Northeast China(NEC),a critical agricultural and ecological zone,has experienced intensified hydrological variability under global warming,with cascading impacts on food security and ecosystem resilience.This study ut...Northeast China(NEC),a critical agricultural and ecological zone,has experienced intensified hydrological variability under global warming,with cascading impacts on food security and ecosystem resilience.This study utilized observational data and two new generation reanalysis products(i.e.,the fifth major global reanalysis produced by ECMWF(ERA5)and the Japanese Reanalysis for Three Quarters of a Century(JRA-3Q))to investigate the shift changes in precipitation in NEC around 2000 and associated water vapor transport.The analysis identified a pivotal interdecadal shift in 1998/99,transitioning from moderate increases(17.5 mm/10 yr during 1980-1998)to accelerated but more variable precipitation growth(85.4 mm/10 yr post-1999).While the mean precipitation during the post-shift period decreased,enhanced anticyclonic circulation amplified moisture divergence over continental NEC,redirecting vapor flux toward coastal regions.Crucially,trajectory analysis demonstrated regime-dependent moisture sourcing:midlatitude westerlies dominated during wet extremes(44% of trajectories in 1998),whereas East Asian monsoon flows prevailed in drought years(36% of trajectories in 2007).The post-1998 period exhibited increased reliance on localized recycling(45%of mid-tropospheric trajectories),reflecting weakened monsoonal inflow.These findings highlight NEC’s growing vulnerability to competing moisture pathways and atmospheric blocking-a dual mechanism that explains rising extremes despite declining mean precipitation.By reconciling dataset discrepancies(ERA5 vs.JRA-3Q trends)and elucidating circulation-precipitation linkages,this work provides actionable insights for climate-resilient agriculture in NEC’s water-stressed ecosystems.展开更多
Data center industries have been facing huge energy challenges due to escalating power consumption and associated carbon emissions.In the context of carbon neutrality,the integration of data centers with renewable ene...Data center industries have been facing huge energy challenges due to escalating power consumption and associated carbon emissions.In the context of carbon neutrality,the integration of data centers with renewable energy has become a prevailing trend.To advance the renewable energy integration in data centers,it is imperative to thoroughly explore the data centers’operational flexibility.Computing workloads and refrigeration systems are recognized as two promising flexible resources for power regulationwithin data centermicro-grids.This paper identifies and categorizes delay-tolerant computing workloads into three types(long-running non-interruptible,long-running interruptible,and short-running)and develops mathematical time-shifting models for each.Additionally,this paper examines the thermal dynamics of the computer room and derives a time-varying temperature model coupled to refrigeration power.Building on these models,this paper proposes a two-stage,multi-time scale optimization scheduling framework that jointly coordinates computing workloads time-shift in day-ahead scheduling and refrigeration power control in intra-day dispatch to mitigate renewable variability.A case study demonstrates that the framework effectively enhances the renewable-energy utilization,improves the operational economy of the data center microgrid,and mitigates the impact of renewable power uncertainty.The results highlight the potential of coordinated computing workloads and thermal system flexibility to support greener,more cost-effective data center operation.展开更多
Potassium(K)is known to enhance the catalytic performance of Fe-based catalysts in the reverse water-gas shift(rWGS)reaction,which is highly relevant during Fischer-Tropsch(FT)synthesis of CO_(2)-H_(2) mixtures.To elu...Potassium(K)is known to enhance the catalytic performance of Fe-based catalysts in the reverse water-gas shift(rWGS)reaction,which is highly relevant during Fischer-Tropsch(FT)synthesis of CO_(2)-H_(2) mixtures.To elucidate the mechanistic role of K promoter,we employed density functional theory(DFT)calculations in conjunction with microkinetic modelling for two representative surface terminations of Hägg carbide(χ-Fe_(5)C_(2)),i.e.,(010)and(510).K_(2)O results in stronger adsorption of CO_(2)and H_(2) on Hägg carbide and promotes C–O bond dissociation of adsorbed CO_(2)by increasing the electron density on Fe atoms close to the promoter oxide.The increased electron density of the surface Fe atoms results in an increased electron-electron repulsion with bonding orbitals of adsorbed CO_(2).Microkinetics simulations predict that K_(2)O increases the CO_(2)conversion during CO_(2)-FT synthesis.K_(2)O also enhances CO adsorption and dissociation,facilitating the formation of methane,used here as a proxy for hydrocarbons formation during CO_(2)-FT synthesis.CO dissociation and O removal via H_(2)O compete as the rate-controlling steps in CO_(2)-FT.展开更多
Anthropogenic climate change is altering species distributions globally.While species distributions are expected to shift to higher latitudes and elevations under global warming,empirical evidence on distribution shif...Anthropogenic climate change is altering species distributions globally.While species distributions are expected to shift to higher latitudes and elevations under global warming,empirical evidence on distribution shifts is mixed,and factors mediating the direction and magnitude of range shifts remain unclear.Using a dataset of 132new provincial records for 96 resident bird species from 2000 to 2023,we measured geographic distance,latitudinal shift,and temperature shift from each new record to the historical range for each species to test for poleward shifts.We assessed taxonomic variation in the magnitude of range shifts and used phylogenetic generalized linear mixed models to quantify relationships between species traits and the extent of range shifts.Our results revealed that new records occurred at a mean geographic distance of 420 km from historical ranges,with mean latitudinal shifts of+1.68°(poleward)and temperature shifts of-1.33℃(toward colder climates).The magnitude of geographic range shifts was strongly constrained by phylogenetic relatedness.Habitat breadth,habitat openness,and centroid latitude of historical ranges emerged as significant predictors of range shifts.Our results suggest that resident bird species'geographic ranges in China are shifting poleward,but the magnitude of these shifts is non-random across lineages.Species with broader habitat preferences and those from warmer climates are more likely to shift farther from their historical ranges and toward higher latitudes.This study emphasizes taxonomic variation in species range shifts and highlights the need for species-and site-specific conservation strategies under global warming.展开更多
