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Revisiting Active Sites for Nitrogen Reduction Reaction on 2D Materials Supported Metal Atoms: A Theoretical Investigation
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作者 Mingxin Qin Wenhua Zhang 《Chinese Journal of Chemical Physics》 2025年第3期311-322,I0025-I0036,I0109,共25页
Single atom catalysts supported by two-dimensional(2D)materials,including graphene,g-C_(3)N_(4),and graphdiyne,ex-hibit promising electrocatalytic nitrogen reduction reaction(NRR)activity.Nevertheless,sometimes theore... Single atom catalysts supported by two-dimensional(2D)materials,including graphene,g-C_(3)N_(4),and graphdiyne,ex-hibit promising electrocatalytic nitrogen reduction reaction(NRR)activity.Nevertheless,sometimes theoretical works failed to predict the high activity of NRR of single atom cat-alysts,especially for Fe,Co,Mn,Cu,Ru.In this work,based on DFT calculations,it is suggested that dual-atom sites on N doped graphene(M_(2)@N-graphene)rather than single-atom sites are more likely to be the active sites for NRR.Notably,Fe_(2)@N_(3),Co_(2)@N_(2),Mn_(2)@N_(2),Cu_(2)@N_(1),and Ru_(2)@N_(3)endow the best catalytic activity with corresponding limiting potentials of-0.26,-0.18,-0.17,-0.39,and-0.30 V,re-spectively.Furthermore,on g-C_(3)N_(4)and graphdiyne,triple-atom sites(TAS,M_(3))such as Ru_(3)(Co_(3))@g-C_(3)N_(4)and Ru_(3)(Rh_(3))@graphdiyne are expected to exhibit higher stability and NRR catalytic performance than single-atom sites(SAS)and dual-atom sites(DAS),with corresponding limiting potentials of-0.28,-0.48,-0.24,and-0.23 V.The calculated results with the corresponding experimental potentials indicate that the origin of superior NRR ac-tivity observed in experiments may be contributed by M_(2)or M_(3)on 2D materials.This study provides an in-depth investigation into real active NRR sites of metal atoms supported on 2D materials and contributes to the design of effective NRR catalysts. 展开更多
关键词 Single-atom catalysts Dual-atom sites Density functional theory Electrocat-alytic nitrogen reduction Active sites
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Siting of Dark Sky Reserves in China Based on Multi-source Spatial Data and Multiple Criteria Evaluation Method 被引量:5
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作者 WEI Ye CHEN Zuoqi +2 位作者 XIU Chunliang YU Bailang LIU Hongxing 《Chinese Geographical Science》 SCIE CSCD 2019年第6期949-961,共13页
With the rapid development of population and urbanization and the progress of lighting technology, the influence of artificial light sources has increased.In this context, the problem of light pollution has attracted ... With the rapid development of population and urbanization and the progress of lighting technology, the influence of artificial light sources has increased.In this context, the problem of light pollution has attracted wide attention.Previous studies have revealed that light pollution can affect biological living environments, human physical and mental health, astronomical observations and many other aspects.Therefore, organizations internationally have begun to advocate for measures to prevent light pollution, many of which are recognized by the International Dark-Sky Association(IDA).In addition to improving public awareness, legal protections, technical treatments and other means, the construction of Dark Sky Reserves(DSR) has proven to be an effective preventive measure.So far, as a pioneer practice in this field, the IDA has identified 11 DSRs worldwide.Based on the DA requirements for DSRs, this paper utilizes NPP-VIIRS nighttime light data and other multi-source spatial data to analyze possible DSR sites in China.The land of China was divided into more than ten thousand 30 km × 30 km fishnets, and constraint and suitable conditions were designated, respectively, as light and cloud conditions, and scale, traffic and attractiveness conditions.Using a multiple criteria evaluation, 1443 fishnets were finally selected as most suitable sites for the construction of DSRs.Results found that less than 25% of China is not subject to light pollution, and less than 13% is suitable for DSR construction, primarily in western and northern areas, including Tibet, Xinjiang, Qinghai, Gansu and Inner Mongolia. 展开更多
关键词 DARK SKY RESERVES light POLLUTION NPP-VIIRS siting multiple criteria evaluation China
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Charging Pile Siting Recommendations via the Fusion of Points of Interest and Vehicle Trajectories 被引量:6
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作者 Yuan Kong Jianping Wu +1 位作者 Ming Xu Kezhen Hu 《China Communications》 SCIE CSCD 2017年第11期29-38,共10页
