The presence of aluminum(Al^(3+))and fluoride(F^(−))ions in the environment can be harmful to ecosystems and human health,highlighting the need for accurate and efficient monitoring.In this paper,an innovative approac...The presence of aluminum(Al^(3+))and fluoride(F^(−))ions in the environment can be harmful to ecosystems and human health,highlighting the need for accurate and efficient monitoring.In this paper,an innovative approach is presented that leverages the power of machine learning to enhance the accuracy and efficiency of fluorescence-based detection for sequential quantitative analysis of aluminum(Al^(3+))and fluoride(F^(−))ions in aqueous solutions.The proposed method involves the synthesis of sulfur-functionalized carbon dots(C-dots)as fluorescence probes,with fluorescence enhancement upon interaction with Al^(3+)ions,achieving a detection limit of 4.2 nmol/L.Subsequently,in the presence of F^(−)ions,fluorescence is quenched,with a detection limit of 47.6 nmol/L.The fingerprints of fluorescence images are extracted using a cross-platform computer vision library in Python,followed by data preprocessing.Subsequently,the fingerprint data is subjected to cluster analysis using the K-means model from machine learning,and the average Silhouette Coefficient indicates excellent model performance.Finally,a regression analysis based on the principal component analysis method is employed to achieve more precise quantitative analysis of aluminum and fluoride ions.The results demonstrate that the developed model excels in terms of accuracy and sensitivity.This groundbreaking model not only showcases exceptional performance but also addresses the urgent need for effective environmental monitoring and risk assessment,making it a valuable tool for safeguarding our ecosystems and public health.展开更多
The technology of solid-state lighting has developed for decades in various industries.Phosphor,as an element part,determines the application domain of lighting products.For instance,blue and redemitting phosphors are...The technology of solid-state lighting has developed for decades in various industries.Phosphor,as an element part,determines the application domain of lighting products.For instance,blue and redemitting phosphors are required in the process of plant supplementing light,arrow-band emitting phosphors are applied to backlight displays,etc.In this work,a Bi^(3+)-activated blue phosphor was obtained in a symmetrical and co mpact crystal structure of Gd3Sb07(GSO).Then,the co-doping strategy of alkali metal ions(Li^(+),Na^(+),and K^(+))was used to optimize the performance.The result shows that the photoluminescence intensity is increased by 2.1 times and 1.3 times respectively by introducing Li~+and K^(+)ions.Not only that,it also achieves narrow-band emitting with the full width of half-maximum(FWHM)reaching 42 nm through Na^(+)doping,and its excitation peak position also shifts from 322 to 375 nm,which can be well excited by near-ultraviolet(NUV)light emitting diode(LED)chips(365 nm).Meanwhile,the electroluminescence spectrum of GSO:0.6 mol%Bi^(3+),3 wt%Na^(+)matches up to 93.39%of the blue part of the absorption spectrum of chlorophyll a.In summary,the Bi^(3+)-activated blue phosphor reported in this work can synchronously meet the requirements of plant light replenishment and field emission displays.展开更多
The combined reagents of sodium N-oleoylsarcosinate(SNOS)with metal ions(Ca(Ⅱ),Mg(Ⅱ),Cu(Ⅱ),and Pb(Ⅱ))was employed to facilitate the separation of lepidolite from feldspar.The synergistic interaction mechanism of t...The combined reagents of sodium N-oleoylsarcosinate(SNOS)with metal ions(Ca(Ⅱ),Mg(Ⅱ),Cu(Ⅱ),and Pb(Ⅱ))was employed to facilitate the separation of lepidolite from feldspar.The synergistic interaction mechanism of this combined reagent was systematically investigated via contact angle measurements,AFM,FTIR,species distribution calculations,and DFT calculations.The results suggested that Ca(Ⅱ)exhibited the best selectivity for activating lepidolite flotation.SNOS was chemically adsorbed on the Ca(Ⅱ)-activated lepidolite surface with an adsorption energy of−1248.91 kJ/mol while a lower adsorption energy of−598.84 kJ/mol of SNOS on Ca(Ⅱ)-activated feldspar was calculated.Therefore,this combination of SNOS and Ca(Ⅱ)is a promising reagent scheme for the efficient recovery of lithium from aluminosilicate ore.展开更多
Gallium nitride(GaN)-based devices have significant potential for space applications.However,the mechanisms of radiation damage to the device,particularly from strong ionizing radiation,remains unknown.This study inve...Gallium nitride(GaN)-based devices have significant potential for space applications.However,the mechanisms of radiation damage to the device,particularly from strong ionizing radiation,remains unknown.This study investigates the effects of radiation on p-gate AlGaN/GaN high-electron-mobility transistors(HEMTs).Under a high voltage,the HEMT leakage current increased sharply and was accompanied by a rapid increase in power density that caused"thermal burnout"of the devices.In addition,a burnout signature appeared on the surface of the burned devices,proving that a single-event burnout effect occurred.Additionally,degradation,including an increase in the on-resistance and a decrease in the breakdown voltage,was observed in devices irradiated with high-energy heavy ions and without bias.The latent tracks induced by heavy ions penetrated the heterojunction interface and extended into the GaN layer.Moreover,a new type of N_(2)bubble defect was discovered inside the tracks using Fresnel analysis.The accumulation of N_(2)bubbles in the heterojunction and buffer layers is more likely to cause leakage and failure.This study indicates that electrical stress accelerates the failure rate and that improving heat dissipation is an effective reinforcement method for GaN-based devices.展开更多
The traditional von Neumann architecture faces inherent limitations due to the separation of memory and computa-tion,leading to high energy consumption,significant latency,and reduced operational efficiency.Neuromorph...The traditional von Neumann architecture faces inherent limitations due to the separation of memory and computa-tion,leading to high energy consumption,significant latency,and reduced operational efficiency.Neuromorphic computing,inspired by the architecture of the human brain,offers a promising alternative by integrating memory and computational func-tions,enabling parallel,high-speed,and energy-efficient information processing.Among various neuromorphic technologies,ion-modulated optoelectronic devices have garnered attention due to their excellent ionic tunability and the availability of multi-dimensional control strategies.This review provides a comprehensive overview of recent progress in ion-modulation optoelec-tronic neuromorphic devices.It elucidates the key mechanisms underlying ionic modulation of light fields,including ion migra-tion dynamics and capture and release of charge through ions.Furthermore,the synthesis of active materials and the proper-ties of these devices are analyzed in detail.The review also highlights the application of ion-modulation optoelectronic devices in artificial vision systems,neuromorphic computing,and other bionic fields.Finally,the existing challenges and future direc-tions for the development of optoelectronic neuromorphic devices are discussed,providing critical insights for advancing this promising field.展开更多
