Tetravalent tin(Sn^(4+))-based inorganic perovskite semiconductors like Cs_(2)SnI_(6)are expected to replace lead-based perovskite counterparts due to advantages such as structural stability and environmental friendli...Tetravalent tin(Sn^(4+))-based inorganic perovskite semiconductors like Cs_(2)SnI_(6)are expected to replace lead-based perovskite counterparts due to advantages such as structural stability and environmental friendliness.In this paper,we reported the dopant compensation effect in the component-dependent self-doped(111)-oriented Cs_(2)SnI_(6)thin films grown with pulsed laser deposition(PLD)at room temperature.The films were grown on(100)-SrTiO_(3)(STO)substrates at room temperature by PLD.Hall results of the Cs_(2)SnI_(6)films with different components realizing by controlling the ratio of SnI_(4)/CsI in the targets demonstrate a clear change of conductivity type from N-type to P-type,while the carrier concentration decreases from 1018 to 1013 and accordingly the film resistivity increases significantly from 3.8 to 2506Ωcm.The defect-relatedopticalfingerprints of Cs_(2)SnI_(6)films werealsoinvestigated withtemperature-dependent photoluminescence spectroscopy.At low temperatures of 10 K,the Cs_(2)SnI_(6)films exhibit donor-bound(D^(0)X)and donor-acceptor pair(DAP)emission,respectively,due to the self-doping effect.These re-sults indicate that controlling the composition of the PLD target is a powerful way to tune the electrical properties of Cs_(2)SnI_(6)films for possible applications in solar cells or X-ray detectors.展开更多
Urbanization alters vegetation productivity by both direct(ωd)and indirect(ω_(i))effects.The direct effect is from the change of vegetated area indicated by impervious surface intensity(ISI),while indirect effects a...Urbanization alters vegetation productivity by both direct(ωd)and indirect(ω_(i))effects.The direct effect is from the change of vegetated area indicated by impervious surface intensity(ISI),while indirect effects arise from changes in urban environmental factors,such as near-surface air temperatures,precipitation,urban heat island(UHI)intensity,and population density(POP).The respective contributions ofω_(d) andω_(i) to vegetation net primary productivity(NPP)under various phases of urbanization are not well quantified.Using multisource remote-sensing data from 1990 to 2020,we analyzed the spatiotemporal variation in urban expansion and the effect thatω_(d) andω_(i) had on NPP in the megalopolis of Beijing,China,over 5-year intervals.During this period,Beijing underwent significant planar expansion rates of about 58.9 km^(2)/yr.Annual mean loss of NPP byω_(d) was estimated to be about 77.1 g C/(m^(2)·yr)during the 1990-2020 period,while annual mean improvement to NPP byω_(i) amounted to an increase of 28.9 g C/(m^(2)·yr).The NPP losses were partially offset by NPP improvements in the order of 18.6%-69.3%.The impact of forcing variables on NPP varied spatially.Air temperature,precipitation,UHI,POP,and ISI explained about 13.8%,23.2%,23.7%,14.7%,and 24.6%of the spatial variation in NPP.The impact of air temperature on NPP was related to available moisture,negatively affecting NPP in regions with water deficits.Our findings demonstrate the dual impact of urbanization on vegetation and underscore the necessity for spatially adaptive ecological management strategies in regions experiencing rapid urban growth.展开更多
In this study,the mechanism and characteristics of the responseαparticles and the damage caused by them in CMOS active pixel(APS)sensors were investigated.A detection and compensation algorithm for dead pixels caused...In this study,the mechanism and characteristics of the responseαparticles and the damage caused by them in CMOS active pixel(APS)sensors were investigated.A detection and compensation algorithm for dead pixels caused byαparticle ionizing radiation was proposed,and the effects of dead-pixel compensation algorithms were compared and analyzed under different parameter conditions.The experimental results show thatαparticle response signal has highest accuracy at 9 dB gain,with an obvious“target-ring”distribution.With increasing cumulative dose,the CMOS APS pedestal tends to saturation while dead pixels continue increasing.Though some pixel damage recovers through natural annealing,the dead-to-noise ratio increases with irradiation time,reaching 32.54%after 72 h.A hierarchical clustering dead-pixel detection method is proposed,categorizing pixels into two types:those within and outside the response event.A classification compensation strategy combining mean and majority filtering is proposed.This compensation algorithm can address dead-pixel interference without affectingαparticle radiation response data.When iterated multiple times and with integration time exceeding 6.31 ms,the number of dead pixels can be effectively reduced.展开更多
The development of electrocatalysts that both work effectively at industrial current density and resist chloride ion(Cl^(-))corrosion remains a key challenge for hydrogen production from Cl^(-)-rich alkaline water.Her...The development of electrocatalysts that both work effectively at industrial current density and resist chloride ion(Cl^(-))corrosion remains a key challenge for hydrogen production from Cl^(-)-rich alkaline water.Herein,we report a CrO_(x)-engineered nickel-based oxide catalyst(FeCoCrO_(x)/NF)that achieves exceptional activity and stability through a dual-functional interfacial mechanism.Combing in situ Raman spectroscopy,18O isotopic labeling,and electrochemical analysis,we demonstrate that the oxygen evolution reaction follows a lattice oxygen-mediated mechanism.The CrO_(x)layer selectively adsorbs hydroxide ions,forming a dynamic interfacial barrier that electrostatically repels Cl^(-)ingress,thereby mitigating Cl^(-)corrosion.Through enthalpy-based analysis,we demonstrate that electronic redistribution via Cr-O-Fe bonding increases the vacancy formation energy of Fe,thereby suppressing its dissolution.In alkaline electrolyte containing 0.5 M Cl^(-)(1.0 M KOH),the catalyst is operating continuously for 1400 h at an industrial current density of 1000 mA cm^(-2).Furthermore,the catalyst retains 99.5%of its initial activity under fluctuating current density(100-1000 mA cm^(-2)),demonstrating robustness required for industrial electrolyzers.This study establishes a paradigm for designing corrosion-resistant electrocatalysts through the synergistic modulation of interfacial ion selectivity and bulk lattice oxygen activation,advancing the application of green hydrogen production in Cl^(-)-rich alkaline water.展开更多
