The accelerated decline of Arctic sea ice since the 1980s has paradoxically amplified greenhouse gas(GHG)emissions through increased shipping activities in this ecologically vulnerable region.This study investigates h...The accelerated decline of Arctic sea ice since the 1980s has paradoxically amplified greenhouse gas(GHG)emissions through increased shipping activities in this ecologically vulnerable region.This study investigates how to reconcile the decarbonization of Arctic shipping with conflicting environmental,economic,and geopolitical interests.Through systematic literature review and interest-balancing analysis,our findings identify three systemic barriers:(1)inadequate adaptation of International Maritime Organization(IMO)regulations to Arctic-specific environmental risks,(2)fragmented enforcement mechanisms among Arctic and non-Arctic States,and(3)technological limitations in clean fuel adoption for ice-class vessels.To address these challenges,a tripartite governance framework is proposed.First,legally binding amendments to International Convention for the Prevention of Pollution from Ships(MARPOL)Annex VI introducing Arctic-specific Energy Efficiency eXisting ship Index(EEXI)standards and extending energy efficiency regulations to fishing vessels.Second,a phased fuel transition prioritizing liquefied natural gas(LNG)and methanol,followed by hydrogen-ammonia synthetics.Third,enhanced multilateral cooperation through an Arctic Climate Shipping Alliance to coordinate joint research and development in cold-adapted technologies and ice-route optimization.By integrating United Nations Convention on the Law of the Sea(UNCLOS)obligations with IMO Polar Code implementation,this study advances a dynamic interest-balancing framework for policymakers,offering actionable pathways to achieve Paris Agreement targets while safeguarding Arctic ecosystems.展开更多
The contamination of wastewater with organic pollutants and nitrogen compounds poses significant environmental challenges.The primary objective of wastewater treatment is the simultaneous denitrification and decarboni...The contamination of wastewater with organic pollutants and nitrogen compounds poses significant environmental challenges.The primary objective of wastewater treatment is the simultaneous denitrification and decarbonization of ammonia nitrogen and organics into harmless by-products.This study presents a novel method for the directional generation of chlorine radical species like·ClO and·Cl using electro-reactive membranes(EMs)known as RuO_(2)@PbO_(2)-M,which were fabricated using an electro-deposition coupled template approach.This method facilitates the rapid and efficient conversion of ammonia to nitrogen and concurrently reduces the chemical oxygen demand in the effluent.Our system achieved ultra-efficient simultaneous denitrification and decarbonization with minimal energy consumption in single-filtration mode,thereby eliminating the need for chemical precursors.We elucidate the formation pathway of·ClO and·Cl during the electrochemical oxidation process involving RuO_(2)@PbO_(2)-M,where·Cl generated from RuO_(2)reacts with·OH from PbO_(2)under hypochlorous acid conditions,thereby enhancing nitrogen and carbon removal.These findings highlight a novel electro-filtration and an innovative reactive membrane design for·ClO synthesis,which provides a new research framework for the concurrent removal of nitrogen and carbon,and offers a promising solution to enhance wastewater treatment efficiency.展开更多
Developing low-carbon and efficient power systems is critical for energy security in the global warming context.We address this issue by focusing on the productivity impact of a decarbonization policy in China’s ther...Developing low-carbon and efficient power systems is critical for energy security in the global warming context.We address this issue by focusing on the productivity impact of a decarbonization policy in China’s thermal power sector—namely,the“Constructing Large Units and Restricting Small Ones”(CLRS)initiative.Utilizing a resource misallocation model,we construct a new theoretical framework to distinguish between technical and allocative efficiency and analyze productivity using plant-level data.The results indicate that the CLRS policy has significantly improved the allocative and technical efficiency of China’s coal-fired power sector,thereby ensuring power security.The closure of outdated and highly distorted small coal-fired units,which have been replaced by technologically advanced large units,primarily drives the enhanced efficiency.The policy’s effects are most pronounced in large-scale power plants and those with high coal combustion efficiency.Furthermore,a comparison of power plants’productivity distribution before and after policy implementation reveals that the CLRS policy not only enhances capital productivity in the coal-fired power sector but also increases rational labor allocation.Our findings have important policy implications for developing countries vis-à-vis building efficient and stable power systems amid climate change.展开更多
This study investigates the disparities in the deployment of photovoltaic(PV)technology for carbon emissions reduction across different nations,highlighting the mismatch between countries with high economic capacity a...This study investigates the disparities in the deployment of photovoltaic(PV)technology for carbon emissions reduction across different nations,highlighting the mismatch between countries with high economic capacity and those where PV installation would maximize global decarbonization benefits.This mismatch is discussed based on three key factors influencing decarbonization via PV technology:per capita gross domestic product;carbon intensity of the energy system;and solar resource availability.Current PV deployment is predominantly concentrated in economically advanced countries,and does not coincide with regions where the environmental and economic impact of such installations would be most significant.Through a series of thought experiments,it is demonstrated how alternative prioritization strategies could significantly reduce global carbon emissions.Argument is put forward for a globally coordinated approach to PV deployment,particularly targeting high-impact sunbelt regions,to enhance the efficacy of decarbonization efforts and promote equitable energy access.The study underscores the need for international policies that support sustainable energy transitions in economically less developed regions through workforce development and assistance with the activation of capital.展开更多
