Superhydrophobicity endows various substrates with astonishing multifunctional properties and has received widespread praise in industrial production.However,the fragile connection between the coating and the substrat...Superhydrophobicity endows various substrates with astonishing multifunctional properties and has received widespread praise in industrial production.However,the fragile connection between the coating and the substrate not only limits the service life of superhydrophobic coatings,but also poses limitations.To address this issue,this study used 3-(perfluorooctyl)propanol and organic polysilazane(OPSZ)with universal anchoring properties as starting materials to obtain fluorine modified OPSZ through a one-step synthesis method,and then doped SiO_(2)micro nano particles to produce superhydrophobic coatings that can be widely applied to various substrates.Investigating the relationship between the hydrophobic properties of the coatings and the amounts of SiO_(2)microparticles and nanoparticles used to create the microscopic rough structure of the superhydrophobic coatings,it was discovered that the hydrophobic properties of the coatings tended to increase as the number of nanoparticles increased.The water contact angle of prepared coatings was still over 157°after 48 h of UV exposure or 180 days of exposure to air.The heat resistance of the created superhydrophobic coatings was tested in a muffle furnace at 400℃ for 2 h.The results revealed that the coatings maintained their water contact angle of 155.1°±3.01°and water sliding angle of 6.4°±1.98°,demonstrating their excellent heat resistance and suitability for use in a variety of high-temperatu re environme nts.The work provided a practical way for creating superhydrophobic composite coatings with excellent mechanical stability,acid and alkali corrosion resistance,and heat resistance,and had potential application in antifouling and anti-corrosion.展开更多
We investigated the influence of PEG on the surface morphology,photocatalytic performance,photovoltaic conversion efficiency(PCE),and performance in complex environments of TiO_(2)-PEG composite films.The PEG content ...We investigated the influence of PEG on the surface morphology,photocatalytic performance,photovoltaic conversion efficiency(PCE),and performance in complex environments of TiO_(2)-PEG composite films.The PEG content was varied to further optimize the comprehensive performance of the composite films.Using titanium isopropoxide as the main raw material,TiO_(2)-PEG sol was prepared via sol-gel method and coated on the surface of photovoltaic(PV)glass by spin coating.The surface morphology and crystalline phase of the TiO_(2)-PEG film were analyzed,and the effects of the TiO_(2)-PEG film on the photocatalytic performance,PCE,contact angle,and performance in complex environments of PV glass were studied.The experimental results show that under the specified experimental conditions,when 4 g PEG10000 is added,the comprehensive performance of the coated PV glass reaches its optimum,with an average transmittance of 91.73%at 550 nm.Using methylene blue(MB)dye degradation experiments,the degradation rate after 2 hours of xenon lamp irradiation reaches 98.15%.The photovoltaic conversion efficiency of the composite film reaches 16.33%,and the contact angle is 3.28°,indicating a superhydrophilic state.It is demonstrated that the appropriate amount of PEG can enhance the transmittance,self-cleaning performance,and photovoltaic conversion efficiency of coated PV glass.展开更多
The Savitzky-Golay(SG)filter,which employs polynomial least-squares approximations to smooth data and estimate derivatives,is widely used for processing noisy data.However,noise suppression by the SG filter is recogni...The Savitzky-Golay(SG)filter,which employs polynomial least-squares approximations to smooth data and estimate derivatives,is widely used for processing noisy data.However,noise suppression by the SG filter is recognized to be limited at data boundaries and high frequencies,which can significantly reduce the signal-to-noise ratio(SNR).To solve this problem,a novel method synergistically integrating Principal Component Analysis(PCA)with SG filtering is proposed in this paper.This approach avoids the is-sue of excessive smoothing associated with larger window sizes.The proposed PCA-SG filtering algorithm was applied to a CO gas sensing system based on Cavity Ring-Down Spectroscopy(CRDS).The perform-ance of the PCA-SG filtering algorithm is demonstrated through comparison with Moving Average Filtering(MAF),Wavelet Transformation(WT),Kalman Filtering(KF),and the SG filter.The results demonstrate that the proposed algorithm exhibits superior noise reduction capabilities compared to the other algorithms evaluated.The SNR of the ring-down signal was improved from 11.8612 dB to 29.0913 dB,and the stand-ard deviation of the extracted ring-down time constant was reduced from 0.037μs to 0.018μs.These results confirm that the proposed PCA-SG filtering algorithm effectively improves the smoothness of the ring-down curve data,demonstrating its feasibility.展开更多
Accurate estimation of the State of Charge(SOC),State of Health(SOH),and Terminal Resistance(TR)is crucial for the effective operation of Battery Management Systems(BMS)in lithium-ion batteries.This study conducts a c...Accurate estimation of the State of Charge(SOC),State of Health(SOH),and Terminal Resistance(TR)is crucial for the effective operation of Battery Management Systems(BMS)in lithium-ion batteries.This study conducts a comprehensive comparative analysis of four Kalman filter variants Extended Kalman Filter(EKF),Extended Kalman-Bucy Filter(EKBF),Unscented Kalman Filter(UKF),and Unscented Kalman-Bucy Filter(UKBF)under varying battery parameter conditions.These include temperature fluctuation,self-discharge,current direction,cell capacity,process noise,and measurement noise.Our findings reveal significant variations in the performance of SOC and SOH predictions across filters,emphasizing that UKF demonstrates superior robustness to noise,while EKF performs better under accurate system dynamics.The study underscores the need for adaptive filtering strategies that can dynamically adjust to evolving battery parameters,thereby enhancing BMS reliability and extending battery lifespan.展开更多
1 Introduction Recently,the increasing demand for advanced telecommunication systems has spurred extensive research into bandpass filters(BPFs),with particular emphasis on miniaturization,reduction of insertion loss(I...1 Introduction Recently,the increasing demand for advanced telecommunication systems has spurred extensive research into bandpass filters(BPFs),with particular emphasis on miniaturization,reduction of insertion loss(IL),and enhancement of upper stopband rejection(Huang et al.,2021;Snyder et al.,2021;Lin et al.,2023;Zeng et al.,2023).展开更多