The depression mechanism of sulfite ions on sphalerite and Pb^(2+)activated sphalerite in the flotation separation of galena from sphalerite still lacked in-depth insight.Therefore,the depression mechanism of sulfite ...The depression mechanism of sulfite ions on sphalerite and Pb^(2+)activated sphalerite in the flotation separation of galena from sphalerite still lacked in-depth insight.Therefore,the depression mechanism of sulfite ions on sphalerite and Pb^(2+)activated sphalerite in the flotation separation of galena from sphalerite was further systematically investigated with experiments and density functional theory(DFT)calculations.The X-ray photoelectric spectroscopy(XPS)results,DFT calculation results,and frontier molecular orbital analysis indicated that sulfite ions were difficult to be adsorbed on sphalerite surface,suggesting that sulfite ions achieved depression effects on sphalerite through other non-adsorption mechanisms.First,the oxygen content in the surface of sphalerite treated with sulfite ions in creased,which enhanced the hydrophilicity of the sphalerite and further increased the difference in hydrophilicity between sphalerite and galena.Then,sulfite ions were chelated with lead ions to form PbSO_(3)in solution.The hydrophilic PbSO_(3)was more easily adsorbed on sphalerite than galena.The interaction between sulfite ions and lead ions could effectively inhibit the activation of sphalerite.In addition the UV spectrum showed that after adding sulfite ions,the peak of perxanthate in the sphalerite treated xanthate solution was significantly stronger than that in the galena with xanthate solution,indicating that xanthate interacted more readily with sulfite ions and oxygen mo lecules within the sphalerite system,leading to the formation of perxanthate.However,sulfite ions hardly depressed the flotation of ga lena and could promote the flotation of galena to some extent.This study deepened the understanding of the depression mechanism o sulfite ions on sphalerite and Pb^(2+)activated sphalerite.展开更多
One of the detection objectives of the Chinese Asteroid Exploration mission is to investigate the space environment near the Main-belt Comet(MBC,Active Asteroid)311P/PANSTARRS.This paper outlines the scientific object...One of the detection objectives of the Chinese Asteroid Exploration mission is to investigate the space environment near the Main-belt Comet(MBC,Active Asteroid)311P/PANSTARRS.This paper outlines the scientific objectives,measurement targets,and measurement requirements for the proposed Gas and Ion Analyzer(GIA).The GIA is designed for in-situ mass spectrometry of neutral gases and low-energy ions,such as hydrogen,carbon,and oxygen,in the vicinity of 311P.Ion sampling techniques are essential for the GIA's Time-of-Flight(TOF)mass analysis capabilities.In this paper,we present an enhanced ion sampling technique through the development of an ion attraction model and an ion source model.The ion attraction model demonstrates that adjusting attraction grid voltage can enhance the detection efficiency of low-energy ions and mitigate the repulsive force of ions during sampling,which is influenced by the satellite's surface positive charging.The ion source model simulates the processes of gas ionization and ion multiplication.Simulation results indicate that the GIA can achieve a lower pressure limit below 10-13Pa and possess a dynamic range exceeding 10~9.These performances ensure the generation of ions with stable and consistent current,which is crucial for high-resolution and broad dynamic range mass spectrometer analysis.Preliminary testing experiments have verified GIA's capability to detect gas compositions such as H2O and N2.In-situ measurements near 311P using GIA are expected to significantly contribute to our understanding of asteroid activity mechanisms,the evolution of the atmospheric and ionized environments of main-belt comets,the interactions with solar wind,and the origin of Earth's water.展开更多
Calcium ions(Ca^(2+))and manganese ions(Mn^(2+))are essential for sustaining life activities and are key monitoring indicators in drinking water.Developing highly sensitive,selective,and portable detection methods for...Calcium ions(Ca^(2+))and manganese ions(Mn^(2+))are essential for sustaining life activities and are key monitoring indicators in drinking water.Developing highly sensitive,selective,and portable detection methods for Ca^(2+)and Mn^(2+)is significant for water quality monitoring and human health.In this paper,blue fluorescent Ti3C2 MXene-based quantum dots(MQDs,λ_(em)=445 nm)are prepared using Ti_(3)C_(2)MXene as the precursor.Through the chelation effect of ethylene diamine tetraacetic acid(EDTA),a blue and red dual-emission fluorescent probe,MQDs-EDTA-Eu^(3+)-DPA,was constructed.Herein,dipicolinic acid(DPA)acts as an absorbing ligand and significantly enhances the red fluorescence of europium ions(Eu^(3+))at 616 nm through the“antenna effect”.The blue fluorescence of MQDs serves as an internal reference signal.High concentrations of Ca^(2+)can quench the red fluorescence of Eu^(3+)-DPA;Mn^(2+)can be excited to emit purple fluorescence at 380 nm after coordinating with DPA,red fluorescence of Eu^(3+)-DPA serves as the internal reference signal.Based on the above two fluorescence intensity changes,ratiometric fluorescence detection methods for Ca^(2+)and Mn^(2+)are established.The fluorescence intensity ratio(IF_(616)/IF_(445))exhibits a linear relationship with Ca^(2+)in the range of 35-120μmol/L,with a detection limit of 5.98μmol/L.The fluorescence intensity ratio(IF_(380)/IF_(616))shows good linearity with Mn^(2+)in the range of 0-14μmol/L,with a detection limit of 28.6 nmol/L.This method was successfully applied to the quantitative analysis of Ca^(2+)and Mn^(2+)in commercially available mineral water(Nongfu Spring,Ganten,and Evergrande),with recovery rates of 80.6%-117%and relative standard deviations(RSD)of 0.76%-4.6%.Additionally,by preparing MQD-based fluorescent test strips,visual detections of Ca^(2+)and Mn^(2+)are achieved.This work demonstrates the application potential of MQDs in the field of visual fluorescence sensing of ions in water quality.展开更多
Graphene fiber supercapacitors(GFSCs)have garnered significant attention due to their exceptional features,including high power density,rapid charge/discharge rates,prolonged cycling durability,and versatile weaving c...Graphene fiber supercapacitors(GFSCs)have garnered significant attention due to their exceptional features,including high power density,rapid charge/discharge rates,prolonged cycling durability,and versatile weaving capabilities.Nevertheless,inherent challenges in graphene fibers(GFs),particularly the restricted ion-accessible specific surface area(SSA)and sluggish ion transport kinetics,hinder the achievement of optimal capacitance and rate performance.Despite existing reviews on GFSCs,a notable gap exists in thoroughly exploring the kinetics governing the energy storage process in GFSCs.This review aims to address this gap by thoroughly analyzing the energy storage mechanism,fabrication methodologies,property manipulation,and wearable applications of GFSCs.Through theoretical analysis of the energy storage process,specific parameters in advanced GF fabrication methodologies are carefully summarized,which can be used to modulate nano/micro-structures,thereby enhancing energy storage kinetics.In particular,enhanced ion storage is realized by creating more ion-accessible SSA and introducing extra-capacitive components,while accelerated ion transport is achieved by shortening the transport channel length and improving the accessibility of electrolyte ions.Building on the established structure-property relationship,several critical strategies for constructing optimal surface and structure profiles of GF electrodes are summarized.Capitalizing on the exceptional flexibility and wearability of GFSCs,the review further underscores their potential as foundational elements for constructing multifunctional e-textiles using conventional textile technologies.In conclusion,this review provides insights into current challenges and suggests potential research directions for GFSCs.展开更多
