Recently,the Standardization Administration of China issued Announcement No.1 of 2026,officially approving the establishment of the Subcommittee 1 on Nonwoven Material of National Technical Committee 606 on Technical ...Recently,the Standardization Administration of China issued Announcement No.1 of 2026,officially approving the establishment of the Subcommittee 1 on Nonwoven Material of National Technical Committee 606 on Technical Textiles of Standardization Administration of China(SAC/TC606/SC1)and the Subcommittee 2 on Filtration and Separation Textiles of National Technical Committee 606 on Technical Textiles of Standardization Administration of China(SAC/TC606/SC2).The formation of these two subcommittees marks a crucial step in the standardization development of China's industrial textiles sector in specialized fields.展开更多
Self-regulating heating and self-powered flexibility are pivotal for future wearable devices.However,the low energy-conversion rate of wearable devices at low temperatures limits their application in plateaus and othe...Self-regulating heating and self-powered flexibility are pivotal for future wearable devices.However,the low energy-conversion rate of wearable devices at low temperatures limits their application in plateaus and other environments.This study introduces an azopolymer with remarkable semicrystallinity and reversible photoinduced solid-liquid transition ability that is obtained through copolymerization of azoben-zene(Azo)monomers and styrene.A composite of one such copolymer with an Azo:styrene molar ratio of 9:1(copolymer is denoted as PAzo9:1-co-polystyrene(PS))and nylon fabrics(NFs)is prepared(composite is denoted as PAzo9:1-co-PS@NF).PAzo9:1-co-PS@NF exhibits hydrophobicity and high wear resistance.Moreover,it shows good responsiveness(0.624 s^(−1))during isomerization under solid ultraviolet(UV)light(365 nm)with an energy density of 70.6 kJ kg^(−1).In addition,the open-circuit voltage,short-circuit current and quantity values of PAzo9:1-co-PS@NF exhibit small variations in a temperature range of−20℃ to 25℃ and remain at 170 V,5 μA,and 62 nC,respectively.Notably,the involved NFs were cut and sewn into gloves to be worn on a human hand model.When the model was exposed to both UV radiation and friction,the temperature of the finger coated with PAzo9:1-co-PS was approximately 6.0°C higher than that of the other parts.Therefore,developing triboelectric nanogenerators based on the in situ photothermal cycles of Azo in wearable devices is important to develop low-temperature self-regulating heating and self-powered flexible devices for extreme environments.展开更多
Purpose:Interdisciplinary research has become a critical approach to addressing complex societal,economic,technological,and environmental challenges,driving innovation and integrating scientific knowledge.While interd...Purpose:Interdisciplinary research has become a critical approach to addressing complex societal,economic,technological,and environmental challenges,driving innovation and integrating scientific knowledge.While interdisciplinarity indicators are widely used to evaluate research performance,the impact of classification granularity on these assessments remains underexplored.Design/methodology/approach:This study investigates how different levels of classification granularity-macro,meso,and micro-affect the evaluation of interdisciplinarity in research institutes.Using a dataset of 262 institutes from four major German non-university organizations(FHG,HGF,MPG,WGL)from 2018 to 2022,we examine inconsistencies in interdisciplinarity across levels,analyze ranking changes,and explore the influence of institutional fields and research focus(applied vs.basic).Findings:Our findings reveal significant inconsistencies in interdisciplinarity across classification levels,with rankings varying substantially.Notably,the Fraunhofer Society(FHG),which performs well at the macro level,experiences significant ranking declines at meso and micro levels.Normalizing interdisciplinarity by research field confirmed that these declines persist.The research focus of institutes,whether applied,basic,or mixed,does not significantly explain the observed ranking dynamics.Research limitations:This study has only considered the publication-based dimension of institutional interdisciplinarity and has not explored other aspects.Practical implications:The findings provide insights for policymakers,research managers,and scholars to better interpret interdisciplinarity metrics and support interdisciplinary research effectively.Originality/value:This study underscores the critical role of classification granularity in interdisciplinarity assessment and emphasizes the need for standardized approaches to ensure robust and fair evaluations.展开更多
Although national transplant organizations share common visions and goals,the creation of a unified global organization remains impractical.Differences in ethnicity,culture,religion,and education shape local practices...Although national transplant organizations share common visions and goals,the creation of a unified global organization remains impractical.Differences in ethnicity,culture,religion,and education shape local practices and infrastructure,making the establishment of a single global entity unfeasible.Even with these social disparities aside,logistical factors such as time and distance between organ procurement and transplantation sites pose significant challenges.While technological advancements have extended organ preservation times,they have yet to support the demands of transcontinental transplantations effectively.This review presents a comparative analysis of the structures,operational frameworks,policies,and legislation governing various transplant organizations around the world.Key differences pertain to the administration of these organizations,trends in organ donation,and organ allocation policies,which reflect the financial,cultural,and religious diversity across different regions.While a global transplant organization may be out of reach,agreeing on best practices for the benefit of patients is essential.展开更多
In the post-college era,university research organizations are facing unprecedented changes in their structure and operational models.In terms of organizational form,these institutions are transitioning from single-dis...In the post-college era,university research organizations are facing unprecedented changes in their structure and operational models.In terms of organizational form,these institutions are transitioning from single-disciplinebased models to interdisciplinary and multidisciplinary collaboration models.This shift reflects the growing need to address complex,real-world problems that require expertise from multiple fields.From a management perspective,interdisciplinary research organizations face unique challenges.They must coordinate researchers from diverse disciplinary backgrounds,navigate potential conflicts between traditional departments and interdisciplinary units,and address differences in goals and organizational culture among members.These complexities make management more intricate and demanding.Simultaneously,the focus of university research organizations has become increasingly interest-driven,with research objectives,content,and participants reflecting specific areas of interest or societal demand.To adapt to these evolving trends,university research organizations must adopt flexible models tailored to their unique development needs.This approach will ensure the efficient execution of research activities and facilitate the effective transformation of research outcomes into practical applications.展开更多
The high-quality development of grassroots teaching organizations in universities is crucial to improving the quality of higher education.From the perspective of dual-track drive,this paper deeply analyzes the synerge...The high-quality development of grassroots teaching organizations in universities is crucial to improving the quality of higher education.From the perspective of dual-track drive,this paper deeply analyzes the synergetic evolution relationship between institutions and teachers in the development of grassroots teaching organizations in universities.At present,the development of grassroots teaching organizations in universities is faced with such dilemmas as lagging institutional supply,insufficient motivation for teachers’development,and lack of synergy mechanisms.These interwoven problems have formed systemic obstacles restricting high-quality development,which urgently need in-depth analysis and resolution.Currently,only from the perspective of synergistic promotion of institutions and teachers and by constructing a systematic implementation framework can the existing problems be effectively solved.Through three dimensions-goal guidance,resource guarantee,and mechanism optimization-this paper refines nine specific measures,aiming to break the barriers between institutional development and teachers’development,form a joint force,provide theoretical support and practical paths for improving the efficiency of grassroots teaching organizations,promote the overall improvement of education and teaching quality,enhance the quality of talent training in universities,and advance the in-depth development of education and teaching reform.展开更多
