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Three Shifts That Will Redefine Health Systems
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作者 You Wu Haibo Wang Zongjiu Zhang 《Health Care Science》 2026年第1期1-3,共3页
Academic journals,consulting firms,and mainstream media have often published“predictions”about the future develop-ment of medical and health care.These publications often emphasize the potential of cutting-edge scie... Academic journals,consulting firms,and mainstream media have often published“predictions”about the future develop-ment of medical and health care.These publications often emphasize the potential of cutting-edge scientific or technical breakthroughs.Health Care Science looks at the problem from another perspective.We focus on how these changes enter the health system,how they operate in the real world,and how they reshape the organization and governance of medical services.At the beginning of 2026,we envision the following three major shifts that will reshape healthcare. 展开更多
关键词 academic journals health systems health care science mainstream media shiftS cutting edge scientific technical breakthroughs consulting firms
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Hybrid-field channel estimation with phase shift in XL-MIMO systems
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作者 JIN Yong XI Bin +1 位作者 YAN Jiayuan HU Zhentao 《High Technology Letters》 2025年第4期321-328,共8页
Extremely large-scale massive multiple input multiple output(XL-MIMO)is a key enabling technology for future 6th generation mobile communication technology(6G)networks.However,due to challenges such as hardware impair... Extremely large-scale massive multiple input multiple output(XL-MIMO)is a key enabling technology for future 6th generation mobile communication technology(6G)networks.However,due to challenges such as hardware impairments and multipath effects,the existing channel estimation methods can not effectively deal with the phase shift issues in XL-MIMO communication systems.In this paper,a partially coherent hybrid-field channel model is proposed to effectively account for the phase shift encountered in the received signals.Based on this model,the partially coherent hybrid-field compressive phase retrieval(PCHF-CPR)algorithm is constructed to address random phase shift during hybrid-field channel estimation.Unlike traditional coherent and non-coherent estimation methods,our approach,not requiring precise phase information,can effectively address the phase shift issues in XL-MIMO communication systems.Simulation results are given to validate the effectiveness of the proposed method and its superiority over existing techniques. 展开更多
关键词 extremely large-scale massive multiple input multiple output hybrid-field channel estimation phase shift
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Decadal shift in Northeast China’s precipitation around 2000
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作者 Yawen Liao Tianbao Zhao +1 位作者 Jingpeng Zhang Yankun Sun 《Atmospheric and Oceanic Science Letters》 2026年第1期14-21,共8页
Northeast China(NEC),a critical agricultural and ecological zone,has experienced intensified hydrological variability under global warming,with cascading impacts on food security and ecosystem resilience.This study ut... Northeast China(NEC),a critical agricultural and ecological zone,has experienced intensified hydrological variability under global warming,with cascading impacts on food security and ecosystem resilience.This study utilized observational data and two new generation reanalysis products(i.e.,the fifth major global reanalysis produced by ECMWF(ERA5)and the Japanese Reanalysis for Three Quarters of a Century(JRA-3Q))to investigate the shift changes in precipitation in NEC around 2000 and associated water vapor transport.The analysis identified a pivotal interdecadal shift in 1998/99,transitioning from moderate increases(17.5 mm/10 yr during 1980-1998)to accelerated but more variable precipitation growth(85.4 mm/10 yr post-1999).While the mean precipitation during the post-shift period decreased,enhanced anticyclonic circulation amplified moisture divergence over continental NEC,redirecting vapor flux toward coastal regions.Crucially,trajectory analysis demonstrated regime-dependent moisture sourcing:midlatitude westerlies dominated during wet extremes(44% of trajectories in 1998),whereas East Asian monsoon flows prevailed in drought years(36% of trajectories in 2007).The post-1998 period exhibited increased reliance on localized recycling(45%of mid-tropospheric trajectories),reflecting weakened monsoonal inflow.These findings highlight NEC’s growing vulnerability to competing moisture pathways and atmospheric blocking-a dual mechanism that explains rising extremes despite declining mean precipitation.By reconciling dataset discrepancies(ERA5 vs.JRA-3Q trends)and elucidating circulation-precipitation linkages,this work provides actionable insights for climate-resilient agriculture in NEC’s water-stressed ecosystems. 展开更多
