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Improved Interleaved Single-Ended Primary Inductor-Converter forSingle-Phase Grid-Connected System
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作者 T.J.Thomas Thangam K.Muthu Vel 《Intelligent Automation & Soft Computing》 SCIE 2023年第3期3459-3478,共20页
The generation of electricity based on renewable energy sources,parti-cularly Photovoltaic(PV)system has been greatly increased and it is simply insti-gated for both domestic and commercial uses.The power generated fr... The generation of electricity based on renewable energy sources,parti-cularly Photovoltaic(PV)system has been greatly increased and it is simply insti-gated for both domestic and commercial uses.The power generated from the PV system is erratic and hence there is a need for an efficient converter to perform the extraction of maximum power.An improved interleaved Single-ended Primary Inductor-Converter(SEPIC)converter is employed in proposed work to extricate most of power from renewable source.This proposed converter minimizes ripples,reduces electromagnetic interference due tofilter elements and the contin-uous input current improves the power output of PV panel.A Crow Search Algo-rithm(CSA)based Proportional Integral(PI)controller is utilized for controlling the converter switches effectively by optimizing the parameters of PI controller.The optimized PI controller reduces ripples present in Direct Current(DC)vol-tage,maintains constant voltage at proposed converter output and reduces over-shoots with minimum settling and rise time.This voltage is given to single phase grid via 1�Voltage Source Inverter(VSI).The command pulses of 1�VSI are produced by simple PI controller.The response of the proposed converter is thus improved with less input current.After implementing CSA based PI the efficiency of proposed converter obtained is 96%and the Total Harmonic Distor-tion(THD)is found to be 2:4%.The dynamics and closed loop operation is designed and modeled using MATLAB Simulink tool and its behavior is performed. 展开更多
关键词 Improved interleaved DC-DC SEPIC converter crow search algorithm PI controller voltage source inverter PV array single phase grid
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A General Approach for Direct Conversion of Single Phase AC to AC Converter for Induction Heating System
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作者 Dr. P. Umasankar Dr. S. Senthil Kumar 《Circuits and Systems》 2016年第11期3896-3910,共15页
This paper signifies the study of modeling and simulation of a single phase matrix converter for induction heating system. The working principle and the control method, using PID are revealing in detail. The performan... This paper signifies the study of modeling and simulation of a single phase matrix converter for induction heating system. The working principle and the control method, using PID are revealing in detail. The performance of the system is carried out in MATLAB/Simulink environment with pulse width modulation switching strategy by varying the duty cycle. PID control is employed to obtain the better performance for a specified input supply for various output frequencies. The proposed control strategy of AC to AC converter has been discussed with a wide range of operating frequencies and results in low Total Harmonic Distortion. 展开更多
关键词 single phase Matrix Converter PID Control Induction Heating Pulse Width Modulation Total Harmonic Distortion
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Solidification Structure Formation of Undercooled Single Phase Alloys 被引量:4
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作者 Jinfu LI Yaohe ZHOU +1 位作者 Wanqi JIE Gencang YANG 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2002年第4期295-298,共4页
Solidification structure variation of single phase alloy with undercooling prior to nucleation has been widely studied. The progress, especially during the last decade, is reviewed so as to give a comprehensive knowle... Solidification structure variation of single phase alloy with undercooling prior to nucleation has been widely studied. The progress, especially during the last decade, is reviewed so as to give a comprehensive knowledge for it, in which the emphases are laid on the structure evolution mechanism and the potential application. Lastly, the future interesting subjects are presented. 展开更多
关键词 single phase alloy UNDERCOOLING SOLIDIFICATION Microstructure
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Preparation of a single-phase Mg-6Zn alloy via ECAP-stimulated solution treatment 被引量:3
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作者 Kai Yan Huan Liu +4 位作者 Na Feng Jing Bai Honghui Cheng Jingjing Liu Fuyu Huang 《Journal of Magnesium and Alloys》 SCIE EI CAS 2019年第2期305-314,共10页