Decarbonising the building sector,particularly residential heating,represents a critical challenge for achieving carbon-neutral energy systems.Efficient solutions must integrate both technological performance and rene...Decarbonising the building sector,particularly residential heating,represents a critical challenge for achieving carbon-neutral energy systems.Efficient solutions must integrate both technological performance and renewable energy sources while considering operational constraints of existing systems.This study investigates a hybrid heating system combining a natural gas boiler(NGB)with an air-to-water heat pump(AWHP),evaluated through a combination of laboratory experiments and dynamic modelling.A prototype developed in the Electrical and Energy Engineering Laboratory enabled the characterization of both heat generators,the collection of experimental data,and the calibration of a MATLAB/Simulink model,including emissions and exhaust analyses.Sensitivity analyses were performed to identify optimal configurations for energy efficiency and system control,accounting for interactions between subsystems.Results highlight that hybridisation significantly improves primary energy efficiency and reduces fuel consumption compared to conventional NGB-only systems.Environmental performance,assessed through CO_(2) and NOx emissions and renewable energy integration,demonstrates the benefits of partial electrification in the residential sector.Economic assessment further quantifies decarbonization costs and fuel savings,illustrating tradeoffs between low-capital,moderate-performance systems and high-efficiency,high-renewable solutions requiring larger investments.The analysis shows that strategic decisions for residential decarbonisation cannot be separated from system-wide considerations,including control strategies,component integration,and economic feasibility.The study underlines the importance of hybrid and renewable-based solutions as pivotal pathways for energy transition in the residential building sector.展开更多
In order to reveal the nonlinear dynamics characteristics of unsteady self-heating process of sulfide ores, nine different kinds of sulfide ore samples from a pyrite mine in China were taken as experimental materials ...In order to reveal the nonlinear dynamics characteristics of unsteady self-heating process of sulfide ores, nine different kinds of sulfide ore samples from a pyrite mine in China were taken as experimental materials and their self-heating characteristics were measured in laboratory. Furthermore, the measured temperature was studied by integrating wavelet transform, nonlinear characteristic parameters extraction and fuzzy comprehensive evaluation. The results indicate that only the ore samples 1, 2, 6 and 9 have obvious self-heating phenomenon, and their self-heating initiative temperatures are 220 ℃, 239 ℃, 220 ℃ and 220 ℃, respectively, which means that they are difficult to produce self-heating under normal mining conditions. The correlation dimension of self-heating process is fraction and the maximum Lyapunov exponent is positive, which means that it is feasible to study the self-heating process based on chaotic dynamics theory. The nonlinearities of self-heating process of these four samples （ore samples 1, 2, 6 and 9） are 0.8227, 0.7521, 0.9401 and 0.8827 respectively and the order of the samples according to these results is： sample 6, sample 9, sample 1, sample 2, which is consistent with the measured results of self-heating characteristics. Therefore, the nonlinearity method can be used to evaluate the self-heating tendency of sulfide ores, and it is an effective verification of the reliability of measured results.展开更多
A crystalline sapphire （Al2O3） boule （Ф10 × 80mm^3） grown by the temperature gradient technique （TGT） is a bit colored due to carbon volatilization from the graphite heater at high temperatures and the abs...A crystalline sapphire （Al2O3） boule （Ф10 × 80mm^3） grown by the temperature gradient technique （TGT） is a bit colored due to carbon volatilization from the graphite heater at high temperatures and the absorption of transitional metal inclusions in the raw material. The sapphire becomes colorless and transparent after decolorization and decarbonization in successive annealings in air and hydrogen at high temperatures. The quality, optical transmissivity,and homogeneity of the sapphire are remarkably improved.展开更多
On the basis of understanding the principle of rotary triboelectrostatic separation, dynamic analysis of charged fly ash particles aimed at determining the key factors and separation experiments to improve decarboniza...On the basis of understanding the principle of rotary triboelectrostatic separation, dynamic analysis of charged fly ash particles aimed at determining the key factors and separation experiments to improve decarbonization efficiency had been carried out Variables of electrode plate voltage and corrected wind speed are the key factors which affect the decarbonization efficiency on the separation of fly ash, The results of separation experiments show that:(1) With the plate voltage increasing, the efficiency of decarbonization continuously rises and in its selected range, the optimal voltage level is 45 KV;(2) The corrected wind speed can impact the efficiency of decarbonization significantly: with the speed increasing, the efficiency of decarbonization shows a trend of first decline, then increase and decrease again, and in its selected range, the optimal speed is 2.0 m/s. This study is of significance for the improvement of rotary triboelectrostatic separation performance and its decarbonization separation efficiency.展开更多
The basic principle of fly ash triboelectrification is analysed. The mineral electrical index and test method are introduced. The electric difference of different mineral composition of fly ash is discussed by analysi...The basic principle of fly ash triboelectrification is analysed. The mineral electrical index and test method are introduced. The electric difference of different mineral composition of fly ash is discussed by analysis of chemical and mineral composition of fly ash in Xinwen power plant. The dielectric constant and charge-mass ratio of carbon and ash of fly ash are tested. Combined with the experimental study on rotary triboelectrostatic separation, the charged characteristic of fly ash particles with different size is gained. The results show that the dielectric constant of fly ash with different grain size decreased with the decrease of particle size, which lead to the poor electrical conductivity, Thus it can be seen that par- ticle size plays a leading role in conductivity, The charge of carbon and ash with each size increased with the decreased of particle size; and the charge-mass ratio between carbon and ash with the same size lar- ger with the decrease of size, which indicated that the finer particle size, the more favorable for triboelec- trification separation. In the same conditions, the best decarburization effect is realized when the particle size ranges from 0.038 to 0.074 ram, whose decarbonization rate and efficiency index reached 38.93% and 120.83% respectively.展开更多
For exploiting advantages of electron beam air plasma in some unusual applications, a Monte Carlo （MC） model coupled with heat transfer model is established to simulate the characteristics of electron beam air plasm...For exploiting advantages of electron beam air plasma in some unusual applications, a Monte Carlo （MC） model coupled with heat transfer model is established to simulate the characteristics of electron beam air plasma by considering the self-heating effect. Based on the model, the electron beam induced temperature field and the related plasma properties are investigated. The results indicate that a nonuniform temperature field is formed in the electron beam plasma region and the average temperature is of the order of 600 K. Moreover, much larger volume pear-shaped electron beam plasma is produced in hot state rather than in cold state. The beam ranges can, with beam energies of 75 keV and 80 keV, exceed 1.0 m and 1.2 m in air at pressure of 100 torr, respectively. Finally, a well verified formula is obtained for calculating the range of high energy electron beam in atmosphere.展开更多