By mining of the requirements of lots of electric vehicle users for charging piles, this paper proposes the charging pile siting algorithm via the fusion of Points of Interest and vehicle trajectories. The proposed al... By mining of the requirements of lots of electric vehicle users for charging piles, this paper proposes the charging pile siting algorithm via the fusion of Points of Interest and vehicle trajectories. The proposed algorithm computes appropriate charging pile locations by: 1) mining user Points of Interest from social network; 2) mining parking sites of vehicle form GPS trajectories and 3) fusing the Points of Interest and parking sites together then clustering the fusions with our improved DBSCAN algorithm, whose clustering results indicates the final appropriate charging pile locations. Experimental results show that our proposed methods are more efficient than existing methods. 展开更多
关键词 charging pile siting recommendation Points of Interest vehicle trajectories
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Landform Classification for Community Siting: A case Study in Quxian County, China
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作者 ZHAO Ke DENG Zhao-hua 《Journal of Mountain Science》 SCIE CSCD 2015年第4期1025-1037,共13页
This study is to explore a suitable method to classify landform, in order to support the decision making for community siting in mountainous areas.It first proposes the landform classification for community siting(LCC... This study is to explore a suitable method to classify landform, in order to support the decision making for community siting in mountainous areas.It first proposes the landform classification for community siting(LCCS) method with detailed discussions on its rationality and the chosen parameters.This method is then tested and verified in Quxian county.The LCCS method entails twograde parameters, which uses relative relief as the first grading parameter, slope as the second, followed by a synthesis process to form a suitable landform classification system.By applying the LCCS method in Quxian county, the result shows that its use of watershed to identify geomorphometric units, and its use of the altitude datum concept, can effectively classify landform according to the local cultural traditions, and the economic and environmental conditions.The verification result shows that comparing to the conventional methods, the LCCS method respects to people's daily experience due to its bottom-up approach.It not only help to minimize the disturbance to the nature when choosing locations for community development, but also helps to prepare more precise land management policies,which maximizes agricultural production and minimizes terrain transformation. 展开更多
关键词 Landform classification Community siting Relative relief SLOPE Mountainous areas China
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Optimal Siting of Electric Vehicle Charging Stations Based on Voronoi Diagram and FAHP Method
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作者 Zheci Tang Chunlin Guo +1 位作者 Pengxin Hou Yubo Fan 《Energy and Power Engineering》 2013年第4期1404-1409,共6页
The electric vehicle charging station should be allocated based on traffic density, geographical distribution and other factors, and Voronoi diagram is adopted to set the service area of charging station. In combinati... The electric vehicle charging station should be allocated based on traffic density, geographical distribution and other factors, and Voronoi diagram is adopted to set the service area of charging station. In combination with the actual situation of site selection of electric vehicle charging station, the comprehensive benefits index system is established. There are numerous factors influencing the site selection, among which there are uncertainty and fuzziness. The comprehensive evaluation method based on the fuzzy analysis and Analytical Hierarchy Process (AHP) is used to evaluate the comprehensive benefits in the site selection of electric vehicle charging stations, with the consultation of experts. This paper contributes to the best selection of comprehensive benefits and provides the reference for the decision-making of building the electric vehicle charging station. Actual examples show that the method proposed is effective. 展开更多
关键词 Electric Vehicles CHARGING STATION VORONOI DIAGRAM FUZZY-AHP OPTIMAL siting
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Post Evaluation of Wind Resource Assessment and Micro-Siting
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作者 Shuang Han Linyue Gao +1 位作者 Yongqian Liu Wei Yang 《Journal of Power and Energy Engineering》 2014年第4期288-296,共9页