In this study,a fifth-degree cubature particle filter(5CPF)is proposed to address the limited estimation accuracy in traditional particle filter algorithms for bearings-only tracking(BOT).This algorithm calculates the...In this study,a fifth-degree cubature particle filter(5CPF)is proposed to address the limited estimation accuracy in traditional particle filter algorithms for bearings-only tracking(BOT).This algorithm calculates the recommended density function by introducing a fifth-degree cubature Kalman filter algorithm to guide particle sampling,which effectively alleviates the problem of particle degradation and significantly improves the estimation accuracy of the filter.However,the 5CPF algorithm exhibits high computational complexity,particularly in scenarios with a large number of particles.Therefore,we propose the extended Kalman filter(EKF)-5CPF algorithm,which employs an EKF to replace the time update step for each particle in the 5CPF.This enhances the algorithm’s real-time capability while maintaining the high precision advantage of the 5CPF algorithm.In addition,we construct bearing-only dual-station and single-motion station target tracking systems,and the filtering performances of 5CPF and EKF-5CPF algorithms under different conditions are analyzed.The results show that both the 5CPF algorithm and EKF-5CPF have strong robustness and can adapt to different noise environments.Furthermore,both algorithms significantly outperform traditional nonlinear filtering algorithms in terms of convergence speed,tracking accuracy,and overall stability.展开更多
Color filters are essential components for optical modulation.However,conventional filters are restricted to operating exclusively in either reflective or transmissive mode.Furthermore,they suffer from limited UV and ...Color filters are essential components for optical modulation.However,conventional filters are restricted to operating exclusively in either reflective or transmissive mode.Furthermore,they suffer from limited UV and thermal stability,low color purity,and exhibit identical coloration on both surfaces.Herein,we propose a novel design strategy for trans-reflective color filters by integrating the absorptive properties of dye-doped polysulfone(PSU)with the diffractive capabilities of photonic crystals.This composite filter achieved broad-spectrum transmission with deep color outputs—yellow(0.410,0.510),magenta(0.446,0.231),and cyan(0.201,0.425)—closely aligned with standard color space coordinates.By tuning the refractive index of CeO_(2)@SiO_(2)nanoparticles to match dye-based PSU matrix,the transmittance of filters exceeded 70%.Moreover,dye-mediated absorption reduces the scattering light,thereby enhancing reflection color purity(full width at half maxima(FWHM)=25 nm)and producing vibrant blue,green,and red hues.The incorporation of UV-absorbing CeO_(2)@SiO_(2)nanoparticles effectively mitigated dye photodegradation,yielding exceptional UV stability(ΔT<2%under prolonged UV exposure).The filters also exhibited outstanding thermal stability(ΔT<1%after 30 min heat treatment at 230°C).This work establishes a robust materials design framework for multifunctional optical filters,advancing the development of highfidelity dual-mode color systems for next-generation display technologies.展开更多
Recommendation systems are an integral and indispensable part of every digital platform,as they can suggest content or items to users based on their respective needs.Collaborative filtering is a technique often used i...Recommendation systems are an integral and indispensable part of every digital platform,as they can suggest content or items to users based on their respective needs.Collaborative filtering is a technique often used in various studies,which produces recommendations by analyzing similarities between users and items based on their behavior.Although often used,traditional collaborative filtering techniques still face the main challenge of sparsity.Sparsity problems occur when the data in the system is sparse,meaning that only a portion of users provide feedback on some items,resulting in inaccurate recommendations generated by the system.To overcome this problem,we developed aHybrid Collaborative Filtering model based onMatrix Factorization andGradient Boosting(HCF-MFGB),a new hybrid approach.Our proposed model integrates SVD++,the XGBoost ensemble learning algorithm,and utilizes user demographic data and meta items.We utilize information,both explicitly and implicitly,to learn user preference patterns using SVD++.The XGBoost algorithm is used to create hundreds of decision trees incrementally,thereby improving model accuracy.Meanwhile,user demographic and meta-item data are clustered using the K-Means Clustering algorithm to capture similarities in user and item characteristics.This combination is designed to improve rating prediction accuracy by reducing reliance on minimal explicit rating data,while addressing sparsity issues in movie recommendation systems.The results of experiments on the MovieLens 100K,MovieLens 1M,and CiaoDVD datasets show significant improvements,outperforming various other baselinemodels in terms of RMSE and MAE.On theMovieLens 100K dataset,the HCF-MFGB model obtained an RMSE value of 0.853 and an MAE value of 0.674.On theMovieLens 1M dataset,the HCF-MFGB model obtained an RMSE value of 0.763 and an MAE value of 0.61.On the CiaoDCD dataset,the HCF-MFGB model achieved an RMSE value of 0.718 and an MAE value of 0.495.These results confirm a significant improvement in movie recommendation accuracy with the proposed approach.展开更多
This article presents an adaptive intelligent control strategy applied to a lumped-parameter evaporator model,i.e.,a simplified dynamic representation treating the evaporator as a single thermal node with uniform temp...This article presents an adaptive intelligent control strategy applied to a lumped-parameter evaporator model,i.e.,a simplified dynamic representation treating the evaporator as a single thermal node with uniform temperature distribution,suitable for control design due to its balance between physical fidelity and computational simplicity.The controller uses a wavelet-based neural proportional,integral,derivative(PID)controller with IIR filtering(infinite impulse response).The dynamic model captures the essential heat and mass transfer phenomena through a nonlinear energy balance,where the cooling capacity“Qevap”is expressed as a non-linear function of the compressor frequency and the temperature difference,specifically,Q_(evap)=k_(1)u(T_(in)−T_(e))with u as compressor frequency,Te evaporator temperature,and Tin inlet fluid temperature.The operating conditions of the system,in general terms,focus on the following variables,the overall thermal capacity is 1000 J/K,typical for small-capacity heat exchangers,The mass flow is 0.05 kg/s,typical for secondary liquid cooling circuits,the overall loss coefficient of 50 W/K that corresponds to small evaporators with partial insulation,the temperatures(inlet)of 10℃and the temperature of environment of 25℃,thermal load of 200 W that corresponds to a small-scaled air conditioning