The extraction characteristics of multi-charged ions produced by ion sources are important for some useful applications.In this paper,the extraction process of Cu^(+),Cu^(2+),Cu^(3+),and Cu^(4+)mixed ions is simulated...The extraction characteristics of multi-charged ions produced by ion sources are important for some useful applications.In this paper,the extraction process of Cu^(+),Cu^(2+),Cu^(3+),and Cu^(4+)mixed ions is simulated by setting ideal physical parameters in a two-dimensional particle-in-cell(PIC)code,and the evolution characteristics of density and velocity distributions of different charged ions during plasma(density about 10^(15)m^(-3))motion and extraction are presented.Besides,the effects of grid thickness and grid aperture on the motion behavior of different charged ions and the extracted ion current are analyzed.The results showed that the ion diffusion increases with the increase of the ion charge,and higher charged ions are more likely to be affected by the grid.This provides support for further understanding of the extraction characteristics of multi-charged mixed ion beams.展开更多
We study the fragmentation of NO^(q+)(q=2,3)molecular ions produced by collisions between 96 keV O^(6+)ions and neutral nitric oxide(NO)molecules,using the cold target recoil ion momentum spectrometer(COLTRIMS).The ki...We study the fragmentation of NO^(q+)(q=2,3)molecular ions produced by collisions between 96 keV O^(6+)ions and neutral nitric oxide(NO)molecules,using the cold target recoil ion momentum spectrometer(COLTRIMS).The kinetic energy release(KER)for various dissociation channels is obtained.For the channel NO^(2+)→N^(+)+O^(+),double-electron capture followed by autoionization of the projectile ions is the dominant process,which can be explained by the recapture of loosely bound electrons into highly excited states of the target.For NO3+trication,two dissociation channels,i.e.,(a)N^(+)+O^(2+)and(b)N^(2+)+O^(+),are observed,where channel(b)is the dominant channel.Moreover,for dissociation channels originating from the same parent molecular ion,the dissociation channel with a higher charge for the oxygen ion fragment exhibits a higher most probable KER,which is consistent with studies of CO fragmentation by Rajput et al.Additionally,it is observed that as capture stability increases,the average KER shifts to higher values.展开更多
State-selective single-and double-electron capture processes in collisions of S^(5+)ions with helium at energies ranging from 50.8 keV to 100 keV were investigated using cold target recoil ion momentum spectroscopy(CO...State-selective single-and double-electron capture processes in collisions of S^(5+)ions with helium at energies ranging from 50.8 keV to 100 keV were investigated using cold target recoil ion momentum spectroscopy(COLTRIMS).Q-value spectra and projectile scattering angle distributions were obtained.For single-electron capture,single electron capture into n=3 states of the projectile ion is dominant.As the projectile energy increases,the contribution of single electron capture into n=4 states is observed.Experimental relative cross-sections for single-electron capture into different projectile final states were compared with theoretical predictions based on the molecular orbital close-coupling(MOCC)method.In double-electron capture,two-electron populating into the 3s^(2)3p and 3s3p^(2)states of projectile dominates.The reaction window calculated from the classical molecular Coulombic barrier model can qualitatively explain the experimental results.The scattering angle distribution of the multi-peak structure of the double-electron capture process is observed.The database is openly available in Science Data Bank at https://doi.org/10.57760/sciencedb.j00113.00233.展开更多
Laser-driven ion acceleration,as produced by interaction of a high-intensity laser with a target,is a growing field of interest.One of the current challenges is to enhance the acceleration process,i.e.,to increase the...Laser-driven ion acceleration,as produced by interaction of a high-intensity laser with a target,is a growing field of interest.One of the current challenges is to enhance the acceleration process,i.e.,to increase the produced ion energy and the ion number and to shape the energy distribution for future applications.In this paper,we investigate the effect of helical coil(HC)targets on the laser-matter interaction process using a 150 TW laser.We demonstrate that HC targets significantly enhance proton acceleration,improving energy bunching and beam focusing and increasing the cutoff energy.For the first time,we extend this analysis to carbon ions,revealing a marked reduction in the number of low-energy carbon ions and the potential for energy bunching and post-acceleration through an optimized HC design.Simulations using the particle-in-cell code SOPHIE confirm the experimental results,providing insights into the current propagation and ion synchronization mechanisms in HCs.Our findings suggest that HC targets can be optimized for multispecies ion acceleration.展开更多
To address the temperature cross-talk issue in detecting heavy metal ions in natural waters, a highly-integrated and fully fiber-optic metal ion sensing system capable of temperature-concentration decoupling measureme...To address the temperature cross-talk issue in detecting heavy metal ions in natural waters, a highly-integrated and fully fiber-optic metal ion sensing system capable of temperature-concentration decoupling measurement has been designed. This system integrates a fluidic detection structure assisted by side-polished fibers(SPFs) with a Sagnac interferometer.展开更多
We study the production of the X(6900)in the ultra-peripheral heavy ion collisions at the LHC energy region.The potential quantum numbers of X(6900)could be 0^(±+)and 2^(±+).We find that the transverse momen...We study the production of the X(6900)in the ultra-peripheral heavy ion collisions at the LHC energy region.The potential quantum numbers of X(6900)could be 0^(±+)and 2^(±+).We find that the transverse momentum and the polar angle distributions of X(6900)can be used to distinguish these four potential quantum numbers.These characteristic distributions originate from linearly polarized photons emitted by relativistic nuclei and can be measured by further LHC experiments.展开更多
