As the most important component of marine siliceous organisms,diatoms are vital primary producers of the ocean that are often used as indicators of paleoenvironmental change.To understand the response of sedimental di...As the most important component of marine siliceous organisms,diatoms are vital primary producers of the ocean that are often used as indicators of paleoenvironmental change.To understand the response of sedimental diatoms to regional environmental changes and the factors affecting the distribution of sedimental diatoms in the Taiwan Strait,this study quantified and classified the diatoms found in surface sediments collected during four surveys from 2019 to 2020.Overall,118 diatom taxa and 44 genera were identified with total diatom abundance of 8-27353 valves/g.Four diatom assemblages representing different environments were identified.Among them,assemblageⅠrepresented a coastal environment,assemblageⅡcomprised warm water species of a coastal environment,AssemblageⅢrepresented a coastal environment affected markedly by exorheism,AssemblageⅣrepresented a group with lowest diatom abundance.Seasonal variation in total diatom abundance was controlled by seven environmental factors:depth,sea surface salinity,mean grain size,silicate,nitrite,nitrate,and phosphate.Spatiotemporal variation in each of the diatom assemblages was substantial and strongly affected by various currents,upwelling,and low-salinity water.Specifically,it was found that the succession of diatom assemblages reflects change in the range of influence of local warm currents.展开更多
Fluoroquinolones(FQs)have the propensity to accumulate in sediments once introduction into aquatic envi-ronments,thereby posing potential threats to benthic organisms,yet the ecotoxicity of sediment-associated FQs rem...Fluoroquinolones(FQs)have the propensity to accumulate in sediments once introduction into aquatic envi-ronments,thereby posing potential threats to benthic organisms,yet the ecotoxicity of sediment-associated FQs remains unclear.In this study,the toxicokinetics and responses of multiple biomarkers in Bellamya aeruginosa,exposed to the three commonly used FQs(norfloxacin,NOR;ciprofloxacin,CIP;levofloxacin,LEVO)at envi-ronmentally relevant concentrations were investigated under sediment exposure scenario.The results revealed that FQs were effectively ingested by B.aeruginosa from sediments,CIP showing the highest bioaccumulation(180.59μg/kg),followed by NOR(74.49μg/kg)and LEVO(36.02μg/kg).CIP exhibiting a highest uptake rate constant(Ks)(4.64 g/(g·day))and the lowest elimination rate constant(K_(e))(0.05 g/(g·day)).The descending order of biological half-life is as follows:CIP(13.62 days),LEVO(8.14 days),and NOR(6.83 days).NOR induced the activity of superoxide dismutase,catalase,and glutathione-S-transferase while CIP and LEVO depressed their activities and increased malondialdehyde content,indicating a more pronounced oxidative damage to B.aerug-inosa caused by CIP and LEVO than NOR.Furthermore,all three FQs were found to induce DNA damage and elevate acetylcholinesterase activity,suggesting distinct genotoxic and neurotoxic effects.Interestingly,despite its low bioaccumulation potential,LEVO exhibited high toxicity towards B.aeruginosa.These findings enhance our understanding of the ecotoxicity of FQs in sediments,providing further evidence of their potential ecological risks.展开更多
Noncohesive particle clusters are identified and tracked in turbulent flows to determine the breakdown and time evolution of cluster statistics and their implications for interscale mass transfer,which has connections...Noncohesive particle clusters are identified and tracked in turbulent flows to determine the breakdown and time evolution of cluster statistics and their implications for interscale mass transfer,which has connections to the classical turbulent energy cascade and its mass cascade counterpart running in parallel.In particular,the formation and dynamics of sediment and larvae clusters are of interest to coral larvae settlement in coastal regions and particularly the resilience of green-gray coastal protection solutions.Analogous cluster behavior is relevant to cloud microphysics and precipitation initiation,radiation transport and light transmission through colloids and suspensions,heat and mass transfer in particle-laden flows,and viral and pollutant transmission.Following a comparison between various clustering techniques,we adopt a density-based cluster identification algorithm based on its simplicity and efficiency,where particles are clustered based on the number of neighboring particles in their individual spheres of influence.We establish parallels with lattice-based percolation theory,as evident in the power-law scaling of the cluster size distribution near the percolation threshold.The degree of discontinuity of the phase transition associated with this percolation threshold is observed to broaden with larger Stokes numbers and thereby large-scale clustering.The sensitivity of our findings to the employed clustering algorithm is discussed.A novel cluster tracking algorithm is deployed to determine the interscale transfer rate along the particle-number phase-space dimension via accounting of cluster breakup and merger events,extending previous work on the bubble breakup cascade beneath surface breaking waves.Our findings shed light on the interaction between particle clusters and their carrier turbulent flows,with an eye toward transport models incorporating cluster characteristics and dynamics.展开更多
Accurate identification of sediment sources and erosion hotspots is crucial for implementing targeted soil and water conservation measures.This study analyzed the temporal dynamics of sediment source contributions dur...Accurate identification of sediment sources and erosion hotspots is crucial for implementing targeted soil and water conservation measures.This study analyzed the temporal dynamics of sediment source contributions during seven rainfall events(A_(1)–A_(7))that generated both runoff and suspended sediment at the outlet of the Hantaichuan watershed,located in the wind–water erosion crisscross region of the northern Loess Plateau,China.A total of 82 suspended sediment samples were collected at the Xiangshawan hydrological station during 2021 and 2022.Additionally,145 soil samples were collected from three primary potential sources:sandy soil,loess soil,and Pisha sandstone.Mid-infrared(MIR)spectroscopy and geochemical fingerprinting were used to trace and quantify sediment sources.For MIRbased source apportionment,twelve predictive models were developed using partial least squares regression(PLSR)and support vector machine regression(SVMR)in combination with six spectral preprocessing techniques.The PLSR model with first-derivative Savitzky–Golay(SGD1)preprocessing achieved the best performance.Source apportionment results indicated that Pisha sandstone was the dominant sediment source(44.00%–72.23%),followed by sandy soil(14.23%–37.00%)and loess soil(10.01%–24.00%).Among the analyzed rainfall events,the contribution of Pisha sandstone was lowest in the small flow magnitude event A3(57.53%)and highest in the large flow magnitude event A6(63.48%),suggesting that sediment source composition was strongly controlled by rainfall event magnitude.Both MIR spectroscopic and geochemical fingerprinting methods showed high consistency,confirming MIR spectroscopy as a reliable,non-destructive,and cost-effective alternative for rapid sediment source apportionment and for supporting erosion control prioritization in highly erodible catchments.展开更多
As an essential component of terrestrial carbon sinks,lake sediments store vast quantities of both organic carbon(OC)and inorganic carbon(IC).However,the spatiotemporal relationship between the OC and IC in sediments ...As an essential component of terrestrial carbon sinks,lake sediments store vast quantities of both organic carbon(OC)and inorganic carbon(IC).However,the spatiotemporal relationship between the OC and IC in sediments and their responses to climate change remains unclear,which hinders the comprehensive understanding of carbon dynamics in lake ecosystems.This study systematically analyzes the spatiotemporal dynamics of carbon burial across the Tibetan Plateau using surface sediments from 119 lakes and sediment cores from four representative lakes.Results show that OC burial dominates in humid and dry sub-humid zones,whereas IC burial prevails in arid and semi-arid regions.This distribution reflects the influences of lake and catchment productivity and water chemistry on OC and IC patterns.Sediment cores confirm that these factors have consistently affected lake carbon burial over the past century.Specifically,in humid and dry sub-humid zones,increased precipitation enhances watershed productivity and sedimentation,promoting coupled OC and IC burial.In arid and semi-arid regions,wind-driven dust supplies nutrients and alters water chemistry,also driving coupled OC and IC burial.Based on these findings,the carbon sink capacity of lake sediments on the Tibetan Plateau is projected to increase under the“warming and wetting”trend.展开更多