The solution of the intermetallic phase and the homogenization of composition are important for Mg alloy biomaterials.A single-phase Mg-6Zn alloy with the average grain size of about 20μm was prepared by ECAP process... The solution of the intermetallic phase and the homogenization of composition are important for Mg alloy biomaterials.A single-phase Mg-6Zn alloy with the average grain size of about 20μm was prepared by ECAP processed for six passes at 320°C.It indicated that the ECAP could significantly promote the process of solid solution in Mg-Zn alloy.The results showed that complete dissolution of the intermetallic phase improved the corrosion resistance of Mg-6Zn alloy in 0.9%NaCl solution by turning the corrosion behavior into uniform corrosion and increased the hardness in combination with its smaller grain size. 展开更多
关键词 Mg-6Zn alloy Equal-channel angular pressing(ECAP) Solution treatment single phase Corrosion resistance
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Realization of warm white light emitting in single phase Gd(P_(x)V_(1−x))O_(4):y at% Sm^(3+),1 at% Bi^(3+) phosphor 被引量:3
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作者 Chao Dou Yanzhen Yin +6 位作者 Fei Zheng Zhen Wang Shijia Sun Chen Hu Yang Che Bing Teng Degao Zhong 《Journal of Rare Earths》 SCIE EI CAS CSCD 2022年第4期559-566,I0002,共9页
A series of single phase,warm white light emitting phosphors,Gd(P_(x)V_(1−x))O_(4):y at%Sm^(3+),with 1 at%Bi^(3+) doping concentration were synthesized by high temperature solid state method in this work.The experimen... A series of single phase,warm white light emitting phosphors,Gd(P_(x)V_(1−x))O_(4):y at%Sm^(3+),with 1 at%Bi^(3+) doping concentration were synthesized by high temperature solid state method in this work.The experimental results indicate broadband cyan emission of Bi^(3+)and characteristic orange-red emission of Sm^(3+)can be effectively tuned by changing the ratios of PO^(3−)_(4)/VO^(3−)_(4) in Gd(P_(x)V_(1−x))O_(4):1 at%Sm^(3+),1 at%Bi^(3+),and the energy transfer process among VO^(3−)_(4),Sm^(3+),Bi^(3+) also can be adjusted.Based on this,warm white light emitting can be realized by further optimizing the doping concentration of Sm^(3+) in the phosphors.At 423 K,the PL intensity of Gd(P_(0.7)V_(0.3))O_(4):2 at%Sm^(3+),1 at%Bi^(3+) remains~84.3%of the initial value at 293 K,while the measured quantum efficiency is 67.8%.EL spectrum analysis results of the fabricated white light emitting diode(wLED)based on a 310 nm UV-chip and Gd(P_(0.7)V_(0.3))O4:2 at%Sm^(3+),1 at%Bi^(3+)phosphors imply low correlated color temperature(3132 K)and appropriate color-rending index(R_(a)=82.7).These results demonstrate that Gd(P_(0.7)V_(0.3))O4:2 at%Sm^(3+),1 at%Bi^(3+)is a good candidate for manufacturing UV-activated warm white light emitting diodes. 展开更多
关键词 Warm white light emitting single phase phosphor Color-tunability Rare earths
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Comparison between open phase fault of arc suppression coil and single phase to earth fault in coal mine distribution network 被引量:3
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作者 LI Xiao-bo WANG Chong-lin 《Journal of China University of Mining and Technology》 EI 2008年第3期368-372,共5页
When, in a coal mine distribution network whose neutral point is grounded by an arc suppression coil (ASC), a fault occurs in the ASC, compensation cannot be properly realized. Furthermore, it can damage the safe and ... When, in a coal mine distribution network whose neutral point is grounded by an arc suppression coil (ASC), a fault occurs in the ASC, compensation cannot be properly realized. Furthermore, it can damage the safe and reliable run of the network. We first introduce a three-phase five-column arc suppression coil (TPFCASC) and discuss its autotracking compensation theory. Then we compare the single phase to ground fault of the coal mine distribution network with an open phase fault at the TPFCASC using the Thévenin theory, the symmetrical-component method and the complex sequence network respectively. The results show that, in both types of faults, zero-sequence voltage of the network will appear and the maximum magnitude of this zero-sequence voltage is different in both faults. Based on this situation, a protection for the open phase fault at the TPFCASC should be estab-lished. 展开更多
关键词 open phase PROTECTION single phase to ground fault three-phase five-column arc suppression coil (TPFCASC)
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Novel Traveling Wave Sandwich Piezoelectric Transducer with Single Phase Drive:Theoretical Modeling,Experimental Validation,and Application Investigation 被引量:1
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作者 Liang Wang Fushi Bai +2 位作者 Viktor Hofmann Jiamei Jin Jens Twiefel 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2021年第5期206-225,共20页
