Batch to batch temperature control of a semi-batch chemical reactor with heating/cooling system was discussed in this study. Without extensive modeling investigations, a two-dimensional(2D) general predictive iterativ...Batch to batch temperature control of a semi-batch chemical reactor with heating/cooling system was discussed in this study. Without extensive modeling investigations, a two-dimensional(2D) general predictive iterative learning control(2D-MGPILC) strategy based on the multi-model with time-varying weights was introduced for optimizing the tracking performance of desired temperature profile. This strategy was modeled based on an iterative learning control(ILC) algorithm for a 2D system and designed in the generalized predictive control(GPC) framework. Firstly, a multi-model structure with time-varying weights was developed to describe the complex operation of a general semi-batch reactor. Secondly, the 2 D-MGPILC algorithm was proposed to optimize simultaneously the dynamic performance along the time and batch axes. Finally, simulation for the controller design of a semi-batch reactor with multiple reactions was involved to demonstrate that the satisfactory performance could be achieved despite of the repetitive or non-repetitive disturbances.展开更多
We present a novel generating function(GF)method for the self-condensing vinyl polymerization(SCVP)system with any initial distribution of preexisted polymers.Such a method was proven to be especially useful to invest...We present a novel generating function(GF)method for the self-condensing vinyl polymerization(SCVP)system with any initial distribution of preexisted polymers.Such a method was proven to be especially useful to investigate the semi-batch SCVP system allowing a sequence of feeding operations during the polymerization.Consequently,the number-,weight-,and z-average molecular weights as well as dispersity index of hyperbranched polymers can be explicitly given,which are determined by predetermined feeding details and conversions in each polymerization step.These analytical results are further confirmed by the corresponding Monte Carlo simulations.Therefore,the present GF method has provided a unified treatment to the semi-batch SCVP system.Accordingly,hyperbranched polymers with desired properties can be prepared by designing feeding details and presetting conversions at each step based on the present GF method.展开更多
An optimal iterative learning control （ILC） strategy of improving endpoint products in semi-batch processes is presented by combining a neural network model. Control affine feed-forward neural network （CAFNN） is p...An optimal iterative learning control （ILC） strategy of improving endpoint products in semi-batch processes is presented by combining a neural network model. Control affine feed-forward neural network （CAFNN） is proposed to build a model of semi-batch process. The main advantage of CAFNN is to obtain analytically its gradient of endpoint products with respect to input. Therefore, an optimal ILC law with direct error feedback is obtained explicitly, and the convergence of tracking error can be analyzed theoretically. It has been proved that the tracking errors may converge to small values. The proposed modeling and control strategy is illustrated on a simulated isothermal semi-batch reactor, and the results show that the endpoint products can be improved gradually from batch to batch.展开更多
Semi-batch operated reaction processes are necessary for some competitive reaction systems to achieve a desirable process selectivity and productivity of fine chemical products.Herein the structural and operating para...Semi-batch operated reaction processes are necessary for some competitive reaction systems to achieve a desirable process selectivity and productivity of fine chemical products.Herein the structural and operating parameters of the teethed high shear mixers were adjusted to study the micromixing performance in the semi-batch operated system,using the Villermaux/Dushman reaction system.The results indicate that the rising of the rotor speed and the number of rotor teeth,the decrease of the width of the shear gap and the radial distance between the feed position and the inner wall of stator can enhance the micromixing level and lead to the decrease of the segregation index.Additionally,computational fluid dynamics calculations were carried out to disclose the evolution of the flow pattern and turbulent energy dissipation rate of the semi-batch operated high shear mixer.Furthermore,the correlation was established with a mean relative error of 8.05%and R^(2)of 0.955 to fit the segregation index and the parameters studied in this work,which can provide valuable guidance on the design and optimization of the semi-batch operated high shear mixers in practical applications.展开更多
The mixing-precipitation process for producing phenylpyruvic acid sodium salt(PPNa) by neutralization of phenylpyruic acid(PPA) with aqueous sodium hydroxide in a semi-batch stirred tank was studied.The effects of mix...The mixing-precipitation process for producing phenylpyruvic acid sodium salt(PPNa) by neutralization of phenylpyruic acid(PPA) with aqueous sodium hydroxide in a semi-batch stirred tank was studied.The effects of mixing characteristics and chemical characteristics on the precipitation process were investigated experimentally.It was found that the crystals growth rate and morphology obviously changed due to ripening.Crystal redissolution agglomeration and solvent inclusion also changed the purity of PPNa product considerably.展开更多
基金Projects(61673205,21727818,61503180)supported by the National Natural Science Foundation of ChinaProject(2017YFB0307304)supported by National Key R&D Program of ChinaProject(BK20141461)supported by the Natural Science Foundation of Jiangsu Province,China
文摘Batch to batch temperature control of a semi-batch chemical reactor with heating/cooling system was discussed in this study. Without extensive modeling investigations, a two-dimensional(2D) general predictive iterative learning control(2D-MGPILC) strategy based on the multi-model with time-varying weights was introduced for optimizing the tracking performance of desired temperature profile. This strategy was modeled based on an iterative learning control(ILC) algorithm for a 2D system and designed in the generalized predictive control(GPC) framework. Firstly, a multi-model structure with time-varying weights was developed to describe the complex operation of a general semi-batch reactor. Secondly, the 2 D-MGPILC algorithm was proposed to optimize simultaneously the dynamic performance along the time and batch axes. Finally, simulation for the controller design of a semi-batch reactor with multiple reactions was involved to demonstrate that the satisfactory performance could be achieved despite of the repetitive or non-repetitive disturbances.
