Protoporphyrin Ⅸ(PPⅨ), a basic porphyrin system found in nature, all “porphyrin-type”tetrapyrroles with a biological function are biosynthetically derived thereof. PPⅨ is a metalloprosthetic group of numerous pro...Protoporphyrin Ⅸ(PPⅨ), a basic porphyrin system found in nature, all “porphyrin-type”tetrapyrroles with a biological function are biosynthetically derived thereof. PPⅨ is a metalloprosthetic group of numerous proteins involved in diverse metabolic and respiratory processes across all domains of life, and is thus considered essential for respiring organisms. Determining the biotic and abiotic factors that influence marine microbial growth and community structure is critical for understanding global biogeochemical cycles. Here,we present vertical profiles of intracellular PPⅨ and four derivative products(Chlorophylla/b and Pheophytin-a/b) from two coastal sediment cores, alongside ancillary geochemical and 16S rRNA microbial community data. Our findings indicated that PPⅨ is present in the natural sediment environment and displays a decreasing trend with depth, revealing a significant positive correlation with both organic matter and microbial abundance. Cooccurrence networks revealed that the environmental distribution of PPⅨ was positively correlated with the microbial porphyrin producer(high genetic completeness), but negatively correlated with auxotrophs(absence or low genetic completeness). It emphasized the critical role of PPⅨ as a biological molecule involved in key physiological processes. These results suggest that PPⅨ is a prominent component of the shared extracellular metabolite pool, especially in anoxic marine sediments where it exists at physiologically relevant concentrations for microbial metabolism. This study highlighted the significance of PPⅨ in microbial ecology and its potential impact on biogeochemical cycles in marine sedimentary environments.展开更多
Soft-sediment deformation structures(SSDS)in water-saturated,unconsolidated sediments are the product of various causes and provide a valuable record of environmental and geological perturbations.We report a record of...Soft-sediment deformation structures(SSDS)in water-saturated,unconsolidated sediments are the product of various causes and provide a valuable record of environmental and geological perturbations.We report a record of SSDS preserved in a~166 m-long drill core(DX-2)extracted from the Late Pleistocene Diexi Palaeolake,eastern Tibetan Plateau.Two factors make this an outstanding site for studying SSDS:(1)it is among the most seismically active regions on Earth,and(2)it has experienced extremely fast sedimentation rates(~15 mm/yr)thanks to the prodigious sediment supply from seismically perturbed hillslopes and rivers upstream.We describe and interpret 13 SSDS types within the DX-2 based on detailed sedimentological,morphological,and lithological analysis.We consider the genesis of the abundant SSDS observed in the DX-2 core with several possibilities:mass movement,rock avalanche-driven tsunamis,rapid sedimentation,and seismic shaking as the most probable triggering mechanisms.We suggest high-intensity earthquakes of VI(Modified Mercalli Intensity)or greater as drivers of SSDS in the DX-2.Based on our observations,we propose a conceptual model that attempts to explain the transition from ductile to brittle SSDS behaviour with progressive accumulation and consolidation of the sediment pile.This paper highlights the value of SSDS analysis in palaeo-earthquake identification,aiming to improve the applicability of SSDS as a palaeo-earthquake marker in alpine and canyon areas.展开更多
Fluoroquinolones(FQs)have the propensity to accumulate in sediments once introduction into aquatic envi-ronments,thereby posing potential threats to benthic organisms,yet the ecotoxicity of sediment-associated FQs rem...Fluoroquinolones(FQs)have the propensity to accumulate in sediments once introduction into aquatic envi-ronments,thereby posing potential threats to benthic organisms,yet the ecotoxicity of sediment-associated FQs remains unclear.In this study,the toxicokinetics and responses of multiple biomarkers in Bellamya aeruginosa,exposed to the three commonly used FQs(norfloxacin,NOR;ciprofloxacin,CIP;levofloxacin,LEVO)at envi-ronmentally relevant concentrations were investigated under sediment exposure scenario.The results revealed that FQs were effectively ingested by B.aeruginosa from sediments,CIP showing the highest bioaccumulation(180.59μg/kg),followed by NOR(74.49μg/kg)and LEVO(36.02μg/kg).CIP exhibiting a highest uptake rate constant(Ks)(4.64 g/(g·day))and the lowest elimination rate constant(K_(e))(0.05 g/(g·day)).The descending order of biological half-life is as follows:CIP(13.62 days),LEVO(8.14 days),and NOR(6.83 days).NOR induced the activity of superoxide dismutase,catalase,and glutathione-S-transferase while CIP and LEVO depressed their activities and increased malondialdehyde content,indicating a more pronounced oxidative damage to B.aerug-inosa caused by CIP and LEVO than NOR.Furthermore,all three FQs were found to induce DNA damage and elevate acetylcholinesterase activity,suggesting distinct genotoxic and neurotoxic effects.Interestingly,despite its low bioaccumulation potential,LEVO exhibited high toxicity towards B.aeruginosa.These findings enhance our understanding of the ecotoxicity of FQs in sediments,providing further evidence of their potential ecological risks.展开更多
The Martian core mainly contains iron,nickel and some light elements.However,controversies remain about the structure and chemical composition of the Martian core due to a lack of samples and marsquake data.Recently,t...The Martian core mainly contains iron,nickel and some light elements.However,controversies remain about the structure and chemical composition of the Martian core due to a lack of samples and marsquake data.Recently,the InSight lander collected long-term marsquake data,which improved the Martian interior structure model.B ased on the preliminary analysis of marsquake data,Mars has a molten liquid core with a radius of around 1700 km.As the Martian core has a smaller density and lower temperature than pure iron at corresponding pressure and temperature conditions,some light elements are introduced to reduce the density and liquidus temperature.With various methods for seismic analysis,in-situ high-pressure and high-temperature experiments,and first-principal calculations,the Martian core composition and evolution models have been updated in the past few years.Here,we review those studies on the light elements in the Martian core from four aspects including(1)high-temperature and high-pressure experiments,(2)marsquake data,(3)mineral physics model with molecular dynamics simulations and(4)cosmochemistry investigation.We discussed the effect of different light elements on the Martian core s density,sound velocity and liquidus temperature.Moreover,the review examines the varieties,abundances and forms of light elements in the Martian core.展开更多