The design energy productions deviate from the actual situation, which are affected by the accuracy of two significant factors - the wind resource assessment and wind farm micro-siting. A running wind farm in northern... The design energy productions deviate from the actual situation, which are affected by the accuracy of two significant factors - the wind resource assessment and wind farm micro-siting. A running wind farm in northern China was taken as the object in this investigation. The measured data obtained in operation phase and the relevant information in design phase were integrated and a post evaluation of wind resource assessment, micro-siting and generating capacity reduction factors of the wind farm in design phase was provided. The results indicate that the representative year wind regimes of the wind farm in design phase can basically reflect the wind conditions in the wind farm without the consideration of the trends of long-term changes in wind speed;micro-siting project in design phase is superior to that in practical;generating capacity reduction factors, overall on the high side, should be further optimized considering 20-year operation period. 展开更多
关键词 POST Evaluation WIND RESOURCE ASSESSMENT Micro siting REDUCTION FACTOR
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Relative Importance Analysis of Factors Influencing Unauthorized Siting of Residential Buildings in the Sekondi-Takoradi Metropolis of Ghana
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作者 M. K. Somiah G. Osei-Poku I. Aidoo 《Journal of Building Construction and Planning Research》 2015年第3期117-126,共10页
The act of unauthorized siting of buildings has persisted in most developing countries. Despite numerous efforts at local levels to address this problem, its existence and effects keep on rising in various metropolise... The act of unauthorized siting of buildings has persisted in most developing countries. Despite numerous efforts at local levels to address this problem, its existence and effects keep on rising in various metropolises in Ghana. This research explores the causes of unauthorized siting of buildings in Asakae, a suburb of the Sekondi-Takoradi Metropolis, and suggests measures to curb them. In view of this, a sample size of 182 house-owners was chosen for the study. Accordingly, the sample size was determined using Fisher et al. formula and questionnaire survey approach was adopted for the study. More so, data generated from the survey were further analyzed, using Relative Importance Index. The findings of the survey indicated that ignorance on planning and building regulations, inadequate housing schemes, unrealistic zonings and the location of land are critical variables which influence unauthorized siting of buildings. It is recommended that the populace should be given regular public education on land-use planning and the building regulations of Ghana. More so, the Assemblies should automate their systems, with respect to monitoring and detection of buildings under construction;so that buildings that were being located at unapproved places could be quickly detected, and appropriate measures could be taken before their completion. 展开更多
关键词 FACTORS Unauthorized BUILDINGS Sekondi-Takoradi siting
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Anti-seismic research on nuclear engineering siting
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作者 Li CHEN Lei NIE +2 位作者 Jijiang LI Delong WANG Xiangyu REN 《Global Geology》 2006年第2期224-226,共3页
Nuclear engineering belongs to significant project;there is higher requirement on sitings.The study has discussed basic factors of selecting sites,anti-seismic research on sitings including the seismic ground motion,p... Nuclear engineering belongs to significant project;there is higher requirement on sitings.The study has discussed basic factors of selecting sites,anti-seismic research on sitings including the seismic ground motion,probability methods of seismic hazard analysis as well as interaction about structure and foundation,meanwhile provide the reason for nuclear engineering selecting sites. 展开更多
关键词 nuclear engineering anti-seismic research siting
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Visiting Historic Sites at Shanhaiguan
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《China & The World Cultural Exchange》 1998年第4期14-18,共5页
关键词 Visiting Historic Sites at Shanhaiguan
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A GIS-Based Suitability Analysis for Siting a Solid Waste Incineration Power Plant in an Urban Area Case Study: Alexandria Governorate, Egypt 被引量:1
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作者 Mahmoud A. Hassaan 《Journal of Geographic Information System》 2015年第6期643-657,共15页