Most of traditional traveling wave piezoelectric transducers are driven by two phase different excitation signals,leading to a complex control system and seriously limiting their applications in industry.To overcome t... Most of traditional traveling wave piezoelectric transducers are driven by two phase different excitation signals,leading to a complex control system and seriously limiting their applications in industry.To overcome these issues,a novel traveling wave sandwich piezoelectric transducer with a single-phase drive is proposed in this study.Traveling waves are produced in two driving rings of the transducer while the longitudinal vibration is excited in its sandwich composite beam,due to the coupling property of the combined structure.This results in the production of elliptical motions in the two driving rings to achieve the drive function.An analytical model is firstly developed using the transfer matrix method to analyze the dynamic behavior of the proposed transducer.Its vibration characteristics are measured and compared with computational results to validate the effectiveness of the proposed analytical model.Besides,the driving concept of the transducer is investigated by computing the motion trajectory of surface points of the driving ring and the quality of traveling wave of the driving ring.Additionally,application example investigations on the driving effect of the proposed transducer are carried out by constructing and assembling a tracked mobile system.Experimental results indicated that 1)the assembled tracked mobile system moved in the driving frequency of 19410 Hz corresponding to its maximum mean velocity through frequency sensitivity experiments;2)motion characteristic and traction performance measurements of the system prototype presented its maximum mean velocity with 59 mm/s and its maximum stalling traction force with 1.65 N,at the excitation voltage of 500 V_(RMS).These experimental results demonstrate the feasibility of the proposed traveling wave sandwich piezoelectric transducer. 展开更多
关键词 Traveling wave Sandwich piezoelectric transducer single phase excitation Transfer matrix method Ultrasonic motor
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Microstructure,Mechanical Properties and Corrosion Behavior of Extruded Mg–Zn–Ag Alloys with Single-Phase Structure 被引量:4
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作者 Hong Zhao Li-Qing Wang +3 位作者 Yu-Ping Ren Bo Yang Song Li Gao-Wu Qin 《Acta Metallurgica Sinica(English Letters)》 SCIE EI CAS CSCD 2018年第6期575-583,共9页
Mg–Zn–Ag alloys have been extensively studied in recent years for potential biodegradable implants due to their unique mechanical properties,biodegradability and biocompatibility.In the present study,Mg–3Zn-x Ag(w... Mg–Zn–Ag alloys have been extensively studied in recent years for potential biodegradable implants due to their unique mechanical properties,biodegradability and biocompatibility.In the present study,Mg–3Zn-x Ag(wt%,x=0.2,0.5 and0.8)alloys with single-phase crystal structure were prepared by backward extrusion at 340°C.The addition of Ag element into Mg–3Zn slightly influences the ultimate tensile strength and microstructure,but the elongation firstly increases from12%to 19.8%and then decreases from 19.8%to 9.9%with the increment of Ag concentration.The tensile yield strength,ultimate tensile strength and elongation of Mg–3Zn–0.2Ag alloy reach up to 142,234 MPa and 19.8%,respectively,which are the best mechanical performance of Mg–Zn–Ag alloys in the present work.The extruded Mg–3Zn–0.2Ag alloy also possesses the best corrosion behavior with the corresponding corrosion rate of 3.2 mm/year in immersion test,which could be explained by the single-phase and uniformly distributed grain structure,and the fewer twinning. 展开更多
关键词 Mg–Zn–Ag single phase Backward extrusion Mechanical performance Corrosion behavior
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A new measuring technique in detecting of high voltage three phase induction motor for single phasing
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作者 Ali M El-Rifaie Hala M Abdel Mageed 《Journal of Measurement Science and Instrumentation》 CAS 2014年第3期6-11,共6页
Open phase in three phase induction motors is a common fault that can occur as a result of a fuse blowing or a pro- tective device failing on one phase of the motor. This paper introduces a new method,which is based o... Open phase in three phase induction motors is a common fault that can occur as a result of a fuse blowing or a pro- tective device failing on one phase of the motor. This paper introduces a new method,which is based on the transient mea- surement and can distinguish the fault of one phase connecting ground. The method has been proved to be in correspondence with the simulation results by Matlab and LabVIEW in practice, The method has merits of simplicity, accuracy and ease of USe. 展开更多