applications.To handle system nonlinearities and improve control performance,aMorlet wavelet-based neural network(Wavenet)is used to dynamically adjust the PID gains online.An IIR filter is incorporated to smooth the adaptive gains,improving stability and reducing oscillations.In contrast to prior wavelet-or neural-adaptive PID controllers in HVAC applications,which typically adjust gains without explicit filtering or not tailored to evaporator dynamics,this work introduces the first PID–Wavenet scheme augmented with an IIR-based stabilization layer,specifically designed to address the combined challenges of nonlinear evaporator behavior,gain oscillation,and real-time implementability.The proposed controller(PID-Wavenet+IIR)is implemented and validated inMATLAB/Simulink,demonstrating superior performance compared to a conventional PID tuned using Simulink’s auto-tuning function.Key results include a reduction in settling time from 13.3 to 8.2 s,a reduction in overshoot from 3.5%to 0.8%,a reduction in steady-state error from 0.12℃ to 0.02℃and a 13%reduction in energy overall consumption.The controller also exhibits greater robustness and adaptability under varying thermal loads.This explicit integration of wavelet-driven adaptation with IIR-filtered gain shaping constitutes the main methodological contribution and novelty of the work.These findings validate the effectiveness of the wavelet-based adaptive approach for advanced thermal management in refrigeration and HVAC systems,with potential applications in controlling variable-speed compressors,liquid chillers,and compact cooling units.展开更多
Although multifunctional aerogels are expected to be used in applications such as portable electronic devices,it is still a great challenge to confer multifunctionality to aerogels while maintaining their inherent mic...Although multifunctional aerogels are expected to be used in applications such as portable electronic devices,it is still a great challenge to confer multifunctionality to aerogels while maintaining their inherent microstructure.Herein,a simple method is proposed to prepare multifunctional NiCo/C aerogels with excellent electromagnetic wave absorption properties,superhydrophobicity,and self-cleaning by water-induced NiCo-MOF self-assembly.Specifically,the impedance matching of the three-dimensional(3D)structure and the interfacial polarization provided by CoNi/C as well as the defect-induced dipole polarization are the primary contributors to the broadband absorption.As a result,the prepared NiCo/C aerogels have a broadband width of 6.22 GHz at 1.9 mm.Due to the presence of hydrophobic functional groups,CoNi/C aerogels improve the stability in humid environments and obtain hydrophobicity with large contact angles>140°.This multifunctional aerogel has promising applications in electromagnetic wave absorption,resistance to water or humid environments.展开更多
Superhydrophobic materials have shown tremendous potential in various fields.However,the adhesion,wetting,and pinning of low-surface-tension liquids greatly limit their multifunctional applications.Therefore,the creat...Superhydrophobic materials have shown tremendous potential in various fields.However,the adhesion,wetting,and pinning of low-surface-tension liquids greatly limit their multifunctional applications.Therefore,the creation of superamphiphobic coatings that combine superhydrophobic and superoleophobic properties through a simple preparation strategy is desirable.In this study,we successfully developed an organic-inorganic hybrid superamphiphobic coating on Q235 carbon steel using aluminum oxide nanopar-ticles,organosilanes,and waterborne epoxy resin via a versatile spray-coating technique.The coating ex-hibited high contact angles(>151°)and low sliding angles(<7°)for water and oil liquids,demonstrating excellent superamphiphobic characteristics.Electrochemical tests demonstrated significant improvements in charge transfer resistance and low-frequency modulus for the superamphiphobic coating.The corro-sion potential shifted positively by 590 mV,and the corrosion current density decreased by four orders of magnitude.Additionally,the coating endured 480 h of salt spray and 2400 h of outdoor atmospheric exposure,showcasing superior anti-corrosion capacity.Freezing tests of water droplets at-10℃and-15℃confirmed that the coating significantly prolonged the freezing time with reduced ice adhesion strength.We believe that the designed superamphiphobic coating with integrated functionalities of selfcleaning,anti-corrosion,anti-icing,and anti-liquid-adhesion can provide important solutions for extending the lifespan of materials in marine and industrial environments.展开更多
Double-walled carbon nanotube （DWCNT） macro-films with large areas, excellent flexibility and superhydrophobicity are reported. The area of the macro-film is larger than 30 cm×15 cm, and this large film can be ...Double-walled carbon nanotube （DWCNT） macro-films with large areas, excellent flexibility and superhydrophobicity are reported. The area of the macro-film is larger than 30 cm×15 cm, and this large film can be bended, or folded without any damage, and even can be tailored freely. After a simple modification of perfluoroalkysilane, the surface of the macro-film shows excellent superhydrophobicity with a water contact angle of 165.74-2 deg. and sliding angle lower than 3 deg., the prepared superhydrophobic films showing excellent antifouling, self-cleaning and water-repellent functions. The topographic roughness and perfluoroalkysilane modification are found to contribute to the observed superhydrophobicity. Considering the outstanding electronic, chemical and mechanical properties of DWCNTs, it is expected that this multifunctional DWCNT macro-film has potential applications in many fields.展开更多
Magnesium alloys with superhydrophobicity are constructed by controlling rough surface structure and grafting long hydrophobic alkyl chains. Changes of morphology, phase structure, chemical composition as well as wett...Magnesium alloys with superhydrophobicity are constructed by controlling rough surface structure and grafting long hydrophobic alkyl chains. Changes of morphology, phase structure, chemical composition as well as wettability, corrosion resistance of superhydrophobic magnesium alloy upon immersing in corrosive media are investigated comparatively. Meanwhile, the contaminating particles on as-prepared superhydrophobic surfaces can be taken away easily by rolling water droplets. Therefore, the results show that as-prepared superhydrophobic magnesium alloys exhibit enhanced corrosion resistance and self-healing performance. Finally, anti-corrosion and self-cleaning mechanisms are deduced. It can be concluded that it is an effective strategy of preparing superhydrophobic surfaces for improving the corrosion resistance and selfcleaning performance of magnesium alloys.展开更多
