Understanding the complex flow behavior along a rough rock fracture under high-temperature,high-stress,and high-seepage pressure(HTHM)coupling conditions is of great significance for optimizing deep resource extractio...Understanding the complex flow behavior along a rough rock fracture under high-temperature,high-stress,and high-seepage pressure(HTHM)coupling conditions is of great significance for optimizing deep resource extraction.This study investigates the complex flow behavior of a single rock fracture under coupled HTHM conditions using a self-developed multi-field coupling experimental system,considering real-time high temperatures(20–90℃),confining pressures(30–120 MPa),and seepage pressures(5–60 MPa).Experimental results show that as confining pressure increases,two typical nonlinear flow behaviors are observed,which are Forchheimer flow and low-velocity nonlinear flow.The increase in temperature and decrease in roughness significantly promote the fluid flow and enhance the nonlinear relationship between the volumetric flow rate and the hydraulic gradient at lower confining pressures(30 MPa).However,the change in temperature and fracture surface roughness does not affect the nonlinear type of fluid flow.Under a given hydraulic gradient,the influence of temperature and fracture roughness on the volumetric flow rate varies with changes in confining pressure.Additionally,this study considers both the viscous and inertial terms,and a modified Forchheimer equation is proposed using two parameters:the contact area ratio and the thermal expansion coefficient of the rock.The proposed model can effectively predict the nonlinear flow behavior of fluid along rough fractured rocks under varying temperatures and surface roughness.The experimental results and the proposed model provide valuable data and theoretical guidance for deep oil and gas exploration as well as hydraulic fracturing design.展开更多
Deep tight reservoirs exhibit complex stress and seepage fields due to varying pore structures,thus the seepage characteristics are significant for enhancing oil production.This study conducted triaxial compression an...Deep tight reservoirs exhibit complex stress and seepage fields due to varying pore structures,thus the seepage characteristics are significant for enhancing oil production.This study conducted triaxial compression and permeability tests to investigate the mechanical and seepage properties of tight sandstone.A digital core of tight sandstone was built using Computed Tomography(CT)scanning,which was divided into matrix and pore phases by a pore equivalent diameter threshold.A fluid-solid coupling model was established to investigate the seepage characteristics at micro-scale.The results showed that increasing the confining pressure decreased porosity,permeability,and flow velocity,with the pore phase becoming the dominant seepage channel.Cracks and large pores closed first under increasing pressure,resulted in a steep drop in permeability.However,permeability slightly decreased under high confining pressure,which followed a first-order exponential function.Flow velocity increased with seepage pressure.And the damage mainly occurred in stress-concentration regions under low seepage pressure.Seepage behavior followed linear Darcy flow,the damage emerged at seepage entrances under high pressure,which decreased rock elastic modulus and significantly increased permeability.展开更多
Deep underground excavation causes considerable unloading effects,leading to a pronounced bias pressure phenomenon.The deformation and seepage characteristics of rock masses under different gas and confining pressures...Deep underground excavation causes considerable unloading effects,leading to a pronounced bias pressure phenomenon.The deformation and seepage characteristics of rock masses under different gas and confining pressures were investigated via triaxial loading and unloading seepage tests.When the influential coefficient of effective confining pressure(β)is less than 0.065,the seepage force considerably weakens the strength of fractured rock masses.Conversely,whenβis greater than 0.065,the opposite is true.Moreover,the increase in the axial load leads to an increase in the precast fracture volumetric strain,which is the main reason for the increase in fracture permeability.This effect is particularly significant during the unloading stage.Based on the test results,a method for calculating the dynamic seepage evolution of rock masses,considering the effects of rock mass damage and fracture deformation,is introduced,and the effectiveness of the calculation is validated.The entire description of the seepage under loading and unloading was accomplished.The equivalent relationship between the lateral and normal stresses on fracture surfaces ranges from 0.001 to 0.1,showing an exponential variation between the lateral stress influence coefficient on normal deformation(χ)and seepage pressure.Before the failure of the rock mass,the seepage in the fractures was in a linear laminar flow state.However,after the failure,when the gas pressure reached 2 MPa,the flow state in the fractures transitioned to nonlinear laminar flow.The results are important for predicting hazardous gas leaks during deep underground engineering excavation.展开更多
Hydraulic fracturing technology has played an important role in the exploitation of unconventional oil and gas resources,however,its application to gas hydrate reservoirs has been rarely studied.Currently,there is sti...Hydraulic fracturing technology has played an important role in the exploitation of unconventional oil and gas resources,however,its application to gas hydrate reservoirs has been rarely studied.Currently,there is still limited understanding of the propagation and extension of fractures around the wellbore during the fracturing process of horizontal wells in hydrate reservoirs,as well as the stress interference patterns between fractures.This study simulates hydraulic fracturing processes in hydrate reservoirs using a fluidsolid coupling discrete element method(DEM),and analyzes the impacts of hydrate saturation and geological and engineering factors on fracture extension and stress disturbance.The results show that hydraulic fracturing is more effective when hydrate saturation exceeds 30%and that fracture pressure increases with saturation.The increase in horizontal stress differential enhances the directionality of fracture propagation and reduces stress disturbance.The distribution uniformity index(DUI)reveals that injection pressure is directly proportional to the number of main fractures and inversely proportional to fracturing time,with fracturing efficiency depending on the spacing between injection points and the distance between wells.This work may provide reference for the commercial exploitation of natural gas hydrates.展开更多