To deepen understanding of the evolution of coal char microstructural properties of coal char during the co-pyrolysis of coking coal with additives,this study incorporated two typical additives,coal tar pitch(CTP)and ...To deepen understanding of the evolution of coal char microstructural properties of coal char during the co-pyrolysis of coking coal with additives,this study incorporated two typical additives,coal tar pitch(CTP)and waste plastic(HDPE),into a blended coal sample and carried out pyrolysis experiments.The pyrolysis process and the microstructure of char were systematically characterized using various analytical techniques,including thermogravimetric analysis(TGA),X-ray diffraction(XRD)and Raman spectroscopy.Data correlation analysis was performed to reveal the mechanism of carbon structural ordering evolution within the critical temperature range(350−600℃)from colloidal layer formation to semi-coke conversion in coking coal,and to elucidate the regulatory effects of different additives on coal pyrolysis pathways.The results indicate that HDPE releases free radicals during high-temperature pyrolysis,accelerating the pyrolysis reaction and increase the yield of volatile components.Conversely,CTP facilitates pyrolysis at low temperatures through its light components,thereby delaying high-temperature reactions due to the colloidal layer’s effect.XRD results indicate that during the process of pyrolysis,there is a progressive decrease in the interlayer spacing of aromatic layers(d002),while the aromatic ring stacking height(L_(c))and lateral size(L_(a))undergo significant of carbon skeleton ordering.Further comparative reveals that CTP partially suppresses structural ordering at low temperatures,whereas HDPE promotes the condensation and alignment of aromatic clusters via a free radical mechanism.Raman spectroscopy reveals a two-stage reorganization mechanism in the microstructure of the coal char:the decrease in the I_(D)/I_(G)ratio between 350 and 550℃is primarily attributed to the cleavage of aliphatic side chains and cross-linking bonds,leading to a reduction in defective structures;whereas the increase in ID/IG between 550 and 600℃is closely associated with enhanced condensation reactions of aromatic structures.Correlation analysis further demonstrates progressive graphitization during pyrolysis,with a significant positive correlation(R^(2)>0.85)observed between d002 and the full width at half maximum of the G-band(FWHM-G).展开更多
Temperature has a substantial impact on the emission of biogenic volatile organic compounds(BVOCs).Moder-ate warm temperatures,e.g.,30–40°C,could boost plant metabolism,increasing BVOC emissions.Against the back...Temperature has a substantial impact on the emission of biogenic volatile organic compounds(BVOCs).Moder-ate warm temperatures,e.g.,30–40°C,could boost plant metabolism,increasing BVOC emissions.Against the backdrop of global warming,plants emit more BVOCs to cope with thermal stress,leading to elevated concen-trations of tropospheric ozone(O_(3))and secondary organic aerosols(SOA).In recent years,a considerable body of research has explored the interaction between tree species and BVOCs under the influence of various environ-mental factors.Although many studies have examined explored the temperature dependence of BVOC emissions in the past,few studies have conducted a comprehensive and in-depth investigation into the impacts of tempera-ture.This review summarizes the relevant studies on BVOCs in the past decade,including the main biosynthetic pathways,emission observation techniques and emission inventories,as well as how temperature affects isoprene and monoterpene emission rates and the formation of O_(3) and SOA.Our work offers a theoretical foundation and guidance for future efforts to advance the comprehension of BVOC emission characteristics and develop strategies to mitigate secondary pollution.展开更多
Microplastic contamination has emerged as a threat in transplantation,with evidence of its presence in human tissues and potential to compromise grafts.Transplant recipients,vulnerable due to immunosuppression and sur...Microplastic contamination has emerged as a threat in transplantation,with evidence of its presence in human tissues and potential to compromise grafts.Transplant recipients,vulnerable due to immunosuppression and surgical exposure,face risk from microplastics via airborne particles,surgical materials,and organ preservation systems.These particles trigger inflammation,oxidative stress,and immune dysregulation—pathways critical in rejection.Microplastics support biofilm formation,potentially facilitating antimicrobial resistance in clinical settings.Despite this risk,transplant-specific research is lacking.We urge action through environmental controls,material substitutions,and procedural modifications,alongside research targeting exposure pathways,biological impact,and mitigation strategies.Transplantation has historically led medical innovation and must do so in confronting this environmental challenge.Leadership from global transplant societies is essential to protect recipients and ensure safe procedures.展开更多
In natural aquatic ecosystems,algal-derived organic carbon(AOC)often coexists with exogenous organic carbon(EOC).Microbial utilization of these distinct carbon sources affects carbon flux and transformation in water c...In natural aquatic ecosystems,algal-derived organic carbon(AOC)often coexists with exogenous organic carbon(EOC).Microbial utilization of these distinct carbon sources affects carbon flux and transformation in water column and algal growth.Microcystis blooms significantly increase AOC levels in water,but the microbial transformation process of Microcystis-derived AOC in the presence of EOC remain poorly understood.We conducted a simulated experiment by introducing^(13)C-sodium bicarbonate and^(13)C-glucose as substrates for indoor simulation of non-axenic Microcystis aeruginosa(M.aeruginosa)populations in a sealed system.The microbial transformation processes of AOC and EOC and their effects on M.aeruginosa growth were investigated.Results demonstrated that the addition of glucose accelerated M.aeruginosa growth and significantly increased their biomass.During the experiment,as the particulate organic carbon and nitrogen content increased,the concentrations of CO_(2)and N_(2)O were gradually decreased,while the concentration of CH4 were gradually increased.Significant differences were observed in the microbial processes involved in the uptake of AOC and EOC.Bacteria involved in AOC transformation throughout the growth period were dominated by Proteobacteria,Gemmatimonadota,Actinobacteriota,Bacteroidota,Acidobacteriota,and Firmicutes.The bacteria involved in EOC transformation were dominated by Proteobacteria,Actinobacteriota,Firmicutes,Cyanobacteria,Armatimonadota,and Bacteroidota.Linear discriminant analysis Effect Size(LEfSe)analysis revealed Massilia and Akkermansia as biomarkers involved in AOC transformation,while Ligilactobacillus was associated with EOC transformation.These findings provide valuable insights into the effects of EOC on algae-bacteria interaction,and on the dynamics of carbon and nitrogen cycling among M.aeruginosa and its associated bacteria.展开更多
