Nd-Fe-B sintered magnet sludge wastes are one kind of typical commodity of recyclable rare-earth permanent magnet resources,and recycling such kind of wastes with economical and environmentally friendly techniques is ...Nd-Fe-B sintered magnet sludge wastes are one kind of typical commodity of recyclable rare-earth permanent magnet resources,and recycling such kind of wastes with economical and environmentally friendly techniques is crucial to the sustainable rare-earth industry.However,the current multistage wet process recycling technique for the sludge wastes involves high fabrication cost,excessive energy consumption,and heavy environmental burden.Therefore,short-process recycling techniques for Nd-Fe-B sintered magnet wastes have drawn increasing attention in the past decades.In this paper,we review recent efforts into short-process recycling Nd-Fe-B sintered magnet sludge wastes with emphasis on in-situ recycling techniques.展开更多
Lithium-ion batteries(LIBs)are the most popular energy storage devices due to their high energy density,high operating voltage,and long cycle life.However,green and effective recycling methods are needed because LIBs ...Lithium-ion batteries(LIBs)are the most popular energy storage devices due to their high energy density,high operating voltage,and long cycle life.However,green and effective recycling methods are needed because LIBs contain heavy metals such as Co,Ni,and Mn and organic compounds inside,which seriously threaten human health and the environment.In this work,we review the current status of spent LIB recycling,discuss the traditional pyrometallurgical and hydrometallurgical recovery processes,and summarize the existing short-process recovery technologies such as salt-assisted roasting,flotation processes,and direct recycling.Finally,we analyze the problems and potential research prospects of the current recycling process,and point out that the multidisciplinary integration of recycling will become the mainstream technology for the development of spent LIBs.展开更多
【目的】针对高浑浊度矿井水处理技术存在处理工序长、超滤(UF)膜进水水质要求高、膜污染严重的问题,采用短流程超滤膜化学反应器(MCR)组器处理高浑浊度矿井水。【方法】在保留短流程超滤MCR工艺精简、集成度高、占地面积小的优势基础上...【目的】针对高浑浊度矿井水处理技术存在处理工序长、超滤(UF)膜进水水质要求高、膜污染严重的问题,采用短流程超滤膜化学反应器(MCR)组器处理高浑浊度矿井水。【方法】在保留短流程超滤MCR工艺精简、集成度高、占地面积小的优势基础上,对短流程超滤MCR技术的抗污染膜组器型式进行改进,探究高效膜污染控制组器型式;并对改进后组器的运行参数开展试验研究,通过优化运行通量、系统回收率、运行周期、反洗通量4个运行参数,考察不同运行条件对膜污染控制效果,从而确定抗污染膜组器的稳定运行参数,通过进水悬浮物浓度,考察短流程超滤MCR组器的进水条件。【结果】结果表明,短流程超滤MCR组器中振动模式的抗污染性能优于曝气模式,跨膜压差(TMP)低于曝气模式0.16~0.26 k Pa/d。而在振动模式中,线性振动模式TMP低于旋转振动模式0.5 k Pa/d,表明线性振动模式抗污染能力强,且线性振动模式的吨水能耗为0.03 k W·h、水阻能耗占比为28.8%,均优于旋转振动模式。此外,线性振动模式短流程超滤MCR组器在运行通量≤40L/(m^(2)·h),系统回收率≤97%,运行周期为45 min,反洗通量为60 L/(m^(2)·h)条件下,能保证膜抗污染效果,短流程超滤MCR组器进水耐受悬浮物质量浓度达到2000 mg/L,运行参数调整对产水水质无显著影响。【结论】振动模式短流程超滤MCR组器可有效减少处理工艺流程,放宽UF膜进水水质要求,缓解UF膜运行过程中膜污染的情况,可为高浑浊度矿井水工艺改造提供技术指导。展开更多
单晶硅作为常用的红外光学材料,随着红外技术的不断发展,对光学元件的质量要求也越来越高。为了获得高面形精度、高表面质量的复杂曲面单晶硅光学元件,提出了激光原位辅助超精密车削、磁流变和小磨头抛光组合抛光修形的短流程加工工艺...单晶硅作为常用的红外光学材料,随着红外技术的不断发展,对光学元件的质量要求也越来越高。为了获得高面形精度、高表面质量的复杂曲面单晶硅光学元件,提出了激光原位辅助超精密车削、磁流变和小磨头抛光组合抛光修形的短流程加工工艺。采用激光原位辅助超精密车削加工后的单晶硅元件具有低亚表面损伤,与未加激光时相比,激光原位辅助超精密车削后的单晶硅亚表面损伤由920 n m降低至318 nm。并经过多轮磁流变和小磨头抛光组合工艺迭代加工后,单晶硅光学元件面形精度和表面质量得到有效提升,最终面形精度RMS值优于1/50λ,表面粗糙度Ra值优于0.5 nm。该方法抑制了加工过程中的亚表面损伤,减少了后续抛光过程中损伤去除时间,有效提高了单晶硅光学元件加工效率,且面形精度和表面质量可满足高精度光学元件应用要求。展开更多
基金the National Key R&D Project(2021YFB3500800,2020YFC1909004)Science and Technology Program ofAnhui Province(201903a07020002)+1 种基金Program of Top DisciplinesConstruction in Beijing(PXM2019_014204_500031)State Key Laboratoryof Rare Earth Permanent Magnetic Materials Opening Foundation(SKLREPM17OF02)。
文摘Nd-Fe-B sintered magnet sludge wastes are one kind of typical commodity of recyclable rare-earth permanent magnet resources,and recycling such kind of wastes with economical and environmentally friendly techniques is crucial to the sustainable rare-earth industry.However,the current multistage wet process recycling technique for the sludge wastes involves high fabrication cost,excessive energy consumption,and heavy environmental burden.Therefore,short-process recycling techniques for Nd-Fe-B sintered magnet wastes have drawn increasing attention in the past decades.In this paper,we review recent efforts into short-process recycling Nd-Fe-B sintered magnet sludge wastes with emphasis on in-situ recycling techniques.
