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Formation and evolution of thiadiamondoids in petroleum:Evidence from thermochemical sulfate reduction simulation experiments with 1,3-dimethyladamantane
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作者 Anlai Ma Zhaowen Zhan +2 位作者 Cuishan Zhu Yunpeng Wang Jinzhong Liu 《Energy Geoscience》 2025年第3期223-238,共16页
Thiadiamondoids(TDs)have recently attracted increasing attention as molecular proxies for thermochemical sulfate reduction(TSR)reactions in reservoirs.However,their formation mechanisms,as well as the generation and e... Thiadiamondoids(TDs)have recently attracted increasing attention as molecular proxies for thermochemical sulfate reduction(TSR)reactions in reservoirs.However,their formation mechanisms,as well as the generation and evolution processes,remain poorly understood.In this study,simulation experiments with a duration of 160 h were conducted on the model compound 1,3-dimethyladamantane(1,3-DMA)using the CaSO_(4),MgSO_(4),and elemental S systems,with measurements at the 10th,20th,40th,80th and 160th hours during the simulation process being presented.The results indicate that at the end of simulation,the MgSO_(4) system exhibited the lowest residual amounts of 1,3-DMA,suggesting the highest degree of TSR.Four types of non-hydrocarbon compounds with adamantane structures were detected in the liquid products in the three experiment systems:adamantanones,adamantanols,adamantanethiols(ATs),and thiaadamantanes(TAs).Among these,adamantanones exhibited the highest concentrations in the three simulation systems.In addition,TAs were dominated by C_(3)-TAs in the CaSO_(4) and MgSO_(4) systems and by C_(2)-TAs in the elemental S system.The simulation experiments revealed a strong correlation between the concentrations of TAs and adamantanones,suggesting that adamantanones might be the intermediates for TAs.Combined with the synthesis mechanism of TAs from thiaadamamantane-4,8-dione,TDs might have two different genetic mechanisms:(a)low temperature cationic carbon ion rearrangement from diagenesis to early catagenesis stage,and(b)a free sulfur radical mechanism in high-temperature TSR process during middle-late catagenesis.TAs exhibited different generation and evolution processes across different experiment systems.Notably,the MgSO_(4) system revealed that TAs undergo generation,accumulation,and destruction process,corresponding to Easy%Ro values of 0.89%-0.98%,0.98%-1.21%,and>1.21%,respectively.Among these three simulation systems,dibenzothiophenes(DBTs)concentrations consistently trended upwards,indicating TAs have lower thermal stability than DBTs. 展开更多
关键词 Thiadiamondoids(TDs) Dibenzothiophenes(DBTs) Thermal stability Thermochemical sulfate reduction(TSR) Simulation experiment
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Study on the Hydraulic Performance and Efficiency of a Siphon Sediment Discharge Device with Bottom Hole Opening through Simulation Experiments
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作者 Henglong Hui Yan Li Zhiying Cui 《Journal of Electronic Research and Application》 2025年第1期169-175,共7页
In this study,the hydraulic behavior and sand transport efficiency of the siphon automatic sand discharge device were studied by software simulation tests.By simulating the actual situation,this study analyzed how fac... In this study,the hydraulic behavior and sand transport efficiency of the siphon automatic sand discharge device were studied by software simulation tests.By simulating the actual situation,this study analyzed how factors such as the difference in water level,sediment concentration,and pipeline layout affected the sediment discharge effect.The results show that the sediment discharge device can effectively discharge sediment under diverse operating conditions and show adaptability to different environmental conditions,which indicates that it is suitable for various types of reservoir environments. 展开更多
关键词 Siphon sand discharge Bottom hole opening Sand transport efficiency Simulation experiment
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Using Physical Model Experiments for Hazards Assessment of Rainfall-Induced Debris Landslides 被引量:13
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作者 Qianqian Li Dong Huang +2 位作者 Shufeng Pei Jianping Qiao Meng Wang 《Journal of Earth Science》 SCIE CAS CSCD 2021年第5期1113-1128,共16页
Using physical simulation models, rainfall-induced landslides have been simulated under various rainfall intensities. During these simulations, we have monitored the physical and mechanical behaviors of the landslide ... Using physical simulation models, rainfall-induced landslides have been simulated under various rainfall intensities. During these simulations, we have monitored the physical and mechanical behaviors of the landslide over the slip surface at different heights of the model slopes, as well as taking the whole slope to identify its deformation and failure processes. The results show that the rainfall duration corresponding to the initiation of the debris landslide and is exponentially related to rainfall intensity. Corresponding to the three intervals of the rainfall intensity, there are three types of slope failure modes:(1) the small-slump failure at the leading edge of the slope;(2) the block-slump failure but sometimes there are large blocks sliding down;and(3) the bulk failure but sometimes there is the block-slump failure. Based on the total rainfall-lasting time and the associated proportion of failed mass volume, the early warning of debris landslide can be classified into five grades, i.e., red, orange to red, orange, yellow to orange and yellow, which correspond to the five slope failure modes, respectively. 展开更多
