Fe-N compounds with excellent electrocatalytic oxygen reduction activity are considered to be one of the most promising non-precious metal materials for fuel cells.Fe-N compounds with excellent electrocatalytic oxygen...Fe-N compounds with excellent electrocatalytic oxygen reduction activity are considered to be one of the most promising non-precious metal materials for fuel cells.Fe-N compounds with excellent electrocatalytic oxygen reduction activity are considered to be one of the most promising non-precious metal materials for fuel cells,which focuses on the Fe-N4 single-atom catalysts and the iron nitride materials(such as Fe2N and Fe3N).A hybridized catalyst having a hierarchical porous structure with regular macropores could enable the desired mass transfer efficiency in the catalytic process.In this study,we have constructed a new type of hybrid catalyst having iron and iron-nitrogen alloy nanoparticles(Fe-N austenite,termed as Fe-NA)embedded in the three-dimensional ordered macroporous N-doped carbon(3DOM Fe/Fe-NA@NC)by direct pyrolysis of single-source dicyandiamide-based iron metal-organic frameworks.The as-synthesized composites preserve the hierarchical porous carbon framework with ordered macropores and high specific surface area,incorporating the uniformly dispersed iron/iron-nitrogen austenite nanoparticles.Thereby,the striking architectural configuration embedded with highly active catalytic species delivers a superior oxygen reduction activity with a half-wave potential of 0.88 V and a subsequent superior Zn-air battery performance with high open-circuit voltage and continuous stability as compared to those using a commercial 20%Pt/C catalyst.展开更多
Coastal tourism is the main resources from tourism sector in North Kayong Regency.Despite the fact that its potential resource from coastal area tourism has similar attraction in order to attract the tourist more exte...Coastal tourism is the main resources from tourism sector in North Kayong Regency.Despite the fact that its potential resource from coastal area tourism has similar attraction in order to attract the tourist more extensively,it is necessary to make an effort to tackle the stagnant market of tourism towards similar coastal tourism destinations.Therefore,it would be a good to make the destination to be more attractive by enhancing the existing tourist attractions through strengthening the destination characteristics as attractiveness that are derived from its signature.Moreover,it could diverse the destination that would impact for its benefits in terms of diversity destination.The lack of development in costal tourism destination tends not to take all part of the area for the benefit of its tourist destination development that is caused by many factors.One of many possible efforts to support the development of coastal tourism is the identification of its availability and establishment of signature tourist destination characteristics.Every tourist destination has their own difference characteristic.This is one of the reason why the development and develop of tourist destination for coastal tourism tend to be influenced by its own unique characteristics.In order to enhance the values,it is needed to put an effort to classify and look for the uniqueness,for further appreciate of uniqueness characteristic.The result of classification from this research has been determined by its own potential and characteristic for each destination.For every category derived from the variable identified from existing condition of every destination.The variables are used to determine many factors of successful development of destination,which are very dependable to the existing resources and coastal resources such as tourism infrastructure,general infrastructure and accessibility as part of the efforts of shortening the access time.The purpose of this research is to search for characteristic of coastal tourism in Remote Island and coastal area of North Kayong Regency.Secondly,it is to find the opportunity to create multi-destination concept in the pattern of tourist visits in the corridor of coastal tourism and to match the appropriateness between the tourist destination characteristic toward the opportunity to create multi-destination concept as direction for strategic development concept to enhance the value of representative destination in remote area location.This research uses descriptive qualitative method with an emphasis on deductive approach.The instruments used for analysis are questionnaire,interview,and continum scale that produce from the Likert method of satisfaction questionnaire.This research reveals that there are many strong characteristics from the uniqueness of nature,i.e.,geographic condition,and ecology which has unique landscape for its gold sand color and natural geological coastal stone distinctive for every destination and its own unique panorama.There are many opportunities to develop the potential of rich natural from coastal area,such as the potency to match up the creative economy with community based tourism.There are many factors that are very crucial to support coastal tourism as multi-destination tourist destination such as infrastructure availability.All of those things will make contribution to enhance the potential of economic growth from tourism industry especially coastal area of tourist destination.展开更多