SiO_(2)/TiO_(2)composite films have been frequently used to realize the functions of self-cleaning and antireflection.Increasing the TiO_(2)volume ratio in SiO_(2)/TiO_(2)composite film is beneficial to enhance the se...SiO_(2)/TiO_(2)composite films have been frequently used to realize the functions of self-cleaning and antireflection.Increasing the TiO_(2)volume ratio in SiO_(2)/TiO_(2)composite film is beneficial to enhance the self-cleaning effect,while high TiO_(2)content leads to a strong Rayleigh scattering and depresses the antireflective performance,resulting in a bottleneck problem for the dual-functional application.Here,we have achieved a high-quality TiO_(2)nanotubes film with excellent antireflective and near-perfect selfcleaning performances.Ultrasound assisted pickling method has been developed to effectively prepare the well-dispersed protonated titanate nanotubes colloid.After spin-coating and annealing treatment,glass substrate coated with double-side TiO_(2)nanotubes film has a peak transmittance of 99.2%and average transmittance of 97.4%at 400-800 nm.Ultra-high porosity of TiO_(2)nanotubes film(80%)and ultra-fine size of TiO_(2)nanotubes(8.6 nm in outer diameter)lead to excellent antireflective performance.With high UV absorptivity(80%at 254 nm)and formal quantum efficiency of stearic acid(10.9×10^(-3)),TiO_(2)nanotubes film shows near-perfect self-cleaning performance.A persistent anti-fogging ability is also presented.This study demonstrates the feasibility to fabricate pure TiO_(2)antireflective coating for glass substrate,extends application field of the classic TiO_(2)nanotubes,and sheds lights on the practical applications of high-powered TiO_(2)nanotube-based multi-functional films.展开更多
Self-cleaning surfaces are desirable in many engineering applications where low energy consumption,reusability and sustainability are of the biggest concerns.Inspired by the gecko’s unique ’dry selfcleaning’ hierar...Self-cleaning surfaces are desirable in many engineering applications where low energy consumption,reusability and sustainability are of the biggest concerns.Inspired by the gecko’s unique ’dry selfcleaning’ hierarchical structures.Here we fabricated artificial Fe304/PDMS composites that show robust self-cleaning capabilities.The enhanced adhesion performance is attributable to the decrease of PDMS polymerization degree and the load transfer between PDMS matrix and Fe304 magnetic particles.The self-cleaning surfaces showed up to 24.3% self-cleaning rate with as few as 4 steps.Simulation result indicated that the changing of cross linking between Fe304 and PDMS is the main reason for the enhanced self-cleaning surfaces.This work reveals an alternative route of making high-performance self-cleaning smart surfaces that are applicable in the textile industry,robotic locomotion/gripping technology,outerspace explorations and tissue engineering.展开更多
The self-cleaning glass coated with Fe3+-TiO2 photocatalytic thin film was prepared by sol-gel process from the system Ti（OC4H9）4-NH（C2H4OH）2-C2H5OH-H2O containing FeCl3. The microstructure and properties of the f...The self-cleaning glass coated with Fe3+-TiO2 photocatalytic thin film was prepared by sol-gel process from the system Ti（OC4H9）4-NH（C2H4OH）2-C2H5OH-H2O containing FeCl3. The microstructure and properties of the film were studied using differential thermal analysis-thermogravimetry（DTA-TG）, X-ray diffration（XRD） and scanning electron microscope（SEM）. The transmittance of the self-cleaning glass was measured by using UV-Vis spectrometer. The effects of content of Fe3+ and the thickness of Fe3+-TiO2 thin film on the photocatalytic activity were examined. The results show that the photocatalytic thin films are mainly composed of Fe3O4 and TiO2 particles within 10100 nm. The appropriate amount of Fe3+ is effective for improving the photocatalytic activities of TiO2. The best photocatalytic activity is obtained when the molar ratio of Fe3+ to TiO2 is 0.005 and the glass is coated with 9 layers.展开更多
How to fabricate durable superhydrophobic materials for cyclic oil/water separation to solve oil-induced pollutions is still a problem.Herein,we fabricated a durable Superhydrophobic Stainless Steel Mesh(SH-SSM)with n...How to fabricate durable superhydrophobic materials for cyclic oil/water separation to solve oil-induced pollutions is still a problem.Herein,we fabricated a durable Superhydrophobic Stainless Steel Mesh(SH-SSM)with nano/micro flower-like sheets by self-assembly of zinc stearate for the cyclic separation of various oil/water mixtures.The SH-SSM exhibits durable superhydrophobicity against static or dynamic treatments.In virtue of durable superhydrophobicity of the SH-SSM,the dusts on surface of SH-SSM can be removed completely by running water immediately showing excellent self-cleaning performance.Moreover,the SH-SSM can be used to perform gravity-driven separation of heavy oil/water and light oil/water mixtures by utilizing its superhydrophobicity that oil phase penetrates the mesh and water phase is restricted.Separation efficiencies of the SH-SSM can reach 99.99%.After 20 cycles of separation,the separation efficiencies for are>97.00%and>98.25%for heavy oil/water and light oil/water mixtures,respectively.Flux values of dichloromethane,hexane and petroleum ether are 2.5×10^(5) L m^(−2) h^(−1),1.7×10^(5) L m^(−2) h^(−1),and 1.8×10^(5) L m^(−2) h^(−1),respectively.This study proposes a facial approach to prepare durable superhydrophobic and self-cleaning material for cyclic and fast separation of oil/water.展开更多
Daylighting structures,including solar cells and building windows,utilize sunlight whilst suffering from undesired solar heat and outdoor dust contamination.A radiative cooling system that is transparent to sunlight a...Daylighting structures,including solar cells and building windows,utilize sunlight whilst suffering from undesired solar heat and outdoor dust contamination.A radiative cooling system that is transparent to sunlight and has a superhydrophobic surface would cool and clean the daylighting structures in a sustainable manner.However,the majority of the current daytime radiative cooling systems were designed to fully reflect the incident sunlight to maximize the cooling power.In this work,we optimized both the sunlight transmission and infrared thermal irradiation by modeling the size-dependent scattering and absorption of light by SiO_(2)spheres embedded in a polymer matrix,we found that the use of nanospheres(20 nm)enabled both high sunlight transmittance(>90%)and infrared emissivity(-0.85).This theoretical prediction was confirmed by experimental measurements of a solution-processed nanocomposite film.When coated on a solar cell,the as-prepared film not only preserved the power conversion efficiency of the cell(14.71%,uncoated cell has an efficiency of 14.79%)but also radiatively cooled the cell by up to 5℃under direct sunlight.This reduction of the operating temperature of the solar cell further enhanced its electrical power output,evidenced by an increase in the equilibrium temperature of the LED load by about 14℃.The nanoscale textured surface formed by the nanospheres further led to superhydrophobicity and thus excellent self-cleaning performance(efficient removal of dust by wind and/or water droplets).展开更多