Solid waste represents a key issue that threatens environmental quality in Egyptian urban areas. One of the most viable options to treat such an issue is to incinerate the collected solid waste for electricity generat... Solid waste represents a key issue that threatens environmental quality in Egyptian urban areas. One of the most viable options to treat such an issue is to incinerate the collected solid waste for electricity generation, which can reduce the cost of solid waste disposal as well as pollution and generate surplus energy. Selecting appropriate site for a solid waste incineration power plant is a crucial step due to its economic and environmental implications. This would require assessing various constraining and favorable factors that determine feasibility and sustainability of the power plant site. This paper is intended to develop a GIS-based model for siting a municipal solid waste incineration power plant in Alexandria governorate, Egypt. For this purpose, five criteria are considered and a composite index was suggested to integrate these criteria in a numerical term reflecting suitability of various parts of the governorate for siting solid waste incineration power plant. 展开更多
关键词 Suitability Analysis Site Selection GIS MUNICIPAL Solid Waste ALEXANDRIA EGYPT
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Landfill Siting Evaluation Using GIS and Multi-Criteria Decision-Making Method: A Case Study: Dammam Municipal Solid Waste Landfill 被引量:1
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作者 Nora Al Khaldi Firdos Almadani Sara Ouerghi 《Journal of Geographic Information System》 2021年第4期508-522,共15页
Waste landfills are a prominent global issue that does not concern a country without the other because of its long-term effects especially in the environmental aspect. As these pose an environmental threat to water, a... Waste landfills are a prominent global issue that does not concern a country without the other because of its long-term effects especially in the environmental aspect. As these pose an environmental threat to water, air and soil;and directly affect human life and health. Accordingly, this research uses the integration of Geographic Information Systems (GIS) and Multi-Criteria Decision-Making (MCDM) approaches to assess the location of the municipal solid waste dump in Dammam, which was established in (2000AD) twenty years ago, due to the lack of recent studies assessing the current status of the landfill and whether it is in a suitable location and keeps pace with the population and urbanization increase in the region. For this purpose, the researchers are using the tools and techniques of GIS to evaluate eight criteria on the study area. The required standards were directed to the landfill site and transformed into maps that represent the most important economic, social, environmental, geological, geomorphological and Public Acceptance standards. These standards have been processed using the tools of spatial and statistical analyses. Analytic Hierarchy Process (AHP) is implemented in geographical information system for building the suitable cartographic model, and thus allowed to determine the suitable degree of Dammam municipal solid waste landfill site in light of the study criteria. The study concluded that the current landfill site achieves a good degree of suitability, as it achieved 63% measured against the quality standards set by the study, and that the current landfill site conforms to most of the criteria in this study to a good degree. But it violates two standards, which are distance from wells standard and distance between landfill and the center of waste generation standard. 展开更多
关键词 Landfill Site Criteria Weights GIS Analytic Hierarchy Process (AHP)
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Upgrade of Transportation Infrastructure and Siting of Polluting Enterprises:The Case of High-Speed Railway Launch in China
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作者 Cai Hongbo Zhong Chao Han Jinrong 《China Economist》 2022年第3期89-112,共24页
With the quasi-natural experiment of the launching of high-speed railways in Chinese cities,this paper empirically investigated the effects of the upgrade of the transportation infrastructure on the site selection of ... With the quasi-natural experiment of the launching of high-speed railways in Chinese cities,this paper empirically investigated the effects of the upgrade of the transportation infrastructure on the site selection of polluting enterprises.We found that although the launching of a high-speed railway generally has a negative impact on the siting of polluting enterprises:(i)While there was a significant decrease in polluting enterprises of a private and other nature,the reduction in overseas-funded and state-owned enterprises was insignificant;(ii)while the launching of a high-speed railway greatly restrained the entry of polluting enterprises in the eastern region,large cities and more developed cities,this was followed by the movement of more polluting enterprises to the central and western regions,small and medium-sized cities and less developed cities;(iii)there was a significant decrease in polluting enterprises in environmentally conscious cities after the launching of a high-speed railway.This paper also found that infrastructure upgrade may influence the siting of polluting enterprises through the following:Environmental cleanness,factor concentration and spatial integration.Government authorities and market entities should be fully aware of and attach great importance to how the transportation infrastructure influences the site selection of businesses,as this is of great significance for China’s regional development planning,local business climate and investment planning,environmental protection,and other related policymaking initiatives. 展开更多
