An account of recent work on supported single‐atom catalyst design is given here for reactions as diverse as the low‐temperature water‐gas shift,methanol steam reforming,selective ethanol dehydrogenation,and select...An account of recent work on supported single‐atom catalyst design is given here for reactions as diverse as the low‐temperature water‐gas shift,methanol steam reforming,selective ethanol dehydrogenation,and selective hydrogenation of alkynes and dienes.It is of fundamental interest to investigate the intrinsic activity and selectivity of the active metal atom site and compare them to the properties of the corresponding metal nanoparticles and sub‐nm clusters.It is also important to understand what constitutes a stable active metal atom site in the various reaction environments,and maximize their loadings to allow us to design robust catalysts for industrial applications.Combined activity and stability studies,ideally following the evolution of the active site as a function of catalyst treatment in real time are recommended.Advanced characterization methods with atomic resolution will play a key role here and will be used to guide the design of new catalysts.展开更多
Because of hydraulic-electromagnetic double supporting forms,the supporting capacity and stiffness of magnetic-liquid double suspension bearing(MLDSB)can be improved sharply and then it is more suitable for medium spe...Because of hydraulic-electromagnetic double supporting forms,the supporting capacity and stiffness of magnetic-liquid double suspension bearing(MLDSB)can be improved sharply and then it is more suitable for medium speed,heavy load and frequent-starting occasions.Due to the multiple uncertainty,such as the coupling,the unmodeled dynamics,the parameter perturbation and the external disturbance perturbation,the robust stability and stiffness of control system of MLDSB are hard to meet the design requirements.Firstly,the structural features and the regulation mechanisms of MLDSB are presented and the radial 4-DOF kinetic equations are established.Secondly,the influence factors of the control system's coupling on unbalanced vibration caused by the deviation of the rotor center of mass are revealed,and then the weighting function of suppressing the unbalanced vibration can be obtained.Finally,H∞ controller of MLDSB is designed with H∞ mixed-sensitivity method,and the control performances of H∞ controller is compared with the state feedback controller.The simulation results show that single degree of freedom(DOF)supporting system of MLDSB with H∞ controller has good robust stability,stiffness and the ability to suppress unbalanced external disturbances.This study can provide the theoretical reference for stabilized suspension and control of MLDSB.展开更多
A practical suspen-dome project, Changzhou Gym roof, is adopted as an example and its transient analysis based on the multi-support excitations of the earthquake wave is carried out. Compared with the single support e...A practical suspen-dome project, Changzhou Gym roof, is adopted as an example and its transient analysis based on the multi-support excitations of the earthquake wave is carried out. Compared with the single support excitation, the position and value of the maximum stress under multi-support excitations both change and the amount of elements with obvious changes is large and more than 70% of the total. Moreover, when other terms are not changed, this influence will decrease as the span decreases, but increa...展开更多
The layout features of unit shafting and their effects on vibration, as well as evaluation criteria, were introduced for a 1000-MW ultra-supercritical turbine-generator unit with Simens technology. Based on vibration ...The layout features of unit shafting and their effects on vibration, as well as evaluation criteria, were introduced for a 1000-MW ultra-supercritical turbine-generator unit with Simens technology. Based on vibration diagnosis and treatment for more than 10 units, some typical vibration faults were summarized, such as the vibration fluctuation of the high pressure (HP) rotor, abnormal vibration increases of the No.3 bearing pedestal and large vibration of the exciter rotor during its critical speed range. The vibration characteristics and the causes of faults and countermeasures were analyzed. Three applications for further illustration were given. The vibration fault identification method, control measures, and applications can provide a reference for vibration diagnoses and treatment of same type units.展开更多
基金financial support of the work by the U.S. Department of Energy (DOE), Office of Science, Basic Energy Sciences (BES), under Awards Grant Number DE-FG02-05ER15730
文摘An account of recent work on supported single‐atom catalyst design is given here for reactions as diverse as the low‐temperature water‐gas shift,methanol steam reforming,selective ethanol dehydrogenation,and selective hydrogenation of alkynes and dienes.It is of fundamental interest to investigate the intrinsic activity and selectivity of the active metal atom site and compare them to the properties of the corresponding metal nanoparticles and sub‐nm clusters.It is also important to understand what constitutes a stable active metal atom site in the various reaction environments,and maximize their loadings to allow us to design robust catalysts for industrial applications.Combined activity and stability studies,ideally following the evolution of the active site as a function of catalyst treatment in real time are recommended.Advanced characterization methods with atomic resolution will play a key role here and will be used to guide the design of new catalysts.
基金Supported by the National Nature Science Foundation of China(No.51705445,52075468)General Project of Natural Science Foundation of Hebei Province(E2020203052)+1 种基金Youth Fund Project of Scientific Research Project of Hebei University(QN202013)Open Project Funding of Jiangsu Provincial Key Laboratory of Advanced Manufacture and Process for Marine Mechanical Equipment and Open Project Funding of Fluid Power Transmission Control Laboratory of Yanshan University.
文摘Because of hydraulic-electromagnetic double supporting forms,the supporting capacity and stiffness of magnetic-liquid double suspension bearing(MLDSB)can be improved sharply and then it is more suitable for medium speed,heavy load and frequent-starting occasions.Due to the multiple uncertainty,such as the coupling,the unmodeled dynamics,the parameter perturbation and the external disturbance perturbation,the robust stability and stiffness of control system of MLDSB are hard to meet the design requirements.Firstly,the structural features and the regulation mechanisms of MLDSB are presented and the radial 4-DOF kinetic equations are established.Secondly,the influence factors of the control system's coupling on unbalanced vibration caused by the deviation of the rotor center of mass are revealed,and then the weighting function of suppressing the unbalanced vibration can be obtained.Finally,H∞ controller of MLDSB is designed with H∞ mixed-sensitivity method,and the control performances of H∞ controller is compared with the state feedback controller.The simulation results show that single degree of freedom(DOF)supporting system of MLDSB with H∞ controller has good robust stability,stiffness and the ability to suppress unbalanced external disturbances.This study can provide the theoretical reference for stabilized suspension and control of MLDSB.
基金Supported by National Natural Science Foundation of China (No. 50778122)Program for New Century Excellent Talents in University (NCET)
文摘A practical suspen-dome project, Changzhou Gym roof, is adopted as an example and its transient analysis based on the multi-support excitations of the earthquake wave is carried out. Compared with the single support excitation, the position and value of the maximum stress under multi-support excitations both change and the amount of elements with obvious changes is large and more than 70% of the total. Moreover, when other terms are not changed, this influence will decrease as the span decreases, but increa...
文摘The layout features of unit shafting and their effects on vibration, as well as evaluation criteria, were introduced for a 1000-MW ultra-supercritical turbine-generator unit with Simens technology. Based on vibration diagnosis and treatment for more than 10 units, some typical vibration faults were summarized, such as the vibration fluctuation of the high pressure (HP) rotor, abnormal vibration increases of the No.3 bearing pedestal and large vibration of the exciter rotor during its critical speed range. The vibration characteristics and the causes of faults and countermeasures were analyzed. Three applications for further illustration were given. The vibration fault identification method, control measures, and applications can provide a reference for vibration diagnoses and treatment of same type units.