Organic photovoltaics(OPVs)have achieved remarkable progress,with laboratory-scale single-junction devices now demonstrating power conversion efficiencies(PCEs)exceeding 20%.However,these efficiencies are highly depen...Organic photovoltaics(OPVs)have achieved remarkable progress,with laboratory-scale single-junction devices now demonstrating power conversion efficiencies(PCEs)exceeding 20%.However,these efficiencies are highly dependent on the thickness of the photoactive layer,which is typically around 100 nm.This sensitivity poses a challenge for industrial-scale fabrication.Achieving high PCEs in thick-film OPVs is therefore essential.This review systematically examines recent advancements in thick-film OPVs,focusing on the fundamental mechanisms that lead to efficiency loss and strategies to enhance performance.We provide a comprehensive analysis spanning the complete photovoltaic process chain:from initial exciton generation and diffusion dynamics,through dissociation mechanisms,to subsequent charge-carrier transport,balance optimization,and final collection efficiency.Particular emphasis is placed on cutting-edge solutions in molecular engineering and device architecture optimization.By synthesizing these interdisciplinary approaches and investigating the potential contributions in stability,cost,and machine learning aspects,this work establishes comprehensive guidelines for designing high-performance OPVs devices with minimal thickness dependence,ultimately aiming to bridge the gap between laboratory achievements and industrial manufacturing requirements.展开更多
Achieving simultaneous enhancement of crystallinity and optimal domain size remains a fundamental challenge in organic photovoltaics(OPVs),where conventional crystallization strategies often trigger excessive aggregat...Achieving simultaneous enhancement of crystallinity and optimal domain size remains a fundamental challenge in organic photovoltaics(OPVs),where conventional crystallization strategies often trigger excessive aggregation of small-molecule acceptors.This work pioneers a kinetic paradigm for resolving the crystallinity-domain size trade-off in organic photovoltaics through dual-additive-guided stepwise crystallization.By strategically pairing 1,2-dichlorobenzene(o-DCB,low binding energy to Y6)and 1-fluoronaphthalene(FN,high binding energy),we achieve temporally decoupled crystallization control:o-DCB first mediates donor-acceptor co-crystallization during film formation,constructing a metastable network,whereupon FN induces confined Y6 crystallization within this framework during thermal annealing,refining nanostructure without over-aggregation.Morphology studies reveal that this synergy enhances crystallinity of(100)diffraction peaks by 21%–10%versus single-additive controls(o-DCB/FN alone),while maintaining optimal domain size.These morphological advantages yield balanced carrier transport(μh/μe=1.23),near-unity exciton dissociation(98.53%),and a champion power conversion efficiency(PCE)of 18.08%for PM6:Y6,significantly surpassing single-additive devices(o-DCB:17.20%;FN:17.53%).Crucially,the dual-additive strategy demonstrates universal applicability across diverse active layer systems,achieving an outstanding PCE of 19.27%in PM6:L8-BO-based devices,thereby establishing a general framework for morphology control in high-efficiency OPVs.展开更多
Multi-organ-on-a-chip(MOOC)technology represents a pivotal direction in the organ-on-a-chip field,seeking to emulate the complex interactions of multiple human organs in vitro through microfluidic systems.This technol...Multi-organ-on-a-chip(MOOC)technology represents a pivotal direction in the organ-on-a-chip field,seeking to emulate the complex interactions of multiple human organs in vitro through microfluidic systems.This technology overcomes the limitations of traditional single-organ models,providing a novel platform for investigating complex disease mechanisms and evaluating drug efficacy and toxicity.Although it demonstrates broad application prospects,its development still faces critical bottlenecks,including inadequate physiological coupling between organs,short functional maintenance durations,and limited real-time monitoring capabilities.Contemporary research is advancing along three key directions,including functional coupling,sensor integration,and full-process automation systems,to propel the technology toward enhanced levels of physiological relevance and predictive accuracy.展开更多
In this study,we meticulously designed a layered carbon-based catalytic material to induce the degradation of a series of organic pollutants by activating peroxymonosulfate(PMS) in the PMS-based advanced oxidation pro...In this study,we meticulously designed a layered carbon-based catalytic material to induce the degradation of a series of organic pollutants by activating peroxymonosulfate(PMS) in the PMS-based advanced oxidation processes(AOPs).Results indicated that the silicon and oxygen elements from the montmorillonite were incorporated into the catalyst matrix to form the Si-O-C structure.It was notable that the layered carbonaceous material with Si-O-C structure exhibited an outstanding catalytic effect on the synthesized layered catalytic material array,achieving over 90 % removal rate of most pollutants within 60 min.It was notable that the layered carbonaceous material with Si-O-C structure exhibited an outstanding catalytic effect on the synthesized layered catalytic material array.The salt bridge system confirmed that pollutants can provide electrons to the Si-O-C/PMS system,and we verified that the electron transfer process(ETP) mechanism was the main pathway for the degradation of pollutants in the Si-O-C/PMS system via the open-circuit potential analysis.In combination with the structural properties of different pollutants,we discovered that electron-donating pollutants can supply more electrons to the Si-O-C/PMS system,thereby enhancing the ETP process.The findings of this study are anticipated to advance the development and practical application of layered carbonaceous materials-based catalysts and support the design and implementation of nanoconfined catalysts in the field of AOPs.展开更多
In floodplain wetlands,alterations in hydrological patterns resulting from climate change and human activities could potentially diminish the carbon sequestration capacity of the soils,thereby having a negative impact...In floodplain wetlands,alterations in hydrological patterns resulting from climate change and human activities could potentially diminish the carbon sequestration capacity of the soils,thereby having a negative impact on global climate change.However,the magnitude of the influence of hydrological regime change on soil carbon remains inadequately monitored.To address this research gap,we collected 306 upper layer(0–20 cm)soil samples from the Dongting Lake floodplain between 2013 and 2022.The random forest(RF)algorithm was used to analyze the spatial distribution of soil organic carbon(SOC)in the upper soil layer of Dongting Lake floodplain and the impact of climate and hydrological changes in the past decade on surface SOC in the East Dongting Lake area was studied.In 2022,the SOC concentration of the Dongting Lake floodplain upper layer soil ranged from 3.34 to 17.67 g kg^(-1),averaging 10.43 g kg^(-1),with a corresponding SOC density of(2.65±0.49)kg m^(-2) and total SOC stock of 6.82 Tg C(2.87–13.48 Tg C).From 2013 to 2022,the SOC concentration of the upper soil layer of the East Dongting Lake area decreased from 18.37 to 10.82 g kg^(-1).This reduction could be attributed to climate and hydrological changes which reduce SOC input by reducing vegetation growth and accelerating SOC decomposition.Above 21.4 m elevation,the amount of SOC loss increased with elevation,the loss being related to the decline in Miscanthus community biomass and greater susceptibility of higher altitude areas to climate and hydrological changes.Our results highlight the need for strengthening wetland SOC management to increase SOC in the soils to help combat climate change.展开更多
The crystallization and aggregation characteristics of the active layer components in organic solar cells(OSCs)are one of the core factors determining photovoltaic performance,influencing the entire process from light...The crystallization and aggregation characteristics of the active layer components in organic solar cells(OSCs)are one of the core factors determining photovoltaic performance,influencing the entire process from light absorption to charge separation,transport,and ultimately charge collection.Dynamic changes in crystallization and aggregation states can also disrupt the microstructure of the active layer,thus shortening the lifetime of the cell.In this study,a morphology modulation strategy is proposed to regulate the crystallization kinetics of non-fullerene acceptors by employing the polymer molecule PYIT as a nucleating agent.An appropriate amount of PYIT was first completely dissolved with the non-fullerene acceptor Y6 and left to stand for 24 h,followed by the fabrication of layer-by-layer processed OSCs.Experiments demonstrated that high crystallinity of PYIT allows it to act as a crystallization nucleus,promoting the crystallization,orientation consistency,and ordered stacking of the acceptor.These nanoscale structural optimizations facilitate efficient charge transport,enhance exciton dissociation efficiency,and suppress unfavorable energetic disorder.Consequently,not only was the power conversion efficiency(PCE)of D18-Cl/Y6-based layer-by-layer processed OSC increased from 18.08%to 19.13%,but the atmospheric stability and long-term lifetime of the OSCs were also significantly improved.Notably,this strategy is also applicable to indoor OSCs,and the PYIT-optimized device can achieve a PCE of 27.0%under 1000 lux light-emitting diode(LED,3200K)irradiation,which is superior to that of the control device(24.2%).This work develops a crystal engineering strategy that is able to simultaneously optimize the microscopic morphology and charge dynamics properties in OSCs,thereby achieving simultaneous improvement in efficiency and stability.展开更多
