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Tomographic velocity inversion for ADCIGs in areas with a rugged surface 被引量:2
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作者 张凯 李振春 +2 位作者 曾同生 秦宁 姚云霞 《Applied Geophysics》 SCIE CSCD 2012年第3期313-318,361,共7页
Pre-stack depth migration velocity analysis is one of the key techniques influencing image quality. As for areas with a rugged surface and complex subsurface, conventional prestack depth migration velocity analysis co... Pre-stack depth migration velocity analysis is one of the key techniques influencing image quality. As for areas with a rugged surface and complex subsurface, conventional prestack depth migration velocity analysis corrects the rugged surface to a known datum or designed surface velocity model on which to perform migration and update the velocity. We propose a rugged surface tomographic velocity inversion method based on angle-domain common image gathers by which the velocity field can be updated directly from the rugged surface without static correction for pre-stack data and improve inversion precision and efficiency. First, we introduce a method to acquire angle-domain common image gathers (ADCIGs) in rugged surface areas and then perform rugged surface tornographic velocity inversion. Tests with model and field data prove the method to be correct and effective. 展开更多
关键词 rugged surface angle-domain common image gathers tomographic inversion velocity modeling
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应用RUGⅢ对脑梗塞康复病例试行分类的研究 被引量:7
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作者 姚瑾 刘松筠 +2 位作者 党雅君 刘桂芬 王万斌 《中国康复理论与实践》 CSCD 1996年第4期171-175,共5页
采用RUGⅢ这一新的慢性病例分类模式,对我院75例脑梗塞康复患者试行分类,结果表明,RUGⅢ能比较客观地反映康复医疗的全面成本,可表明费用支付的合理性。同时,探讨了RUGⅢ对疗养、家庭病床、临终护理等机构的费用管理的... 采用RUGⅢ这一新的慢性病例分类模式,对我院75例脑梗塞康复患者试行分类,结果表明,RUGⅢ能比较客观地反映康复医疗的全面成本,可表明费用支付的合理性。同时,探讨了RUGⅢ对疗养、家庭病床、临终护理等机构的费用管理的意义。 展开更多
关键词 脑梗塞 康复 rug 病例分类
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Two-dimensional frequency-domain acoustic fullwaveform inversion with rugged topography 被引量:1
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作者 张钱江 戴世坤 +3 位作者 陈龙伟 李昆 赵东东 黄兴兴 《Applied Geophysics》 SCIE CSCD 2015年第3期378-388,467,468,共13页
We studied finite-element-method-based two-dimensional frequency-domain acoustic FWI under rugged topography conditions. The exponential attenuation boundary condition suitable for rugged topography is proposed to sol... We studied finite-element-method-based two-dimensional frequency-domain acoustic FWI under rugged topography conditions. The exponential attenuation boundary condition suitable for rugged topography is proposed to solve the cutoff botmdary problem as well as to consider the requirement of using the same subdivision grid in joint multifrequency inversion. The proposed method introduces the attenuation factor, and by adjusting it, acoustic waves are sufficiently attenuated in the attenuation layer to minimize the cutoff boundary effect. Based on the law of exponential attenuation, expressions for computing the