In this investigation,the coupling losses caused by Fresnel reflection,core misalignment between single mode fiber(SMF)and HC-PCF are analyzed.A novel solution proposed from this research will reduce the coupling loss...In this investigation,the coupling losses caused by Fresnel reflection,core misalignment between single mode fiber(SMF)and HC-PCF are analyzed.A novel solution proposed from this research will reduce the coupling losses by using a T-type tube as a connector.Meanwhile,the theoretically calculated optimized gaps are at 15μm in SMF-HCPCF direction and 25μm in HCPCF-SMF direction.Thus,an experiment has been carried out,and the results of the practical gap in the above mentioned two directions have also been obtained.Furthermore,compared with detection by traditional methods,the proposed new detection method with PCF can remarkably enhance the Raman spectroscopy signal.Finally,the prospect of using the combination of HC-PCF and Raman spectroscopy in gas-cell detection has been demonstrated by using oxygen and nitrogen.展开更多
Palladium(Pd)‐based catalysts are essential to drive high‐performance Suzuki coupling reactions,which are powerful tools for the synthesis of functional organic compounds.Herein,we developed a solution‐rapid‐annea...Palladium(Pd)‐based catalysts are essential to drive high‐performance Suzuki coupling reactions,which are powerful tools for the synthesis of functional organic compounds.Herein,we developed a solution‐rapid‐annealing process to stabilize nitrogen‐mesoporous carbon supported Pd single‐atom/cluster(Pd/NMC)material,which provided a catalyst with superior performance for Suzuki coupling reactions.In comparison with commercial palladium/carbon(Pd/C)catalysts,the Pd/NMC catalyst exhibited significantly boosted activity(100%selectivity and 95%yield)and excellent stability(almost no decay in activity after 10 reuse cycles)for the Suzuki coupling reactions of chlorobenzenes,together with superior yield and excellent selectivity in the fields of the board scope of the reactants.Moreover,our newly developed rapid annealing process of precursor solutions is applied as a generalized method to stabilize metal clusters(e.g.Pd,Pt,Ru),opening new possibilities in the construction of efficient highly dispersed metal atom and sub‐nanometer cluster catalysts with high performance.展开更多
Cavity optomechanical systems provide powerful platforms to manipulate photons and phonons, open potential ap- plications for modern optical communications and precise measurements. With the refrigeration and ground-s...Cavity optomechanical systems provide powerful platforms to manipulate photons and phonons, open potential ap- plications for modern optical communications and precise measurements. With the refrigeration and ground-state cooling technologies, studies of cavity optomechanics are making significant progress towards the quantum regime including non- classical state preparation, quantum state tomography, quantum information processing, and future quantum internet. With further research, it is found that abundant physical phenomena and important applications in both classical and quan- tum regimes appeal as they have a strong optomechanical nonlinearity, which essentially depends on the single-photon optomechanical coupling strength. Thus, engineering the optomechanical interactions and improving the single-photon optomechanical coupling strength become very important subjects. In this article, we first review several mechanisms, theoretically proposed for enhancing optomechanical coupling. Then, we review the experimental progresses on enhancing optomechanical coupling by optimizing its structure and fabrication process. Finally, we review how to use novel structures and materials to enhance the optomechanical coupling strength. The manipulations of the photons and phonons at the level of strong optomechanical coupling are also summarized.展开更多
Engineering the electronic structure of surface active sites at the atomic level can be an efficient way to modulate the reactivity of catalysts.Herein,we report the rational tuning of surface electronic structure of ...Engineering the electronic structure of surface active sites at the atomic level can be an efficient way to modulate the reactivity of catalysts.Herein,we report the rational tuning of surface electronic structure of FePS_(3) nanosheets(NSs)by anchoring atomically dispersed metal atom.Theoretical calculations predict that the strong electronic coupling effect in single-atom Ni-FePS_(3) facilitates electron aggregation from Fe atom to the nearby Ni-S bond and enhances the electron-transfer of Ni and S sites,which balances the oxygen species adsorption capacity,reinforces water adsorption and dissociation process to accelerate corresponding oxygen evolution reaction(OER)and hydrogen evolution reaction(HER).The optimal Ni-FePS_(3)NSs/C exhibits outstanding electrochemical water-splitting activities,delivering an overpotential of 287 mV at the current density of 10 mA cm^(-2) and a Tafel slope of 41.1 mV dec^(-1) for OER;as well as an overpotential decrease of 219 mV for HER compared with pure FePS_(3)NSs/C.The concept of electronic coupling interaction between the substrate and implanted single active species offers an additional method for catalyst design and beyond.展开更多
The influence of temperature on mode coupling effect in piezoelectric vibrators remains unclear.In this work,we discuss the influence of temperature on two-dimensional(2D)mode coupling effect and electromechanical cou...The influence of temperature on mode coupling effect in piezoelectric vibrators remains unclear.In this work,we discuss the influence of temperature on two-dimensional(2D)mode coupling effect and electromechanical coupling coefficient of cylindrical[001]c-poled Mn-doped 0.24PIN-0.46PMN-0.30PT piezoelectric single-crystal vibrator with an arbitrary configuration ratio.The electromechanical coupling coefficient kt decreases with temperature increasing,whereas k33 is largely invariant in a temperature range of 25℃-55℃.With the increase of temperature,the shift in the‘mode dividing point’increases the scale of the poling direction of the piezoelectric vibrator.The temperature has little effect on coupling constantΓ.At a given temperature,the coupling constantΓof the cylindrical vibrator is slightly greater than that of the rectangular vibrator.When the temperature changes,the applicability index(M)values of the two piezoelectric vibrators are close to 1,indicating that the coupling theory can be applied to piezoelectric vibrators made of late-model piezoelectric single crystals.展开更多
