Possessing excellent mechanical properties,a high-coverage slide-ring conductive gel is constructed by in situ polymerization ofα-cyclodextrin(α-CD)polyrotaxane(PR)and 1-vinyl-3-ethylimidazolium bromide([VEIM]Br)ion...Possessing excellent mechanical properties,a high-coverage slide-ring conductive gel is constructed by in situ polymerization ofα-cyclodextrin(α-CD)polyrotaxane(PR)and 1-vinyl-3-ethylimidazolium bromide([VEIM]Br)ionic liquid(IL),using 1-ethyl-3-methylimidazolium bromide([EMIM]Br)IL as solvent.Benefiting from the compatibility of ILs and alkene-PR,the cross-linked network slide-ring gel not only maintains excellent conductivity(1.52×10^(−2) S/m),but also has effectively improved mechanical properties(513%fracture strain,0.713 MPa fracture stress,211 kPa elastic modulus and 1366 kJ/m^(3) toughness)and adhesive properties(472.3±25.9 kPa).The supramolecular gel can be used as a strain sensor to efficiently monitor deformation signals in real-time at least 200 times.Especially,the slide-ring gel can self-power generated by triboelectric effect and electrostatic induction between the skin layer and the polydimethylsiloxane(PDMS)layer that encapsulates the gel,achieving reversible and durable motion sensing,which provides a convenient pathway for constructing supramolecular self-powered flexible electronic materials.展开更多
Yongtao Yu,Yuelin Yu et al.Solvent-Resistant Wearable Triboelectric Nanogenerator for Energy-Harvesting and Self-Powered Sensors.Energy Environ.Mater.2024,7,e12700.On page 4 of this article,the first paragraph of 2.4,...Yongtao Yu,Yuelin Yu et al.Solvent-Resistant Wearable Triboelectric Nanogenerator for Energy-Harvesting and Self-Powered Sensors.Energy Environ.Mater.2024,7,e12700.On page 4 of this article,the first paragraph of 2.4,line 14(PDF version,same below),there is a spelling mistake of“sui,”.It should be changed to“suitable”.The denominator“dt”in the Equation(3)should be changed to“dt”.展开更多
Smart sensors are becoming one of the necessities for connecting and detecting surrounding stimuli with tremendous convenience, especially when exploiting a single powerful sensor with multifunctionality. To successfu...Smart sensors are becoming one of the necessities for connecting and detecting surrounding stimuli with tremendous convenience, especially when exploiting a single powerful sensor with multifunctionality. To successfully accomplish the design of a self-powered sensor, serving power is becoming a critical issue because of its continuously consumed energy required by electronics. A variety of nanogenerators aiming for the rational design of self-powered system are reviewed and compared, followed by their recent advances with polymer nanocomposites for self-powered sensors. More importantly, the proposed conceptual design of a self-powered unit/device with triboelectric nanogenerator has been emphasized to eventually realize the practical activities towards multiple detections and human–machine interaction. Finally, challenges and new prospects of rational design of self-powered polymer composite sensors in achieving human–machine interaction/interface are discussed.展开更多
For traditional piezoelectric sensors based on poled ceramics,a low curie tem-perature(T_(c))is a fatal flaw due to the depolarization phenomenon.However,in this study,we find the low T_(c) would be a benefit for flex...For traditional piezoelectric sensors based on poled ceramics,a low curie tem-perature(T_(c))is a fatal flaw due to the depolarization phenomenon.However,in this study,we find the low T_(c) would be a benefit for flex-ible piezoelectric sensors because small alterations of force trig-ger large changes in polarization.BaTi_(0.88)Sn_(0.12)O_(3)(BTS)with high piezoelectric coefficient and low T_(c) close to human body temperature is taken as an example for materials of this kind.Continuous piezo-electric BTS films were deposited on the flexible glass fiber fabrics(GFF),self-powered sensors based on the ultra-thin,superflexible,and polarization-free BTS-GFF/PVDF composite piezoelectric films are used for human motion sensing.In the low force region(1-9 N),the sensors have the outstanding performance with voltage sensitivity of 1.23 V N^(−1) and current sensitivity of 41.0 nA N^(−1).The BTS-GFF/PVDF sensors can be used to detect the tiny forces of falling water drops,finger joint motion,tiny surface deformation,and fatigue driving with high sensitivity.This work provides a new paradigm for the preparation of superflexible,highly sensitive and wearable self-powered piezoelectric sensors,and this kind of sensors will have a broad application prospect in the fields of medical rehabilitation,human motion monitoring,and intelligent robot.展开更多
Flexible electronic sensors composed of flexible film and conductive materials play an increasingly important role in wearable and internet information transmission.It has received more and more attention and made som...Flexible electronic sensors composed of flexible film and conductive materials play an increasingly important role in wearable and internet information transmission.It has received more and more attention and made some progress over the decades.However,it is still a great challenge to prepare biocompatible and highly transparent conductive films.Egg white is a pure natural protein-rich material.Hydroxypropylmethyl cellulose has a good compatibility and high transparency,which is an ideal material for flexible sensors.Here,we overcome the problem of poor mechanical flexibility and electrical conductivity of protein,and develop a high transparency and good flexibility hydroxypropylmethyl cellulose/egg white protein composite membrane-based triboelectric nanogenerator('X'-TENG).The experimental results show that the flexible pressure sensor based on'X'-TENG has a high sensitivity,fast response speed,and low detection limit.It can even be used as a touch/pressure sensing artificial electronic skin.It can also be made into an intelligent waffle keyboard for recording and tracking users of the keyboard.Our strategy may provide a new way to easily build flexible electronic sensors and move toward practical applications.展开更多
Wearable triboelectric nanogenerators(TENGs)have attracted attention owing to their ability to harvest energy from the surrounding environment without maintenance.Herein,polyetherimide-Al_(2)O_(3)(PAl)and polyvinylide...Wearable triboelectric nanogenerators(TENGs)have attracted attention owing to their ability to harvest energy from the surrounding environment without maintenance.Herein,polyetherimide-Al_(2)O_(3)(PAl)and polyvinylidene fluoride-co-hexafluoropropylene(PVDF-HFP,PH)nanofiber membranes were used as tribo-positive and tribo-negative materials,respectively.Phytic acid-doped polyaniline(PANI)/cotton fabric(PPCF)and ethylenediamine(EDA)-crosslinked PAl(EPAl)nanofiber membranes were used as triboelectrode and triboencapsulation materials,respectively.The result showed that when the PAl-PH-based TENG was shaped as a circle with a radius of 1 cm,under the pressure of 50 N,and the frequency of 0.5 Hz,the open-circuit voltage(V_(oc))and short-circuit current(I_(sc))reached the highest value of 66.6 V and-93.4 to 110.1 nA,respectively.Moreover,the PH-based TENG could be used as a fabric sensor to detect fabric composition and as a sensor-inductive switch for light bulbs or beeping warning devices.When the PAl-PH-based TENG was shaped as a 5×5 cm^(2)rectangle,a 33 pF capacitor could be charged to 15 V in 28 s.Interestingly,compared to PAl nanofiber membranes,EPAl nanofiber membranes exhibited good dyeing properties and excellent solvent resistance.The PPCF exhibited<5%resistance change after washing,bending,and stretching.展开更多