The Grassland Ecological Compensation Policy(GECP)is a large-scale project that has been investing in China since 2011.Despite the significant investment and long duration of the GECP,its impact on carbon sequestratio...The Grassland Ecological Compensation Policy(GECP)is a large-scale project that has been investing in China since 2011.Despite the significant investment and long duration of the GECP,its impact on carbon sequestration in grasslands remains unclear.Based on panel data from prefecture-level cities in the Yellow River Basin(YRB)from 2000 to 2020,this study explored the effects of the GECP on grassland carbon sequestration in the YRB and its heterogeneity using a time-varying difference-in-differences(TV-DID)model.Subsequently,we predicted changes in carbon sequestration in grasslands under the influence of the GECP from 2021 to 2040 using a simulation.The main conclusions are as follows:First,the implementation of the GECP promoted carbon sequestration in grasslands.This conclusion was validated after conducting a series of robustness tests.Moreover,the effects of the GECP were heterogeneous across different geographical locations,highway densities,and grassland areas.Finally,the simulation results indicated that over the next 20 years,grassland carbon sequestration will generally increase but exhibit cyclical changes.The government should align the principles and objectives of the GECP with local geographic conditions,resource availability,and socio-economic development.It must formulate and implement tailored policies that maximize the ecological protection benefits of the GECP and promote carbon sequestration in the grasslands of the YRB.展开更多
Self-trapped excitons(STEs),known for their unique radiative properties,have been harnessed in diverse photonic devices;however,their comprehensive understanding and manipulation remain elusive.In this study,we presen...Self-trapped excitons(STEs),known for their unique radiative properties,have been harnessed in diverse photonic devices;however,their comprehensive understanding and manipulation remain elusive.In this study,we present novel experimental and theoretical evidence revealing the hybrid nature and optical tunability of STE state in Cs_(2)Ag_(0.4)Na_(0.6)InCl_(6).The detection of the Fano resonance in laser energy-dependent Raman and photoluminescence spectra indicates the emergence of an exciton-phonon hybrid state,arising from robust quantum interference between the discrete phonon and continuum exciton states.Moreover,we demonstrate continuous tuning of this hybrid state with the energy and intensity of the laser field.These findings lay the foundation for a comprehensive understanding of the nature of STE and their potential for state control.展开更多
Self-supported nanoarrays have emerged as a promising alternative electrocatalyst for alkaline H_(2)O splitting,owing to their accessible active sites and strongly coupled interfaces with current collectors for improv...Self-supported nanoarrays have emerged as a promising alternative electrocatalyst for alkaline H_(2)O splitting,owing to their accessible active sites and strongly coupled interfaces with current collectors for improved mass transfer and stability.Herein,self-supported crystalline/amorphous NiO/Ni(OH)_(2)nanosheet arrays on nickel foam(NF)are fabricated via an in-situ dissolution-deposition hydrothermal growing of Ni(OH)_(2)nanosheets without additional metal sources assisted by a common Lewis base,EDTA,followed by a rapid calcination at 300℃in air.The as-prepared EDTA-NF-12 h exhibits high OER and HER performance under alkaline conditions,requiring 235 mV and 158 mV,respectively,to reach 10 mA cm^(-2),and the decent performance can be maintained for 24 h without obvious degradation.The dual interfaces,i.e.,the dense crystalline/amorphous interfaces within the NiO/Ni(OH)_(2)nanosheet arrays,as well as the intimate interfaces between nanoarrays and NF,both serve as reaction active sites,facilitate electron transfer,and endow the catalyst with high activity and stability.Furthermore,by applying EDTA-Ni^(2+)and other Lewis bases with varying basicities instead of EDTA,the interfaces with the NF substrate are found to promote the formation of crystalline/amorphous interfaces within the nanosheets.This study offers appealing opportunities for tailoring the electrocatalytic performance of self-supported electrodes via dual interface engineering.展开更多
Measuring cross sections of nuclear reactions,such as the so-called“Holy Grail”reaction,^(12)C(σ,γ)^(16)O,is essential for understanding stellar nucleosynthesis but presents significant challenges due to extremely...Measuring cross sections of nuclear reactions,such as the so-called“Holy Grail”reaction,^(12)C(σ,γ)^(16)O,is essential for understanding stellar nucleosynthesis but presents significant challenges due to extremely low cross sections.Key challenges include significant energy loss as ions penetrate the target material,limiting measurements to thin target layers.To overcome these obstacles,we propose a novel method,the in-target energy loss compensating(eLOC)method,specifically designed for gas targets,which utilizes a gas-filled magnetic field and accelerating electric fields to compensate for ion energy loss in the target.Simulations show that this approach significantly enhances the effective target thickness by over 140 times in the case of the“Holy Grail”reaction with an inverse-kinematics setup.This eLOC method may provide a powerful new tool for obtaining critical data in nuclear astrophysics,thereby advancing our understanding of stellar nucleosynthesis and the origins of elements in the universe,as well as benefiting other related fields such as isotope production.展开更多