attenuation factor and the thickness of attenuation layers are derived for different frequencies. In multifrequency-domain FWI, the conjugate gradient method is used to solve equations in the Gauss-Newton algorithm and thus minimize the computation cost in calculating the Hessian matrix. In addition, the effect of initial model selection and frequency combination on FWI is analyzed. Examples using numerical simulations and FWI calculations are used to verify the efficiency of the proposed method. 展开更多
关键词 Full-waveform inversion rugged topography attenuation boundary condition finite element method
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Rugged Resonant Pole and Its Applications in Soft-Switching Converter
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作者 肖岚 严仰光 《Journal of Southeast University(English Edition)》 EI CAS 2002年第3期225-232,共8页
The soft switching operation principle and operation performance of rugged resonant pole (RRP) is given. The applications of RRP in soft switching DC DC converter and soft switching inverter are discussed in detail. R... The soft switching operation principle and operation performance of rugged resonant pole (RRP) is given. The applications of RRP in soft switching DC DC converter and soft switching inverter are discussed in detail. RRP can constitute buck boost soft switching DC DC converter and isolated soft switching DC DC converter with the automatic limitation performance of output power. Partial series resonant DC DC converter with RRP can realize the zero voltage/zero current switching of power devices. RR... 展开更多
关键词 rugged resonant pole soft switching DC DC converter INVERTER
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Plane-Wave Least-Squares Reverse Time Migration for Rugged Topography 被引量:7
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作者 Jianping Huang Chuang Li +1 位作者 Rongrong Wang Qingyang Li 《Journal of Earth Science》 SCIE CAS CSCD 2015年第4期471-480,共10页
We present a method based on least-squares reverse time migration with plane-wave encoding (P-LSRTM) for rugged topography. Instead of modifying the wave field before migration, we modify the plane-wave encoding fun... We present a method based on least-squares reverse time migration with plane-wave encoding (P-LSRTM) for rugged topography. Instead of modifying the wave field before migration, we modify the plane-wave encoding function and fill constant velocity to the area above rugged topography in the model so that P-LSRTM can be directly performed from rugged surface in the way same to shot domain reverse time migration. In order to improve efficiency and reduce I/O (input/output) cost, the dynamic en- coding strategy and hybrid encoding strategy are implemented. Numerical test on SEG rugged topography model show that P-LSRTM can suppress migration artifacts in the migration image, and compensate am- plitude in the middle-deep part efficiently. Without data correction, P-LSRTM can produce a satisfying image of near-surface if we could get an accurate near-surface velocity model. Moreover, the pre-stack P- LSRTM is more robust than conventional RTM in the presence of migration velocity errors. 展开更多