Switchable polymerization is emerging as a powerful tool to construct block copolymers directly from mixtures of monomers.However,current achievements typically iterate between two polymerization cycles to afford prod...Switchable polymerization is emerging as a powerful tool to construct block copolymers directly from mixtures of monomers.However,current achievements typically iterate between two polymerization cycles to afford products with fixed sequences and compositions.Herein,we report the triethylborane/1,8-diazabicyclo[5.4.0]undec-7-ene(Et_3B/DBU)pair-mediated four-component switchable polymerization of propylene oxide(PO),CO_(2),phthalic anhydride(PA),and racemic lactide(rac-LA),which enables the on-demand synthesis of four different block copolymers,i.e.,poly(propylene phthalate)-b-polylactide(PPE-b-PLA),PPE-b-PLA-b-poly(propylene carbonate)(PPC),PPE-b-PPC-b-PLA,and PPE-b-PPCb-poly(propylene oxide)(PPO),through rationally modulating the Lewis pair(LP)ratio.Core to this protocol is that increasing the loading of Et_(3)B accelerates the ring-opening of PO while impeding the reactivity of rac-LA,thus allowing for fine-tuning of the thermodynamic and kinetic of the switchable polymerization.Therefore,the four polymerization cycles involving PO/PA ring-opening copolymerization(ROCOP),PO/CO_(2) ROCOP,rac-LA ring-opening polymerization(ROP),and PO ROP can be connected and discriminated in precisely programmed manners.展开更多
The lateral transport of labile organic carbon represents a critical pathway for soil organic carbon(SOC) loss,reducing organic carbon sequestration and increasing the risk of waterbody pollution.Livestock manure appl...The lateral transport of labile organic carbon represents a critical pathway for soil organic carbon(SOC) loss,reducing organic carbon sequestration and increasing the risk of waterbody pollution.Livestock manure application on croplands serves as a common fertilizer reduction practice to sustain crop yields,enhance SOC sequestration,and reduce water erosion.However,limited quantitative assessments have examined the effects of livestock manure substitution on labile organic carbon lateral loss and fluxes in long-term experiments.This study conducted a three-year field investigation on subtropical sloping croplands to assess the impact of livestock manure substitution on dissolved organic carbon(DOC) and particulate organic carbon(POC) loss via surface runoff,interflow and eroded sediments.There are four treatments:no fertilization(CK);chemical nitrogen fertilizer(SF),40% nitrogen substitution with pig manure(PMF),and 100% nitrogen substitution from pig manure(PM).Compared to SF treatment,long-term livestock manure substitution in PMF and PM treatments significantly(P<0.05) reduced annual cumulative surface runoff fluxes by 13.5 and 21.6%,respectively.Manure applications decreased annual sediment fluxes by 12.9 and 19.1%,respectively.Soil water stable aggregates for mean weight diameter(MWD) increased significantly by 37.7 and 73.6%.Annual cumulative POC loss flux via eroded sediment under PMF and PM treatments increased significantly(P<0.05) by 61.1 and 47.9%,respectively.The labile organic carbon loss fluxes,including DOC and POC losses,under PMF and PM treatments increased significantly(P<0.05) by 11.9 and 31.4%,respectively.These results demonstrate that while water erosion intensity decreases due to enhanced soil aggregate stability,the risk of labile organic carbon loss increases after long-term livestock manure substitution in subtropical sloping croplands.Future research should examine labile organic carbon lateral migration under various soil types and slope gradients for livestock manure application in subtropical agricultural ecosystem croplands to better understand extreme rainfall effects.展开更多
CO_(2)reduction technology can promote the resource utilization of carbon and help alleviate global warming and energy supply pressure.It is an effective way to achieve energy conversion and utilization.Covalent organ...CO_(2)reduction technology can promote the resource utilization of carbon and help alleviate global warming and energy supply pressure.It is an effective way to achieve energy conversion and utilization.Covalent organic frameworks(COFs)are porous crystalline materials formed by connecting organic monomers through covalent bonds.They have the characteristics of functional diversity and rich chemical properties.Their advantages,such as high porosity,a wide range of visible light absorption,and excellent charge separation efficiency,give them good potential in CO_(2)capture,separation,and conversion.Currently,Cu is a key metal in the catalytic CO_(2)reduction reaction(CO_(2)RR)for the preparation of high-value-added chemicals.The preparation of highly stable and large-pore Cu-based COFs using COFs as an ideal sacrificial template for loading Cu can be used to develop high-performance electrocatalysts and photocatalysts.In this review,we discuss the latest advancements in this field,including the development of various Cu-based COFs and their applications as catalysts for CO_(2)RR.Here,we mainly introduce the synthesis strategies,some important characterization information,and the applications of electrocatalytic and photocatalytic CO_(2)conversion using these previously reported Cu-based COFs.展开更多
Fenton-like technology based on peroxymonosulfate activation has shown great potential in refractory organics degradation.In this work,single Fe atom catalysts were synthesized through facile ball milling and exhibite...Fenton-like technology based on peroxymonosulfate activation has shown great potential in refractory organics degradation.In this work,single Fe atom catalysts were synthesized through facile ball milling and exhibited very high performance in peroxymonosulfate activation.The Fe single-atom filled an N vacancy on the triazine ring edge of C_(3)N_(4),as confirmed through X-ray absorption fine structure,density functional calculation and elec-tron paramagnetic resonance.The SAFe_(0.4)–C_(3)N_(4)/PMS system could completely remove phenol(20 mg/L)within 10 min and its first-order kinetic constant was 12.3 times that of the Fe_(3)O_(4)/PMS system.Under different ini-tial pH levels and in various anionic environments,SAFe_(0.4)–C_(3)N_(4) still demonstrated excellent catalytic activity,achieving a removal rate of over 90%for phenol within 12 min.In addition,SAFe_(0.4)–C_(3)N_(4) exhibited outstanding selectivity in reaction systems with different pollutants,showing excellent degradation effects on electron-rich pollutants only.Hydroxyl radicals(•OH),singlet oxygen(1O_(2))and high-valent iron oxide(Fe(Ⅳ)=O)were de-tected in the SAFe_(0.4)–C_(3)N_(4)/PMS system through free radical capture experiments.Further experiments on the quenching of active species and a methyl phenyl sulfoxide probe confirmed that 1O_(2) and Fe(Ⅳ)=O played dom-inant roles.Additionally,the change in the current response after adding PMS and phenol in succession proved that a direct electron transfer path between organic matter and the catalyst surface was unlikely to exist in the SAFe_(0.4)–C_(3)N_(4)/PMS/Phenol degradation system.This study provides a new demonstration of the catalytic mech-anism of single-atom catalysts.展开更多
文摘Recently,the Standardization Administration of China issued Announcement No.1 of 2026,officially approving the establishment of the Subcommittee 1 on Nonwoven Material of National Technical Committee 606 on Technical Textiles of Standardization Administration of China(SAC/TC606/SC1)and the Subcommittee 2 on Filtration and Separation Textiles of National Technical Committee 606 on Technical Textiles of Standardization Administration of China(SAC/TC606/SC2).The formation of these two subcommittees marks a crucial step in the standardization development of China's industrial textiles sector in specialized fields.