The nano-MOF-303 synthesized by microwave method exhibited efficient adsorption capacity(232 mg/g)toward Ag^(+),in which the adsorption behaviors were fitted by the pseudo-second-order kinetic and the Freundlich isoth...The nano-MOF-303 synthesized by microwave method exhibited efficient adsorption capacity(232 mg/g)toward Ag^(+),in which the adsorption behaviors were fitted by the pseudo-second-order kinetic and the Freundlich isotherm model.The outstanding Ag^(+)sorption ability of nano-MOF-303 could be contributed to electrostatic interactions,weak coordination interaction of Ag-N,and Ag Cl precipitates originating from the stored Cl^(-)in nano-MOF-303.Besides the adsorbent regeneration,the formed Ag/Ag Cl onto nano-MOF-303 could produce Ag/Ag Cl/MOF-303 as a photocatalyst for sulfamethoxazole degradation under visible light.In this work,both the adsorption and photocatalysis mechanisms were clarified,which might provide insight to develop more effective adsorbents for mining the critical resource from the wastewater.展开更多
Laser-produced plasmas in the field of inertial confinement fusion usually consist of multiple ion species with different atomic numbers and charge-to-mass ratios.With the presence of various plasma gradients,ion diff...Laser-produced plasmas in the field of inertial confinement fusion usually consist of multiple ion species with different atomic numbers and charge-to-mass ratios.With the presence of various plasma gradients,ion diffusion is driven,causing ion concentration to evolve and deviate from its initial value.In order to investigate the effect of ion diffusion on laserproduced plasmas,we implement an ion diffusion module within the radiation-hydro code MULTI-1D[Comput.Phys.Commun.203226(2016)].Under the planar target geometry and simulation parameters considered in this study,ion species separation primarily occurs near ablation front and underdense region.Although ion diffusion just has a slight impact on plasma hydrodynamics such as density,temperature and pressure profiles,it could have significant influence on the processes in relevant to ion-acoustic wave,whose damping rate depends sensitively on ion concentration.It is found that the coupling factor of cross-beam energy transfer(CBET)could change a lot when ion diffusion is taken into account,indicating that ion diffusion could play important role in laser fusion.展开更多
Recently,large-scale trapped ion systems have been realized in experiments for quantum simulation and quantum computation.They are the simplest systems for dynamical stability and parametric resonance.In this model,th...Recently,large-scale trapped ion systems have been realized in experiments for quantum simulation and quantum computation.They are the simplest systems for dynamical stability and parametric resonance.In this model,the Mathieu equation plays the most fundamental role for us to understand the stability and instability of a single ion.In this work,we investigate the dynamics of trapped ions with the Coulomb interaction based on the Hamiltonian equation.We show that the many-body interaction will not influence the phase diagram for instability.Then,the dynamics of this model in the large damping limit will also be analytically calculated using few trapped ions.Furthermore,we find that in the presence of modulation,synchronization dynamics can be observed,showing an exchange of velocities between distant ions on the left side and on the right side of the trap.These dynamics resemble that of the exchange of velocities in Newton's cradle for the collision of balls at the same time.These dynamics are independent of their initial conditions and the number of ions.As a unique feature of the interacting Mathieu equation,we hope this behavior,which leads to a quasi-periodic solution,can be measured in current experimental systems.Finally,we have also discussed the effect of anharmonic trapping potential,showing the desynchronization during the collision process.It is hoped that the dynamics in this many-body Mathieu equation with damping may find applications in quantum simulations.This model may also find interesting applications in dynamics systems as a pure mathematical problem,which may be beyond the results in the Floquet theorem.展开更多
A novel hydroxy late-rich functionalized biosorbent by grafting citric acid on the decrystallized Dicranopteris dichotoma stem(DDS) was prepared.The obtained g-DDS-3 exhibits good hydrophilicity,thermal stability and ...A novel hydroxy late-rich functionalized biosorbent by grafting citric acid on the decrystallized Dicranopteris dichotoma stem(DDS) was prepared.The obtained g-DDS-3 exhibits good hydrophilicity,thermal stability and superior adsorption performance for Ce^(3+).The effects of citric acid dosage,pH and initial Ce^(3+)concentration on the adsorption experiments were investigated.The maximum adsorption capacity(Langmuir model) of Ce^(3+)by g-DDS-3 is 131.0 mg/g at pH of 7.0,which surpasses that of most previously reported biomass-based materials.Adsorption kinetic results indicate that the adsorption process conforms to the pseudo-second-order model and can achieve equilibrium quickly.By analyzing the adsorption mechanism,we find that carboxyl groups are uniformly distributed on the surface of g-DDS-3 post modification,which provides abundant adsorption sites,and the adsorption is primarily driven by the ion exchange between Ce^(3+)and carboxyl groups protons.In addition,the adsorption-desorption experiments suggest that the g-DDS-3 has excellent recyclability since the adsorption capacity still remain above 90% after five cycles.These findings prove that carboxylate-rich modified D.dichotoma has great potential for application in the effective separation and recovery of Ce^(3+)from leaching tailings.展开更多
The past decade has witnessed the rapid increasement in power conversion efficiency of perovskite solar cells(PSCs).However,serious ion migration hampers their operational stability.Although dopants composed of varied...The past decade has witnessed the rapid increasement in power conversion efficiency of perovskite solar cells(PSCs).However,serious ion migration hampers their operational stability.Although dopants composed of varied cations and anions are introduced into perovskite to suppress ion migration,the impact of cations or anions is not individually explored,which hinders the evaluation of different cations and further application of doping strategy.Here we report that a special group of sulfonic anions(like CF_(3)SO_(3)^(-))successfully introduce alkaline earth ions(like Ca^(2+))into perovskite lattice compared to its halide counterparts.Furthermore,with effective crystallization regulation and defect passivation of sulfonic anions,perovskite with Ca(CF_(3)SO_(3))_(2)shows reduced PbI2 residue and metallic Pb0 defects;thereby,corresponding PSCs show an enhanced PCE of 24.95%.Finally by comparing the properties of perovskite with Ca(CF_(3)SO_(3))_(2)and FACF_(3)SO_(3),we found that doped Ca^(2+)significantly suppressed halide migration with an activation energy of 1.246 eV which accounts for the improved operational stability of Ca(CF_(3)SO_(3))_(2-)doped PSCs,while no obvious impact of Ca^(2+)on trap density is observed.Combining the benefits of cations and anions,this study presents an effective method to decouple the effects of cations and anions and fabricate efficient and stable PSCs.展开更多
基金supported by the National Natural Science Foundation of China(No.U21A20290)Guangdong Basic and Applied Basic Research Foundation(No.2022A1515011656)+2 种基金the Projects of Talents Recruitment of GDUPT(No.2023rcyj1003)the 2022“Sail Plan”Project of Maoming Green Chemical Industry Research Institute(No.MMGCIRI2022YFJH-Y-024)Maoming Science and Technology Project(No.2023382).