Aim Aiming at the position tracking control for valve controlled motor electrohydraulic proportional servo systems mainly driving the static load torque, the tracking performance was studied in the presence of the v...Aim Aiming at the position tracking control for valve controlled motor electrohydraulic proportional servo systems mainly driving the static load torque, the tracking performance was studied in the presence of the variable gain and deadzone. Methods On the basis of conventional composite control with the deadzone compensation method, a comprehensive control approach with the deadzone and self adjusting feedforward compensation was proposed. Results Experimental results showed that the good tracking performance was achieved for the sinusoidal and constant velocity position tracking under a wide variations of load torque. Conclusion The position tracking accuracy for valve controlled motor electrohydraulic proportional servo systems has been solved by using the comprehensive control approach with the deadzone and self adjusting feedforward compensation.展开更多
In order to deal with the dynamic positioning system control problems of dredgers working under strong dredging reaction or harsh environments,an adaptive backstepping method is proposed.Disturbances are estimated and...In order to deal with the dynamic positioning system control problems of dredgers working under strong dredging reaction or harsh environments,an adaptive backstepping method is proposed.Disturbances are estimated and compensated for by the adaptive method without extra sensors on dredging equipment,and the control mechanism is simplified.Adaptive control is used to compensate for the reaction and environmental disturbances on the dredger,so the dredger can maintain the desired position with a minimum error and shock.The proposed adaptive robust controller guarantees the global asymptotic stability of the closed-loop system and rapid position tracking of the dredger.The simulation results show that the proposed controller has superior performance in position tracking and robustness to large disturbances.展开更多
Microstructured roll workpieces have been widely used as functional components in the precision industries. Current researches on quality control have focused on surface profile measurement of microstructured roll wor...Microstructured roll workpieces have been widely used as functional components in the precision industries. Current researches on quality control have focused on surface profile measurement of microstructured roll workpieces, and types of measurement systems and measurement methods have been developed. However, low measurement efficiency and low measurement accuracy caused by setting errors are the common disadvantages for surface profile measurement of microstructured roll workpieces. In order to shorten the measurement time and enhance the measurement accuracy, a method for self-calibration and compensation of setting errors is proposed for surface profile measurement of microstructured roll workpieces. A measurement system is constructed for the measurement, in which a precision spindle is employed to rotate the roll workpiece and an air-bearing displacement sensor with a micro-stylus probe is employed to scan the microstructured surface of the roll workpiece. The resolution of the displacement sensor is 0.14 nm and that of the rotary encoder of the spindle was 0.15r~. Geometrical and mathematical models are established for analyzing the influences of the setting errors of the roll workpiece and the displacement sensor with respect to the axis of the spindle, including the eccentric error of the roll workpiece, the offset error of the sensor axis and the zero point error of the sensor output. Measurement experiments are carded out on a roll workpiece on which periodic microstructures are a period of 133 i^m along the circumferential direction. Experimental results demonstrate the feasibility of the self-compensation method. The proposed method can be used to detect and compensate the setting errors without using any additional accurate artifact.展开更多
The micro-Doppler effect of moving targets may suffer from aliasing and Doppler migration due to the translational motion, which affects the application in real-time target identification. A new compensating method fo...The micro-Doppler effect of moving targets may suffer from aliasing and Doppler migration due to the translational motion, which affects the application in real-time target identification. A new compensating method for the rotationally symmetric target is proposed and demonstrated. By utilizing the micro-Doppler symmetry cancellation effect, the method can accurately compensate the translation effect, meanwhile, it behaves well in noise restraint. Computer simulations verify the high accuracy and efficiency of this method.展开更多
The spherical plain bearing test bench is a necessary detecting equipment in the research process of self?lubricating spherical plain bearings. The varying environmental temperatures cause the thermal deformation of t...The spherical plain bearing test bench is a necessary detecting equipment in the research process of self?lubricating spherical plain bearings. The varying environmental temperatures cause the thermal deformation of the wear?depth detecting system of bearing test benches and then a ect the accuracy of the wear?depth detecting data. However, few researches about the spherical plain bearing test benches can be found with the implementation of the detect?ing error compensation. Based on the self?made modular spherical plain bearing test bench, two main causes of ther?mal errors, the friction heat of bearings and the environmental temperature variation, are analysed. The thermal errors caused by the friction heat of bearings are calculated, and the thermal deformation of the wear?depth detecting sys?tem caused by the varying environmental temperatures is detected. In view of the above results, the environmental temperature variation is the main cause of the two error factors. When the environmental temperatures rise is 10.3 °C, the thermal deformation is approximately 0.01 mm. In addition, the comprehensive compensating model of the thermal error of the wear?depth detecting system is built by multiple linear regression(MLR) and time series analysis. Compared with the detecting data of the thermal errors, the comprehensive compensating model has higher fitting precision, and the maximum residual is only 1 μm. A comprehensive compensating model of the thermal error of the wear?depth detecting system is proposed, which provides a theoretical basis for the improvement of the real?time wear?depth detecting precision of the spherical plain bearing test bench.展开更多