With the continuous improvement of the medical industry’s requirements for the professional capabilities of nursing talents,traditional nursing teaching models can hardly meet the needs of complex nursing work in neu...With the continuous improvement of the medical industry’s requirements for the professional capabilities of nursing talents,traditional nursing teaching models can hardly meet the needs of complex nursing work in neurology.This paper focuses on nursing education for neurology nursing students and explores the construction of the“one-on-one”teaching model,aiming to achieve a paradigm shift in nursing education.By analyzing the current status of neurology nursing education,this paper identifies the problems in traditional teaching models.Combining the advantages of the“one-on-one”teaching model,it elaborates on the construction path of this model from aspects such as the selection and training of teaching instructors,the design of teaching content,the innovation of teaching methods,and the improvement of the teaching evaluation system.The research shows that the“one-on-one”teaching model can significantly enhance nursing students’mastery of professional knowledge,clinical operation skills,communication skills,and emergency response capabilities,as well as strengthen their professional identity and sense of responsibility.It provides an effective way to cultivate high-quality nursing talents who can meet the needs of neurology nursing work and promotes the innovative development of nursing education.展开更多
Highly accurate international height reference frames with long-term stability,global consistency,and homogeneity are crucial for monitoring sea level variations,understanding climate change,managing disasters,and sup...Highly accurate international height reference frames with long-term stability,global consistency,and homogeneity are crucial for monitoring sea level variations,understanding climate change,managing disasters,and supporting other applications that benefit scientific research and societal well-being.Currently,there are over 100 local height reference systems worldwide.Unifying these systems is a pivotal step toward constructing international height reference frames.The method introduced in this study-the gravity frequency shift via Satellite Frequency Signal Transfer(SFST)-represents a groundbreaking relativistic geodetic approach,demonstrating its potential to surpass the constraints of conventional techniques.The advent of high-precision optical atomic clocks(OAC)with an accuracy level of 1×10^(-18) has facilitated this method's implementation.The International Association of Geodesy(IAG)has established the International Height Reference System(IHRS)and its practical realization,the International Height Reference Frame(IHRF).Our study focuses on two neighbouring height systems:the China Height System(CHS)and the Nepal Height System(NHS),separated by the Himalayas and the Xizang plateau.We aim to unify these two systems by determining the geopotential and orthometric height differences between their respective height datum stations:the Qingdao Height Datum Station(QHDS)and the Madar Height Datum Station(MHDS)using a simulation experiment with the method mentioned above.Using an OAC with an accuracy of 1×10^(-18),we identified a geopotential difference of-8.348±0.464 m^(2)s^(-2) and an orthometric height difference of 0.786±0.047 m between QHDS and MHDS.These results suggest that the introduced method could unify any two height systems with fewcentimeter-level precision,emphasizing its significance in contributing to the construction of the IHRS/IHRF with today's required precision.In summary,the SFST technique is a novel geodetic method that offers an alternative for height system unification,delivering centimeter-level precision,surpassing traditional methods,and supporting the development of the IHRF.展开更多
The transition energies of the 1s^(2)2s^(2)S_(1/2)→1s^(2)2p^(2)p_(1/2,3/2)transitions in Li-like Th87+ions were calculated by combining the multi-configuration Dirac-Hartree-Fock(MCDHF)method with the model-quantum e...The transition energies of the 1s^(2)2s^(2)S_(1/2)→1s^(2)2p^(2)p_(1/2,3/2)transitions in Li-like Th87+ions were calculated by combining the multi-configuration Dirac-Hartree-Fock(MCDHF)method with the model-quantum electrodynamics(modelQED)approach.The effects of electron correlation,Breit interaction,and QED effects were analyzed in detail.The isotope shifts,including the mass shifts and field shifts,due to the 2s2S_(1/2)→2p^(2)P_(1/2,3/2)transitions were then calculated using two different methods,namely,the MCDHF method and the finite-field method.The results show that these two methods are in excellent agreement.展开更多
According to the 2024 China Marine Economy Statistical Bulletin(hereinafter“the Bulletin”),China’s marine economy surpassed the 10 trillion yuan(US$1.38 trillion)mark for the first time in 2024,0.9 percentage point...According to the 2024 China Marine Economy Statistical Bulletin(hereinafter“the Bulletin”),China’s marine economy surpassed the 10 trillion yuan(US$1.38 trillion)mark for the first time in 2024,0.9 percentage points higher than the growth rate of the national GDP.展开更多
Amid overlapping crises and uncertainties as the world enters an era of turbulence and transformation,the countries of the Global South are swiftly emerging from the periphery of world politics to the forefront of int...Amid overlapping crises and uncertainties as the world enters an era of turbulence and transformation,the countries of the Global South are swiftly emerging from the periphery of world politics to the forefront of international cooperation,playing an increasingly vital role in advancing humanity’s collective progress.展开更多