Soil erosion is a fundamental physical process driving land degradation across various spatial and temporal scales.The Soil and Water Assessment Tool(SWAT)model is a robust tool for predicting soil erosion and evaluat...Soil erosion is a fundamental physical process driving land degradation across various spatial and temporal scales.The Soil and Water Assessment Tool(SWAT)model is a robust tool for predicting soil erosion and evaluating water and soil quality within watersheds.The latest version,SWAT+,introduces advanced encoding capabilities and improved performance,making it better suited for addressing complex watershed modeling challenges.This study implemented the SWAT+model to quantify soil erosion rates within the Chehelchay watershed in northern Iran.The foundational dataset comprises a 30-meter resolution Digital Elevation Model(DEM),land use classification,soil,and weather data.Model performance was evaluated using Nash-Sutcliffe Efficiency(NSE),coefficient of determination(R^(2)),root mean square error(RMSE),and percent bias(PBIAS).The SWAT+simulation revealed substantial spatial variation in erosion patterns across the watershed,with annual sediment yields in critical HRUs,reflecting diverse erosion intensities driven by variations in land use,soil characteristics,and slope.Among the Hydrological Response Units(HRUs),50 critical units,representing approximately 9%of the total watershed area,generate sediment yields exceeding 5 tons per hectare per year.The most severe erosion occurs predominantly in the central zone of the watershed.Downstream regions exhibit minimal soil loss due to gentle topography while upstream areas maintain soil stability through protective forest cover,resulting in negligible erosion rates.Best Management Practices(BMPs)were designed to safeguard water and soil resources at a watershed level.The study evaluated three strategic conservation interventions:alfalfa cultivation,agroforestry implementation,and garden development.When applied in combination,these measures achieved approximately 30%reduction in sediment yield at the HRU level.This integrated approach demonstrates the potential of combining multiple land management strategies to combat erosion effectively.展开更多
Low reactivity and appropriate wettability between molten superalloys and ceramic materials are crucial for the production of high-quality superalloy castings.The sessile-drop experiment was employed to systematically...Low reactivity and appropriate wettability between molten superalloys and ceramic materials are crucial for the production of high-quality superalloy castings.The sessile-drop experiment was employed to systematically investigate the interfacial reaction and wettability between the 4777DS1 superalloy and SiO_(2)-based ceramic core at various temperatures(1,480℃,1,500℃,1,520℃,and 1,550℃).The wetting behavior and interfacial reaction products at different temperatures were analyzed by scanning electron microscopy(SEM),energy dispersive spectroscopy(EDS),and X-ray diffraction(XRD).The interfacial reaction process and products were discussed,and the thermodynamic behavior and interfacial reaction mechanisms were elucidated.The results demonstrate that the wetting behavior and interfacial reaction between the 4777DS1 alloy and the ceramic core are significantly influenced by temperature.The wettability angle exhibits a trend of initial decrease followed by an increase with rising temperature,reaching a maximum of 139°at 1,480℃,indicating poorer wettability of the 4777DS1 superalloy with the ceramic core and better casting properties at this specific temperature.The most intense interfacial reaction occurs at 1,520℃,resulting in the formation of the main interfacial reaction products such as Al_(2)O_(3),SiO_(2),and HfO_(2).Additionally,some crystal-like products rich in Si and Hf distribute on the reaction layer.展开更多
With the legislative development,the organic and inorganic composition separation has become the primary requirement for sewer sediment disposal,however the relevant technology has been rarely reported and the driving...With the legislative development,the organic and inorganic composition separation has become the primary requirement for sewer sediment disposal,however the relevant technology has been rarely reported and the driving mechanism was still unclear.In this study,direct disintegration of biopolymers and indirect broken of connection point were investigated on the hydrolysis and component separation.Three typical sewer sediment treatment approaches,i.e.,alkaline,thermal and cation exchange treatments were proposed,which represented the hydrolysis-driving forces of chemical hydrolysis,physical hydrolysis and innovative cation bridging break-age.The results showed that the organic and inorganic separation rates of sewer sediment driven by alkaline,thermal and cation exchange treatments reached 21.26%,23.80%,and 19.56%-48.0%,respectively,compared to 4.43%in control.The secondary structure of proteins was disrupted,transitioning from𝛼α-helix to𝛽β-turn and random coil.Meanwhile,much biopolymers were released from solid to the liquid phase.From thermody-namic perspective,sewer sediment deposition was controlled by short-range interfacial interactions described by extended Derjaguin-Landau-Verwey-Overbeek theory.Additionally,the separation of organic and inorganic components was positively correlated with the thermodynamic parameters(Corr=0.87),highlighted the robust-ness of various driving forces.And the flocculation energy barriers were 2.40(alkaline),1.60 times(thermal),and 4.02–4.97 times(cation exchange)compared to control group.The findings revealed the contrition differ-ence of direct disintegration of gelatinous biopolymers and indirect breakage of composition connection sites in sediment composition separation,filling the critical gaps in understanding the specific mechanisms of sediment biopolymer disintegration and intermolecular connection breakage.展开更多
We read with great interest Deng et al.’s study 1 comparing sextant(6-core)and 12-core systematic biopsy in theMRI-targeted era,which valuably challenges the“more cores=higher accuracy”dogma by proposing a precisio...We read with great interest Deng et al.’s study 1 comparing sextant(6-core)and 12-core systematic biopsy in theMRI-targeted era,which valuably challenges the“more cores=higher accuracy”dogma by proposing a precision sampling strategy based on prostate cancer’s spatial distribution,aligning with personalized diagnosis trends.展开更多
