Rare earth elements were extracted using a sulfuric acid roasting-water leaching process.The effect of acid roasting on a new type of low-grade sedimentary rare earth ore found in Guizhou Province,China was analyzed u...Rare earth elements were extracted using a sulfuric acid roasting-water leaching process.The effect of acid roasting on a new type of low-grade sedimentary rare earth ore found in Guizhou Province,China was analyzed using X-ray diffraction and scanning electron microscopy.A systematic study was conducted on process parameters such as amount of acid,roasting temperature,roasting time,water leaching temperature,and leaching time.The results reveal that the total recove ry of rare earth elements reaches 81.37%,which is 3.1 times higher than that achieved through direct acid leaching,under the optimal conditions.In addition,the leaching rate of heavy rare earth elements reaches 72.53%.Rare earth elements and some other valuable metals are transformed into soluble sulfate through the local decomposition of clay minerals under the action of the sulfuric acid attack.The dissolution rates of aluminum,iron,and titanium ions are 34.94%,17.05%,and 62.77%,respectively.The precipitation rate of Ti reaches 99%,and the loss of rare earth ions in the solution is less than 1%.Meanwhile,the results of a leaching kinetics analysis indicate that the leaching process of rare ions is controlled by diffusion.Precious metal ions such as iron and aluminum in the leaching solution can reduce the adsorption of rare earth ions by kaolinite.This study efficiently recovered rare earth ions under conditions of low calcination te mperature and direct water leaching,resulting in reduced energy consumption of the extraction process and acidity of the leaching solution.These findings provide a solid foundation for the further separation and extraction of rare earth ions.展开更多
Objective The Huashan group（composed of the lower Hongshansi Formation and the upper Liufangzui Formation）is an important Neoproterozoic stratigraphic unit along the northern margin of the Yangtze Block.Previous doc...Objective The Huashan group（composed of the lower Hongshansi Formation and the upper Liufangzui Formation）is an important Neoproterozoic stratigraphic unit along the northern margin of the Yangtze Block.Previous documents have focused on the geochronological and geochemical aspects of the Neoproterozoic sedimentary basin in the Dahongshan region.However.展开更多
The geothermal resources in China are primarily found in its sedimentary basins,particularly in the large basins located in eastern China,which hold significant potential for geothermal energy development.The Songliao...The geothermal resources in China are primarily found in its sedimentary basins,particularly in the large basins located in eastern China,which hold significant potential for geothermal energy development.The Songliao,North China,and Zhangzhou basins are of special interest due to their considerable exploration depths,extensive development history,and high levels of research activity.This study focuses on the three basins to analyze their thermal reservoir characteristics in eastern China.Between 2017 and 2023,the research team carried out a comprehensive analysis involving deep boreholes that exceeded 4000 m in depth within these three basins.They meticulously created detailed physical profiles that captured essential characteristics such as porosity,permeability,and thermal properties,reaching down to the basement of each basin.The findings indicated that variations in thermal conductivity within shallow geotechnical layers significantly influence the redistribution of deep thermal energy in the upper layers of the earth.Furthermore,differences in physical properties notably affect heat transport processes.The research proposes distinct heat models tailored for each basin:For the Songliao Basin,a low-permeability model with homogeneous thermal properties is constructed;for the North China Basin,high permeability and thermal conductivity layers are highlighted;and a fracture network controlling water and heat is presented in the Zhangzhou Basin.To elucidate the thermal structure of these basins,the Curie surface and Moho surface were analyzed.The shallow Curie surface indicates ongoing intense thermal activity stemming from crustal heat sources,while a shallow Moho surface signifies historical vigorous mantle thermal activity associated with mantle source heat production.Furthermore,the research evaluates the geothermal resources and the potential for carbon emission reduction in these basins.Total volume of exploitable geothermal fluid is estimated to be 76.9×10~9 m^(3)/a,corresponding to an annual renewable geothermal energy 1.47×10^(16)k J.The implementation of geothermal energy could lead to a reduction in annual CO_(2)emissions by nearly 2×10~9 t,which constitutes about 17.4%of China’s national carbon emissions in 2022.This estimation provides invaluable theoretical insights and data support for geothermal exploration and sustainable development in eastern China.展开更多