For the first time, ZrC-ZrB_2-SiC ceramic nanocomposites were successfully prepared by a single-source-precursor route, with allylhydridopolycarbosilane(AHPCS),triethylamine borane(TEAB),and bis(cyclopentadienyl) zirc...For the first time, ZrC-ZrB_2-SiC ceramic nanocomposites were successfully prepared by a single-source-precursor route, with allylhydridopolycarbosilane(AHPCS),triethylamine borane(TEAB),and bis(cyclopentadienyl) zirconium dichloride(Cp_2 ZrCl_2) as starting materials. The polymer-to-ceramic transformation and thermal behavior of obtained single-source precursor were characterized by means of Fourier transform infrared spectroscopy(FT-IR) and thermal gravimetric analysis(TGA). The results show that the precursor possesses a high ceramic yield about 85% at 1000 ℃.The phase composition and microstructure of formed ZrC-ZrB_2-SiC ceramics were investigated by means of X-ray diffraction(XRD) and high resolution transmission electron microscopy(HRTEM).Meanwhile, the weight loss and chemical composition of the resultant ZrC-ZrB_2-SiC nanocomposites were investigated after annealing at high temperature up to 1800 ℃. High temperature behavior with respect to decomposition as well as crystallization shows a promising high temperature stability of the formed ZrC-ZrB_2-SiC nanocomposites.展开更多
L10-FePt nan oparticles(NPs)with high chemical ordering represent effective electrocatalysts to reduce the cost and enhance theircatalytic performanee in fuel cells.A molecular strategy of preparing highly ordered FeP...L10-FePt nan oparticles(NPs)with high chemical ordering represent effective electrocatalysts to reduce the cost and enhance theircatalytic performanee in fuel cells.A molecular strategy of preparing highly ordered FePt NPs was used by direct pyrolysis of a Fe,Pt-containing bimetallic complex.The resultant L10-FePt NPs had very high crystallinity as reflected by the obvious diffractionpatterns,clear lattice fringes and characteristic X-ray diffraction peaks,etc.Besides,the strong ferromagnetism with room temperaturecoercivity of 27 kOe further confirmed the face-centered tetrag on al(fet)phase in good agreement with the ordered nano structures.TheFePt NPs can be used as electrocatalysts to catalyze oxygen reduction reaction(ORR)in an O2·saturated 0.1 M HClO4 solution andhydrogen evolution reaction(HER)in the 0.5 M H2SO4 electrolyte with much better performance than commercial Pt/C,and showedquite high stability after 10,000 cycles.The strategy utilizing orga no metallic precursors to prepare metal alloy NPs was dem on strated tobe a reliable approach for improving the catalytic efficiency in fuel cells.展开更多
Increasing demands for improvement in power quality and power capacity have contributed to development of switched-capacitor multilevel inverters(SCMLIs).Recently developed SCMLIs enable single-stage voltage boosting,...Increasing demands for improvement in power quality and power capacity have contributed to development of switched-capacitor multilevel inverters(SCMLIs).Recently developed SCMLIs enable single-stage voltage boosting,as well as inversion resulting in step-up ac output.Towards reduction in number of components,this paper introduces a boost type singlesource nine-level(9-level)SCMLI employing two capacitors and three diodes.Owing to the series-parallel connection process,capacitor voltages are inherently balanced and assist in quadruple voltage boosting from a single-source.Maximum voltage stress across semiconductor devices is limited to twice input voltage only.Using a minimum number of components,the proposed SCMLI can be extended to increase voltage levels without additional dc input.Each extension module adds two additional voltage steps in the output while maintaining maximum voltage stress the same as 9-level circuit.Followed by in-depth analysis of circuit operation and power losses,a thorough comparison of recently developed single-phase 9-level MLIs is carried out,which verifies design superiority.Extensive simulation and experimental results are presented to verify the prominent features of the 9-level SCMLI under dynamic operating conditions.展开更多
Patterning of L10 FePt nanoparticles(NPs) with high coercivity offers a promising route to develop bit-patterned media(BPM) for the next generation magnetic data recording system, but the synthesis of monodisperse FeP...Patterning of L10 FePt nanoparticles(NPs) with high coercivity offers a promising route to develop bit-patterned media(BPM) for the next generation magnetic data recording system, but the synthesis of monodisperse FePt NPs and mass production of their nanopatterns has been a longstanding challenge. Here, highly efficient nanoimprint lithography was applied for large-scale universal patterning, which was achieved by imprinting the solution of a single-source bimetallic precursor. The rigid coplanar metallic cores and the surrounding flexible tails in the bimetallic complex permit the spontaneous molecular arrangements to form the highly ordered negative morphology replicated from the soft template.In-situ pyrolysis study was then investigated by one-pot pyrolysis of the precursor under an Ar/H2 atmosphere, and the resultant NPs were fully characterized to identify the phase,morphology and magnetic properties. Finally, highly-ordered patterns on certain substrates were preserved perfectly after pyrolysis and could be potentially utilized in magnetic data recording media.展开更多