This study compares the environmental sustainability of five alternatives for the remediation of marine sediments of one of the most polluted coastal sites in Europe(Bagnoli-Coroglio bay,Mediterranean Sea),using the L...This study compares the environmental sustainability of five alternatives for the remediation of marine sediments of one of the most polluted coastal sites in Europe(Bagnoli-Coroglio bay,Mediterranean Sea),using the Life Cycle Assessment(LCA)methodology.The treatments are either in-situ or exsitu,the latter requiring an initial dredging to transport the contaminated sediments to the management site.More in detail,four ex-situ remediation technologies based on landfilling,bioremediation,electrokinetic technique and soil washing were identified.These technologies are compared to an in-situ strategy currently under validation for enhancing bioremediation of the polluted sediments of the Bagnoli-Coroglio site.Our results indicate that the disposal in landfilling site is the worst option in most categories(e.g.,650 kg CO_(2) eq./t of treated sediment,considering the nearest landfilling site),followed by the bioremediation,mainly due to the high energy demand.Electrokinetic remediation,soil washing,and innovative in-situ technology represent the most sustainable options.In particular,the new in-situ technology appears to be the least impacting in all categories(e.g.,54 kg CO_(2) eq./t of treated sediment),although it is expected to require longer treatment time(estimated up to 12 months based on its potential efficiency).It can reduce the impact on climate change more than 12 times compared to the disposal and 7 times compared to bioremediation in addition to the possibility to avoid/reduce the dredging operations and the consequent dispersion of pollutants.The results open relevant perspectives towards more eco-sustainable and costly effective actions for the reclamation of contaminated marine sediments.展开更多
Benthic habitat mapping is an emerging discipline in the international marine field in recent years,providing an effective tool for marine spatial planning,marine ecological management,and decision-making applications...Benthic habitat mapping is an emerging discipline in the international marine field in recent years,providing an effective tool for marine spatial planning,marine ecological management,and decision-making applications.Seabed sediment classification is one of the main contents of seabed habitat mapping.In response to the impact of remote sensing imaging quality and the limitations of acoustic measurement range,where a single data source does not fully reflect the substrate type,we proposed a high-precision seabed habitat sediment classification method that integrates data from multiple sources.Based on WorldView-2 multi-spectral remote sensing image data and multibeam bathymetry data,constructed a random forests(RF)classifier with optimal feature selection.A seabed sediment classification experiment integrating optical remote sensing and acoustic remote sensing data was carried out in the shallow water area of Wuzhizhou Island,Hainan,South China.Different seabed sediment types,such as sand,seagrass,and coral reefs were effectively identified,with an overall classification accuracy of 92%.Experimental results show that RF matrix optimized by fusing multi-source remote sensing data for feature selection were better than the classification results of simple combinations of data sources,which improved the accuracy of seabed sediment classification.Therefore,the method proposed in this paper can be effectively applied to high-precision seabed sediment classification and habitat mapping around islands and reefs.展开更多
The vertical profile distribution characteristics of nitrogen in core sediments of Three Rivers Estuary in Poyang Lake were studied.The results showed that TN content in core sediments ranged from 480.0 to 1 900.0 μg...The vertical profile distribution characteristics of nitrogen in core sediments of Three Rivers Estuary in Poyang Lake were studied.The results showed that TN content in core sediments ranged from 480.0 to 1 900.0 μg/g with the change of depth,which was divided into three distribution types as follows:TN content decreases gradually with the increase of depth,TN content increases gradually with the increase of depth or higher content in the middle but lower content in two ends.NH4+-N content ranged from 8.7 ...展开更多
The occurrence percentage and abundance of General Aerobic Hetero- trophic Bacteria （GAB） were determined by using the method of MPN for 182 sub- samples from 10 sediment cores taken from the Canadian basin and the ...The occurrence percentage and abundance of General Aerobic Hetero- trophic Bacteria （GAB） were determined by using the method of MPN for 182 sub- samples from 10 sediment cores taken from the Canadian basin and the Chukchi Sea at two different culturing temperatures. The results showed that the general occurrence percentage of GAB was quite high, average abundanees of GAB at cultured temperatares of 4℃ and 25℃ were 4.46 ×10^7 and 5.47×10^7 cells·g^-1（wt）, respectively. The highest abundance of GAB occurred at 20 -22 cm section in the sediment. GAB abundances changed among the section of sediments, but there is a trend ： the a-bundances at the middle or lower sections were lower than those at upper section. Cultivation at 25℃ could improve the occurrence percentage and abundances of GAB, which suggests that the increasing of temperature may change the living circum-stances of GAB. The differences of GAB among the latitudes areas indicated that occurrence percentage and abundances of GAB in middle latitude areas were higher than those in the higher or lower latitude areas, and were more obvious at 4℃ than those at 25℃. The GAB abundances in sediment under the shallower water seemed to be low- er than those in sediments under the deeper water and this status was more obvious at 25℃ than that at 4℃.展开更多
Three sediment cores were collected in November 2003 from Dagu estuary to Qikou estuary. The main polluted heavy metals in the sediment of tidal zones for the Bohai Bay have been found by analyzing the relationship am...Three sediment cores were collected in November 2003 from Dagu estuary to Qikou estuary. The main polluted heavy metals in the sediment of tidal zones for the Bohai Bay have been found by analyzing the relationship among the contents of heavy metals, the contents of geochemical elements （Fe, AI and Mn） and the size of grain. The dominating contaminative elements in tidal sediments of Bohai Bay are Pb, Zn and Cd. Their contents are higher than the corresponding upper limit of environmental background values and they have very faint correlation with the corresponding contents of geochemical elements and the size of grain, indicating the anthropogenic enrichment. Especially, the preliminary study on the pollution sources and the history of heavy metals in the Dagu estuary has been done using the dated results. The contamination by Zn and Cd also started in the middle 1950s, while the contamination by Pb appeared in the early 1940s. The pollution by Zn and Cd mainly originate from sewage discharge, while the pollution by Pb has many sources, like atmosphere deposition and industrial discharRe.展开更多