关键词 least-squares migration rugged topography plane-wave encoding dynamic encoding hybrid encoding.
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Distributed modeling of direct solar radiation on rugged terrain of the Yellow River Basin 被引量:4
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作者 ZENG Yan QIU Xinfa +1 位作者 LIU Changming JIANG Aijun 《Journal of Geographical Sciences》 SCIE CSCD 2005年第4期439-447,共9页
Due to the influences of local topographical factors and terrain inter-shielding, calculation of direct solar radiation (DSR) quantity of rugged terrain is very complex. Based on digital elevation model (DEM) data... Due to the influences of local topographical factors and terrain inter-shielding, calculation of direct solar radiation (DSR) quantity of rugged terrain is very complex. Based on digital elevation model (DEM) data and meteorological observations, a distributed model for calculating DSR over rugged terrain is developed. This model gives an all-sided consideration on factors influencing th a resolution of 1 km × 1 km for thDSR. Using the developed model, normals of annual DSR quantity wie Yellow River Basin was generated, with DEM data as the general characterization of terrain. Characteristics of DSR quantity influenced by geographic and topographic factors over rugged terrain were analyzed thoroughly. Results suggest that: influenced by local topographic factors, i.e. azimuth, slope and so on, and annual DSR quantity over mountainous area has a clear spatial difference; annual DSR quantity of sunny slope (or southern slope) of mountains is obviously larger than that of shady slope (or northern slope). The calculated DSR quantity of the Yellow River Basin is provided in the same way as other kinds of spatial information and can be employed as basic geographic data for relevant studies as well. 展开更多
关键词 direct solar radiation (DSR) rugged terrain digital elevation model (DEM) distributed model Yellow River Basin
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Distributed Modeling of Extraterrestrial Solar Radiation Over the Rugged Terrains of Pakistan 被引量:3
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作者 Romana AMBREEN QIU Xinfa Iftikhar AHMAD 《Journal of Mountain Science》 SCIE CSCD 2011年第3期427-436,共10页
In Pakistan,the solar analogue has been addressed but its surface geographical parameterization has given least attention.Inappropriate density of stations and their spatial coverage particularly in difficult peripher... In Pakistan,the solar analogue has been addressed but its surface geographical parameterization has given least attention.Inappropriate density of stations and their spatial coverage particularly in difficult peripheral national territories,little or no solar radiation data,non-satisfactory sunshine hours data,and low quality of ground observed cloud cover data create a situation in which the spatial modeling