To accelerate the scan speed and improve the image quality, a new type of CT configuration, "double-source double-multislice spiral CT" (DSDMS-CT), which is based on two sets of single-source multislice spir...To accelerate the scan speed and improve the image quality, a new type of CT configuration, "double-source double-multislice spiral CT" (DSDMS-CT), which is based on two sets of single-source multislice spiral CT was proposed with a special reconstruction algorithm. Simulation results using the fan-beam filtered backprojection algorithm with a special interpolation method were presented for both single-source multislice spiral CT and DSDMS-CT. The results of new CT model show that it scans faster than the traditional spiral CT and has a better slice sensitivity profile (SSP) with larger pitch value.展开更多
Dataflow architecture has shown its advantages in many high-performance computing cases. In dataflow computing, a large amount of data are frequently transferred among processing elements through the network-on-chip ...Dataflow architecture has shown its advantages in many high-performance computing cases. In dataflow computing, a large amount of data are frequently transferred among processing elements through the network-on-chip （NoC）. Thus the router design has a significant impact on the performance of dataflow architecture. Common routers are designed for control-flow multi-core architecture and we find they are not suitable for dataflow architecture. In this work, we analyze and extract the features of data transfers in NoCs of dataflow architecture： multiple destinations, high injection rate, and performance sensitive to delay. Based on the three features, we propose a novel and efficient NoC router for dataflow architecture. The proposed router supports multi-destination; thus it can transfer data with multiple destinations in a single transfer. Moreover, the router adopts output buffer to maximize throughput and adopts non-flit packets to minimize transfer delay. Experimental results show that the proposed router can improve the performance of dataflow architecture by 3.6x over a state-of-the-art router.展开更多
In the research of service composition,it demands efficient algorithms that not only retrieve correct service compositions automatically from thousands of services but also satisfy the quality requirements of differen...In the research of service composition,it demands efficient algorithms that not only retrieve correct service compositions automatically from thousands of services but also satisfy the quality requirements of different service users.However,most approaches treat these two aspects as two separate problems,automatic service composition and service selection.Although the latest researches realize the restriction of this separate view and some specific methods are proposed,they still suffer from serious limitations in scalability and accuracy when addressing both requirements simultaneously.In order to cope with these limitations and efficiently solve the combined problem which is known as QoS-aware or QoS-driven automatic service composition problem,we propose a new graph search problem,single-source optimal directed acyclic graphs （DAGs）,for the first time.This novel single-source optimal DAGs （SSOD） problem is similar to,but more general than the classical single-source shortest paths （SSSP） problem.In this paper,a new graph model of SSOD problem is proposed and a Sim-Dijkstra algorithm is presented to address the SSOD problem with the time complexity of O（n log n ＋ m） （n and m are the number of nodes and edges in the graph respectively）,and the proofs of its soundness.It is also directly applied to solve the QoS-aware automatic service composition problem,and a service composition tool named QSynth is implemented.Evaluations show that Sim-Dijkstra algorithm achieves superior scalability and efficiency with respect to a large variety of composition scenarios,even more efficient than our worklist algorithm that won the performance championship of Web Services Challenge 2009.展开更多
文摘Fe-N compounds with excellent electrocatalytic oxygen reduction activity are considered to be one of the most promising non-precious metal materials for fuel cells.Fe-N compounds with excellent electrocatalytic oxygen reduction activity are considered to be one of the most promising non-precious metal materials for fuel cells,which focuses on the Fe-N4 single-atom catalysts and the iron nitride materials(such as Fe2N and Fe3N).A hybridized catalyst having a hierarchical porous structure with regular macropores could enable the desired mass transfer efficiency in the catalytic process.In this study,we have constructed a new type of hybrid catalyst having iron and iron-nitrogen alloy nanoparticles(Fe-N austenite,termed as Fe-NA)embedded in the three-dimensional ordered macroporous N-doped carbon(3DOM Fe/Fe-NA@NC)by direct pyrolysis of single-source dicyandiamide-based iron metal-organic frameworks.The as-synthesized composites preserve the hierarchical porous carbon framework with ordered macropores and high specific surface area,incorporating the uniformly dispersed iron/iron-nitrogen austenite nanoparticles.Thereby,the striking architectural configuration embedded with highly active catalytic species delivers a superior oxygen reduction activity with a half-wave potential of 0.88 V and a subsequent superior Zn-air battery performance with high open-circuit voltage and continuous stability as compared to those using a commercial 20%Pt/C catalyst.