关键词 high voltage induction motor transient protection single phasing detection
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PREPARATION OF A SINGLE PHASE R_(3)(Fe,Mo)_(29)(R=Ce,Nd,Sm,Gd,Tb,Dy AND Y)
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作者 Pan Hongge Chen Weixiang +1 位作者 Chen Yun Chen Changpin 《中国有色金属学会会刊:英文版》 EI CSCD 1998年第3期37-41,共5页
1INTRODUCTIONInrecentyears,researchersinthefieldofpermanentmagneticmaterialshavepaidmoreattentiontothenewtyp... 1INTRODUCTIONInrecentyears,researchersinthefieldofpermanentmagneticmaterialshavepaidmoreattentiontothenewtypeofrareearthiron... 展开更多
关键词 3:29 compounds PREPARATION a single phase
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A Modified Regression Estimator for Single Phase Sampling in the Presence of Observational Errors
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作者 Nujayma M. A. Salim Christopher O. Onyango 《Open Journal of Statistics》 2022年第2期175-187,共13页
In this paper, a regression method of estimation has been used to derive the mean estimate of the survey variable using simple random sampling without replacement in the presence of observational errors. Two covariate... In this paper, a regression method of estimation has been used to derive the mean estimate of the survey variable using simple random sampling without replacement in the presence of observational errors. Two covariates were used and a case where the observational errors were in both the survey variable and the covariates was considered. The inclusion of observational errors was due to the fact that data collected through surveys are often not free from errors that occur during observation. These errors can occur due to over-reporting, under-reporting, memory failure by the respondents or use of imprecise tools of data collection. The expression of mean squared error (MSE) based on the obtained estimator has been derived to the first degree of approximation. The results of a simulation study show that the derived modified regression mean estimator under observational errors is more efficient than the mean per unit estimator and some other existing estimators. The proposed estimator can therefore be used in estimating a finite population mean, while considering observational errors that may occur during a study. 展开更多
关键词 ESTIMATE Regression COVARIATES single phase Sampling Observational Errors Mean Squared Error
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Single Phase Induction Motor Drive with Restrained Speed and Torque Ripples Using Neural Network Predictive Controller
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作者 S. Saravanan K. Geetha 《Circuits and Systems》 2016年第11期3670-3684,共15页
In industrial drives, electric motors are extensively utilized to impart motion control and induction motors are the most familiar drive at present due to its extensive performance characteristic similar with that of ... In industrial drives, electric motors are extensively utilized to impart motion control and induction motors are the most familiar drive at present due to its extensive performance characteristic similar with that of DC drives. Precise control of drives is the main attribute in industries to optimize the performance and to increase its production rate. In motion control, the major considerations are the torque and speed ripples. Design of controllers has become increasingly complex to such systems for better management of energy and raw materials to attain optimal performance. Meager parameter appraisal results are unsuitable, leading to unstable operation. The rapid intensification of digital computer revolutionizes to practice precise control and allows implementation of advanced control strategy to extremely multifaceted systems. To solve complex control problems, model predictive control is an authoritative scheme, which exploits an explicit model of the process to be controlled. This paper presents a predictive control strategy by a neural network predictive controller based single phase induction motor drive to minimize the speed and torque ripples. The proposed method exhibits better performance than the conventional controller and validity of the proposed method is verified by the simulation results using MATLAB software. 展开更多
关键词 Dynamic Model Low Torque Ripples Neural Model Neural Network Predictive Controller Unstable Operation single phase Induction Motor Variable Speed Drives
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Micrometer-scale indirect photopatterning of RGB OLED emissive layers in single phase network structure