of Extraterrestrial Solar Radiation(ESR) and its ground parameterization got sufficient scope.The Digital Elevation Model (DEM) input into Geographic Information System (GIS) is a compatible tool to demonstrate the spatial distribution of ESR over the rugged terrains of the study domain.For the first time,distributed modeling of ESR is done over the rugged terrains of Pakistan,based on DEM and ArcGIS..Results clearly depict that the complex landforms profoundly disrupt the zonal distribution of ESR in Pakistan.The screening impact of topography is higher on spatial distribution of ESR in winter and considerably low in summer.The combined effect of topography and latitude is obvious.Hence,the model was further testified by plotting Rb (ratio of ESR quantity over rugged terrain against plane surface) against azimuth at different latitudes with different angled slopes.The results clearly support the strong screening effect of rugged terrain through out the country especially in Himalayas,Karakoram and Hindukush (HKH),western border mountains and Balochistan Plateau.This model can be instrumental as baseline geospatial information for scientific investigations in Pakistan,where substantial fraction of national population is living in mountainous regions. 展开更多
关键词 Pakistan distributed modeling ESR DEM GIS rugged terrain
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RUGⅢ:一种新的支付医疗费用的慢性病例分类模式 被引量:2
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作者 张宝库 侯延武 +3 位作者 王桂玲 栾淑珍 赵瑞 卢国华 《中国卫生事业管理》 1994年第10期528-531,共4页
RUGⅢ:一种新的支付医疗费用的慢性病例分类模式中国医院管理杂志社(150036)张宝库,侯延武,王桂玲黑龙江省医院栾淑珍中国卫生信息报社赵瑞兴隆林业局第二职工医院卢国华在医疗保险和社会福利制度中,设计能合理补偿供给... RUGⅢ:一种新的支付医疗费用的慢性病例分类模式中国医院管理杂志社(150036)张宝库,侯延武,王桂玲黑龙江省医院栾淑珍中国卫生信息报社赵瑞兴隆林业局第二职工医院卢国华在医疗保险和社会福利制度中,设计能合理补偿供给医疗服务所需成本的医疗费用支付方式... 展开更多
关键词 医院改革 医疗制度 医疗费用 rug
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Core-Germplasm Construction of <i>Rosa rugosa</i>Collections by CDDP Molecular Markers 被引量:2
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作者 Liyuan Jiang Dekui Zang 《Open Journal of Applied Sciences》 2017年第11期635-645,共11页
A method for constructing core-germplasm of Rosa rugosa in China based on molecular marker data was probed and the optimum core germplasm was established. Studies were initiated to analyze the genetic diversity of 120... A method for constructing core-germplasm of Rosa rugosa in China based on molecular marker data was probed and the optimum core germplasm was established. Studies were initiated to analyze the genetic diversity of 120 rugged roses from 6 different Chinese source populations based on CDDP marker, and a preliminary construction of the core collection was established using stepwise UPGMA clustering sampling method. The 26 core collection resources of R. rugosa collections in China have 20% germplasm samples of initial collection, the retention ratio of polymorphic loci, effective number of alleles (Ne), Nei’s genetic diversity (H) and Shannon information index (I) were respectively 97.52%, 104.16%, 108.38% and 106.18%. The results of t-test showed that no significant difference was found in genetic diversity indexes between the core collection and the original collection. These results also demonstrated that the core collection could stand for original collection excellently. The results show that CDDP molecular technology can be successfully applied to the construction of core germplasm resources of rugged roses. 展开更多