文摘Coastal tourism is the main resources from tourism sector in North Kayong Regency.Despite the fact that its potential resource from coastal area tourism has similar attraction in order to attract the tourist more extensively,it is necessary to make an effort to tackle the stagnant market of tourism towards similar coastal tourism destinations.Therefore,it would be a good to make the destination to be more attractive by enhancing the existing tourist attractions through strengthening the destination characteristics as attractiveness that are derived from its signature.Moreover,it could diverse the destination that would impact for its benefits in terms of diversity destination.The lack of development in costal tourism destination tends not to take all part of the area for the benefit of its tourist destination development that is caused by many factors.One of many possible efforts to support the development of coastal tourism is the identification of its availability and establishment of signature tourist destination characteristics.Every tourist destination has their own difference characteristic.This is one of the reason why the development and develop of tourist destination for coastal tourism tend to be influenced by its own unique characteristics.In order to enhance the values,it is needed to put an effort to classify and look for the uniqueness,for further appreciate of uniqueness characteristic.The result of classification from this research has been determined by its own potential and characteristic for each destination.For every category derived from the variable identified from existing condition of every destination.The variables are used to determine many factors of successful development of destination,which are very dependable to the existing resources and coastal resources such as tourism infrastructure,general infrastructure and accessibility as part of the efforts of shortening the access time.The purpose of this research is to search for characteristic of coastal tourism in Remote Island and coastal area of North Kayong Regency.Secondly,it is to find the opportunity to create multi-destination concept in the pattern of tourist visits in the corridor of coastal tourism and to match the appropriateness between the tourist destination characteristic toward the opportunity to create multi-destination concept as direction for strategic development concept to enhance the value of representative destination in remote area location.This research uses descriptive qualitative method with an emphasis on deductive approach.The instruments used for analysis are questionnaire,interview,and continum scale that produce from the Likert method of satisfaction questionnaire.This research reveals that there are many strong characteristics from the uniqueness of nature,i.e.,geographic condition,and ecology which has unique landscape for its gold sand color and natural geological coastal stone distinctive for every destination and its own unique panorama.There are many opportunities to develop the potential of rich natural from coastal area,such as the potency to match up the creative economy with community based tourism.There are many factors that are very crucial to support coastal tourism as multi-destination tourist destination such as infrastructure availability.All of those things will make contribution to enhance the potential of economic growth from tourism industry especially coastal area of tourist destination.