关键词 rainfall-induced landslides simulation model experiments failure mode hazards assessment
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Passive walker that can walk down steps:simulations and experiments 被引量:7
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作者 Ning Liu Junfeng Li Tianshu Wang 《Acta Mechanica Sinica》 SCIE EI CAS CSCD 2008年第5期569-573,共5页
A planar passive walking model with straight legs and round feet was discussed. This model can walk down steps, both on stairs with even steps and with random steps. Simulations showed that models with small moments o... A planar passive walking model with straight legs and round feet was discussed. This model can walk down steps, both on stairs with even steps and with random steps. Simulations showed that models with small moments of inertia can navigate large height steps. Period-doubling has been observed when the space between steps grows. This period-doubling has been validated by experiments, and the results of experiments were coincident with the simulation. 展开更多
关键词 Passive walking Period-doubling Simulation - experiments Poincaré map Nonlinear dynamics
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Simulation Experiments on the Reaction of CH_4-CaSO_4 and Its Carbon Kinetic Isotope Fractionation 被引量:3
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作者 YueChangtao LiShuyuan DingKangle ZhongNingning 《Petroleum Science》 SCIE CAS CSCD 2005年第1期82-85,共4页
Thermochemical sulfate reduction (TSR) in geological deposits can account for the accumulation of H2S in deep sour gas reservoirs. In this paper, thermal simulation experiments on the reaction of CH4-CaSO4 were carri... Thermochemical sulfate reduction (TSR) in geological deposits can account for the accumulation of H2S in deep sour gas reservoirs. In this paper, thermal simulation experiments on the reaction of CH4-CaSO4 were carried out using an autoclave at high temperatures and high pressures. The products were characterized with analytical methods including carbon isotope analysis. It is found that the reaction can proceed to produce H2S, H2O and CaCO3 as the main products. Based on the experimental results, the carbon kinetic isotope fractionation was investigated, and the value of Ki (kinetic isotope effect) was calculated. The results obtained in this paper can provide useful information to explain the occurrence of H2S in deep carbonate gas reservoirs. 展开更多
关键词 Thermochemical sulfate reduction (TSR) hydrogen sulfide (H2S) simulation experiment carbon kinetic isotope fractionation
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Simulation experiments on counter beam lighting in highway tunnel 被引量:2
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作者 王志伟 《Journal of Chongqing University》 CAS 2010年第3期139-145,共7页
Counter beam lighting was introduced as well as transverse symmetrical lighting and longitudinal symmetrical lighting.Simulation experiments were carried out by using DIAlux lighting software for the above three light... Counter beam lighting was introduced as well as transverse symmetrical lighting and longitudinal symmetrical lighting.Simulation experiments were carried out by using DIAlux lighting software for the above three lighting methods.The results show that counter beam lighting is more reasonable to be adopted in the tunnel entrance zone because its threshold increment of disability glare is greater.Counter beam lighting can improve the background luminance of the obstacles and lighting efficiency compared with transverse symmetrical lighting and longitudinal symmetrical lighting.Therefore,tunnel lighting energy-saving can be achieved by reducing the road luminance demands and luminaries power.Longitudinal symmetrical lighting is conducive to the large luminaries spacing in the tunnel internal zone;so power consumption can be reduced by decreasing the number of luminaries used.Tunnel walls are unsuitable to pave with smooth or bright material.Installation height of the luminaries has less effect on counter beam lighting. 展开更多
关键词 counter beam lighting simulation experiments disability glare lighting efficiency
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Factors influencing physical property evolution in sandstone mechanical compaction:the evidence from diagenetic simulation experiments 被引量:5
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作者 Ke-Lai Xi Ying-Chang Cao +7 位作者 Yan-Zhong Wang Qing-Qing Zhang Jie-Hua Jin Ru-Kai Zhu Shao-Min Zhang Jian Wang Tian Yang Liang-Hui Du 《Petroleum Science》 SCIE CAS CSCD 2015年第3期391-405,共15页