Combined with the parameters of the production process of a steel factory, numerical simulations for a new ladle from preheating to turnover are conducted using the finite element analysis system software （ANSYS）. T...Combined with the parameters of the production process of a steel factory, numerical simulations for a new ladle from preheating to turnover are conducted using the finite element analysis system software （ANSYS）. The measured data proved that the simulated results are reliable. The effects of preheating time, thermal cycling times, and empty package time on steel temperature are calculated, an ideal preheating time is provided, besides, based on the analysis of a single factor and use the nonlinear analysis method, a steel temperature compensating model with di- versified coupling factors is proposed, with the largest error of the present coupling model at 1. 462 ~C, and the er- rors between actual and target steel temperature in tundish after the model is applied to practical production are basi- cally controlled within -4-6 ~C, which can meet the accuracy of the manufacturer and has a practical guiding significance for the production in steelmaking workshops.展开更多
According to the Doppler sensitive of the phase coded pulse compression signal, a Doppler estimating and compensating method based on phase is put forward to restrain the Doppler sidelobes, raise the signal-to-noise r...According to the Doppler sensitive of the phase coded pulse compression signal, a Doppler estimating and compensating method based on phase is put forward to restrain the Doppler sidelobes, raise the signal-to-noise ratio and improve measuring resolution. The compensation method is used to decompose the echo to amplitude and phase, and then compose the new compensated echo by the amplitude and the nonlinear component of the phase. Furthermore the linear component of the phase can be used to estimate the Doppler frequency shift. The computer simulation and the real data processing show that the method has accurately estimated the Doppler frequency shift, successfully restrained the energy leakage on spectrum, greatly increased the echo signal-to-noise ratio and improved the detection performance of the radio system in both time domain and frequency domain.展开更多
In the docking process of aeroengine rotor parts,docking accuracy that indicates the gaps between the end faces is strictly required.A key issue is improving docking accuracy using automated docking equipment.In this ...In the docking process of aeroengine rotor parts,docking accuracy that indicates the gaps between the end faces is strictly required.A key issue is improving docking accuracy using automated docking equipment.In this paper,a systematic study is carried out on the error modeling and compensation of a novel six-degrees-of-freedom(6-DOF)docking equipment for aeroengine rotors.First,a new model for indicating the main indexes of docking accuracy is proposed.Then,the error model of a specially designed 6-DOF docking equipment is established based on a modified Denavit Hartenberg method with five parameters.Subsequently,two error compensation methods are proposed.Based on the above models,a docking accuracy simulation algorithm is proposed using the Monte Carlo method.Finally,verification experiments are conducted.The results show that,for the maximum values and standard deviations of the gaps between the rotor end-faces in the actual and target positions and attitudes,i.e.,main indexes that represent docking accuracy,the deviation rates between the simulation and experimental results are less than20%.The modeling methods have referential significance.The decline rates of these values are 50–65%when using the two proposed compensation methods.The compensation methods significantly improve the docking accuracy.展开更多
To solve the rate-dependent hysteresis compensation problem in fast steering mirror(FSM) systems, an improved Prandtl-Ishlinskii(P-I) model is proposed in this paper. The proposed model is formulated by employing a li...To solve the rate-dependent hysteresis compensation problem in fast steering mirror(FSM) systems, an improved Prandtl-Ishlinskii(P-I) model is proposed in this paper. The proposed model is formulated by employing a linear density function into the STOP operator. By this way, the proposed model has a relatively simple mathematic format, which can be applied to compensate the rate-dependent hysteresis directly. Adaptive differential evolution algorithm is utilized to obtain the accurate parameters of the proposed model. A fast steering mirror control system is established to demonstrate the validity and feasibility of the improved P-I model. Comparative experiments with different input signals are performed and analyzed, and the results show that the proposed model not only suppresses the rate-dependent hysteresis effectively, but also obtains high tracking precision.展开更多
Dispersion and nonlinear distortion have an effect on transmission performanc es of optic al fiber transimission systems. The schemes of dispersion compensation and nonli near distortion self-compens ation in telecom-...Dispersion and nonlinear distortion have an effect on transmission performanc es of optic al fiber transimission systems. The schemes of dispersion compensation and nonli near distortion self-compens ation in telecom-CATV co-network transmission systems are reported, followed by investigation on (1) the impact of dispersion compensation fiber (DCF) on fi ber nonlinear effects with a cascade of erbium-doped fiber amplifiers (EDFAs) an d different dispersion compensation schemes, (2) the impact of the complex on th e total nonlinear distortion induced by EDFA gain tilt and the light source. As a result , dispersion compensation optimal scheme and EDFA negative gain tilt are suggest ed as a solution to dispersion compensation and the nonlinear distortion self-c ompensation.展开更多
基金financially supported by the National Key Re-search and Development Program of China(No.2022YFC3700801)the Key R&D Program of Shandong Province,China(No.2024SFGC0102),the Jinan Bureau of Education(No.JNSX2023015)the Jinan Bureau of Science and Technology(No.202333042).