To obtain intrinsic overcharge boundary and investigate overcharge mechanism,here we propose an innovative method,the step overcharge test,to reduce the thermal crossover and distinguish the overcharge thermal behavio...To obtain intrinsic overcharge boundary and investigate overcharge mechanism,here we propose an innovative method,the step overcharge test,to reduce the thermal crossover and distinguish the overcharge thermal behavior,including 5%state of charge(SOC)with small current overcharge and resting until the temperature equilibrium under adiabatic conditions.The intrinsic thermal response and the self-excitation behaviour are analysed through temperature and voltage changes during the step overcharge period.Experimental results show that the deintercalated state of the cathode is highly correlated to self-heating parasitic reactions.Before reaching the upper limit of Negative/Positive(N/P)ratio,the temperature changes little,the heat generation is significantly induced by the reversible heat(endothermic)and ohmic heat,which could balance each other.Following that the lithium metal is gradually deposited on the surface of the anode and reacts with electrolyte upon overcharge,inducing selfheating side reaction.However,this spontaneous thermal reaction could be“self-extinguished”.When the lithium in cathode is completely deintercalated,the boundary point of overcharge is about 4.7 V(~148%SOC,>40℃),and from this point,the self-heating behaviour could be continuously triggered until thermal runaway(TR)without additional overcharge.The whole static and spontaneous process lasts for 115 h and the side reaction heat is beyond 320,000 J.The continuous self-excitation behavior inside the battery is attributed to the interaction between the highly oxidized cathode and the solvent,which leads to the dissolution of metal ions.The dissolved metal ions destroy the SEI(solid electrolyte interphase)film on the surface of the deposited Li of anode,which induces the thermal reaction between lithium metal and the solvent.The interaction between cathode,the deposited Li of anode,and solvent promotes the temperature of the battery to rise slowly.When the temperature of the battery reaches more than 60℃,the reaction between lithium metal and solvent is accelerated.After the temperature rises rapidly to the melting point of the separator,it triggers the thermal runaway of the battery due to the short circuit of the battery.展开更多
Original surface chemistry of sulphidesis altered upon contact with air, leading to ''oxidation'', which is accompanied by evolution of heat. The current study reports results of an investigation on ex...Original surface chemistry of sulphidesis altered upon contact with air, leading to ''oxidation'', which is accompanied by evolution of heat. The current study reports results of an investigation on extent of exothermicity of an experimental nickel-copper sulphide stockpile that was formed at a mining site in Sudbury, Canada. The ore contained pentlandite and chalcopyrite that are accompanied by a large quantity of pyrrhotite. The self-heating characteristics were recorded by temperature sensors placed inside the stockpile. Ambient conditions such as temperature, humidity, and wind velocity were simultaneously recorded. The inner temperature of the stockpile indicated significant fluctuations due to rapid changes, particularly in the outside temperature. The minimum and maximum temperatures recorded in the outside and inside were 5 and 10.5, 44.3 and 32 ℃, respectively. The self-heating capacity of the sulphide ore stockpile observed represents a mild case compared to that experienced by coals. Possible reasons are discussed.展开更多
Climate change is becoming an important issue in all fields of infrastructure development.Electricity plays a core role in the decarbonized energy system’s path to a regional zero-emission pattern.A well-built trans-...Climate change is becoming an important issue in all fields of infrastructure development.Electricity plays a core role in the decarbonized energy system’s path to a regional zero-emission pattern.A well-built trans-Mediterranean backbone grid can hedge the profound evolution of regional power generation,transmission,and consumption.To date,only Turkey and the Maghreb countries(i.e.,Morocco,Algeria,and Tunisia)are connected with the Continental European Synchronous Area.Other south-and east-shore countries have insufficient interconnection infrastructures and synchronization difficulties that have proven to be major hurdles to the implementation of large-scale solar and wind projects and achievement of climate goals.This study analyzes the current trans-boundary grid interconnections and power and carbon emission portfolios in the Mediterranean region.To align with the recently launched new climate target‘Fit for 55’program and the accelerated large-scale renewables target,a holistic review of projected trans-Mediterranean grids and their market,technical,and financial obstacles of implementation was conducted.For south-and east-shore countries,major legal and regulatory barriers encompassing non-liberalized market structure,regulation gaps of taxation and transmission tariffs,and the private sector’s access rights need to be removed.Enhancement of domestic grids,substations,and harmonized grid codes and frequency,voltage,and communication technology standards among all trans-Mediterranean countries are physical prerequisites for implementing the Trans-Mediterranean Electricity Market.In addition,the mobilization of capital instruments along with private and international investments is indispensable for the realization of supranational transmission projects.As the final section of the decarbonization roadmap,the development of electric appliances,equipment,and vehicles with higher efficiency is inevitable in the decarbonized building,transportation,and industry sectors.展开更多
Decarbonization is a critical issue for peaking CO_(2) emissions of energy-intensive industries,such as the iron and steel industry.The decarbonization options of China’s ironmaking and steelmaking sector were discus...Decarbonization is a critical issue for peaking CO_(2) emissions of energy-intensive industries,such as the iron and steel industry.The decarbonization options of China’s ironmaking and steelmaking sector were discussed based on a systematic three-dimensional low-carbon analysis from the aspects of resource utilization(Y),energy utilization(Q),and energy cleanliness which is evaluated by a process general emission factor(PGEF)on all the related processes,including the current blast furnace(BF)-basic oxygen furnace(BOF)integrated process and the specific sub-processes,as well as the electric arc furnace(EAF)process,typical direct reduction(DR)process,and smelting reduction(SR)process.The study indicates that the three-dimensional aspects,particularly the energy structure,should be comprehensively considered to quantitatively evaluate the decarbonization road map based on novel technologies or processes.Promoting scrap utilization(improvement of Y)and the substitution of carbon-based energy(improvement of PGEF)in particular is critical.In terms of process scale,promoting the development of the scrap-based EAF or DR-EAF process is highly encouraged because of their lower PGEF.The three-dimensional method is expected to extend to other processes or industries,such as the cement production and thermal electricity generation industries.展开更多