In order to analyze the factors influencing sandstone mechanical compaction and its physical property evolution during compaction processes, simulation exper- iments on sandstone mechanical compaction were carried out... In order to analyze the factors influencing sandstone mechanical compaction and its physical property evolution during compaction processes, simulation exper- iments on sandstone mechanical compaction were carried out with a self-designed diagenetic simulation system. The experimental materials were modem sediments from dif- ferent sources, and the experiments were conducted under high temperature and high pressure. Results of the exper- iments show a binary function relation between primary porosity and mean size as well as sorting. With increasing overburden pressure during mechanical compaction, the evolution of porosity and permeability can be divided into rapid compaction at an early stage and slow compaction at a late stage, and the dividing pressure value of the two stages is about 12 MPa and the corresponding depth is about 600 m. In the slow compaction stage, there is a good exponential relationship between porosity and overburden pressure, while a good power function relationship exists between permeability and overburden pressure. There is also a good exponential relationship between porosity and permeability. The influence of particle size on sandstone mechanical compaction is mainly reflected in the slowcompaction stage, and the influence of sorting is mainly reflected in the rapid compaction stage. Abnormally high pressure effectively inhibits sandstone mechanical com- paction, and its control on sandstone mechanical com- paction is stronger than that of particle size and sorting. The influence of burial time on sandstone mechanical compaction is mainly in the slow compaction stage, and the porosity reduction caused by compaction is mainly con- trolled by average particle size. 展开更多
关键词 Primary porosity Mechanical compaction Unconsolidated sand Diagenetic simulation experiment
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Observation system simulation experiments using an ensemble-based method in the northeastern South China Sea 被引量:1
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作者 GENG Wu CHENG Feng +9 位作者 XIE Qiang ZOU Xiaoli HE Weihong WANG Zhaozheng SHU Yeqiang CHEN Gengxin LIU Danian YE Dong WANG Ruiwen LIU Chuanyu 《Journal of Oceanology and Limnology》 SCIE CAS CSCD 2020年第6期1729-1745,共17页
An ensemble-based method for the observation system simulation experiment(OSSE)is employed to design optimal observation stations and assess the present observation stations in the northeastern South China Sea(SCS).We... An ensemble-based method for the observation system simulation experiment(OSSE)is employed to design optimal observation stations and assess the present observation stations in the northeastern South China Sea(SCS).We employed the 20-year(1992-2012)sea surface height(SSH)data to design an array to monitor the intraseasonal to interannual variability.The results show that the most key region was found located at the northwest of Luzon Island(LI)where the energetic Luzon cyclonic gyre(LCG)occurs;other key regions include the edge of the LCG,the northwest of the Luzon Strait(LS),and the southwest of Taiwan,China.By contrast,we found that the present observation stations might oversample at the northwest of the LS and undersample at the northwest of LI.In addition,the optimal stations perform better in a larger area than the present stations.In vertical direction,the key layer is located within the upper 200-m depth,of which the surface and subsurface layers are most valuable to the observing system. 展开更多
关键词 ASSIMILATION observation system simulation experiment(OSSE) ENSEMBLE South China Sea(SCS) Kalman filter
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Simulation Experiments of Land Surface Physical Processes and Ecological Effect over Different Underlying Surface 被引量:1
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作者 LIU Shu-hua~(1,2), JIANG Hao-yu, HU Fei~2 LIU Hui-zhi~2 LIANG Fu-ming~1, WANG Jiang-hua~1(1. Group of Atmosphere Boundary Layer and turbulence, Ministry Laboratory of Storm and Drought Flood Damage, Department of Atmospheric Sciences the School of Physics Peking University, Beijing 100871, China 2. State Key Laboratories of Atmosphere Physics and Chemistry, Institute of Atmospheric Physics, Chinese Academy of Science, Beijing 100029, China) 《地球科学进展》 CAS CSCD 2004年第S1期15-20,共6页
Based on the existing Land Surface Physical Process Models(Deardorff, Dickinson, LIU, Noilhan, Seller, ZHAO), a Comprehensive Land Surface Physical Process Model (CLSPPM) is developed by considering the different phys... Based on the existing Land Surface Physical Process Models(Deardorff, Dickinson, LIU, Noilhan, Seller, ZHAO), a Comprehensive Land Surface Physical Process Model (CLSPPM) is developed by considering the different physical processes of the earth's surface-vegetation-atmosphere system more completely. Compared with SiB and BATS, which are famous for their detailed parameterizations of physical variables, this simplified model is more convenient and saves much more computation time. Though simple, the feas... 展开更多
关键词 Comprehensive land surface Physical process model (CLSPPM) Simulation experiment Land surface physical process Ecological effect.
