Based on the nonlinear saturable absorption properties(NSAPs)of a two-dimensional(2D)material of antimony selenide(Sb_(2)Se_(3)),a Q-switched erbium-doped fiber(EDF)laser is systematically demonstrated.The Sb_(2)Se_(3...Based on the nonlinear saturable absorption properties(NSAPs)of a two-dimensional(2D)material of antimony selenide(Sb_(2)Se_(3)),a Q-switched erbium-doped fiber(EDF)laser is systematically demonstrated.The Sb_(2)Se_(3)nano sheets are prepared by liquid-phase exfoliation(LPE)method.After the sandwich-structured Sb_(2)Se_(3)saturable absorber(SA)is fabricated,the NSAPs are characterized and the modulation depth,the saturation intensity and the unsaturated loss are determined to be 25.2%,2.02 MW/cm^(2),and 3.29%,respectively.When the as-prepared Sb_(2)Se_(3)-SA is integrated into the ring cavity,the laser operates at a stable Q-switching regime in the pump power range of 100—400 mW.The laser oscillates at the central wavelength of 1558.48 nm with a 3 dB bandwidth of 2.32 nm.Take the advantages of the Sb_(2)Se_(3)-SA,the pulse duration can be compressed from 40.49 kHz to 128.12 kHz.At the pump power of 400 mW,the Q-switching laser gives the narrowest pulse duration the highest average output power,the largest pulse energy,and the signal-to-noise ratio(SNR)of 0.93μs,2.16 mW,16.89 nJ,and 53 dB,respectively.Our new attempt on Sb_(2)Se_(3)-based Q-switched EDF laser,combining the existing mode-locking achievements,proves that Sb_(2)Se_(3)is a powerful candidate for pulse compression due to the characteristics of high modulation depth and high stability.展开更多
Selenium(Se)deficiency is a global health problem affecting more than 500 million people;crop biofortification is a sustainable strategy for its mitigation.This study investigated the effect of the application of sele...Selenium(Se)deficiency is a global health problem affecting more than 500 million people;crop biofortification is a sustainable strategy for its mitigation.This study investigated the effect of the application of selenate nanoparticles(SeO_(4)^(2−))and the combination of selenate(SeO_(4)^(2−))and chitosan(CS)(forming a SeO_(4)^(2−)-CS complex)on the antioxidant profile,growth,biomass,bioactive compounds,enzymes,and Se accumulation of wheat(Triticum spp.)sprouts.Fourteen treatments were applied using a factorial design combining seven concentrations and two formulations:SeO_(4)^(2−)and SeO_(4)^(2−)-CS.It was identified that chitosan increased Se uptake efficiency by 30%versus conventional selenate.The optimal dose for biomass was 0.15 mg L^(−1) of SeO_(4)^(2−)-CS(+40%vs.control),while 0.25 mg L^(−1) maximized bioactive compounds(phenolics(25%)and flavonoids(21%))as well as antioxidant capacity(26%)and enzymatic activity(SOD:37%;POD:41%).In addition,CS reduced Se phytotoxicity at doses≥1.50 mg L^(−1),evidencing its dual role as a delivery vehicle and cell protector.These findings demonstrate that the SeO_(4)^(2−)-CS hybrid system is a technologically viable and efficient alternative to traditional selenate for the production of biofortified sprouts.This strategy shows high potential for scaling up in the functional food industry and for application in agricultural regions with selenium-deficient soils.展开更多
芝麻是八大类食物过敏原之一,快速准确识别芝麻过敏原对预防其过敏有重要意义。核酸适配体可以高效识别靶标过敏原,在过敏原检测中有良好的应用前景。为了获得芝麻主要过敏原Ses i 2的特异性核酸适体,本研究以Ses i 2为靶标,通过磁珠筛...芝麻是八大类食物过敏原之一,快速准确识别芝麻过敏原对预防其过敏有重要意义。核酸适配体可以高效识别靶标过敏原,在过敏原检测中有良好的应用前景。为了获得芝麻主要过敏原Ses i 2的特异性核酸适体,本研究以Ses i 2为靶标,通过磁珠筛选法(磁珠-SELEX)开展10轮筛选,经由高通量测序获得6条候补序列(S1~S6),并进行家族性、同源性分析及二级结构预测。结果表明,6条候选核酸适体的重复率可达46.38%,其自由能在-9.02到-2.47 kcal·moL^(-1)之间,根据自由能能量稳定原则,S1和S5吉布斯自由能最低最稳定,分别为-6.70和-9.02 kcal·moL^(-1)。利用ELISA试验进行亲和力测试,结果表明核酸适体S1和S2的亲和能力较强,S1:KD=67.02 nmol·L^(-1),R2=0.925 8,S2:KD=97.65 nmol·L^(-1),R2=0.795 1。核酸适体S1与过敏原Ses i 2的结合力和其他过敏原蛋白相比有显著差异,可视为具有特异性。本研究最终获得一条兼具良好亲和力和特异性的核酸适体S1,为芝麻过敏原快速检测提供了技术支撑。展开更多