Permafrost is widely distributed in China and around the world.In permafrost regions,soil frost heave and thawing are severe and frequent,and can destabilize pile foundations.To this end,a finite element model of a si...Permafrost is widely distributed in China and around the world.In permafrost regions,soil frost heave and thawing are severe and frequent,and can destabilize pile foundations.To this end,a finite element model of a single pile in frozen soil is established to investigate the frost heave and frost jacking response to ensure its safety in the Qinghai-Tibet Plateau.Firstly,a hydro-thermal coupling model of a single pile in frozen soil is established based on coupling parameters and initial and boundary conditions.Then the temperature and moisture distributions are analyzed through the established coupling model.A hydro-thermo-mechanical coupling model is developed by importing the ice content and temperature results.Simulation results indicate that the amount of frost heave is greater at locations closer to the ground surface,and the displacement is smaller for frozen soil that is closer to the side of the pile.The results on frost jacking behavior of piles from this study can serve as a reference for the design,construction and maintenance of foundations.展开更多
Gradient-index rod lens (GRIN-lens) whose pitch is ordinary value with bevel ferrule coupling system is analyzed, an equivalent method which can be used to analyze this system is put forward, and a general formula for...Gradient-index rod lens (GRIN-lens) whose pitch is ordinary value with bevel ferrule coupling system is analyzed, an equivalent method which can be used to analyze this system is put forward, and a general formula for determining the coupling loss with axes mismatch, radial mismatch, and angular mismatch is derived by use of the Gaussian field approximation and mode-field coupling theory. The experimental results are in good agreement with the theory prediction. It indicates that these formulas are suitable to analyze the gradient-index rod lens coupling system with pigtail fiber.展开更多
An effective method is introduced to compensate the effects of mutual coupling for the Estimation of Signal Parameter via Rotational Invariance Techniques (ESPRIT) direction finding algorithm in application of signal ...An effective method is introduced to compensate the effects of mutual coupling for the Estimation of Signal Parameter via Rotational Invariance Techniques (ESPRIT) direction finding algorithm in application of signal snapshot array processing.Changing the covariance matrix into a Teoplitz matrix can achieve high resolution in the Direction Of Arrive (DOA) estimation.How the mutual coupling affects the array antennas has been discussed and a new definition of mutual im- pedance has been used to characterize the mutual coupling effects between the array elements.Based on the new mutual impedance matrix,a practical method is presented to eliminate the effects of mutual coupling for ESPRIT in the single snapshot data processing.The simulation results show that, this new method not only properly reduces the effects of mutual coupling,but also maintains its steady performance even for weak signals.展开更多
The single photon frequency conversion is investigated theoretically in the system composed of a V-type system chiral coupling to a pair of waveguides. The single photon scattering amplitudes are obtained using the re...The single photon frequency conversion is investigated theoretically in the system composed of a V-type system chiral coupling to a pair of waveguides. The single photon scattering amplitudes are obtained using the real-space Hamiltonian. The calculated results show that the probability of single photon frequency down-or up-conversion can reach a unit by choosing appropriate parameters in the non-dissipative system with perfect chiral coupling.We present a nonreciprocal single photon beam splitter whose frequency of the output photon is different from that of the input photon. The influences of dissipations and non-perfect chiral coupling on the single frequency conversion are also shown. Our results may be useful in designing quantum devices at the single-photon level.展开更多
The fluid-solid coupling theory, an interdisciplinary science between hydrodynamics and solid mechanics, is an important tool for response analysis and direct design of structures in naval architecture and ocean engin...The fluid-solid coupling theory, an interdisciplinary science between hydrodynamics and solid mechanics, is an important tool for response analysis and direct design of structures in naval architecture and ocean engineering. By applying the corresponding relations between generalized forces and generalized displacements, convolutions were performed between the basic equations of elasto-dynamics in the primary space and corresponding virtual quantities. The results were integrated and then added algebraically. In light of the fact that body forces and surface forces are both follower forces, the generalized quasi-complementary energy principle with two kinds of variables for an initial value problem is established in non-conservative systems. Using the generalized quasi-complementary energy principle to deal with the fluid-solid coupling problem and to analyze the dynamic response of structures, a method for using two kinds of variables simultaneously for calculation of force and displacement was derived.展开更多
Abstract： A joint solution model of variabk：-mass flow in two-phase region and fluid-solid coupling heat transfer, concerned about the charge process of variable-mass thermodynamic system, is built up and calculated...Abstract： A joint solution model of variabk：-mass flow in two-phase region and fluid-solid coupling heat transfer, concerned about the charge process of variable-mass thermodynamic system, is built up and calculated by the finite element method （FEM）. The results are basically consistent with relative experimental data. The calculated average heat transfer coefficient reaches 1.7~105 W/（m2. K）. When the equal percentage valve is used, the system needs the minimum requirements of valve control, but brings the highest construction cost. With the： decrease of initial steam pressure, the heat transfer intensity also weakens but the steam flow increases. With the initial water filling coefficient increasing or the temperature of steam supply decreasing, the amount of accumulative steam flow increases with the growth of steam pressure. When the pressure of steam supply drops, the steam flow gradient increases during the maximum opening period of control valve, and causes the maximum steam flow to increase.展开更多
The seismic response characteristics of underground structures in saturated soils are investigated.A fully fluid-solid coupling dynamic model is developed and implemented into ABAQUS with a user-defined element to sim...The seismic response characteristics of underground structures in saturated soils are investigated.A fully fluid-solid coupling dynamic model is developed and implemented into ABAQUS with a user-defined element to simulate the dynamic behavior of saturated soils.The accuracy of the model is validated using a classic example in literature.The performance of the model is verified by its application on simulating the seismic response characteristics of a subway station built in saturated soils.The merits of the model are demonstrated by comparing the difference of the seismic response of an underground structure in saturated soils between using the fully coupling model and a single-phase medium model.The study finds that the fully coupling model developed herein can simulate the dynamic response characteristics of the underground structures in saturated soils with high accuracy.The seismic response of the underground structure tends to be underestimated by using the single-phase medium model compared with using the fully coupling model,which provides a weaker confining action to the underground structure.展开更多