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EXPERIMENTS ON ASSIMILATION OF INITIAL VALUES IN NUMERICAL PREDICTION OF A WARM-SECTOR PRECIPITATION IN SOUTH CHINA
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作者 张诚忠 万齐林 +2 位作者 黄燕燕 陈子通 丁伟钰 《Journal of Tropical Meteorology》 SCIE 2009年第1期73-77,共5页
In order to understand the impact of initial conditions upon prediction accuracy of short-term forecast and nowcast of precipitation in South China, four experiments i.e. a control, an assimilation of conventional sou... In order to understand the impact of initial conditions upon prediction accuracy of short-term forecast and nowcast of precipitation in South China, four experiments i.e. a control, an assimilation of conventional sounding and surface data, testing with nudging rainwater data and the assimilation of radar-derived radial wind, are respectively conducted to simulate a case of warm-sector heavy rainfall that occurred over South China, by using the GRAPES_MESO model. The results show that (1) assimilating conventional surface and sounding observations helps improve the 24-h rainfall forecast in both the area and order of magnitude; (2) nudging rainwater contributes to a significant improvement of nowcast, and (3) the assimilation of radar-derived radial winds distinctly improves the 24-h rainfall forecast in both the area and order of magnitude. These results serve as significant technical reference for the study on short-term forecast and nowcast of precipitation over South China in the future. 展开更多
关键词 South China initial conditions warm-sector precipitation numerical simulation experiment
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Simulation and Experiments on the Capillary Force between a Circular Disk and a Parallel Substrate
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作者 王乐锋 黄本松 +2 位作者 何元哲 荣伟彬 孙立宁 《Chinese Physics Letters》 SCIE CAS CSCD 2017年第5期92-95,共4页
The capillary force of a liquid bridge with a pinned contact line between a small disk and a parallel plate is investigated by simulation and experiments. The numerical minimization simulation method is utilized to ca... The capillary force of a liquid bridge with a pinned contact line between a small disk and a parallel plate is investigated by simulation and experiments. The numerical minimization simulation method is utilized to calculate the capillary force. The results show excellent agreement with the Young-Laplace equation method. An experimental setup is built to measure the capillary force. The experimental results indicate that the simulation results agree well with the measured forces at large separation distances, while some deviation may occur due to the transition from the advancing contact angle to the receding one at small distances. It is also found that the measured rupture distance is slightly larger than the simulation value due to the effect of the viscous interaction inside the liquid bridge. 展开更多
关键词 Simulation and experiments on the Capillary Force between a Circular Disk and a Parallel Substrate
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Mechanisms of fine-grained sedimentation and reservoir characteristics of shale oil in continental freshwater lacustrine basin:A case study from Chang 7_(3) sub-member of Triassic Yanchang Formation in southwestern Ordos Basin,NW China 被引量:1
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作者 LIU Xianyang LIU Jiangyan +6 位作者 WANG Xiujuan GUO Qiheng Lv Qiqi YANG Zhi ZHANG Yan ZHANG Zhongyi ZHANG Wenxuan 《Petroleum Exploration and Development》 2025年第1期95-111,共17页
Based on recent advancements in shale oil exploration within the Ordos Basin,this study presents a comprehensive investigation of the paleoenvironment,lithofacies assemblages and distribution,depositional mechanisms,a... Based on recent advancements in shale oil exploration within the Ordos Basin,this study presents a comprehensive investigation of the paleoenvironment,lithofacies assemblages and distribution,depositional mechanisms,and reservoir characteristics of shale oil of fine-grained sediment deposition in continental freshwater lacustrine basins,with a focus on the Chang 7_(3) sub-member of Triassic Yanchang Formation.The research integrates a variety of exploration data,including field outcrops,drilling,logging,core samples,geochemical analyses,and flume simulation.The study indicates that:(1)The paleoenvironment of the Chang 7_(3) deposition is characterized by a warm and humid climate,frequent monsoon events,and a large water depth of freshwater lacustrine basin.The paleogeomorphology exhibits an asymmetrical pattern,with steep slopes in the southwest and gentle slopes in the northeast,which can be subdivided into microgeomorphological units,including depressions and ridges in lakebed,as well as ancient channels.(2)The Chang 7_(3) sub-member is characterized by a diverse array of fine-grained sediments,including very fine sandstone,siltstone,mudstone and tuff.These sediments are primarily distributed in thin interbedded and laminated arrangements vertically.The overall grain size of the sandstone predominantly falls below 62.5μm,with individual layer thicknesses of 0.05–0.64 m.The deposits contain intact plant fragments and display various sedimentary structure,such as wavy bedding,inverse-to-normal grading sequence,and climbing ripple bedding,which indicating a depositional origin associated with density flows.