With the legislative development,the organic and inorganic composition separation has become the primary requirement for sewer sediment disposal,however the relevant technology has been rarely reported and the driving...With the legislative development,the organic and inorganic composition separation has become the primary requirement for sewer sediment disposal,however the relevant technology has been rarely reported and the driving mechanism was still unclear.In this study,direct disintegration of biopolymers and indirect broken of connection point were investigated on the hydrolysis and component separation.Three typical sewer sediment treatment approaches,i.e.,alkaline,thermal and cation exchange treatments were proposed,which represented the hydrolysis-driving forces of chemical hydrolysis,physical hydrolysis and innovative cation bridging break-age.The results showed that the organic and inorganic separation rates of sewer sediment driven by alkaline,thermal and cation exchange treatments reached 21.26%,23.80%,and 19.56%-48.0%,respectively,compared to 4.43%in control.The secondary structure of proteins was disrupted,transitioning from𝛼α-helix to𝛽β-turn and random coil.Meanwhile,much biopolymers were released from solid to the liquid phase.From thermody-namic perspective,sewer sediment deposition was controlled by short-range interfacial interactions described by extended Derjaguin-Landau-Verwey-Overbeek theory.Additionally,the separation of organic and inorganic components was positively correlated with the thermodynamic parameters(Corr=0.87),highlighted the robust-ness of various driving forces.And the flocculation energy barriers were 2.40(alkaline),1.60 times(thermal),and 4.02–4.97 times(cation exchange)compared to control group.The findings revealed the contrition differ-ence of direct disintegration of gelatinous biopolymers and indirect breakage of composition connection sites in sediment composition separation,filling the critical gaps in understanding the specific mechanisms of sediment biopolymer disintegration and intermolecular connection breakage.展开更多
Chlorophyll-a is the most abundant chlorophyll pigment produced by marine phytoplankton,and it bears the isotope signature of the nitrate source assimilated in the N-atoms that are embedded in its porphyrin ring.The c...Chlorophyll-a is the most abundant chlorophyll pigment produced by marine phytoplankton,and it bears the isotope signature of the nitrate source assimilated in the N-atoms that are embedded in its porphyrin ring.The chloropigment and its degradation product,i.e.,pheophytin-a,could be well preserved in marine sediment,usually at nanomolar level.A sensitive and accurate measurement of theδ15N of chloropigment is capable of providing rich information to greatly enhance our understanding of past nitrogen cycling,which therefore is urgently needed.Hereby,we present a successful method based on two-step HPLC separation followed by'denitrifier method'.The N-content in acetone and potassium persulfate(K_(2)S_(2)O_(8))are very critical to the precision and accuracy of the measurements,because they constitute the majority of the N contamination to the Chl-a samples.In this method,the recrystallized K_(2)S_(2)O_(8)that is used as oxidization reagent was discovered to have aδ15N background of-15‰,consolidated by repeated examinations over a period of two months.This 15N background of K_(2)S_(2)O_(8)would cause-1‰–-2‰deviation on theδ^(15)N of sample that contains nanomolar level N,and highlight the need to examine theδ^(15)N of recrystallized K_(2)S_(2)O_(8)when it is used to oxidize samples of organic nitrogen.The overall measurement ofδ^(15)N pigment is reliable and has an average analytical precision better than±0.5‰(1σ).This study establish a sensitive method for accurate measurement of theδ^(15)N of nano-molar level chlorophyll pigment,and with no doubts will advance its wide application in marine nitrogen cycling studying.展开更多
Identifying geohazards such as landslides and methane leakage is crucial during gas extraction from natural gas hydrate(NGH)reservoirs,and understanding reservoir settlement behavior is central to this assessment.Hori...Identifying geohazards such as landslides and methane leakage is crucial during gas extraction from natural gas hydrate(NGH)reservoirs,and understanding reservoir settlement behavior is central to this assessment.Horizontal wells can enlarge the pressure relief zone within the formation,improving single-well productivity,and are therefore considered a promising approach for NGH development.This study examines the settlement response of hydrate-bearing sediments during depressurization using horizontal wells.A fully coupled thermal,hydraulic,mechanical,and chemical(THMC)model with representative reservoir properties(Shenhu region in the South China Sea)is presented accordingly.The simulations show that lower production pressures,while increasing gas output,also intensify formation settlement.The maximum difference in settlement between the lowest and highest production pressures reaches 0.016 m,contributing to more pronounced differential subsidence.Optimal well placement,specifically targeting a low-saturation hydrate zone containing free gas and situated adjacent to a high-saturation hydrate layer,markedly improves both gas production rate and cumulative yield,while reducing overall settlement and limiting changes in effective stress.展开更多
The variation laws of runoff and sediment load under different climate,vegetation,and human activity scenarios are significantly different.Exploring the impacts of climate change and human activities on runoff and sed...The variation laws of runoff and sediment load under different climate,vegetation,and human activity scenarios are significantly different.Exploring the impacts of climate change and human activities on runoff and sediment load dynamics can provide a profound understanding of the mechanism of runoff and sediment load variability in basins,which is crucial for the sustainable development of regional ecosystems.This study investigates the Tao River Basin(TRB)on the Tibetan Plateau,as well as the Zuli River Basin(ZRB)and Jing River Basin(JRB)on the Loess Plateau,to differentiate the impacts of climate change and human activities on runoff and sediment load dynamics.The runoff and sediment load of the three watersheds have shown a decreasing trend over the past 40 years,and combined with the DMC(Dual mass curve)method,it was found that the slope of the runoff sediment gradually tends to flatten out.After the time period was divided,the CA(Cumulative anomaly)method was used for verification,which revealed good correspondence between the two before 2000 and then gradual deviations.The power function best represents the relationship between runoff and sediment load.During the initial period,climate had a significant impact on runoff variation in the TRB and JRB,with contribution rates of-54.93%and-63.02%,respectively.In the later period,human activities became the dominant influence,contributing more than-60%of the runoff variation.In the ZRB,human activities consistently dominated runoff variation,with contribution rates of-72.72%and-55.66%during both periods.In the early stages of research,the impact of climate change on sediment load was more severe in the TRB and JRB,and human activities played a significant role in the later stages.However,in the ZRB,human activities have always been the main contributor.Based on the actual local situation,runoff and sediment load in the TRB are influenced primarily by engineering measures,and vegetation and check dams exert greater impacts on the ZRB and JRB.This study explores the attribution of water and sediment load changes in different ecological geographic regions from a comparative perspective,providing a valuable theoretical basis and reference for understanding global runoff and sediment transport changes in similar areas.展开更多
Estuaries are key areas for organic carbon cycling,where polymeric carbohydrates are abundant and chemically diverse.The recycling of these polymers by microbes depends on a variety of carbohydrate-active enzymes(CAZy...Estuaries are key areas for organic carbon cycling,where polymeric carbohydrates are abundant and chemically diverse.The recycling of these polymers by microbes depends on a variety of carbohydrate-active enzymes(CAZymes).However,it remains unclear whether other gene traits,particularly those related to cell motility toward polymeric carbohydrates,are intertwined with carbohydrate depolymerization and niche specialization in estuarine sediment soils.In this study,estuarine sediments were incubated with four prevalent polymeric carbohydrates(laminarin,fucan,cellulose,and chitin) under anaerobic conditions.Based on metagenomic analysis,we identified potential responses to the degradation and utilization of polymeric carbohydrate substrates from the perspectives of CAZymes and sugar transporters.The analysis of metagenomic gene data also revealed a positive correlation between chemotaxis and the abundance of CAZymes genes.Furthermore,metagenomes-assembled genomes(MAGs) that exhibited higher abundance in polysaccharide-treated samples compared to controls also featured elevated copies of genes involved in polysaccharide utilization loci(PULs),chemotaxis,as well as those associated with flagellar or gliding movement.SprB and CTDs associated with gliding proteins genes are essential for type Ⅸ secretion system-mediated secretion of CAZymes and gliding motility in Bacteroidota.The enhanced potential for mobility,coupled with the ability to degrade polymeric carbohydrates,may enable these bacteria to exploit nutrients beyond carbon sources,thereby potentially broadening their ecological niches.展开更多