The available heat content (stored heat energy) of hot dry rock (HDR) at a depth of 1–10 km in the global land crust is estimated to be 5.06×10~8 EJ,attracting considerable global attention.This paper presents a...The available heat content (stored heat energy) of hot dry rock (HDR) at a depth of 1–10 km in the global land crust is estimated to be 5.06×10~8 EJ,attracting considerable global attention.This paper presents a comprehensive analysis of the geological framework,HDR resource potential,exploration advancements,and the development of enhanced geothermal systems (EGSs) in China.HDR resources are extensively distributed across China.Within the depth range of 3–10 km,China’s estimated potential approximates2.29×10~7 EJ,with a theoretical power generation capacity of approximately 1.67×10^(16) k Wh.Replacing coal power with HDR can help to achieve a net emission reduction of 1.34×10^(16) kg CO_(2) (approximately1.34×10^(13) t),representing an emission reduction efficiency of 94.4%.Based on a development cycle of100 years,the average annual emission reduction reaches 1.34×10^(10) t CO_(2),equivalent to 117%of China’s annual carbon emissions in 2022.Furthermore,in the context of global warming,the development and utilization of HDR,which is feasible in virtually any region worldwide,offers significant potential to support global carbon reduction efforts.China has made substantial progress in HDR exploration in recent years.This paper systematically classifies China’s HDR resources into four genetic types—highly radioactive heat-producing,sedimentary basin,active volcanic,and intensely tectonic zones—and offers detailed exploration insights for each category.Each classification exhibits distinct geological and tectonic characteristics that influence heat source mechanisms and resource distribution.Furthermore,this paper documents significant advances in EGS construction,particularly in the Gonghe Basin on the northeastern margin of the Qianghai-Xizang Plateau and the Matouying uplift in the North China Basin,where successful reservoir stimulation,microseismic monitoring,and experimental power generation have been achieved.Despite these developments,challenges persist,including technical adaptability under complex geological conditions and the economic viability of large-scale HDR development.This paper suggests that future initiatives should emphasize resource exploration,technological research,and policy support to foster sustainable HDR resource development in China,thereby contributing to the global energy transition and environmental sustainability.展开更多
基金supported by the Guizhou Provincial Science and Technology Program ([2022]ZD006)。
文摘Rare earth elements were extracted using a sulfuric acid roasting-water leaching process.The effect of acid roasting on a new type of low-grade sedimentary rare earth ore found in Guizhou Province,China was analyzed using X-ray diffraction and scanning electron microscopy.A systematic study was conducted on process parameters such as amount of acid,roasting temperature,roasting time,water leaching temperature,and leaching time.The results reveal that the total recove ry of rare earth elements reaches 81.37%,which is 3.1 times higher than that achieved through direct acid leaching,under the optimal conditions.In addition,the leaching rate of heavy rare earth elements reaches 72.53%.Rare earth elements and some other valuable metals are transformed into soluble sulfate through the local decomposition of clay minerals under the action of the sulfuric acid attack.The dissolution rates of aluminum,iron,and titanium ions are 34.94%,17.05%,and 62.77%,respectively.The precipitation rate of Ti reaches 99%,and the loss of rare earth ions in the solution is less than 1%.Meanwhile,the results of a leaching kinetics analysis indicate that the leaching process of rare ions is controlled by diffusion.Precious metal ions such as iron and aluminum in the leaching solution can reduce the adsorption of rare earth ions by kaolinite.This study efficiently recovered rare earth ions under conditions of low calcination te mperature and direct water leaching,resulting in reduced energy consumption of the extraction process and acidity of the leaching solution.These findings provide a solid foundation for the further separation and extraction of rare earth ions.
基金financially supported by the National Natural Science Foundation of China(grant No. 41402103,41502114 and 41372124)
文摘Objective The Huashan group（composed of the lower Hongshansi Formation and the upper Liufangzui Formation）is an important Neoproterozoic stratigraphic unit along the northern margin of the Yangtze Block.Previous documents have focused on the geochronological and geochemical aspects of the Neoproterozoic sedimentary basin in the Dahongshan region.However.