The rapid development of supercapacitors and wearable devices has allowed the construction of integrated self-powered wearable devices.However,most current research focuses on increasing supercapacitor capacity and th...The rapid development of supercapacitors and wearable devices has allowed the construction of integrated self-powered wearable devices.However,most current research focuses on increasing supercapacitor capacity and the sensitivity of sensors,overlooking the self-powered and integration of one single device.In this study,the editable,flexible yarn-based supercapacitor(FYSC)and an integrated self-powered wearable sensor(SPWS)were constructed based on one yarn.The FYSC demonstrated adjustable capacitive behaviors by controlling the electrode reduction degree,electrode spaces,and integration.The supercapacitors exhibit a high specific capacitance of 1.82 F cm^(-3),92.57%capacity retention after 5000 cycles,and stable performance under static and dynamic strain conditions.Additionally,the integrated SPWSs demonstrated the accuracy and sensitivity in discriminating bending magnitudes.The SPWSs further present the accuracy and stability in recognizing human physiological activities(joint motions of finger,wrist,knee,and elbow,respiration,and handwriting).The proposed strategy offers a practical approach to developing energy storage systems with customizable functionality.More importantly,the self-powered devices realized the integration of supercapacitors and sensors would facilitate the seamless integration of 1D functional yarns into wearable electronics.展开更多
Due to its ability to convert body heat into electricity,organic thermoelectric material is considered a promising and smart maintenance-free power source to charge wearable electronics.However,developing flexible n-t...Due to its ability to convert body heat into electricity,organic thermoelectric material is considered a promising and smart maintenance-free power source to charge wearable electronics.However,developing flexible n-type organic thermoelectric materials and wearable p/n junction thermoelectric devices remains challenging.In this work,two insulated polyamides(PA6 and PA66)that have been widely used as fiber materials are employed as novel dopants for converting p-type single-walled carbon nanotubes(SWCNTs)to n-type thermoelectric materials.Because of the electron transferability of the amide group,polyamide-doped SWCNTs exhibit excellent thermopower values as large as-56.0μV K^(-1) for PA66,and-54.5μV K^(-1) for PA6.Thermoelectric devices with five p/n junctions connected in series are fabricated.The testing device produces a thermoelectric voltage of 43.1 mV and generates 1.85μW thermoelectric power under temperature gradients of approximately 80 K.Furthermore,they display charming capability for temperature recognition and monitoring human activities as sensors.These promising results suggest that the flexible polyamide-doped SWCNT composites herein have high application potential as wearable thermoelectric electronics.展开更多
Flexible electronics face critical challenges in achieving monolithic three-dimensional(3D)integration,including material compatibility,structural stability,and scalable fabrication methods.Inspired by the tactile sen...Flexible electronics face critical challenges in achieving monolithic three-dimensional(3D)integration,including material compatibility,structural stability,and scalable fabrication methods.Inspired by the tactile sensing mechanism of the human skin,we have developed a flexible monolithic 3D-integrated tactile sensing system based on a holey MXene paste,where each vertical one-body unit simultaneously functions as a microsupercapacitor and pressure sensor.The in-plane mesopores of MXene significantly improve ion accessibility,mitigate the self-stacking of nanosheets,and allow the holey MXene to multifunctionally act as a sensing material,an active electrode,and a conductive interconnect,thus drastically reducing the interface mismatch and enhancing the mechanical robustness.Furthermore,we fabricate a large-scale device using a blade-coating and stamping method,which demonstrates excellent mechanical flexibility,low-power consumption,rapid response,and stable long-term operation.As a proof-of-concept application,we integrate our sensing array into a smart access control system,leveraging deep learning to accurately identify users based on their unique pressing behaviors.This study provides a promising approach for designing highly integrated,intelligent,and flexible electronic systems for advanced human-computer interactions and personalized electronics.展开更多
Natural polymers possess the qualities of abundant resources,low cost,as well as excellent biocompatibility and biodegradability,and are ideal materials for next-generation wearable and portable electronic devices.To ...Natural polymers possess the qualities of abundant resources,low cost,as well as excellent biocompatibility and biodegradability,and are ideal materials for next-generation wearable and portable electronic devices.To further augment the application scope of natural polymer materials,integrating them with functional materials represents a promising approach that is of great value for the sustainable development of triboelectric nanogenerators.Here,we successfully synthesized starch-[CsPbBr_(3)-KBr]-Fe_(3)O_(4)composite films through the combination of natural polymer materials with magnetic and fluorescent components.It is capable of achieving reversible hydrochromic conversion by exposing or removing water.The combination of fluorescent CsPbBr_(3)-KBr,magnetic Fe_(3)O_(4),and waterproof starch-[CsPbBr_(3)-KBr]-Fe_(3)O_(4)-Polydimethylsiloxane leads to the realization of fluorescence and magnetic composite anti-counterfeiting.This composite anti-counterfeiting technology presents a novel and highly effective approach for ensuring the authenticity and security of various types of information.In addition,the Composite film based triboelectric nanogenerator has been assembled,which has a stable output with a short circuit current and open-circuit voltage of 15.1μA and 170.1 V,respectively.The triboelectric nanogenerator can light 204 red LED lights at the same time,and the electrical output is not reduced even after 4200 mechanical cycles.Furthermore,based on the triboelectric nanogenerator,we have successfully demonstrated a self-powered sensor that can monitor human movement signals in real time.The sensor has shown broad application prospects in the field of health monitoring and motion analysis.展开更多
The rapid advancement of flexible electronics technology has placed higher demands on the structural design and performance regulation of elastic materials.Cellulosic elastomers,with their biodegradability,renewabilit...The rapid advancement of flexible electronics technology has placed higher demands on the structural design and performance regulation of elastic materials.Cellulosic elastomers,with their biodegradability,renewability,and tunability,emerge as ideal candidate materials.Entropy-driven self-as sembly promotes the spontaneous formation of ordered structures,serving as a crucial pathway for optimizing cellulose elastomer properties.However,the structure-property relationship between the self-assembled ordered structures of cellulose elastomers and their mechanical and electrical properties remains insufficiently explored.It hinders the expansion of their applications in electronic devices.This paper systematically reviews the structure-property regulation mechanisms of self-assembled cellulosic elastomers from an entropy-driven perspective.It elucidates the application principles and performance optimization strategies for mechanical energy harvesting and self-powered sensing,while also exploring the challenges and prospects for performance enhancement.This work provides a reference for the development of self-assembled cellulosic elastomers in the field of energy devices.展开更多