The self-heating effect severely limits device performance and reliability.Although some studies have revealed the heat distribution ofβ-Ga_(2)O_(3) MOSFETs under biases,those devices all have small areas and have di...The self-heating effect severely limits device performance and reliability.Although some studies have revealed the heat distribution ofβ-Ga_(2)O_(3) MOSFETs under biases,those devices all have small areas and have difficulty reflecting practical con-ditions.This work demonstrated a multi-fingerβ-Ga_(2)O_(3) MOSFET with a maximum drain current of 0.5 A.Electrical characteris-tics were measured,and the heat dissipation of the device was investigated through infrared images.The relationship between device temperature and time/bias is analyzed.展开更多
CFD models have been developed to investigate the Iongwall goaf gas flow patternsunder different mining and geological control conditions.The Iongwall goaf wastreated as porous regions and gas flow was modelled as a m...CFD models have been developed to investigate the Iongwall goaf gas flow patternsunder different mining and geological control conditions.The Iongwall goaf wastreated as porous regions and gas flow was modelled as a momentum sink added to themomentum equation.Gas desorption from the caved goaf and destressed coal seamswithin the mining disturbed area was modelled as additional mass sources in the continuityequation.These CFD models were developed according to specific Iongwall layoutsand calibrated against field monitoring data.Two case studies were presented demonstratingthe application of CFD modelling of goaf gas flow characteristics for improved goafgas capture and the reduction of oxygen ingress into the goaf areas for self-heating prevention.Results from the case studies indicate that the optimum goaf drainage strategywould be a combination of shallow (near the face) and deep holes to improve the overalldrainage efficiency and gas purity.For gassy Iongwall faces retreating against the seam dip,it is recommended to conduct cross-measure roof hole drainage targeting the fracturedzones overlying the return corner,rather than high capacity surface goaf drainage deep inthe goaf.展开更多
A thermal model of 4H-SiC MESFET is developed based on the temperature dependences of material parameters and three-region I - V model. The static current characteristics of 4H-SiC MESFET have been obtained with the c...A thermal model of 4H-SiC MESFET is developed based on the temperature dependences of material parameters and three-region I - V model. The static current characteristics of 4H-SiC MESFET have been obtained with the consideration of the self-heating effect on related parameters including electron mobility, saturation velocity and thermal conductivity. High voltage performances are analysed using equivalent thermal conductivity model. Using the physicalbased simulations, we studied the dependence of self-heating temperature on the thickness and doping of substrate. The obtained results can be used for optimization of the thermal design of the SiC-based high-power field effect transistors.展开更多
Self-heating effect in amorphous InGaZnO thin-film transistors remains a critical issue that degrades device performance and stability, hindering their wider applications. In this work, pulsed current–voltage analysi...Self-heating effect in amorphous InGaZnO thin-film transistors remains a critical issue that degrades device performance and stability, hindering their wider applications. In this work, pulsed current–voltage analysis has been applied to explore the physics origin of self-heating induced degradation, where Joule heat is shortly accumulated by drain current and dissipated in repeated time cycles as a function of gate bias. Enhanced positive threshold voltage shift is observed at reduced heat dissipation time, higher drain current, and increased gate width. A physical picture of Joule heating assisted charge trapping process has been proposed and then verified with pulsed negative gate bias stressing scheme, which could evidently counteract the self-heating effect through the electric-field assisted detrapping process. As a result, this pulsed gate bias scheme with negative quiescent voltage could be used as a possible way to actively suppress self-heating related device degradation.展开更多
Dynamic self-heating effect(SHE)of silicon-on-insulator(SOI)MOSFET is comprehensively evaluated by ultrafast pulsed I-V measurement in this work.It is found for the first time that the SHE complete heating response an...Dynamic self-heating effect(SHE)of silicon-on-insulator(SOI)MOSFET is comprehensively evaluated by ultrafast pulsed I-V measurement in this work.It is found for the first time that the SHE complete heating response and cooling response of SOI MOSFETs are conjugated,with two-stage curves shown.We establish the effective thermal transient response model with stage superposition corresponding to the heating process.The systematic study of SHE dependence on workload shows that frequency and duty cycle have more significant effect on SHE in first-stage heating process than in the second stage.In the first-stage heating process,the peak lattice temperature and current oscillation amplitude decrease by more than 25 K and 4%with frequency increasing to 10 MHz,and when duty cycle is reduced to 25%,the peak lattice temperature drops to 306 K and current oscillation amplitude decreases to 0.77%.Finally,the investigation of two-stage(heating and cooling)process provides a guideline for the unified optimization of dynamic SHE in terms of workload.As the operating frequency is raised to GHz,the peak temperature depends on duty cycle,and self-heating oscillation is completely suppressed.展开更多
The influence of self-heating on the millimeter-wave(mm-wave)and terahertz(THz)performance of double-drift region(DDR)impact avalanche transit time(IMPATT)sources based on silicon(Si)has been investigated in this pape...The influence of self-heating on the millimeter-wave(mm-wave)and terahertz(THz)performance of double-drift region(DDR)impact avalanche transit time(IMPATT)sources based on silicon(Si)has been investigated in this paper.The dependences of static and large-signal parameters on junction temperature are estimated using a non-sinusoidal voltage excited(NSVE)large-signal simulation technique developed by the authors,which is based on the quantum-corrected drift-diffusion(QCDD)model.Linear variations of static parameters and non-linear variations of large-signal parameters with temperature have been observed.Analytical expressions representing the temperature dependences of static and large-signal parameters of the diodes are developed using linear and 2nd degree polynomial curve fitting techniques,which will be highly useful for optimizing the thermal design of the oscillators.Finally,the simulated results are found to be in close agreement with the experimentally measured data.展开更多
基金supported by the Major Research Projects of the National Social Science Fund of China(NSFC,Grant no.23VHQ015).