文摘The presence of aluminum(Al^(3+))and fluoride(F^(−))ions in the environment can be harmful to ecosystems and human health,highlighting the need for accurate and efficient monitoring.In this paper,an innovative approach is presented that leverages the power of machine learning to enhance the accuracy and efficiency of fluorescence-based detection for sequential quantitative analysis of aluminum(Al^(3+))and fluoride(F^(−))ions in aqueous solutions.The proposed method involves the synthesis of sulfur-functionalized carbon dots(C-dots)as fluorescence probes,with fluorescence enhancement upon interaction with Al^(3+)ions,achieving a detection limit of 4.2 nmol/L.Subsequently,in the presence of F^(−)ions,fluorescence is quenched,with a detection limit of 47.6 nmol/L.The fingerprints of fluorescence images are extracted using a cross-platform computer vision library in Python,followed by data preprocessing.Subsequently,the fingerprint data is subjected to cluster analysis using the K-means model from machine learning,and the average Silhouette Coefficient indicates excellent model performance.Finally,a regression analysis based on the principal component analysis method is employed to achieve more precise quantitative analysis of aluminum and fluoride ions.The results demonstrate that the developed model excels in terms of accuracy and sensitivity.This groundbreaking model not only showcases exceptional performance but also addresses the urgent need for effective environmental monitoring and risk assessment,making it a valuable tool for safeguarding our ecosystems and public health.
基金Project supported by the Key R&D Projects in Hunan Province(2021SK2047,2022NK2044)Science and Technology Innovation Program of Hunan Province(2022WZ1022)Superior Youth Project of the Science Research Project of Hunan Provincial Department of Education(22B0211)。
文摘The technology of solid-state lighting has developed for decades in various industries.Phosphor,as an element part,determines the application domain of lighting products.For instance,blue and redemitting phosphors are required in the process of plant supplementing light,arrow-band emitting phosphors are applied to backlight displays,etc.In this work,a Bi^(3+)-activated blue phosphor was obtained in a symmetrical and co mpact crystal structure of Gd3Sb07(GSO).Then,the co-doping strategy of alkali metal ions(Li^(+),Na^(+),and K^(+))was used to optimize the performance.The result shows that the photoluminescence intensity is increased by 2.1 times and 1.3 times respectively by introducing Li~+and K^(+)ions.Not only that,it also achieves narrow-band emitting with the full width of half-maximum(FWHM)reaching 42 nm through Na^(+)doping,and its excitation peak position also shifts from 322 to 375 nm,which can be well excited by near-ultraviolet(NUV)light emitting diode(LED)chips(365 nm).Meanwhile,the electroluminescence spectrum of GSO:0.6 mol%Bi^(3+),3 wt%Na^(+)matches up to 93.39%of the blue part of the absorption spectrum of chlorophyll a.In summary,the Bi^(3+)-activated blue phosphor reported in this work can synchronously meet the requirements of plant light replenishment and field emission displays.
基金financial support from the National Natural Science Foundation of China(Nos.U2067201,52204300)the National 111 Project,China(No.B14034)the Fundamental Research Funds for the Central Universities of Central South University,China(No.2021zzts0297).
文摘The combined reagents of sodium N-oleoylsarcosinate(SNOS)with metal ions(Ca(Ⅱ),Mg(Ⅱ),Cu(Ⅱ),and Pb(Ⅱ))was employed to facilitate the separation of lepidolite from feldspar.The synergistic interaction mechanism of this combined reagent was systematically investigated via contact angle measurements,AFM,FTIR,species distribution calculations,and DFT calculations.The results suggested that Ca(Ⅱ)exhibited the best selectivity for activating lepidolite flotation.SNOS was chemically adsorbed on the Ca(Ⅱ)-activated lepidolite surface with an adsorption energy of−1248.91 kJ/mol while a lower adsorption energy of−598.84 kJ/mol of SNOS on Ca(Ⅱ)-activated feldspar was calculated.Therefore,this combination of SNOS and Ca(Ⅱ)is a promising reagent scheme for the efficient recovery of lithium from aluminosilicate ore.
基金supported by the National Natural Science Foundation of China(Nos.12035019,62234013,12205350,12075290,12175287)the China National Postdoctoral Program for Innovative Talents(BX20200340)+1 种基金the fund of Innovation Center of Radiation Application(No.KFZC2022020601)the Chinese Academy of Sciences(CAS)“Light of West China"Program hosted by Jian Zeng.
文摘Gallium nitride(GaN)-based devices have significant potential for space applications.However,the mechanisms of radiation damage to the device,particularly from strong ionizing radiation,remains unknown.This study investigates the effects of radiation on p-gate AlGaN/GaN high-electron-mobility transistors(HEMTs).Under a high voltage,the HEMT leakage current increased sharply and was accompanied by a rapid increase in power density that caused"thermal burnout"of the devices.In addition,a burnout signature appeared on the surface of the burned devices,proving that a single-event burnout effect occurred.Additionally,degradation,including an increase in the on-resistance and a decrease in the breakdown voltage,was observed in devices irradiated with high-energy heavy ions and without bias.The latent tracks induced by heavy ions penetrated the heterojunction interface and extended into the GaN layer.Moreover,a new type of N_(2)bubble defect was discovered inside the tracks using Fresnel analysis.The accumulation of N_(2)bubbles in the heterojunction and buffer layers is more likely to cause leakage and failure.This study indicates that electrical stress accelerates the failure rate and that improving heat dissipation is an effective reinforcement method for GaN-based devices.
基金supported by National Natural Science Foundation of China(62174164,U23A20568,and U22A2075)National Key Research and Development Project(2021YFA1202600)+2 种基金Talent Plan of Shanghai Branch,Chinese Academy of Sciences(CASSHB-QNPD-2023-022)Ningbo Technology Project(2022A-007-C)Ningbo Key Research and Development Project(2023Z021).
文摘The traditional von Neumann architecture faces inherent limitations due to the separation of memory and computa-tion,leading to high energy consumption,significant latency,and reduced operational efficiency.Neuromorphic computing,inspired by the architecture of the human brain,offers a promising alternative by integrating memory and computational func-tions,enabling parallel,high-speed,and energy-efficient information processing.Among various neuromorphic technologies,ion-modulated optoelectronic devices have garnered attention due to their excellent ionic tunability and the availability of multi-dimensional control strategies.This review provides a comprehensive overview of recent progress in ion-modulation optoelec-tronic neuromorphic devices.It elucidates the key mechanisms underlying ionic modulation of light fields,including ion migra-tion dynamics and capture and release of charge through ions.Furthermore,the synthesis of active materials and the proper-ties of these devices are analyzed in detail.The review also highlights the application of ion-modulation optoelectronic devices in artificial vision systems,neuromorphic computing,and other bionic fields.Finally,the existing challenges and future direc-tions for the development of optoelectronic neuromorphic devices are discussed,providing critical insights for advancing this promising field.