基金supported by the National Key Research and Development Program of China(2022YFC3004901-3)the National Natural Science Foundation of China(21908109)+2 种基金the Open Project of Key Laboratory of Fire Emergency Rescue Equipment of Ministry of Emergency Management of People's Republic of China(2020XFZB05)the Fundamental Research Funds for the Central Universities(30919011272)the Natural Science Foundation of Jiangsu Province(BK20180816)。
文摘Superhydrophobicity endows various substrates with astonishing multifunctional properties and has received widespread praise in industrial production.However,the fragile connection between the coating and the substrate not only limits the service life of superhydrophobic coatings,but also poses limitations.To address this issue,this study used 3-(perfluorooctyl)propanol and organic polysilazane(OPSZ)with universal anchoring properties as starting materials to obtain fluorine modified OPSZ through a one-step synthesis method,and then doped SiO_(2)micro nano particles to produce superhydrophobic coatings that can be widely applied to various substrates.Investigating the relationship between the hydrophobic properties of the coatings and the amounts of SiO_(2)microparticles and nanoparticles used to create the microscopic rough structure of the superhydrophobic coatings,it was discovered that the hydrophobic properties of the coatings tended to increase as the number of nanoparticles increased.The water contact angle of prepared coatings was still over 157°after 48 h of UV exposure or 180 days of exposure to air.The heat resistance of the created superhydrophobic coatings was tested in a muffle furnace at 400℃ for 2 h.The results revealed that the coatings maintained their water contact angle of 155.1°±3.01°and water sliding angle of 6.4°±1.98°,demonstrating their excellent heat resistance and suitability for use in a variety of high-temperatu re environme nts.The work provided a practical way for creating superhydrophobic composite coatings with excellent mechanical stability,acid and alkali corrosion resistance,and heat resistance,and had potential application in antifouling and anti-corrosion.
基金Funded by the Project of Guangxi Science and Technology(No.ZY24212061)the Project of Guangxi Science and Technology Major Program(No.AA24263054)the Project of Beihai Science and Technology(No.202379002)。
文摘We investigated the influence of PEG on the surface morphology,photocatalytic performance,photovoltaic conversion efficiency(PCE),and performance in complex environments of TiO_(2)-PEG composite films.The PEG content was varied to further optimize the comprehensive performance of the composite films.Using titanium isopropoxide as the main raw material,TiO_(2)-PEG sol was prepared via sol-gel method and coated on the surface of photovoltaic(PV)glass by spin coating.The surface morphology and crystalline phase of the TiO_(2)-PEG film were analyzed,and the effects of the TiO_(2)-PEG film on the photocatalytic performance,PCE,contact angle,and performance in complex environments of PV glass were studied.The experimental results show that under the specified experimental conditions,when 4 g PEG10000 is added,the comprehensive performance of the coated PV glass reaches its optimum,with an average transmittance of 91.73%at 550 nm.Using methylene blue(MB)dye degradation experiments,the degradation rate after 2 hours of xenon lamp irradiation reaches 98.15%.The photovoltaic conversion efficiency of the composite film reaches 16.33%,and the contact angle is 3.28°,indicating a superhydrophilic state.It is demonstrated that the appropriate amount of PEG can enhance the transmittance,self-cleaning performance,and photovoltaic conversion efficiency of coated PV glass.
文摘The Savitzky-Golay(SG)filter,which employs polynomial least-squares approximations to smooth data and estimate derivatives,is widely used for processing noisy data.However,noise suppression by the SG filter is recognized to be limited at data boundaries and high frequencies,which can significantly reduce the signal-to-noise ratio(SNR).To solve this problem,a novel method synergistically integrating Principal Component Analysis(PCA)with SG filtering is proposed in this paper.This approach avoids the is-sue of excessive smoothing associated with larger window sizes.The proposed PCA-SG filtering algorithm was applied to a CO gas sensing system based on Cavity Ring-Down Spectroscopy(CRDS).The perform-ance of the PCA-SG filtering algorithm is demonstrated through comparison with Moving Average Filtering(MAF),Wavelet Transformation(WT),Kalman Filtering(KF),and the SG filter.The results demonstrate that the proposed algorithm exhibits superior noise reduction capabilities compared to the other algorithms evaluated.The SNR of the ring-down signal was improved from 11.8612 dB to 29.0913 dB,and the stand-ard deviation of the extracted ring-down time constant was reduced from 0.037μs to 0.018μs.These results confirm that the proposed PCA-SG filtering algorithm effectively improves the smoothness of the ring-down curve data,demonstrating its feasibility.
基金supported by the Royal Academy of Engineering,UK,in the scheme of Distinguished International Associate(DIA-2424-5-134).
文摘Accurate estimation of the State of Charge(SOC),State of Health(SOH),and Terminal Resistance(TR)is crucial for the effective operation of Battery Management Systems(BMS)in lithium-ion batteries.This study conducts a comprehensive comparative analysis of four Kalman filter variants Extended Kalman Filter(EKF),Extended Kalman-Bucy Filter(EKBF),Unscented Kalman Filter(UKF),and Unscented Kalman-Bucy Filter(UKBF)under varying battery parameter conditions.These include temperature fluctuation,self-discharge,current direction,cell capacity,process noise,and measurement noise.Our findings reveal significant variations in the performance of SOC and SOH predictions across filters,emphasizing that UKF demonstrates superior robustness to noise,while EKF performs better under accurate system dynamics.The study underscores the need for adaptive filtering strategies that can dynamically adjust to evolving battery parameters,thereby enhancing BMS reliability and extending battery lifespan.
基金supported by the National Natural Science Foundation of China(No.62371263)the Postgraduate Research&Practice Innovation Program of Jiangsu Province(No.SJCK25_1995).
文摘1 Introduction Recently,the increasing demand for advanced telecommunication systems has spurred extensive research into bandpass filters(BPFs),with particular emphasis on miniaturization,reduction of insertion loss(IL),and enhancement of upper stopband rejection(Huang et al.,2021;Snyder et al.,2021;Lin et al.,2023;Zeng et al.,2023).
基金Supported by the Guangxi Special Program for Technological Innovation Guidance(No.GuiKeAC25069006).
