highest potential from the practical point of view;it has the widest dynamic range and good precision at the same time.
基金supported by the Basic Science Research Program through the National Research Foundation of Korea(NRF)funded by the Ministry of Education(NRF-2021R1A2C1008380)Nano Material Technology Development Program[NRF-2015M3A7B6027970]+1 种基金the Chey Institute for Advanced Studies'International Scholar Exchange Fellowship for the academic year of 2021-2022supported by the Korea Institute of Energy Technology Evaluation and Planning(KETEP)grant funded by the Korea government(MOTIE)(20215710100170).
文摘Wearable and stretchable strain sensors have potential values in the fields of human motion and health monitoring,flexible electronics,and soft robotic skin.The wearable and stretchable strain sensors can be directly attached to human skin,providing visualized detection for human motions and personal healthcare.Conductive polymer composites(CPC)composed of conductive fillers and flexible polymers have the advantages of high stretchability,good flexibility,superior durability,which can be used to prepare flexible strain sensors with large working strain and outstanding sensitivity.This review has put forward a comprehensive summary on the fabrication methods,advanced mechanisms and strain sensing abilities of CPC strain sensors reported in recent years,especially the sensors with superior performance.Finally,the structural design,bionic function,integration technology and further application of CPC strain sensors are prospected.
基金supported by the National Natural Science Foundation of China(Nos.52203148,51973047,and 12002113)the Research Foundation of Talented Scholars of Zhejiang A&F University(Nos.2020FR070 and 2021FR024)+1 种基金the Zhejiang A&F University Scientific Research Training Program for Undergraduates(No.S202210341186)the Key Research and Development Program of Shaanxi(No.2022-JBGS3-09).
文摘For advanced conductive hydrogels,adaptable mechanical properties and high conductivity are essential requirements for practical application,e.g.,soft electronic devices.Here,a straightforward strategy to develop a mechanically robust hydrogel with high conductivity by constructing complicated 3D structures composed of covalently cross-linked polymer network and two nanofillers with distinguishing dimensions is reported.The combination of one-dimensional quaternized cellulose nanofibrils(QACNF)and two-dimensional MXene nanosheets not only provides prominent and tunable mechanical properties modulated by materials composition,but results in electronically conductive path with high conductivity(1281 mS m^(-1)).Owing to the uniform interconnectivity of network structure attributed to the strong macro-molecular interaction and nano-reinforced effect,the resultant hydrogel exhibits a balanced mechanical feature,i.e.,high tensile strength(449 kPa),remarkable stretchability(>1700%),and ultra-high toughness(5.46 MJ m^(-3)),outperforming those of virgin one.Additionally,the enhanced conductive characteristic with the aid of QACNF enables hydrogels with impressive electromechanical behavior,containing high sensitivity(maximum gauge factor:2.24),wide working range(0-1465%),and fast response performance(response time:141 ms,recover time:140 ms).Benefiting from the excellent mechanical performance,a flexible strain sensor based on such conductive hydrogel can deliver an appealing sensing performance of monitoring multi-scale deformations,from large and monotonous mechanical deformation to tiny and complex physiological motions(e.g.,joint movement and signature/vocal recognition).Together,the hydrogel material in this work opens up opportunities in the design and fabrication of advanced gel-based materials for emerging wearable electronics.
文摘Compressive force sensors or pressure sensors are indispensable to tactile sensors in humanoid robots. It is investigated that low-cost electro-conducting rubber sheets are applied to the force sensor, of which the biggest problem is its poor reproducibility. It was found that the aluminum deposition by a vacuum evaporation method shows excellent characteristics but suffers deterioration by a radiation heating effect. The aluminum electrode was deposited by a sputtering method, known to have an advantage of a low-temperature method, and the reproducibility of the output was improved.