关键词 PRECIPITATION Decadal shift Water vapor transport Northeast China
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Multi-Time Scale Optimization Scheduling of Data Center Considering Workload Shift and Refrigeration Regulation
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作者 Luyao Liu Xiao Liao +1 位作者 Yiqian Li Shaofeng Zhang 《Energy Engineering》 2026年第2期451-486,共36页
Data center industries have been facing huge energy challenges due to escalating power consumption and associated carbon emissions.In the context of carbon neutrality,the integration of data centers with renewable ene... Data center industries have been facing huge energy challenges due to escalating power consumption and associated carbon emissions.In the context of carbon neutrality,the integration of data centers with renewable energy has become a prevailing trend.To advance the renewable energy integration in data centers,it is imperative to thoroughly explore the data centers’operational flexibility.Computing workloads and refrigeration systems are recognized as two promising flexible resources for power regulationwithin data centermicro-grids.This paper identifies and categorizes delay-tolerant computing workloads into three types(long-running non-interruptible,long-running interruptible,and short-running)and develops mathematical time-shifting models for each.Additionally,this paper examines the thermal dynamics of the computer room and derives a time-varying temperature model coupled to refrigeration power.Building on these models,this paper proposes a two-stage,multi-time scale optimization scheduling framework that jointly coordinates computing workloads time-shift in day-ahead scheduling and refrigeration power control in intra-day dispatch to mitigate renewable variability.A case study demonstrates that the framework effectively enhances the renewable-energy utilization,improves the operational economy of the data center microgrid,and mitigates the impact of renewable power uncertainty.The results highlight the potential of coordinated computing workloads and thermal system flexibility to support greener,more cost-effective data center operation. 展开更多
关键词 Data center renewable energy load shift multi-time scale optimization
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Multi-dynamic torque coordination control strategy for a power-split hybrid electric vehicle during mode shift
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作者 Kun Huang Weida Wang +2 位作者 Jiankang Cheng Chao Yang Changle Xiang 《Chinese Journal of Mechanical Engineering》 2026年第1期486-495,共10页
Mode shift is a special mechanism for a power-split hybrid electric vehicle(HEV)to realise electrically variable transmission,but the sudden change of equivalent inertia caused by topological configuration recombinati... Mode shift is a special mechanism for a power-split hybrid electric vehicle(HEV)to realise electrically variable transmission,but the sudden change of equivalent inertia caused by topological configuration recombination during mode shift induces a significant torque shock.Therefore,a smooth transient process,among other concerns,typically associated with this category of vehicles,is of great importance.The present research aims to introduce a novel control strategy to manage the dynamic torque of multiple power sources and therefore im-prove ride comfort.To this end,a dynamic model of the objective power-split HEV is first built.To resolve the contention between vehicle jerk and clutch friction loss,a model predictive control(MPC)combined with control allocation(CA)is then designed for the clutch-engaged phase.To reduce the torque fluctuation caused by the inertia torques of multiple power sources,a dynamic compensation control strategy(DCcs)that coordinates motorgenerator torque to compensate for the transition torque is proposed for the brake-disengaged phase.Finally,the proposed control strategy is validated by simulation and bench test,and results show great potential in reducing shift duration,torque variation,vehicle jerk and friction loss(the simulation results show decreases of 22%,39%,83%and 53%,and the experimental results show decreases of 21%,74%,77%,and 59%,re-spectively),thereby improving shift quality. 展开更多