文摘In this study,a fifth-degree cubature particle filter(5CPF)is proposed to address the limited estimation accuracy in traditional particle filter algorithms for bearings-only tracking(BOT).This algorithm calculates the recommended density function by introducing a fifth-degree cubature Kalman filter algorithm to guide particle sampling,which effectively alleviates the problem of particle degradation and significantly improves the estimation accuracy of the filter.However,the 5CPF algorithm exhibits high computational complexity,particularly in scenarios with a large number of particles.Therefore,we propose the extended Kalman filter(EKF)-5CPF algorithm,which employs an EKF to replace the time update step for each particle in the 5CPF.This enhances the algorithm’s real-time capability while maintaining the high precision advantage of the 5CPF algorithm.In addition,we construct bearing-only dual-station and single-motion station target tracking systems,and the filtering performances of 5CPF and EKF-5CPF algorithms under different conditions are analyzed.The results show that both the 5CPF algorithm and EKF-5CPF have strong robustness and can adapt to different noise environments.Furthermore,both algorithms significantly outperform traditional nonlinear filtering algorithms in terms of convergence speed,tracking accuracy,and overall stability.
基金supported by the Program of the National Natural Science Foundation of China(22238002)the Fundamental Research Funds for the Central Universities(DUT22-LAB610)Research and Innovation Team Project of Dalian University of Technology(DUT2022TB10).
文摘Color filters are essential components for optical modulation.However,conventional filters are restricted to operating exclusively in either reflective or transmissive mode.Furthermore,they suffer from limited UV and thermal stability,low color purity,and exhibit identical coloration on both surfaces.Herein,we propose a novel design strategy for trans-reflective color filters by integrating the absorptive properties of dye-doped polysulfone(PSU)with the diffractive capabilities of photonic crystals.This composite filter achieved broad-spectrum transmission with deep color outputs—yellow(0.410,0.510),magenta(0.446,0.231),and cyan(0.201,0.425)—closely aligned with standard color space coordinates.By tuning the refractive index of CeO_(2)@SiO_(2)nanoparticles to match dye-based PSU matrix,the transmittance of filters exceeded 70%.Moreover,dye-mediated absorption reduces the scattering light,thereby enhancing reflection color purity(full width at half maxima(FWHM)=25 nm)and producing vibrant blue,green,and red hues.The incorporation of UV-absorbing CeO_(2)@SiO_(2)nanoparticles effectively mitigated dye photodegradation,yielding exceptional UV stability(ΔT<2%under prolonged UV exposure).The filters also exhibited outstanding thermal stability(ΔT<1%after 30 min heat treatment at 230°C).This work establishes a robust materials design framework for multifunctional optical filters,advancing the development of highfidelity dual-mode color systems for next-generation display technologies.
基金funded by the Directorate General of Research and Development,Ministry of Higher Education,Science and Technology of the Republic of Indonesia,with grant number 2.6.63/UN32.14.1/LT/2025.
文摘Recommendation systems are an integral and indispensable part of every digital platform,as they can suggest content or items to users based on their respective needs.Collaborative filtering is a technique often used in various studies,which produces recommendations by analyzing similarities between users and items based on their behavior.Although often used,traditional collaborative filtering techniques still face the main challenge of sparsity.Sparsity problems occur when the data in the system is sparse,meaning that only a portion of users provide feedback on some items,resulting in inaccurate recommendations generated by the system.To overcome this problem,we developed aHybrid Collaborative Filtering model based onMatrix Factorization andGradient Boosting(HCF-MFGB),a new hybrid approach.Our proposed model integrates SVD++,the XGBoost ensemble learning algorithm,and utilizes user demographic data and meta items.We utilize information,both explicitly and implicitly,to learn user preference patterns using SVD++.The XGBoost algorithm is used to create hundreds of decision trees incrementally,thereby improving model accuracy.Meanwhile,user demographic and meta-item data are clustered using the K-Means Clustering algorithm to capture similarities in user and item characteristics.This combination is designed to improve rating prediction accuracy by reducing reliance on minimal explicit rating data,while addressing sparsity issues in movie recommendation systems.The results of experiments on the MovieLens 100K,MovieLens 1M,and CiaoDVD datasets show significant improvements,outperforming various other baselinemodels in terms of RMSE and MAE.On theMovieLens 100K dataset,the HCF-MFGB model obtained an RMSE value of 0.853 and an MAE value of 0.674.On theMovieLens 1M dataset,the HCF-MFGB model obtained an RMSE value of 0.763 and an MAE value of 0.61.On the CiaoDCD dataset,the HCF-MFGB model achieved an RMSE value of 0.718 and an MAE value of 0.495.These results confirm a significant improvement in movie recommendation accuracy with the proposed approach.
文摘This article presents an adaptive intelligent control strategy applied to a lumped-parameter evaporator model,i.e.,a simplified dynamic representation treating the evaporator as a single thermal node with uniform temperature distribution,suitable for control design due to its balance between physical fidelity and computational simplicity.The controller uses a wavelet-based neural proportional,integral,derivative(PID)controller with IIR filtering(infinite impulse response).The dynamic model captures the essential heat and mass transfer phenomena through a nonlinear energy balance,where the cooling capacity“Qevap”is expressed as a non-linear function of the compressor frequency and the temperature difference,specifically,Q_(evap)=k_(1)u(T_(in)−T_(e))with u as compressor frequency,Te evaporator temperature,and Tin inlet fluid temperature.The operating conditions of the system,in general terms,focus on the following variables,the overall thermal capacity is 1000 J/K,typical for small-capacity heat exchangers,The mass flow is 0.05 kg/s,typical for secondary liquid cooling circuits,the overall loss coefficient of 50 W/K that corresponds to small evaporators with partial insulation,the temperatures(inlet)of 10℃and the temperature of environment of 25℃,thermal load of 200 W that corresponds to a small-scaled air conditioning applications.To handle system nonlinearities and improve control performance,aMorlet wavelet-based neural network(Wavenet)is used to dynamically adjust the PID gains online.An IIR filter is incorporated to smooth the adaptive gains,improving stability and reducing oscillations.In contrast to prior wavelet-or neural-adaptive PID controllers in HVAC applications,which typically adjust gains without explicit filtering or not tailored to evaporator dynamics,this work introduces the first PID–Wavenet scheme augmented with an IIR-based stabilization layer,specifically designed to address the combined challenges of nonlinear evaporator behavior,gain oscillation,and real-time implementability.The proposed controller(PID-Wavenet+IIR)is implemented and validated inMATLAB/Simulink,demonstrating superior performance compared to a conventional PID tuned using Simulink’s auto-tuning function.Key results include a reduction in settling time from 13.3 to 8.2 s,a reduction in overshoot from 3.5%to 0.8%,a reduction in steady-state error from 0.12℃ to 0.02℃and a 13%reduction in energy overall consumption.The controller also exhibits greater robustness and adaptability under varying thermal loads.This explicit integration of wavelet-driven adaptation with IIR-filtered gain shaping constitutes the main methodological contribution and novelty of the work.These findings validate the effectiveness of the wavelet-based adaptive approach for advanced thermal management in refrigeration and HVAC systems,with potential applications in controlling variable-speed compressors,liquid chillers,and compact cooling units.