文摘The accelerated decline of Arctic sea ice since the 1980s has paradoxically amplified greenhouse gas(GHG)emissions through increased shipping activities in this ecologically vulnerable region.This study investigates how to reconcile the decarbonization of Arctic shipping with conflicting environmental,economic,and geopolitical interests.Through systematic literature review and interest-balancing analysis,our findings identify three systemic barriers:(1)inadequate adaptation of International Maritime Organization(IMO)regulations to Arctic-specific environmental risks,(2)fragmented enforcement mechanisms among Arctic and non-Arctic States,and(3)technological limitations in clean fuel adoption for ice-class vessels.To address these challenges,a tripartite governance framework is proposed.First,legally binding amendments to International Convention for the Prevention of Pollution from Ships(MARPOL)Annex VI introducing Arctic-specific Energy Efficiency eXisting ship Index(EEXI)standards and extending energy efficiency regulations to fishing vessels.Second,a phased fuel transition prioritizing liquefied natural gas(LNG)and methanol,followed by hydrogen-ammonia synthetics.Third,enhanced multilateral cooperation through an Arctic Climate Shipping Alliance to coordinate joint research and development in cold-adapted technologies and ice-route optimization.By integrating United Nations Convention on the Law of the Sea(UNCLOS)obligations with IMO Polar Code implementation,this study advances a dynamic interest-balancing framework for policymakers,offering actionable pathways to achieve Paris Agreement targets while safeguarding Arctic ecosystems.
基金supported by the National Natural Science Foundation of China(52270043)the National Key Research and Development Program of China(2023YFE0113800 and 2024YFC3715000)the Natural Science Foundation of Beijing Municipality(8242030).
文摘The contamination of wastewater with organic pollutants and nitrogen compounds poses significant environmental challenges.The primary objective of wastewater treatment is the simultaneous denitrification and decarbonization of ammonia nitrogen and organics into harmless by-products.This study presents a novel method for the directional generation of chlorine radical species like·ClO and·Cl using electro-reactive membranes(EMs)known as RuO_(2)@PbO_(2)-M,which were fabricated using an electro-deposition coupled template approach.This method facilitates the rapid and efficient conversion of ammonia to nitrogen and concurrently reduces the chemical oxygen demand in the effluent.Our system achieved ultra-efficient simultaneous denitrification and decarbonization with minimal energy consumption in single-filtration mode,thereby eliminating the need for chemical precursors.We elucidate the formation pathway of·ClO and·Cl during the electrochemical oxidation process involving RuO_(2)@PbO_(2)-M,where·Cl generated from RuO_(2)reacts with·OH from PbO_(2)under hypochlorous acid conditions,thereby enhancing nitrogen and carbon removal.These findings highlight a novel electro-filtration and an innovative reactive membrane design for·ClO synthesis,which provides a new research framework for the concurrent removal of nitrogen and carbon,and offers a promising solution to enhance wastewater treatment efficiency.
基金supported by the Chengdu Philosophy and Social Science Planning Project[Grant No.2022C05]National Natural Science Foundation of China[Grant No.71904158].
文摘Developing low-carbon and efficient power systems is critical for energy security in the global warming context.We address this issue by focusing on the productivity impact of a decarbonization policy in China’s thermal power sector—namely,the“Constructing Large Units and Restricting Small Ones”(CLRS)initiative.Utilizing a resource misallocation model,we construct a new theoretical framework to distinguish between technical and allocative efficiency and analyze productivity using plant-level data.The results indicate that the CLRS policy has significantly improved the allocative and technical efficiency of China’s coal-fired power sector,thereby ensuring power security.The closure of outdated and highly distorted small coal-fired units,which have been replaced by technologically advanced large units,primarily drives the enhanced efficiency.The policy’s effects are most pronounced in large-scale power plants and those with high coal combustion efficiency.Furthermore,a comparison of power plants’productivity distribution before and after policy implementation reveals that the CLRS policy not only enhances capital productivity in the coal-fired power sector but also increases rational labor allocation.Our findings have important policy implications for developing countries vis-à-vis building efficient and stable power systems amid climate change.
基金supported by the Helmholtz Association within the framework of the innovation platform“Solar TAP”[Az:714-62150-3/1(2023)]co-funded by the European Union(ERC,C2C-PV,project number 101088359)。
文摘This study investigates the disparities in the deployment of photovoltaic(PV)technology for carbon emissions reduction across different nations,highlighting the mismatch between countries with high economic capacity and those where PV installation would maximize global decarbonization benefits.This mismatch is discussed based on three key factors influencing decarbonization via PV technology:per capita gross domestic product;carbon intensity of the energy system;and solar resource availability.Current PV deployment is predominantly concentrated in economically advanced countries,and does not coincide with regions where the environmental and economic impact of such installations would be most significant.Through a series of thought experiments,it is demonstrated how alternative prioritization strategies could significantly reduce global carbon emissions.Argument is put forward for a globally coordinated approach to PV deployment,particularly targeting high-impact sunbelt regions,to enhance the efficacy of decarbonization efforts and promote equitable energy access.The study underscores the need for international policies that support sustainable energy transitions in economically less developed regions through workforce development and assistance with the activation of capital.
基金supported by European Commission and is a part of the HORIZON2020 project RES Heatfunding from the European Union’s Horizon 2020 program in the field of research and innovation on the basis of grant agreement No.956255.