An enhanced understanding of the history of the western Qinling-Dabie orogen is pivotal in reconstructing geological processes of the east Asian mainland.However,less attention has been paid to its early-stage uplift-...An enhanced understanding of the history of the western Qinling-Dabie orogen is pivotal in reconstructing geological processes of the east Asian mainland.However,less attention has been paid to its early-stage uplift-erosion history after closure of surrounding oceanic basins at the mid-Paleozoic.In this study,we undertook a comprehensive study including paleocurrent reconstruction,sandstone petrology,and detrital zircon U-Pb dating on Late Carboniferous to Early Permian successions in the southern Ordos neighboring the northern Qinling-Dabie.New provenance data reveal a significant provenance shift at the Carboniferous-Permian transition.The older Benxi Formation was sourced southerly from the North Qinling Terrane that provided detritus mostly of Neoproterozoic and Early Paleozoic ages.In contrast,Early Permian samples yield age relation dominated by Neoarchean,Paleoproterozoic,Early Paleozoic,and Late Paleozoic age populations,with a significant gap of ca.1600-550 Ma,implying a sediment derivation from the Inner Mongolia Continental Arc.This shift is further verified by paleocurrent transition from south to north then.We suggest that the North Qinling Terrane experienced a significant uplift history from ca.500 Ma and remained as a highland until end-Carboniferous.From Early Permian,the North Qinling Terrane was submerged,covered by widespread deltaic sedimentation there.Northerly source from the Inner Mongolia Continental Arc began to be accumulated in the northern flank of the North Qinling Terrane,before termination approximately along the southern North Qinling Terrane,where shallow-water carbonate shelf sedimentation sustained from Devonian to Triassic.This new finding indicates that uplift of the North Qinling Terrane lasted about 150 Ma after the Proto-Tethys Ocean closure.展开更多
National Fire codes,mandated by government authorities to tackle technical challenges in fire prevention and control,establish fundamental standards for construction practices.International collaboration in fire prote...National Fire codes,mandated by government authorities to tackle technical challenges in fire prevention and control,establish fundamental standards for construction practices.International collaboration in fire protection technologies has opened avenues for China to access a wealth of documents and codes,which are crucial in crafting regulations and developing a robust,scientific framework for fire code formulation.However,the translation of these codes into Chinese has been inadequate,thereby diminishing the benefits of technological exchange and collaborative learning.This underscores the necessity for comprehensive research into code translation,striving for higher-quality translations guided by established translation theories.In this study,we translated the initial segment of the NFPA 1 Fire Code into Chinese and examined both the source text and target text through the lens of Translation Shift Theory,a concept introduced by Catford.The conclusion culminated in identifying four key shifts across various linguistic levels:lexis,sentences,and groups,to ensure an accurate and precise translation of fire codes.This study offers a through and lucid explanation of how the translator integrates Catford’s theories to solve technical challenges in NFPA 1 Fire Code translation,and establish essential standards for construction translation practices.展开更多
The current dialogue system can be sensitive to the emotions in the user's words,generating an empathetic response to help calm the user's emotions.But in some cases,eliciting empathetic responses may not adeq...The current dialogue system can be sensitive to the emotions in the user's words,generating an empathetic response to help calm the user's emotions.But in some cases,eliciting empathetic responses may not adequately mitigate the adverse effects that the current conversation topic is having on users.The dialogue system will continue the conversation with the user under this uncomfortable topic,which will lead to a worse chat situation or even an impasse.To solve this problem,a dialogue system that can change the topic autonomously according to the user's emotions is proposed in this paper.Specifically,the dialogue system first collects the emotional semantic information of the users and then detects it according to the emotion classification module.Once the detection results show that the user is in a bad mood,the topic change module selects a new topic from the context to shift to and generates a response.This not only helps to calm the user's mood but also move the conversation to a new area,steering the user away from the uncomfortable topic.The experimental results show that the proposed method incurs less cost in terms of content quality,but improves the emotional perception ability.Additionally,it endows the dialogue system with the ability to change the topic,and improves the user's dialogue experience.展开更多
Introduction Task-shifting and task-sharing strategies show promise for managing chronic diseases especially in low-income and middle-income countries(LMICs),though their effectiveness in multimorbidity management rem...Introduction Task-shifting and task-sharing strategies show promise for managing chronic diseases especially in low-income and middle-income countries(LMICs),though their effectiveness in multimorbidity management remains unclear.This study synthesised evidence on task-shifting and task-sharing strategies globally and assessed the impact on core health outcomes in multimorbidity management.Methods We conducted a systematic review and meta-analysis of global studies evaluating task-shifting and sharing interventions for individuals with multimorbidity.Six databases,including PubMed,Embase,Web of Science,Ovid(Medline),CINAHL and Cochrane Library,were searched for studies reporting the core outcomes of multimorbidity management in quality of life,mortality,hospitalisation,emergency department visits and symptoms of depression and anxiety.Random-effects models were used to calculate pooled effect sizes with heterogeneity assessed through subgroup and meta-regression analyses.Results From 8471 records,36 studies from 14 countries were included,with only 5 conducted in LMICs.Twenty-one studies,encompassing 20989 participants,were eligible for meta-analysis.More than half of the studies involved nurses as delegates,with some sharing the tasks with health professionals and about 10%of studies involved non-health professionals,including community healthcare workers as delegates to share the responsibility in caring for individuals with multimorbidity.Most studies were multicomponent,with 16.7%addressing all guideline-recommended aspects of multimorbidity management.By pooling the findings,task-shifting and task-sharing interventions were associated with a 27%reduction in mortality(OR:0.73,95%CI:0.55 to 0.97,I2=0%),a modest improvement in quality of life(standardised mean difference(SMD):0.1,95%CI:0.03 to 0.17,I2=47%)and reduced symptoms of depression(SMD:0.27,95%CI:−0.52 to–0.02,I2=90%),but showed no significant effect on hospitalisation,emergency visits or anxiety-related symptoms.展开更多