文摘Tetravalent tin(Sn^(4+))-based inorganic perovskite semiconductors like Cs_(2)SnI_(6)are expected to replace lead-based perovskite counterparts due to advantages such as structural stability and environmental friendliness.In this paper,we reported the dopant compensation effect in the component-dependent self-doped(111)-oriented Cs_(2)SnI_(6)thin films grown with pulsed laser deposition(PLD)at room temperature.The films were grown on(100)-SrTiO_(3)(STO)substrates at room temperature by PLD.Hall results of the Cs_(2)SnI_(6)films with different components realizing by controlling the ratio of SnI_(4)/CsI in the targets demonstrate a clear change of conductivity type from N-type to P-type,while the carrier concentration decreases from 1018 to 1013 and accordingly the film resistivity increases significantly from 3.8 to 2506Ωcm.The defect-relatedopticalfingerprints of Cs_(2)SnI_(6)films werealsoinvestigated withtemperature-dependent photoluminescence spectroscopy.At low temperatures of 10 K,the Cs_(2)SnI_(6)films exhibit donor-bound(D^(0)X)and donor-acceptor pair(DAP)emission,respectively,due to the self-doping effect.These re-sults indicate that controlling the composition of the PLD target is a powerful way to tune the electrical properties of Cs_(2)SnI_(6)films for possible applications in solar cells or X-ray detectors.
基金supported by the National Key Research and Develop-ment Program of China(No.2020YFA0608100)the National Nat-ural Science Foundation of China(Nos.32071842 and 32101588).
文摘Urbanization alters vegetation productivity by both direct(ωd)and indirect(ω_(i))effects.The direct effect is from the change of vegetated area indicated by impervious surface intensity(ISI),while indirect effects arise from changes in urban environmental factors,such as near-surface air temperatures,precipitation,urban heat island(UHI)intensity,and population density(POP).The respective contributions ofω_(d) andω_(i) to vegetation net primary productivity(NPP)under various phases of urbanization are not well quantified.Using multisource remote-sensing data from 1990 to 2020,we analyzed the spatiotemporal variation in urban expansion and the effect thatω_(d) andω_(i) had on NPP in the megalopolis of Beijing,China,over 5-year intervals.During this period,Beijing underwent significant planar expansion rates of about 58.9 km^(2)/yr.Annual mean loss of NPP byω_(d) was estimated to be about 77.1 g C/(m^(2)·yr)during the 1990-2020 period,while annual mean improvement to NPP byω_(i) amounted to an increase of 28.9 g C/(m^(2)·yr).The NPP losses were partially offset by NPP improvements in the order of 18.6%-69.3%.The impact of forcing variables on NPP varied spatially.Air temperature,precipitation,UHI,POP,and ISI explained about 13.8%,23.2%,23.7%,14.7%,and 24.6%of the spatial variation in NPP.The impact of air temperature on NPP was related to available moisture,negatively affecting NPP in regions with water deficits.Our findings demonstrate the dual impact of urbanization on vegetation and underscore the necessity for spatially adaptive ecological management strategies in regions experiencing rapid urban growth.
基金supported by the National Natural Science Foundation of China(No.11905102)Hunan Provincial Postgraduate Research and Innovation Project(No.QL20230234)。
文摘In this study,the mechanism and characteristics of the responseαparticles and the damage caused by them in CMOS active pixel(APS)sensors were investigated.A detection and compensation algorithm for dead pixels caused byαparticle ionizing radiation was proposed,and the effects of dead-pixel compensation algorithms were compared and analyzed under different parameter conditions.The experimental results show thatαparticle response signal has highest accuracy at 9 dB gain,with an obvious“target-ring”distribution.With increasing cumulative dose,the CMOS APS pedestal tends to saturation while dead pixels continue increasing.Though some pixel damage recovers through natural annealing,the dead-to-noise ratio increases with irradiation time,reaching 32.54%after 72 h.A hierarchical clustering dead-pixel detection method is proposed,categorizing pixels into two types:those within and outside the response event.A classification compensation strategy combining mean and majority filtering is proposed.This compensation algorithm can address dead-pixel interference without affectingαparticle radiation response data.When iterated multiple times and with integration time exceeding 6.31 ms,the number of dead pixels can be effectively reduced.