关键词 Transportation infrastructure high-speed railway polluting enterprises site selection
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Optimal Siting and Sizing of Distributed Renewable Energy in an Active Distribution Network 被引量:7
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作者 Haijun Xing Hong Fan +2 位作者 Xin Sun Shaoyun Hong Haozhong Cheng 《CSEE Journal of Power and Energy Systems》 SCIE 2018年第3期380-387,共8页
The distributed generation (DG) plays an important role in the context of the environmental problems and sustain- able development throughout the world. This paper proposes a DG siting and sizing model in an active di... The distributed generation (DG) plays an important role in the context of the environmental problems and sustain- able development throughout the world. This paper proposes a DG siting and sizing model in an active distribution network (ADN). The objective is to minimize the total cost, including investment, operation and maintenance costs. The proposed model is transferred to a Mixed Integer Second-Order Cone Programming (MISOCP) model based on a distribution network forward backward-sweep power flow and constraint relaxation. The CVX platform and GUROBI solver are used for the solution. The scenario analysis is used for the uncertainties of load and DG. Different numbers of operational scenarios are considered in order to analyze the effect of a non-network solution to the final planning result and total investment. The planning results with and without consideration of active managements, and the planning results with and without taking environmental profits into consideration, are compared and analyzed. The proposed methodology is verified with a modified IEEE 33 example. 展开更多
关键词 Active distribution network distributed generation distribution network siting and sizing second-order cone programming
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Analytical Hybrid Particle Swarm Optimization Algorithm for Optimal Siting and Sizing of Distributed Generation in Smart Grid 被引量:3
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作者 Syed Muhammad Arif Akhtar Hussain +2 位作者 Tek Tjing Lie Syed Muhammad Ahsan Hassan Abbas Khan 《Journal of Modern Power Systems and Clean Energy》 SCIE EI CSCD 2020年第6期1221-1230,共10页
In this paper,the hybridization of standard particle swarm optimisation(PSO)with the analytical method(2/3 rd rule)is proposed,which is called as analytical hybrid PSO(AHPSO)algorithm used for the optimal siting and s... In this paper,the hybridization of standard particle swarm optimisation(PSO)with the analytical method(2/3 rd rule)is proposed,which is called as analytical hybrid PSO(AHPSO)algorithm used for the optimal siting and sizing of distribution generation.The proposed AHPSO algorithm is implemented to cater for uniformly distributed,increasingly distributed,centrally distributed,and randomly distributed loads in conventional power systems.To demonstrate the effectiveness of the proposed algorithm,the convergence speed and optimization performances of standard PSO and the proposed AHPSO algorithms are compared for two cases.In the first case,the performances of both the algorithms are compared for four different load distributions via an IEEE 10-bus system.In the second case,the performances of both the algorithms are compared for IEEE 10-bus,IEEE 33-bus,IEEE 69-bus systems,and a real distribution system of Korea.Simulation results show that the proposed AHPSO algorithm converges significantly faster than the standard PSO.The results of the proposed algorithm are compared with those of an analytical algorithm,and the results of them are similar. 展开更多
关键词 siting and sizing of distributed generation distribution system hybrid algorithm loss minimization particle swarm optimization(PSO)
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Supporting energy policy research with large language models:A case study in wind energy siting ordinances 被引量:2
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作者 Grant Buster Pavlo Pinchuk +3 位作者 Jacob Barrons Ryan McKeever Aaron Levine Anthony Lopez 《Energy and AI》 2024年第4期231-239,共9页
