This study identified castor oil and phosphate ester as effective retarders through setting time,tensile,and flexural tests,and determined their optimal dosages.The mechanism by which phosphate ester affects the setti...This study identified castor oil and phosphate ester as effective retarders through setting time,tensile,and flexural tests,and determined their optimal dosages.The mechanism by which phosphate ester affects the setting time of polyurethane was further investigated using molecular dynamics simulations.Fourier transform infrared spectroscopy was also employed to systematically study the physical and chemical interactions between phosphate esters and polyurethane materials.The results demonstrate that a 1%concentration of phosphate ester provides the most effective retarding effect with minimal impact on the strength of polyurethane.When phosphate ester is added to the B component of the two-component polyurethane system,its interaction energy with component A decreases,as do the diffusion coefficient and aggregation degree of component B on the surface of component A.This reduction in interaction slows the setting time.Additionally,the addition of phosphate ester to polyurethane leads to the disappearance or weakening of functional groups,indicating competitive interactions within the phosphate ester components that inhibit the reaction rate.展开更多
The bio-clogging using bacteria can be an eco-friendly and sustainable alternative to conventional grouting methods for seepage control.However,it remains unclear to date how the dilute concentration of bacterium and ...The bio-clogging using bacteria can be an eco-friendly and sustainable alternative to conventional grouting methods for seepage control.However,it remains unclear to date how the dilute concentration of bacterium and medium during field installation can affect the setting time of bacterium and its correlation with permeability reduction.In this study,the setting time of bacterium and its effectiveness in permeability reduction were addressed through experimental and theoretical investigations.A series of sand column was cultivated using different concentrations of Leuconostoc mesenteroides and culture medium.The distribution and composition of the bacterial product(i.e.dextran)were observed by refractometer,scanning electron microscope(SEM),and energy dispersive X-ray spectroscopy(EDS).Soil permeability was recorded using a constant head test.The results revealed that bacterium was effective to produce dextran at the setting time of about 5 d after installation.This dextran can reduce the permeability of bio-mediated soil by two orders of magnitude,even without culture medium supply.In general,the dextran production decreased proportionally with increase of bacterium and medium concentration.However,at 50%bacterium and medium concentration by weight,it still has a significant influence on permeability reduction with similar setting time,compared to 100%concentration.展开更多
In order to veritably measure the first peak of hydration heat evolution that has been illustrated important in indicating cement behavior in early hydration, an improved way of water addition into cement in isotherma...In order to veritably measure the first peak of hydration heat evolution that has been illustrated important in indicating cement behavior in early hydration, an improved way of water addition into cement in isothermally calorimetric experiment is put forward. The experimental results indicated that: the magnitude of first peak of heat evolution varies from sample to sample, correlation between heat evolution during first peak of heat evolution and initial (as well as final) setting time is unsatisfactory when samples are not classified; while groups of sample classified based on strength grade represent satisfactory correlations, which indicating the existence of close relation between hydration heat evolution in much earlier hydration age and setting property of cement in rather later age. Importance of first peak in hydration heat evolution for understanding cement setting property and reasons for sample classification are also discussed in this paper.展开更多
This paper discusses the problem of finite-time stability with respect to a closed, but not necessarily compact, invariant set for a class of nonlinear systems with discontinuous right-hand sides in the sense of the F...This paper discusses the problem of finite-time stability with respect to a closed, but not necessarily compact, invariant set for a class of nonlinear systems with discontinuous right-hand sides in the sense of the Filippov solutions. When the Lyapunov function is Lipschitz continuous and regular, the Lyapunov theorem on finite-time stability with respect to a closed invariant set is presented.展开更多
Plant aggregate-based building materials are a viable solution for reducing greenhouse gas emissions and providing good thermal and acoustic performances.In this study,the investigated lightweight mortars require a hy...Plant aggregate-based building materials are a viable solution for reducing greenhouse gas emissions and providing good thermal and acoustic performances.In this study,the investigated lightweight mortars require a hydraulic reaction.Laboratory and on-site empirical observations about plant aggregate-based materials indicate a delay in setting time and a decrease in the mechanical performances of concretes based on plant aggregates.The natural origin of plant-aggregates causes a lot of variability in their properties.Related studies have shown that the incompatibility between plant aggregates and cement is mainly caused by the dissolved and decomposed components of plant aggregates in alkaline environments.Currently,no research on the specific impact of each component on the setting time of lime-based binder exists.In this work,the impact of some soluble compounds(e.g.,sucrose,glucose,fructose,pectin)on the setting reaction of the lime matrix was studied using Vicat test,thermogravimetric analysis(TGA)and FT-IR spectroscopy.Experimental results showed that carbohydrates such as glucose and sucrose not only affect the setting time but also have a long-term impact on the carbonation of lime.The measure of the setting time by Vicat test appears as a possible indicator to predict the compatibility between the matrix and plant aggregates.展开更多
Occurrence of mafic dykes in Himalaya has been intriguing and debated since long because of its difficulty to ascent and emplacement through a thickened crust.Mafic dykes in Kumaun Lesser Himalaya(KLH)of central Indian
基金Funded by the National Natural Science Foundation of China(No.52370128)the Fundamental Research Funds for the Central Universities(No.2572022AW54)。
文摘This study identified castor oil and phosphate ester as effective retarders through setting time,tensile,and flexural tests,and determined their optimal dosages.The mechanism by which phosphate ester affects the setting time of polyurethane was further investigated using molecular dynamics simulations.Fourier transform infrared spectroscopy was also employed to systematically study the physical and chemical interactions between phosphate esters and polyurethane materials.The results demonstrate that a 1%concentration of phosphate ester provides the most effective retarding effect with minimal impact on the strength of polyurethane.When phosphate ester is added to the B component of the two-component polyurethane system,its interaction energy with component A decreases,as do the diffusion coefficient and aggregation degree of component B on the surface of component A.This reduction in interaction slows the setting time.Additionally,the addition of phosphate ester to polyurethane leads to the disappearance or weakening of functional groups,indicating competitive interactions within the phosphate ester components that inhibit the reaction rate.