基金financially supported by the National Natural Science Foundation of China(No.52074356)Open Foundation of State Key Laboratory of Mineral Processing(No.BGRIMM-KJSKL-2023-06)+5 种基金the National Key R&D Program of China(No.2022YFC2904500)the Science and Technology Innovation Program of Hunan Province,China(No.2022RC1183)Changsha Science and Technology Project,China(Outstanding Innovative Youth Training Program)Innovation driven program of Central South University(No.2023CXQD002)National 111 Project(No.B14034)the Fundamental Research Funds for the Central Universities of Central South University Project(No.50621747)。
文摘The depression mechanism of sulfite ions on sphalerite and Pb^(2+)activated sphalerite in the flotation separation of galena from sphalerite still lacked in-depth insight.Therefore,the depression mechanism of sulfite ions on sphalerite and Pb^(2+)activated sphalerite in the flotation separation of galena from sphalerite was further systematically investigated with experiments and density functional theory(DFT)calculations.The X-ray photoelectric spectroscopy(XPS)results,DFT calculation results,and frontier molecular orbital analysis indicated that sulfite ions were difficult to be adsorbed on sphalerite surface,suggesting that sulfite ions achieved depression effects on sphalerite through other non-adsorption mechanisms.First,the oxygen content in the surface of sphalerite treated with sulfite ions in creased,which enhanced the hydrophilicity of the sphalerite and further increased the difference in hydrophilicity between sphalerite and galena.Then,sulfite ions were chelated with lead ions to form PbSO_(3)in solution.The hydrophilic PbSO_(3)was more easily adsorbed on sphalerite than galena.The interaction between sulfite ions and lead ions could effectively inhibit the activation of sphalerite.In addition the UV spectrum showed that after adding sulfite ions,the peak of perxanthate in the sphalerite treated xanthate solution was significantly stronger than that in the galena with xanthate solution,indicating that xanthate interacted more readily with sulfite ions and oxygen mo lecules within the sphalerite system,leading to the formation of perxanthate.However,sulfite ions hardly depressed the flotation of ga lena and could promote the flotation of galena to some extent.This study deepened the understanding of the depression mechanism o sulfite ions on sphalerite and Pb^(2+)activated sphalerite.
基金Supported by the National Natural Science Foundation of China(42474239,41204128)China National Space Administration(Pre-research project on Civil Aerospace Technologies No.D010301)Strategic Priority Research Program of the Chinese Academy of Sciences(XDA17010303)。
文摘One of the detection objectives of the Chinese Asteroid Exploration mission is to investigate the space environment near the Main-belt Comet(MBC,Active Asteroid)311P/PANSTARRS.This paper outlines the scientific objectives,measurement targets,and measurement requirements for the proposed Gas and Ion Analyzer(GIA).The GIA is designed for in-situ mass spectrometry of neutral gases and low-energy ions,such as hydrogen,carbon,and oxygen,in the vicinity of 311P.Ion sampling techniques are essential for the GIA's Time-of-Flight(TOF)mass analysis capabilities.In this paper,we present an enhanced ion sampling technique through the development of an ion attraction model and an ion source model.The ion attraction model demonstrates that adjusting attraction grid voltage can enhance the detection efficiency of low-energy ions and mitigate the repulsive force of ions during sampling,which is influenced by the satellite's surface positive charging.The ion source model simulates the processes of gas ionization and ion multiplication.Simulation results indicate that the GIA can achieve a lower pressure limit below 10-13Pa and possess a dynamic range exceeding 10~9.These performances ensure the generation of ions with stable and consistent current,which is crucial for high-resolution and broad dynamic range mass spectrometer analysis.Preliminary testing experiments have verified GIA's capability to detect gas compositions such as H2O and N2.In-situ measurements near 311P using GIA are expected to significantly contribute to our understanding of asteroid activity mechanisms,the evolution of the atmospheric and ionized environments of main-belt comets,the interactions with solar wind,and the origin of Earth's water.
基金The Tertiary Education Scientific Research Project of the Guangzhou Municipal Education Bureau(2024312227)Innovative and Entrepreneurial Projects of Guangzhou University Students(202411078014)+2 种基金Guangzhou University Open Sharing Fund for Instruments and Equipment(2025)National Major Scientific Research Instrument Development Project(22227804)Sub-subject of the National Key Research Project(2023YFB3210100)。
文摘Calcium ions(Ca^(2+))and manganese ions(Mn^(2+))are essential for sustaining life activities and are key monitoring indicators in drinking water.Developing highly sensitive,selective,and portable detection methods for Ca^(2+)and Mn^(2+)is significant for water quality monitoring and human health.In this paper,blue fluorescent Ti3C2 MXene-based quantum dots(MQDs,λ_(em)=445 nm)are prepared using Ti_(3)C_(2)MXene as the precursor.Through the chelation effect of ethylene diamine tetraacetic acid(EDTA),a blue and red dual-emission fluorescent probe,MQDs-EDTA-Eu^(3+)-DPA,was constructed.Herein,dipicolinic acid(DPA)acts as an absorbing ligand and significantly enhances the red fluorescence of europium ions(Eu^(3+))at 616 nm through the“antenna effect”.The blue fluorescence of MQDs serves as an internal reference signal.High concentrations of Ca^(2+)can quench the red fluorescence of Eu^(3+)-DPA;Mn^(2+)can be excited to emit purple fluorescence at 380 nm after coordinating with DPA,red fluorescence of Eu^(3+)-DPA serves as the internal reference signal.Based on the above two fluorescence intensity changes,ratiometric fluorescence detection methods for Ca^(2+)and Mn^(2+)are established.The fluorescence intensity ratio(IF_(616)/IF_(445))exhibits a linear relationship with Ca^(2+)in the range of 35-120μmol/L,with a detection limit of 5.98μmol/L.The fluorescence intensity ratio(IF_(380)/IF_(616))shows good linearity with Mn^(2+)in the range of 0-14μmol/L,with a detection limit of 28.6 nmol/L.This method was successfully applied to the quantitative analysis of Ca^(2+)and Mn^(2+)in commercially available mineral water(Nongfu Spring,Ganten,and Evergrande),with recovery rates of 80.6%-117%and relative standard deviations(RSD)of 0.76%-4.6%.Additionally,by preparing MQD-based fluorescent test strips,visual detections of Ca^(2+)and Mn^(2+)are achieved.This work demonstrates the application potential of MQDs in the field of visual fluorescence sensing of ions in water quality.
基金Shanghai Municipal Commission for Science and Technology,Grant/Award Number:23ZR1402500National Natural Science Foundation of China,Grant/Award Number:51973034+1 种基金National Scholarship CouncilNational Key Research and Development Program of China,Grant/Award Number:2023YFB3809800.