Study on form characteristics of nitrogen in marine sediments is the primary method to research its biogeochemical cycling and nitrogen form characteristics in core sediments can reflect the process and results of ear...Study on form characteristics of nitrogen in marine sediments is the primary method to research its biogeochemical cycling and nitrogen form characteristics in core sediments can reflect the process and results of early diagenesis in a certain degree. In this paper, Sequential extraction process in natural grain size was used for studying the existent forms of nitrogen in five core sediments of the southern Bohai Sea for the first time. Nitrogen was divided into two parts - transferable and fixed based on whether it could be extracted by the reagent. Distributions and early diagenesis of transferable nitrogen forms in the southern Bohai Sea were researched integratedly. Results indicate that IEF - N and OSF-N are predominant forms in transferable part in the studied core sediments. Contents of different nitrogen forms vary differently with depth, and have different diagenesis process. Decomposition constant of organic nitrogen (ON) and OC are about 15.51 -× 10^(-3)a^(-3)and 4.79× 10^(-3)a^(-1) respectively, and the decomposition content of biogenic elements C, N, P, Si has the sequence N>P>CSi. OC/TN (simplified as C/N in the following) ratio is much lower than OC/ON, which indicates that sediment preserves plenty of inorganic nitrogen (IN) and/or fixed nitrogen, and the decrease of OC/ON ratio with depth is due to ON reservation in sediments. Generally, transferable nitrogen accounts for more proportion of TN in the surface layer than in the deep layer of core sediments, whereas, some stable forms of nitrogen can activate and become transferable under appropriate environment, which induces the proportion of transferable nitrogen in TN in the deep layer to be almost the same as that in the surface layer.展开更多
Receptor models are a useful tool for identifying sources of polycyclic aromatic hydrocarbons(PAHs)in multiple environmental media.In this study,three different receptor models(including the principal component analys...Receptor models are a useful tool for identifying sources of polycyclic aromatic hydrocarbons(PAHs)in multiple environmental media.In this study,three different receptor models(including the principal component analysis-multiple linear regression(PCA-MLR),positive matrix factorization(PMF),and Unmix models)were used to apportion the sources of 16 priority PAHs in a sediment core of Lake Dagze Co.TheΣPAHs(sum of all 16 measured PAHs)concentrations ranged from 51.89 to 132.82 ng/g with an average of 80.39 ng/g.TheΣPAHs were dominated by 2-3 ring PAHs,accounting for 80.12%on average,thereby indicating that they mainly originated from biomass and coal combustion and/or from long-range atmospheric transportation.The three models produced consistent source apportionment results.The greatest contributor toΣPAHs was biomass combustion,followed by coal combustion,vehicle emissions,and petrogenic sources.Moreover,the temporal variation of the common sources was well-correlated among models.The multi-method comparison and evaluation results showed that all three models were useful tools for source apportionment of PAHs,with the PMF model providing better results than the PCA-MLR and Unmix models.The temporal trends of factor contributions were verified by PAHs with different ring numbers.Significant correlations were found between the simulated concentrations of each source factor and the PAHs with different ring numbers(P<0.01),except for the petrogenic source identified by the Unmix model(P>0.05).This study can provide useful information for further investigation of source apportionment of PAHs in the sediment cores.展开更多
The concentration of zinc, chromium, cadmium, nickel, lead and copper was measured on both surface sediments and core sediments in the Shenzhen Bay. The average contents of all metals have exceeded the background valu...The concentration of zinc, chromium, cadmium, nickel, lead and copper was measured on both surface sediments and core sediments in the Shenzhen Bay. The average contents of all metals have exceeded the background values in the coastal zone of Guangdong Province. Cadmium is a heavy pollution matter which indicates a strong pollution level according to the ecological risk coefficient method. The ecological risk index of the whole area is 299 which belongs to middle and strong level. The area with strong pollution level is the near shore area closing to the inside of Shenzhen Bay, Shakou area is in the middle level while the weak pollution level occurs in Shenzhenhe Estuary according to ecological risk index. The four sediment cores can be divided into two parts based on lead-210 dating, sediments size analysis and economic development period in surrounding areas since 1950 with strong human intervention. The sediment size, deposition rate and human activities have positive relationship with the contents of heavy metals which directly impact the pollution level of heavy metals in sediments in Shenzhen Bay.展开更多
The vertical profiles of nonylphenol （NP） and nonylphenol ethoxylates （NPEOs） were investigated in a sediment core from the Beipaiming Channel, North China using high sensitive LC-MS and GC-MS metthods In this cor...The vertical profiles of nonylphenol （NP） and nonylphenol ethoxylates （NPEOs） were investigated in a sediment core from the Beipaiming Channel, North China using high sensitive LC-MS and GC-MS metthods In this core, relatively high concentrations of NP and NPEOs occurred in the surface sediment （≤40 cm）, with the maximum value of NP and NPEOs reaching 3539 and 12735 mg/g, respectively, whereas, no NP or NPEOs were detected in deeper sediments （〉40 cm）. The high concentrations of NP and NPEOs in the surface layers suggested recent inputs in this area. NPEOs with short ethoxy chains （NPnEO, n=0-3） were dominant in the NPEO mixture with percentages from 54% to 78%, which were similar to the distribution of homolog NPEO in effluents from nearby sewage treatment plants （STPs）, indicating that the channel received the effluents from these STPs. The sewage treatment ratio was quite similar to that found in North America before the 1980s. Finally, the concentrations of NP and NPEOs were related to the total organic carbon （TOC） （p〈0.001）, suggesting that TOC was an important factor for vertical distribution of NPEOs and NP from the Beipaiming Channel.展开更多
The cored sediments sampled by R/V Marion Dufrense in the active margin off southwestern Taiwan on the east side of the Manila Trench are mostly muds consisting mainly of quartz, feldspar, illite, chlorite ＋ kaolinit...The cored sediments sampled by R/V Marion Dufrense in the active margin off southwestern Taiwan on the east side of the Manila Trench are mostly muds consisting mainly of quartz, feldspar, illite, chlorite ＋ kaolinite with a trace amount of montmorillonite. The cored sediments have higher Fe, Ti, Cr, Cs, Li, Ni, and V but lower Ca, Na, Mn, Hf, Nb, Sr, Ta, U and Zr contents when compared with the upper continental crust（UCC, Taylor and McLennan, 1985）. The Eu/Eu＊ ratios of the sediments averaging 0.69 indicate that the recycling effect on the Eu anomaly may be minor and the contribution of mafic source rock was unimportant, which can also be depicted in the La-Th-Sc plot（Cullers, 1994） showing a ＂mixed origin＂ close to the felsic end member. The chemistry of the cored sediment can be explained by a mixing model designed by Ho and Chen（1996） with four end members i.e., greywacke, shale, quartzite and limestone, which are widely distributed in the Cenozoic formations of southern Taiwan with greywacke as the dominant contributor followed by shale.展开更多
基金supported by the Doctoral Research Initiation Fund Project of Hebei Normal University(No.L2025B19)PhD Fellowship of the State Key Laboratory of Marine Environmental Science at Xiamen University.