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作者 Seunghan Lee Hyobin Ham +11 位作者 Shahid Ameen Byung Hak Jhun SeungHwan Roh Hyeono Yee Chang Hyeok Lim Yuchan Heo Hyukmin Kweon Dongheon Han Do Hwan Kim Youngmin You BongSoo Kim Moon Sung Kang 《Light(Science & Applications)》 2025年第9期2642-2655,共14页
Organic light-emitting diodes(OLEDs)used in virtual and augmented reality displays require micrometer-scale red-green-blue(RGB)pixel patterns in the emissive layer(EML).However,conventional patterning methods based on... Organic light-emitting diodes(OLEDs)used in virtual and augmented reality displays require micrometer-scale red-green-blue(RGB)pixel patterns in the emissive layer(EML).However,conventional patterning methods based on evaporation and shadow masks can only produce patterns larger than tens of micrometers owing to the geometric constraint of the mask.Herein,an indirect method for photopatterning solution-processed OLED EMLs is proposed,which can be used to form micrometer-scale RGB pixel patterns without involving direct exposure to UV radiation or harsh etching processes on EMLs.EMLs can be patterned byⅰ)forming a sacrificial photoresist(PR)pattern,ⅱ)spin-coating an EML film,ⅲ)converting the EML film into a single-phase network(SPN)structure by crosslinking vinylbenzyl-group-appended hosts and dopants at a low temperature,andⅳ)stripping the pre-formed PR pattern.Furthermore,repeating the process thrice results in the formation of RGB EML patterns.During the repeated process,the sacrificial PR pattern serves as a protective layer for the underlying EML pattern,effectively preventing the EML pattern from being exposed to solutions in subsequent processes.Using a conventional photolithography setup,we produced sets of RGB EML patterns with densities exceeding 3000 patterns/in.,which indicated the potential of the method for industrial use. 展开更多
关键词 shadow masks emissive layer virtual augmented reality displays emissive layer eml howeverconventional patterning methods micrometer scale photopatterning single phase network structure indirect photopatterning
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Rectifier Configurations Based on Harmonic Injecting and Counteracting Principle
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作者 何丹 戴先中 +1 位作者 肖仁良 徐以荣 《Journal of Southeast University(English Edition)》 EI CAS 1999年第1期81-88,共8页
On the basis of detailed analysis of a novel harmonic counteracting method which can be used to effectively compensate the supply line harmonic currents of a passive single phase diode bridge rectifier, this paper pr... On the basis of detailed analysis of a novel harmonic counteracting method which can be used to effectively compensate the supply line harmonic currents of a passive single phase diode bridge rectifier, this paper presents two simpler single phase diode bridge rectifier configurations and their alternatives which can achieve low supply line current THD(total harmonic distortion) too. Moreover, this paper also proposes a few passive hamonic counteracting networks for multi single phase rectifiers which are connected in parallel. 展开更多
关键词 single phase rectifier harmonic compensation current injection THD
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Methodology Approach Using Harmonic Synthesis as Simulation Method for Investigation of Power Network with Non-Linear Loads 被引量:2
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作者 M. Befiova B. Dobrucky M. Pokorny 《Journal of Energy and Power Engineering》 2010年第11期36-42,共7页
The paper deals with analysis and synthesis of non-harmonic and non-linear sources and appliances, and their interaction with harmonic power supply network. Basic idea is based on knowledge of harmonic spectrum of the... The paper deals with analysis and synthesis of non-harmonic and non-linear sources and appliances, and their interaction with harmonic power supply network. Basic idea is based on knowledge of harmonic spectrum of the sources and/or appliances, respectively. Obviously, one need to know voltage harmonic components of voltage sources (renewable with inverters,...), and current harmonic components generated by non-linear appliances (rectifiers,...). Method of investigation lies on decomposition of real electric circuit into n-harmonic separated equivalent schemes for each harmonic component. Then transient analysis will be done for each scheme separately using "impedance harmonic matrices". The important fact is that each equivalent scheme is now linearized and therefore easily calculated. Finally, the effects of each investigated schemes arc summed into resulting quantities of real non-linear electric circuit. 展开更多
关键词 HARMONICS MODELING SIMULATION converter circuits single phase systems Fourier analysis.