Advanced healthcare monitors for air pollution applications pose a significant challenge in achieving a balance between high-performance filtration and multifunctional smart integration.Electrospinning triboelectric n...Advanced healthcare monitors for air pollution applications pose a significant challenge in achieving a balance between high-performance filtration and multifunctional smart integration.Electrospinning triboelectric nanogenerators(TENG)provide a significant potential for use under such difficult circumstances.We have successfully constructed a high-performance TENG utilizing a novel multi-scale nanofiber architecture.Nylon 66(PA66)and chitosan quaternary ammonium salt(HACC)composites were prepared by electrospinning,and PA66/H multiscale nanofiber membranes composed of nanofibers(≈73 nm)and submicron-fibers(≈123 nm)were formed.PA66/H multi-scale nanofiber membrane as the positive electrode and negative electrode-spun PVDF-HFP nanofiber membrane composed of respiration-driven PVDF-HFP@PA66/H TENG.The resulting PVDF-HFP@PA66/H TENG based air filter utilizes electrostatic adsorption and physical interception mechanisms,achieving PM_(0.3)filtration efficiency over 99%with a pressure drop of only 48 Pa.Besides,PVDF-HFP@PA66/H TENG exhibits excellent stability in high-humidity environments,with filtration efficiency reduced by less than 1%.At the same time,the TENG achieves periodic contact separation through breathing drive to achieve self-power,which can ensure the long-term stability of the filtration efficiency.In addition to the air filtration function,TENG can also monitor health in real time by capturing human breathing signals without external power supply.This integrated system combines high-efficiency air filtration,self-powered operation,and health monitoring,presenting an innovative solution for air purification,smart protective equipment,and portable health monitoring.These findings highlight the potential of this technology for diverse applications,offering a promising direction for advancing multifunctional air filtration systems.展开更多
Ionogel,a novel flexible electronic material,presents a plethora of applications.Despite its potential,the fabrication of multifunctional ionogel with high-performance suitable for diverse scenarios remains a signific...Ionogel,a novel flexible electronic material,presents a plethora of applications.Despite its potential,the fabrication of multifunctional ionogel with high-performance suitable for diverse scenarios remains a significant challenge.In this study,we prepare a multifunctional amphibious ionogel skin(AIGS)using a polymerizable ionic liquid(PIL)and a conductive ionic liquid(IL)in conjunction with titanium carbide(Ti_(3)C_(2)T_(x)-MXene).The resulting soft AIGS materials exhibit ductility,self-healing,and robust adhesion in mechanical properties due to non-covalent interactions,such as ion-dipole interactions and hydrogen bonding.They also demonstrate a wide sensing range(2%-400%),high sensing sensitivity(gauge factor(GF)up to 6.06),and stable sensing performance(good reliability and stability after strain)in electrical properties.The hydrophobic and dynamic viscoelastic network formed by extensive C-F bonds in the used polymer matrix,ensures the AIGS's suitability for amphibious environments.We find that AIGS has excellent triboelectric properties.Utilizing AIGS as a flexible electrode,a single-electrode triboelectric nanogenerator(SE-TENG)was constructed,achieving outstanding output performance(~300 V open-circuit voltage,172 nA short-circuit current,and 34 nC transferred charge).This device can power commercial portable electronic devices and identify different body movements.AIGS-based wearable strain sensors have also been shown to reliably detect human motion,including larger limb movements such as finger flexion and elbow flexion and extension,as well as subtle muscle movements such as frowning and swallowing.In addition,depending on the characteristics of the AIGS application in amphibious environments,the following functions can be realized simultaneously.AIGS in an aquatic environment combined with machine learning for intelligent recognition of breathing type,in an underwater environment combined with Morse code to convey simple information,and motion monitoring in an amphibious environment,demonstrates its potential feasibility in a variety of situations.展开更多
Today,energy is essential for every aspect of human life,including clothing,food,housing and transportation.However,traditional energy resources are insufficient to meet our modern needs.Self-powered sensing devices e...Today,energy is essential for every aspect of human life,including clothing,food,housing and transportation.However,traditional energy resources are insufficient to meet our modern needs.Self-powered sensing devices emerge as promising alternatives,offering sustained operation without relying on external power sources.Leveraging advancements in materials and manufacturing research,these devices can autonomously harvest energy from various sources.In this review,we focus on the current landscape of self-powered wearable sensors,providing a concise overview of energy harvesting technologies,conversion mechanisms,structural or material innovations,and energy storage platforms.Then,we present experimental advances in different energy sources,showing their underlying mechanisms,and the potential for energy acquisition.Furthermore,we discuss the applications of self-powered flexible sensors in diverse fields such as medicine,sports,and food.Despite significant progress in this field,widespread commercialization will necessitate enhanced sensor detection abilities,improved design factors for adaptable devices,and a balance between sensitivity and standardization.展开更多
With the rapid advancement of optoelectronic technology,high-performance photodetectors are increasingly in demand in fields such as environmental monitoring,optical communication,and defense systems,where ultraviolet...With the rapid advancement of optoelectronic technology,high-performance photodetectors are increasingly in demand in fields such as environmental monitoring,optical communication,and defense systems,where ultraviolet detection is critical.However,conventional semiconductor materials suffer from limited UV-visible detection capabilities owing to their narrow bandgaps and high dark currents.To address these challenges,wide-bandgap semiconductors have emerged as promising alternatives.Here,we fabricated a horizontally structured n–n heterojunction photodetector by growingβ-Ga_(2)O_(3) on Si–GaN via plasma-enhanced chemical vapor deposition.The device exhibits a self-powered photocurrent of 3.5 nA at zero bias,enabled by the photovoltaic effect of the space charge region.Under 254-nm and 365-nm illumination,it exhibits rectification behavior,achieving a responsivity of 0.475 m A/W(0 V,220??W/cm~2 at 254 nm)and 257.6 mA/W(-5 V),respectively.Notably,the photodetector demonstrates a high photocurrent-to-dark current ratio of 10~5 under-5-V bias,highlighting its potential for self-powered and high-performance UV detection applications.展开更多