(3)Flume simulation experiments have successfully replicated the transport processes and sedimentary characteristics associated with density flows.The initial phase is characterized by a density-velocity differential,resulting in a thicker,coarser sediment layer at the flow front,while the upper layers are thinner and finer in grain size.During the mid-phase,sliding water effects cause the fluid front to rise and facilitate rapid forward transport.This process generates multiple“new fronts”,enabling the long-distance transport of fine-grained sandstones,such as siltstone and argillaceous siltstone,into the center of the lake basin.(4)A sedimentary model primarily controlled by hyperpynal flows was established for the southwestern part of the basin,highlighting that the frequent occurrence of flood events and the steep slope topography in this area are primary controlling factors for the development of hyperpynal flows.(5)Sandstone and mudstone in the Chang 7_(3) sub-member exhibit micro-and nano-scale pore-throat systems,shale oil is present in various lithologies,while the content of movable oil varies considerably,with sandstone exhibiting the highest content of movable oil.(6)The fine-grained sediment complexes formed by multiple episodes of sandstones and mudstones associated with density flow in the Chang 7_(3) formation exhibit characteristics of“overall oil-bearing with differential storage capacity”.The combination of mudstone with low total organic carbon content(TOC)and siltstone is identified as the most favorable exploration target at present. 展开更多
关键词 fine-grained sedimentation density flow mode flume simulation experiments reservoir characteristics Chang 7_(3)sub-member Triassic Yanchang Formation shale oil Ordos Basin
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Structural physical simulation experiment on vertical growth process of strike-slip faults in ultra-deep strata of Tarim Basin,NW China
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作者 NENG Yuan XIE Zhou +5 位作者 SHAO Longfei RUAN Qiqi KANG Pengfei ZHANG Jianan TIAN Zhiwen LIU Genji 《Petroleum Exploration and Development》 2025年第5期1179-1192,共14页
In the ultra-deep strata of the Tarim Basin,the vertical growth process of strike-slip faults remains unclear,and the vertical distribution of fractured-cavity carbonate reservoirs is complex.This paper investigates t... In the ultra-deep strata of the Tarim Basin,the vertical growth process of strike-slip faults remains unclear,and the vertical distribution of fractured-cavity carbonate reservoirs is complex.This paper investigates the vertical growth process of strike-slip faults through field outcrop observations in the Keping area,interpretation of seismic data from the Fuman Oilfield,Tarim Basim,NW China,and structural physical simulation experiments.The results are obtained mainly in four aspects.First,field outcrops and ultra-deep seismic profiles indicate a three-layer structure within the strike-slip fault,consisting of fault core,fracture zone and primary rock.The fault core can be classified into three parts vertically:fracture-cavity unit,fault clay and breccia zone.The distribution of fracture-cavity units demonstrates a distinct pattern of vertical stratification,owing to the structural characteristics and growth process of the slip-strike fault.Second,the ultra-deep seismic profiles show multiple fracture-cavity units in the strike-slip fault zone.These units can be classified into four types:top fractured,middle connected,deep terminated,and intra-layer fractured.Third,structural physical simulation experiments and ultra-deep seismic data interpretation reveal that the strike-slip faults have evolved vertically in three stages:segmental rupture,vertical growth,and connection and extension.The particle image velocimetry detection demonstrates that the initial fracture of the fault zone occurred at the top or bottom and then evolved into cavities gradually along with the fault growth,accompanied by the emergence of new fractures in the middle part of the strata,which subsequently connected with the deep and shallow cavities to form a complete fault zone.Fourth,the ultra-deep carbonate strata primarily develop three types of fractured-cavity reservoirs:flower-shaped fracture,large and deep fault and staggered overlap.The first two types are larger in size with better reservoir conditions,suggesting a significant exploration potential. 展开更多
关键词 strike-slip fault vertical growth evolution process structural physical simulation experiment Ordovician fractured-cavity carbonate reservoir ultra-deep Tarim Basin Fuman oilfield
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Carbon isotope fractionation and production patterns of adsorbed and free gas during deep coal-rock gas production
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作者 DUAN Xianggang LI Wenbiao +6 位作者 HU Zhiming WANG Jun ZHAO Qun XIA Yonghui MA Zhanrong XU Yingying SUN Mingyan 《Petroleum Exploration and Development》 2025年第5期1314-1328,共15页