Due to their potential properties unlike traditional materials and structures,elastic wave metamaterials have received significant interests in recent years.With the coupling between the acoustic and vibration,their m...Due to their potential properties unlike traditional materials and structures,elastic wave metamaterials have received significant interests in recent years.With the coupling between the acoustic and vibration,their mechanical characteristics can be tuned by the active feedback control system at low frequency ranges in which the traditional passive control is limited.This work illustrates that the superior performances of the effective mass density and sound pressure level(SPL)of an elastic wave metamaterial can be significantly changed by the active control,in which the periodic array of local resonators and orthogonal stiffeners are included.Significantly,based on the locally resonant mechanism,the negative density occurs over a frequency range.Due to the effects of lattice constant,structural damping and other parameters,the SPL with the function of fluid-solid coupling are illustrated and discussed.展开更多
The process of contaminant transport is a problem of multicomponent and multiphase flow in unsaturated zone. Under the presupposition that gas existence affects water transport, a coupled mathematical model of contami...The process of contaminant transport is a problem of multicomponent and multiphase flow in unsaturated zone. Under the presupposition that gas existence affects water transport, a coupled mathematical model of contaminant transport in unsaturated zone has been established based on fluid_solid interaction mechanics theory. The asymptotical solutions to the nonlinear coupling mathematical model were accomplished by the perturbation and integral transformation method. The distribution law of pore pressure, pore water velocity and contaminant concentration in unsaturated zone has been presented under the conditions of with coupling and without coupling gas phase. An example problem was used to provide a quantitative verification and validation of the model. The asymptotical solution was compared with Faust model solution. The comparison results show reasonable agreement between asymptotical solution and Faust solution, and the gas effect and media deformation has a large impact on the contaminant transport. The theoretical basis is provided for forecasting contaminant transport and the determination of the relationship among pressure_saturation_permeability in laboratory.展开更多
We discuss the effects of dissipation on the behavior of single photon transport in a system of coupled cavity arrays, with the two nearest cavities nonlocally coupled to a two-level atom. The single photon transmissi...We discuss the effects of dissipation on the behavior of single photon transport in a system of coupled cavity arrays, with the two nearest cavities nonlocally coupled to a two-level atom. The single photon transmission amplitude is solved exactly by employing the quasi-boson picture. We investigate two different situations of local and nonlocal couplings, respectively. Comparing the dissipative case with the nondissipative one reveals that the dissipation of the system increases the middle dip and lowers the peak of the single photon transmission amplitudes, broadening the line width of the transport spectrum. It should be noted that the influence of the cavity dissipation to the single photon transport spectrum is asymmet- ric. By comparing the nonlocal coupling with the local one, one can find that the enhancement of the middle dip of single photon transmission amplitudes is mostly caused by the atom dissipation and that the reduced peak is mainly caused by the cavity dissipation, no matter whether it is a nonlocal or local coupling case. Whereas in the nonlocal coupling case, when the coupling strength gets stronger, the cavity dissipation has a greater effect on the single photon transport spectrum and the atom dissipation affection becomes weak, so it can be ignored.展开更多
As the oil or gas exploration and development activities in deep and ultra- deep waters become more and more, encountering gas hydrate bearing sediments （HBS） is almost inevitable. The variation in temperature and p...As the oil or gas exploration and development activities in deep and ultra- deep waters become more and more, encountering gas hydrate bearing sediments （HBS） is almost inevitable. The variation in temperature and pressure can destabilize gas hydrate in nearby formation around the borehole, which may reduce the strength of the formation and result in wellbore instability. A non-isothermal, transient, two-phase, and fluid-solid coupling mathematical model is proposed to simulate the complex stability performance of a wellbore drilled in HBS. In the model, the phase transition of hydrate dissociation, the heat exchange between drilling fluid and formation, the change of mechanical and petrophysical properties, the gas-water two-phase seepage, and its interaction with rock deformation are considered. A finite element simulator is developed, and the impact of drilling mud on wellbore instability in HBS is simulated. Results indicate that the re- duction in pressure and the increase in temperature of the drilling fluid can accelerate hydrate decomposition and lead to mechanical properties getting worse tremendously. The cohesion decreases by 25% when the hydrate totally dissociates in HBS. This easily causes the wellbore instability accordingly. In the first two hours after the formation is drilled, the regions of hydrate dissociation and wellbore instability extend quickly. Then, with the soaking time of drilling fluid increasing, the regions enlarge little. Choosing the low temperature drilling fluid and increasing the drilling mud pressure appropriately can benefit the wellbore stability of HBS. The established model turns out to be an efficient tool in numerical studies of the hydrate dissociation behavior and wellbore stability of HBS.展开更多
基金supported by the National Natural Science Foundation of China(Nos.52034010 and 52479113)the Natural Science Foundation of Shandong Province,China(No.ZR2024ME165)the Postgraduate Education and Teaching Reform Project of China University of Petroleum(East China)(No.YJG2024005).