Standard perturbation theory is employed to calculate the mass shifts of the 2^(1)S_(0)-^(3)S_(1)and 2^(3)S_(1)-2^(3)P_(J)transitions for^(4,6,8)He.High-precision results are obtained for the mass shifts in the isotop...Standard perturbation theory is employed to calculate the mass shifts of the 2^(1)S_(0)-^(3)S_(1)and 2^(3)S_(1)-2^(3)P_(J)transitions for^(4,6,8)He.High-precision results are obtained for the mass shifts in the isotope pairs 6He-4He and 8He-4He,with uncertainties below 1 part per million(ppm).Our analysis provides a complete set of isotope-shift results and systematically examines their sensitivity to nuclear charge-radius differences.Once experimental measurements reach a precision comparable to that of the calculated mass shifts,the squared differences of nuclear charge radii can be determined with an accuracy of approximately 0.4%-0.6%,representing an order-of-magnitude improvement over current values.展开更多
The aggressive nature and high mortality rate of lung cancer underscore the imperative need for early diagnosis of the disease.Thus,aminopeptidase N(APN),a potential biomarker for lung cancer,should be thoroughly inve...The aggressive nature and high mortality rate of lung cancer underscore the imperative need for early diagnosis of the disease.Thus,aminopeptidase N(APN),a potential biomarker for lung cancer,should be thoroughly investigated in this context.This report describes the development of HA-apn,a novel near-infrared fluorescent probe,specifically engineered for the sensitive detection of endogenous APN.Characterized by its high selectivity,straightforward molecular architecture,and suitable optical properties,including a long-wavelength emission at 835 nm and a large Stokes shift of 285 nm,HA-apn had high efficacy in identifying overexpressed APN in tumor cells,which shows its potential in pinpointing malignancies.To further validate its applicability and effectiveness in facilitating the direct and enhanced visualization of pulmonary alterations,an in situ lung cancer mouse model was employed.Notably,HAapn was applied for in vivo imaging of APN activity in the lung cancer mouse model receiving the probe through aerosol inhalation,and rapid and precise diagnostic results were achieved within 30min postadministration.Overall,HA-apn can be applied as an effective,non-intrusive tool for the rapid and accurate detection of pulmonary conditions.展开更多
We investigate theoretically the effects of chirped laser pulses on high-order harmonic generation(HHG)from solids.We find that the harmonic spectra display redshifts for the driving laser pulses with negative chirp a...We investigate theoretically the effects of chirped laser pulses on high-order harmonic generation(HHG)from solids.We find that the harmonic spectra display redshifts for the driving laser pulses with negative chirp and blueshifts for those with positive chirp,which is due to the change in the instantaneous frequency of the driving laser for different chirped pulses.The analysis of crystal-momentum-resolved(k-resolved)HHG reveals that the frequency shifts are equal for the harmonics generated by different crystal momentum channels.The frequency shifts in the cutoff region are larger than those in the plateau region.With the increase of the absolute value of the chirp parameters,the frequency shifts of HHG become more significant,leading to the shifts from odd-to even-order harmonics.We also demonstrate that the frequency shifts of harmonic spectra are related to the duration of the chirped laser field,but are insensitive to the laser intensity and dephasing time.展开更多
Against the backdrop of climate change,the activity of tropical cyclones(TCs)has captured widespread attention.Observational datasets indicate a declining trend in the genesis longitude of western North Pacific(WNP)TC...Against the backdrop of climate change,the activity of tropical cyclones(TCs)has captured widespread attention.Observational datasets indicate a declining trend in the genesis longitude of western North Pacific(WNP)TCs.This study investigates the zonal changes of WNP TCs with CMIP6-HighResMIP models.These models capture the genesis density of WNP TCs fairly well.The results reveal a westward shift in TC genesis longitude.This trend is associated with the significant reduction in the TC frequency over the southeastern WNP.The study also discusses changes in large-scale circulation patterns and the impact of the strengthening Pacific Walker circulation.展开更多
The research on ocean dynamics information plays a crucial role in understanding ocean phenomena, assessing marine environmental impacts, and guiding engineering designs. The Doppler information observed by radars ref...The research on ocean dynamics information plays a crucial role in understanding ocean phenomena, assessing marine environmental impacts, and guiding engineering designs. The Doppler information observed by radars reflects sea surface dynamics, to which ocean waves make important contributions. Low-incidence-angle real aperture radar(RAR)demonstrates great potential for independently observing vectorial Doppler information on the ocean surface. To systematically characterize and accurately estimate the wave-induced Doppler frequency shift(WVF) from lowincidence-angle RAR, this study conducts comprehensive influencing factor analysis and establishes sea-stateparameterized WVF models. First, a simulated WVF dataset is generated under a rotating low-incidence-angle RAR.The feature parameters of WVF are then determined by analysing contributing factors including wind waves, swells,and sea state parameters. Furthermore, two WVF models(WVF_Ku P9 with 9 inputs and WVF_Ku P4 with 4 inputs) are constructed by the Transformer encoder for different application scenarios. Both models achieve high accuracy for WVF estimation with root mean square errors(RMSE) of 1.874 Hz and 2.716 Hz, respectively. The reliability and superiority of the proposed models are validated through comparisons with the Ka DOP, which is a typical geophysical model function(GMF). The findings in this paper advance the understanding of WVF characteristics and generation mechanisms. The proposed estimation models can provide reliable estimates, offering critical references for lowincidence-angle RAR applications such as ocean surface current retrieval.展开更多
基金supported by the National Natural Science Foundation of China[grant numbers 42275185 and 42205032]the Fundamental Research Funds for the Central Universities[grant number B250201118]。