Quantitative determination of tetracycline(TC)in environment and foods is of great importance,as excessive residues might have negative effects on human health and environmental risks.Herein,a selfpowered molecularly ...Quantitative determination of tetracycline(TC)in environment and foods is of great importance,as excessive residues might have negative effects on human health and environmental risks.Herein,a selfpowered molecularly imprinted photoelectrochemical(PEC)sensor based on the Zn O/C photoanode and the Fe-doped CuBi_(2)O_(4)(CBFO)photocathode is developed for the sensitive detection of TC.The photocathodic current can be amplified by the efficient electron transfer caused by the Fermi energy level gap between the photoanode and photocathode.Furthermore,molecularly imprinted polymers(MIPs)at photocathode can selectivity identify the TC templates and thus improve the specificity.Under the optimal conditions,the sensor has a linear range of 10^(-2)-1.0×10^(5) nmol/L,and a limit of detection(LOD)of 0.007 nmol/L(S/N=3).More crucially,the milk sample detection is carried out using the as-prepared sensor,and the outcome is satisfactory.The research gives us a novel sensing platform for quick and accurate antibiotic(like TC)in environment and food monitoring.展开更多
Lip language provides a silent,intuitive,and efficient mode of communication,offering a promising solution for individuals with speech impairments.Its articulation relies on complex movements of the jaw and the muscle...Lip language provides a silent,intuitive,and efficient mode of communication,offering a promising solution for individuals with speech impairments.Its articulation relies on complex movements of the jaw and the muscles surrounding it.However,the accurate and real-time acquisition and decoding of these movements into reliable silent speech signals remains a significant challenge.In this work,we propose a real-time silent speech recognition system,which integrates a triboelectric nanogenerator-based flexible pressure sensor(FPS)with a deep learning framework.The FPS employs a porous pyramid-structured silicone film as the negative triboelectric layer,enabling highly sensitive pressure detection in the low-force regime(1 V N^(-1) for 0-10 N and 4.6 V N^(-1) for 10-24 N).This allows it to precisely capture jaw movements during speech and convert them into electrical signals.To decode the signals,we proposed a convolutional neural networklong short-term memory(CNN-LSTM)hybrid network,combining CNN and LSTM model to extract both local spatial features and temporal dynamics.The model achieved 95.83%classification accuracy in 30 categories of daily words.Furthermore,the decoded silent speech signals can be directly translated into executable commands for contactless and precise control of the smartphone.The system can also be connected to AR glasses,offering a novel human-machine interaction approach with promising potential in AR/VR applications.展开更多
This paper aims to study a novel smart self-powered wireless lightweight (SPWL) bridge health monitoring sensor, which integrates key technologies such as large-scale, low-power wireless data transmission, environment...This paper aims to study a novel smart self-powered wireless lightweight (SPWL) bridge health monitoring sensor, which integrates key technologies such as large-scale, low-power wireless data transmission, environmental energy self-harvesting, and intelligent perception, and can operate stably for a long time in complex and changing environments. The self-powered system of the sensor can meet the needs of long-term bridge service performance monitoring, significantly improving the coverage and efficiency of monitoring. By optimizing the sensor system design, the maximum energy conversion of the energy harvesting unit is achieved. In order to verify the function and practicality of the new SPWL monitoring sensor, this study combined the actual bridge engineering, carried out a bridge monitoring case study, and developed an SPWL monitoring scheme based on the bridge structure principle. Compared with traditional monitoring methods, this technology significantly improves the sustainability and performance of infrastructure monitoring based on the new SPWL sensor, fully demonstrating the excellent monitoring capabilities of this type of sensor, and providing strong support for the development of intelligent transportation and intelligent infrastructure.展开更多
Improving the response of sensors is often hindered by inadequate molding effects and complex manufacturing processes. Here, combining a simple magnetic-field-orientation and nano-imprinting process, a micropillar arr...Improving the response of sensors is often hindered by inadequate molding effects and complex manufacturing processes. Here, combining a simple magnetic-field-orientation and nano-imprinting process, a micropillar arrayed sensor was successfully fabricated, meanwhile, the boron nitride nanosheets (BNNS) were oriented in the polymer matrix. Due to the strain confinement effect, the outputted voltage of m-BNNS/PDMS composite film (SABNNS) demonstrated an improvement of 115.5% compared to the film sample with randomly dispersed nanoparticles. And the device showed a high sensitivity and rapid response capability to human motion. Furthermore, the oriented arrangement of m-BNNS and the enlarged heat dis-sipation area of the micropillar array contribute to the optimized thermal conductivity of the device.展开更多
Piezoelectric and triboelectric effects are of growing interest for facilitating high-sensitivity and self-powered tactile sensor applications.The working principles of piezoelectric and triboelectric nanogenerators p...Piezoelectric and triboelectric effects are of growing interest for facilitating high-sensitivity and self-powered tactile sensor applications.The working principles of piezoelectric and triboelectric nanogenerators provide strategies for enhancing output voltage signals to achieve high sensitivity.Increasing the piezoelectric constant and surface triboelectric charge density are key factors in this enhancement.Methods such as annealing processes,doping techniques,grain orientation controls,crystallinity controls,and composite structures can effectively enhance the piezoelectric constant.For increasing triboelectric output,surface plasma treatment,charge injection,microstructuring,control of dielectric constant,and structural modification are effective methods.The fabrication methods present significant opportunities in tactile sensor applications.This review article summarizes the overall piezoelectric and triboelectric fabrication processes from materials to device aspects.It highlights applications in pressure,touch,bending,texture,distance,and material recognition sensors.The conclusion section addresses challenges and research opportunities,such as limited flexibility,stretchability,decoupling from multi-stimuli,multifunctional sensors,and data processing.展开更多
基金National Natural Science Foundation of China(NSFC,No.22131008)Natural Science Foundation of Tianjin(No.22JCYBJC00500)the Haihe Laboratory of Sustainable Chemical Transformations for financial support.
