Two-dimensional(2D)nitride MXenes are predicted to exhibit exceptional metallic properties and high polarity;however,their synthesis remains challenging.Research has relied on traditional molten salt etching,highlight...Two-dimensional(2D)nitride MXenes are predicted to exhibit exceptional metallic properties and high polarity;however,their synthesis remains challenging.Research has relied on traditional molten salt etching,highlighting the need for a scalable,high-purity approach.Here,we present the first solution-based synthesis of Ti_(4)N_(3)T_(x)MXene via a novel saturated salt solution(S^(3))etching technique employing alkali metal salts.By optimizing the sintering process for high-purity Ti_(4)AlN_(3)MAX and refining the S^(3)etching route,we significantly reduced the etch pit density to 1.2×10^(6)cm^(-2)and lowered the etch pit formation rate to 4%,yielding high-quality,phasepure Ti_(4)N_(3)T_(x)MXene.Our study highlights the critical role of alkali metal ions in selective A-layer removal and demonstrates the impressive electrical conductivity and electromagnetic interference shielding performance of 2D nitride MXene,setting a new benchmark for this underexplored material.These findings pave the way for advancing 2D nitride MXenes and their diverse applications.展开更多
This paper study stability of saturated salt solutions cells at 25 ℃. These cells were prepared and measured at National Institute for Standard （NIS-Egypt） to study the stability of the saturated salt solutions. Th...This paper study stability of saturated salt solutions cells at 25 ℃. These cells were prepared and measured at National Institute for Standard （NIS-Egypt） to study the stability of the saturated salt solutions. The study was carried out using three saturated salt solutions, which are Potassium Acetate 22.5%, Potassium Iodide 68.9% and Potassium Sulphate 97.3% to cover low, medium and high relative humidity. The study was carried out using different shapes and volumes half liter spherical, liter spherical and liter conical per each salt which was prepared. The apparatus which used in measurement system in the first time are the same which used after ten years. The results show that the change of relative humidity value after ten years ranged from 0.1% to 0.7%. This value is suitable within uncertainty ＋ 2%. The period of stability for each run for all cells was found to be more than five hours and this period enough for calibration. The measurements show that the cells are stable for more than ten years with accepted value.展开更多
基金supported by the Nano&Material Technology Development Program through the National Research Foundation of Korea(NRF)funded by Ministry of Science and ICT(Grant No.RS-2024-00408180)by Institute for Basic Science(No.IBS-R019-G1).
文摘Two-dimensional(2D)nitride MXenes are predicted to exhibit exceptional metallic properties and high polarity;however,their synthesis remains challenging.Research has relied on traditional molten salt etching,highlighting the need for a scalable,high-purity approach.Here,we present the first solution-based synthesis of Ti_(4)N_(3)T_(x)MXene via a novel saturated salt solution(S^(3))etching technique employing alkali metal salts.By optimizing the sintering process for high-purity Ti_(4)AlN_(3)MAX and refining the S^(3)etching route,we significantly reduced the etch pit density to 1.2×10^(6)cm^(-2)and lowered the etch pit formation rate to 4%,yielding high-quality,phasepure Ti_(4)N_(3)T_(x)MXene.Our study highlights the critical role of alkali metal ions in selective A-layer removal and demonstrates the impressive electrical conductivity and electromagnetic interference shielding performance of 2D nitride MXene,setting a new benchmark for this underexplored material.These findings pave the way for advancing 2D nitride MXenes and their diverse applications.
文摘This paper study stability of saturated salt solutions cells at 25 ℃. These cells were prepared and measured at National Institute for Standard （NIS-Egypt） to study the stability of the saturated salt solutions. The study was carried out using three saturated salt solutions, which are Potassium Acetate 22.5%, Potassium Iodide 68.9% and Potassium Sulphate 97.3% to cover low, medium and high relative humidity. The study was carried out using different shapes and volumes half liter spherical, liter spherical and liter conical per each salt which was prepared. The apparatus which used in measurement system in the first time are the same which used after ten years. The results show that the change of relative humidity value after ten years ranged from 0.1% to 0.7%. This value is suitable within uncertainty ＋ 2%. The period of stability for each run for all cells was found to be more than five hours and this period enough for calibration. The measurements show that the cells are stable for more than ten years with accepted value.