基金supported by the National Nature Science Foundation of China under Grant No.22269021the Tianshan Talent Project of Xinjiang Uygur Autonomous Region:2023TSYCQNTJ0039the Open project of Key Laboratory in Xinjiang Uygur Autonomous Region of China:2023D04027。
文摘The development of electrocatalysts that both work effectively at industrial current density and resist chloride ion(Cl^(-))corrosion remains a key challenge for hydrogen production from Cl^(-)-rich alkaline water.Herein,we report a CrO_(x)-engineered nickel-based oxide catalyst(FeCoCrO_(x)/NF)that achieves exceptional activity and stability through a dual-functional interfacial mechanism.Combing in situ Raman spectroscopy,18O isotopic labeling,and electrochemical analysis,we demonstrate that the oxygen evolution reaction follows a lattice oxygen-mediated mechanism.The CrO_(x)layer selectively adsorbs hydroxide ions,forming a dynamic interfacial barrier that electrostatically repels Cl^(-)ingress,thereby mitigating Cl^(-)corrosion.Through enthalpy-based analysis,we demonstrate that electronic redistribution via Cr-O-Fe bonding increases the vacancy formation energy of Fe,thereby suppressing its dissolution.In alkaline electrolyte containing 0.5 M Cl^(-)(1.0 M KOH),the catalyst is operating continuously for 1400 h at an industrial current density of 1000 mA cm^(-2).Furthermore,the catalyst retains 99.5%of its initial activity under fluctuating current density(100-1000 mA cm^(-2)),demonstrating robustness required for industrial electrolyzers.This study establishes a paradigm for designing corrosion-resistant electrocatalysts through the synergistic modulation of interfacial ion selectivity and bulk lattice oxygen activation,advancing the application of green hydrogen production in Cl^(-)-rich alkaline water.
基金supported by the National Natural Science Foundation of China[Grant No.71773091]the Graduate Student Science and Technology Innovation Program of College of Economics and Management[Grant No.JGYJSCXXM202308].
文摘The Grassland Ecological Compensation Policy(GECP)is a large-scale project that has been investing in China since 2011.Despite the significant investment and long duration of the GECP,its impact on carbon sequestration in grasslands remains unclear.Based on panel data from prefecture-level cities in the Yellow River Basin(YRB)from 2000 to 2020,this study explored the effects of the GECP on grassland carbon sequestration in the YRB and its heterogeneity using a time-varying difference-in-differences(TV-DID)model.Subsequently,we predicted changes in carbon sequestration in grasslands under the influence of the GECP from 2021 to 2040 using a simulation.The main conclusions are as follows:First,the implementation of the GECP promoted carbon sequestration in grasslands.This conclusion was validated after conducting a series of robustness tests.Moreover,the effects of the GECP were heterogeneous across different geographical locations,highway densities,and grassland areas.Finally,the simulation results indicated that over the next 20 years,grassland carbon sequestration will generally increase but exhibit cyclical changes.The government should align the principles and objectives of the GECP with local geographic conditions,resource availability,and socio-economic development.It must formulate and implement tailored policies that maximize the ecological protection benefits of the GECP and promote carbon sequestration in the grasslands of the YRB.
基金funding support from the National Natural Science Foundation of China(Grant No.12525405)funding support from the National Natural Science Foundation of China(Grant No.12393831)the CAS Project for Young Scientists in Basic Research(Grant No.YSBR-120)。
文摘Self-trapped excitons(STEs),known for their unique radiative properties,have been harnessed in diverse photonic devices;however,their comprehensive understanding and manipulation remain elusive.In this study,we present novel experimental and theoretical evidence revealing the hybrid nature and optical tunability of STE state in Cs_(2)Ag_(0.4)Na_(0.6)InCl_(6).The detection of the Fano resonance in laser energy-dependent Raman and photoluminescence spectra indicates the emergence of an exciton-phonon hybrid state,arising from robust quantum interference between the discrete phonon and continuum exciton states.Moreover,we demonstrate continuous tuning of this hybrid state with the energy and intensity of the laser field.These findings lay the foundation for a comprehensive understanding of the nature of STE and their potential for state control.
基金the foundation of Guangdong Engineering Technology Research Center for Hydrogen Energy and Fuel Cells,the Guangdong Provincial Department of Education Innovation Project(No.2022KQNCX056)the Guangdong Basic and Applied Basic Research Foundation(Nos.2022A1515110354 and 2021A1515110582)。
文摘Self-supported nanoarrays have emerged as a promising alternative electrocatalyst for alkaline H_(2)O splitting,owing to their accessible active sites and strongly coupled interfaces with current collectors for improved mass transfer and stability.Herein,self-supported crystalline/amorphous NiO/Ni(OH)_(2)nanosheet arrays on nickel foam(NF)are fabricated via an in-situ dissolution-deposition hydrothermal growing of Ni(OH)_(2)nanosheets without additional metal sources assisted by a common Lewis base,EDTA,followed by a rapid calcination at 300℃in air.The as-prepared EDTA-NF-12 h exhibits high OER and HER performance under alkaline conditions,requiring 235 mV and 158 mV,respectively,to reach 10 mA cm^(-2),and the decent performance can be maintained for 24 h without obvious degradation.The dual interfaces,i.e.,the dense crystalline/amorphous interfaces within the NiO/Ni(OH)_(2)nanosheet arrays,as well as the intimate interfaces between nanoarrays and NF,both serve as reaction active sites,facilitate electron transfer,and endow the catalyst with high activity and stability.Furthermore,by applying EDTA-Ni^(2+)and other Lewis bases with varying basicities instead of EDTA,the interfaces with the NF substrate are found to promote the formation of crystalline/amorphous interfaces within the nanosheets.This study offers appealing opportunities for tailoring the electrocatalytic performance of self-supported electrodes via dual interface engineering.