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Microstructure and mechanical properties of CoCrNi-Mo medium entropy alloys:Experiments and first-principle calculations 被引量:8
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作者 Ruobin Chang Wei Fang +6 位作者 Jiaohui Yan Haoyang Yu Xi Bai Jia Li Shiying Wang Shijian Zheng Fuxing Yin 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2021年第3期25-33,共9页
The effect of Mo additions on the microstructures and mechanical properties of CoCrNi alloys was investigated,meanwhile,ab initio calculations are performed to quantitatively evaluate the lattice distortion and stacki... The effect of Mo additions on the microstructures and mechanical properties of CoCrNi alloys was investigated,meanwhile,ab initio calculations are performed to quantitatively evaluate the lattice distortion and stacking fault energy(SFE).The yield strength,ultimate tensile strength,and elongation of(CoCrNi)_(97)Mo_(3)alloy are 475 MPa,983 MPa and 69%,respectively.The yield strength is increased by~30%and high ductility is maintained,in comparison with CoCrNi alloy.Besides the nano-twins and dislocations,the higher density of stacking faults is induced during the tensile deformation for(CoCrNi)_(97)Mo_(3)alloy.Ab initio calculation results indicate the mean square atomic displacement(MSAD)and SFE value of(CoCrNi)_(97)Mo_(3)alloy is 42.6 pm^(2)and-40.4 mJ/m^(2)at 0 K,respectively.The relationship between mechanical properties and MSAD,SFE for various multiple principal element alloys is discussed. 展开更多
关键词 Medium entropy alloys Severe lattice distortion Stacking fault energy single phase Mechanical properties Ab initio calculations High entropy alloys
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Influence of Co Content on Raman and Photoluminescence Spectra of Co Doped ZnO Nanowires 被引量:4
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作者 Y.Q. Chang P.W. Wang +2 位作者 S.L. Ni Y. Long X.D. Li 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2012年第4期313-316,共4页
Co doped ZnO nanowires with different Co contents have been fabricated by a chemical vapor deposition method. X-ray diffraction results show that all the samples are of single phase and crystallize in wurtzite ZnO str... Co doped ZnO nanowires with different Co contents have been fabricated by a chemical vapor deposition method. X-ray diffraction results show that all the samples are of single phase and crystallize in wurtzite ZnO structure. The lattice parameter a increases with increasing Co content, while the parameter c has no obvious change with increasing Co. Raman spectra show that the nonpolar E2(High) mode becomes broad and weak with the doping of Co, which indicates that the incorporation of Co causes structural disorder in the crystalline columnar ZnO lattice. The photolurninescence spectra exhibit that the position of the ultraviolet emission shifts to short wavelength and the intensity decreases with increasing Co. The green emission is affected by two contrary factors. It is increased by the introduced defects, but suppressed by the interaction between Co doping and native defects and the later affects it more significantly. 展开更多
关键词 Co doped ZnO nanowires RAMAN PHOTOLUMINESCENCE single phase
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Instantaneous power calculation based on intrinsic frequency of single-phase virtual synchronous generator 被引量:6
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作者 Yangyang ZHAO Jianyun CHAI +1 位作者 Shien WANG Kai SUN 《Journal of Modern Power Systems and Clean Energy》 SCIE EI 2017年第6期970-978,共9页