文摘Northeast China(NEC),a critical agricultural and ecological zone,has experienced intensified hydrological variability under global warming,with cascading impacts on food security and ecosystem resilience.This study utilized observational data and two new generation reanalysis products(i.e.,the fifth major global reanalysis produced by ECMWF(ERA5)and the Japanese Reanalysis for Three Quarters of a Century(JRA-3Q))to investigate the shift changes in precipitation in NEC around 2000 and associated water vapor transport.The analysis identified a pivotal interdecadal shift in 1998/99,transitioning from moderate increases(17.5 mm/10 yr during 1980-1998)to accelerated but more variable precipitation growth(85.4 mm/10 yr post-1999).While the mean precipitation during the post-shift period decreased,enhanced anticyclonic circulation amplified moisture divergence over continental NEC,redirecting vapor flux toward coastal regions.Crucially,trajectory analysis demonstrated regime-dependent moisture sourcing:midlatitude westerlies dominated during wet extremes(44% of trajectories in 1998),whereas East Asian monsoon flows prevailed in drought years(36% of trajectories in 2007).The post-1998 period exhibited increased reliance on localized recycling(45%of mid-tropospheric trajectories),reflecting weakened monsoonal inflow.These findings highlight NEC’s growing vulnerability to competing moisture pathways and atmospheric blocking-a dual mechanism that explains rising extremes despite declining mean precipitation.By reconciling dataset discrepancies(ERA5 vs.JRA-3Q trends)and elucidating circulation-precipitation linkages,this work provides actionable insights for climate-resilient agriculture in NEC’s water-stressed ecosystems.
基金supported by Science and Technology Standard Project of Guangdong Electric Power Design Institute(ER11301W,ER11811W).
文摘Data center industries have been facing huge energy challenges due to escalating power consumption and associated carbon emissions.In the context of carbon neutrality,the integration of data centers with renewable energy has become a prevailing trend.To advance the renewable energy integration in data centers,it is imperative to thoroughly explore the data centers’operational flexibility.Computing workloads and refrigeration systems are recognized as two promising flexible resources for power regulationwithin data centermicro-grids.This paper identifies and categorizes delay-tolerant computing workloads into three types(long-running non-interruptible,long-running interruptible,and short-running)and develops mathematical time-shifting models for each.Additionally,this paper examines the thermal dynamics of the computer room and derives a time-varying temperature model coupled to refrigeration power.Building on these models,this paper proposes a two-stage,multi-time scale optimization scheduling framework that jointly coordinates computing workloads time-shift in day-ahead scheduling and refrigeration power control in intra-day dispatch to mitigate renewable variability.A case study demonstrates that the framework effectively enhances the renewable-energy utilization,improves the operational economy of the data center microgrid,and mitigates the impact of renewable power uncertainty.The results highlight the potential of coordinated computing workloads and thermal system flexibility to support greener,more cost-effective data center operation.
文摘Potassium(K)is known to enhance the catalytic performance of Fe-based catalysts in the reverse water-gas shift(rWGS)reaction,which is highly relevant during Fischer-Tropsch(FT)synthesis of CO_(2)-H_(2) mixtures.To elucidate the mechanistic role of K promoter,we employed density functional theory(DFT)calculations in conjunction with microkinetic modelling for two representative surface terminations of Hägg carbide(χ-Fe_(5)C_(2)),i.e.,(010)and(510).K_(2)O results in stronger adsorption of CO_(2)and H_(2) on Hägg carbide and promotes C–O bond dissociation of adsorbed CO_(2)by increasing the electron density on Fe atoms close to the promoter oxide.The increased electron density of the surface Fe atoms results in an increased electron-electron repulsion with bonding orbitals of adsorbed CO_(2).Microkinetics simulations predict that K_(2)O increases the CO_(2)conversion during CO_(2)-FT synthesis.K_(2)O also enhances CO adsorption and dissociation,facilitating the formation of methane,used here as a proxy for hydrocarbons formation during CO_(2)-FT synthesis.CO dissociation and O removal via H_(2)O compete as the rate-controlling steps in CO_(2)-FT.
基金supported by grants from the National Natural Science Foundation of China(Grant No.32271733)Guangdong Basic and Applied Basic Research Foundation(Grant No.2023A1515011045)+1 种基金Science and Technology Projects in Guangzhou(Grant No.2023A04J0121)SCNU Training Program of Innovation for Undergraduates,China。
文摘Anthropogenic climate change is altering species distributions globally.While species distributions are expected to shift to higher latitudes and elevations under global warming,empirical evidence on distribution shifts is mixed,and factors mediating the direction and magnitude of range shifts remain unclear.Using a dataset of 132new provincial records for 96 resident bird species from 2000 to 2023,we measured geographic distance,latitudinal shift,and temperature shift from each new record to the historical range for each species to test for poleward shifts.We assessed taxonomic variation in the magnitude of range shifts and used phylogenetic generalized linear mixed models to quantify relationships between species traits and the extent of range shifts.Our results revealed that new records occurred at a mean geographic distance of 420 km from historical ranges,with mean latitudinal shifts of+1.68°(poleward)and temperature shifts of-1.33℃(toward colder climates).The magnitude of geographic range shifts was strongly constrained by phylogenetic relatedness.Habitat breadth,habitat openness,and centroid latitude of historical ranges emerged as significant predictors of range shifts.Our results suggest that resident bird species'geographic ranges in China are shifting poleward,but the magnitude of these shifts is non-random across lineages.Species with broader habitat preferences and those from warmer climates are more likely to shift farther from their historical ranges and toward higher latitudes.This study emphasizes taxonomic variation in species range shifts and highlights the need for species-and site-specific conservation strategies under global warming.