基金National Natural Science Foundation of China (No. 51872246)Alexander von Humboldt Foundation, and Creative Research Foundation of Science and Technology on Thermo Structural Composite Materials Laboratory (No. 6142911040114) for financial supportthe National Key R&D Program of China (No. 2017YFB0703200)
文摘For the first time, ZrC-ZrB_2-SiC ceramic nanocomposites were successfully prepared by a single-source-precursor route, with allylhydridopolycarbosilane(AHPCS),triethylamine borane(TEAB),and bis(cyclopentadienyl) zirconium dichloride(Cp_2 ZrCl_2) as starting materials. The polymer-to-ceramic transformation and thermal behavior of obtained single-source precursor were characterized by means of Fourier transform infrared spectroscopy(FT-IR) and thermal gravimetric analysis(TGA). The results show that the precursor possesses a high ceramic yield about 85% at 1000 ℃.The phase composition and microstructure of formed ZrC-ZrB_2-SiC ceramics were investigated by means of X-ray diffraction(XRD) and high resolution transmission electron microscopy(HRTEM).Meanwhile, the weight loss and chemical composition of the resultant ZrC-ZrB_2-SiC nanocomposites were investigated after annealing at high temperature up to 1800 ℃. High temperature behavior with respect to decomposition as well as crystallization shows a promising high temperature stability of the formed ZrC-ZrB_2-SiC nanocomposites.
基金This work was supported by the National Natural Science Foundation of China(No.21701112)Science,Technology and Innovation Committee of Shenzhen Municipality(No.JCYJ20170303160036674)+2 种基金Hong Kong Research Grants Council(PolyU153062/18R C4006-17G and HKUST16304117)the Hong Kong Polytechnic University(1-ZE1C)Ms Clarea Au(847S)for the Endowed Professorship in Energy.Special thanks were also given to Instrumental Analysis Center of Shenzhen University(Xili Campus).
文摘L10-FePt nan oparticles(NPs)with high chemical ordering represent effective electrocatalysts to reduce the cost and enhance theircatalytic performanee in fuel cells.A molecular strategy of preparing highly ordered FePt NPs was used by direct pyrolysis of a Fe,Pt-containing bimetallic complex.The resultant L10-FePt NPs had very high crystallinity as reflected by the obvious diffractionpatterns,clear lattice fringes and characteristic X-ray diffraction peaks,etc.Besides,the strong ferromagnetism with room temperaturecoercivity of 27 kOe further confirmed the face-centered tetrag on al(fet)phase in good agreement with the ordered nano structures.TheFePt NPs can be used as electrocatalysts to catalyze oxygen reduction reaction(ORR)in an O2·saturated 0.1 M HClO4 solution andhydrogen evolution reaction(HER)in the 0.5 M H2SO4 electrolyte with much better performance than commercial Pt/C,and showedquite high stability after 10,000 cycles.The strategy utilizing orga no metallic precursors to prepare metal alloy NPs was dem on strated tobe a reliable approach for improving the catalytic efficiency in fuel cells.
文摘Increasing demands for improvement in power quality and power capacity have contributed to development of switched-capacitor multilevel inverters(SCMLIs).Recently developed SCMLIs enable single-stage voltage boosting,as well as inversion resulting in step-up ac output.Towards reduction in number of components,this paper introduces a boost type singlesource nine-level(9-level)SCMLI employing two capacitors and three diodes.Owing to the series-parallel connection process,capacitor voltages are inherently balanced and assist in quadruple voltage boosting from a single-source.Maximum voltage stress across semiconductor devices is limited to twice input voltage only.Using a minimum number of components,the proposed SCMLI can be extended to increase voltage levels without additional dc input.Each extension module adds two additional voltage steps in the output while maintaining maximum voltage stress the same as 9-level circuit.Followed by in-depth analysis of circuit operation and power losses,a thorough comparison of recently developed single-phase 9-level MLIs is carried out,which verifies design superiority.Extensive simulation and experimental results are presented to verify the prominent features of the 9-level SCMLI under dynamic operating conditions.
基金supported by the National Natural Science Foundation of China (21701112, 21504074 and 51573151)Hong Kong Research Grants Council (HKBU12317216, Poly U153062/18P and Poly U153015/14P)+2 种基金Areas of Excellence Scheme, University Grants Committee of HKSAR (Ao E/P-03/08)the Hong Kong Polytechnic University (1-ZE1C and 1-ZE25)the Science, Technology and Innovation Committee of Shenzhen Municipality (JCYJ20160531193836532)
文摘Patterning of L10 FePt nanoparticles(NPs) with high coercivity offers a promising route to develop bit-patterned media(BPM) for the next generation magnetic data recording system, but the synthesis of monodisperse FePt NPs and mass production of their nanopatterns has been a longstanding challenge. Here, highly efficient nanoimprint lithography was applied for large-scale universal patterning, which was achieved by imprinting the solution of a single-source bimetallic precursor. The rigid coplanar metallic cores and the surrounding flexible tails in the bimetallic complex permit the spontaneous molecular arrangements to form the highly ordered negative morphology replicated from the soft template.In-situ pyrolysis study was then investigated by one-pot pyrolysis of the precursor under an Ar/H2 atmosphere, and the resultant NPs were fully characterized to identify the phase,morphology and magnetic properties. Finally, highly-ordered patterns on certain substrates were preserved perfectly after pyrolysis and could be potentially utilized in magnetic data recording media.