文摘Understanding the complex flow behavior along a rough rock fracture under high-temperature,high-stress,and high-seepage pressure(HTHM)coupling conditions is of great significance for optimizing deep resource extraction.This study investigates the complex flow behavior of a single rock fracture under coupled HTHM conditions using a self-developed multi-field coupling experimental system,considering real-time high temperatures(20–90℃),confining pressures(30–120 MPa),and seepage pressures(5–60 MPa).Experimental results show that as confining pressure increases,two typical nonlinear flow behaviors are observed,which are Forchheimer flow and low-velocity nonlinear flow.The increase in temperature and decrease in roughness significantly promote the fluid flow and enhance the nonlinear relationship between the volumetric flow rate and the hydraulic gradient at lower confining pressures(30 MPa).However,the change in temperature and fracture surface roughness does not affect the nonlinear type of fluid flow.Under a given hydraulic gradient,the influence of temperature and fracture roughness on the volumetric flow rate varies with changes in confining pressure.Additionally,this study considers both the viscous and inertial terms,and a modified Forchheimer equation is proposed using two parameters:the contact area ratio and the thermal expansion coefficient of the rock.The proposed model can effectively predict the nonlinear flow behavior of fluid along rough fractured rocks under varying temperatures and surface roughness.The experimental results and the proposed model provide valuable data and theoretical guidance for deep oil and gas exploration as well as hydraulic fracturing design.
基金financially supported by the National Natural Science Foundation of China(Nos.42272153 and 42472195)the Research Fund of PetroChina Tarim Oilfield Company(No.671023060003)the Research Fund of China National Petroleum Corporation Limited(No.2023ZZ16YJ04).
文摘Deep tight reservoirs exhibit complex stress and seepage fields due to varying pore structures,thus the seepage characteristics are significant for enhancing oil production.This study conducted triaxial compression and permeability tests to investigate the mechanical and seepage properties of tight sandstone.A digital core of tight sandstone was built using Computed Tomography(CT)scanning,which was divided into matrix and pore phases by a pore equivalent diameter threshold.A fluid-solid coupling model was established to investigate the seepage characteristics at micro-scale.The results showed that increasing the confining pressure decreased porosity,permeability,and flow velocity,with the pore phase becoming the dominant seepage channel.Cracks and large pores closed first under increasing pressure,resulted in a steep drop in permeability.However,permeability slightly decreased under high confining pressure,which followed a first-order exponential function.Flow velocity increased with seepage pressure.And the damage mainly occurred in stress-concentration regions under low seepage pressure.Seepage behavior followed linear Darcy flow,the damage emerged at seepage entrances under high pressure,which decreased rock elastic modulus and significantly increased permeability.
基金supported by the National Natural Science Foundation of China(Grant No.52374079)Chongqing Graduate Research Innovation Project(Grant No.CYB22032)Chongqing Talents and Outstanding Scientists Project(Grant No.cstc2024ycjhbgzxm0032).
文摘Deep underground excavation causes considerable unloading effects,leading to a pronounced bias pressure phenomenon.The deformation and seepage characteristics of rock masses under different gas and confining pressures were investigated via triaxial loading and unloading seepage tests.When the influential coefficient of effective confining pressure(β)is less than 0.065,the seepage force considerably weakens the strength of fractured rock masses.Conversely,whenβis greater than 0.065,the opposite is true.Moreover,the increase in the axial load leads to an increase in the precast fracture volumetric strain,which is the main reason for the increase in fracture permeability.This effect is particularly significant during the unloading stage.Based on the test results,a method for calculating the dynamic seepage evolution of rock masses,considering the effects of rock mass damage and fracture deformation,is introduced,and the effectiveness of the calculation is validated.The entire description of the seepage under loading and unloading was accomplished.The equivalent relationship between the lateral and normal stresses on fracture surfaces ranges from 0.001 to 0.1,showing an exponential variation between the lateral stress influence coefficient on normal deformation(χ)and seepage pressure.Before the failure of the rock mass,the seepage in the fractures was in a linear laminar flow state.However,after the failure,when the gas pressure reached 2 MPa,the flow state in the fractures transitioned to nonlinear laminar flow.The results are important for predicting hazardous gas leaks during deep underground engineering excavation.
基金financially supported by the National Key Research and Development Plan(2023YFC2811001)the National Natural Science Foundation of China(42206233)the Taishan Scholars Program(tsqn202312280,tsqn202306297)。
文摘Hydraulic fracturing technology has played an important role in the exploitation of unconventional oil and gas resources,however,its application to gas hydrate reservoirs has been rarely studied.Currently,there is still limited understanding of the propagation and extension of fractures around the wellbore during the fracturing process of horizontal wells in hydrate reservoirs,as well as the stress interference patterns between fractures.This study simulates hydraulic fracturing processes in hydrate reservoirs using a fluidsolid coupling discrete element method(DEM),and analyzes the impacts of hydrate saturation and geological and engineering factors on fracture extension and stress disturbance.The results show that hydraulic fracturing is more effective when hydrate saturation exceeds 30%and that fracture pressure increases with saturation.The increase in horizontal stress differential enhances the directionality of fracture propagation and reduces stress disturbance.The distribution uniformity index(DUI)reveals that injection pressure is directly proportional to the number of main fractures and inversely proportional to fracturing time,with fracturing efficiency depending on the spacing between injection points and the distance between wells.This work may provide reference for the commercial exploitation of natural gas hydrates.