关键词 rugged Rose in China CDDP Markers Genetic Diversity CORE Collection
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Application of Gaussian beam pre-stack depth migration in rugged seabed
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作者 HAN Fuxing YI Xin +3 位作者 SUN Zhangqing HU Jia XU Baoyin XU Hai 《Global Geology》 2021年第2期119-128,共10页
Strong fluctuation of seabed,abrupt variation in depth and dip of seabed bring seismic imaging problems,such as irregular reflection waves,obvious multiple waves,serious lateral wave development,poor imaging on base s... Strong fluctuation of seabed,abrupt variation in depth and dip of seabed bring seismic imaging problems,such as irregular reflection waves,obvious multiple waves,serious lateral wave development,poor imaging on base surface and depression structure,low signal-to-noise ratio of middle and deep layers.In this paper,Gaussian beam migration imaging method is used to analyze the imaging effect of rugged seabed in deep water area,and the ray tracing method of wavefront construction method is used to analyze the kinematic characteristics of seismic waves.By improving the design of seismic data acquisition and observation system,imaging quality of fine structures is improved. 展开更多
关键词 Gaussian beam migration wavefront construction method Gaussian beam pre-stack depth rugged seabed
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户外爱好者挚爱 Lacia Rugged XL移动硬盘
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《数码》 2009年第5期34-34,共1页
不管做什么都讲究专业.哪怕是移动硬盘这样的小东西。对于户外爱好者和探险家来说.拥有一款可以和JEEP媲美的移动硬盘同样重要。它必须拥有结实的外表.舒适的使用环境,超强的速度体验.能够克服任何恶劣的环境,它就是来自法国莱希L... 不管做什么都讲究专业.哪怕是移动硬盘这样的小东西。对于户外爱好者和探险家来说.拥有一款可以和JEEP媲美的移动硬盘同样重要。它必须拥有结实的外表.舒适的使用环境,超强的速度体验.能够克服任何恶劣的环境,它就是来自法国莱希Lacie的移动硬盘Rugged XL——探路者。 展开更多
关键词 移动硬盘 使用环境 Lacia rugged XL
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Stanton Rug公司推出家用系列地毯
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《纺织装饰科技》 2003年第4期27-27,共1页
在今年7月13日至16日的亚特兰大国际区域地毯展上,Stanton Rug公司介绍了一种配套家用系列区域地毯,它是长方形,阔幅的地毯,图案设计是新颖的。据国家地毯销售经理Mike Shupp讲:'我们的配套地毯产品的推出是非常成功的,它将满足各... 在今年7月13日至16日的亚特兰大国际区域地毯展上,Stanton Rug公司介绍了一种配套家用系列区域地毯,它是长方形,阔幅的地毯,图案设计是新颖的。据国家地毯销售经理Mike Shupp讲:'我们的配套地毯产品的推出是非常成功的,它将满足各种不同的需要'。 Stanton公司新设计地毯Royal Sovereign系列中包括下列几个名称的地毯: Anastasia:是100%新西兰羊毛地毯,有两种色彩:深暗蓝色及紫红色,地毯的尺寸有:5′×8′,8′×10′,10′×13′及2′6″×8′的长形地毯。 Catherine:是100%新西兰羊毛。 展开更多
关键词 Stanton rug公司 家用系列地毯 产品设计 Anastasia Catherine 产品规格
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Distributed modeling of monthly air temperatures over the rugged terrain of the Yellow River Basin 被引量:12