Taking deep coal-rock gas in the Yulin and Daning-Jixian areas of the Ordos Basin,NW China,as the research object,full-diameter coal rock samples with different cleat/fracture development degrees from the Carboniferou... Taking deep coal-rock gas in the Yulin and Daning-Jixian areas of the Ordos Basin,NW China,as the research object,full-diameter coal rock samples with different cleat/fracture development degrees from the Carboniferous Benxi Formation were selected to conduct physical simulation and isotope monitoring experiments of the full-life-cycle depletion development of coal-rock gas.Based on the experimental results,a dual-medium carbon isotope fractionation(CIF)model coupling cleats/fractures and matrix pores was constructed,and an evaluation method for free gas production patterns was established to elucidate the carbon isotope fractionation mechanism and adsorbed/free gas production characteristics during deep coal-rock gas development.The results show that the deep coal-rock gas development process exhibits a three-stage carbon isotope fractionation pattern:“Stable(Ⅰ)→Decrease(Ⅱ)→Increase(Ⅲ)”.A rapid decline in boundary pressure in stageⅢleads to fluctuations in isotope value,characterized by a“rapid decrease followed by continued increase”,with free gas being produced first and long-term supply of adsorbed gas.The CIF model can effectively match measured gas pressure,cumulative gas production,and δ^(13)C_(1) value of produced gas.During the first two stages of isotope fractionation,free gas dominated cumulative production.During the mid-late stages of slow depletion production,the staged pressure control development method can effectively increase the gas recovery.The production of adsorbed gas is primarily controlled by the rock's adsorption capacity and the presence of secondary flow channels.Effectively enhancing the recovery of adsorbed gas during the late stage remains crucial for maintaining stable production and improving the ultimate recovery factor of deep coal-rock gas. 展开更多
关键词 deep coal-rock gas isotope fractionation physical simulation experiment adsorbed gas free gas gas production ratio
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The hydrocarbon generation potential of the mudstone source rock in the Jurassic Shuixigou Group,the Turpan-Hami Basin,and indicative significance for oil and gas exploration
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作者 Tong Lin Kangle Wang +3 位作者 Haidong Wang Runze Yang Pan Li Long Su 《Natural Gas Industry B》 2025年第1期50-63,共14页
The coal-bearing source rocks in the Jurassic Shuixigou Group have received widespread attention as the primary source rocks in the Turpan-Hami Basin of China,but the hydrocarbon generation potential and process of th... The coal-bearing source rocks in the Jurassic Shuixigou Group have received widespread attention as the primary source rocks in the Turpan-Hami Basin of China,but the hydrocarbon generation potential and process of the mudstone in the Shuixigou Group,especially the mudstone at the top of the Sangonghe Formation,are unclear.Taking the source rocks of the Xishanyao Formation and the Sangonghe Formation as objectives,this study conducted rock pyrolysis and gold tube simulation experiment to investigate their hydrocarbon generation characteristics and differences.Our results indicate that the source rocks of the Xishanyao Formation include mudstone,carbonaceous mudstone and coal,and the quality of the source rocks is highly heterogeneous;the source rocks of the Sangonghe Formation are mainly composed of mudstone,and it is a good gas source rock.Simulation experiments found that the activation energy required for the generation of gaseous hydrocarbons by the mudstone of the Sangonghe Formation is lower than that by the mudstone of the Xishanyao Formation.The hydrocarbon generation process can be divided into three stages for both formations,but the gas generation potential of the Xishanyao Formation mudstone is higher than that of the Sangonghe Formation mudstone.A large amount of hydrocarbon was generated by the mudstone of the Xishanyao Formation when entering late thermal evolution,of which methane is dominant,mainly from the demethylation reaction of mature kerogen.On the other hand,a large amount of hydrocarbon was generated by the mudstone of the Sangonghe Formation in the early stage of thermal evolution,of which light hydrocarbon and wet gas are dominant,mainly from the early cracking stage of kerogen.This difference may be attributed to the structure of kerogen.The mudstone of the Xishanyao Formation is conducive to the formation of highly mature dry gas reservoirs,while the mudstone of the Sangonghe Formation is conducive to the formation of low maturity condensate gas and volatile oil reservoirs.The research result provides a scientific basis for the comparison of oil and gas sources and the evaluation of oil and gas resources in the Turpan-Hami Basin. 展开更多
关键词 Turpan-Hami Basin Gas generation potential Hydrocarbon generation characteristics Sangonghe Formation mudstone Xishanyao Formation mudstone Gold tube simulation experiment
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Flow characteristics of shale oil and their geological controls:A case study of the Lucaogou Formation in the Jimsar Sag,Junggar Basin
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作者 Jia-Qi Liu Jun-Qian Li +1 位作者 Zhao-Jing Song An-Chao Shen 《Petroleum Science》 2025年第10期3900-3914,共15页