文摘Protoporphyrin Ⅸ(PPⅨ), a basic porphyrin system found in nature, all “porphyrin-type”tetrapyrroles with a biological function are biosynthetically derived thereof. PPⅨ is a metalloprosthetic group of numerous proteins involved in diverse metabolic and respiratory processes across all domains of life, and is thus considered essential for respiring organisms. Determining the biotic and abiotic factors that influence marine microbial growth and community structure is critical for understanding global biogeochemical cycles. Here,we present vertical profiles of intracellular PPⅨ and four derivative products(Chlorophylla/b and Pheophytin-a/b) from two coastal sediment cores, alongside ancillary geochemical and 16S rRNA microbial community data. Our findings indicated that PPⅨ is present in the natural sediment environment and displays a decreasing trend with depth, revealing a significant positive correlation with both organic matter and microbial abundance. Cooccurrence networks revealed that the environmental distribution of PPⅨ was positively correlated with the microbial porphyrin producer(high genetic completeness), but negatively correlated with auxotrophs(absence or low genetic completeness). It emphasized the critical role of PPⅨ as a biological molecule involved in key physiological processes. These results suggest that PPⅨ is a prominent component of the shared extracellular metabolite pool, especially in anoxic marine sediments where it exists at physiologically relevant concentrations for microbial metabolism. This study highlighted the significance of PPⅨ in microbial ecology and its potential impact on biogeochemical cycles in marine sedimentary environments.
基金financially supported by the National Natural Science Foundation for Distinguished Young Scholars of China(42125702)the National Natural Science Foundation for International Cooperation and Exchange(W2412050)+4 种基金the National Science and Technology Major Project of Sichuan Province(2024ZDZX0020)the New Cornerstone Science Foundation through the XPLORER PRIZE(XPLORER-2022-1012)the Activity Prediction and Risk Identification of LargeScale Plateau Debris Flows(XZ202401ZY0029)the Formation Mechanisms and Monitoring-Warning Methods for Moraine Soil Debris Flows in the Eastern Himalayan Syntaxis Region(XZ202401ZR0073)funding from the Czech Science Foundation(22-13190S)。
文摘Soft-sediment deformation structures(SSDS)in water-saturated,unconsolidated sediments are the product of various causes and provide a valuable record of environmental and geological perturbations.We report a record of SSDS preserved in a~166 m-long drill core(DX-2)extracted from the Late Pleistocene Diexi Palaeolake,eastern Tibetan Plateau.Two factors make this an outstanding site for studying SSDS:(1)it is among the most seismically active regions on Earth,and(2)it has experienced extremely fast sedimentation rates(~15 mm/yr)thanks to the prodigious sediment supply from seismically perturbed hillslopes and rivers upstream.We describe and interpret 13 SSDS types within the DX-2 based on detailed sedimentological,morphological,and lithological analysis.We consider the genesis of the abundant SSDS observed in the DX-2 core with several possibilities:mass movement,rock avalanche-driven tsunamis,rapid sedimentation,and seismic shaking as the most probable triggering mechanisms.We suggest high-intensity earthquakes of VI(Modified Mercalli Intensity)or greater as drivers of SSDS in the DX-2.Based on our observations,we propose a conceptual model that attempts to explain the transition from ductile to brittle SSDS behaviour with progressive accumulation and consolidation of the sediment pile.This paper highlights the value of SSDS analysis in palaeo-earthquake identification,aiming to improve the applicability of SSDS as a palaeo-earthquake marker in alpine and canyon areas.
基金supported by the Hunan Provincial Natural Science Foundation of China(Nos.2023JJ40518 and 2023JJ30490)the Scientific Research Foundation of Hunan Provincial Education Department(Nos.21B0511 and 22A0384)the Research Funding Project of Jishou University for talent introduction.
文摘Fluoroquinolones(FQs)have the propensity to accumulate in sediments once introduction into aquatic envi-ronments,thereby posing potential threats to benthic organisms,yet the ecotoxicity of sediment-associated FQs remains unclear.In this study,the toxicokinetics and responses of multiple biomarkers in Bellamya aeruginosa,exposed to the three commonly used FQs(norfloxacin,NOR;ciprofloxacin,CIP;levofloxacin,LEVO)at envi-ronmentally relevant concentrations were investigated under sediment exposure scenario.The results revealed that FQs were effectively ingested by B.aeruginosa from sediments,CIP showing the highest bioaccumulation(180.59μg/kg),followed by NOR(74.49μg/kg)and LEVO(36.02μg/kg).CIP exhibiting a highest uptake rate constant(Ks)(4.64 g/(g·day))and the lowest elimination rate constant(K_(e))(0.05 g/(g·day)).The descending order of biological half-life is as follows:CIP(13.62 days),LEVO(8.14 days),and NOR(6.83 days).NOR induced the activity of superoxide dismutase,catalase,and glutathione-S-transferase while CIP and LEVO depressed their activities and increased malondialdehyde content,indicating a more pronounced oxidative damage to B.aerug-inosa caused by CIP and LEVO than NOR.Furthermore,all three FQs were found to induce DNA damage and elevate acetylcholinesterase activity,suggesting distinct genotoxic and neurotoxic effects.Interestingly,despite its low bioaccumulation potential,LEVO exhibited high toxicity towards B.aeruginosa.These findings enhance our understanding of the ecotoxicity of FQs in sediments,providing further evidence of their potential ecological risks.
基金financially supported by the National Natural Science Foundation of China(grant no.42120104005)Guizhou Provincial 2021 Science and Technology Subsidies(grant no.GZ2021SIG)+1 种基金Guizhou Provincial Science and Technology Projects(grant nos.ZK[2024]087GCC[2023]060)。
文摘The Martian core mainly contains iron,nickel and some light elements.However,controversies remain about the structure and chemical composition of the Martian core due to a lack of samples and marsquake data.Recently,the InSight lander collected long-term marsquake data,which improved the Martian interior structure model.B ased on the preliminary analysis of marsquake data,Mars has a molten liquid core with a radius of around 1700 km.As the Martian core has a smaller density and lower temperature than pure iron at corresponding pressure and temperature conditions,some light elements are introduced to reduce the density and liquidus temperature.With various methods for seismic analysis,in-situ high-pressure and high-temperature experiments,and first-principal calculations,the Martian core composition and evolution models have been updated in the past few years.Here,we review those studies on the light elements in the Martian core from four aspects including(1)high-temperature and high-pressure experiments,(2)marsquake data,(3)mineral physics model with molecular dynamics simulations and(4)cosmochemistry investigation.We discussed the effect of different light elements on the Martian core s density,sound velocity and liquidus temperature.Moreover,the review examines the varieties,abundances and forms of light elements in the Martian core.