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作者 ZENG Yan QIU XinFa +2 位作者 HE YongJian SHI GuoPing LIU ChangMing 《Science China Earth Sciences》 SCIE EI CAS 2009年第5期694-707,共14页
Our analyses of the monthly mean air temperature of meteorological stations show that altitude, global solar radiation and surface effective radiation have a significant impact on air temperature. We set up a physical... Our analyses of the monthly mean air temperature of meteorological stations show that altitude, global solar radiation and surface effective radiation have a significant impact on air temperature. We set up a physically-based empirical model for monthly air temperature simulation. Combined the proposed model with the distributed modeling results of global solar radiation and routine meteorological observation data, we also developed a method for the distributed simulation of monthly air temperatures over rugged terrain. Spatial distribution maps are generated at a resolution of 1 km×1 km for the monthly mean, the monthly mean maximum and the monthly mean minimum air temperatures for the Yellow River Basin. Analysis shows that the simulation results reflect to a considerable extent the macro and local distribution characteristics of air temperature. Cross-validation shows that the proposed model displays good stability with mean absolute bias errors of 0.19°C–0.35°C. Tests carried out on local meteorological station data and case year data show that the model has good spatial and temporal simulation capacity. The proposed model solely uses routine meteorological data and can be applied easily to other regions. 展开更多
关键词 YELLOW RIVER BASIN MONTHLY mean air temperature rugged TERRAIN DISTRIBUTED modeling
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Modeling the land surface reflectance for optical remote sensing data in rugged terrain 被引量:12
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作者 WEN JianGuang LIU QinHuo +2 位作者 XIAO Qing LIU Qiang LI XiaoWen 《Science China Earth Sciences》 SCIE EI CAS 2008年第8期1169-1178,共10页
A model for topographic correction and land surface reflectance estimation for optical remote sensing data in rugged terrian is presented.Considering a directional-directional reflectance that is used for direct solar... A model for topographic correction and land surface reflectance estimation for optical remote sensing data in rugged terrian is presented.Considering a directional-directional reflectance that is used for direct solar irradiance correction and a hemispheric-directional reflectance that is used for atmospheric diffuse irradiance and terrain background reflected irradiance correction respectively,the directional reflectance-based model for topographic effects removing and land surface reflectance calculation is developed by deducing the directional reflectance with topographic effects and using a radiative transfer model.A canopy reflectance simulated by GOMS model and Landsat/TM raw data covering Jiangxi rugged area were taken to validate the performance of the model presented in the paper.The validation results show that the model presented here has a remarkable ability to correct topography and estimate land surface reflectance and also provides a technique method for sequently quantitative remote sensing application in terrain area. 展开更多