文摘With the continuous improvement of the medical industry’s requirements for the professional capabilities of nursing talents,traditional nursing teaching models can hardly meet the needs of complex nursing work in neurology.This paper focuses on nursing education for neurology nursing students and explores the construction of the“one-on-one”teaching model,aiming to achieve a paradigm shift in nursing education.By analyzing the current status of neurology nursing education,this paper identifies the problems in traditional teaching models.Combining the advantages of the“one-on-one”teaching model,it elaborates on the construction path of this model from aspects such as the selection and training of teaching instructors,the design of teaching content,the innovation of teaching methods,and the improvement of the teaching evaluation system.The research shows that the“one-on-one”teaching model can significantly enhance nursing students’mastery of professional knowledge,clinical operation skills,communication skills,and emergency response capabilities,as well as strengthen their professional identity and sense of responsibility.It provides an effective way to cultivate high-quality nursing talents who can meet the needs of neurology nursing work and promotes the innovative development of nursing education.
基金the National Natural Science Foundation of China(NSFC)(Grant Nos.42030105,42274011,42074019,41974034,42204006)。
文摘Highly accurate international height reference frames with long-term stability,global consistency,and homogeneity are crucial for monitoring sea level variations,understanding climate change,managing disasters,and supporting other applications that benefit scientific research and societal well-being.Currently,there are over 100 local height reference systems worldwide.Unifying these systems is a pivotal step toward constructing international height reference frames.The method introduced in this study-the gravity frequency shift via Satellite Frequency Signal Transfer(SFST)-represents a groundbreaking relativistic geodetic approach,demonstrating its potential to surpass the constraints of conventional techniques.The advent of high-precision optical atomic clocks(OAC)with an accuracy level of 1×10^(-18) has facilitated this method's implementation.The International Association of Geodesy(IAG)has established the International Height Reference System(IHRS)and its practical realization,the International Height Reference Frame(IHRF).Our study focuses on two neighbouring height systems:the China Height System(CHS)and the Nepal Height System(NHS),separated by the Himalayas and the Xizang plateau.We aim to unify these two systems by determining the geopotential and orthometric height differences between their respective height datum stations:the Qingdao Height Datum Station(QHDS)and the Madar Height Datum Station(MHDS)using a simulation experiment with the method mentioned above.Using an OAC with an accuracy of 1×10^(-18),we identified a geopotential difference of-8.348±0.464 m^(2)s^(-2) and an orthometric height difference of 0.786±0.047 m between QHDS and MHDS.These results suggest that the introduced method could unify any two height systems with fewcentimeter-level precision,emphasizing its significance in contributing to the construction of the IHRS/IHRF with today's required precision.In summary,the SFST technique is a novel geodetic method that offers an alternative for height system unification,delivering centimeter-level precision,surpassing traditional methods,and supporting the development of the IHRF.
基金Project supported by the National Key Research and Development Program of China(Grant No.2022YFA1602500)the National Natural Science Foundation of China(Grant Nos.1236040286,12474250,12174316,12464036,and12404306)+1 种基金the Young Teachers Scientific Research Ability Promotion Plan of Northwest Normal University(Grant No.NWNU-LKQN2020-10)the Funds for Innovative Fundamental Research Group Project of Gansu Province(Grant No.20JR5RA541)。
文摘The transition energies of the 1s^(2)2s^(2)S_(1/2)→1s^(2)2p^(2)p_(1/2,3/2)transitions in Li-like Th87+ions were calculated by combining the multi-configuration Dirac-Hartree-Fock(MCDHF)method with the model-quantum electrodynamics(modelQED)approach.The effects of electron correlation,Breit interaction,and QED effects were analyzed in detail.The isotope shifts,including the mass shifts and field shifts,due to the 2s2S_(1/2)→2p^(2)P_(1/2,3/2)transitions were then calculated using two different methods,namely,the MCDHF method and the finite-field method.The results show that these two methods are in excellent agreement.
文摘According to the 2024 China Marine Economy Statistical Bulletin(hereinafter“the Bulletin”),China’s marine economy surpassed the 10 trillion yuan(US$1.38 trillion)mark for the first time in 2024,0.9 percentage points higher than the growth rate of the national GDP.
文摘Amid overlapping crises and uncertainties as the world enters an era of turbulence and transformation,the countries of the Global South are swiftly emerging from the periphery of world politics to the forefront of international cooperation,playing an increasingly vital role in advancing humanity’s collective progress.
基金the National Natural Science Foundation of China(Grant Nos:42372253 and 42072260)the Youth Innovation Team of Shaanxi Universitiesthe Science and Technology Project of PetroChina(No.2023ZZ0201).