Exploring hydroclimatic variability and its driving mechanisms during the Holocene is essential for comprehending both historical and prospective responses of water resources to climatic shifts in Arid Central Asia(AC...Exploring hydroclimatic variability and its driving mechanisms during the Holocene is essential for comprehending both historical and prospective responses of water resources to climatic shifts in Arid Central Asia(ACA)region.However,debate persists regarding whether dryland lakes in this region exhibited aridification or humidification during the Holocene.Lopnur serves as the terminal lake of Tarim rivers during the Holocene,which offers an ideal natural laboratory to address the questions.In this study,a high-resolution chronological framework was established through precise radiocarbon dating.Multi-proxy analyses,including geochemical composition,grain size distributions,MS,LOI,and C/N ratios were conducted from a lacustrine profile in the core area of“Great ear”in the southern part of Lopnur catchment.These analyses enabled the reconstruction of hydrological dynamics and facilitated the disentanglement of independent signals linked to climate variability,runoff fluctuations,and lake-level changes.The results demonstrate that the MidHolocene(7800–4000 cal yr B.P.)was characterized by cold and humid conditions,resulting in elevated surface runoff and lake level.The Late Holocene(4000–1300 cal yr B.P.)experienced intensified aridification,characterized by reduced runoff and declining lake level.These evidences suggested a climatic regime of a distinctive alternation between“cold-wet”and“warm-dry”climatic regimes during the Mid-to-Late Holocene.Compared with the previous studies from adjacent regions,we speculate that the hydroclimatic evolution of Lopnur catchment possibly influenced by a complex interplay of large spatial scale forcings,including variations in annual insolation,greenhouse gas concentrations,and ice sheets,as well as the localized controls such as topographic features,vegetation cover,and cloud-radiative feedbacks.Our findings enhance the understanding of past climatic complexity and provide valuable insights for future water resource management strategies in drylands.展开更多
In this study,we perform particle-resolved simulations of settling spheroidal particles,considering oblate and prolate spheroids and spheres,and investigate the shape effect on the particle dynamics in suspensions wit...In this study,we perform particle-resolved simulations of settling spheroidal particles,considering oblate and prolate spheroids and spheres,and investigate the shape effect on the particle dynamics in suspensions with volume fraction 1%and 5%.We first examine the single-point statistics of the translational and rotational motion of the settling particles.The horizontal velocity has a symmetrical distribution with standard deviation dependent on the particle shape.The greater horizontal velocity fluctuations of the non-spherical particles,compared to that of spheres,are attributed to the horizontal drift of settling spheroids with oblique orientations induced by the fluid-particle and particle-particle interactions.The fluctuation of particle vertical velocity,instead,is skewed under the effect of wake-induced hydrodynamic interactions.Further,we explore the particle pair statistics,which demonstrate the formation of column-like particle micro-structures for the lowest volume fraction considered.This clustering is more pronounced for spheroidal particles than spheres,due to the stronger attractions among vertically-aligned settling spheroids.Moreover,the particle pair statistics are directly related to the collision rate among the dispersed particles.The local accumulation of oblate/prolate spheroids serves as the major mechanism to promote the particle-particle collisions in dilute suspensions.展开更多
Organic-rich sediments represent vital components of Earth's geochemical cycles, acting both as potential hydrocarbon and coal reservoirs and as unconventional archives for critical metals such as rare earth eleme...Organic-rich sediments represent vital components of Earth's geochemical cycles, acting both as potential hydrocarbon and coal reservoirs and as unconventional archives for critical metals such as rare earth elements(REEs). With the growing emphasis on clean energy technologies, the Cenozoic organic deposits of India have gained renewed significance;however, those from the southern state of Kerala remain understudied. This study investigates lignite and associated carbonaceous sediments from the Cheruvathur and Warkalli Formations using a multi-proxy approach integrating organic petrography,infrared spectroscopy, stable carbon isotopes, and REE geochemistry. The lignite exhibits huminite dominance with Type Ⅲ kerogen, deposited in a wet, mesotropic bog forest swamp under anoxic conditions. The mineral assemblage, dominated by kaolinite, quartz, illite, montmorillonite, feldspar,and pyrite/marcasite, reflects strong chemical alteration in a reducing environment. The δ^(13)C values(-25.1 to-27.3) indicate a C_(3) angiosperm source and deposition in tropical to subtropical swamp settings. REE patterns reveal LREE enrichment in carbonaceous shales and HREE enrichment in lignite,with distinct Ce, Eu, and Gd anomalies associated with provenance and redox conditions. The findings provide new insights into the paleoenvironmental evolution of Kerala's Cenozoic basins and highlight their potential as unconventional REE-bearing resources in the context of the global energy transition.展开更多
Soil erosion is a fundamental physical process driving land degradation across various spatial and temporal scales.The Soil and Water Assessment Tool(SWAT)model is a robust tool for predicting soil erosion and evaluat...Soil erosion is a fundamental physical process driving land degradation across various spatial and temporal scales.The Soil and Water Assessment Tool(SWAT)model is a robust tool for predicting soil erosion and evaluating water and soil quality within watersheds.The latest version,SWAT+,introduces advanced encoding capabilities and improved performance,making it better suited for addressing complex watershed modeling challenges.This study implemented the SWAT+model to quantify soil erosion rates within the Chehelchay watershed in northern Iran.The foundational dataset comprises a 30-meter resolution Digital Elevation Model(DEM),land use classification,soil,and weather data.Model performance was evaluated using Nash-Sutcliffe Efficiency(NSE),coefficient of determination(R^(2)),root mean square error(RMSE),and percent bias(PBIAS).The SWAT+simulation revealed substantial spatial variation in erosion patterns across the watershed,with annual sediment yields in critical HRUs,reflecting diverse erosion intensities driven by variations in land use,soil characteristics,and slope.Among the Hydrological Response Units(HRUs),50 critical units,representing approximately 9%of the total watershed area,generate sediment yields exceeding 5 tons per hectare per year.The most severe erosion occurs predominantly in the central zone of the watershed.Downstream regions exhibit minimal soil loss due to gentle topography while upstream areas maintain soil stability through protective forest cover,resulting in negligible erosion rates.Best Management Practices(BMPs)were designed to safeguard water and soil resources at a watershed level.The study evaluated three strategic conservation interventions:alfalfa cultivation,agroforestry implementation,and garden development.When applied in combination,these measures achieved approximately 30%reduction in sediment yield at the HRU level.This integrated approach demonstrates the potential of combining multiple land management strategies to combat erosion effectively.展开更多
The volume change behavior of natural gas hydrate-bearing sediment is essential as it influences settlement,strength,and stiffness,which directly affect the stability of hydrate reservoirs during hydrate extraction or...The volume change behavior of natural gas hydrate-bearing sediment is essential as it influences settlement,strength,and stiffness,which directly affect the stability of hydrate reservoirs during hydrate extraction or in response to environmental changes.The volume change is influenced not only by stress but also by the formation and dissociation of hydrates.This study adopted a customized apparatus for one-dimensional compression tests,allowing independent control of gas pressure and effective stress.Tests were conducted on samples with different hydrate saturations along various temperature-gas pressure-effective stress paths,yielding some conclusions related to compressibility and creep.An unusual phenomenon was observed under low-stress conditions:hydrate formation led to shrinkage rather than expansion.Three potential mechanisms behind this occurrence were discussed.As hydrate saturation increases,the yield stress rises while the compression and swelling indexes remain minimally affected.After hydrate dissociation,the compression curve of hydrate-bearing sediment drops to that of hydrate-free sediment.Once hydrate is formed,the compression curve of hydrate-free sediment gradually approaches that of hydrate-bearing sediment during the subsequent loading.Under low-stress conditions,the creep of both hydrate-free and hydrate-bearing sediments is very weak.However,when stress increases,significantly beyond the yield stress,the creep of both sediments increases significantly,with hydrate-bearing sediment exhibiting much greater creep than hydrate-free sediment.展开更多