文摘Decarbonising the building sector,particularly residential heating,represents a critical challenge for achieving carbon-neutral energy systems.Efficient solutions must integrate both technological performance and renewable energy sources while considering operational constraints of existing systems.This study investigates a hybrid heating system combining a natural gas boiler(NGB)with an air-to-water heat pump(AWHP),evaluated through a combination of laboratory experiments and dynamic modelling.A prototype developed in the Electrical and Energy Engineering Laboratory enabled the characterization of both heat generators,the collection of experimental data,and the calibration of a MATLAB/Simulink model,including emissions and exhaust analyses.Sensitivity analyses were performed to identify optimal configurations for energy efficiency and system control,accounting for interactions between subsystems.Results highlight that hybridisation significantly improves primary energy efficiency and reduces fuel consumption compared to conventional NGB-only systems.Environmental performance,assessed through CO_(2) and NOx emissions and renewable energy integration,demonstrates the benefits of partial electrification in the residential sector.Economic assessment further quantifies decarbonization costs and fuel savings,illustrating tradeoffs between low-capital,moderate-performance systems and high-efficiency,high-renewable solutions requiring larger investments.The analysis shows that strategic decisions for residential decarbonisation cannot be separated from system-wide considerations,including control strategies,component integration,and economic feasibility.The study underlines the importance of hybrid and renewable-based solutions as pivotal pathways for energy transition in the residential building sector.
基金Project(51304238)supported by the National Natural Science Foundation of ChinaProject(JSK200206)supported by the Foundation of Key Laboratory of Mine Thermo-motive Disaster and Prevention,Ministry of Education,China
文摘In order to reveal the nonlinear dynamics characteristics of unsteady self-heating process of sulfide ores, nine different kinds of sulfide ore samples from a pyrite mine in China were taken as experimental materials and their self-heating characteristics were measured in laboratory. Furthermore, the measured temperature was studied by integrating wavelet transform, nonlinear characteristic parameters extraction and fuzzy comprehensive evaluation. The results indicate that only the ore samples 1, 2, 6 and 9 have obvious self-heating phenomenon, and their self-heating initiative temperatures are 220 ℃, 239 ℃, 220 ℃ and 220 ℃, respectively, which means that they are difficult to produce self-heating under normal mining conditions. The correlation dimension of self-heating process is fraction and the maximum Lyapunov exponent is positive, which means that it is feasible to study the self-heating process based on chaotic dynamics theory. The nonlinearities of self-heating process of these four samples （ore samples 1, 2, 6 and 9） are 0.8227, 0.7521, 0.9401 and 0.8827 respectively and the order of the samples according to these results is： sample 6, sample 9, sample 1, sample 2, which is consistent with the measured results of self-heating characteristics. Therefore, the nonlinearity method can be used to evaluate the self-heating tendency of sulfide ores, and it is an effective verification of the reliability of measured results.
文摘A crystalline sapphire （Al2O3） boule （Ф10 × 80mm^3） grown by the temperature gradient technique （TGT） is a bit colored due to carbon volatilization from the graphite heater at high temperatures and the absorption of transitional metal inclusions in the raw material. The sapphire becomes colorless and transparent after decolorization and decarbonization in successive annealings in air and hydrogen at high temperatures. The quality, optical transmissivity,and homogeneity of the sapphire are remarkably improved.
基金provided by the National Natural Science Foundation of China(No.51274200)Research Fund for the Doctoral Program of Higher Education of China(No.20130095110010)
文摘On the basis of understanding the principle of rotary triboelectrostatic separation, dynamic analysis of charged fly ash particles aimed at determining the key factors and separation experiments to improve decarbonization efficiency had been carried out Variables of electrode plate voltage and corrected wind speed are the key factors which affect the decarbonization efficiency on the separation of fly ash, The results of separation experiments show that:(1) With the plate voltage increasing, the efficiency of decarbonization continuously rises and in its selected range, the optimal voltage level is 45 KV;(2) The corrected wind speed can impact the efficiency of decarbonization significantly: with the speed increasing, the efficiency of decarbonization shows a trend of first decline, then increase and decrease again, and in its selected range, the optimal speed is 2.0 m/s. This study is of significance for the improvement of rotary triboelectrostatic separation performance and its decarbonization separation efficiency.
基金supported by the National Natural Science Foundation of China(Nos.51274200 and 51221462)
文摘The basic principle of fly ash triboelectrification is analysed. The mineral electrical index and test method are introduced. The electric difference of different mineral composition of fly ash is discussed by analysis of chemical and mineral composition of fly ash in Xinwen power plant. The dielectric constant and charge-mass ratio of carbon and ash of fly ash are tested. Combined with the experimental study on rotary triboelectrostatic separation, the charged characteristic of fly ash particles with different size is gained. The results show that the dielectric constant of fly ash with different grain size decreased with the decrease of particle size, which lead to the poor electrical conductivity, Thus it can be seen that par- ticle size plays a leading role in conductivity, The charge of carbon and ash with each size increased with the decreased of particle size; and the charge-mass ratio between carbon and ash with the same size lar- ger with the decrease of size, which indicated that the finer particle size, the more favorable for triboelec- trification separation. In the same conditions, the best decarburization effect is realized when the particle size ranges from 0.038 to 0.074 ram, whose decarbonization rate and efficiency index reached 38.93% and 120.83% respectively.
基金supported by National Natural Science Foundation of China (No.10905044)
文摘For exploiting advantages of electron beam air plasma in some unusual applications, a Monte Carlo （MC） model coupled with heat transfer model is established to simulate the characteristics of electron beam air plasma by considering the self-heating effect. Based on the model, the electron beam induced temperature field and the related plasma properties are investigated. The results indicate that a nonuniform temperature field is formed in the electron beam plasma region and the average temperature is of the order of 600 K. Moreover, much larger volume pear-shaped electron beam plasma is produced in hot state rather than in cold state. The beam ranges can, with beam energies of 75 keV and 80 keV, exceed 1.0 m and 1.2 m in air at pressure of 100 torr, respectively. Finally, a well verified formula is obtained for calculating the range of high energy electron beam in atmosphere.