文摘An enhanced understanding of the history of the western Qinling-Dabie orogen is pivotal in reconstructing geological processes of the east Asian mainland.However,less attention has been paid to its early-stage uplift-erosion history after closure of surrounding oceanic basins at the mid-Paleozoic.In this study,we undertook a comprehensive study including paleocurrent reconstruction,sandstone petrology,and detrital zircon U-Pb dating on Late Carboniferous to Early Permian successions in the southern Ordos neighboring the northern Qinling-Dabie.New provenance data reveal a significant provenance shift at the Carboniferous-Permian transition.The older Benxi Formation was sourced southerly from the North Qinling Terrane that provided detritus mostly of Neoproterozoic and Early Paleozoic ages.In contrast,Early Permian samples yield age relation dominated by Neoarchean,Paleoproterozoic,Early Paleozoic,and Late Paleozoic age populations,with a significant gap of ca.1600-550 Ma,implying a sediment derivation from the Inner Mongolia Continental Arc.This shift is further verified by paleocurrent transition from south to north then.We suggest that the North Qinling Terrane experienced a significant uplift history from ca.500 Ma and remained as a highland until end-Carboniferous.From Early Permian,the North Qinling Terrane was submerged,covered by widespread deltaic sedimentation there.Northerly source from the Inner Mongolia Continental Arc began to be accumulated in the northern flank of the North Qinling Terrane,before termination approximately along the southern North Qinling Terrane,where shallow-water carbonate shelf sedimentation sustained from Devonian to Triassic.This new finding indicates that uplift of the North Qinling Terrane lasted about 150 Ma after the Proto-Tethys Ocean closure.
基金Hangzhou Philosophy and Social Science Planning Program(24JD15)。
文摘National Fire codes,mandated by government authorities to tackle technical challenges in fire prevention and control,establish fundamental standards for construction practices.International collaboration in fire protection technologies has opened avenues for China to access a wealth of documents and codes,which are crucial in crafting regulations and developing a robust,scientific framework for fire code formulation.However,the translation of these codes into Chinese has been inadequate,thereby diminishing the benefits of technological exchange and collaborative learning.This underscores the necessity for comprehensive research into code translation,striving for higher-quality translations guided by established translation theories.In this study,we translated the initial segment of the NFPA 1 Fire Code into Chinese and examined both the source text and target text through the lens of Translation Shift Theory,a concept introduced by Catford.The conclusion culminated in identifying four key shifts across various linguistic levels:lexis,sentences,and groups,to ensure an accurate and precise translation of fire codes.This study offers a through and lucid explanation of how the translator integrates Catford’s theories to solve technical challenges in NFPA 1 Fire Code translation,and establish essential standards for construction translation practices.
基金Sponsored by Natural Science Foundation of Heilongjiang Provincial(Grant No.LH2023F033)Science and Technology Innovation Talent Project of Harbin(Grant No.2022CXRCCG006).
文摘The current dialogue system can be sensitive to the emotions in the user's words,generating an empathetic response to help calm the user's emotions.But in some cases,eliciting empathetic responses may not adequately mitigate the adverse effects that the current conversation topic is having on users.The dialogue system will continue the conversation with the user under this uncomfortable topic,which will lead to a worse chat situation or even an impasse.To solve this problem,a dialogue system that can change the topic autonomously according to the user's emotions is proposed in this paper.Specifically,the dialogue system first collects the emotional semantic information of the users and then detects it according to the emotion classification module.Once the detection results show that the user is in a bad mood,the topic change module selects a new topic from the context to shift to and generates a response.This not only helps to calm the user's mood but also move the conversation to a new area,steering the user away from the uncomfortable topic.The experimental results show that the proposed method incurs less cost in terms of content quality,but improves the emotional perception ability.Additionally,it endows the dialogue system with the ability to change the topic,and improves the user's dialogue experience.
基金supported by the National Key R&D programprogramme of China(Grant No.2023 YFC 3605002)Noncommunicable Chronic Disease National Science and Technology Major Project(Grant No.2023ZD0506001)+1 种基金the CAMS Innovation Fund for Medical Sciences(ClFMS)(Grant No.2025-I2M-KJ-029)the non-profit Central Research Institute Fund of Chinese Academy of Medical Sciences(Grant No.2022-ZHCH330-01).
文摘Introduction Task-shifting and task-sharing strategies show promise for managing chronic diseases especially in low-income and middle-income countries(LMICs),though their effectiveness in multimorbidity management remains unclear.This study synthesised evidence on task-shifting and task-sharing strategies globally and assessed the impact on core health outcomes in multimorbidity management.Methods We conducted a systematic review and meta-analysis of global studies evaluating task-shifting and sharing interventions for individuals with multimorbidity.Six databases,including PubMed,Embase,Web of Science,Ovid(Medline),CINAHL and Cochrane Library,were searched for studies reporting the core outcomes of multimorbidity management in quality of life,mortality,hospitalisation,emergency department visits and symptoms of depression and anxiety.Random-effects models were used to calculate pooled effect sizes with heterogeneity assessed through subgroup and meta-regression analyses.Results From 8471 records,36 studies from 14 countries were included,with only 5 conducted in LMICs.Twenty-one studies,encompassing 20989 participants,were eligible for meta-analysis.More than half of the studies involved nurses as delegates,with some sharing the tasks with health professionals and about 10%of studies involved non-health professionals,including community healthcare workers as delegates to share the responsibility in caring for individuals with multimorbidity.Most studies were multicomponent,with 16.7%addressing all guideline-recommended aspects of multimorbidity management.By pooling the findings,task-shifting and task-sharing interventions were associated with a 27%reduction in mortality(OR:0.73,95%CI:0.55 to 0.97,I2=0%),a modest improvement in quality of life(standardised mean difference(SMD):0.1,95%CI:0.03 to 0.17,I2=47%)and reduced symptoms of depression(SMD:0.27,95%CI:−0.52 to–0.02,I2=90%),but showed no significant effect on hospitalisation,emergency visits or anxiety-related symptoms.