This study compares the environmental sustainability of five alternatives for the remediation of marine sediments of one of the most polluted coastal sites in Europe(Bagnoli-Coroglio bay,Mediterranean Sea),using the L...This study compares the environmental sustainability of five alternatives for the remediation of marine sediments of one of the most polluted coastal sites in Europe(Bagnoli-Coroglio bay,Mediterranean Sea),using the Life Cycle Assessment(LCA)methodology.The treatments are either in-situ or exsitu,the latter requiring an initial dredging to transport the contaminated sediments to the management site.More in detail,four ex-situ remediation technologies based on landfilling,bioremediation,electrokinetic technique and soil washing were identified.These technologies are compared to an in-situ strategy currently under validation for enhancing bioremediation of the polluted sediments of the Bagnoli-Coroglio site.Our results indicate that the disposal in landfilling site is the worst option in most categories(e.g.,650 kg CO_(2) eq./t of treated sediment,considering the nearest landfilling site),followed by the bioremediation,mainly due to the high energy demand.Electrokinetic remediation,soil washing,and innovative in-situ technology represent the most sustainable options.In particular,the new in-situ technology appears to be the least impacting in all categories(e.g.,54 kg CO_(2) eq./t of treated sediment),although it is expected to require longer treatment time(estimated up to 12 months based on its potential efficiency).It can reduce the impact on climate change more than 12 times compared to the disposal and 7 times compared to bioremediation in addition to the possibility to avoid/reduce the dredging operations and the consequent dispersion of pollutants.The results open relevant perspectives towards more eco-sustainable and costly effective actions for the reclamation of contaminated marine sediments.展开更多
A debris flow descending through an erodible convex colluvial bed,originating from a landslide dam and its upstream deposits,can entrain massive amounts of sediment,dramatically increasing the debris flow volume.Most ...A debris flow descending through an erodible convex colluvial bed,originating from a landslide dam and its upstream deposits,can entrain massive amounts of sediment,dramatically increasing the debris flow volume.Most existing erosion models assume that bed sediments are fully saturated,although this condition is rarely observed in nature.Therefore,a thorough understanding of debris flow overtopping erosion on a convex unsaturated bed is crucial for quantifying disaster risk.In this study,we experimentally investigated the effects of sediment composition,specifically coarse-grain size distribution and fine particle content,on the pore pressure evolution and entrainment of debris flows overriding a convex unsaturated colluvial bed.The average entrainment rate at convex sites for continuously graded bed sediment was higher than its discontinuous counterpart.The measured pore pressures within the unsaturated bed sediments were primarily generated by the passing debris flows.Furthermore,it was found that these pressures decreased as the fine particle content increased and the coarse-grain size of the erodible substrates decreased.When the coarse-grain size of the debris flow was smaller than that of the bed sediment,only a portion of the eroded material was entrained by the moving debris flow.In contrast,when the coarse-grain size of the debris flow was equal to or greater than that of the bed sediment,nearly all of the eroded material was entrained.The findings of this study could contribute to the assessment of hazard amplification and inform the design of mitigation and prevention strategies.展开更多
State Field Observation and Research Station of Debris Flow in Dongchuan,Yunnan is also named Dongchuan Debris Flow Observation and Research Station,Chinese Academy of Sciences.The study area,Jiangjia Ravine,is about ...State Field Observation and Research Station of Debris Flow in Dongchuan,Yunnan is also named Dongchuan Debris Flow Observation and Research Station,Chinese Academy of Sciences.The study area,Jiangjia Ravine,is about 48.6 km2 and characterized by intense tectonism.Accumulated clastic detritus is the main source of the materials in the debris flows when an intense rainfall occurs.The recorded highest density and sediment transport are 2370 kg/m^(3) and 6.079×10^(6) kg/s,respectively.The ravine is now called the“debris flow museum”in China and supplies advantageous research conditions.展开更多
The lateral transport of labile organic carbon represents a critical pathway for soil organic carbon(SOC) loss,reducing organic carbon sequestration and increasing the risk of waterbody pollution.Livestock manure appl...The lateral transport of labile organic carbon represents a critical pathway for soil organic carbon(SOC) loss,reducing organic carbon sequestration and increasing the risk of waterbody pollution.Livestock manure application on croplands serves as a common fertilizer reduction practice to sustain crop yields,enhance SOC sequestration,and reduce water erosion.However,limited quantitative assessments have examined the effects of livestock manure substitution on labile organic carbon lateral loss and fluxes in long-term experiments.This study conducted a three-year field investigation on subtropical sloping croplands to assess the impact of livestock manure substitution on dissolved organic carbon(DOC) and particulate organic carbon(POC) loss via surface runoff,interflow and eroded sediments.There are four treatments:no fertilization(CK);chemical nitrogen fertilizer(SF),40% nitrogen substitution with pig manure(PMF),and 100% nitrogen substitution from pig manure(PM).Compared to SF treatment,long-term livestock manure substitution in PMF and PM treatments significantly(P<0.05) reduced annual cumulative surface runoff fluxes by 13.5 and 21.6%,respectively.Manure applications decreased annual sediment fluxes by 12.9 and 19.1%,respectively.Soil water stable aggregates for mean weight diameter(MWD) increased significantly by 37.7 and 73.6%.Annual cumulative POC loss flux via eroded sediment under PMF and PM treatments increased significantly(P<0.05) by 61.1 and 47.9%,respectively.The labile organic carbon loss fluxes,including DOC and POC losses,under PMF and PM treatments increased significantly(P<0.05) by 11.9 and 31.4%,respectively.These results demonstrate that while water erosion intensity decreases due to enhanced soil aggregate stability,the risk of labile organic carbon loss increases after long-term livestock manure substitution in subtropical sloping croplands.Future research should examine labile organic carbon lateral migration under various soil types and slope gradients for livestock manure application in subtropical agricultural ecosystem croplands to better understand extreme rainfall effects.展开更多
Sedimentary microbial communities play an important role in driving biogeochemical cycles in river ecosystems.The Yellow River is one of the rivers with the highest turbidity over the world.However,limited is known ab...Sedimentary microbial communities play an important role in driving biogeochemical cycles in river ecosystems.The Yellow River is one of the rivers with the highest turbidity over the world.However,limited is known about the microbial variation and its influencing factors in the Yellow River.In this study,we examined the microbial communities and their influencing factors in the sediment of Upper and Mid–Lower reaches of the Yellow River.The results showed that Gammaproteobacteria were most dominant(with Hydrogenophilaceae being the predominant family)in the studied Yellow River sediments.Phyla of Deltaproteobacteria,Nitrospirae and family of Bacillaceae,Geobaceraceae were more abundant in the Mid–Lower reaches than in the Upper reaches,while phyla of Gammaproteobacteria,Verrucomicrobia and family of Caldilineaceae,Llumatobacteraceae were more abundant in the Upper reaches than in the Mid–Lower reaches.The microbial communities were predominantly affected by nutrient factors(such as NH_(4)^(+),TN and TP),followed by the spatial and the content of Chla in the Mid–Lower reaches,while they were by predominantly affected by spatial factors,followed by the nutrient factors and the content of Chla in the Upper reaches.The dominant microbial taxa were mostly correlated with COD,NH_(4)^(+),TP and temperature,but they responded differently to these physiochemical factors between the Upper and Mid–Lower reaches.In summary,the sedimentary microbial communities differ between the Upper and Mid–Lower reaches and respond differently to the environmental and spatial factors in the sediment of the Yellow River.展开更多
基金The Natural Science Foundation of Fujian Province of China under contract No.2023J011378the National Key Research and Development Program of China under contract No.2019YFE0124700the Special Fund for Basic Scientific Research Foundation of the Third Institute of Oceanography,Ministry of Natural Resources,China under contract Nos 2019018 and 2020017.