基金funded by the National Key Research and Development Program of China(2018YFB0104400)supported by the Beijing Natural Science Foundation(2214066)。
文摘To obtain intrinsic overcharge boundary and investigate overcharge mechanism,here we propose an innovative method,the step overcharge test,to reduce the thermal crossover and distinguish the overcharge thermal behavior,including 5%state of charge(SOC)with small current overcharge and resting until the temperature equilibrium under adiabatic conditions.The intrinsic thermal response and the self-excitation behaviour are analysed through temperature and voltage changes during the step overcharge period.Experimental results show that the deintercalated state of the cathode is highly correlated to self-heating parasitic reactions.Before reaching the upper limit of Negative/Positive(N/P)ratio,the temperature changes little,the heat generation is significantly induced by the reversible heat(endothermic)and ohmic heat,which could balance each other.Following that the lithium metal is gradually deposited on the surface of the anode and reacts with electrolyte upon overcharge,inducing selfheating side reaction.However,this spontaneous thermal reaction could be“self-extinguished”.When the lithium in cathode is completely deintercalated,the boundary point of overcharge is about 4.7 V(~148%SOC,>40℃),and from this point,the self-heating behaviour could be continuously triggered until thermal runaway(TR)without additional overcharge.The whole static and spontaneous process lasts for 115 h and the side reaction heat is beyond 320,000 J.The continuous self-excitation behavior inside the battery is attributed to the interaction between the highly oxidized cathode and the solvent,which leads to the dissolution of metal ions.The dissolved metal ions destroy the SEI(solid electrolyte interphase)film on the surface of the deposited Li of anode,which induces the thermal reaction between lithium metal and the solvent.The interaction between cathode,the deposited Li of anode,and solvent promotes the temperature of the battery to rise slowly.When the temperature of the battery reaches more than 60℃,the reaction between lithium metal and solvent is accelerated.After the temperature rises rapidly to the melting point of the separator,it triggers the thermal runaway of the battery due to the short circuit of the battery.
基金made possible through a visiting postdoctoral fellowship to A.H. Ozdeniz by the Scientific and Technological Research Council of Turkey (TUBITAK)An operating research grant through the Natural Sciences and Engineering Council of Canada (NSERC) is also acknowledged
文摘Original surface chemistry of sulphidesis altered upon contact with air, leading to ''oxidation'', which is accompanied by evolution of heat. The current study reports results of an investigation on extent of exothermicity of an experimental nickel-copper sulphide stockpile that was formed at a mining site in Sudbury, Canada. The ore contained pentlandite and chalcopyrite that are accompanied by a large quantity of pyrrhotite. The self-heating characteristics were recorded by temperature sensors placed inside the stockpile. Ambient conditions such as temperature, humidity, and wind velocity were simultaneously recorded. The inner temperature of the stockpile indicated significant fluctuations due to rapid changes, particularly in the outside temperature. The minimum and maximum temperatures recorded in the outside and inside were 5 and 10.5, 44.3 and 32 ℃, respectively. The self-heating capacity of the sulphide ore stockpile observed represents a mild case compared to that experienced by coals. Possible reasons are discussed.
基金supported by the National Science Foundation of China(Grant No.41701232).
文摘Climate change is becoming an important issue in all fields of infrastructure development.Electricity plays a core role in the decarbonized energy system’s path to a regional zero-emission pattern.A well-built trans-Mediterranean backbone grid can hedge the profound evolution of regional power generation,transmission,and consumption.To date,only Turkey and the Maghreb countries(i.e.,Morocco,Algeria,and Tunisia)are connected with the Continental European Synchronous Area.Other south-and east-shore countries have insufficient interconnection infrastructures and synchronization difficulties that have proven to be major hurdles to the implementation of large-scale solar and wind projects and achievement of climate goals.This study analyzes the current trans-boundary grid interconnections and power and carbon emission portfolios in the Mediterranean region.To align with the recently launched new climate target‘Fit for 55’program and the accelerated large-scale renewables target,a holistic review of projected trans-Mediterranean grids and their market,technical,and financial obstacles of implementation was conducted.For south-and east-shore countries,major legal and regulatory barriers encompassing non-liberalized market structure,regulation gaps of taxation and transmission tariffs,and the private sector’s access rights need to be removed.Enhancement of domestic grids,substations,and harmonized grid codes and frequency,voltage,and communication technology standards among all trans-Mediterranean countries are physical prerequisites for implementing the Trans-Mediterranean Electricity Market.In addition,the mobilization of capital instruments along with private and international investments is indispensable for the realization of supranational transmission projects.As the final section of the decarbonization roadmap,the development of electric appliances,equipment,and vehicles with higher efficiency is inevitable in the decarbonized building,transportation,and industry sectors.
基金supported by the State Key Laboratory of Advanced Metallurgy,China(Project Code:41603006).
文摘Decarbonization is a critical issue for peaking CO_(2) emissions of energy-intensive industries,such as the iron and steel industry.The decarbonization options of China’s ironmaking and steelmaking sector were discussed based on a systematic three-dimensional low-carbon analysis from the aspects of resource utilization(Y),energy utilization(Q),and energy cleanliness which is evaluated by a process general emission factor(PGEF)on all the related processes,including the current blast furnace(BF)-basic oxygen furnace(BOF)integrated process and the specific sub-processes,as well as the electric arc furnace(EAF)process,typical direct reduction(DR)process,and smelting reduction(SR)process.The study indicates that the three-dimensional aspects,particularly the energy structure,should be comprehensively considered to quantitatively evaluate the decarbonization road map based on novel technologies or processes.Promoting scrap utilization(improvement of Y)and the substitution of carbon-based energy(improvement of PGEF)in particular is critical.In terms of process scale,promoting the development of the scrap-based EAF or DR-EAF process is highly encouraged because of their lower PGEF.The three-dimensional method is expected to extend to other processes or industries,such as the cement production and thermal electricity generation industries.