关键词 Power-split hybrid electric vehicle Mode shift Model predictive control Control allocation Dynamic compensation control
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结合局部差分的CamShift动目标跟踪算法 被引量:5
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作者 周帅 秦明伟 侯宝临 《自动化仪表》 CAS 2017年第2期1-4,共4页
Cam Shift算法具有计算量小、对目标形变适应能力强、执行效率高等优点,其在图像处理领域具有重要地位。但仅采用颜色直方图作为目标特征,忽略目标位置信息,会造成该算法在目标形态调整的过程中容易将颜色相似的背景纳入跟踪目标,从而... Cam Shift算法具有计算量小、对目标形变适应能力强、执行效率高等优点,其在图像处理领域具有重要地位。但仅采用颜色直方图作为目标特征,忽略目标位置信息,会造成该算法在目标形态调整的过程中容易将颜色相似的背景纳入跟踪目标,从而发散甚至跟踪漂移。针对这一现象,提出了一种结合局部差分的Cam Shift跟踪算法,以进一步改善该算法的实际应用效果。改进后的算法首先结合Mean Shift迭代结果和扩展后统计区域的背景差分结果,综合判断移动物体的中心位置、长度、宽度等信息;然后通过此信息对运动目标形态变化的调整进行约束,使调整后的范围更加符合实际情况。试验结果显示,改进后的算法能够在复杂背景下准确地锁定跟踪目标,证明了结合局部背景差分技术的Cam Shift算法可以在增加较少计算量的情况下排除相似颜色的干扰,减少了跟踪过程中出现的不稳定现象,提高了算法的准确性和鲁棒性。 展开更多
关键词 图像处理 CAM shift算法 目标跟踪 漂移 鲁棒性 自适应 嵌入式系统
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CAMSHIFT与基于核的目标跟踪算法的比较与分析 被引量:3
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作者 宁纪锋 姜光 吴成柯 《计算机工程与应用》 CSCD 北大核心 2009年第28期177-179,共3页
CAMSHIFT和基于核的目标跟踪是两种经典的基于Mean Shift的目标跟踪算法,它们的实现过程有许多类似之处。为了说明在实际应用中如何选择合理的跟踪方案,从目标模型、候选模型、核函数、迭代过程等方面对二者进行了深入的比较和分析,指... CAMSHIFT和基于核的目标跟踪是两种经典的基于Mean Shift的目标跟踪算法,它们的实现过程有许多类似之处。为了说明在实际应用中如何选择合理的跟踪方案,从目标模型、候选模型、核函数、迭代过程等方面对二者进行了深入的比较和分析,指出了二者的特点和区别,对于正确理解和使用这两种方法将会有一定的帮助。 展开更多
关键词 Mean shift 连续自适应均值移动跟踪算法(CAMshift) 基于核的目标跟踪 权值图像
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结合mean-shift与MST的K-means聚类算法 被引量:5
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作者 徐沁 罗斌 《计算机工程》 CAS CSCD 2013年第12期204-210,共7页
针对初始点选择不当导致K-means陷入局部最小值问题,提出一种结合自适应mean-shift与最小生成树(MST)的K-means聚类算法。将数据对象投影到主成分分析(PCA)子空间,给出自适应mean-shift算法,并在PCA子空间内将数据向密度大的区域聚集,... 针对初始点选择不当导致K-means陷入局部最小值问题,提出一种结合自适应mean-shift与最小生成树(MST)的K-means聚类算法。将数据对象投影到主成分分析(PCA)子空间,给出自适应mean-shift算法,并在PCA子空间内将数据向密度大的区域聚集,再利用MST与图连通分量算法,找出数据的类别数和类标签,据此计算原始空间的密度峰值,并将其作为K-means聚类的初始中心点。对K-means的目标函数、聚类精度和运行时间进行比较,结果表明,该算法在较短的运行时间内能给出较优的全局解。 展开更多
关键词 聚类分析 K—means算法 初始中心点 Mean—shift算法 主成分分析 最小生成树
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基于Mean Shift算法的Camshift跟踪技术研究
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作者 徐磊 《价值工程》 2015年第29期202-204,共3页
计算机算法是目标跟踪技术的核心部分,直接决定目标跟踪的精确性与稳定性。文章将研究基于Mean Shift算法的Camshift算法,并将仿真实验的结果进行比较,找到该算法在跟踪技术领域里的优缺点。
关键词 计算机视觉 目标跟踪 Mean shift算法 CAMshift算法
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Adaptive compensating method for Doppler frequency shift using LMS and phase estimation 被引量:7
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作者 Jing Qingfeng Guo Qing 《Journal of Systems Engineering and Electronics》 SCIE EI CSCD 2009年第5期913-919,共7页
The novel compensating method directly demodulates the signals without the carrier recovery processes, in which the carrier with original modulation frequency is used as the local coherent carrier. In this way, the ph... The novel compensating method directly demodulates the signals without the carrier recovery processes, in which the carrier with original modulation frequency is used as the local coherent carrier. In this way, the phase offsets due to frequency shift are linear. Based on this premise, the compensation processes are: firstly, the phase offsets between the baseband neighbor-symbols after clock recovery is unbiasedly estimated among the reference symbols; then, the receiving signals symbols are adjusted by the phase estimation value; finally, the phase offsets after adjusting are compensated by the least mean squares (LMS) algorithm. In order to express the compensation processes and ability clearly, the quadrature phase shift keying (QPSK) modulation signals are regarded as examples for Matlab simulation. BER simulations are carried out using the Monte-Carlo method. The learning curves are obtained to study the algorithm's convergence ability. The constellation figures are also simulated to observe the compensation results directly. 展开更多
关键词 Doppler frequency shift least mean square minimum phase shift keying unbiased estimation Matlab simulation.