文摘Possessing excellent mechanical properties,a high-coverage slide-ring conductive gel is constructed by in situ polymerization ofα-cyclodextrin(α-CD)polyrotaxane(PR)and 1-vinyl-3-ethylimidazolium bromide([VEIM]Br)ionic liquid(IL),using 1-ethyl-3-methylimidazolium bromide([EMIM]Br)IL as solvent.Benefiting from the compatibility of ILs and alkene-PR,the cross-linked network slide-ring gel not only maintains excellent conductivity(1.52×10^(−2) S/m),but also has effectively improved mechanical properties(513%fracture strain,0.713 MPa fracture stress,211 kPa elastic modulus and 1366 kJ/m^(3) toughness)and adhesive properties(472.3±25.9 kPa).The supramolecular gel can be used as a strain sensor to efficiently monitor deformation signals in real-time at least 200 times.Especially,the slide-ring gel can self-power generated by triboelectric effect and electrostatic induction between the skin layer and the polydimethylsiloxane(PDMS)layer that encapsulates the gel,achieving reversible and durable motion sensing,which provides a convenient pathway for constructing supramolecular self-powered flexible electronic materials.
文摘Yongtao Yu,Yuelin Yu et al.Solvent-Resistant Wearable Triboelectric Nanogenerator for Energy-Harvesting and Self-Powered Sensors.Energy Environ.Mater.2024,7,e12700.On page 4 of this article,the first paragraph of 2.4,line 14(PDF version,same below),there is a spelling mistake of“sui,”.It should be changed to“suitable”.The denominator“dt”in the Equation(3)should be changed to“dt”.
基金supported by the Start-Up Funds for Outstanding Talents in Central South University,China(Nos.202045007 and 202044017)the Open Sharing Fund for the Large-scale Instruments and Equipments of Central South University,China。
文摘Smart sensors are becoming one of the necessities for connecting and detecting surrounding stimuli with tremendous convenience, especially when exploiting a single powerful sensor with multifunctionality. To successfully accomplish the design of a self-powered sensor, serving power is becoming a critical issue because of its continuously consumed energy required by electronics. A variety of nanogenerators aiming for the rational design of self-powered system are reviewed and compared, followed by their recent advances with polymer nanocomposites for self-powered sensors. More importantly, the proposed conceptual design of a self-powered unit/device with triboelectric nanogenerator has been emphasized to eventually realize the practical activities towards multiple detections and human–machine interaction. Finally, challenges and new prospects of rational design of self-powered polymer composite sensors in achieving human–machine interaction/interface are discussed.
基金This work is financially supported by the basic research project of science and technology of Shanghai(No.20JC1415000)National Natural Science Foundation of China(Nos.11874257 and 52032012)the Fund for Science and Technology Innovation of Shanghai Jiao Tong University.
文摘For traditional piezoelectric sensors based on poled ceramics,a low curie tem-perature(T_(c))is a fatal flaw due to the depolarization phenomenon.However,in this study,we find the low T_(c) would be a benefit for flex-ible piezoelectric sensors because small alterations of force trig-ger large changes in polarization.BaTi_(0.88)Sn_(0.12)O_(3)(BTS)with high piezoelectric coefficient and low T_(c) close to human body temperature is taken as an example for materials of this kind.Continuous piezo-electric BTS films were deposited on the flexible glass fiber fabrics(GFF),self-powered sensors based on the ultra-thin,superflexible,and polarization-free BTS-GFF/PVDF composite piezoelectric films are used for human motion sensing.In the low force region(1-9 N),the sensors have the outstanding performance with voltage sensitivity of 1.23 V N^(−1) and current sensitivity of 41.0 nA N^(−1).The BTS-GFF/PVDF sensors can be used to detect the tiny forces of falling water drops,finger joint motion,tiny surface deformation,and fatigue driving with high sensitivity.This work provides a new paradigm for the preparation of superflexible,highly sensitive and wearable self-powered piezoelectric sensors,and this kind of sensors will have a broad application prospect in the fields of medical rehabilitation,human motion monitoring,and intelligent robot.
基金financially supported by the National Key R&D Project from Ministry of Science and Technology,China(2016YFA0202702,2016YFA0202701)the Key Research Program of Frontier Sciences,CAS(ZDBS-LY-DQC025)
文摘Flexible electronic sensors composed of flexible film and conductive materials play an increasingly important role in wearable and internet information transmission.It has received more and more attention and made some progress over the decades.However,it is still a great challenge to prepare biocompatible and highly transparent conductive films.Egg white is a pure natural protein-rich material.Hydroxypropylmethyl cellulose has a good compatibility and high transparency,which is an ideal material for flexible sensors.Here,we overcome the problem of poor mechanical flexibility and electrical conductivity of protein,and develop a high transparency and good flexibility hydroxypropylmethyl cellulose/egg white protein composite membrane-based triboelectric nanogenerator('X'-TENG).The experimental results show that the flexible pressure sensor based on'X'-TENG has a high sensitivity,fast response speed,and low detection limit.It can even be used as a touch/pressure sensing artificial electronic skin.It can also be made into an intelligent waffle keyboard for recording and tracking users of the keyboard.Our strategy may provide a new way to easily build flexible electronic sensors and move toward practical applications.
基金supported by the JSPS KAKENHI(Grant numbers JP20H00288 and JP22K02136)
文摘Wearable triboelectric nanogenerators(TENGs)have attracted attention owing to their ability to harvest energy from the surrounding environment without maintenance.Herein,polyetherimide-Al_(2)O_(3)(PAl)and polyvinylidene fluoride-co-hexafluoropropylene(PVDF-HFP,PH)nanofiber membranes were used as tribo-positive and tribo-negative materials,respectively.Phytic acid-doped polyaniline(PANI)/cotton fabric(PPCF)and ethylenediamine(EDA)-crosslinked PAl(EPAl)nanofiber membranes were used as triboelectrode and triboencapsulation materials,respectively.The result showed that when the PAl-PH-based TENG was shaped as a circle with a radius of 1 cm,under the pressure of 50 N,and the frequency of 0.5 Hz,the open-circuit voltage(V_(oc))and short-circuit current(I_(sc))reached the highest value of 66.6 V and-93.4 to 110.1 nA,respectively.Moreover,the PH-based TENG could be used as a fabric sensor to detect fabric composition and as a sensor-inductive switch for light bulbs or beeping warning devices.When the PAl-PH-based TENG was shaped as a 5×5 cm^(2)rectangle,a 33 pF capacitor could be charged to 15 V in 28 s.Interestingly,compared to PAl nanofiber membranes,EPAl nanofiber membranes exhibited good dyeing properties and excellent solvent resistance.The PPCF exhibited<5%resistance change after washing,bending,and stretching.