基金supported by the China Postdoctoral Science Foundation(No.2023M732344)the National Natural Science Foundation of China(Nos.51973119,52327802,52173078)+4 种基金Shenzhen Key Laboratory of Photonics and Biophotonics(ZDSYS20210623092006020)Shenzhen Key Laboratory for Low-carbon Natural Science Foundation of Guangdong Province(No.2024A1515010639)Construction Material and Technology(No.ZDSYS20220606100406016)National Key Laboratory of Green and Long-Life Road Engineering in Extreme Environment(Shenzhen)(No.868-000003010103)Joint Funds of Ministry of Education(No.8091B022225).
文摘Self-regulating heating and self-powered flexibility are pivotal for future wearable devices.However,the low energy-conversion rate of wearable devices at low temperatures limits their application in plateaus and other environments.This study introduces an azopolymer with remarkable semicrystallinity and reversible photoinduced solid-liquid transition ability that is obtained through copolymerization of azoben-zene(Azo)monomers and styrene.A composite of one such copolymer with an Azo:styrene molar ratio of 9:1(copolymer is denoted as PAzo9:1-co-polystyrene(PS))and nylon fabrics(NFs)is prepared(composite is denoted as PAzo9:1-co-PS@NF).PAzo9:1-co-PS@NF exhibits hydrophobicity and high wear resistance.Moreover,it shows good responsiveness(0.624 s^(−1))during isomerization under solid ultraviolet(UV)light(365 nm)with an energy density of 70.6 kJ kg^(−1).In addition,the open-circuit voltage,short-circuit current and quantity values of PAzo9:1-co-PS@NF exhibit small variations in a temperature range of−20℃ to 25℃ and remain at 170 V,5 μA,and 62 nC,respectively.Notably,the involved NFs were cut and sewn into gloves to be worn on a human hand model.When the model was exposed to both UV radiation and friction,the temperature of the finger coated with PAzo9:1-co-PS was approximately 6.0°C higher than that of the other parts.Therefore,developing triboelectric nanogenerators based on the in situ photothermal cycles of Azo in wearable devices is important to develop low-temperature self-regulating heating and self-powered flexible devices for extreme environments.
文摘Purpose:Interdisciplinary research has become a critical approach to addressing complex societal,economic,technological,and environmental challenges,driving innovation and integrating scientific knowledge.While interdisciplinarity indicators are widely used to evaluate research performance,the impact of classification granularity on these assessments remains underexplored.Design/methodology/approach:This study investigates how different levels of classification granularity-macro,meso,and micro-affect the evaluation of interdisciplinarity in research institutes.Using a dataset of 262 institutes from four major German non-university organizations(FHG,HGF,MPG,WGL)from 2018 to 2022,we examine inconsistencies in interdisciplinarity across levels,analyze ranking changes,and explore the influence of institutional fields and research focus(applied vs.basic).Findings:Our findings reveal significant inconsistencies in interdisciplinarity across classification levels,with rankings varying substantially.Notably,the Fraunhofer Society(FHG),which performs well at the macro level,experiences significant ranking declines at meso and micro levels.Normalizing interdisciplinarity by research field confirmed that these declines persist.The research focus of institutes,whether applied,basic,or mixed,does not significantly explain the observed ranking dynamics.Research limitations:This study has only considered the publication-based dimension of institutional interdisciplinarity and has not explored other aspects.Practical implications:The findings provide insights for policymakers,research managers,and scholars to better interpret interdisciplinarity metrics and support interdisciplinary research effectively.Originality/value:This study underscores the critical role of classification granularity in interdisciplinarity assessment and emphasizes the need for standardized approaches to ensure robust and fair evaluations.
文摘Although national transplant organizations share common visions and goals,the creation of a unified global organization remains impractical.Differences in ethnicity,culture,religion,and education shape local practices and infrastructure,making the establishment of a single global entity unfeasible.Even with these social disparities aside,logistical factors such as time and distance between organ procurement and transplantation sites pose significant challenges.While technological advancements have extended organ preservation times,they have yet to support the demands of transcontinental transplantations effectively.This review presents a comparative analysis of the structures,operational frameworks,policies,and legislation governing various transplant organizations around the world.Key differences pertain to the administration of these organizations,trends in organ donation,and organ allocation policies,which reflect the financial,cultural,and religious diversity across different regions.While a global transplant organization may be out of reach,agreeing on best practices for the benefit of patients is essential.
文摘In the post-college era,university research organizations are facing unprecedented changes in their structure and operational models.In terms of organizational form,these institutions are transitioning from single-disciplinebased models to interdisciplinary and multidisciplinary collaboration models.This shift reflects the growing need to address complex,real-world problems that require expertise from multiple fields.From a management perspective,interdisciplinary research organizations face unique challenges.They must coordinate researchers from diverse disciplinary backgrounds,navigate potential conflicts between traditional departments and interdisciplinary units,and address differences in goals and organizational culture among members.These complexities make management more intricate and demanding.Simultaneously,the focus of university research organizations has become increasingly interest-driven,with research objectives,content,and participants reflecting specific areas of interest or societal demand.To adapt to these evolving trends,university research organizations must adopt flexible models tailored to their unique development needs.This approach will ensure the efficient execution of research activities and facilitate the effective transformation of research outcomes into practical applications.
基金Interim results of the 2024 high-quality development project at Jingjiang College,Jiangsu University,titled“Research on the Teacher Evaluation Mechanism of Independent Colleges Based on the Three-Dimensional System of Innovation-Efficiency-Impact”(2024JFYA001)Interim results of the special project“Research on the Digitalization of Textbooks in the New Era”in Jiangsu Province’s universities in 2024(2024JCSZ37)。
文摘The high-quality development of grassroots teaching organizations in universities is crucial to improving the quality of higher education.From the perspective of dual-track drive,this paper deeply analyzes the synergetic evolution relationship between institutions and teachers in the development of grassroots teaching organizations in universities.At present,the development of grassroots teaching organizations in universities is faced with such dilemmas as lagging institutional supply,insufficient motivation for teachers’development,and lack of synergy mechanisms.These interwoven problems have formed systemic obstacles restricting high-quality development,which urgently need in-depth analysis and resolution.Currently,only from the perspective of synergistic promotion of institutions and teachers and by constructing a systematic implementation framework can the existing problems be effectively solved.Through three dimensions-goal guidance,resource guarantee,and mechanism optimization-this paper refines nine specific measures,aiming to break the barriers between institutional development and teachers’development,form a joint force,provide theoretical support and practical paths for improving the efficiency of grassroots teaching organizations,promote the overall improvement of education and teaching quality,enhance the quality of talent training in universities,and advance the in-depth development of education and teaching reform.
基金Supported by National Natural Science Foundation of China(22378180,22078141)Education Department Foundation of Liaoning Province(JYTMS20230960)。
文摘To deepen understanding of the evolution of coal char microstructural properties of coal char during the co-pyrolysis of coking coal with additives,this study incorporated two typical additives,coal tar pitch(CTP)and waste plastic(HDPE),into a blended coal sample and carried out pyrolysis experiments.The pyrolysis process and the microstructure of char were systematically characterized using various analytical techniques,including thermogravimetric analysis(TGA),X-ray diffraction(XRD)and Raman spectroscopy.Data correlation analysis was performed to reveal the mechanism of carbon structural ordering evolution within the critical temperature range(350−600℃)from colloidal layer formation to semi-coke conversion in coking coal,and to elucidate the regulatory effects of different additives on coal pyrolysis pathways.The results indicate that HDPE releases free radicals during high-temperature pyrolysis,accelerating the pyrolysis reaction and increase the yield of volatile components.Conversely,CTP facilitates pyrolysis at low temperatures through its light components,thereby delaying high-temperature reactions due to the colloidal layer’s effect.XRD results indicate that during the process of pyrolysis,there is a progressive decrease in the interlayer spacing of aromatic layers(d002),while the aromatic ring stacking height(L_(c))and lateral size(L_(a))undergo significant of carbon skeleton ordering.Further comparative reveals that CTP partially suppresses structural ordering at low temperatures,whereas HDPE promotes the condensation and alignment of aromatic clusters via a free radical mechanism.Raman spectroscopy reveals a two-stage reorganization mechanism in the microstructure of the coal char:the decrease in the I_(D)/I_(G)ratio between 350 and 550℃is primarily attributed to the cleavage of aliphatic side chains and cross-linking bonds,leading to a reduction in defective structures;whereas the increase in ID/IG between 550 and 600℃is closely associated with enhanced condensation reactions of aromatic structures.Correlation analysis further demonstrates progressive graphitization during pyrolysis,with a significant positive correlation(R^(2)>0.85)observed between d002 and the full width at half maximum of the G-band(FWHM-G).