The two-dimensional van der Waals layered semiconductor In_(2)Se_(3) has emerged as a promising candidate for non-volatile ferroelectric memory,optoelectronic devices,and polymorphic phase engineering.Polymorphic In_(...The two-dimensional van der Waals layered semiconductor In_(2)Se_(3) has emerged as a promising candidate for non-volatile ferroelectric memory,optoelectronic devices,and polymorphic phase engineering.Polymorphic In_(2)Se_(3) typically stabilizes in three distinct phases:α-,β′-,and β^(*)-In_(2)Se_(3),each dominant within specific temperature ranges.Although the crystal structures and ferroelectric properties of these phases have been widely studied,the unambiguous assignment of their in-plane and out-of-plane ferroelectric behaviors,as well as the mechanisms governing their phase transitions,remains a subject of active debate.In this study,we investigate the evolution of atomic and electronic structures in molecular beam epitaxy-grown ultrathin In_(2)Se_(3) films through correlated microstructural and macroscopic physical property analysis.By employing scanning tunneling microscopy/spectroscopy,temperature-dependent Raman spectroscopy,and piezoresponse force microscopy,we demonstrate a reversible temperature-induced phase transition between the in-plane ferroelectric β^(*)and antiferroelectric β′phases.Furthermore,we confirm robust out-of-plane ferroelectric polarization in the as-grown films and achieve an electric-field-driven transition from the β^(*)to β′phase.Our findings not only advance the fundamental understanding of phase transitions and polarization evolution in two-dimensional semiconductors but also open new avenues for the design of tunable,non-volatile ferroelectric memory devices.展开更多
基金supported by the National Natural Science Foundation of China(No.11304184)the Shandong University of Technology and Zibo City Integration Development Project(No.2019ZBXC120)。
文摘Based on the nonlinear saturable absorption properties(NSAPs)of a two-dimensional(2D)material of antimony selenide(Sb_(2)Se_(3)),a Q-switched erbium-doped fiber(EDF)laser is systematically demonstrated.The Sb_(2)Se_(3)nano sheets are prepared by liquid-phase exfoliation(LPE)method.After the sandwich-structured Sb_(2)Se_(3)saturable absorber(SA)is fabricated,the NSAPs are characterized and the modulation depth,the saturation intensity and the unsaturated loss are determined to be 25.2%,2.02 MW/cm^(2),and 3.29%,respectively.When the as-prepared Sb_(2)Se_(3)-SA is integrated into the ring cavity,the laser operates at a stable Q-switching regime in the pump power range of 100—400 mW.The laser oscillates at the central wavelength of 1558.48 nm with a 3 dB bandwidth of 2.32 nm.Take the advantages of the Sb_(2)Se_(3)-SA,the pulse duration can be compressed from 40.49 kHz to 128.12 kHz.At the pump power of 400 mW,the Q-switching laser gives the narrowest pulse duration the highest average output power,the largest pulse energy,and the signal-to-noise ratio(SNR)of 0.93μs,2.16 mW,16.89 nJ,and 53 dB,respectively.Our new attempt on Sb_(2)Se_(3)-based Q-switched EDF laser,combining the existing mode-locking achievements,proves that Sb_(2)Se_(3)is a powerful candidate for pulse compression due to the characteristics of high modulation depth and high stability.