基金supported in part by the Science Foundation of Zhejiang Sci-Tech University(20200209-Y)。
文摘The rapid development of supercapacitors and wearable devices has allowed the construction of integrated self-powered wearable devices.However,most current research focuses on increasing supercapacitor capacity and the sensitivity of sensors,overlooking the self-powered and integration of one single device.In this study,the editable,flexible yarn-based supercapacitor(FYSC)and an integrated self-powered wearable sensor(SPWS)were constructed based on one yarn.The FYSC demonstrated adjustable capacitive behaviors by controlling the electrode reduction degree,electrode spaces,and integration.The supercapacitors exhibit a high specific capacitance of 1.82 F cm^(-3),92.57%capacity retention after 5000 cycles,and stable performance under static and dynamic strain conditions.Additionally,the integrated SPWSs demonstrated the accuracy and sensitivity in discriminating bending magnitudes.The SPWSs further present the accuracy and stability in recognizing human physiological activities(joint motions of finger,wrist,knee,and elbow,respiration,and handwriting).The proposed strategy offers a practical approach to developing energy storage systems with customizable functionality.More importantly,the self-powered devices realized the integration of supercapacitors and sensors would facilitate the seamless integration of 1D functional yarns into wearable electronics.
基金supported by the National Natural Science Foundation of China(Project no.51973120)the Natural Science Foun-dation of Guangdong Province(No.2019A1515010613)+1 种基金the Shenzhen Science and Technology Research Grant(Nos.JCYJ20170818093417096 and JCYJ20180305125649693)the Shenzhen Science and Technology Program(No.20220809111527001).
文摘Due to its ability to convert body heat into electricity,organic thermoelectric material is considered a promising and smart maintenance-free power source to charge wearable electronics.However,developing flexible n-type organic thermoelectric materials and wearable p/n junction thermoelectric devices remains challenging.In this work,two insulated polyamides(PA6 and PA66)that have been widely used as fiber materials are employed as novel dopants for converting p-type single-walled carbon nanotubes(SWCNTs)to n-type thermoelectric materials.Because of the electron transferability of the amide group,polyamide-doped SWCNTs exhibit excellent thermopower values as large as-56.0μV K^(-1) for PA66,and-54.5μV K^(-1) for PA6.Thermoelectric devices with five p/n junctions connected in series are fabricated.The testing device produces a thermoelectric voltage of 43.1 mV and generates 1.85μW thermoelectric power under temperature gradients of approximately 80 K.Furthermore,they display charming capability for temperature recognition and monitoring human activities as sensors.These promising results suggest that the flexible polyamide-doped SWCNT composites herein have high application potential as wearable thermoelectric electronics.
基金supported by the National Natural Science Foundation of China(52272177,12204010)the Foundation for the Introduction of High-Level Talents of Anhui University(S020118002/097)+1 种基金the University Synergy Innovation Program of Anhui Province(GXXT-2023-066)the Scientific Research Project of Anhui Provincial Higher Education Institution(2023AH040008)。
文摘Flexible electronics face critical challenges in achieving monolithic three-dimensional(3D)integration,including material compatibility,structural stability,and scalable fabrication methods.Inspired by the tactile sensing mechanism of the human skin,we have developed a flexible monolithic 3D-integrated tactile sensing system based on a holey MXene paste,where each vertical one-body unit simultaneously functions as a microsupercapacitor and pressure sensor.The in-plane mesopores of MXene significantly improve ion accessibility,mitigate the self-stacking of nanosheets,and allow the holey MXene to multifunctionally act as a sensing material,an active electrode,and a conductive interconnect,thus drastically reducing the interface mismatch and enhancing the mechanical robustness.Furthermore,we fabricate a large-scale device using a blade-coating and stamping method,which demonstrates excellent mechanical flexibility,low-power consumption,rapid response,and stable long-term operation.As a proof-of-concept application,we integrate our sensing array into a smart access control system,leveraging deep learning to accurately identify users based on their unique pressing behaviors.This study provides a promising approach for designing highly integrated,intelligent,and flexible electronic systems for advanced human-computer interactions and personalized electronics.
基金supported by the Key Research Program of Frontier Sciences,CAS,China(ZDBS-LY-DQC025)the Basic Scientific Research Project of the National Institute of Metrology,China(AKYZZ2449,AKYZZ2546).
文摘Natural polymers possess the qualities of abundant resources,low cost,as well as excellent biocompatibility and biodegradability,and are ideal materials for next-generation wearable and portable electronic devices.To further augment the application scope of natural polymer materials,integrating them with functional materials represents a promising approach that is of great value for the sustainable development of triboelectric nanogenerators.Here,we successfully synthesized starch-[CsPbBr_(3)-KBr]-Fe_(3)O_(4)composite films through the combination of natural polymer materials with magnetic and fluorescent components.It is capable of achieving reversible hydrochromic conversion by exposing or removing water.The combination of fluorescent CsPbBr_(3)-KBr,magnetic Fe_(3)O_(4),and waterproof starch-[CsPbBr_(3)-KBr]-Fe_(3)O_(4)-Polydimethylsiloxane leads to the realization of fluorescence and magnetic composite anti-counterfeiting.This composite anti-counterfeiting technology presents a novel and highly effective approach for ensuring the authenticity and security of various types of information.In addition,the Composite film based triboelectric nanogenerator has been assembled,which has a stable output with a short circuit current and open-circuit voltage of 15.1μA and 170.1 V,respectively.The triboelectric nanogenerator can light 204 red LED lights at the same time,and the electrical output is not reduced even after 4200 mechanical cycles.Furthermore,based on the triboelectric nanogenerator,we have successfully demonstrated a self-powered sensor that can monitor human movement signals in real time.The sensor has shown broad application prospects in the field of health monitoring and motion analysis.