基金supported by the the National Key R&D Program of China (Grant Nos.2023YFA1606900 and 2022YFA1602301)the National Natural Science Foundation of China (Grant Nos.12235003,12435010,and 12147101)+3 种基金the Guangdong Major Project of Basic and Applied Basic Research (Grant No.2020B0301030008)the STCSM (Grant No.23590780100)the Natural Science Foundation of Shanghai (Grant No.23JC1400200)the China Postdoctoral Science Foundation (Grant No.2024M760483)。
文摘Measuring cross sections of nuclear reactions,such as the so-called“Holy Grail”reaction,^(12)C(σ,γ)^(16)O,is essential for understanding stellar nucleosynthesis but presents significant challenges due to extremely low cross sections.Key challenges include significant energy loss as ions penetrate the target material,limiting measurements to thin target layers.To overcome these obstacles,we propose a novel method,the in-target energy loss compensating(eLOC)method,specifically designed for gas targets,which utilizes a gas-filled magnetic field and accelerating electric fields to compensate for ion energy loss in the target.Simulations show that this approach significantly enhances the effective target thickness by over 140 times in the case of the“Holy Grail”reaction with an inverse-kinematics setup.This eLOC method may provide a powerful new tool for obtaining critical data in nuclear astrophysics,thereby advancing our understanding of stellar nucleosynthesis and the origins of elements in the universe,as well as benefiting other related fields such as isotope production.
文摘Aim Aiming at the position tracking control for valve controlled motor electrohydraulic proportional servo systems mainly driving the static load torque, the tracking performance was studied in the presence of the variable gain and deadzone. Methods On the basis of conventional composite control with the deadzone compensation method, a comprehensive control approach with the deadzone and self adjusting feedforward compensation was proposed. Results Experimental results showed that the good tracking performance was achieved for the sinusoidal and constant velocity position tracking under a wide variations of load torque. Conclusion The position tracking accuracy for valve controlled motor electrohydraulic proportional servo systems has been solved by using the comprehensive control approach with the deadzone and self adjusting feedforward compensation.
基金The National Basic Research Program of China (973 Program) (No. 2005CB221505)Open Fund of Provincial Open Laboratory for Control Engineering Key Disciplines (No. KG2009-02)
文摘In order to deal with the dynamic positioning system control problems of dredgers working under strong dredging reaction or harsh environments,an adaptive backstepping method is proposed.Disturbances are estimated and compensated for by the adaptive method without extra sensors on dredging equipment,and the control mechanism is simplified.Adaptive control is used to compensate for the reaction and environmental disturbances on the dredger,so the dredger can maintain the desired position with a minimum error and shock.The proposed adaptive robust controller guarantees the global asymptotic stability of the closed-loop system and rapid position tracking of the dredger.The simulation results show that the proposed controller has superior performance in position tracking and robustness to large disturbances.
文摘Microstructured roll workpieces have been widely used as functional components in the precision industries. Current researches on quality control have focused on surface profile measurement of microstructured roll workpieces, and types of measurement systems and measurement methods have been developed. However, low measurement efficiency and low measurement accuracy caused by setting errors are the common disadvantages for surface profile measurement of microstructured roll workpieces. In order to shorten the measurement time and enhance the measurement accuracy, a method for self-calibration and compensation of setting errors is proposed for surface profile measurement of microstructured roll workpieces. A measurement system is constructed for the measurement, in which a precision spindle is employed to rotate the roll workpiece and an air-bearing displacement sensor with a micro-stylus probe is employed to scan the microstructured surface of the roll workpiece. The resolution of the displacement sensor is 0.14 nm and that of the rotary encoder of the spindle was 0.15r~. Geometrical and mathematical models are established for analyzing the influences of the setting errors of the roll workpiece and the displacement sensor with respect to the axis of the spindle, including the eccentric error of the roll workpiece, the offset error of the sensor axis and the zero point error of the sensor output. Measurement experiments are carded out on a roll workpiece on which periodic microstructures are a period of 133 i^m along the circumferential direction. Experimental results demonstrate the feasibility of the self-compensation method. The proposed method can be used to detect and compensate the setting errors without using any additional accurate artifact.
文摘The micro-Doppler effect of moving targets may suffer from aliasing and Doppler migration due to the translational motion, which affects the application in real-time target identification. A new compensating method for the rotationally symmetric target is proposed and demonstrated. By utilizing the micro-Doppler symmetry cancellation effect, the method can accurately compensate the translation effect, meanwhile, it behaves well in noise restraint. Computer simulations verify the high accuracy and efficiency of this method.