基金supported by the National Key R&D Program of China(No.2024YFC3714200)Guangxi Key Research and Development Program,China(No.Guike AB24010074)+2 种基金the National Natural Science Foundation of China(Nos.22276099,U24A20515 and 22361162668)the Natural Science Foundation of Jiangsu Province(No.BK20240036)the Postgraduate Research&Practice Innovation Program of Jiangsu Province(No.KYCX24_1529).
文摘Temperature has a substantial impact on the emission of biogenic volatile organic compounds(BVOCs).Moder-ate warm temperatures,e.g.,30–40°C,could boost plant metabolism,increasing BVOC emissions.Against the backdrop of global warming,plants emit more BVOCs to cope with thermal stress,leading to elevated concen-trations of tropospheric ozone(O_(3))and secondary organic aerosols(SOA).In recent years,a considerable body of research has explored the interaction between tree species and BVOCs under the influence of various environ-mental factors.Although many studies have examined explored the temperature dependence of BVOC emissions in the past,few studies have conducted a comprehensive and in-depth investigation into the impacts of tempera-ture.This review summarizes the relevant studies on BVOCs in the past decade,including the main biosynthetic pathways,emission observation techniques and emission inventories,as well as how temperature affects isoprene and monoterpene emission rates and the formation of O_(3) and SOA.Our work offers a theoretical foundation and guidance for future efforts to advance the comprehension of BVOC emission characteristics and develop strategies to mitigate secondary pollution.
文摘Microplastic contamination has emerged as a threat in transplantation,with evidence of its presence in human tissues and potential to compromise grafts.Transplant recipients,vulnerable due to immunosuppression and surgical exposure,face risk from microplastics via airborne particles,surgical materials,and organ preservation systems.These particles trigger inflammation,oxidative stress,and immune dysregulation—pathways critical in rejection.Microplastics support biofilm formation,potentially facilitating antimicrobial resistance in clinical settings.Despite this risk,transplant-specific research is lacking.We urge action through environmental controls,material substitutions,and procedural modifications,alongside research targeting exposure pathways,biological impact,and mitigation strategies.Transplantation has historically led medical innovation and must do so in confronting this environmental challenge.Leadership from global transplant societies is essential to protect recipients and ensure safe procedures.
基金Supported by the Jiangsu Provincial Science and Technology Planning Project(No.BK20231516)the National Natural Science Foundation of China(Nos.42293264,32371606,31971449)。
文摘In natural aquatic ecosystems,algal-derived organic carbon(AOC)often coexists with exogenous organic carbon(EOC).Microbial utilization of these distinct carbon sources affects carbon flux and transformation in water column and algal growth.Microcystis blooms significantly increase AOC levels in water,but the microbial transformation process of Microcystis-derived AOC in the presence of EOC remain poorly understood.We conducted a simulated experiment by introducing^(13)C-sodium bicarbonate and^(13)C-glucose as substrates for indoor simulation of non-axenic Microcystis aeruginosa(M.aeruginosa)populations in a sealed system.The microbial transformation processes of AOC and EOC and their effects on M.aeruginosa growth were investigated.Results demonstrated that the addition of glucose accelerated M.aeruginosa growth and significantly increased their biomass.During the experiment,as the particulate organic carbon and nitrogen content increased,the concentrations of CO_(2)and N_(2)O were gradually decreased,while the concentration of CH4 were gradually increased.Significant differences were observed in the microbial processes involved in the uptake of AOC and EOC.Bacteria involved in AOC transformation throughout the growth period were dominated by Proteobacteria,Gemmatimonadota,Actinobacteriota,Bacteroidota,Acidobacteriota,and Firmicutes.The bacteria involved in EOC transformation were dominated by Proteobacteria,Actinobacteriota,Firmicutes,Cyanobacteria,Armatimonadota,and Bacteroidota.Linear discriminant analysis Effect Size(LEfSe)analysis revealed Massilia and Akkermansia as biomarkers involved in AOC transformation,while Ligilactobacillus was associated with EOC transformation.These findings provide valuable insights into the effects of EOC on algae-bacteria interaction,and on the dynamics of carbon and nitrogen cycling among M.aeruginosa and its associated bacteria.
基金supported by Natural Science Foundation of Zhejiang Province(Nos.LQ23E030002,LZ23B040001)the National Natural Science Foundation of China(Nos.52303226,21971049)L.Zhan acknowledges the research start-up fund from Hangzhou Normal University(4095C50222204002).
文摘Organic photovoltaics(OPVs)have achieved remarkable progress,with laboratory-scale single-junction devices now demonstrating power conversion efficiencies(PCEs)exceeding 20%.However,these efficiencies are highly dependent on the thickness of the photoactive layer,which is typically around 100 nm.This sensitivity poses a challenge for industrial-scale fabrication.Achieving high PCEs in thick-film OPVs is therefore essential.This review systematically examines recent advancements in thick-film OPVs,focusing on the fundamental mechanisms that lead to efficiency loss and strategies to enhance performance.We provide a comprehensive analysis spanning the complete photovoltaic process chain:from initial exciton generation and diffusion dynamics,through dissociation mechanisms,to subsequent charge-carrier transport,balance optimization,and final collection efficiency.Particular emphasis is placed on cutting-edge solutions in molecular engineering and device architecture optimization.By synthesizing these interdisciplinary approaches and investigating the potential contributions in stability,cost,and machine learning aspects,this work establishes comprehensive guidelines for designing high-performance OPVs devices with minimal thickness dependence,ultimately aiming to bridge the gap between laboratory achievements and industrial manufacturing requirements.
基金supported by the Shaanxi Provincial High level Talent Introduction Project(5113220044)the Shaanxi Outstanding Youth Project(2023-JC-JQ-33)+8 种基金the Youth Science and Technology Talent Promotion Project of Jiangsu Association for Science and Technology(TJ-2022-088)the Project funded by China Postdoctoral Science Foundation(2023TQ0273,2023TQ0274,2023M742833)the NationalNatural Science Foundation of China(62304181)the Natural Science Basic Research Program of Shaanxi(2023-JC-QN-0726,2025JC-YBQN-469)the GuangdongBasic and Applied Basic Research Foundation(2022A1515110286,2024A1515012538)the Basic Research Programs of Taicang(TC2024JC04)the Suzhou Science and Technology Development Plan Innovation Leading Talent Project(ZXL2023183)the Fundamental Research Funds for the Central Universities(G2022KY05108,G2024KY0605,G2023KY0601)and the Aeronautical Science Foundation of China(2018ZD53047).