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Relative Chemical Shifts for Obtaining Accurate Chemical Shifts of Hydrogen Atoms in CH Groups
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作者 张荣一 李俊 吴文娟 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2014年第2期240-242,I0004,共4页
Accurate chemical shifts of hydrogen atoms in CH groups are difficult to obtain. To solve this problem, relative chemical shifts are introduced. Internal and external standard methods were used to measure the chemical... Accurate chemical shifts of hydrogen atoms in CH groups are difficult to obtain. To solve this problem, relative chemical shifts are introduced. Internal and external standard methods were used to measure the chemical shifts in a whole-concentration of N-methylacetamide- water system. Determination of the chemical shifts of hydrogen atoms, especially those of CH groups, according to the two methods yielded significant differences. Relative chemical shifts were proven to be independent of the reference and may be applied to other systems. 展开更多
关键词 Relative chemical shift CH group Internal and external method
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LMSF Mean Shift目标跟踪算法
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作者 李波 袁保宗 《信号处理》 CSCD 北大核心 2005年第z1期335-338,共4页
Mean shift作为一种有效的目标跟踪算法近年来得到了广泛的应用,但如何有效地更新核函数直方图模型仍是一个需要解决的问题.本文针对mean shift跟踪算法中模型更新问题,提出了一种新的模型更新策略.对mean shift中目标模型核函数直方图... Mean shift作为一种有效的目标跟踪算法近年来得到了广泛的应用,但如何有效地更新核函数直方图模型仍是一个需要解决的问题.本文针对mean shift跟踪算法中模型更新问题,提出了一种新的模型更新策略.对mean shift中目标模型核函数直方图的分量进行自适应LMS滤波(LMS Filter),并且动态更新目标模型的核函数直方图分量,即解决了目标模型更新过快引起的过更新问题,同时核直方图模型又可以及时反映当前目标的颜色、外观变化.本方法通过实验证明取得了较好的跟踪效果. 展开更多
关键词 目标跟踪 mean shift 核直方图 模型更新 Lms滤波
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Effects of shifting time on pressure impact in hydraulic systems 被引量:5
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作者 ZHU Zhen-cai CHEN Guo-an 《Journal of Central South University of Technology》 2005年第z1期217-221,共5页
The limitations in existing measures for absorbing pressure impact in hydraulic systems were summarized in this paper. Based on the forming principle of the oil in a hydrostatic closed pressure chamber, the underlying... The limitations in existing measures for absorbing pressure impact in hydraulic systems were summarized in this paper. Based on the forming principle of the oil in a hydrostatic closed pressure chamber, the underlying reasons of the pressure impact were analyzed theoretically, the intrinsic laws that the extent of the pressure impact in hydraulic oil lines are affected by some factors, such as oil elastic modulus, oil line's geometrical volume, and changing rate of oil volume versus time etc, were discussed. Experimental investigations into pressure impact in all pressure chambers because of shifting were conducted under different working conditions by employing a special experimental system. The effects of shifting time on pressure impact were studied. A new concept with universal meaning, i.e. optimal shifting time, and its characterizing parameter and the methods of shifting at optimal shifting time were also proposed. The results show that shifting time lag △t is of rationality and maneuverablility. The higher the working pressure, the shorter the shifting time. 展开更多
关键词 HYDRAULIC system shiftING TIME PRESSURE impact EXPERIMENT LAW
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Food Security of Shifting Cultivation Systems: Case Studies from Luang Prabang and Oudomxay Provinces, Lao PDR 被引量:3
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作者 Linkham Douangsavanh Anan Polthanee Roengsak Katawatin 《Journal of Mountain Science》 SCIE CSCD 2006年第1期48-57,共10页
The Government of the Lao PDR’s policy is to eliminate the cultivation of upland rice by means of ‘slash-and-burn’ cultivation and to replace it with more ecologically stable systems based on sustainable land use a... The Government of the Lao PDR’s policy is to eliminate the cultivation of upland rice by means of ‘slash-and-burn’ cultivation and to replace it with more ecologically stable systems based on sustainable land use at the village and household level. The objectives of this policy are to alleviate poverty and to introduce more sustainable management of agricultural resources. In order to achieve these objectives, the government has initiated a program of relocation to upland ‘focal areas’ from which marketing, distribution and other services can be supplied, these being essential preconditions for effective agricultural development in these regions. This diagnostic study has examined communal and household strategies for addressing food security issues, and has highlighted the main problems encountered in the pursuit of food security on the local level. The specific objective was to conduct a broadly focused participatory problem diagnosis of the study areas in two districts Phonsay and Namo, in