The recent growth in renewable energy development in the United States has been accompanied by a simultaneous surge in renewable energy siting ordinances.These zoning laws play a critical role in dictating the placeme... The recent growth in renewable energy development in the United States has been accompanied by a simultaneous surge in renewable energy siting ordinances.These zoning laws play a critical role in dictating the placement of wind and solar resources that are critical for achieving low-carbon energy futures.In this context,efficient access to and management of siting ordinance data becomes imperative.The National Renewable Energy Laboratory(NREL)recently introduced a public wind and solar siting database to fill this need.This paper presents a method for harnessing Large Language Models(LLMs)to automate the extraction of these siting ordinances from legal documents,enabling this database to maintain accurate up-to-date information in the rapidly changing energy policy landscape.A novel contribution of this research is the integration of a decision tree framework with LLMs.Our results show that this approach is 85 to 90%accurate with outputs that can be used directly in downstream quantitative modeling.We discuss opportunities to use this work to support similar largescale policy research in the energy sector.By unlocking new efficiencies in the extraction and analysis of legal documents using LLMs,this study enables a path forward for automated large-scale energy policy research. 展开更多
关键词 Energy policy Energy analysis siting ordinances Large language models(LLMs) Natural language processing(NLP)
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Sizing and Siting of Battery Energy Storage Systems:A Colombian Case
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作者 Alvaro Avendano Pena David Romero-Quete Camilo A.Cortes 《Journal of Modern Power Systems and Clean Energy》 SCIE EI CSCD 2022年第3期700-709,共10页
This paper presents a mixed-integer linear programming(MILP)formulation for sizing and siting of battery energy storage systems(BESSs).The problem formulation seeks to minimize both operation costs and BESS investment... This paper presents a mixed-integer linear programming(MILP)formulation for sizing and siting of battery energy storage systems(BESSs).The problem formulation seeks to minimize both operation costs and BESS investment.The proposed model includes restrictions of the conventional securityconstrained unit commitment problem,a piece-wise linear approximation to model power losses,and a linear model of hydro generation units.The proposed model is tested in a 6-bus test system and a 15-bus system representing the Colombian power system.For the two studied systems,simulation results show that the reduction of operation costs due to the installation of BESSs compensates the investments,under some of the considered technical cost cases.Additionally,results show that adequate sizing and siting of BESSs reduce renewable energy curtailment in the Colombian power system with high penetration of fluctuating renewable generation. 展开更多
关键词 Battery energy storage curtailment sizing and siting renewable energy
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Saturated Alcohols Electrocatalytic Oxidations on Ni-Co Bimetal Oxide Featuring Balanced B-and L-Acidic Active Sites
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作者 Junqing Ma Wenshu Luo +9 位作者 Xunlu Wang Xu Yu Jiacheng Jayden Wang Huashuai Hu Hanxiao Du Jianrong Zeng Wei Chen Minghui Yang Jiacheng Wang Xiangzhi Cui 《Nano-Micro Letters》 2026年第2期105-123,共19页
Investigating structural and hydroxyl group effects in electrooxidation of alcohols to value-added products by solid-acid electrocatalysts is essential for upgrading biomass alcohols.Herein,we report efficient electro... Investigating structural and hydroxyl group effects in electrooxidation of alcohols to value-added products by solid-acid electrocatalysts is essential for upgrading biomass alcohols.Herein,we report efficient electrocatalytic oxidations of saturated alcohols(C_(1)-C_(6))to selectively form formate using Ni Co hydroxide(Ni Co-OH)derived Ni Co_(2)O_(4)solid-acid electrocatalysts with balanced Lewis acid(LASs)and Brønsted acid sites(BASs).Thermal treatment transforms BASs-rich(89.6%)Ni Co-OH into Ni Co_(2)O_(4)with nearly equal distribution of LASs(53.1%)and BASs(46.9%)which synergistically promote adsorption and activation of OH-and alcohol molecules for enhanced oxidation activity.In contrast,BASs-enriched Ni Co-OH facilitates formation of higher valence metal sites,beneficial for water oxidation.The combined experimental studies and theoretical calculation imply the oxidation ability of C1-C6alcohols increases as increased number of hydroxyl groups and decreased HOMO-LUMO gaps:methanol(C_(1))<ethylene glycol(C_(2))<glycerol(C3)<meso-erythritol(C4)<xylitol(C5)<sorbitol(C6),while the formate selectivity shows the opposite trend from 100 to 80%.This study unveils synergistic roles of LASs and BASs,as well as hydroxyl group effect in electro-upgrading of alcohols using solid-acid electrocatalysts. 展开更多