The Lucaogou Formation in Jimsar has a significant development potential due to its massive shale oil resources.Nevertheless,the complex and heterogeneous lithology,coupled with unclear flow mechanisms,poses a challen... The Lucaogou Formation in Jimsar has a significant development potential due to its massive shale oil resources.Nevertheless,the complex and heterogeneous lithology,coupled with unclear flow mechanisms,poses a challenge in effectively predicting its development potential.Therefore,it is crucial to clarify the flow characteristics of shale oil and its controlling factors.In this study,we used a flow simulation experiment to investigate the flow characteristics of different samples under various temperatures and confining stresses and quantitatively evaluated flow characteristics using threshold pressure gradient and total loss of flow rate.Additionally,by combining scanning electron microscopy and mercury intrusion capillary pressure techniques for pore structure characterization,and the relationship between microscopic pore structure and flow parameters was discussed.The findings indicate that rock composition and pore throat structure collaboratively control shale oil flow.Mesopores and macropores primarily develop between dolomite or albite,leading to well-developed pore throat structure with larger average throat radius,lower displacement pressure,and better reservoir quality,enhancing shale oil flowability.Dolomitic siltstone often exhibits these characteristics,making it a favorable lithology for shale oil flow.This study reveals the flow mechanism of shale oil under the action of reservoir physical properties,material compositions,temperatures and confining stresses,summarizes the geological characteristics of advantageous reservoirs.It provides theoretical support for layer selection and efficient development of shale oil reservoirs in the Lucaogou Formation of the Jimsar. 展开更多
关键词 Shale oil Flow simulation experiment Flow characteristic Pore throat structure Lucaogou Formation
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Evolution and generation mechanism of retained oil in lacustrine shales:A combined ReaxFF-MD and pyrolysis simulation perspective
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作者 Biao Sun Xiao-Ping Liu +3 位作者 Jie Liu Tian Liu Zu-Xian Hua Wen-Di Peng 《Petroleum Science》 2025年第1期29-41,共13页
To accurately investigate the evolution characteristics and generation mechanism of retained oil,the study analyzed organic-rich lacustrine shale samples from the Paleogene Kongdian Formation in Cangdong Sag,Bohai Bay... To accurately investigate the evolution characteristics and generation mechanism of retained oil,the study analyzed organic-rich lacustrine shale samples from the Paleogene Kongdian Formation in Cangdong Sag,Bohai Bay Basin.This analysis involves Rock-Eval pyrolysis,pyrolysis simulation experiments,Gas Chromatograph Mass Spectrometer(GC-MS),and reactive molecular dynamics simulations(ReaxFF).The results revealed the retained oil primarily consisted of n-alkanes with carbon numbers ranging from C14 to C36.The generation of retained oil occurred through three stages.A slow growth stage of production rate was observed before reaching the peak of oil production in Stage Ⅰ.Stage Ⅱ involved a rapid increase in oil retention,with C12-C17 and C24-C32 serving as the primary components,increasing continuously during the pyrolysis process.The generation process involved the cleavage of weak bonds,including bridging bonds(hydroxyl,oxy,peroxy,imino,amino,and nitro),ether bonds,and acid amides in the first stage(Ro=0.50%-0.75%).The carbon chains in aromatic ring structures with heteroatomic functional groups breaks in the second stage(R_(o)=0.75%-1.20%).In the third stage(R_(o)=1.20%-2.50%),the ring structures underwent ring-opening reactions to synthesize iso-short-chain olefins and radicals,while further breakdown of aliphatic chains occurred.By coupling pyrolysis simu-lation experiments and molecular simulation technology,the evolution characteristics and bond breaking mechanism of retained oil in three stages were revealed,providing a reference for the for-mation and evolution mechanism of retained oil. 展开更多
关键词 Lacustrine shale Retained oiliness evolution Pyrolysis simulation experiments ReaxFF molecular dynamics Hydrocarbon generation evolution
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Hysteresis-Loop Criticality in Disordered Ferromagnets–A Comprehensive Review of Computational Techniques
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作者 Djordje Spasojevic Sanja Janicevic +1 位作者 Svetislav Mijatovic Bosiljka Tadic 《Computer Modeling in Engineering & Sciences》 2025年第2期1021-1107,共87页
Disordered ferromagnets with a domain structure that exhibit a hysteresis loop when driven by the external magnetic field are essential materials for modern technological applications.Therefore,the understanding and p... Disordered ferromagnets with a domain structure that exhibit a hysteresis loop when driven by the external magnetic field are essential materials for modern technological applications.Therefore,the understanding and potential for controlling the hysteresis phenomenon in thesematerials,especially concerning the disorder-induced critical behavior on the hysteresis loop,have attracted significant experimental,theoretical,and numerical research efforts.We review the challenges of the numerical modeling of physical phenomena behind the hysteresis loop critical behavior in disordered ferromagnetic systems related to the non-equilibriumstochastic dynamics of domain walls driven by external fields.Specifically,using the extended Random Field Ising Model,we present different simulation approaches and advanced numerical