An 8-hydroxyquinolinate-based metal–organic framework[Zn(L)]·2MeOH·H_(2)O(1)was synthesized for the first time by treating a novel 8-hydroxyquinolinate ligand H_(2)L involving two carboxylate groups with zi...An 8-hydroxyquinolinate-based metal–organic framework[Zn(L)]·2MeOH·H_(2)O(1)was synthesized for the first time by treating a novel 8-hydroxyquinolinate ligand H_(2)L involving two carboxylate groups with zinc salt.Based on single-crystal X-ray analysis,the Zn-MOF exhibits a porous framework assembled from interlinked nanotubes that are constructed from three 4_(3)helices.展开更多
基金supported by the National Natural Science Foundation of China(Grants 21671002 and 21603001)Anhui Province Natural Science Funds for Distinguished Young Scholar(Grants 1808085J25)the Provincial Natural Science Research Program of Higher Education Institutions of Anhui Province(KJ2019A0071).
文摘An 8-hydroxyquinolinate-based metal–organic framework[Zn(L)]·2MeOH·H_(2)O(1)was synthesized for the first time by treating a novel 8-hydroxyquinolinate ligand H_(2)L involving two carboxylate groups with zinc salt.Based on single-crystal X-ray analysis,the Zn-MOF exhibits a porous framework assembled from interlinked nanotubes that are constructed from three 4_(3)helices.