基金supported by the National Natural Science Foundation of China(32571991)Guangxi Natural Science Foundation of China(2023GXNSFGA026001&2025GXNSFAA069870)the Foundation of State Key Laboratory of Biobased Material and Green Papermaking.(No.GZKF202323)。
文摘The rapid advancement of flexible electronics technology has placed higher demands on the structural design and performance regulation of elastic materials.Cellulosic elastomers,with their biodegradability,renewability,and tunability,emerge as ideal candidate materials.Entropy-driven self-as sembly promotes the spontaneous formation of ordered structures,serving as a crucial pathway for optimizing cellulose elastomer properties.However,the structure-property relationship between the self-assembled ordered structures of cellulose elastomers and their mechanical and electrical properties remains insufficiently explored.It hinders the expansion of their applications in electronic devices.This paper systematically reviews the structure-property regulation mechanisms of self-assembled cellulosic elastomers from an entropy-driven perspective.It elucidates the application principles and performance optimization strategies for mechanical energy harvesting and self-powered sensing,while also exploring the challenges and prospects for performance enhancement.This work provides a reference for the development of self-assembled cellulosic elastomers in the field of energy devices.
基金financial support from the National Key Research and Development Program of China(2022YFB3804905)National Natural Science Foundation of China(22375047,22378068,and 22378071)+1 种基金Natural Science Foundation of Fujian Province(2022J01568)111 Project(No.D17005).
文摘Advanced healthcare monitors for air pollution applications pose a significant challenge in achieving a balance between high-performance filtration and multifunctional smart integration.Electrospinning triboelectric nanogenerators(TENG)provide a significant potential for use under such difficult circumstances.We have successfully constructed a high-performance TENG utilizing a novel multi-scale nanofiber architecture.Nylon 66(PA66)and chitosan quaternary ammonium salt(HACC)composites were prepared by electrospinning,and PA66/H multiscale nanofiber membranes composed of nanofibers(≈73 nm)and submicron-fibers(≈123 nm)were formed.PA66/H multi-scale nanofiber membrane as the positive electrode and negative electrode-spun PVDF-HFP nanofiber membrane composed of respiration-driven PVDF-HFP@PA66/H TENG.The resulting PVDF-HFP@PA66/H TENG based air filter utilizes electrostatic adsorption and physical interception mechanisms,achieving PM_(0.3)filtration efficiency over 99%with a pressure drop of only 48 Pa.Besides,PVDF-HFP@PA66/H TENG exhibits excellent stability in high-humidity environments,with filtration efficiency reduced by less than 1%.At the same time,the TENG achieves periodic contact separation through breathing drive to achieve self-power,which can ensure the long-term stability of the filtration efficiency.In addition to the air filtration function,TENG can also monitor health in real time by capturing human breathing signals without external power supply.This integrated system combines high-efficiency air filtration,self-powered operation,and health monitoring,presenting an innovative solution for air purification,smart protective equipment,and portable health monitoring.These findings highlight the potential of this technology for diverse applications,offering a promising direction for advancing multifunctional air filtration systems.
基金Outstanding Talent in Tianjin(JC20230428)Young Scientific and Technological Talents(Level Three)in Tianjin(QN20230304)the National Key Research and Development Program of China(Grant Nos.AMMS-QNPY-2021-008,2021ZZKY02)。
文摘Ionogel,a novel flexible electronic material,presents a plethora of applications.Despite its potential,the fabrication of multifunctional ionogel with high-performance suitable for diverse scenarios remains a significant challenge.In this study,we prepare a multifunctional amphibious ionogel skin(AIGS)using a polymerizable ionic liquid(PIL)and a conductive ionic liquid(IL)in conjunction with titanium carbide(Ti_(3)C_(2)T_(x)-MXene).The resulting soft AIGS materials exhibit ductility,self-healing,and robust adhesion in mechanical properties due to non-covalent interactions,such as ion-dipole interactions and hydrogen bonding.They also demonstrate a wide sensing range(2%-400%),high sensing sensitivity(gauge factor(GF)up to 6.06),and stable sensing performance(good reliability and stability after strain)in electrical properties.The hydrophobic and dynamic viscoelastic network formed by extensive C-F bonds in the used polymer matrix,ensures the AIGS's suitability for amphibious environments.We find that AIGS has excellent triboelectric properties.Utilizing AIGS as a flexible electrode,a single-electrode triboelectric nanogenerator(SE-TENG)was constructed,achieving outstanding output performance(~300 V open-circuit voltage,172 nA short-circuit current,and 34 nC transferred charge).This device can power commercial portable electronic devices and identify different body movements.AIGS-based wearable strain sensors have also been shown to reliably detect human motion,including larger limb movements such as finger flexion and elbow flexion and extension,as well as subtle muscle movements such as frowning and swallowing.In addition,depending on the characteristics of the AIGS application in amphibious environments,the following functions can be realized simultaneously.AIGS in an aquatic environment combined with machine learning for intelligent recognition of breathing type,in an underwater environment combined with Morse code to convey simple information,and motion monitoring in an amphibious environment,demonstrates its potential feasibility in a variety of situations.
基金supported by the Shanghai Collaborative Innovation Centre for Tumour Energy Therapy Technology and Equipment。
文摘Today,energy is essential for every aspect of human life,including clothing,food,housing and transportation.However,traditional energy resources are insufficient to meet our modern needs.Self-powered sensing devices emerge as promising alternatives,offering sustained operation without relying on external power sources.Leveraging advancements in materials and manufacturing research,these devices can autonomously harvest energy from various sources.In this review,we focus on the current landscape of self-powered wearable sensors,providing a concise overview of energy harvesting technologies,conversion mechanisms,structural or material innovations,and energy storage platforms.Then,we present experimental advances in different energy sources,showing their underlying mechanisms,and the potential for energy acquisition.Furthermore,we discuss the applications of self-powered flexible sensors in diverse fields such as medicine,sports,and food.Despite significant progress in this field,widespread commercialization will necessitate enhanced sensor detection abilities,improved design factors for adaptable devices,and a balance between sensitivity and standardization.
基金Project supported by the Joints Fund of the National Natural Science Foundation of China(Grant No.U23A20349)the Young Scientists Fund of the National Natural Science Foundation of China(Grant Nos.62204126,62305171,62304113)。
文摘With the rapid advancement of optoelectronic technology,high-performance photodetectors are increasingly in demand in fields such as environmental monitoring,optical communication,and defense systems,where ultraviolet detection is critical.However,conventional semiconductor materials suffer from limited UV-visible detection capabilities owing to their narrow bandgaps and high dark currents.To address these challenges,wide-bandgap semiconductors have emerged as promising alternatives.Here,we fabricated a horizontally structured n–n heterojunction photodetector by growingβ-Ga_(2)O_(3) on Si–GaN via plasma-enhanced chemical vapor deposition.The device exhibits a self-powered photocurrent of 3.5 nA at zero bias,enabled by the photovoltaic effect of the space charge region.Under 254-nm and 365-nm illumination,it exhibits rectification behavior,achieving a responsivity of 0.475 m A/W(0 V,220??W/cm~2 at 254 nm)and 257.6 mA/W(-5 V),respectively.Notably,the photodetector demonstrates a high photocurrent-to-dark current ratio of 10~5 under-5-V bias,highlighting its potential for self-powered and high-performance UV detection applications.
