Owing to unique advantages of patternability and high substrate compatibility,screen-printing allows for the fabrication of flexible perovskite solar cells(f-PSCs)with designable device patterns,while the defective an...Owing to unique advantages of patternability and high substrate compatibility,screen-printing allows for the fabrication of flexible perovskite solar cells(f-PSCs)with designable device patterns,while the defective and fragile contact at the buried interface seriously restricted the device performance.Herein,a series of siloxane coupling agents(SCAs)with different ending groups i.e.,-SH,-NH_(2),and-CN were incorporated at the SnO_(2)/perovskite interface,which can selectively interact with MA+and Pb^(2+)via hydrogen and coordination bonding,respectively.It was revealed that the selection of(3-Cyanopropyl)Triethoxysilane(CN-PTES)can regulate perovskite crystallization with accelerated nucleation and retarded crystal growth,leading to improved crystallinity with released residual lattice strain.Moreover,the incorporated CN-PTES aligned the energy structure of the underlying SnO_(2)and boosted the interfacial adhesion between perovskite and SnO_(2),resulting in facilitated electron extraction and enhanced interfacial fracture energy.Consequently,the first screen-printed f-PSCs with improved mechanical resistance were finally obtained.展开更多
基金supported by the Natural Science Foundation of China(22425903,U24A20568,61705102,62288102,22409091,22409090 and 62205142)the National Key R&D Program of China(2023YFB4204500,2020YFA07099003)+1 种基金the Jiangsu Provincial Departments of Science and Technology(BK20241875,BE2022023,BK20220010,and BZ2023060)the Excellent Doctoral Dissertation Cultivation Program of Nanjing Tech University(2023-02).
文摘Owing to unique advantages of patternability and high substrate compatibility,screen-printing allows for the fabrication of flexible perovskite solar cells(f-PSCs)with designable device patterns,while the defective and fragile contact at the buried interface seriously restricted the device performance.Herein,a series of siloxane coupling agents(SCAs)with different ending groups i.e.,-SH,-NH_(2),and-CN were incorporated at the SnO_(2)/perovskite interface,which can selectively interact with MA+and Pb^(2+)via hydrogen and coordination bonding,respectively.It was revealed that the selection of(3-Cyanopropyl)Triethoxysilane(CN-PTES)can regulate perovskite crystallization with accelerated nucleation and retarded crystal growth,leading to improved crystallinity with released residual lattice strain.Moreover,the incorporated CN-PTES aligned the energy structure of the underlying SnO_(2)and boosted the interfacial adhesion between perovskite and SnO_(2),resulting in facilitated electron extraction and enhanced interfacial fracture energy.Consequently,the first screen-printed f-PSCs with improved mechanical resistance were finally obtained.