In order to enhance the stability of single-phase microgrid,virtual synchronous generator(VSG)control method is investigated in this paper.Its electromagnetic model and electromechanical model are established to illus... In order to enhance the stability of single-phase microgrid,virtual synchronous generator(VSG)control method is investigated in this paper.Its electromagnetic model and electromechanical model are established to illustrate the performance of VSG.Considering the 2 nd fluctuation of fundamental-frequency in the output power,an instantaneous power calculation strategy is proposed based on the intrinsic frequency of single-phase VSG.Besides,a virtual power calculation method is presented to achieve islanded/grid-connected seamless transition.Stability analysis and comparison simulation results demonstrate the correctness of the presented power calculation method.At last,the effectiveness of the proposed approach is verified by comparison experiments of islanded/gridconnected operations in a 500 VA single-phase inverter. 展开更多
关键词 Virtual synchronous generator single phase inverter Instantaneous power calculation Seamless transition
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Advanced partial nucleation for single-phase FA0.92MA0.08PbI3-based high-efficiency perovskite solar cells 被引量:3
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作者 Pengju Shi Yong Ding +7 位作者 Cheng Liu Yi Yang Zulqarnain Arain Molang Cai Yingke Ren Tasawar Hayat Ahmed Alsaedi Songyuan Dai 《Science China Materials》 SCIE EI CSCD 2019年第12期1846-1856,共11页
To date, extensive research has been carried out,with considerable success, on the development of highperformance perovskite solar cells(PSCs). Owing to its wide absorption range and remarkable thermal stability, the ... To date, extensive research has been carried out,with considerable success, on the development of highperformance perovskite solar cells(PSCs). Owing to its wide absorption range and remarkable thermal stability, the mixedcation perovskite FAxMA1-xPbI3(formamidinium/methylammonium lead iodide) promises high performance. However, the ratio of the mixed cations in the perovskite film has proved difficult to control with precursor solution. In addition, the FAxMA1-xPbI3 films contain a high percentage of MA+and suffer from serious phase separation and high trap states, resulting in inferior photovoltaic performance. In this study, to suppress phase separation, a post-processing method was developed to partially nucleate before annealing, by treating the as-prepared intermediate phase FAI-Pb I2-DMSO(DMSO: dimethylsulfoxide) with mixed FAI/MAI solution. It was found that in the final perovskite, FA0.92MA0.08 PbI3, defects were substantially reduced because the analogous molecular structure initiated ion exchange in the post-processed thin perovskite films, which advanced partial nucleation. As a result, the increased light harvesting and reduced trap states contributed to the enhancement of open-circuit voltage and short-circuit current. The PSCs produced by the post-processing method presented reliable reproducibility, with a maximum power conversion efficiency of 20.80% and a degradation of ~30% for 80 days in standard atmospheric conditions. 展开更多
关键词 perovskite solar cell (PSC) mixed cations partialnucleation single phase defects stability
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Air oxidation of Cu-50Ni and Cu-70Ni alloys at 800℃ 被引量:1
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作者 曹中秋 牛焱 F.Gesmundo 《中国有色金属学会会刊:英文版》 CSCD 2001年第4期499-502,共4页
The air oxidation of Cu Ni alloys with 50% and 70% nickel (mole fraction) at 800?℃ was studied. The kinetic curves for the oxidation of the two alloys are complex and deviate from the parabolic rate law. Typical doub... The air oxidation of Cu Ni alloys with 50% and 70% nickel (mole fraction) at 800?℃ was studied. The kinetic curves for the oxidation of the two alloys are complex and deviate from the parabolic rate law. Typical double layered scales are produced, which consist of a CuO outer layer and an inner layer containing a mixture of Cu 2O and NiO with many pores. Cu 50Ni presents a small degree of internal oxidation of nickel, which is observed in many binary double phase systems, but is quite rare in single phase systems. 展开更多
关键词 copper nickel alloy single phase high temperature oxidation
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