The preparation of green and economical bio-aviation fuel is a priority for the sustainable development industry.In this study,Jatropha oil was used as a raw material to catalyze the conversion of raw material to avia...The preparation of green and economical bio-aviation fuel is a priority for the sustainable development industry.In this study,Jatropha oil was used as a raw material to catalyze the conversion of raw material to aviation kerosene fraction by photothermal coupling under the conditions of light and low temperature.The correlations among conversion rate,target alkane selectivity,composition distribution,and catalyst microstructure were investigated by X-ray diffraction(XRD),high-resolution transmission electron microscopy(HRTEM),nitrogen(N2)adsorption and desorption,X-ray fluorescence(XRF),ammoniatemperature programmed desorption(NH3-TPD),ultraviolet-visible spectrophotometry(UV-Vis),and other characterization.The correlation between conversion and target alkane selectivity and composition distribution and catalyst microstructure was investigated,and different modification methods and different molecular sieve materials were selected.The results showed that the molecular sieves modified with the solid dispersion method could retain the structural stability of titanium dioxide(TiO2)and molecular sieves to a great extent while slightly enhancing the pore capacity and pore size of the catalyst to make it easier to adsorb reactants;the introduction of active metal platinum(Pt)could reduce the forbidden bandwidth of the catalyst,increase the weak acid amount of the catalyst,improve the adsorption capacity of hydrogen(H2),and thus improve the catalytic ability,resulting in a suitable catalyst for this study:P-21.The photothermal catalytic reaction of Jatropha oil using P-21 catalyst obtained 97.21%conversion and 74.99%selectivity of the target alkanes under the optimal process parameters.The results of this study provide effective catalyst parameters for research in the field of clean energy.展开更多
基金supported by the National Natural Science Foundation of China(Grant No.21868014)a Key Project of the Yunnan Fundamental Research Program(Study on Design of Novel Catalyst and Catalytic Process for Preparation of Bioaviation Kerosene from Vegetable Oils Based on Photo-thermal Catalytic Technology),2021 Low-carbon Development Guide Project of Yunnan Province,China(No.135),Key S&T Project of China Tobacco Yunnan Industrial Co.,Ltd.,(Grant No.2022GY03)+4 种基金Yunnan Academician and Expert Workstation(Grant No.202205AF150024)Yunnan International S&T Cooperation Program,China(Grant No.202003AF140001)Yunnan S&T Talents and Platform Program(Grant No.202105AC160058)Kunming International S&T Cooperation Base,China(Grant No.GHJD-2020026)Scientific research project of Yunnan Environmental Science Society,China(Grant No.XHKYKT006).
文摘The preparation of green and economical bio-aviation fuel is a priority for the sustainable development industry.In this study,Jatropha oil was used as a raw material to catalyze the conversion of raw material to aviation kerosene fraction by photothermal coupling under the conditions of light and low temperature.The correlations among conversion rate,target alkane selectivity,composition distribution,and catalyst microstructure were investigated by X-ray diffraction(XRD),high-resolution transmission electron microscopy(HRTEM),nitrogen(N2)adsorption and desorption,X-ray fluorescence(XRF),ammoniatemperature programmed desorption(NH3-TPD),ultraviolet-visible spectrophotometry(UV-Vis),and other characterization.The correlation between conversion and target alkane selectivity and composition distribution and catalyst microstructure was investigated,and different modification methods and different molecular sieve materials were selected.The results showed that the molecular sieves modified with the solid dispersion method could retain the structural stability of titanium dioxide(TiO2)and molecular sieves to a great extent while slightly enhancing the pore capacity and pore size of the catalyst to make it easier to adsorb reactants;the introduction of active metal platinum(Pt)could reduce the forbidden bandwidth of the catalyst,increase the weak acid amount of the catalyst,improve the adsorption capacity of hydrogen(H2),and thus improve the catalytic ability,resulting in a suitable catalyst for this study:P-21.The photothermal catalytic reaction of Jatropha oil using P-21 catalyst obtained 97.21%conversion and 74.99%selectivity of the target alkanes under the optimal process parameters.The results of this study provide effective catalyst parameters for research in the field of clean energy.