文摘Soil erosion is a fundamental physical process driving land degradation across various spatial and temporal scales.The Soil and Water Assessment Tool(SWAT)model is a robust tool for predicting soil erosion and evaluating water and soil quality within watersheds.The latest version,SWAT+,introduces advanced encoding capabilities and improved performance,making it better suited for addressing complex watershed modeling challenges.This study implemented the SWAT+model to quantify soil erosion rates within the Chehelchay watershed in northern Iran.The foundational dataset comprises a 30-meter resolution Digital Elevation Model(DEM),land use classification,soil,and weather data.Model performance was evaluated using Nash-Sutcliffe Efficiency(NSE),coefficient of determination(R^(2)),root mean square error(RMSE),and percent bias(PBIAS).The SWAT+simulation revealed substantial spatial variation in erosion patterns across the watershed,with annual sediment yields in critical HRUs,reflecting diverse erosion intensities driven by variations in land use,soil characteristics,and slope.Among the Hydrological Response Units(HRUs),50 critical units,representing approximately 9%of the total watershed area,generate sediment yields exceeding 5 tons per hectare per year.The most severe erosion occurs predominantly in the central zone of the watershed.Downstream regions exhibit minimal soil loss due to gentle topography while upstream areas maintain soil stability through protective forest cover,resulting in negligible erosion rates.Best Management Practices(BMPs)were designed to safeguard water and soil resources at a watershed level.The study evaluated three strategic conservation interventions:alfalfa cultivation,agroforestry implementation,and garden development.When applied in combination,these measures achieved approximately 30%reduction in sediment yield at the HRU level.This integrated approach demonstrates the potential of combining multiple land management strategies to combat erosion effectively.
基金supported by the fund of State Key Laboratory of Clean and Efficient Turbomachinery Power Equipment(No.DEC8300CG202210353EE280297)the China Postdoctoral Science Foundation(No.2021M692555)+1 种基金the Shaanxi Province Qinchuangyuan‘Scientists+Engineers’Team Building Project(No.2023KXJ-266)the Fundamental Research Funds for the Central Universities(No.xzy012023145)。
文摘Low reactivity and appropriate wettability between molten superalloys and ceramic materials are crucial for the production of high-quality superalloy castings.The sessile-drop experiment was employed to systematically investigate the interfacial reaction and wettability between the 4777DS1 superalloy and SiO_(2)-based ceramic core at various temperatures(1,480℃,1,500℃,1,520℃,and 1,550℃).The wetting behavior and interfacial reaction products at different temperatures were analyzed by scanning electron microscopy(SEM),energy dispersive spectroscopy(EDS),and X-ray diffraction(XRD).The interfacial reaction process and products were discussed,and the thermodynamic behavior and interfacial reaction mechanisms were elucidated.The results demonstrate that the wetting behavior and interfacial reaction between the 4777DS1 alloy and the ceramic core are significantly influenced by temperature.The wettability angle exhibits a trend of initial decrease followed by an increase with rising temperature,reaching a maximum of 139°at 1,480℃,indicating poorer wettability of the 4777DS1 superalloy with the ceramic core and better casting properties at this specific temperature.The most intense interfacial reaction occurs at 1,520℃,resulting in the formation of the main interfacial reaction products such as Al_(2)O_(3),SiO_(2),and HfO_(2).Additionally,some crystal-like products rich in Si and Hf distribute on the reaction layer.
基金supported by Shaanxi Key Research and Development Program(No.2024SF-YBXM-546)the National Natural Science Foundation of China(No.52470161)the State Key Laboratory of Pollution Control and Resource Reuse Foundation(No.PCRRF21007).
文摘With the legislative development,the organic and inorganic composition separation has become the primary requirement for sewer sediment disposal,however the relevant technology has been rarely reported and the driving mechanism was still unclear.In this study,direct disintegration of biopolymers and indirect broken of connection point were investigated on the hydrolysis and component separation.Three typical sewer sediment treatment approaches,i.e.,alkaline,thermal and cation exchange treatments were proposed,which represented the hydrolysis-driving forces of chemical hydrolysis,physical hydrolysis and innovative cation bridging break-age.The results showed that the organic and inorganic separation rates of sewer sediment driven by alkaline,thermal and cation exchange treatments reached 21.26%,23.80%,and 19.56%-48.0%,respectively,compared to 4.43%in control.The secondary structure of proteins was disrupted,transitioning from𝛼α-helix to𝛽β-turn and random coil.Meanwhile,much biopolymers were released from solid to the liquid phase.From thermody-namic perspective,sewer sediment deposition was controlled by short-range interfacial interactions described by extended Derjaguin-Landau-Verwey-Overbeek theory.Additionally,the separation of organic and inorganic components was positively correlated with the thermodynamic parameters(Corr=0.87),highlighted the robust-ness of various driving forces.And the flocculation energy barriers were 2.40(alkaline),1.60 times(thermal),and 4.02–4.97 times(cation exchange)compared to control group.The findings revealed the contrition differ-ence of direct disintegration of gelatinous biopolymers and indirect breakage of composition connection sites in sediment composition separation,filling the critical gaps in understanding the specific mechanisms of sediment biopolymer disintegration and intermolecular connection breakage.
文摘We read with great interest Deng et al.’s study 1 comparing sextant(6-core)and 12-core systematic biopsy in theMRI-targeted era,which valuably challenges the“more cores=higher accuracy”dogma by proposing a precision sampling strategy based on prostate cancer’s spatial distribution,aligning with personalized diagnosis trends.
基金support in the literature analysis.This study has been carried out in the framework of the project funded by EU entitled“Bioremediation of contaminated sediments in coastal areas of exindustrial sites-LIFE SEDREMED”(No.LIFE20 ENV/IT/000572).
