A new conceptual water-gas-shift(WGS) process is designed for integrated gasification combined cycle(IGCC), using membrane reactor(MR) equipped with H2-permselective zeolite membranes for the WGS reaction.The new proc...A new conceptual water-gas-shift(WGS) process is designed for integrated gasification combined cycle(IGCC), using membrane reactor(MR) equipped with H2-permselective zeolite membranes for the WGS reaction.The new process makes it possible to capture CO2 before power generation process by converting CO in the syngas to CO2 which can be collected after WGS reaction. The new process also produces purer H2 for combustion in gas turbine. Conceptual design of the MR, mass and heat balance analysis, and cost estimation of the new process are also provided in this paper.展开更多
The effect of COD/N ratio on the granulation process and microbial population succession was investigated.Four identical sequencing batch reactors,R1,R2,R3 and R4,were operated with various initial COD/N ratios rangin...The effect of COD/N ratio on the granulation process and microbial population succession was investigated.Four identical sequencing batch reactors,R1,R2,R3 and R4,were operated with various initial COD/N ratios ranging from 0/200 to 800/200（m/m）.Ethanol was fed as the source of COD.Aerobic granules were successfully cultivated in R2 and R3,operating with the COD/N ratio of 200/200 and 400/200,respectively.Scanning electron microscope observations indicated that short rod-shaped and spherical bacteria were dominant in R2,while granules produced in R3 were surrounded with a large amount of filamentous bacteria.The average specific nitritation rate in R2 and R3 were 0.019 and 0.008 mg N/（mg MLVSS.hr）,respectively.Fluorescence in situ hybridization results demonstrated that nitrifying bacteria population was enriched remarkably in R2.It indicated that nitrification ability and nitrifying bacteria population were enriched remarkably at low COD/N ratio.However,no granules were formed in R1 and R4 which might attribute to either limited or excessive extracellular polymeric substances production.This study contributed to a better understanding of the role of COD/N ratio in nitrifying sludge granulation.展开更多
文摘A new conceptual water-gas-shift(WGS) process is designed for integrated gasification combined cycle(IGCC), using membrane reactor(MR) equipped with H2-permselective zeolite membranes for the WGS reaction.The new process makes it possible to capture CO2 before power generation process by converting CO in the syngas to CO2 which can be collected after WGS reaction. The new process also produces purer H2 for combustion in gas turbine. Conceptual design of the MR, mass and heat balance analysis, and cost estimation of the new process are also provided in this paper.
基金supported by the National Key Technologies R&D Program of China during the Eleventh Five-year Plan Period (No. 2009BAC57B01)the State Key Laboratory of Urban Water Resource and Environment(HIT) (No. QAK201006)
文摘The effect of COD/N ratio on the granulation process and microbial population succession was investigated.Four identical sequencing batch reactors,R1,R2,R3 and R4,were operated with various initial COD/N ratios ranging from 0/200 to 800/200（m/m）.Ethanol was fed as the source of COD.Aerobic granules were successfully cultivated in R2 and R3,operating with the COD/N ratio of 200/200 and 400/200,respectively.Scanning electron microscope observations indicated that short rod-shaped and spherical bacteria were dominant in R2,while granules produced in R3 were surrounded with a large amount of filamentous bacteria.The average specific nitritation rate in R2 and R3 were 0.019 and 0.008 mg N/（mg MLVSS.hr）,respectively.Fluorescence in situ hybridization results demonstrated that nitrifying bacteria population was enriched remarkably in R2.It indicated that nitrification ability and nitrifying bacteria population were enriched remarkably at low COD/N ratio.However,no granules were formed in R1 and R4 which might attribute to either limited or excessive extracellular polymeric substances production.This study contributed to a better understanding of the role of COD/N ratio in nitrifying sludge granulation.