关键词 Solid-acid electrocatalyst Alcohol oxidation reaction Bronsted acid sites Lewis acid sites C_(1)-C_(6)saturated alcohols
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Current status of the geological disposal programme and an overview of the safety case at the pre-siting stage in Japan
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作者 Tetsuo Fujiyama Kenichi Kaku 《Rock Mechanics Bulletin》 2023年第3期78-92,共15页
In Japan,high-level radioactive waste and specific low-level radioactive waste which includes long-lived radionuclides are planned to be disposed of in the geological formations at depths greater than 300 m.The dispos... In Japan,high-level radioactive waste and specific low-level radioactive waste which includes long-lived radionuclides are planned to be disposed of in the geological formations at depths greater than 300 m.The disposal site will be selected through a stepwise site investigation process that consists of a Literature Survey,Preliminary Investigation,and Detailed Investigation phases.In October 2020 a Literature Survey was launched in Japan at two municipalities in Hokkaido for the first time since NUMO initiated a nationwide call for volunteer municipalities in 2002,and the outcomes are currently being compiled.To enhance the public’s understanding of how to implement safe geological disposal in Japan based on the latest scientific knowledge and technology,NUMO,as the implementing organisation,developed and published a safety case for geological disposal at the pre-siting stage.This safety case provides multiple lines of arguments and evidence to demonstrate the feasibility of the geological disposal and a basic structure for a safety case that will be applicable to any potential sites in Japan.The safety case also presented some R&D challenges to enhance the technical confidence of the project,including the R&D topics related to rock mechanics.This report presents the current status of the geological disposal programme in Japan,together with the status of the Literature Survey phase and an overview of the NUMO safety case. 展开更多
关键词 High-level radioactive waste TRU waste Geological disposal Site selection process Literature survey Safety case
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CEACAM1源性荧光多肽底物Site 84对MMP-2、-7、-9、-12酶活性检测的研究
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作者 万雯 叶雨佳 +5 位作者 杨晓娜 杨理宏 王华炜 董玲 陈丽星 孟照辉 《昆明医科大学学报》 2025年第2期9-16,共8页
目的探索CEACAM1源性多肽合成的荧光底物Site 84对MMP-2,-7,-9,-12酶活性的检测,并进一步探索荧光多肽底物Site 84在区分同属于MMPs明胶酶谱中MMP-2和MMP-9的应用。方法采用荧光酶学法观察荧光多肽底物Site 84对MMP-2,-7,-9,-12酶活性... 目的探索CEACAM1源性多肽合成的荧光底物Site 84对MMP-2,-7,-9,-12酶活性的检测,并进一步探索荧光多肽底物Site 84在区分同属于MMPs明胶酶谱中MMP-2和MMP-9的应用。方法采用荧光酶学法观察荧光多肽底物Site 84对MMP-2,-7,-9,-12酶活性的检测;进一步观察底物Site 84对明胶酶谱中MMP-2和MMP-9酶活性的敏感性和特异性;获得底物Site 84与MMP-2的酶促反应的动力学参数Km、Kcat。结果以Site 84为底物,获得MMP-12、-7、-2的酶活力曲线,但未获得MMP-9的酶活力曲线;此外,以Site 84为底物,可特异性检测明胶酶谱中MMP-2的酶活性,其可检测低浓度(0.6μM)MMP-2的酶活性,然而对高浓度(6μM)MMP-9未见明显酶促反应;最后,MMP-2和底物Site 84的酶促反应动力学参数:Km=315μM,Kcat/Km=2565/MS。结论以CEACAM1源性底物Site 84作为新型的荧光多肽底物,可获得MMP-12、-7、-2的酶活力曲线,且可特异性检测MMPs明胶酶谱中MMP-2的酶活性。 展开更多
关键词 Site 84 荧光多肽底物 酶活性 明胶酶 CEACAM1源性
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Selenate-based heterojunction with cobalt-nickel paired site for electrocatalytic oxidation of 5-hydroxymethylfurfural coupling water splitting to produce hydrogen 被引量:1
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作者 Zhengru Yang Jia Hui +4 位作者 Wangxi Fan Pengcheng Liu Chunyong Zhang Shuang Dong Zhou Yang 《Journal of Energy Chemistry》 2025年第2期156-162,I0005,共8页
It is very appealing that 5-hydroxymethylfurfural(HMF)is electrocatalytical oxidized as 2,5-furandicarboxylic acid(FDCA)linking to non-classical cathodic hydrogen(H_(2))production.However,the electrocatalysts for elec... It is very appealing that 5-hydroxymethylfurfural(HMF)is electrocatalytical oxidized as 2,5-furandicarboxylic acid(FDCA)linking to non-classical cathodic hydrogen(H_(2))production.However,the electrocatalysts for electrocatalytic HMF oxidative reaction(e-HMFOR)have been facing low Faradaic efficiency(FE)and high water splitting voltage.Herein,we propose a strategy of the NiSeO_(3)@(CoSeO_(3))_(4)heterojunction by constructing a Co-Ni paired site,where the Co site is in charge of adsorbing for HMF while the electrons are transferred to the Ni site,thus giving the NiSeO_(3)@(CoSeO_(3))_(4)heterojunction superior electrocata lytic performances for e-HMFOR and water splitting.By optimizing conditions,the NiSeO_(3)@(CoSeO_(3))_(4)heterojunction has high conversion of 99.7%,high selectivity of 99.9%,and high FE of 98.4%at 1.3 V,as well as low cell voltage of 1.31 V at 10 mA cm^(-2)in 1 M KOH+0.1 M HMF.This study offers a potential insight for e-HMFOR to high value-added FDCA coupling water splitting to produce H_(2)in an economical manner. 展开更多
关键词 e-HMFOR FDCA Co-Ni paired site HETEROJUNCTION Hydrogen evolution
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