文摘This study compares the environmental sustainability of five alternatives for the remediation of marine sediments of one of the most polluted coastal sites in Europe(Bagnoli-Coroglio bay,Mediterranean Sea),using the Life Cycle Assessment(LCA)methodology.The treatments are either in-situ or exsitu,the latter requiring an initial dredging to transport the contaminated sediments to the management site.More in detail,four ex-situ remediation technologies based on landfilling,bioremediation,electrokinetic technique and soil washing were identified.These technologies are compared to an in-situ strategy currently under validation for enhancing bioremediation of the polluted sediments of the Bagnoli-Coroglio site.Our results indicate that the disposal in landfilling site is the worst option in most categories(e.g.,650 kg CO_(2) eq./t of treated sediment,considering the nearest landfilling site),followed by the bioremediation,mainly due to the high energy demand.Electrokinetic remediation,soil washing,and innovative in-situ technology represent the most sustainable options.In particular,the new in-situ technology appears to be the least impacting in all categories(e.g.,54 kg CO_(2) eq./t of treated sediment),although it is expected to require longer treatment time(estimated up to 12 months based on its potential efficiency).It can reduce the impact on climate change more than 12 times compared to the disposal and 7 times compared to bioremediation in addition to the possibility to avoid/reduce the dredging operations and the consequent dispersion of pollutants.The results open relevant perspectives towards more eco-sustainable and costly effective actions for the reclamation of contaminated marine sediments.
基金Supported by the National Natural Science Foundation of China(Nos.42376185,41876111)the Shandong Provincial Natural Science Foundation(No.ZR2023MD073)。
文摘Benthic habitat mapping is an emerging discipline in the international marine field in recent years,providing an effective tool for marine spatial planning,marine ecological management,and decision-making applications.Seabed sediment classification is one of the main contents of seabed habitat mapping.In response to the impact of remote sensing imaging quality and the limitations of acoustic measurement range,where a single data source does not fully reflect the substrate type,we proposed a high-precision seabed habitat sediment classification method that integrates data from multiple sources.Based on WorldView-2 multi-spectral remote sensing image data and multibeam bathymetry data,constructed a random forests(RF)classifier with optimal feature selection.A seabed sediment classification experiment integrating optical remote sensing and acoustic remote sensing data was carried out in the shallow water area of Wuzhizhou Island,Hainan,South China.Different seabed sediment types,such as sand,seagrass,and coral reefs were effectively identified,with an overall classification accuracy of 92%.Experimental results show that RF matrix optimized by fusing multi-source remote sensing data for feature selection were better than the classification results of simple combinations of data sources,which improved the accuracy of seabed sediment classification.Therefore,the method proposed in this paper can be effectively applied to high-precision seabed sediment classification and habitat mapping around islands and reefs.
基金Supported by Science and Technology Project from Jiangxi Provincial Department of Education(GJJ09430)International Scienceand Technology Cooperation Project(2006DFB91920)NationalKey Water Project(2008ZX07526-008)~~
文摘The vertical profile distribution characteristics of nitrogen in core sediments of Three Rivers Estuary in Poyang Lake were studied.The results showed that TN content in core sediments ranged from 480.0 to 1 900.0 μg/g with the change of depth,which was divided into three distribution types as follows:TN content decreases gradually with the increase of depth,TN content increases gradually with the increase of depth or higher content in the middle but lower content in two ends.NH4+-N content ranged from 8.7 ...
基金sponsored by the national ministry of finance.And as a part of the second Arctic research expedition(CHINARE-2003) which is organized by Polar Expedition Office of State Oceanic Administration of China,we would like to thank the crew on RV Xuelong for their support and assistance.Research funds are supplied by National Natural Science Foundation of China(No.40576060,40376017 and 40176017).
文摘The occurrence percentage and abundance of General Aerobic Hetero- trophic Bacteria （GAB） were determined by using the method of MPN for 182 sub- samples from 10 sediment cores taken from the Canadian basin and the Chukchi Sea at two different culturing temperatures. The results showed that the general occurrence percentage of GAB was quite high, average abundanees of GAB at cultured temperatares of 4℃ and 25℃ were 4.46 ×10^7 and 5.47×10^7 cells·g^-1（wt）, respectively. The highest abundance of GAB occurred at 20 -22 cm section in the sediment. GAB abundances changed among the section of sediments, but there is a trend ： the a-bundances at the middle or lower sections were lower than those at upper section. Cultivation at 25℃ could improve the occurrence percentage and abundances of GAB, which suggests that the increasing of temperature may change the living circum-stances of GAB. The differences of GAB among the latitudes areas indicated that occurrence percentage and abundances of GAB in middle latitude areas were higher than those in the higher or lower latitude areas, and were more obvious at 4℃ than those at 25℃. The GAB abundances in sediment under the shallower water seemed to be low- er than those in sediments under the deeper water and this status was more obvious at 25℃ than that at 4℃.
基金The National Basic Research Program (973) of China (No. 2002CB412409) and the Hi-Tech Research and Development Program(863) of China(No. 2002AA648010)
文摘Three sediment cores were collected in November 2003 from Dagu estuary to Qikou estuary. The main polluted heavy metals in the sediment of tidal zones for the Bohai Bay have been found by analyzing the relationship among the contents of heavy metals, the contents of geochemical elements （Fe, AI and Mn） and the size of grain. The dominating contaminative elements in tidal sediments of Bohai Bay are Pb, Zn and Cd. Their contents are higher than the corresponding upper limit of environmental background values and they have very faint correlation with the corresponding contents of geochemical elements and the size of grain, indicating the anthropogenic enrichment. Especially, the preliminary study on the pollution sources and the history of heavy metals in the Dagu estuary has been done using the dated results. The contamination by Zn and Cd also started in the middle 1950s, while the contamination by Pb appeared in the early 1940s. The pollution by Zn and Cd mainly originate from sewage discharge, while the pollution by Pb has many sources, like atmosphere deposition and industrial discharRe.
基金This study was supported by the National Science Foundation for Outstanding Young Scientists of China under contract No. 49925614 the Knowledge Innovation Program of the Chinese Academy of Sciences under contract No. KZCX1 - SW -01-08.