基金financially supported by the Project for Talent Engineering of Hebei Province(No.A2016015001)the Project for Top Young Talent of Hebei Province and that for general colleges of Hebei Province(No.BJ2017017)。
文摘We present a novel generating function(GF)method for the self-condensing vinyl polymerization(SCVP)system with any initial distribution of preexisted polymers.Such a method was proven to be especially useful to investigate the semi-batch SCVP system allowing a sequence of feeding operations during the polymerization.Consequently,the number-,weight-,and z-average molecular weights as well as dispersity index of hyperbranched polymers can be explicitly given,which are determined by predetermined feeding details and conversions in each polymerization step.These analytical results are further confirmed by the corresponding Monte Carlo simulations.Therefore,the present GF method has provided a unified treatment to the semi-batch SCVP system.Accordingly,hyperbranched polymers with desired properties can be prepared by designing feeding details and presetting conversions at each step based on the present GF method.
基金Supported by the National Natural Science Foundation of China (Grant Nos. 60404012, 60874049)the National High-Tech Research & Development Program of China (Grant No. 2007AA041402)+1 种基金the New Star of Science and Technology of Beijing City (Grant No. 2006A62)the IBM China Research Lab 2008 UR-Program
文摘An optimal iterative learning control （ILC） strategy of improving endpoint products in semi-batch processes is presented by combining a neural network model. Control affine feed-forward neural network （CAFNN） is proposed to build a model of semi-batch process. The main advantage of CAFNN is to obtain analytically its gradient of endpoint products with respect to input. Therefore, an optimal ILC law with direct error feedback is obtained explicitly, and the convergence of tracking error can be analyzed theoretically. It has been proved that the tracking errors may converge to small values. The proposed modeling and control strategy is illustrated on a simulated isothermal semi-batch reactor, and the results show that the endpoint products can be improved gradually from batch to batch.
基金supported by the National Natural Science Foundation of China(Grant Nos.22090034,U20A20151,21776179)Chemistry and Chemical Engineering Guangdong Laboratory(Grant No.1922015).
文摘Semi-batch operated reaction processes are necessary for some competitive reaction systems to achieve a desirable process selectivity and productivity of fine chemical products.Herein the structural and operating parameters of the teethed high shear mixers were adjusted to study the micromixing performance in the semi-batch operated system,using the Villermaux/Dushman reaction system.The results indicate that the rising of the rotor speed and the number of rotor teeth,the decrease of the width of the shear gap and the radial distance between the feed position and the inner wall of stator can enhance the micromixing level and lead to the decrease of the segregation index.Additionally,computational fluid dynamics calculations were carried out to disclose the evolution of the flow pattern and turbulent energy dissipation rate of the semi-batch operated high shear mixer.Furthermore,the correlation was established with a mean relative error of 8.05%and R^(2)of 0.955 to fit the segregation index and the parameters studied in this work,which can provide valuable guidance on the design and optimization of the semi-batch operated high shear mixers in practical applications.
文摘The mixing-precipitation process for producing phenylpyruvic acid sodium salt(PPNa) by neutralization of phenylpyruic acid(PPA) with aqueous sodium hydroxide in a semi-batch stirred tank was studied.The effects of mixing characteristics and chemical characteristics on the precipitation process were investigated experimentally.It was found that the crystals growth rate and morphology obviously changed due to ripening.Crystal redissolution agglomeration and solvent inclusion also changed the purity of PPNa product considerably.