文摘Achieving simultaneous enhancement of crystallinity and optimal domain size remains a fundamental challenge in organic photovoltaics(OPVs),where conventional crystallization strategies often trigger excessive aggregation of small-molecule acceptors.This work pioneers a kinetic paradigm for resolving the crystallinity-domain size trade-off in organic photovoltaics through dual-additive-guided stepwise crystallization.By strategically pairing 1,2-dichlorobenzene(o-DCB,low binding energy to Y6)and 1-fluoronaphthalene(FN,high binding energy),we achieve temporally decoupled crystallization control:o-DCB first mediates donor-acceptor co-crystallization during film formation,constructing a metastable network,whereupon FN induces confined Y6 crystallization within this framework during thermal annealing,refining nanostructure without over-aggregation.Morphology studies reveal that this synergy enhances crystallinity of(100)diffraction peaks by 21%–10%versus single-additive controls(o-DCB/FN alone),while maintaining optimal domain size.These morphological advantages yield balanced carrier transport(μh/μe=1.23),near-unity exciton dissociation(98.53%),and a champion power conversion efficiency(PCE)of 18.08%for PM6:Y6,significantly surpassing single-additive devices(o-DCB:17.20%;FN:17.53%).Crucially,the dual-additive strategy demonstrates universal applicability across diverse active layer systems,achieving an outstanding PCE of 19.27%in PM6:L8-BO-based devices,thereby establishing a general framework for morphology control in high-efficiency OPVs.
基金supported by the Shenzhen Medical Research Fund(Grant No.A2303049)Guangdong Basic and Applied Basic Research(Grant No.2023A1515010647)+1 种基金National Natural Science Foundation of China(Grant No.22004135)Shenzhen Science and Technology Program(Grant No.RCBS20210706092409020,GXWD20201231165807008,20200824162253002).
文摘Multi-organ-on-a-chip(MOOC)technology represents a pivotal direction in the organ-on-a-chip field,seeking to emulate the complex interactions of multiple human organs in vitro through microfluidic systems.This technology overcomes the limitations of traditional single-organ models,providing a novel platform for investigating complex disease mechanisms and evaluating drug efficacy and toxicity.Although it demonstrates broad application prospects,its development still faces critical bottlenecks,including inadequate physiological coupling between organs,short functional maintenance durations,and limited real-time monitoring capabilities.Contemporary research is advancing along three key directions,including functional coupling,sensor integration,and full-process automation systems,to propel the technology toward enhanced levels of physiological relevance and predictive accuracy.
基金supported by National Natural Science Foundation of China (Nos.52170086,22476116,52074176)Natural Science Foundation of Shandong Province (Nos.ZR2021ME013,ZR2024ME156,ZR2022QB250)。
文摘In this study,we meticulously designed a layered carbon-based catalytic material to induce the degradation of a series of organic pollutants by activating peroxymonosulfate(PMS) in the PMS-based advanced oxidation processes(AOPs).Results indicated that the silicon and oxygen elements from the montmorillonite were incorporated into the catalyst matrix to form the Si-O-C structure.It was notable that the layered carbonaceous material with Si-O-C structure exhibited an outstanding catalytic effect on the synthesized layered catalytic material array,achieving over 90 % removal rate of most pollutants within 60 min.It was notable that the layered carbonaceous material with Si-O-C structure exhibited an outstanding catalytic effect on the synthesized layered catalytic material array.The salt bridge system confirmed that pollutants can provide electrons to the Si-O-C/PMS system,and we verified that the electron transfer process(ETP) mechanism was the main pathway for the degradation of pollutants in the Si-O-C/PMS system via the open-circuit potential analysis.In combination with the structural properties of different pollutants,we discovered that electron-donating pollutants can supply more electrons to the Si-O-C/PMS system,thereby enhancing the ETP process.The findings of this study are anticipated to advance the development and practical application of layered carbonaceous materials-based catalysts and support the design and implementation of nanoconfined catalysts in the field of AOPs.
基金supported by the National Key Research and Development Program of China(2022YFC3204101 and 2023YFF0807202)the National Natural Science Foundation of China(U22A20570 and U2444221)+4 种基金the Youth Promotion Association of the Chinese Academy of Sciences(2021365)the Changsha Outstanding Innovative Youth Project,China(kq2305035)the Science,Technology and Innovation Platform Plan of Hunan Province,China(2022PT1010)the Major Scientific and Technological Projects of the Ministry of Water Resources,China(SKS-2022081)the Comprehensive Investigation and Potential Evaluation of Natural Resources Carbon Sink in Southern Hilly Region,China(DD20220880)。
文摘In floodplain wetlands,alterations in hydrological patterns resulting from climate change and human activities could potentially diminish the carbon sequestration capacity of the soils,thereby having a negative impact on global climate change.However,the magnitude of the influence of hydrological regime change on soil carbon remains inadequately monitored.To address this research gap,we collected 306 upper layer(0–20 cm)soil samples from the Dongting Lake floodplain between 2013 and 2022.The random forest(RF)algorithm was used to analyze the spatial distribution of soil organic carbon(SOC)in the upper soil layer of Dongting Lake floodplain and the impact of climate and hydrological changes in the past decade on surface SOC in the East Dongting Lake area was studied.In 2022,the SOC concentration of the Dongting Lake floodplain upper layer soil ranged from 3.34 to 17.67 g kg^(-1),averaging 10.43 g kg^(-1),with a corresponding SOC density of(2.65±0.49)kg m^(-2) and total SOC stock of 6.82 Tg C(2.87–13.48 Tg C).From 2013 to 2022,the SOC concentration of the upper soil layer of the East Dongting Lake area decreased from 18.37 to 10.82 g kg^(-1).This reduction could be attributed to climate and hydrological changes which reduce SOC input by reducing vegetation growth and accelerating SOC decomposition.Above 21.4 m elevation,the amount of SOC loss increased with elevation,the loss being related to the decline in Miscanthus community biomass and greater susceptibility of higher altitude areas to climate and hydrological changes.Our results highlight the need for strengthening wetland SOC management to increase SOC in the soils to help combat climate change.
基金supported by the National Natural Science Foundation of China(NSFC grant no.62474028,52130304,and 62222503)the Natural Science Foundation of Sichuan Province(2025ZNSFSC0037,2025ZNSFSC1460,and 2024NSFSC1447)the National Key R and D Program of China(2023YFB2604101).This work was also sponsored by the Sichuan Province Key Laboratory of Display Science and Technology.
文摘The crystallization and aggregation characteristics of the active layer components in organic solar cells(OSCs)are one of the core factors determining photovoltaic performance,influencing the entire process from light absorption to charge separation,transport,and ultimately charge collection.Dynamic changes in crystallization and aggregation states can also disrupt the microstructure of the active layer,thus shortening the lifetime of the cell.In this study,a morphology modulation strategy is proposed to regulate the crystallization kinetics of non-fullerene acceptors by employing the polymer molecule PYIT as a nucleating agent.An appropriate amount of PYIT was first completely dissolved with the non-fullerene acceptor Y6 and left to stand for 24 h,followed by the fabrication of layer-by-layer processed OSCs.Experiments demonstrated that high crystallinity of PYIT allows it to act as a crystallization nucleus,promoting the crystallization,orientation consistency,and ordered stacking of the acceptor.These nanoscale structural optimizations facilitate efficient charge transport,enhance exciton dissociation efficiency,and suppress unfavorable energetic disorder.Consequently,not only was the power conversion efficiency(PCE)of D18-Cl/Y6-based layer-by-layer processed OSC increased from 18.08%to 19.13%,but the atmospheric stability and long-term lifetime of the OSCs were also significantly improved.Notably,this strategy is also applicable to indoor OSCs,and the PYIT-optimized device can achieve a PCE of 27.0%under 1000 lux light-emitting diode(LED,3200K)irradiation,which is superior to that of the control device(24.2%).This work develops a crystal engineering strategy that is able to simultaneously optimize the microscopic morphology and charge dynamics properties in OSCs,thereby achieving simultaneous improvement in efficiency and stability.