文摘As the most important component of marine siliceous organisms,diatoms are vital primary producers of the ocean that are often used as indicators of paleoenvironmental change.To understand the response of sedimental diatoms to regional environmental changes and the factors affecting the distribution of sedimental diatoms in the Taiwan Strait,this study quantified and classified the diatoms found in surface sediments collected during four surveys from 2019 to 2020.Overall,118 diatom taxa and 44 genera were identified with total diatom abundance of 8-27353 valves/g.Four diatom assemblages representing different environments were identified.Among them,assemblageⅠrepresented a coastal environment,assemblageⅡcomprised warm water species of a coastal environment,AssemblageⅢrepresented a coastal environment affected markedly by exorheism,AssemblageⅣrepresented a group with lowest diatom abundance.Seasonal variation in total diatom abundance was controlled by seven environmental factors:depth,sea surface salinity,mean grain size,silicate,nitrite,nitrate,and phosphate.Spatiotemporal variation in each of the diatom assemblages was substantial and strongly affected by various currents,upwelling,and low-salinity water.Specifically,it was found that the succession of diatom assemblages reflects change in the range of influence of local warm currents.
基金supported by the Hunan Provincial Natural Science Foundation of China(Nos.2023JJ40518 and 2023JJ30490)the Scientific Research Foundation of Hunan Provincial Education Department(Nos.21B0511 and 22A0384)the Research Funding Project of Jishou University for talent introduction.
文摘Fluoroquinolones(FQs)have the propensity to accumulate in sediments once introduction into aquatic envi-ronments,thereby posing potential threats to benthic organisms,yet the ecotoxicity of sediment-associated FQs remains unclear.In this study,the toxicokinetics and responses of multiple biomarkers in Bellamya aeruginosa,exposed to the three commonly used FQs(norfloxacin,NOR;ciprofloxacin,CIP;levofloxacin,LEVO)at envi-ronmentally relevant concentrations were investigated under sediment exposure scenario.The results revealed that FQs were effectively ingested by B.aeruginosa from sediments,CIP showing the highest bioaccumulation(180.59μg/kg),followed by NOR(74.49μg/kg)and LEVO(36.02μg/kg).CIP exhibiting a highest uptake rate constant(Ks)(4.64 g/(g·day))and the lowest elimination rate constant(K_(e))(0.05 g/(g·day)).The descending order of biological half-life is as follows:CIP(13.62 days),LEVO(8.14 days),and NOR(6.83 days).NOR induced the activity of superoxide dismutase,catalase,and glutathione-S-transferase while CIP and LEVO depressed their activities and increased malondialdehyde content,indicating a more pronounced oxidative damage to B.aerug-inosa caused by CIP and LEVO than NOR.Furthermore,all three FQs were found to induce DNA damage and elevate acetylcholinesterase activity,suggesting distinct genotoxic and neurotoxic effects.Interestingly,despite its low bioaccumulation potential,LEVO exhibited high toxicity towards B.aeruginosa.These findings enhance our understanding of the ecotoxicity of FQs in sediments,providing further evidence of their potential ecological risks.
文摘Noncohesive particle clusters are identified and tracked in turbulent flows to determine the breakdown and time evolution of cluster statistics and their implications for interscale mass transfer,which has connections to the classical turbulent energy cascade and its mass cascade counterpart running in parallel.In particular,the formation and dynamics of sediment and larvae clusters are of interest to coral larvae settlement in coastal regions and particularly the resilience of green-gray coastal protection solutions.Analogous cluster behavior is relevant to cloud microphysics and precipitation initiation,radiation transport and light transmission through colloids and suspensions,heat and mass transfer in particle-laden flows,and viral and pollutant transmission.Following a comparison between various clustering techniques,we adopt a density-based cluster identification algorithm based on its simplicity and efficiency,where particles are clustered based on the number of neighboring particles in their individual spheres of influence.We establish parallels with lattice-based percolation theory,as evident in the power-law scaling of the cluster size distribution near the percolation threshold.The degree of discontinuity of the phase transition associated with this percolation threshold is observed to broaden with larger Stokes numbers and thereby large-scale clustering.The sensitivity of our findings to the employed clustering algorithm is discussed.A novel cluster tracking algorithm is deployed to determine the interscale transfer rate along the particle-number phase-space dimension via accounting of cluster breakup and merger events,extending previous work on the bubble breakup cascade beneath surface breaking waves.Our findings shed light on the interaction between particle clusters and their carrier turbulent flows,with an eye toward transport models incorporating cluster characteristics and dynamics.
基金supported by the National Key Scientific Research Project(Grant No.2023YFC3209303)jointly funded by the National Natural Sciences Foundation of China(Grant Nos.42577406 and 42077076)the National Natural Science Foundation of China and Yellow River Water Science Research Joint Fund(Grant No.U2243211).
文摘Accurate identification of sediment sources and erosion hotspots is crucial for implementing targeted soil and water conservation measures.This study analyzed the temporal dynamics of sediment source contributions during seven rainfall events(A_(1)–A_(7))that generated both runoff and suspended sediment at the outlet of the Hantaichuan watershed,located in the wind–water erosion crisscross region of the northern Loess Plateau,China.A total of 82 suspended sediment samples were collected at the Xiangshawan hydrological station during 2021 and 2022.Additionally,145 soil samples were collected from three primary potential sources:sandy soil,loess soil,and Pisha sandstone.Mid-infrared(MIR)spectroscopy and geochemical fingerprinting were used to trace and quantify sediment sources.For MIRbased source apportionment,twelve predictive models were developed using partial least squares regression(PLSR)and support vector machine regression(SVMR)in combination with six spectral preprocessing techniques.The PLSR model with first-derivative Savitzky–Golay(SGD1)preprocessing achieved the best performance.Source apportionment results indicated that Pisha sandstone was the dominant sediment source(44.00%–72.23%),followed by sandy soil(14.23%–37.00%)and loess soil(10.01%–24.00%).Among the analyzed rainfall events,the contribution of Pisha sandstone was lowest in the small flow magnitude event A3(57.53%)and highest in the large flow magnitude event A6(63.48%),suggesting that sediment source composition was strongly controlled by rainfall event magnitude.Both MIR spectroscopic and geochemical fingerprinting methods showed high consistency,confirming MIR spectroscopy as a reliable,non-destructive,and cost-effective alternative for rapid sediment source apportionment and for supporting erosion control prioritization in highly erodible catchments.
基金National Natural Science Foundation of China,No.42225105,No.42201175The China Postdoctoral Science Foundation,No.2023M733605。
文摘As an essential component of terrestrial carbon sinks,lake sediments store vast quantities of both organic carbon(OC)and inorganic carbon(IC).However,the spatiotemporal relationship between the OC and IC in sediments and their responses to climate change remains unclear,which hinders the comprehensive understanding of carbon dynamics in lake ecosystems.This study systematically analyzes the spatiotemporal dynamics of carbon burial across the Tibetan Plateau using surface sediments from 119 lakes and sediment cores from four representative lakes.Results show that OC burial dominates in humid and dry sub-humid zones,whereas IC burial prevails in arid and semi-arid regions.This distribution reflects the influences of lake and catchment productivity and water chemistry on OC and IC patterns.Sediment cores confirm that these factors have consistently affected lake carbon burial over the past century.Specifically,in humid and dry sub-humid zones,increased precipitation enhances watershed productivity and sedimentation,promoting coupled OC and IC burial.In arid and semi-arid regions,wind-driven dust supplies nutrients and alters water chemistry,also driving coupled OC and IC burial.Based on these findings,the carbon sink capacity of lake sediments on the Tibetan Plateau is projected to increase under the“warming and wetting”trend.