关键词 bidirectional reflectance topographic/atmospheric correction SKY DIFFUSE IRRADIANCE ADJACENT terrain-reflected IRRADIANCE rugged area
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QuEChERS-液相色谱串联高分辨质谱法检测果蔬中34种农药残留 被引量:1
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作者 罗景阳 周长民 +5 位作者 刘鑫 袁帅 李巧莲 李娇 张承昕 王岩松 《食品研究与开发》 2025年第13期165-176,共12页
采用QuEChERS(quick,easy,cheap,effective,rugged and safe)-液相色谱串联高分辨质谱法建立蔬菜水果样品中34种农药残留的检测方法,并建立数据库。样品提取条件为4 g无水硫酸镁、1.5 g无水乙酸钠、1 g氯化钠和10 mL乙腈(1%乙酸),净化... 采用QuEChERS(quick,easy,cheap,effective,rugged and safe)-液相色谱串联高分辨质谱法建立蔬菜水果样品中34种农药残留的检测方法,并建立数据库。样品提取条件为4 g无水硫酸镁、1.5 g无水乙酸钠、1 g氯化钠和10 mL乙腈(1%乙酸),净化剂条件为10 mg石墨化碳黑、500 mg乙二胺-N-丙基硅烷化硅胶、600 mg MgSO_(4)和200 mg C_(18),在乙腈-水流动相条件下,选择C_(18)色谱柱进行目标物分离,采用一级全扫描-触发二级全扫描模式进行检测,检测结果通过保留时间、一级精确分子质量和二级碎片进行定性,通过一级精确分子质量对样品进行定量,以韭菜、菠菜、茄子、葡萄、桃和香蕉为代表样品,采用基质匹配标准曲线法进行定量。结果表明,各农药在相应线性范围内呈现良好的线性关系,R2均大于0.99,检出限为1~5μg/kg,定量限为2~10μg/kg,回收率为70.06%~119.79%,精密度为0.23%~13.77%。该方法具有简便快速、准确度高、灵敏度好的特点,适用于蔬菜水果中34种农药的检测。 展开更多
关键词 农药残留 高分辨质谱 QuEChERS(quick EASY cheap effective rugged and safe) 水果 蔬菜
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前处理新技术DMsPE与传统QuEChERS技术在果蔬中烟碱类农残检测应用效果比较
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作者 王丹 管益涛 +2 位作者 孙广雷 史亚萍 李勤 《中国卫生工程学》 2025年第4期444-447,451,共5页
目的比较分散微固相萃取(DMsPE)与分散固相萃取(QuEChERS)技术在烟碱类农药残留检测前处理应用的效果,从而获得更快速、简便、回收率高、最低溶剂耗损的前处理手段。方法通过对潍坊市市售蔬菜水果中3种烟碱类农药(环氧虫啶、噻虫嗪、吡... 目的比较分散微固相萃取(DMsPE)与分散固相萃取(QuEChERS)技术在烟碱类农药残留检测前处理应用的效果,从而获得更快速、简便、回收率高、最低溶剂耗损的前处理手段。方法通过对潍坊市市售蔬菜水果中3种烟碱类农药(环氧虫啶、噻虫嗪、吡虫啉)分析检测,使用DMsPE与QuEChERS前处理技术,对检测结果进行比对分析。结果实验数据显示,传统QuEChERS前处理技术和DMsPE技术在果蔬空白基质中平均加标回收率分别为74.7%~108.0%、89.6%~105.0%,RSD分别为0.29%~14.70%、0.11%~5.26%,QuEChERS技术处理后的LOD值为0.001~0.002 mg/kg,DMsPE技术下的LOD值为0.001 mg/kg。在不同果蔬种类基质中,QuEChERS技术的基质效应为0.97~1.78,DMsPE技术的基质效应为0.96~1.82。结论较传统QuEChERS技术,DMsPE有较好的回收率和重复性表现。对于不同基质,DMsPE的测定数值中基质效应有一定程度的减弱,且DMsPE前处理技术使用提取溶剂量较小,降低实验室环境负荷,方法简便易操作,可以满足精准度的实验需求,针对果蔬中烟碱类农残检测的各项指标也均符合国标要求。 展开更多
关键词 分散微固相萃取 分散固相萃取 果蔬 烟碱类 应用效果比较
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QuEChERS结合超高效液相色谱-串联质谱法测定茶叶中18种全氟化合物
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作者 孙维扬 揣雨静 +5 位作者 周晓涛 张添艾 雍莉 任琳 罗新月 邹晓莉 《四川大学学报(医学版)》 北大核心 2025年第5期1215-1225,共11页
目的建立一种基于QuEChERS前处理技术,结合超高效液相色谱-串联质谱同时测定茶叶中18种全氟化合物(perfluorinated compounds,PFCs)的分析方法。方法检测的18种PFCs包括13种全氟羧酸类:全氟丁酸、戊酸、己酸、庚酸、辛酸、壬酸、癸酸、... 目的建立一种基于QuEChERS前处理技术,结合超高效液相色谱-串联质谱同时测定茶叶中18种全氟化合物(perfluorinated compounds,PFCs)的分析方法。方法检测的18种PFCs包括13种全氟羧酸类:全氟丁酸、戊酸、己酸、庚酸、辛酸、壬酸、癸酸、十一酸、十二酸、十三酸、十四酸、十六酸及十八酸;以及5种全氟磺酸类:全氟丁烷磺酸、己烷磺酸、庚烷磺酸、辛烷磺酸和癸烷磺酸。采用响应面法系统优化QuEChERS前处理条件。茶叶样品采用80%乙腈溶液提取后,加入20 mg N-丙基乙二胺(PSA)、210 mg石墨化碳黑(GCB)和60 mg十八烷基硅烷(octadecylsilane,C18)混合吸附剂进行净化,取上清液氮吹浓缩,50%甲醇-2 mmol/L乙酸铵溶液复溶,采用ACQUITY UPLC BEH C18色谱柱(2.1 mm×50 mm,1.7μm)分离,流动相由甲醇(A相)和2 mmol/L乙酸铵水溶液(B相)构成,采用洗脱梯度,总运行时间为18 min。采用电喷雾电离源负离子模式和多反应监测模式进行质谱测定,内标标准曲线法定量。同时采用AGREE和Analytical Eco-Scale算法评估方法绿色性。结果18种PFCs的方法检出限为0.0057~1.23 ng/g,定量限为0.019~4.09 ng/g,大部分化合物的平均回收率为71.1%~117.9%,相对标准偏差<15%。方法的AGREE评分为0.49,Analytical Eco-Scale得分为76。在132份茶叶样品中均检出至少1种PFC,全氟羧酸的检出率高于全氟磺酸,其中全氟丁酸、全氟庚酸和全氟辛酸的检出率最高,分别为97.74%、93.23%和92.24%;全氟庚烷磺酸、全氟十一酸、全氟十二酸、全氟十六酸和全氟十八酸未检出。结论本研究建立的方法具有简单、快速、灵敏的优点,适用于茶叶中18种全氟化合物的同时检测,且该方法绿色性较高,对操作者和环境影响较小。市售茶叶中PFCs污染普遍存在,应加强监督和管控。 展开更多