order to understand farmers’ problems, livelihood goals and how their perspectives on food security have changed, and to investigate food security in shifting cultivation systems in Luang Prabang andOudomxay provinces. Within these two provinces Phonsay and Namo districts were selected as the research areas. The two districts are the poorest districts in the Luang Prabang and Oudomxay provinces and two of ten priority poorest districts in the whole country. Semi-structured interviews were conducted for the study. The results of this study were reviewed against the sustainable land use systems strategy formulated from the Lao PDR policy. The study highlights both the benefits and stresses on household welfare, food insecurity conditions in the study areas, and interrelated problems of insufficient rice for household consumption. Finally based on these results the authors propose recommendations and future research indications. 展开更多
关键词 shifting cultivation food security RICE sustainable land management Lao PDR
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Effect of external magnetic field on the shift of resonant frequency in photoassociation of ultracold Cs atoms 被引量:2
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作者 Pengwei Li Yuqing Li +4 位作者 Guosheng Feng Jizhou Wu Jie Ma Liantuan Xiao Suotang Jia 《Chinese Physics B》 SCIE EI CAS CSCD 2019年第1期367-371,共5页
We study the influence of external magnetic field on the shift of the resonant frequency in the photoassociation of ultracold Cs atoms, which are captured in a magnetically levitated optical crossed dipole trap. With ... We study the influence of external magnetic field on the shift of the resonant frequency in the photoassociation of ultracold Cs atoms, which are captured in a magnetically levitated optical crossed dipole trap. With the increase of the photoassociation laser intensity, the linear variation of the frequency shift is measured by recording the photoassociation spectra of the long-range 0_u^+ state of Cs molecule below the 6S_(1/2)+ 6P_(1/2) dissociation limit at different magnetic fields.The slope of the frequency shift to the intensity of the photoassociation laser exhibits a strong dependence on the external magnetic field. The experimental data is simulated with an analytic theory model, in which a single channel rectangular potential with the tunable well depth is introduced to acquire the influence of the magnetic field on the atomic behavior in the effective range where photoassociation occurs. 展开更多
关键词 ULTRACOLD MOLECULE PHOTOASSOCIATION FREQUENCY shift
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Effect of strain-gradients of surface micro-beams on frequency-shift of a quartz crystal resonator under thickness-shear vibrations 被引量:2
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作者 Ling-Cheng Kong Yuan-Tai Hu 《Acta Mechanica Sinica》 SCIE EI CAS CSCD 2015年第5期647-652,共6页
With introduction of the first-order strain-gradient of surface micro-beams into the energy density function,we developed a two-dimensional dynamic model for a compound quartz crystal resonator(QCR) system,consistin... With introduction of the first-order strain-gradient of surface micro-beams into the energy density function,we developed a two-dimensional dynamic model for a compound quartz crystal resonator(QCR) system,consisting of a QCR and surface micro-beam arrays.The frequency shift that was induced by micro-beams with consideration of strain-gradients is discussed in detail and some useful results are obtained,which have important significance in resonator design and applications. 展开更多
关键词 Micro-beams Strain-gradient Quartz crystal resonator Frequency shift
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Laser Cooling and Deceleration of Neutral Atoms by Red-Shifted Diffuse Light 被引量:2
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作者 CHEN Hongxin CAI Weiquan +3 位作者 LIU Liang SHU Wei LI Fosheng WANG Yuzhu 《Chinese Physics Letters》 SCIE CAS CSCD 1994年第9期541-544,共4页
We report a cooling and deceleration experiment of a thermal beam by using a nearly resonant red-shifted diffuse light in an optical integral sphere cavity.By using of this red-shifted diffuse light,the velocity of a ... We report a cooling and deceleration experiment of a thermal beam by using a nearly resonant red-shifted diffuse light in an optical integral sphere cavity.By using of this red-shifted diffuse light,the velocity of a part of thermal sodium atoms is cooled to 380m/s and the velocity width of cooled atoms is about 18m/s.The mechanism of this kind of laser cooling and the experimental results are discussed. 展开更多
关键词 cavity. shifted THERMAL
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Effects of shifting cultivation on biological and biochemical characteristics of soil microorganisms in Khagrachari hill district, Bangladesh 被引量:2