基金This work is supported by King Mongkut’s Institute of Technology Ladkrabang(Grant No.2563-02-01-014).
文摘The bio-clogging using bacteria can be an eco-friendly and sustainable alternative to conventional grouting methods for seepage control.However,it remains unclear to date how the dilute concentration of bacterium and medium during field installation can affect the setting time of bacterium and its correlation with permeability reduction.In this study,the setting time of bacterium and its effectiveness in permeability reduction were addressed through experimental and theoretical investigations.A series of sand column was cultivated using different concentrations of Leuconostoc mesenteroides and culture medium.The distribution and composition of the bacterial product(i.e.dextran)were observed by refractometer,scanning electron microscope(SEM),and energy dispersive X-ray spectroscopy(EDS).Soil permeability was recorded using a constant head test.The results revealed that bacterium was effective to produce dextran at the setting time of about 5 d after installation.This dextran can reduce the permeability of bio-mediated soil by two orders of magnitude,even without culture medium supply.In general,the dextran production decreased proportionally with increase of bacterium and medium concentration.However,at 50%bacterium and medium concentration by weight,it still has a significant influence on permeability reduction with similar setting time,compared to 100%concentration.
基金Funded by Guangxi Science Foundation(No. 0639006)
文摘In order to veritably measure the first peak of hydration heat evolution that has been illustrated important in indicating cement behavior in early hydration, an improved way of water addition into cement in isothermally calorimetric experiment is put forward. The experimental results indicated that: the magnitude of first peak of heat evolution varies from sample to sample, correlation between heat evolution during first peak of heat evolution and initial (as well as final) setting time is unsatisfactory when samples are not classified; while groups of sample classified based on strength grade represent satisfactory correlations, which indicating the existence of close relation between hydration heat evolution in much earlier hydration age and setting property of cement in rather later age. Importance of first peak in hydration heat evolution for understanding cement setting property and reasons for sample classification are also discussed in this paper.
基金supported by the Mathematical Tianyuan Foundation (No. 10826078)the National Natural Science Foundation of China (No. 60874006)
文摘This paper discusses the problem of finite-time stability with respect to a closed, but not necessarily compact, invariant set for a class of nonlinear systems with discontinuous right-hand sides in the sense of the Filippov solutions. When the Lyapunov function is Lipschitz continuous and regular, the Lyapunov theorem on finite-time stability with respect to a closed invariant set is presented.
文摘Plant aggregate-based building materials are a viable solution for reducing greenhouse gas emissions and providing good thermal and acoustic performances.In this study,the investigated lightweight mortars require a hydraulic reaction.Laboratory and on-site empirical observations about plant aggregate-based materials indicate a delay in setting time and a decrease in the mechanical performances of concretes based on plant aggregates.The natural origin of plant-aggregates causes a lot of variability in their properties.Related studies have shown that the incompatibility between plant aggregates and cement is mainly caused by the dissolved and decomposed components of plant aggregates in alkaline environments.Currently,no research on the specific impact of each component on the setting time of lime-based binder exists.In this work,the impact of some soluble compounds(e.g.,sucrose,glucose,fructose,pectin)on the setting reaction of the lime matrix was studied using Vicat test,thermogravimetric analysis(TGA)and FT-IR spectroscopy.Experimental results showed that carbohydrates such as glucose and sucrose not only affect the setting time but also have a long-term impact on the carbonation of lime.The measure of the setting time by Vicat test appears as a possible indicator to predict the compatibility between the matrix and plant aggregates.
基金supported under a DST (ESS/16/290/2006) grant sanctioned to Santosh Kumar
文摘Occurrence of mafic dykes in Himalaya has been intriguing and debated since long because of its difficulty to ascent and emplacement through a thickened crust.Mafic dykes in Kumaun Lesser Himalaya(KLH)of central Indian