基金financially supported by National Key R&D Program Young Scientists Project(No.2023YFC3903100)the National Natural Science Foundation of China(No.22322503)analytical and testing assistance from the Analysis and Testing Center of HUST。
文摘Switchable polymerization is emerging as a powerful tool to construct block copolymers directly from mixtures of monomers.However,current achievements typically iterate between two polymerization cycles to afford products with fixed sequences and compositions.Herein,we report the triethylborane/1,8-diazabicyclo[5.4.0]undec-7-ene(Et_3B/DBU)pair-mediated four-component switchable polymerization of propylene oxide(PO),CO_(2),phthalic anhydride(PA),and racemic lactide(rac-LA),which enables the on-demand synthesis of four different block copolymers,i.e.,poly(propylene phthalate)-b-polylactide(PPE-b-PLA),PPE-b-PLA-b-poly(propylene carbonate)(PPC),PPE-b-PPC-b-PLA,and PPE-b-PPCb-poly(propylene oxide)(PPO),through rationally modulating the Lewis pair(LP)ratio.Core to this protocol is that increasing the loading of Et_(3)B accelerates the ring-opening of PO while impeding the reactivity of rac-LA,thus allowing for fine-tuning of the thermodynamic and kinetic of the switchable polymerization.Therefore,the four polymerization cycles involving PO/PA ring-opening copolymerization(ROCOP),PO/CO_(2) ROCOP,rac-LA ring-opening polymerization(ROP),and PO ROP can be connected and discriminated in precisely programmed manners.
基金funded by the Joint Funds of the National Natural Science Foundation of China (U20A20107 and U22A20562)the National Key Research and Development Program of China (2023YFD1900201-3)the International Cooperation Project,Ministry of Science and Technology of China (G2023019005L)。
文摘The lateral transport of labile organic carbon represents a critical pathway for soil organic carbon(SOC) loss,reducing organic carbon sequestration and increasing the risk of waterbody pollution.Livestock manure application on croplands serves as a common fertilizer reduction practice to sustain crop yields,enhance SOC sequestration,and reduce water erosion.However,limited quantitative assessments have examined the effects of livestock manure substitution on labile organic carbon lateral loss and fluxes in long-term experiments.This study conducted a three-year field investigation on subtropical sloping croplands to assess the impact of livestock manure substitution on dissolved organic carbon(DOC) and particulate organic carbon(POC) loss via surface runoff,interflow and eroded sediments.There are four treatments:no fertilization(CK);chemical nitrogen fertilizer(SF),40% nitrogen substitution with pig manure(PMF),and 100% nitrogen substitution from pig manure(PM).Compared to SF treatment,long-term livestock manure substitution in PMF and PM treatments significantly(P<0.05) reduced annual cumulative surface runoff fluxes by 13.5 and 21.6%,respectively.Manure applications decreased annual sediment fluxes by 12.9 and 19.1%,respectively.Soil water stable aggregates for mean weight diameter(MWD) increased significantly by 37.7 and 73.6%.Annual cumulative POC loss flux via eroded sediment under PMF and PM treatments increased significantly(P<0.05) by 61.1 and 47.9%,respectively.The labile organic carbon loss fluxes,including DOC and POC losses,under PMF and PM treatments increased significantly(P<0.05) by 11.9 and 31.4%,respectively.These results demonstrate that while water erosion intensity decreases due to enhanced soil aggregate stability,the risk of labile organic carbon loss increases after long-term livestock manure substitution in subtropical sloping croplands.Future research should examine labile organic carbon lateral migration under various soil types and slope gradients for livestock manure application in subtropical agricultural ecosystem croplands to better understand extreme rainfall effects.
文摘CO_(2)reduction technology can promote the resource utilization of carbon and help alleviate global warming and energy supply pressure.It is an effective way to achieve energy conversion and utilization.Covalent organic frameworks(COFs)are porous crystalline materials formed by connecting organic monomers through covalent bonds.They have the characteristics of functional diversity and rich chemical properties.Their advantages,such as high porosity,a wide range of visible light absorption,and excellent charge separation efficiency,give them good potential in CO_(2)capture,separation,and conversion.Currently,Cu is a key metal in the catalytic CO_(2)reduction reaction(CO_(2)RR)for the preparation of high-value-added chemicals.The preparation of highly stable and large-pore Cu-based COFs using COFs as an ideal sacrificial template for loading Cu can be used to develop high-performance electrocatalysts and photocatalysts.In this review,we discuss the latest advancements in this field,including the development of various Cu-based COFs and their applications as catalysts for CO_(2)RR.Here,we mainly introduce the synthesis strategies,some important characterization information,and the applications of electrocatalytic and photocatalytic CO_(2)conversion using these previously reported Cu-based COFs.
基金supported by the National Natural Science Foundation of China(Nos.22406081,22276086,22306086)the Natural Science Foundation of Jiangxi Province(No.20232BAB213029),all of which are greatly acknowledged by the authors.
文摘Fenton-like technology based on peroxymonosulfate activation has shown great potential in refractory organics degradation.In this work,single Fe atom catalysts were synthesized through facile ball milling and exhibited very high performance in peroxymonosulfate activation.The Fe single-atom filled an N vacancy on the triazine ring edge of C_(3)N_(4),as confirmed through X-ray absorption fine structure,density functional calculation and elec-tron paramagnetic resonance.The SAFe_(0.4)–C_(3)N_(4)/PMS system could completely remove phenol(20 mg/L)within 10 min and its first-order kinetic constant was 12.3 times that of the Fe_(3)O_(4)/PMS system.Under different ini-tial pH levels and in various anionic environments,SAFe_(0.4)–C_(3)N_(4) still demonstrated excellent catalytic activity,achieving a removal rate of over 90%for phenol within 12 min.In addition,SAFe_(0.4)–C_(3)N_(4) exhibited outstanding selectivity in reaction systems with different pollutants,showing excellent degradation effects on electron-rich pollutants only.Hydroxyl radicals(•OH),singlet oxygen(1O_(2))and high-valent iron oxide(Fe(Ⅳ)=O)were de-tected in the SAFe_(0.4)–C_(3)N_(4)/PMS system through free radical capture experiments.Further experiments on the quenching of active species and a methyl phenyl sulfoxide probe confirmed that 1O_(2) and Fe(Ⅳ)=O played dom-inant roles.Additionally,the change in the current response after adding PMS and phenol in succession proved that a direct electron transfer path between organic matter and the catalyst surface was unlikely to exist in the SAFe_(0.4)–C_(3)N_(4)/PMS/Phenol degradation system.This study provides a new demonstration of the catalytic mech-anism of single-atom catalysts.