基金Supported by National Nature Science Foundation of China(61308066)
文摘In this investigation,the coupling losses caused by Fresnel reflection,core misalignment between single mode fiber(SMF)and HC-PCF are analyzed.A novel solution proposed from this research will reduce the coupling losses by using a T-type tube as a connector.Meanwhile,the theoretically calculated optimized gaps are at 15μm in SMF-HCPCF direction and 25μm in HCPCF-SMF direction.Thus,an experiment has been carried out,and the results of the practical gap in the above mentioned two directions have also been obtained.Furthermore,compared with detection by traditional methods,the proposed new detection method with PCF can remarkably enhance the Raman spectroscopy signal.Finally,the prospect of using the combination of HC-PCF and Raman spectroscopy in gas-cell detection has been demonstrated by using oxygen and nitrogen.
文摘Palladium(Pd)‐based catalysts are essential to drive high‐performance Suzuki coupling reactions,which are powerful tools for the synthesis of functional organic compounds.Herein,we developed a solution‐rapid‐annealing process to stabilize nitrogen‐mesoporous carbon supported Pd single‐atom/cluster(Pd/NMC)material,which provided a catalyst with superior performance for Suzuki coupling reactions.In comparison with commercial palladium/carbon(Pd/C)catalysts,the Pd/NMC catalyst exhibited significantly boosted activity(100%selectivity and 95%yield)and excellent stability(almost no decay in activity after 10 reuse cycles)for the Suzuki coupling reactions of chlorobenzenes,together with superior yield and excellent selectivity in the fields of the board scope of the reactants.Moreover,our newly developed rapid annealing process of precursor solutions is applied as a generalized method to stabilize metal clusters(e.g.Pd,Pt,Ru),opening new possibilities in the construction of efficient highly dispersed metal atom and sub‐nanometer cluster catalysts with high performance.
基金Project supported by the National Basic Research Program of China(Grant No.2014CB921401)the Tsinghua University Initiative Scientific Research Programthe Tsinghua National Laboratory for Information Science and Technology(TNList)Cross-discipline Foundation
文摘Cavity optomechanical systems provide powerful platforms to manipulate photons and phonons, open potential ap- plications for modern optical communications and precise measurements. With the refrigeration and ground-state cooling technologies, studies of cavity optomechanics are making significant progress towards the quantum regime including non- classical state preparation, quantum state tomography, quantum information processing, and future quantum internet. With further research, it is found that abundant physical phenomena and important applications in both classical and quan- tum regimes appeal as they have a strong optomechanical nonlinearity, which essentially depends on the single-photon optomechanical coupling strength. Thus, engineering the optomechanical interactions and improving the single-photon optomechanical coupling strength become very important subjects. In this article, we first review several mechanisms, theoretically proposed for enhancing optomechanical coupling. Then, we review the experimental progresses on enhancing optomechanical coupling by optimizing its structure and fabrication process. Finally, we review how to use novel structures and materials to enhance the optomechanical coupling strength. The manipulations of the photons and phonons at the level of strong optomechanical coupling are also summarized.
基金the National Natural Science Foundation of China(12025503,U1867215,11875211,U1932134)Hubei Provincial Natural Science Foundation(2019CFA036)the Fundamental Research Funds for the Central Universities(2042020kf0211)。
文摘Engineering the electronic structure of surface active sites at the atomic level can be an efficient way to modulate the reactivity of catalysts.Herein,we report the rational tuning of surface electronic structure of FePS_(3) nanosheets(NSs)by anchoring atomically dispersed metal atom.Theoretical calculations predict that the strong electronic coupling effect in single-atom Ni-FePS_(3) facilitates electron aggregation from Fe atom to the nearby Ni-S bond and enhances the electron-transfer of Ni and S sites,which balances the oxygen species adsorption capacity,reinforces water adsorption and dissociation process to accelerate corresponding oxygen evolution reaction(OER)and hydrogen evolution reaction(HER).The optimal Ni-FePS_(3)NSs/C exhibits outstanding electrochemical water-splitting activities,delivering an overpotential of 287 mV at the current density of 10 mA cm^(-2) and a Tafel slope of 41.1 mV dec^(-1) for OER;as well as an overpotential decrease of 219 mV for HER compared with pure FePS_(3)NSs/C.The concept of electronic coupling interaction between the substrate and implanted single active species offers an additional method for catalyst design and beyond.
基金Project supported by the Basic Scientific Research Foundation of College and University in Heilongjiang Province,China(Grant No.2018QNL-16)the Guiding Science and Technology Project of Daqing City(GSTPDQ),China(Grant No.zd-2019-03)the National Natural Science Foundation of China(Grant Nos.11304061 and 51572056).