基金financially supported by the National Natural Science Foundation of China (No.51407134, No.52002196)Natural Science Foundation of Shandong Province (No.ZR2019YQ24, No.ZR2020QF084)+2 种基金Taishan Scholars and Young Experts Program of Shandong Province (No.tsqn202103057)the Qingchuang Talents Induction Program of Shandong Higher Education Institution (Research and Innovation Team of Structural-Functional Polymer Composites)Special Financial of Shandong Province (Structural Design of Highefficiency Electromagnetic Wave-absorbing Composite Materials and Construction of Shandong Provincial Talent Teams (No. 37000022P990304116449))
文摘Although multifunctional aerogels are expected to be used in applications such as portable electronic devices,it is still a great challenge to confer multifunctionality to aerogels while maintaining their inherent microstructure.Herein,a simple method is proposed to prepare multifunctional NiCo/C aerogels with excellent electromagnetic wave absorption properties,superhydrophobicity,and self-cleaning by water-induced NiCo-MOF self-assembly.Specifically,the impedance matching of the three-dimensional(3D)structure and the interfacial polarization provided by CoNi/C as well as the defect-induced dipole polarization are the primary contributors to the broadband absorption.As a result,the prepared NiCo/C aerogels have a broadband width of 6.22 GHz at 1.9 mm.Due to the presence of hydrophobic functional groups,CoNi/C aerogels improve the stability in humid environments and obtain hydrophobicity with large contact angles>140°.This multifunctional aerogel has promising applications in electromagnetic wave absorption,resistance to water or humid environments.
基金the financial support of the Shandong Provincial Natural Science Foundation(Nos.ZR2022YQ35 and ZR2021LFG004)the Youth Innovation Promotion Association of Chinese Academy of Sciences(No.2021207).
文摘Superhydrophobic materials have shown tremendous potential in various fields.However,the adhesion,wetting,and pinning of low-surface-tension liquids greatly limit their multifunctional applications.Therefore,the creation of superamphiphobic coatings that combine superhydrophobic and superoleophobic properties through a simple preparation strategy is desirable.In this study,we successfully developed an organic-inorganic hybrid superamphiphobic coating on Q235 carbon steel using aluminum oxide nanopar-ticles,organosilanes,and waterborne epoxy resin via a versatile spray-coating technique.The coating ex-hibited high contact angles(>151°)and low sliding angles(<7°)for water and oil liquids,demonstrating excellent superamphiphobic characteristics.Electrochemical tests demonstrated significant improvements in charge transfer resistance and low-frequency modulus for the superamphiphobic coating.The corro-sion potential shifted positively by 590 mV,and the corrosion current density decreased by four orders of magnitude.Additionally,the coating endured 480 h of salt spray and 2400 h of outdoor atmospheric exposure,showcasing superior anti-corrosion capacity.Freezing tests of water droplets at-10℃and-15℃confirmed that the coating significantly prolonged the freezing time with reduced ice adhesion strength.We believe that the designed superamphiphobic coating with integrated functionalities of selfcleaning,anti-corrosion,anti-icing,and anti-liquid-adhesion can provide important solutions for extending the lifespan of materials in marine and industrial environments.
基金supports by the National Natural Science Foundation of China (No. 50871067)the National 863 Project (No. 2007AA05Z128) from the Ministry of Science and Technology of China
文摘Double-walled carbon nanotube （DWCNT） macro-films with large areas, excellent flexibility and superhydrophobicity are reported. The area of the macro-film is larger than 30 cm×15 cm, and this large film can be bended, or folded without any damage, and even can be tailored freely. After a simple modification of perfluoroalkysilane, the surface of the macro-film shows excellent superhydrophobicity with a water contact angle of 165.74-2 deg. and sliding angle lower than 3 deg., the prepared superhydrophobic films showing excellent antifouling, self-cleaning and water-repellent functions. The topographic roughness and perfluoroalkysilane modification are found to contribute to the observed superhydrophobicity. Considering the outstanding electronic, chemical and mechanical properties of DWCNTs, it is expected that this multifunctional DWCNT macro-film has potential applications in many fields.
基金Funded by the National Natural Science Foundation of China(No.21161012)
文摘Magnesium alloys with superhydrophobicity are constructed by controlling rough surface structure and grafting long hydrophobic alkyl chains. Changes of morphology, phase structure, chemical composition as well as wettability, corrosion resistance of superhydrophobic magnesium alloy upon immersing in corrosive media are investigated comparatively. Meanwhile, the contaminating particles on as-prepared superhydrophobic surfaces can be taken away easily by rolling water droplets. Therefore, the results show that as-prepared superhydrophobic magnesium alloys exhibit enhanced corrosion resistance and self-healing performance. Finally, anti-corrosion and self-cleaning mechanisms are deduced. It can be concluded that it is an effective strategy of preparing superhydrophobic surfaces for improving the corrosion resistance and selfcleaning performance of magnesium alloys.