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作者 Sohag Miah S.M. Sirajul Haque +1 位作者 Wahida Sumi Mohammad Mosharraf Hossain 《Journal of Forestry Research》 SCIE CAS CSCD 2014年第3期689-694,共6页
We collected soil samples from two representative sites at Aatmile of Khagarachari hill district in Chittagong Hill Tracts. One of the sites was under shifting cultivation and the other an adjacent 13-year old teak pl... We collected soil samples from two representative sites at Aatmile of Khagarachari hill district in Chittagong Hill Tracts. One of the sites was under shifting cultivation and the other an adjacent 13-year old teak plantation. Both sites were in the same physiographic condition and same aspect with parable soil type, which enabled us to measure the effects of shifting cultivation on soil micro-flora. We studied soil phys-ico-chemical properties and the biochemical and biological properties of soil microbes. Moisture and organic matter content as well as fungi and bacterial populations, both in surface and subsurface soils, were signifi-cantly (p≤0.001) lower in shifting cultivated soils compared to soils not under shifting cultivation, i.e. the teak plantation site. The most abundant bacteria in surface (0-10 cm) and sub-surface (10-20 cm) soils under shifting cultivation were Pseudomonas diminuta and Shigella, respec-tively, while in corresponding soil layers of teak plantation, predominant microbes were Bacillus firmus (0-10 cm) and Xanthomonas (10-20 cm). The microbial population differences cannot be explained by soil texture differences because of the textural similarity in soils from the two sites but could be related to the significantly lower moisture and organic mat-ter contents in soils under shifting cultivation. 展开更多
关键词 shifting cultivation soil biological properties soil biochemical properties soil microflora Chittagong Hill Tracts
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Shift of the principal mode of Pan-Asian monsoon summer precipitation in terms of spatial pattern 被引量:2
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作者 GAO Ya 《Atmospheric and Oceanic Science Letters》 CSCD 2017年第3期221-227,共7页
This paper documents that the principal mode of Pan-Asian monsoon summer precipitation experienced a prominent interdecadal shift around 1992/1993 in terms of spatial pattern and major driving factors. During 1979-19... This paper documents that the principal mode of Pan-Asian monsoon summer precipitation experienced a prominent interdecadal shift around 1992/1993 in terms of spatial pattern and major driving factors. During 1979-1992 (Period 1, P1), Pan-Asian monsoon summer precipitation anomalies mainly display a meridional dipole pattern from north to south, whereas in the period 1993-2016 (Period 2, P2), it shows a meridional tripole pattern instead. The summer precipitation in P1 is primarily associated with a combination of the developing phase (central-eastern Pacific type) and decaying phase (eastern Pacific type) of El Nino-Southem Oscillation (ENSO); while in P2, it is mainly associated with the decaying phase of central-eastern-Pacific-type ENSO. 展开更多
关键词 Pan-Asian monsoon summer precipitation interdecadal shift ENSO phase Maritime Continent SST
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Simulation of ^(13)C NMR chemical shifts of carbinol carbon atoms using quantitative structure-spectrum relationships 被引量:2
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作者 戴益民 黄可龙 +3 位作者 李浔 曹忠 朱志平 杨道武 《Journal of Central South University》 SCIE EI CAS 2011年第2期323-330,共8页
A quantitative structure-spectrum relationship (QSSR) model was developed to simulate 13C nuclear magnetic resonance (NMR) spectra of carbinol carbon atoms for 55 alcohols. The proposed model,using multiple linear reg... A quantitative structure-spectrum relationship (QSSR) model was developed to simulate 13C nuclear magnetic resonance (NMR) spectra of carbinol carbon atoms for 55 alcohols. The proposed model,using multiple linear regression,contained four descriptors solely extracted from the molecular structure of compounds. The statistical results of the final model show that R2= 0.982 4 and S=0.869 8 (where R is the correlation coefficient and S is the standard deviation). To test its predictive ability,the model was further used to predict the 13C NMR spectra of the carbinol carbon atoms of other nine compounds which were not included in the developed model. The average relative errors are 0.94% and 1.70%,respectively,for the training set and the predictive set. The model is statistically significant and shows good stability for data variation as tested by the leave-one-out (LOO) cross-validation. The comparison with other approaches also reveals good performance of this method. 展开更多
关键词 carbinol carbon atom ^13C nuclear magnetic resonance chemical shift topological indices quantitative structure-spectroscopy relationship
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