基金supported by the Fuxiaquan Collaborative Innovation Platform(No.K30001)Major Scientific Research Program for Young and Middle-aged Health Professionals of Fujian Province,China(No.2022ZQNZD007)Youth Innovation Technology Project of Higher School in Shandong Province(Food Nanotechnology Innovation Team)。
文摘Quantitative determination of tetracycline(TC)in environment and foods is of great importance,as excessive residues might have negative effects on human health and environmental risks.Herein,a selfpowered molecularly imprinted photoelectrochemical(PEC)sensor based on the Zn O/C photoanode and the Fe-doped CuBi_(2)O_(4)(CBFO)photocathode is developed for the sensitive detection of TC.The photocathodic current can be amplified by the efficient electron transfer caused by the Fermi energy level gap between the photoanode and photocathode.Furthermore,molecularly imprinted polymers(MIPs)at photocathode can selectivity identify the TC templates and thus improve the specificity.Under the optimal conditions,the sensor has a linear range of 10^(-2)-1.0×10^(5) nmol/L,and a limit of detection(LOD)of 0.007 nmol/L(S/N=3).More crucially,the milk sample detection is carried out using the as-prepared sensor,and the outcome is satisfactory.The research gives us a novel sensing platform for quick and accurate antibiotic(like TC)in environment and food monitoring.
基金supported by the Natural Science Foundation of Fujian Province under Grant No.2024J010016Fujian Province Young and Middle aged Teacher Education Research Project No.JAT241317the Mindu Innovation Laboratory Project under Grant No.2020ZZ113.
文摘Lip language provides a silent,intuitive,and efficient mode of communication,offering a promising solution for individuals with speech impairments.Its articulation relies on complex movements of the jaw and the muscles surrounding it.However,the accurate and real-time acquisition and decoding of these movements into reliable silent speech signals remains a significant challenge.In this work,we propose a real-time silent speech recognition system,which integrates a triboelectric nanogenerator-based flexible pressure sensor(FPS)with a deep learning framework.The FPS employs a porous pyramid-structured silicone film as the negative triboelectric layer,enabling highly sensitive pressure detection in the low-force regime(1 V N^(-1) for 0-10 N and 4.6 V N^(-1) for 10-24 N).This allows it to precisely capture jaw movements during speech and convert them into electrical signals.To decode the signals,we proposed a convolutional neural networklong short-term memory(CNN-LSTM)hybrid network,combining CNN and LSTM model to extract both local spatial features and temporal dynamics.The model achieved 95.83%classification accuracy in 30 categories of daily words.Furthermore,the decoded silent speech signals can be directly translated into executable commands for contactless and precise control of the smartphone.The system can also be connected to AR glasses,offering a novel human-machine interaction approach with promising potential in AR/VR applications.
文摘This paper aims to study a novel smart self-powered wireless lightweight (SPWL) bridge health monitoring sensor, which integrates key technologies such as large-scale, low-power wireless data transmission, environmental energy self-harvesting, and intelligent perception, and can operate stably for a long time in complex and changing environments. The self-powered system of the sensor can meet the needs of long-term bridge service performance monitoring, significantly improving the coverage and efficiency of monitoring. By optimizing the sensor system design, the maximum energy conversion of the energy harvesting unit is achieved. In order to verify the function and practicality of the new SPWL monitoring sensor, this study combined the actual bridge engineering, carried out a bridge monitoring case study, and developed an SPWL monitoring scheme based on the bridge structure principle. Compared with traditional monitoring methods, this technology significantly improves the sustainability and performance of infrastructure monitoring based on the new SPWL sensor, fully demonstrating the excellent monitoring capabilities of this type of sensor, and providing strong support for the development of intelligent transportation and intelligent infrastructure.
基金supported by the National Natural Science Foundation of China(52175544 and 52172098)the Key R&D Program of Shannxi Province(2022GXLH-01-12,2023-GHZD-11 and 2023QCY-LL-26HZ)the Featured Research Base Project of Xi’an Science and Technology Bureau(23TSPT0001).
文摘Improving the response of sensors is often hindered by inadequate molding effects and complex manufacturing processes. Here, combining a simple magnetic-field-orientation and nano-imprinting process, a micropillar arrayed sensor was successfully fabricated, meanwhile, the boron nitride nanosheets (BNNS) were oriented in the polymer matrix. Due to the strain confinement effect, the outputted voltage of m-BNNS/PDMS composite film (SABNNS) demonstrated an improvement of 115.5% compared to the film sample with randomly dispersed nanoparticles. And the device showed a high sensitivity and rapid response capability to human motion. Furthermore, the oriented arrangement of m-BNNS and the enlarged heat dis-sipation area of the micropillar array contribute to the optimized thermal conductivity of the device.
基金supported by National Research Foundation of Korea(2022M3D1A2054488)Technology Innovation Program(20025736,Development of MICS SoC and platform for in-vivo implantable electroceutical device)funded by the Ministry of Trade,Industry&Energy(MOTIE,Korea)。
文摘Piezoelectric and triboelectric effects are of growing interest for facilitating high-sensitivity and self-powered tactile sensor applications.The working principles of piezoelectric and triboelectric nanogenerators provide strategies for enhancing output voltage signals to achieve high sensitivity.Increasing the piezoelectric constant and surface triboelectric charge density are key factors in this enhancement.Methods such as annealing processes,doping techniques,grain orientation controls,crystallinity controls,and composite structures can effectively enhance the piezoelectric constant.For increasing triboelectric output,surface plasma treatment,charge injection,microstructuring,control of dielectric constant,and structural modification are effective methods.The fabrication methods present significant opportunities in tactile sensor applications.This review article summarizes the overall piezoelectric and triboelectric fabrication processes from materials to device aspects.It highlights applications in pressure,touch,bending,texture,distance,and material recognition sensors.The conclusion section addresses challenges and research opportunities,such as limited flexibility,stretchability,decoupling from multi-stimuli,multifunctional sensors,and data processing.