关键词 全氟化合物 茶叶 QUECHERS 超高效液相色谱-串联质谱 响应曲面方法
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QuEChERS结合超高效液相色谱-串联质谱法检测鲫鱼中11种邻苯二甲酸单酯
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作者 张帅 王钰 +8 位作者 谢鹏飞 刘会佳 陈莉君 黄以超 刘开永 周典兵 刘宇欣 刘旭 宋伟 《食品科学》 北大核心 2025年第19期281-289,共9页
开发基于QuEChERS法的鲫鱼中邻苯二甲酸单酯(phthalate monoesters,mono-PAEs)的快速前处理体系,结合超高效液相色谱-串联质谱(ultra-high performance liquid chromatography-tandem mass spectrometry,UPLCMS/MS)建立多残留检测方法... 开发基于QuEChERS法的鲫鱼中邻苯二甲酸单酯(phthalate monoesters,mono-PAEs)的快速前处理体系,结合超高效液相色谱-串联质谱(ultra-high performance liquid chromatography-tandem mass spectrometry,UPLCMS/MS)建立多残留检测方法。鱼肉样品(1.00 g)经98%乙腈甲酸提取,QuEChERS净化,氮吹近干,乙腈∶水(1∶1,V/V)溶液复溶,过膜,进样分析。11种mono-PAEs均有良好的线性关系(决定系数R2≥0.999 03);检出限和定量限分别为3.00μg/kg和10.00μg/kg;在10、20、100、200μg/kg添加量水平下的加标回收实验中,monoPAEs在鱼肉中的回收率范围分别为68.12%~109.93%、74.43%~112.46%、84.92%~109.48%和82.18%~108.92%,相对标准偏差分别为1.06%~8.50%、0.82%~4.07%、0.63%~2.14%和0.79%~2.66%。该方法重现性良好且回收率符合检测要求,具有操作简便、灵敏度高等特点,可满足鲫鱼基质中多种mono-PAEs的痕量分析需求。 展开更多
关键词 邻苯二甲酸单酯 鲫鱼 超高效液相色谱-串联质谱 QUECHERS
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HNN4RP:基于异构图神经网络的以太坊地毯拉动骗局检测
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作者 李晨晨 金海 +1 位作者 吴敏睿 肖江 《电子与信息学报》 北大核心 2025年第10期3395-3409,共15页
去中心化金融(DeFi)依托区块链技术,实现了金融交易和服务的去中心化,重塑了传统金融体系中的信任机制,成为近年来学术界和工业界的研究热点。然而,DeFi的开放性、匿名性和无需许可的特征,虽然赋予用户更大的灵活性和自主权,但也带来了... 去中心化金融(DeFi)依托区块链技术,实现了金融交易和服务的去中心化,重塑了传统金融体系中的信任机制,成为近年来学术界和工业界的研究热点。然而,DeFi的开放性、匿名性和无需许可的特征,虽然赋予用户更大的灵活性和自主权,但也带来了严峻的监管挑战,导致金融欺诈行为频发,尤其是地毯拉动骗局(Rug Pull)屡见不鲜。针对这一问题,该文提出一种基于异构图神经网络的地毯拉动骗局早期检测算法(HNN4RP),用于识别和预警DeFi生态中的地毯拉动骗局。具体而言,将以太坊交易数据建模为异构图,并结合重启随机游走采样策略、异构节点特征提取技术和基于双向长短期记忆网络的时序特征融合方法,以有效应对数据分布不均、异构节点特征提取困难以及时序信息缺失等3大关键挑战。实验结果表明,通过在真实的以太坊数据集上,HNN4RP取得了96%的精确率和94%的召回率,相较于基线方法精确率提升了17.8%,显著优于传统检测方法,并能够提供及时的欺诈预警。此外,消融实验和敏感性分析验证了模型的鲁棒性。 展开更多
关键词 区块链 以太坊 去中心化金融 图神经网络 地毯拉动骗局
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高效液相色谱-串联质谱检测谷物中二乙酰镳草镰刀菌烯醇含量方法研究 被引量:1
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作者 陆秀青 伍先绍 +5 位作者 韦云莹 农子明 马炜烨 林卉 潘药银 胡蓉 《中国粮油学报》 北大核心 2025年第3期179-183,共5页
通过对高效液相色谱-串联质谱检测谷物中二乙酰镳草镰刀菌烯醇含量测定的研究,建立了谷物中二乙酰镳草镰刀菌烯醇含量的测定方法。采用体积分数1%乙酸的乙腈溶液(乙腈与水的体积比为8∶2)混合溶液提取,结合QuEChERS前处理提取方法,用体... 通过对高效液相色谱-串联质谱检测谷物中二乙酰镳草镰刀菌烯醇含量测定的研究,建立了谷物中二乙酰镳草镰刀菌烯醇含量的测定方法。采用体积分数1%乙酸的乙腈溶液(乙腈与水的体积比为8∶2)混合溶液提取,结合QuEChERS前处理提取方法,用体积分数0.1%的甲酸水相和乙睛有机相进行梯度洗脱,经多反应监测模式测定样品中的目标化合物,采用外标法定量。方法学性能考察表明,在质量浓度0.2~10.0 ng/mL范围内具有良好的线性关系,相关系数大于0.998;方法检出限为0.07~0.13μg/kg,定量限为0.25~0.44μg/kg;方法的回收率范围为81.5%~107.9%,变异系数范围为0.39%~3.29%。经验证确定该方法线性良好,灵敏度高,重复性好,结果准确可靠,符合GB/T 27417—2017《合格评定化学分析方法确认和验证指南》的要求,可为科学评价谷物中二乙酰镳草镰刀菌烯醇的污染监测情况分析提供技术依据。 展开更多
关键词 二乙酰镳草镰刀菌烯醇 谷物 QUECHERS 高效液相色谱-串联质谱
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