基金Supported by National Natural Science Foundation of China(Grant No.51405422)Hebei Provincial Natural Science Foundation of China(Grant No.E2015203113)Technological Innovation Fund of Aviation Industry of China(Grant No.2014E00468R)
文摘The spherical plain bearing test bench is a necessary detecting equipment in the research process of self?lubricating spherical plain bearings. The varying environmental temperatures cause the thermal deformation of the wear?depth detecting system of bearing test benches and then a ect the accuracy of the wear?depth detecting data. However, few researches about the spherical plain bearing test benches can be found with the implementation of the detect?ing error compensation. Based on the self?made modular spherical plain bearing test bench, two main causes of ther?mal errors, the friction heat of bearings and the environmental temperature variation, are analysed. The thermal errors caused by the friction heat of bearings are calculated, and the thermal deformation of the wear?depth detecting sys?tem caused by the varying environmental temperatures is detected. In view of the above results, the environmental temperature variation is the main cause of the two error factors. When the environmental temperatures rise is 10.3 °C, the thermal deformation is approximately 0.01 mm. In addition, the comprehensive compensating model of the thermal error of the wear?depth detecting system is built by multiple linear regression(MLR) and time series analysis. Compared with the detecting data of the thermal errors, the comprehensive compensating model has higher fitting precision, and the maximum residual is only 1 μm. A comprehensive compensating model of the thermal error of the wear?depth detecting system is proposed, which provides a theoretical basis for the improvement of the real?time wear?depth detecting precision of the spherical plain bearing test bench.
基金Item Sponsored by Technology Supporting Program During the 11th Five-Year Plan Period(BAE03A07)
文摘Combined with the parameters of the production process of a steel factory, numerical simulations for a new ladle from preheating to turnover are conducted using the finite element analysis system software （ANSYS）. The measured data proved that the simulated results are reliable. The effects of preheating time, thermal cycling times, and empty package time on steel temperature are calculated, an ideal preheating time is provided, besides, based on the analysis of a single factor and use the nonlinear analysis method, a steel temperature compensating model with di- versified coupling factors is proposed, with the largest error of the present coupling model at 1. 462 ~C, and the er- rors between actual and target steel temperature in tundish after the model is applied to practical production are basi- cally controlled within -4-6 ~C, which can meet the accuracy of the manufacturer and has a practical guiding significance for the production in steelmaking workshops.
基金supported partly by the National Natural Science Foundation of China(40804042)the Post DoctorFoundation of China(20070420919).
文摘According to the Doppler sensitive of the phase coded pulse compression signal, a Doppler estimating and compensating method based on phase is put forward to restrain the Doppler sidelobes, raise the signal-to-noise ratio and improve measuring resolution. The compensation method is used to decompose the echo to amplitude and phase, and then compose the new compensated echo by the amplitude and the nonlinear component of the phase. Furthermore the linear component of the phase can be used to estimate the Doppler frequency shift. The computer simulation and the real data processing show that the method has accurately estimated the Doppler frequency shift, successfully restrained the energy leakage on spectrum, greatly increased the echo signal-to-noise ratio and improved the detection performance of the radio system in both time domain and frequency domain.
基金supported by Innovative Research Group Project of the National Natural Science Foundation of China (No. 51621064)
文摘In the docking process of aeroengine rotor parts,docking accuracy that indicates the gaps between the end faces is strictly required.A key issue is improving docking accuracy using automated docking equipment.In this paper,a systematic study is carried out on the error modeling and compensation of a novel six-degrees-of-freedom(6-DOF)docking equipment for aeroengine rotors.First,a new model for indicating the main indexes of docking accuracy is proposed.Then,the error model of a specially designed 6-DOF docking equipment is established based on a modified Denavit Hartenberg method with five parameters.Subsequently,two error compensation methods are proposed.Based on the above models,a docking accuracy simulation algorithm is proposed using the Monte Carlo method.Finally,verification experiments are conducted.The results show that,for the maximum values and standard deviations of the gaps between the rotor end-faces in the actual and target positions and attitudes,i.e.,main indexes that represent docking accuracy,the deviation rates between the simulation and experimental results are less than20%.The modeling methods have referential significance.The decline rates of these values are 50–65%when using the two proposed compensation methods.The compensation methods significantly improve the docking accuracy.
基金supported by the Twelfth Five Year Research Project(No.2015syhz0023)
文摘To solve the rate-dependent hysteresis compensation problem in fast steering mirror(FSM) systems, an improved Prandtl-Ishlinskii(P-I) model is proposed in this paper. The proposed model is formulated by employing a linear density function into the STOP operator. By this way, the proposed model has a relatively simple mathematic format, which can be applied to compensate the rate-dependent hysteresis directly. Adaptive differential evolution algorithm is utilized to obtain the accurate parameters of the proposed model. A fast steering mirror control system is established to demonstrate the validity and feasibility of the improved P-I model. Comparative experiments with different input signals are performed and analyzed, and the results show that the proposed model not only suppresses the rate-dependent hysteresis effectively, but also obtains high tracking precision.
文摘Dispersion and nonlinear distortion have an effect on transmission performanc es of optic al fiber transimission systems. The schemes of dispersion compensation and nonli near distortion self-compens ation in telecom-CATV co-network transmission systems are reported, followed by investigation on (1) the impact of dispersion compensation fiber (DCF) on fi ber nonlinear effects with a cascade of erbium-doped fiber amplifiers (EDFAs) an d different dispersion compensation schemes, (2) the impact of the complex on th e total nonlinear distortion induced by EDFA gain tilt and the light source. As a result , dispersion compensation optimal scheme and EDFA negative gain tilt are suggest ed as a solution to dispersion compensation and the nonlinear distortion self-c ompensation.