基金supported by the National Natural Science Foundation of China(Grant Nos.12204412,12274423,12174402,12393821,and 12004124)the Strategic Priority Research Program of the Chinese Academy of Sciences(Grant Nos.XDB0920100 and XDB0920101)support from the Natural Sciences and Engineering Research Council of Canada.All calculations were performed on the APM-Theoretical Computing Cluster(APM-TCC).
文摘Standard perturbation theory is employed to calculate the mass shifts of the 2^(1)S_(0)-^(3)S_(1)and 2^(3)S_(1)-2^(3)P_(J)transitions for^(4,6,8)He.High-precision results are obtained for the mass shifts in the isotope pairs 6He-4He and 8He-4He,with uncertainties below 1 part per million(ppm).Our analysis provides a complete set of isotope-shift results and systematically examines their sensitivity to nuclear charge-radius differences.Once experimental measurements reach a precision comparable to that of the calculated mass shifts,the squared differences of nuclear charge radii can be determined with an accuracy of approximately 0.4%-0.6%,representing an order-of-magnitude improvement over current values.
基金supported by the National Natural Science Foundation of China(Nos.22004046 and 22074052)the Science and Technology Developing Foundation of Jilin Province of China(Nos.20240404044ZP,20230101033JC and 20220505015ZP).
文摘The aggressive nature and high mortality rate of lung cancer underscore the imperative need for early diagnosis of the disease.Thus,aminopeptidase N(APN),a potential biomarker for lung cancer,should be thoroughly investigated in this context.This report describes the development of HA-apn,a novel near-infrared fluorescent probe,specifically engineered for the sensitive detection of endogenous APN.Characterized by its high selectivity,straightforward molecular architecture,and suitable optical properties,including a long-wavelength emission at 835 nm and a large Stokes shift of 285 nm,HA-apn had high efficacy in identifying overexpressed APN in tumor cells,which shows its potential in pinpointing malignancies.To further validate its applicability and effectiveness in facilitating the direct and enhanced visualization of pulmonary alterations,an in situ lung cancer mouse model was employed.Notably,HAapn was applied for in vivo imaging of APN activity in the lung cancer mouse model receiving the probe through aerosol inhalation,and rapid and precise diagnostic results were achieved within 30min postadministration.Overall,HA-apn can be applied as an effective,non-intrusive tool for the rapid and accurate detection of pulmonary conditions.
基金Project supported by the Natural Science Foundation of Jilin Province of China(Grant No.20230101014JC)the National Natural Science Foundation of China(Grant No.12374265)。
文摘We investigate theoretically the effects of chirped laser pulses on high-order harmonic generation(HHG)from solids.We find that the harmonic spectra display redshifts for the driving laser pulses with negative chirp and blueshifts for those with positive chirp,which is due to the change in the instantaneous frequency of the driving laser for different chirped pulses.The analysis of crystal-momentum-resolved(k-resolved)HHG reveals that the frequency shifts are equal for the harmonics generated by different crystal momentum channels.The frequency shifts in the cutoff region are larger than those in the plateau region.With the increase of the absolute value of the chirp parameters,the frequency shifts of HHG become more significant,leading to the shifts from odd-to even-order harmonics.We also demonstrate that the frequency shifts of harmonic spectra are related to the duration of the chirped laser field,but are insensitive to the laser intensity and dephasing time.
基金supported by a key project of the National Natural Science Foundation of China[grant number 42192563]。
文摘Against the backdrop of climate change,the activity of tropical cyclones(TCs)has captured widespread attention.Observational datasets indicate a declining trend in the genesis longitude of western North Pacific(WNP)TCs.This study investigates the zonal changes of WNP TCs with CMIP6-HighResMIP models.These models capture the genesis density of WNP TCs fairly well.The results reveal a westward shift in TC genesis longitude.This trend is associated with the significant reduction in the TC frequency over the southeastern WNP.The study also discusses changes in large-scale circulation patterns and the impact of the strengthening Pacific Walker circulation.
基金The National Natural Science Foundation of China under contract No. 42274159the Project supported by Key Laboratory of Space Ocean Remote Sensing and Application,MNR under contract No.2023CFO016。
文摘The research on ocean dynamics information plays a crucial role in understanding ocean phenomena, assessing marine environmental impacts, and guiding engineering designs. The Doppler information observed by radars reflects sea surface dynamics, to which ocean waves make important contributions. Low-incidence-angle real aperture radar(RAR)demonstrates great potential for independently observing vectorial Doppler information on the ocean surface. To systematically characterize and accurately estimate the wave-induced Doppler frequency shift(WVF) from lowincidence-angle RAR, this study conducts comprehensive influencing factor analysis and establishes sea-stateparameterized WVF models. First, a simulated WVF dataset is generated under a rotating low-incidence-angle RAR.The feature parameters of WVF are then determined by analysing contributing factors including wind waves, swells,and sea state parameters. Furthermore, two WVF models(WVF_Ku P9 with 9 inputs and WVF_Ku P4 with 4 inputs) are constructed by the Transformer encoder for different application scenarios. Both models achieve high accuracy for WVF estimation with root mean square errors(RMSE) of 1.874 Hz and 2.716 Hz, respectively. The reliability and superiority of the proposed models are validated through comparisons with the Ka DOP, which is a typical geophysical model function(GMF). The findings in this paper advance the understanding of WVF characteristics and generation mechanisms. The proposed estimation models can provide reliable estimates, offering critical references for lowincidence-angle RAR applications such as ocean surface current retrieval.