文摘Graphene fiber supercapacitors(GFSCs)have garnered significant attention due to their exceptional features,including high power density,rapid charge/discharge rates,prolonged cycling durability,and versatile weaving capabilities.Nevertheless,inherent challenges in graphene fibers(GFs),particularly the restricted ion-accessible specific surface area(SSA)and sluggish ion transport kinetics,hinder the achievement of optimal capacitance and rate performance.Despite existing reviews on GFSCs,a notable gap exists in thoroughly exploring the kinetics governing the energy storage process in GFSCs.This review aims to address this gap by thoroughly analyzing the energy storage mechanism,fabrication methodologies,property manipulation,and wearable applications of GFSCs.Through theoretical analysis of the energy storage process,specific parameters in advanced GF fabrication methodologies are carefully summarized,which can be used to modulate nano/micro-structures,thereby enhancing energy storage kinetics.In particular,enhanced ion storage is realized by creating more ion-accessible SSA and introducing extra-capacitive components,while accelerated ion transport is achieved by shortening the transport channel length and improving the accessibility of electrolyte ions.Building on the established structure-property relationship,several critical strategies for constructing optimal surface and structure profiles of GF electrodes are summarized.Capitalizing on the exceptional flexibility and wearability of GFSCs,the review further underscores their potential as foundational elements for constructing multifunctional e-textiles using conventional textile technologies.In conclusion,this review provides insights into current challenges and suggests potential research directions for GFSCs.
基金supported by the Presidential Foundation of China Academy of Engineering Physics(Grant No.YZJJZQ2022016)the National Natural Science Foundation of China(Grant No.52207177).
文摘The extraction characteristics of multi-charged ions produced by ion sources are important for some useful applications.In this paper,the extraction process of Cu^(+),Cu^(2+),Cu^(3+),and Cu^(4+)mixed ions is simulated by setting ideal physical parameters in a two-dimensional particle-in-cell(PIC)code,and the evolution characteristics of density and velocity distributions of different charged ions during plasma(density about 10^(15)m^(-3))motion and extraction are presented.Besides,the effects of grid thickness and grid aperture on the motion behavior of different charged ions and the extracted ion current are analyzed.The results showed that the ion diffusion increases with the increase of the ion charge,and higher charged ions are more likely to be affected by the grid.This provides support for further understanding of the extraction characteristics of multi-charged mixed ion beams.
基金supported by the National Key Research and Development Program of China(Grant No.2022YFA1602500)the National Natural Science Foundation of China(Grant Nos.11934004,12064040,and 11974358)Strategic Key Research Program of the Chinese Academy of Sciences(Grant No.XDB34020000).
文摘We study the fragmentation of NO^(q+)(q=2,3)molecular ions produced by collisions between 96 keV O^(6+)ions and neutral nitric oxide(NO)molecules,using the cold target recoil ion momentum spectrometer(COLTRIMS).The kinetic energy release(KER)for various dissociation channels is obtained.For the channel NO^(2+)→N^(+)+O^(+),double-electron capture followed by autoionization of the projectile ions is the dominant process,which can be explained by the recapture of loosely bound electrons into highly excited states of the target.For NO3+trication,two dissociation channels,i.e.,(a)N^(+)+O^(2+)and(b)N^(2+)+O^(+),are observed,where channel(b)is the dominant channel.Moreover,for dissociation channels originating from the same parent molecular ion,the dissociation channel with a higher charge for the oxygen ion fragment exhibits a higher most probable KER,which is consistent with studies of CO fragmentation by Rajput et al.Additionally,it is observed that as capture stability increases,the average KER shifts to higher values.
基金Project supported by the National Key Research and Development Program of China(Grant No.2022YFA1602500)the National Natural Science Foundation of China(Grant No.11974358)。
文摘State-selective single-and double-electron capture processes in collisions of S^(5+)ions with helium at energies ranging from 50.8 keV to 100 keV were investigated using cold target recoil ion momentum spectroscopy(COLTRIMS).Q-value spectra and projectile scattering angle distributions were obtained.For single-electron capture,single electron capture into n=3 states of the projectile ion is dominant.As the projectile energy increases,the contribution of single electron capture into n=4 states is observed.Experimental relative cross-sections for single-electron capture into different projectile final states were compared with theoretical predictions based on the molecular orbital close-coupling(MOCC)method.In double-electron capture,two-electron populating into the 3s^(2)3p and 3s3p^(2)states of projectile dominates.The reaction window calculated from the classical molecular Coulombic barrier model can qualitatively explain the experimental results.The scattering angle distribution of the multi-peak structure of the double-electron capture process is observed.The database is openly available in Science Data Bank at https://doi.org/10.57760/sciencedb.j00113.00233.
基金supported by the CEA/DAM Laser Plasma Experiments Validation Project and the CEA/DAM Basic Technical and Scientific Studies Projectsupported by the National Sciences and Engineering Research Council of Canada(NSERC)(Grant Nos.RGPIN-2023-05459 and ALLRP 556340-20)+3 种基金the Digital Research Alliance of Canada(Job pve-323-ac)the Canada Foundation for Innovation(CFI)the Ministère de l’Économie,de l’Innovation et de l’Énergie(MEIE)from QuébecThis study was granted access to the HPC resources of IRENE under allocation Grant No.A0170512899 made by GENCI.We acknowledge the financial support of the IdEx University of Bordeaux/Grand Research Program“GPR LIGHT”and of the Graduate Program on Light Sciences and Technologies of the University of Bordeaux.
文摘Laser-driven ion acceleration,as produced by interaction of a high-intensity laser with a target,is a growing field of interest.One of the current challenges is to enhance the acceleration process,i.e.,to increase the produced ion energy and the ion number and to shape the energy distribution for future applications.In this paper,we investigate the effect of helical coil(HC)targets on the laser-matter interaction process using a 150 TW laser.We demonstrate that HC targets significantly enhance proton acceleration,improving energy bunching and beam focusing and increasing the cutoff energy.For the first time,we extend this analysis to carbon ions,revealing a marked reduction in the number of low-energy carbon ions and the potential for energy bunching and post-acceleration through an optimized HC design.Simulations using the particle-in-cell code SOPHIE confirm the experimental results,providing insights into the current propagation and ion synchronization mechanisms in HCs.Our findings suggest that HC targets can be optimized for multispecies ion acceleration.
基金supported by the National Natural Science Foundation of China(Nos.61705027,62375031 and 52075131)the Chongqing Science and Technology Commission Basic Research Project(No.CSTC-2020jcyj-msxm0603)the Chongqing Municipal Education Commission Science and Technology Research Program(No.KJQN202000609)。
文摘To address the temperature cross-talk issue in detecting heavy metal ions in natural waters, a highly-integrated and fully fiber-optic metal ion sensing system capable of temperature-concentration decoupling measurement has been designed. This system integrates a fluidic detection structure assisted by side-polished fibers(SPFs) with a Sagnac interferometer.
基金supported by the Guangdong Major Project of Basic and Applied Basic Research(Grant Nos.2020B0301030008 and 2023A1515010416)the National Natural Science Foundation of China(Grant Nos.12375073,12275091,12147128,and 12035007).