文摘Selenium(Se)deficiency is a global health problem affecting more than 500 million people;crop biofortification is a sustainable strategy for its mitigation.This study investigated the effect of the application of selenate nanoparticles(SeO_(4)^(2−))and the combination of selenate(SeO_(4)^(2−))and chitosan(CS)(forming a SeO_(4)^(2−)-CS complex)on the antioxidant profile,growth,biomass,bioactive compounds,enzymes,and Se accumulation of wheat(Triticum spp.)sprouts.Fourteen treatments were applied using a factorial design combining seven concentrations and two formulations:SeO_(4)^(2−)and SeO_(4)^(2−)-CS.It was identified that chitosan increased Se uptake efficiency by 30%versus conventional selenate.The optimal dose for biomass was 0.15 mg L^(−1) of SeO_(4)^(2−)-CS(+40%vs.control),while 0.25 mg L^(−1) maximized bioactive compounds(phenolics(25%)and flavonoids(21%))as well as antioxidant capacity(26%)and enzymatic activity(SOD:37%;POD:41%).In addition,CS reduced Se phytotoxicity at doses≥1.50 mg L^(−1),evidencing its dual role as a delivery vehicle and cell protector.These findings demonstrate that the SeO_(4)^(2−)-CS hybrid system is a technologically viable and efficient alternative to traditional selenate for the production of biofortified sprouts.This strategy shows high potential for scaling up in the functional food industry and for application in agricultural regions with selenium-deficient soils.
文摘芝麻是八大类食物过敏原之一,快速准确识别芝麻过敏原对预防其过敏有重要意义。核酸适配体可以高效识别靶标过敏原,在过敏原检测中有良好的应用前景。为了获得芝麻主要过敏原Ses i 2的特异性核酸适体,本研究以Ses i 2为靶标,通过磁珠筛选法(磁珠-SELEX)开展10轮筛选,经由高通量测序获得6条候补序列(S1~S6),并进行家族性、同源性分析及二级结构预测。结果表明,6条候选核酸适体的重复率可达46.38%,其自由能在-9.02到-2.47 kcal·moL^(-1)之间,根据自由能能量稳定原则,S1和S5吉布斯自由能最低最稳定,分别为-6.70和-9.02 kcal·moL^(-1)。利用ELISA试验进行亲和力测试,结果表明核酸适体S1和S2的亲和能力较强,S1:KD=67.02 nmol·L^(-1),R2=0.925 8,S2:KD=97.65 nmol·L^(-1),R2=0.795 1。核酸适体S1与过敏原Ses i 2的结合力和其他过敏原蛋白相比有显著差异,可视为具有特异性。本研究最终获得一条兼具良好亲和力和特异性的核酸适体S1,为芝麻过敏原快速检测提供了技术支撑。
基金supported by the National Natural Science Foundation of China(Grant Nos.92365203,12534013,12174096,and 12474167)the Hunan Provincial Science Fund for Distinguished Young Scholars(Grant No.2022JJ10060)+1 种基金the Science and Technology Innovation Program of Hunan Province(Grant Nos.2025ZYJ001 and 2021RC4026)the Science Fund for Self-initiated Innovation of NUDT。
文摘The two-dimensional van der Waals layered semiconductor In_(2)Se_(3) has emerged as a promising candidate for non-volatile ferroelectric memory,optoelectronic devices,and polymorphic phase engineering.Polymorphic In_(2)Se_(3) typically stabilizes in three distinct phases:α-,β′-,and β^(*)-In_(2)Se_(3),each dominant within specific temperature ranges.Although the crystal structures and ferroelectric properties of these phases have been widely studied,the unambiguous assignment of their in-plane and out-of-plane ferroelectric behaviors,as well as the mechanisms governing their phase transitions,remains a subject of active debate.In this study,we investigate the evolution of atomic and electronic structures in molecular beam epitaxy-grown ultrathin In_(2)Se_(3) films through correlated microstructural and macroscopic physical property analysis.By employing scanning tunneling microscopy/spectroscopy,temperature-dependent Raman spectroscopy,and piezoresponse force microscopy,we demonstrate a reversible temperature-induced phase transition between the in-plane ferroelectric β^(*)and antiferroelectric β′phases.Furthermore,we confirm robust out-of-plane ferroelectric polarization in the as-grown films and achieve an electric-field-driven transition from the β^(*)to β′phase.Our findings not only advance the fundamental understanding of phase transitions and polarization evolution in two-dimensional semiconductors but also open new avenues for the design of tunable,non-volatile ferroelectric memory devices.