基金supported by Shaanxi Key Research and Development Program(No.2024SF-YBXM-546)the National Natural Science Foundation of China(No.52470161)the State Key Laboratory of Pollution Control and Resource Reuse Foundation(No.PCRRF21007).
文摘With the legislative development,the organic and inorganic composition separation has become the primary requirement for sewer sediment disposal,however the relevant technology has been rarely reported and the driving mechanism was still unclear.In this study,direct disintegration of biopolymers and indirect broken of connection point were investigated on the hydrolysis and component separation.Three typical sewer sediment treatment approaches,i.e.,alkaline,thermal and cation exchange treatments were proposed,which represented the hydrolysis-driving forces of chemical hydrolysis,physical hydrolysis and innovative cation bridging break-age.The results showed that the organic and inorganic separation rates of sewer sediment driven by alkaline,thermal and cation exchange treatments reached 21.26%,23.80%,and 19.56%-48.0%,respectively,compared to 4.43%in control.The secondary structure of proteins was disrupted,transitioning from𝛼α-helix to𝛽β-turn and random coil.Meanwhile,much biopolymers were released from solid to the liquid phase.From thermody-namic perspective,sewer sediment deposition was controlled by short-range interfacial interactions described by extended Derjaguin-Landau-Verwey-Overbeek theory.Additionally,the separation of organic and inorganic components was positively correlated with the thermodynamic parameters(Corr=0.87),highlighted the robust-ness of various driving forces.And the flocculation energy barriers were 2.40(alkaline),1.60 times(thermal),and 4.02–4.97 times(cation exchange)compared to control group.The findings revealed the contrition differ-ence of direct disintegration of gelatinous biopolymers and indirect breakage of composition connection sites in sediment composition separation,filling the critical gaps in understanding the specific mechanisms of sediment biopolymer disintegration and intermolecular connection breakage.
基金National Science Foundation of China(No.41576082)。
文摘Chlorophyll-a is the most abundant chlorophyll pigment produced by marine phytoplankton,and it bears the isotope signature of the nitrate source assimilated in the N-atoms that are embedded in its porphyrin ring.The chloropigment and its degradation product,i.e.,pheophytin-a,could be well preserved in marine sediment,usually at nanomolar level.A sensitive and accurate measurement of theδ15N of chloropigment is capable of providing rich information to greatly enhance our understanding of past nitrogen cycling,which therefore is urgently needed.Hereby,we present a successful method based on two-step HPLC separation followed by'denitrifier method'.The N-content in acetone and potassium persulfate(K_(2)S_(2)O_(8))are very critical to the precision and accuracy of the measurements,because they constitute the majority of the N contamination to the Chl-a samples.In this method,the recrystallized K_(2)S_(2)O_(8)that is used as oxidization reagent was discovered to have aδ15N background of-15‰,consolidated by repeated examinations over a period of two months.This 15N background of K_(2)S_(2)O_(8)would cause-1‰–-2‰deviation on theδ^(15)N of sample that contains nanomolar level N,and highlight the need to examine theδ^(15)N of recrystallized K_(2)S_(2)O_(8)when it is used to oxidize samples of organic nitrogen.The overall measurement ofδ^(15)N pigment is reliable and has an average analytical precision better than±0.5‰(1σ).This study establish a sensitive method for accurate measurement of theδ^(15)N of nano-molar level chlorophyll pigment,and with no doubts will advance its wide application in marine nitrogen cycling studying.
基金supported by the State Key Research Development Program of China(Grant No.2021YFC2800905-02)the National Natural Science Foundation of China(Grant No.52304208)。
文摘Identifying geohazards such as landslides and methane leakage is crucial during gas extraction from natural gas hydrate(NGH)reservoirs,and understanding reservoir settlement behavior is central to this assessment.Horizontal wells can enlarge the pressure relief zone within the formation,improving single-well productivity,and are therefore considered a promising approach for NGH development.This study examines the settlement response of hydrate-bearing sediments during depressurization using horizontal wells.A fully coupled thermal,hydraulic,mechanical,and chemical(THMC)model with representative reservoir properties(Shenhu region in the South China Sea)is presented accordingly.The simulations show that lower production pressures,while increasing gas output,also intensify formation settlement.The maximum difference in settlement between the lowest and highest production pressures reaches 0.016 m,contributing to more pronounced differential subsidence.Optimal well placement,specifically targeting a low-saturation hydrate zone containing free gas and situated adjacent to a high-saturation hydrate layer,markedly improves both gas production rate and cumulative yield,while reducing overall settlement and limiting changes in effective stress.
基金funding from the Natural Science Foundation of Shanxi Province(202403021222245,20240302121217)。
文摘The variation laws of runoff and sediment load under different climate,vegetation,and human activity scenarios are significantly different.Exploring the impacts of climate change and human activities on runoff and sediment load dynamics can provide a profound understanding of the mechanism of runoff and sediment load variability in basins,which is crucial for the sustainable development of regional ecosystems.This study investigates the Tao River Basin(TRB)on the Tibetan Plateau,as well as the Zuli River Basin(ZRB)and Jing River Basin(JRB)on the Loess Plateau,to differentiate the impacts of climate change and human activities on runoff and sediment load dynamics.The runoff and sediment load of the three watersheds have shown a decreasing trend over the past 40 years,and combined with the DMC(Dual mass curve)method,it was found that the slope of the runoff sediment gradually tends to flatten out.After the time period was divided,the CA(Cumulative anomaly)method was used for verification,which revealed good correspondence between the two before 2000 and then gradual deviations.The power function best represents the relationship between runoff and sediment load.During the initial period,climate had a significant impact on runoff variation in the TRB and JRB,with contribution rates of-54.93%and-63.02%,respectively.In the later period,human activities became the dominant influence,contributing more than-60%of the runoff variation.In the ZRB,human activities consistently dominated runoff variation,with contribution rates of-72.72%and-55.66%during both periods.In the early stages of research,the impact of climate change on sediment load was more severe in the TRB and JRB,and human activities played a significant role in the later stages.However,in the ZRB,human activities have always been the main contributor.Based on the actual local situation,runoff and sediment load in the TRB are influenced primarily by engineering measures,and vegetation and check dams exert greater impacts on the ZRB and JRB.This study explores the attribution of water and sediment load changes in different ecological geographic regions from a comparative perspective,providing a valuable theoretical basis and reference for understanding global runoff and sediment transport changes in similar areas.
基金supported by the National Natural Science Foundation of China(Nos.42073078,U1901211 and 41876126)the National Key Research and Development Program of China(Nos.2023YFC3905003,2023-67 and 2017FY100700)+4 种基金the Hainan Province Science and Technology Special Fund(ZDYF2023SHFZ172)the Natural Science Foundation of Guangdong Province(Nos.2020A1515011137,2023A1515012004 and 2024A1515011203)Nansha District High-Level Talent Innovation Team Project in 2021(Mangrove Wetland Blue Carbon Sequestration Technology Innovation Team)the Strategic Priority Research Program of the Chinese Academy of Sciences(No.XDA19060204)the Key Tasks Guarantee Special Fund Project for Green-Beautiful Guangdong Ecological Construction in 2024(Precise Restoration and Ecological Function Evaluation of Mangroves).
文摘Estuaries are key areas for organic carbon cycling,where polymeric carbohydrates are abundant and chemically diverse.The recycling of these polymers by microbes depends on a variety of carbohydrate-active enzymes(CAZymes).However,it remains unclear whether other gene traits,particularly those related to cell motility toward polymeric carbohydrates,are intertwined with carbohydrate depolymerization and niche specialization in estuarine sediment soils.In this study,estuarine sediments were incubated with four prevalent polymeric carbohydrates(laminarin,fucan,cellulose,and chitin) under anaerobic conditions.Based on metagenomic analysis,we identified potential responses to the degradation and utilization of polymeric carbohydrate substrates from the perspectives of CAZymes and sugar transporters.The analysis of metagenomic gene data also revealed a positive correlation between chemotaxis and the abundance of CAZymes genes.Furthermore,metagenomes-assembled genomes(MAGs) that exhibited higher abundance in polysaccharide-treated samples compared to controls also featured elevated copies of genes involved in polysaccharide utilization loci(PULs),chemotaxis,as well as those associated with flagellar or gliding movement.SprB and CTDs associated with gliding proteins genes are essential for type Ⅸ secretion system-mediated secretion of CAZymes and gliding motility in Bacteroidota.The enhanced potential for mobility,coupled with the ability to degrade polymeric carbohydrates,may enable these bacteria to exploit nutrients beyond carbon sources,thereby potentially broadening their ecological niches.