文摘Study on form characteristics of nitrogen in marine sediments is the primary method to research its biogeochemical cycling and nitrogen form characteristics in core sediments can reflect the process and results of early diagenesis in a certain degree. In this paper, Sequential extraction process in natural grain size was used for studying the existent forms of nitrogen in five core sediments of the southern Bohai Sea for the first time. Nitrogen was divided into two parts - transferable and fixed based on whether it could be extracted by the reagent. Distributions and early diagenesis of transferable nitrogen forms in the southern Bohai Sea were researched integratedly. Results indicate that IEF - N and OSF-N are predominant forms in transferable part in the studied core sediments. Contents of different nitrogen forms vary differently with depth, and have different diagenesis process. Decomposition constant of organic nitrogen (ON) and OC are about 15.51 -× 10^(-3)a^(-3)and 4.79× 10^(-3)a^(-1) respectively, and the decomposition content of biogenic elements C, N, P, Si has the sequence N>P>CSi. OC/TN (simplified as C/N in the following) ratio is much lower than OC/ON, which indicates that sediment preserves plenty of inorganic nitrogen (IN) and/or fixed nitrogen, and the decrease of OC/ON ratio with depth is due to ON reservation in sediments. Generally, transferable nitrogen accounts for more proportion of TN in the surface layer than in the deep layer of core sediments, whereas, some stable forms of nitrogen can activate and become transferable under appropriate environment, which induces the proportion of transferable nitrogen in TN in the deep layer to be almost the same as that in the surface layer.
基金supported by the National Natural Science Foundation of China(Nos.41773097,41971286)the Postgraduate Research Innovation project of Jiangsu Province(No.KYCX21_1330)。
文摘Receptor models are a useful tool for identifying sources of polycyclic aromatic hydrocarbons(PAHs)in multiple environmental media.In this study,three different receptor models(including the principal component analysis-multiple linear regression(PCA-MLR),positive matrix factorization(PMF),and Unmix models)were used to apportion the sources of 16 priority PAHs in a sediment core of Lake Dagze Co.TheΣPAHs(sum of all 16 measured PAHs)concentrations ranged from 51.89 to 132.82 ng/g with an average of 80.39 ng/g.TheΣPAHs were dominated by 2-3 ring PAHs,accounting for 80.12%on average,thereby indicating that they mainly originated from biomass and coal combustion and/or from long-range atmospheric transportation.The three models produced consistent source apportionment results.The greatest contributor toΣPAHs was biomass combustion,followed by coal combustion,vehicle emissions,and petrogenic sources.Moreover,the temporal variation of the common sources was well-correlated among models.The multi-method comparison and evaluation results showed that all three models were useful tools for source apportionment of PAHs,with the PMF model providing better results than the PCA-MLR and Unmix models.The temporal trends of factor contributions were verified by PAHs with different ring numbers.Significant correlations were found between the simulated concentrations of each source factor and the PAHs with different ring numbers(P<0.01),except for the petrogenic source identified by the Unmix model(P>0.05).This study can provide useful information for further investigation of source apportionment of PAHs in the sediment cores.
基金The National Natural Science Foundation of China under contract No.40606025the Program for New Century Excellent Talents in University,Ministry of Education under contract No.NCET-06-0446the "908" Program of State Oceanic Administration under contract No.908-ZC-II-03
文摘The concentration of zinc, chromium, cadmium, nickel, lead and copper was measured on both surface sediments and core sediments in the Shenzhen Bay. The average contents of all metals have exceeded the background values in the coastal zone of Guangdong Province. Cadmium is a heavy pollution matter which indicates a strong pollution level according to the ecological risk coefficient method. The ecological risk index of the whole area is 299 which belongs to middle and strong level. The area with strong pollution level is the near shore area closing to the inside of Shenzhen Bay, Shakou area is in the middle level while the weak pollution level occurs in Shenzhenhe Estuary according to ecological risk index. The four sediment cores can be divided into two parts based on lead-210 dating, sediments size analysis and economic development period in surrounding areas since 1950 with strong human intervention. The sediment size, deposition rate and human activities have positive relationship with the contents of heavy metals which directly impact the pollution level of heavy metals in sediments in Shenzhen Bay.
基金Project supported by the National Basic Research Program of China (No. 2007CB407304, 2003CB415004)the National Natural Science Foundation of China (No. 20307010)
文摘The vertical profiles of nonylphenol （NP） and nonylphenol ethoxylates （NPEOs） were investigated in a sediment core from the Beipaiming Channel, North China using high sensitive LC-MS and GC-MS metthods In this core, relatively high concentrations of NP and NPEOs occurred in the surface sediment （≤40 cm）, with the maximum value of NP and NPEOs reaching 3539 and 12735 mg/g, respectively, whereas, no NP or NPEOs were detected in deeper sediments （〉40 cm）. The high concentrations of NP and NPEOs in the surface layers suggested recent inputs in this area. NPEOs with short ethoxy chains （NPnEO, n=0-3） were dominant in the NPEO mixture with percentages from 54% to 78%, which were similar to the distribution of homolog NPEO in effluents from nearby sewage treatment plants （STPs）, indicating that the channel received the effluents from these STPs. The sewage treatment ratio was quite similar to that found in North America before the 1980s. Finally, the concentrations of NP and NPEOs were related to the total organic carbon （TOC） （p〈0.001）, suggesting that TOC was an important factor for vertical distribution of NPEOs and NP from the Beipaiming Channel.
基金supported by the Central Geological Survey of the Ministry of Economic Affairs under grant 5226902000-05-94-02, No. NRF-2012R1A1A2005044 and 5226902000-95-02
文摘The cored sediments sampled by R/V Marion Dufrense in the active margin off southwestern Taiwan on the east side of the Manila Trench are mostly muds consisting mainly of quartz, feldspar, illite, chlorite ＋ kaolinite with a trace amount of montmorillonite. The cored sediments have higher Fe, Ti, Cr, Cs, Li, Ni, and V but lower Ca, Na, Mn, Hf, Nb, Sr, Ta, U and Zr contents when compared with the upper continental crust（UCC, Taylor and McLennan, 1985）. The Eu/Eu＊ ratios of the sediments averaging 0.69 indicate that the recycling effect on the Eu anomaly may be minor and the contribution of mafic source rock was unimportant, which can also be depicted in the La-Th-Sc plot（Cullers, 1994） showing a ＂mixed origin＂ close to the felsic end member. The chemistry of the cored sediment can be explained by a mixing model designed by Ho and Chen（1996） with four end members i.e., greywacke, shale, quartzite and limestone, which are widely distributed in the Cenozoic formations of southern Taiwan with greywacke as the dominant contributor followed by shale.