基金financial support by the National Natural Science Foundation of China(No.52374293)Zhongyuan Science and Technology Innovation Leading Talent Project,China(No.224200510025)+1 种基金the Science and Technology Innovation Program of Hunan Province,China(No.2022RC1123)One of the authors,Hong-bo ZENG,gratefully acknowledges the support from the Natural Sciences and Engineering Research Council of Canada(NSERC)and the Canada Research Chairs Program.
文摘Lithium-ion batteries(LIBs)are the most popular energy storage devices due to their high energy density,high operating voltage,and long cycle life.However,green and effective recycling methods are needed because LIBs contain heavy metals such as Co,Ni,and Mn and organic compounds inside,which seriously threaten human health and the environment.In this work,we review the current status of spent LIB recycling,discuss the traditional pyrometallurgical and hydrometallurgical recovery processes,and summarize the existing short-process recovery technologies such as salt-assisted roasting,flotation processes,and direct recycling.Finally,we analyze the problems and potential research prospects of the current recycling process,and point out that the multidisciplinary integration of recycling will become the mainstream technology for the development of spent LIBs.
文摘【目的】针对高浑浊度矿井水处理技术存在处理工序长、超滤(UF)膜进水水质要求高、膜污染严重的问题,采用短流程超滤膜化学反应器(MCR)组器处理高浑浊度矿井水。【方法】在保留短流程超滤MCR工艺精简、集成度高、占地面积小的优势基础上,对短流程超滤MCR技术的抗污染膜组器型式进行改进,探究高效膜污染控制组器型式;并对改进后组器的运行参数开展试验研究,通过优化运行通量、系统回收率、运行周期、反洗通量4个运行参数,考察不同运行条件对膜污染控制效果,从而确定抗污染膜组器的稳定运行参数,通过进水悬浮物浓度,考察短流程超滤MCR组器的进水条件。【结果】结果表明,短流程超滤MCR组器中振动模式的抗污染性能优于曝气模式,跨膜压差(TMP)低于曝气模式0.16~0.26 k Pa/d。而在振动模式中,线性振动模式TMP低于旋转振动模式0.5 k Pa/d,表明线性振动模式抗污染能力强,且线性振动模式的吨水能耗为0.03 k W·h、水阻能耗占比为28.8%,均优于旋转振动模式。此外,线性振动模式短流程超滤MCR组器在运行通量≤40L/(m^(2)·h),系统回收率≤97%,运行周期为45 min,反洗通量为60 L/(m^(2)·h)条件下,能保证膜抗污染效果,短流程超滤MCR组器进水耐受悬浮物质量浓度达到2000 mg/L,运行参数调整对产水水质无显著影响。【结论】振动模式短流程超滤MCR组器可有效减少处理工艺流程,放宽UF膜进水水质要求,缓解UF膜运行过程中膜污染的情况,可为高浑浊度矿井水工艺改造提供技术指导。
文摘单晶硅作为常用的红外光学材料,随着红外技术的不断发展,对光学元件的质量要求也越来越高。为了获得高面形精度、高表面质量的复杂曲面单晶硅光学元件,提出了激光原位辅助超精密车削、磁流变和小磨头抛光组合抛光修形的短流程加工工艺。采用激光原位辅助超精密车削加工后的单晶硅元件具有低亚表面损伤,与未加激光时相比,激光原位辅助超精密车削后的单晶硅亚表面损伤由920 n m降低至318 nm。并经过多轮磁流变和小磨头抛光组合工艺迭代加工后,单晶硅光学元件面形精度和表面质量得到有效提升,最终面形精度RMS值优于1/50λ,表面粗糙度Ra值优于0.5 nm。该方法抑制了加工过程中的亚表面损伤,减少了后续抛光过程中损伤去除时间,有效提高了单晶硅光学元件加工效率,且面形精度和表面质量可满足高精度光学元件应用要求。