基金supported by the National Natural Science Foundation of China(No.42001084)the Major Science and Technology Projects of Xinjiang Uygur Autonomous Region(Nos.2022A03009-2,2022A03009)the Third Xinjiang Scientific Expedition Program(No.2022xjkk1303)。
文摘Exploring hydroclimatic variability and its driving mechanisms during the Holocene is essential for comprehending both historical and prospective responses of water resources to climatic shifts in Arid Central Asia(ACA)region.However,debate persists regarding whether dryland lakes in this region exhibited aridification or humidification during the Holocene.Lopnur serves as the terminal lake of Tarim rivers during the Holocene,which offers an ideal natural laboratory to address the questions.In this study,a high-resolution chronological framework was established through precise radiocarbon dating.Multi-proxy analyses,including geochemical composition,grain size distributions,MS,LOI,and C/N ratios were conducted from a lacustrine profile in the core area of“Great ear”in the southern part of Lopnur catchment.These analyses enabled the reconstruction of hydrological dynamics and facilitated the disentanglement of independent signals linked to climate variability,runoff fluctuations,and lake-level changes.The results demonstrate that the MidHolocene(7800–4000 cal yr B.P.)was characterized by cold and humid conditions,resulting in elevated surface runoff and lake level.The Late Holocene(4000–1300 cal yr B.P.)experienced intensified aridification,characterized by reduced runoff and declining lake level.These evidences suggested a climatic regime of a distinctive alternation between“cold-wet”and“warm-dry”climatic regimes during the Mid-to-Late Holocene.Compared with the previous studies from adjacent regions,we speculate that the hydroclimatic evolution of Lopnur catchment possibly influenced by a complex interplay of large spatial scale forcings,including variations in annual insolation,greenhouse gas concentrations,and ice sheets,as well as the localized controls such as topographic features,vegetation cover,and cloud-radiative feedbacks.Our findings enhance the understanding of past climatic complexity and provide valuable insights for future water resource management strategies in drylands.
基金supported by the National Natural Science Foundation of China(Grant Nos.92252104,12388101,and 12472224).
文摘In this study,we perform particle-resolved simulations of settling spheroidal particles,considering oblate and prolate spheroids and spheres,and investigate the shape effect on the particle dynamics in suspensions with volume fraction 1%and 5%.We first examine the single-point statistics of the translational and rotational motion of the settling particles.The horizontal velocity has a symmetrical distribution with standard deviation dependent on the particle shape.The greater horizontal velocity fluctuations of the non-spherical particles,compared to that of spheres,are attributed to the horizontal drift of settling spheroids with oblique orientations induced by the fluid-particle and particle-particle interactions.The fluctuation of particle vertical velocity,instead,is skewed under the effect of wake-induced hydrodynamic interactions.Further,we explore the particle pair statistics,which demonstrate the formation of column-like particle micro-structures for the lowest volume fraction considered.This clustering is more pronounced for spheroidal particles than spheres,due to the stronger attractions among vertically-aligned settling spheroids.Moreover,the particle pair statistics are directly related to the collision rate among the dispersed particles.The local accumulation of oblate/prolate spheroids serves as the major mechanism to promote the particle-particle collisions in dilute suspensions.
文摘Organic-rich sediments represent vital components of Earth's geochemical cycles, acting both as potential hydrocarbon and coal reservoirs and as unconventional archives for critical metals such as rare earth elements(REEs). With the growing emphasis on clean energy technologies, the Cenozoic organic deposits of India have gained renewed significance;however, those from the southern state of Kerala remain understudied. This study investigates lignite and associated carbonaceous sediments from the Cheruvathur and Warkalli Formations using a multi-proxy approach integrating organic petrography,infrared spectroscopy, stable carbon isotopes, and REE geochemistry. The lignite exhibits huminite dominance with Type Ⅲ kerogen, deposited in a wet, mesotropic bog forest swamp under anoxic conditions. The mineral assemblage, dominated by kaolinite, quartz, illite, montmorillonite, feldspar,and pyrite/marcasite, reflects strong chemical alteration in a reducing environment. The δ^(13)C values(-25.1 to-27.3) indicate a C_(3) angiosperm source and deposition in tropical to subtropical swamp settings. REE patterns reveal LREE enrichment in carbonaceous shales and HREE enrichment in lignite,with distinct Ce, Eu, and Gd anomalies associated with provenance and redox conditions. The findings provide new insights into the paleoenvironmental evolution of Kerala's Cenozoic basins and highlight their potential as unconventional REE-bearing resources in the context of the global energy transition.
文摘Soil erosion is a fundamental physical process driving land degradation across various spatial and temporal scales.The Soil and Water Assessment Tool(SWAT)model is a robust tool for predicting soil erosion and evaluating water and soil quality within watersheds.The latest version,SWAT+,introduces advanced encoding capabilities and improved performance,making it better suited for addressing complex watershed modeling challenges.This study implemented the SWAT+model to quantify soil erosion rates within the Chehelchay watershed in northern Iran.The foundational dataset comprises a 30-meter resolution Digital Elevation Model(DEM),land use classification,soil,and weather data.Model performance was evaluated using Nash-Sutcliffe Efficiency(NSE),coefficient of determination(R^(2)),root mean square error(RMSE),and percent bias(PBIAS).The SWAT+simulation revealed substantial spatial variation in erosion patterns across the watershed,with annual sediment yields in critical HRUs,reflecting diverse erosion intensities driven by variations in land use,soil characteristics,and slope.Among the Hydrological Response Units(HRUs),50 critical units,representing approximately 9%of the total watershed area,generate sediment yields exceeding 5 tons per hectare per year.The most severe erosion occurs predominantly in the central zone of the watershed.Downstream regions exhibit minimal soil loss due to gentle topography while upstream areas maintain soil stability through protective forest cover,resulting in negligible erosion rates.Best Management Practices(BMPs)were designed to safeguard water and soil resources at a watershed level.The study evaluated three strategic conservation interventions:alfalfa cultivation,agroforestry implementation,and garden development.When applied in combination,these measures achieved approximately 30%reduction in sediment yield at the HRU level.This integrated approach demonstrates the potential of combining multiple land management strategies to combat erosion effectively.
基金supported by the National Natural Science Foundation of China(Grant No.42171135)the Science and Technology Program of CNOOC Research Institute(Grant No.2023OTKK03)the“CUG Scholar”Scientific Research Funds at China University of Geosciences(Project No.2022098).
文摘The volume change behavior of natural gas hydrate-bearing sediment is essential as it influences settlement,strength,and stiffness,which directly affect the stability of hydrate reservoirs during hydrate extraction or in response to environmental changes.The volume change is influenced not only by stress but also by the formation and dissociation of hydrates.This study adopted a customized apparatus for one-dimensional compression tests,allowing independent control of gas pressure and effective stress.Tests were conducted on samples with different hydrate saturations along various temperature-gas pressure-effective stress paths,yielding some conclusions related to compressibility and creep.An unusual phenomenon was observed under low-stress conditions:hydrate formation led to shrinkage rather than expansion.Three potential mechanisms behind this occurrence were discussed.As hydrate saturation increases,the yield stress rises while the compression and swelling indexes remain minimally affected.After hydrate dissociation,the compression curve of hydrate-bearing sediment drops to that of hydrate-free sediment.Once hydrate is formed,the compression curve of hydrate-free sediment gradually approaches that of hydrate-bearing sediment during the subsequent loading.Under low-stress conditions,the creep of both hydrate-free and hydrate-bearing sediments is very weak.However,when stress increases,significantly beyond the yield stress,the creep of both sediments increases significantly,with hydrate-bearing sediment exhibiting much greater creep than hydrate-free sediment.