techniques that adequately describe the hysteresis loop shapes and the collective nature of the magnetization fluctuations associated with the criticality of the hysteresis loop for different sample shapes and varied parameters of disorder and rate of change of the external field,as well as the influence of thermal fluctuations and demagnetizing fields.The studied examples demonstrate how these numerical approaches reveal newphysical insights,providing quantitativemeasures of pertinent variables extracted from the systems’simulated or experimentally measured Barkhausen noise signals.The described computational techniques using inherent scale-invariance can be applied to the analysis of various complex systems,both quantum and classical,exhibiting non-equilibrium dynamical critical point or self-organized criticality. 展开更多
关键词 Disordered ferromagnets hysteresis-loop criticality magnetization-reversal avalanches in simulations and experiments zero-temperature and thermal Random Field Ising Model simulations computational techniques for multiparameter scaling analysis multifractal Barkhausen noise finite driving rates demagnetizing effects nonequilibrium critical dynamics
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Experimental and numerical study on external explosions of cylindrical versus spherical charges at tunnel entrance
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作者 Dan Luo Jinsheng Hu +4 位作者 Anbao Wang Xiao Yu Mengmeng Zhang Meili Yao Chun Li 《Defence Technology(防务技术)》 2025年第4期227-243,共17页
Most of the existing studies on tunnel blast wave are based on spherical or grouped charges, however,conventional weapons are mostly cylindrical rather than spherical. In order to analyze the impact of cylindrical cha... Most of the existing studies on tunnel blast wave are based on spherical or grouped charges, however,conventional weapons are mostly cylindrical rather than spherical. In order to analyze the impact of cylindrical charges on the tunnel blast wave loads and to develop a quantitative calculation method, this study carried out experimental and numerical research. Initially, external explosion experiments were conducted using both 35 kg spherical charges and cylindrical charges with aspect ratio of 4.8 at two different distances from the tunnel entrance. Comparative analysis of the blast wave parameters in the tunnel revealed that the explosive equivalent of the cylindrical charges was significantly higher than that of the spherical charges. To address this, an equivalent coefficient κ based on the spherical charges was proposed for the cylindrical charges. Subsequently, numerical simulations were conducted for the experimental conditions, and the numerical simulation results match the experiments well. Through numerical calculations, the reliability of the equivalent coefficient κ under the experimental conditions was verified, and comparison analysis indicated that the explosion energy of cylindrical charges spreads more radially, resulting in more explosion energy entering the tunnel, which is the fundamental reason for the increase in tunnel blast wave loads. Additionally, analyzing the explosion energy ratio entering the tunnel is an effective method for calculating the equivalent coefficient κ. Finally, through more than one hundred sets of numerical calculation results, the impact of the proportional distance λ and the ratio of charge mass to the tunnel cross-section dimension φ on the equivalence coefficients κ was investigated. An empirical formula for the equivalence coefficient κ was derived through fitting, and the accuracy of the formula was validated through literature experimental results. The research findings of this paper will provide valuable guidance for the calculation of blast wave loads in tunnel. 展开更多
关键词 Cylindrical charges Tunnel blast wave Equivalent coefficient Empirical formula Experiment and numerical simulation
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Influence analysis of chevron alignment signs on drivers' speed choices at horizontal curves on highways 被引量:4
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作者 伍毅平 赵晓华 +1 位作者 荣建 马建明 《Journal of Southeast University(English Edition)》 EI CAS 2015年第3期412-417,共6页
Using a driving simulator,the effects of Chinese chevrons on drivers’actual and perceived safe speeds at horizontal curves on two-lane rural highways are tested. Twelve horizontal curves with different roadway geomet... Using a driving simulator,the effects of Chinese chevrons on drivers’actual and perceived safe speeds at horizontal curves on two-lane rural highways are tested. Twelve horizontal curves with different roadway geometries are designed and used as the simulated scenarios.The results show that, regardless of the curve radius, chevrons at horizontal curves provide advance warning and speed control for vehicles on the nearside of chevrons.Besides,chevrons can be used as an addition to speed limit signs in preventing excessive speed at horizontal curves and, therefore, can contribute to a reduction in run-off-road crashes.Moreover, Chinese chevrons can also serve to provide an improved sense of safety while driving around sharp curves.These study results lay a foundation for setting Chinese chevrons more reasonably. 展开更多
关键词 chevron alignment sign driving simulator experiment SPEED horizontal curves
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