文摘The influence of temperature on mode coupling effect in piezoelectric vibrators remains unclear.In this work,we discuss the influence of temperature on two-dimensional(2D)mode coupling effect and electromechanical coupling coefficient of cylindrical[001]c-poled Mn-doped 0.24PIN-0.46PMN-0.30PT piezoelectric single-crystal vibrator with an arbitrary configuration ratio.The electromechanical coupling coefficient kt decreases with temperature increasing,whereas k33 is largely invariant in a temperature range of 25℃-55℃.With the increase of temperature,the shift in the‘mode dividing point’increases the scale of the poling direction of the piezoelectric vibrator.The temperature has little effect on coupling constantΓ.At a given temperature,the coupling constantΓof the cylindrical vibrator is slightly greater than that of the rectangular vibrator.When the temperature changes,the applicability index(M)values of the two piezoelectric vibrators are close to 1,indicating that the coupling theory can be applied to piezoelectric vibrators made of late-model piezoelectric single crystals.
基金supported by the National Natural Science Foundation of China(Nos.42071078,41731281 and 41701068)the Natural Science Foundation of Qinghai Province,China(No.2021-ZJ-908).
文摘Permafrost is widely distributed in China and around the world.In permafrost regions,soil frost heave and thawing are severe and frequent,and can destabilize pile foundations.To this end,a finite element model of a single pile in frozen soil is established to investigate the frost heave and frost jacking response to ensure its safety in the Qinghai-Tibet Plateau.Firstly,a hydro-thermal coupling model of a single pile in frozen soil is established based on coupling parameters and initial and boundary conditions.Then the temperature and moisture distributions are analyzed through the established coupling model.A hydro-thermo-mechanical coupling model is developed by importing the ice content and temperature results.Simulation results indicate that the amount of frost heave is greater at locations closer to the ground surface,and the displacement is smaller for frozen soil that is closer to the side of the pile.The results on frost jacking behavior of piles from this study can serve as a reference for the design,construction and maintenance of foundations.
文摘Gradient-index rod lens (GRIN-lens) whose pitch is ordinary value with bevel ferrule coupling system is analyzed, an equivalent method which can be used to analyze this system is put forward, and a general formula for determining the coupling loss with axes mismatch, radial mismatch, and angular mismatch is derived by use of the Gaussian field approximation and mode-field coupling theory. The experimental results are in good agreement with the theory prediction. It indicates that these formulas are suitable to analyze the gradient-index rod lens coupling system with pigtail fiber.
文摘An effective method is introduced to compensate the effects of mutual coupling for the Estimation of Signal Parameter via Rotational Invariance Techniques (ESPRIT) direction finding algorithm in application of signal snapshot array processing.Changing the covariance matrix into a Teoplitz matrix can achieve high resolution in the Direction Of Arrive (DOA) estimation.How the mutual coupling affects the array antennas has been discussed and a new definition of mutual im- pedance has been used to characterize the mutual coupling effects between the array elements.Based on the new mutual impedance matrix,a practical method is presented to eliminate the effects of mutual coupling for ESPRIT in the single snapshot data processing.The simulation results show that, this new method not only properly reduces the effects of mutual coupling,but also maintains its steady performance even for weak signals.
基金Supported by the Anhui Provincial Natural Science Foundation under Grant No 1608085MA09the National Natural Science Foundation of China under Grant Nos 11774262,61675006,11474003 and 61472282
文摘The single photon frequency conversion is investigated theoretically in the system composed of a V-type system chiral coupling to a pair of waveguides. The single photon scattering amplitudes are obtained using the real-space Hamiltonian. The calculated results show that the probability of single photon frequency down-or up-conversion can reach a unit by choosing appropriate parameters in the non-dissipative system with perfect chiral coupling.We present a nonreciprocal single photon beam splitter whose frequency of the output photon is different from that of the input photon. The influences of dissipations and non-perfect chiral coupling on the single frequency conversion are also shown. Our results may be useful in designing quantum devices at the single-photon level.
基金Supported by the National Natural Science Foundation under Grant No.10272034the Doctoral Education Foundation under Grant No.20060217020
文摘The fluid-solid coupling theory, an interdisciplinary science between hydrodynamics and solid mechanics, is an important tool for response analysis and direct design of structures in naval architecture and ocean engineering. By applying the corresponding relations between generalized forces and generalized displacements, convolutions were performed between the basic equations of elasto-dynamics in the primary space and corresponding virtual quantities. The results were integrated and then added algebraically. In light of the fact that body forces and surface forces are both follower forces, the generalized quasi-complementary energy principle with two kinds of variables for an initial value problem is established in non-conservative systems. Using the generalized quasi-complementary energy principle to deal with the fluid-solid coupling problem and to analyze the dynamic response of structures, a method for using two kinds of variables simultaneously for calculation of force and displacement was derived.
基金Project(20080431380) supported by China Postdoctoral Science Foundation
文摘Abstract： A joint solution model of variabk：-mass flow in two-phase region and fluid-solid coupling heat transfer, concerned about the charge process of variable-mass thermodynamic system, is built up and calculated by the finite element method （FEM）. The results are basically consistent with relative experimental data. The calculated average heat transfer coefficient reaches 1.7~105 W/（m2. K）. When the equal percentage valve is used, the system needs the minimum requirements of valve control, but brings the highest construction cost. With the： decrease of initial steam pressure, the heat transfer intensity also weakens but the steam flow increases. With the initial water filling coefficient increasing or the temperature of steam supply decreasing, the amount of accumulative steam flow increases with the growth of steam pressure. When the pressure of steam supply drops, the steam flow gradient increases during the maximum opening period of control valve, and causes the maximum steam flow to increase.