基金support in the literature analysis.This study has been carried out in the framework of the project funded by EU entitled“Bioremediation of contaminated sediments in coastal areas of exindustrial sites-LIFE SEDREMED”(No.LIFE20 ENV/IT/000572).
文摘This study compares the environmental sustainability of five alternatives for the remediation of marine sediments of one of the most polluted coastal sites in Europe(Bagnoli-Coroglio bay,Mediterranean Sea),using the Life Cycle Assessment(LCA)methodology.The treatments are either in-situ or exsitu,the latter requiring an initial dredging to transport the contaminated sediments to the management site.More in detail,four ex-situ remediation technologies based on landfilling,bioremediation,electrokinetic technique and soil washing were identified.These technologies are compared to an in-situ strategy currently under validation for enhancing bioremediation of the polluted sediments of the Bagnoli-Coroglio site.Our results indicate that the disposal in landfilling site is the worst option in most categories(e.g.,650 kg CO_(2) eq./t of treated sediment,considering the nearest landfilling site),followed by the bioremediation,mainly due to the high energy demand.Electrokinetic remediation,soil washing,and innovative in-situ technology represent the most sustainable options.In particular,the new in-situ technology appears to be the least impacting in all categories(e.g.,54 kg CO_(2) eq./t of treated sediment),although it is expected to require longer treatment time(estimated up to 12 months based on its potential efficiency).It can reduce the impact on climate change more than 12 times compared to the disposal and 7 times compared to bioremediation in addition to the possibility to avoid/reduce the dredging operations and the consequent dispersion of pollutants.The results open relevant perspectives towards more eco-sustainable and costly effective actions for the reclamation of contaminated marine sediments.
基金supported by the National Key R&D Program of China(Grant No.2018YFC1505205)the Science and Technology Research Program of the Institute of Mountain Hazards and Environment,Chinese Academy of Sciences(Grant No.IMHE-ZDRW-01)Sichuan Science and Technology Program(Grant No.2024NSFSC0781).
文摘A debris flow descending through an erodible convex colluvial bed,originating from a landslide dam and its upstream deposits,can entrain massive amounts of sediment,dramatically increasing the debris flow volume.Most existing erosion models assume that bed sediments are fully saturated,although this condition is rarely observed in nature.Therefore,a thorough understanding of debris flow overtopping erosion on a convex unsaturated bed is crucial for quantifying disaster risk.In this study,we experimentally investigated the effects of sediment composition,specifically coarse-grain size distribution and fine particle content,on the pore pressure evolution and entrainment of debris flows overriding a convex unsaturated colluvial bed.The average entrainment rate at convex sites for continuously graded bed sediment was higher than its discontinuous counterpart.The measured pore pressures within the unsaturated bed sediments were primarily generated by the passing debris flows.Furthermore,it was found that these pressures decreased as the fine particle content increased and the coarse-grain size of the erodible substrates decreased.When the coarse-grain size of the debris flow was smaller than that of the bed sediment,only a portion of the eroded material was entrained by the moving debris flow.In contrast,when the coarse-grain size of the debris flow was equal to or greater than that of the bed sediment,nearly all of the eroded material was entrained.The findings of this study could contribute to the assessment of hazard amplification and inform the design of mitigation and prevention strategies.
文摘State Field Observation and Research Station of Debris Flow in Dongchuan,Yunnan is also named Dongchuan Debris Flow Observation and Research Station,Chinese Academy of Sciences.The study area,Jiangjia Ravine,is about 48.6 km2 and characterized by intense tectonism.Accumulated clastic detritus is the main source of the materials in the debris flows when an intense rainfall occurs.The recorded highest density and sediment transport are 2370 kg/m^(3) and 6.079×10^(6) kg/s,respectively.The ravine is now called the“debris flow museum”in China and supplies advantageous research conditions.
基金funded by the Joint Funds of the National Natural Science Foundation of China (U20A20107 and U22A20562)the National Key Research and Development Program of China (2023YFD1900201-3)the International Cooperation Project,Ministry of Science and Technology of China (G2023019005L)。
文摘The lateral transport of labile organic carbon represents a critical pathway for soil organic carbon(SOC) loss,reducing organic carbon sequestration and increasing the risk of waterbody pollution.Livestock manure application on croplands serves as a common fertilizer reduction practice to sustain crop yields,enhance SOC sequestration,and reduce water erosion.However,limited quantitative assessments have examined the effects of livestock manure substitution on labile organic carbon lateral loss and fluxes in long-term experiments.This study conducted a three-year field investigation on subtropical sloping croplands to assess the impact of livestock manure substitution on dissolved organic carbon(DOC) and particulate organic carbon(POC) loss via surface runoff,interflow and eroded sediments.There are four treatments:no fertilization(CK);chemical nitrogen fertilizer(SF),40% nitrogen substitution with pig manure(PMF),and 100% nitrogen substitution from pig manure(PM).Compared to SF treatment,long-term livestock manure substitution in PMF and PM treatments significantly(P<0.05) reduced annual cumulative surface runoff fluxes by 13.5 and 21.6%,respectively.Manure applications decreased annual sediment fluxes by 12.9 and 19.1%,respectively.Soil water stable aggregates for mean weight diameter(MWD) increased significantly by 37.7 and 73.6%.Annual cumulative POC loss flux via eroded sediment under PMF and PM treatments increased significantly(P<0.05) by 61.1 and 47.9%,respectively.The labile organic carbon loss fluxes,including DOC and POC losses,under PMF and PM treatments increased significantly(P<0.05) by 11.9 and 31.4%,respectively.These results demonstrate that while water erosion intensity decreases due to enhanced soil aggregate stability,the risk of labile organic carbon loss increases after long-term livestock manure substitution in subtropical sloping croplands.Future research should examine labile organic carbon lateral migration under various soil types and slope gradients for livestock manure application in subtropical agricultural ecosystem croplands to better understand extreme rainfall effects.
基金funded by the National Natural Science Foundation of China(No.42402310)the Natural Science Foundation of Henan Province(No.242300421657)+1 种基金the National Key Research and Development Program(No.2024YFD2402005)the China Agriculture Research System(No.CARS-50)。
文摘Sedimentary microbial communities play an important role in driving biogeochemical cycles in river ecosystems.The Yellow River is one of the rivers with the highest turbidity over the world.However,limited is known about the microbial variation and its influencing factors in the Yellow River.In this study,we examined the microbial communities and their influencing factors in the sediment of Upper and Mid–Lower reaches of the Yellow River.The results showed that Gammaproteobacteria were most dominant(with Hydrogenophilaceae being the predominant family)in the studied Yellow River sediments.Phyla of Deltaproteobacteria,Nitrospirae and family of Bacillaceae,Geobaceraceae were more abundant in the Mid–Lower reaches than in the Upper reaches,while phyla of Gammaproteobacteria,Verrucomicrobia and family of Caldilineaceae,Llumatobacteraceae were more abundant in the Upper reaches than in the Mid–Lower reaches.The microbial communities were predominantly affected by nutrient factors(such as NH_(4)^(+),TN and TP),followed by the spatial and the content of Chla in the Mid–Lower reaches,while they were by predominantly affected by spatial factors,followed by the nutrient factors and the content of Chla in the Upper reaches.The dominant microbial taxa were mostly correlated with COD,NH_(4)^(+),TP and temperature,but they responded differently to these physiochemical factors between the Upper and Mid–Lower reaches.In summary,the sedimentary microbial communities differ between the Upper and Mid–Lower reaches and respond differently to the environmental and spatial factors in the sediment of the Yellow River.