文摘We study the production of the X(6900)in the ultra-peripheral heavy ion collisions at the LHC energy region.The potential quantum numbers of X(6900)could be 0^(±+)and 2^(±+).We find that the transverse momentum and the polar angle distributions of X(6900)can be used to distinguish these four potential quantum numbers.These characteristic distributions originate from linearly polarized photons emitted by relativistic nuclei and can be measured by further LHC experiments.
基金supported by National Natural Science Foundation of China(Nos.22176012,51878023)BUCEA Post Graduate Innovation Project(No.PG2023057)BUCEA Doctor Graduate Scientific Research Ability Improvement Project(No.DG2024022)。
文摘The nano-MOF-303 synthesized by microwave method exhibited efficient adsorption capacity(232 mg/g)toward Ag^(+),in which the adsorption behaviors were fitted by the pseudo-second-order kinetic and the Freundlich isotherm model.The outstanding Ag^(+)sorption ability of nano-MOF-303 could be contributed to electrostatic interactions,weak coordination interaction of Ag-N,and Ag Cl precipitates originating from the stored Cl^(-)in nano-MOF-303.Besides the adsorbent regeneration,the formed Ag/Ag Cl onto nano-MOF-303 could produce Ag/Ag Cl/MOF-303 as a photocatalyst for sulfamethoxazole degradation under visible light.In this work,both the adsorption and photocatalysis mechanisms were clarified,which might provide insight to develop more effective adsorbents for mining the critical resource from the wastewater.
基金supported by the National Nature Science Foundation of China(Grant No.12375242)the Strategic Priority Research Program of the Chinese Academy of Sciences(Grant No.XDA25010200)。
文摘Laser-produced plasmas in the field of inertial confinement fusion usually consist of multiple ion species with different atomic numbers and charge-to-mass ratios.With the presence of various plasma gradients,ion diffusion is driven,causing ion concentration to evolve and deviate from its initial value.In order to investigate the effect of ion diffusion on laserproduced plasmas,we implement an ion diffusion module within the radiation-hydro code MULTI-1D[Comput.Phys.Commun.203226(2016)].Under the planar target geometry and simulation parameters considered in this study,ion species separation primarily occurs near ablation front and underdense region.Although ion diffusion just has a slight impact on plasma hydrodynamics such as density,temperature and pressure profiles,it could have significant influence on the processes in relevant to ion-acoustic wave,whose damping rate depends sensitively on ion concentration.It is found that the coupling factor of cross-beam energy transfer(CBET)could change a lot when ion diffusion is taken into account,indicating that ion diffusion could play important role in laser fusion.
基金supported by the Innovation Program for Quantum Science and Technology(Grant Nos.2021ZD0301200,2021ZD0303200,and 2021ZD0301500)the Alliance of International Science Organizations(ANSO)。
文摘Recently,large-scale trapped ion systems have been realized in experiments for quantum simulation and quantum computation.They are the simplest systems for dynamical stability and parametric resonance.In this model,the Mathieu equation plays the most fundamental role for us to understand the stability and instability of a single ion.In this work,we investigate the dynamics of trapped ions with the Coulomb interaction based on the Hamiltonian equation.We show that the many-body interaction will not influence the phase diagram for instability.Then,the dynamics of this model in the large damping limit will also be analytically calculated using few trapped ions.Furthermore,we find that in the presence of modulation,synchronization dynamics can be observed,showing an exchange of velocities between distant ions on the left side and on the right side of the trap.These dynamics resemble that of the exchange of velocities in Newton's cradle for the collision of balls at the same time.These dynamics are independent of their initial conditions and the number of ions.As a unique feature of the interacting Mathieu equation,we hope this behavior,which leads to a quasi-periodic solution,can be measured in current experimental systems.Finally,we have also discussed the effect of anharmonic trapping potential,showing the desynchronization during the collision process.It is hoped that the dynamics in this many-body Mathieu equation with damping may find applications in quantum simulations.This model may also find interesting applications in dynamics systems as a pure mathematical problem,which may be beyond the results in the Floquet theorem.
基金Project supported by the National Key R&D Program of China (2021YFC2901500)National Natural Science Foundation of China(22208349)+1 种基金Shandong Provincial Natural Science Youth Fund (ZR2022QB244)Shandong Energy Institute Innovation Fund (SEII202107, SEII202133)。
文摘A novel hydroxy late-rich functionalized biosorbent by grafting citric acid on the decrystallized Dicranopteris dichotoma stem(DDS) was prepared.The obtained g-DDS-3 exhibits good hydrophilicity,thermal stability and superior adsorption performance for Ce^(3+).The effects of citric acid dosage,pH and initial Ce^(3+)concentration on the adsorption experiments were investigated.The maximum adsorption capacity(Langmuir model) of Ce^(3+)by g-DDS-3 is 131.0 mg/g at pH of 7.0,which surpasses that of most previously reported biomass-based materials.Adsorption kinetic results indicate that the adsorption process conforms to the pseudo-second-order model and can achieve equilibrium quickly.By analyzing the adsorption mechanism,we find that carboxyl groups are uniformly distributed on the surface of g-DDS-3 post modification,which provides abundant adsorption sites,and the adsorption is primarily driven by the ion exchange between Ce^(3+)and carboxyl groups protons.In addition,the adsorption-desorption experiments suggest that the g-DDS-3 has excellent recyclability since the adsorption capacity still remain above 90% after five cycles.These findings prove that carboxylate-rich modified D.dichotoma has great potential for application in the effective separation and recovery of Ce^(3+)from leaching tailings.
基金support from the National Key Research and Development Program of China(No.2022YFE0137400)the National Natural Science Foundation of China(Grant No.62274040).
文摘The past decade has witnessed the rapid increasement in power conversion efficiency of perovskite solar cells(PSCs).However,serious ion migration hampers their operational stability.Although dopants composed of varied cations and anions are introduced into perovskite to suppress ion migration,the impact of cations or anions is not individually explored,which hinders the evaluation of different cations and further application of doping strategy.Here we report that a special group of sulfonic anions(like CF_(3)SO_(3)^(-))successfully introduce alkaline earth ions(like Ca^(2+))into perovskite lattice compared to its halide counterparts.Furthermore,with effective crystallization regulation and defect passivation of sulfonic anions,perovskite with Ca(CF_(3)SO_(3))_(2)shows reduced PbI2 residue and metallic Pb0 defects;thereby,corresponding PSCs show an enhanced PCE of 24.95%.Finally by comparing the properties of perovskite with Ca(CF_(3)SO_(3))_(2)and FACF_(3)SO_(3),we found that doped Ca^(2+)significantly suppressed halide migration with an activation energy of 1.246 eV which accounts for the improved operational stability of Ca(CF_(3)SO_(3))_(2-)doped PSCs,while no obvious impact of Ca^(2+)on trap density is observed.Combining the benefits of cations and anions,this study presents an effective method to decouple the effects of cations and anions and fabricate efficient and stable PSCs.