基金National Natural Science Foundation of People’s Republic of China under Grant Nos.51178011 and 51778386the Key Fundamental Study Development Project of People’s Republic of China under Grant No.2011CB013602。
文摘The seismic response characteristics of underground structures in saturated soils are investigated.A fully fluid-solid coupling dynamic model is developed and implemented into ABAQUS with a user-defined element to simulate the dynamic behavior of saturated soils.The accuracy of the model is validated using a classic example in literature.The performance of the model is verified by its application on simulating the seismic response characteristics of a subway station built in saturated soils.The merits of the model are demonstrated by comparing the difference of the seismic response of an underground structure in saturated soils between using the fully coupling model and a single-phase medium model.The study finds that the fully coupling model developed herein can simulate the dynamic response characteristics of the underground structures in saturated soils with high accuracy.The seismic response of the underground structure tends to be underestimated by using the single-phase medium model compared with using the fully coupling model,which provides a weaker confining action to the underground structure.
基金the supports by the National Natural Science Foundation of China(Grants 11922209,11991031 and 12021002)for this research work.
文摘Due to their potential properties unlike traditional materials and structures,elastic wave metamaterials have received significant interests in recent years.With the coupling between the acoustic and vibration,their mechanical characteristics can be tuned by the active feedback control system at low frequency ranges in which the traditional passive control is limited.This work illustrates that the superior performances of the effective mass density and sound pressure level(SPL)of an elastic wave metamaterial can be significantly changed by the active control,in which the periodic array of local resonators and orthogonal stiffeners are included.Significantly,based on the locally resonant mechanism,the negative density occurs over a frequency range.Due to the effects of lattice constant,structural damping and other parameters,the SPL with the function of fluid-solid coupling are illustrated and discussed.
文摘The process of contaminant transport is a problem of multicomponent and multiphase flow in unsaturated zone. Under the presupposition that gas existence affects water transport, a coupled mathematical model of contaminant transport in unsaturated zone has been established based on fluid_solid interaction mechanics theory. The asymptotical solutions to the nonlinear coupling mathematical model were accomplished by the perturbation and integral transformation method. The distribution law of pore pressure, pore water velocity and contaminant concentration in unsaturated zone has been presented under the conditions of with coupling and without coupling gas phase. An example problem was used to provide a quantitative verification and validation of the model. The asymptotical solution was compared with Faust model solution. The comparison results show reasonable agreement between asymptotical solution and Faust solution, and the gas effect and media deformation has a large impact on the contaminant transport. The theoretical basis is provided for forecasting contaminant transport and the determination of the relationship among pressure_saturation_permeability in laboratory.
基金Project supported by the National Natural Science Foundation of China (Grant Nos.10704031,10874235,11274148,and 10934010)
文摘We discuss the effects of dissipation on the behavior of single photon transport in a system of coupled cavity arrays, with the two nearest cavities nonlocally coupled to a two-level atom. The single photon transmission amplitude is solved exactly by employing the quasi-boson picture. We investigate two different situations of local and nonlocal couplings, respectively. Comparing the dissipative case with the nondissipative one reveals that the dissipation of the system increases the middle dip and lowers the peak of the single photon transmission amplitudes, broadening the line width of the transport spectrum. It should be noted that the influence of the cavity dissipation to the single photon transport spectrum is asymmet- ric. By comparing the nonlocal coupling with the local one, one can find that the enhancement of the middle dip of single photon transmission amplitudes is mostly caused by the atom dissipation and that the reduced peak is mainly caused by the cavity dissipation, no matter whether it is a nonlocal or local coupling case. Whereas in the nonlocal coupling case, when the coupling strength gets stronger, the cavity dissipation has a greater effect on the single photon transport spectrum and the atom dissipation affection becomes weak, so it can be ignored.
基金supported by the Major National Science and Technology Program(Nos.2008ZX05026-00411 and 2011ZX05026-004-08)the Program for Changjiang Scholars and Innovative Research Team in University(No.RT1086)
文摘As the oil or gas exploration and development activities in deep and ultra- deep waters become more and more, encountering gas hydrate bearing sediments （HBS） is almost inevitable. The variation in temperature and pressure can destabilize gas hydrate in nearby formation around the borehole, which may reduce the strength of the formation and result in wellbore instability. A non-isothermal, transient, two-phase, and fluid-solid coupling mathematical model is proposed to simulate the complex stability performance of a wellbore drilled in HBS. In the model, the phase transition of hydrate dissociation, the heat exchange between drilling fluid and formation, the change of mechanical and petrophysical properties, the gas-water two-phase seepage, and its interaction with rock deformation are considered. A finite element simulator is developed, and the impact of drilling mud on wellbore instability in HBS is simulated. Results indicate that the re- duction in pressure and the increase in temperature of the drilling fluid can accelerate hydrate decomposition and lead to mechanical properties getting worse tremendously. The cohesion decreases by 25% when the hydrate totally dissociates in HBS. This easily causes the wellbore instability accordingly. In the first two hours after the formation is drilled, the regions of hydrate dissociation and wellbore instability extend quickly. Then, with the soaking time of drilling fluid increasing, the regions enlarge little. Choosing the low temperature drilling fluid and increasing the drilling mud pressure appropriately can benefit the wellbore stability of HBS. The established model turns out to be an efficient tool in numerical studies of the hydrate dissociation behavior and wellbore stability of HBS.