基金financially supported by the National Natural Science Foundation of China(No.12074356)the Major/Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology(No.2018CXFX003)+1 种基金the Open Research Fund of State Key Laboratory of Pulsed Power Laser Technology(No.SKL2018KF07)Natural Science Foundation of Anhui Province(No.1808085ME131)。
文摘SiO_(2)/TiO_(2)composite films have been frequently used to realize the functions of self-cleaning and antireflection.Increasing the TiO_(2)volume ratio in SiO_(2)/TiO_(2)composite film is beneficial to enhance the self-cleaning effect,while high TiO_(2)content leads to a strong Rayleigh scattering and depresses the antireflective performance,resulting in a bottleneck problem for the dual-functional application.Here,we have achieved a high-quality TiO_(2)nanotubes film with excellent antireflective and near-perfect selfcleaning performances.Ultrasound assisted pickling method has been developed to effectively prepare the well-dispersed protonated titanate nanotubes colloid.After spin-coating and annealing treatment,glass substrate coated with double-side TiO_(2)nanotubes film has a peak transmittance of 99.2%and average transmittance of 97.4%at 400-800 nm.Ultra-high porosity of TiO_(2)nanotubes film(80%)and ultra-fine size of TiO_(2)nanotubes(8.6 nm in outer diameter)lead to excellent antireflective performance.With high UV absorptivity(80%at 254 nm)and formal quantum efficiency of stearic acid(10.9×10^(-3)),TiO_(2)nanotubes film shows near-perfect self-cleaning performance.A persistent anti-fogging ability is also presented.This study demonstrates the feasibility to fabricate pure TiO_(2)antireflective coating for glass substrate,extends application field of the classic TiO_(2)nanotubes,and sheds lights on the practical applications of high-powered TiO_(2)nanotube-based multi-functional films.
基金supported by the National Natural Science Foundation of China (Nos.51575528,51875577,51704243)Beijing Nova Program (No.Z171100001117058)+1 种基金Tribology Science Fund of State Key Laboratory of Tribology (No.SKLTKF16A06)Science Foundation of China University of Petroleum (No.2462019QNXZ02)
文摘Self-cleaning surfaces are desirable in many engineering applications where low energy consumption,reusability and sustainability are of the biggest concerns.Inspired by the gecko’s unique ’dry selfcleaning’ hierarchical structures.Here we fabricated artificial Fe304/PDMS composites that show robust self-cleaning capabilities.The enhanced adhesion performance is attributable to the decrease of PDMS polymerization degree and the load transfer between PDMS matrix and Fe304 magnetic particles.The self-cleaning surfaces showed up to 24.3% self-cleaning rate with as few as 4 steps.Simulation result indicated that the changing of cross linking between Fe304 and PDMS is the main reason for the enhanced self-cleaning surfaces.This work reveals an alternative route of making high-performance self-cleaning smart surfaces that are applicable in the textile industry,robotic locomotion/gripping technology,outerspace explorations and tissue engineering.
文摘The self-cleaning glass coated with Fe3+-TiO2 photocatalytic thin film was prepared by sol-gel process from the system Ti（OC4H9）4-NH（C2H4OH）2-C2H5OH-H2O containing FeCl3. The microstructure and properties of the film were studied using differential thermal analysis-thermogravimetry（DTA-TG）, X-ray diffration（XRD） and scanning electron microscope（SEM）. The transmittance of the self-cleaning glass was measured by using UV-Vis spectrometer. The effects of content of Fe3+ and the thickness of Fe3+-TiO2 thin film on the photocatalytic activity were examined. The results show that the photocatalytic thin films are mainly composed of Fe3O4 and TiO2 particles within 10100 nm. The appropriate amount of Fe3+ is effective for improving the photocatalytic activities of TiO2. The best photocatalytic activity is obtained when the molar ratio of Fe3+ to TiO2 is 0.005 and the glass is coated with 9 layers.
文摘How to fabricate durable superhydrophobic materials for cyclic oil/water separation to solve oil-induced pollutions is still a problem.Herein,we fabricated a durable Superhydrophobic Stainless Steel Mesh(SH-SSM)with nano/micro flower-like sheets by self-assembly of zinc stearate for the cyclic separation of various oil/water mixtures.The SH-SSM exhibits durable superhydrophobicity against static or dynamic treatments.In virtue of durable superhydrophobicity of the SH-SSM,the dusts on surface of SH-SSM can be removed completely by running water immediately showing excellent self-cleaning performance.Moreover,the SH-SSM can be used to perform gravity-driven separation of heavy oil/water and light oil/water mixtures by utilizing its superhydrophobicity that oil phase penetrates the mesh and water phase is restricted.Separation efficiencies of the SH-SSM can reach 99.99%.After 20 cycles of separation,the separation efficiencies for are>97.00%and>98.25%for heavy oil/water and light oil/water mixtures,respectively.Flux values of dichloromethane,hexane and petroleum ether are 2.5×10^(5) L m^(−2) h^(−1),1.7×10^(5) L m^(−2) h^(−1),and 1.8×10^(5) L m^(−2) h^(−1),respectively.This study proposes a facial approach to prepare durable superhydrophobic and self-cleaning material for cyclic and fast separation of oil/water.
基金financially supported by the National Natural Science Foundation of China(Nos.52071114 and 52001100)the Aviation Science Foundation of China(No.20163877014)。
文摘Daylighting structures,including solar cells and building windows,utilize sunlight whilst suffering from undesired solar heat and outdoor dust contamination.A radiative cooling system that is transparent to sunlight and has a superhydrophobic surface would cool and clean the daylighting structures in a sustainable manner.However,the majority of the current daytime radiative cooling systems were designed to fully reflect the incident sunlight to maximize the cooling power.In this work,we optimized both the sunlight transmission and infrared thermal irradiation by modeling the size-dependent scattering and absorption of light by SiO_(2)spheres embedded in a polymer matrix,we found that the use of nanospheres(20 nm)enabled both high sunlight transmittance(>90%)and infrared emissivity(-0.85).This theoretical prediction was confirmed by experimental measurements of a solution-processed nanocomposite film.When coated on a solar cell,the as-prepared film not only preserved the power conversion efficiency of the cell(14.71%,uncoated cell has an efficiency of 14.79%)but also radiatively cooled the cell by up to 5℃under direct sunlight.This reduction of the operating temperature of the solar cell further enhanced its electrical power output,evidenced by an increase in the equilibrium temperature of the LED load by about 14℃.The nanoscale textured surface formed by the nanospheres further led to superhydrophobicity and thus excellent self-cleaning performance(efficient removal of dust by wind and/or water droplets).