基金funded by the Basic Scientific Research of China Geological Academy(YK202305)National Key R&D Program of China(2019YFB1504101)+1 种基金National Natural Science Foundation of China(41602271)China Geological Survey(DD20160207 and DD20189112)。
文摘The geothermal resources in China are primarily found in its sedimentary basins,particularly in the large basins located in eastern China,which hold significant potential for geothermal energy development.The Songliao,North China,and Zhangzhou basins are of special interest due to their considerable exploration depths,extensive development history,and high levels of research activity.This study focuses on the three basins to analyze their thermal reservoir characteristics in eastern China.Between 2017 and 2023,the research team carried out a comprehensive analysis involving deep boreholes that exceeded 4000 m in depth within these three basins.They meticulously created detailed physical profiles that captured essential characteristics such as porosity,permeability,and thermal properties,reaching down to the basement of each basin.The findings indicated that variations in thermal conductivity within shallow geotechnical layers significantly influence the redistribution of deep thermal energy in the upper layers of the earth.Furthermore,differences in physical properties notably affect heat transport processes.The research proposes distinct heat models tailored for each basin:For the Songliao Basin,a low-permeability model with homogeneous thermal properties is constructed;for the North China Basin,high permeability and thermal conductivity layers are highlighted;and a fracture network controlling water and heat is presented in the Zhangzhou Basin.To elucidate the thermal structure of these basins,the Curie surface and Moho surface were analyzed.The shallow Curie surface indicates ongoing intense thermal activity stemming from crustal heat sources,while a shallow Moho surface signifies historical vigorous mantle thermal activity associated with mantle source heat production.Furthermore,the research evaluates the geothermal resources and the potential for carbon emission reduction in these basins.Total volume of exploitable geothermal fluid is estimated to be 76.9×10~9 m^(3)/a,corresponding to an annual renewable geothermal energy 1.47×10^(16)k J.The implementation of geothermal energy could lead to a reduction in annual CO_(2)emissions by nearly 2×10~9 t,which constitutes about 17.4%of China’s national carbon emissions in 2022.This estimation provides invaluable theoretical insights and data support for geothermal exploration and sustainable development in eastern China.
基金supported by the National Key Research and Development Program of China (2021YFB1507401)Qinghai Province Clean Energy Minerals Special Project(2022013004qj004)Geological Survey Project of China Geological Survey (DD20221676, DD20230019)。
文摘The available heat content (stored heat energy) of hot dry rock (HDR) at a depth of 1–10 km in the global land crust is estimated to be 5.06×10~8 EJ,attracting considerable global attention.This paper presents a comprehensive analysis of the geological framework,HDR resource potential,exploration advancements,and the development of enhanced geothermal systems (EGSs) in China.HDR resources are extensively distributed across China.Within the depth range of 3–10 km,China’s estimated potential approximates2.29×10~7 EJ,with a theoretical power generation capacity of approximately 1.67×10^(16) k Wh.Replacing coal power with HDR can help to achieve a net emission reduction of 1.34×10^(16) kg CO_(2) (approximately1.34×10^(13) t),representing an emission reduction efficiency of 94.4%.Based on a development cycle of100 years,the average annual emission reduction reaches 1.34×10^(10) t CO_(2),equivalent to 117%of China’s annual carbon emissions in 2022.Furthermore,in the context of global warming,the development and utilization of HDR,which is feasible in virtually any region worldwide,offers significant potential to support global carbon reduction efforts.China has made substantial progress in HDR exploration in recent years.This paper systematically classifies China’s HDR resources into four genetic types—highly radioactive heat-producing,sedimentary basin,active volcanic,and intensely tectonic zones—and offers detailed exploration insights for each category.Each classification exhibits distinct geological and tectonic characteristics that influence heat source mechanisms and resource distribution.Furthermore,this paper documents significant advances in EGS construction,particularly in the Gonghe Basin on the northeastern margin of the Qianghai-Xizang Plateau and the Matouying uplift in the North China Basin,where successful reservoir stimulation,microseismic monitoring,and experimental power generation have been achieved.Despite these developments,challenges persist,including technical adaptability under complex geological conditions and the economic viability of large-scale HDR development.This paper suggests that future initiatives should emphasize resource exploration,technological research,and policy support to foster sustainable HDR resource development in China,thereby contributing to the global energy transition and environmental sustainability.