基金The National Natural Science Foundation ofChina (No30570511)
文摘To accelerate the scan speed and improve the image quality, a new type of CT configuration, "double-source double-multislice spiral CT" (DSDMS-CT), which is based on two sets of single-source multislice spiral CT was proposed with a special reconstruction algorithm. Simulation results using the fan-beam filtered backprojection algorithm with a special interpolation method were presented for both single-source multislice spiral CT and DSDMS-CT. The results of new CT model show that it scans faster than the traditional spiral CT and has a better slice sensitivity profile (SSP) with larger pitch value.
基金This work was supported by the National High Technology Research and Development 863 Program of China under Grant No. 2015AA01A301, the National Natural Science Foundation of China under Grant No. 61332009, the National HeGaoJi Project of China under Grant No. 2013ZX0102-8001-001-001, and the Beijing Municipal Science and Technology Commission under Grant Nos. Z15010101009 and Z151100003615006.
文摘Dataflow architecture has shown its advantages in many high-performance computing cases. In dataflow computing, a large amount of data are frequently transferred among processing elements through the network-on-chip （NoC）. Thus the router design has a significant impact on the performance of dataflow architecture. Common routers are designed for control-flow multi-core architecture and we find they are not suitable for dataflow architecture. In this work, we analyze and extract the features of data transfers in NoCs of dataflow architecture： multiple destinations, high injection rate, and performance sensitive to delay. Based on the three features, we propose a novel and efficient NoC router for dataflow architecture. The proposed router supports multi-destination; thus it can transfer data with multiple destinations in a single transfer. Moreover, the router adopts output buffer to maximize throughput and adopts non-flit packets to minimize transfer delay. Experimental results show that the proposed router can improve the performance of dataflow architecture by 3.6x over a state-of-the-art router.
基金Supported by the National Basic Research 973 Program of China under Grant No.2007CB-310805the National Natural Science Foundation of China under Grant No.61070027+2 种基金the Beijing Natural Science Foundation project under Grant No.4092043the Scienceand Technology Project of State Grid Information&Telecommunication Company Ltd.under Grant No.SGIT[2010]449the Planned Science and Technology Project of Guangdong Province,China under Grant No.2010B050100009
文摘In the research of service composition,it demands efficient algorithms that not only retrieve correct service compositions automatically from thousands of services but also satisfy the quality requirements of different service users.However,most approaches treat these two aspects as two separate problems,automatic service composition and service selection.Although the latest researches realize the restriction of this separate view and some specific methods are proposed,they still suffer from serious limitations in scalability and accuracy when addressing both requirements simultaneously.In order to cope with these limitations and efficiently solve the combined problem which is known as QoS-aware or QoS-driven automatic service composition problem,we propose a new graph search problem,single-source optimal directed acyclic graphs （DAGs）,for the first time.This novel single-source optimal DAGs （SSOD） problem is similar to,but more general than the classical single-source shortest paths （SSSP） problem.In this paper,a new graph model of SSOD problem is proposed and a Sim-Dijkstra algorithm is presented to address the SSOD problem with the time complexity of O（n log n ＋ m） （n and m are the number of nodes and edges in the graph respectively）,and the proofs of its soundness.It is also directly applied to solve the QoS-aware automatic service composition problem,and a service composition tool named QSynth is implemented.Evaluations show that Sim-Dijkstra algorithm achieves superior scalability and efficiency with respect to a large variety of composition scenarios,even more efficient than our worklist algorithm that won the performance championship of Web Services Challenge 2009.