基金supported by the National Natural Science Foundation of China(NSFC)under Grant Nos.61925110,62004184 and 62234007the Key-Area Research and Development Program of Guangdong Province under Grant No.2020B010174002.
文摘The self-heating effect severely limits device performance and reliability.Although some studies have revealed the heat distribution ofβ-Ga_(2)O_(3) MOSFETs under biases,those devices all have small areas and have difficulty reflecting practical con-ditions.This work demonstrated a multi-fingerβ-Ga_(2)O_(3) MOSFET with a maximum drain current of 0.5 A.Electrical characteris-tics were measured,and the heat dissipation of the device was investigated through infrared images.The relationship between device temperature and time/bias is analyzed.
文摘CFD models have been developed to investigate the Iongwall goaf gas flow patternsunder different mining and geological control conditions.The Iongwall goaf wastreated as porous regions and gas flow was modelled as a momentum sink added to themomentum equation.Gas desorption from the caved goaf and destressed coal seamswithin the mining disturbed area was modelled as additional mass sources in the continuityequation.These CFD models were developed according to specific Iongwall layoutsand calibrated against field monitoring data.Two case studies were presented demonstratingthe application of CFD modelling of goaf gas flow characteristics for improved goafgas capture and the reduction of oxygen ingress into the goaf areas for self-heating prevention.Results from the case studies indicate that the optimum goaf drainage strategywould be a combination of shallow (near the face) and deep holes to improve the overalldrainage efficiency and gas purity.For gassy Iongwall faces retreating against the seam dip,it is recommended to conduct cross-measure roof hole drainage targeting the fracturedzones overlying the return corner,rather than high capacity surface goaf drainage deep inthe goaf.
基金Project supported by the National Natural Science Foundation of China (Grant No 60606022)the State Key Development Program for Basic Research of China (Grant No 51327010101)Xi’an Applied Materials Innovation Fund,China (Grant No XA-AM-200702)
文摘A thermal model of 4H-SiC MESFET is developed based on the temperature dependences of material parameters and three-region I - V model. The static current characteristics of 4H-SiC MESFET have been obtained with the consideration of the self-heating effect on related parameters including electron mobility, saturation velocity and thermal conductivity. High voltage performances are analysed using equivalent thermal conductivity model. Using the physicalbased simulations, we studied the dependence of self-heating temperature on the thickness and doping of substrate. The obtained results can be used for optimization of the thermal design of the SiC-based high-power field effect transistors.
基金Project supported by the National Key R&D Program of China(Grant No.2016YFB0400100)the National Natural Science Foundation of China(Grant No.91850112)+3 种基金the Natural Science Foundation of Jiangsu Province,China(Grant No.BK20161401)the Priority Academic Program Development of Jiangsu Higher Education Institutions,Chinathe Science and Technology Project of State Grid Corporation of China(Grant No.SGSDDK00KJJS1600071)the Fundamental Research Funds for the Central Universities,China(Grant No.14380098)
文摘Self-heating effect in amorphous InGaZnO thin-film transistors remains a critical issue that degrades device performance and stability, hindering their wider applications. In this work, pulsed current–voltage analysis has been applied to explore the physics origin of self-heating induced degradation, where Joule heat is shortly accumulated by drain current and dissipated in repeated time cycles as a function of gate bias. Enhanced positive threshold voltage shift is observed at reduced heat dissipation time, higher drain current, and increased gate width. A physical picture of Joule heating assisted charge trapping process has been proposed and then verified with pulsed negative gate bias stressing scheme, which could evidently counteract the self-heating effect through the electric-field assisted detrapping process. As a result, this pulsed gate bias scheme with negative quiescent voltage could be used as a possible way to actively suppress self-heating related device degradation.
文摘Dynamic self-heating effect(SHE)of silicon-on-insulator(SOI)MOSFET is comprehensively evaluated by ultrafast pulsed I-V measurement in this work.It is found for the first time that the SHE complete heating response and cooling response of SOI MOSFETs are conjugated,with two-stage curves shown.We establish the effective thermal transient response model with stage superposition corresponding to the heating process.The systematic study of SHE dependence on workload shows that frequency and duty cycle have more significant effect on SHE in first-stage heating process than in the second stage.In the first-stage heating process,the peak lattice temperature and current oscillation amplitude decrease by more than 25 K and 4%with frequency increasing to 10 MHz,and when duty cycle is reduced to 25%,the peak lattice temperature drops to 306 K and current oscillation amplitude decreases to 0.77%.Finally,the investigation of two-stage(heating and cooling)process provides a guideline for the unified optimization of dynamic SHE in terms of workload.As the operating frequency is raised to GHz,the peak temperature depends on duty cycle,and self-heating oscillation is completely suppressed.
文摘The influence of self-heating on the millimeter-wave(mm-wave)and terahertz(THz)performance of double-drift region(DDR)impact avalanche transit time(IMPATT)sources based on silicon(Si)has been investigated in this paper.The dependences of static and large-signal parameters on junction temperature are estimated using a non-sinusoidal voltage excited(NSVE)large-signal simulation technique developed by the authors,which is based on the quantum-corrected drift-diffusion(QCDD)model.Linear variations of static parameters and non-linear variations of large-signal parameters with temperature have been observed.Analytical expressions representing the temperature dependences of static and large-signal parameters of the diodes are developed using linear and 2nd degree polynomial curve fitting techniques,which will be highly useful for optimizing the thermal design of the oscillators.Finally,the simulated results are found to be in close agreement with the experimentally measured data.
