This paper investigated the effects of root-zone (RZ) CO<sub>2</sub> concentration ([CO<sub>2</sub>]) on root morphology and growth, nitrate (NO<sub>3</sub>-</sup>) uptake and...This paper investigated the effects of root-zone (RZ) CO<sub>2</sub> concentration ([CO<sub>2</sub>]) on root morphology and growth, nitrate (NO<sub>3</sub>-</sup>) uptake and assimilation of lettuce plants at different root-zone temperatures (RZT). Elevated RZ [CO<sub>2</sub>] stimulated root development, root and shoot growth compared to ambient RZ [CO<sub>2</sub>]. The greatest increase in root growth was observed in plants grown under elevated RZ [CO<sub>2</sub>] of 50,000 ppm. However, RZ [CO<sub>2</sub>] of 10,000 ppm was sufficient to achieve the maximal leaf area and shoot productivity. Lettuce plants exhibited faster shoot and root growth at 20°C-RZT than at ambient (A)-RZT. However, under elevated RZ [CO<sub>2</sub>], the magnitude of increased growth was greater at A-RZT than at 20°C-RZT. Compared to RZ [CO<sub>2</sub>] of 360 ppm, elevated RZ [CO<sub>2</sub>] of 10,000 ppm increased NO<sub>3</sub>-</sup> accumulation and nitrate reductase activity (NRA) in both leaves and roots. NO<sub>3</sub>-</sup> concentrations of leaf and root were higher at 20°C-RZT than at A-RZT in all plants. NRA was higher in root than in leaf especially under A-RZT. The total reduced nitrogen (TRN) concentration was significantly higher in plants grown under elevated RZ [CO<sub>2</sub>] of 10,000 ppm than under ambient RZ [CO<sub>2</sub>] of 360 ppm with greater concentration in 20°C-RZT plants than in A-RZT plants. These results imply that elevated RZ [CO<sub>2</sub>] significantly affected root morphology, root and shoot growth and N metabolism of temperate lettuce with greater impacts at A-RZT than at 20°C-RZT. These findings have practical significance to vegetable production by growing the vegetable crops at cool-RZT with elevated RZ [CO<sub>2</sub>] to enhance its productivity.展开更多
Although tropical high ambient temperature and humidity severely reduced the productivity of temperate plants, temperate vegetable crops such as lettuce have been successfully grown in Singapore by only cooling its ro...Although tropical high ambient temperature and humidity severely reduced the productivity of temperate plants, temperate vegetable crops such as lettuce have been successfully grown in Singapore by only cooling its root-zone. In this paper, a cool Meditteranean vegetable, Eruca sativa, was studied to understand how different RZTs can impact its shoot productivity, photosynthesis and nutritional quality. All plants were cultivated using aeroponic systems in a tropical greenhouse under hot ambient conditions where roots were subjected to four different root-zone temperatures (RZTs) of 20°C-RZT, 25°C-RZT, 30°C-RZT and fluctuating ambient temperatures ranged from 25°C to 38°C [25°C/38°C (ambient)]-RZT. Parameters studied include shoot fresh weight (FW), photosynthetic gas exchange, midday chlorophyll (Chl) fluorescence F<sub>v</sub>/F<sub>m</sub> ratio, Chl fluorescence photochemical quenching (qP), non-photochemical quenching (qN) and electron transport rate (ETR), total phenolic compounds and mineral content such as potassium (K), calcium (Ca), magnesium (Mg) and iron (Fe). Among the 4 different RZT treatments, E. sativa plants grown under ambient-RZT (25/38°C-RZT) had the lowest shoot and root FW while those plants grown under 20°C-RZT had highest productivity of shoot and root. However, there were no significant differences in shoot and root FW in plants grown at 25°C- and 30°C-RZT. Compared to plants grown under 25°C/38°C (ambient-RZT), light-saturated photosynthetic CO<sub>2</sub> assimilation rate (A<sub>sat</sub>) and stomatal conductance (g<sub>ssat</sub>) were similarly higher in 20°C-, 25°C- and 30°C-RZT. All plants had midday Chl fluorescence F<sub>v</sub>/F<sub>m</sub> ratio lower than <0.8 ranged from 0.785 to 0.606 with the highest and lowest ratios recorded in 20°C-RZT and ambient-RZT plants, respectively. These results indicate that cooling the RZ of E. sativa plants protected their PS II from photoinactivation during midday in the greenhouse. There were no significant differences observed in photochemical quenching (qP), non-photochemical quenching (qN) and electron transport rate among plants grown under 20°C-, 25°C- and 30°C-RZT. However, plants grown under ambient-RZT had lower qP, qN and ETR compared to all other plants. E. sativa at 20°C-RZT with the best developed roots had the highest dietary mineral (K, Mg, Ca and Fe) contents but lower total phenolics content. In contrast, ambient-RZT, plants with poorly developed roots had the lowest mineral content but highest total phenolic content. The results of this study suggest that cooling of roots is a feasible method for the cultivation of E. sativa in the tropic, which enhances the content of dietary minerals in shoots.展开更多
Soil temperature influences crop growth and quality under field and greenhouse conditions;however, precise investigation using controlled cultivation systems is largely lacking. We investigated effects of root-zone te...Soil temperature influences crop growth and quality under field and greenhouse conditions;however, precise investigation using controlled cultivation systems is largely lacking. We investigated effects of root-zone temperatures on growth and components of hydroponically grown red leaf lettuce (Lactuca sativa L. cv. Red Wave) under a controlled cultivation system at 20°C. Compared with ambient root-zone temperature exposure, a 7-day low temperature exposure reduced leaf area, stem size, fresh weight, and water content of lettuce. However, root-zone heating treatments produced no significant changes in growth parameters compared with ambient conditions. Leaves under low root-zone temperature contained higher anthocyanin, phenols, sugar, and nitrate concentrations than leaves under other temperatures. Root oxygen consumption declined with low temperature root exposure, but not with root heating. Leaves of plants under low rootzone temperature showed hydrogen peroxide production, accompanied by lipid peroxidation. Therefore, low temperature root treatment is suggested to induce oxidative stress responses in leaves, activating antioxidative secondary metabolic pathways.展开更多
Air and soil temperatures strongly influence the growth and quality of crops. However, in root vegetables, such as carrot, few experiments aimed at regulating growth and quality by manipulating root-zone temperature h...Air and soil temperatures strongly influence the growth and quality of crops. However, in root vegetables, such as carrot, few experiments aimed at regulating growth and quality by manipulating root-zone temperature have been reported. We investigated the effect of root-zone temperatures (20°C, 25°C, 29°C, and 33°C) on carrot growth and components using a hydroponic system. High root-zone temperatures for 14 days reduced shoot and rootgrowth and water content. In contrast, total phenolic compounds and soluble-solid content increased in tap roots under high-temperature treatment. Root oxygen consumption was upregulated after 7 days under high-temperature treatment. These results suggest that high root-zone temperatures induce drought-like stress responses that modulate carrot biomass and components. High root-zone temperature treatments administered to hydroponically grown crops may be a valuable tool for improving and increasing the quality and value of crops.展开更多
Platinum group metals have high melting points,strong corrosion resistance,stable chemical properties,and low oxygen permeability in high-temperature oxygen-containing environments.As thermal protective coating materi...Platinum group metals have high melting points,strong corrosion resistance,stable chemical properties,and low oxygen permeability in high-temperature oxygen-containing environments.As thermal protective coating materials,they have gained essential applications in the aerospace field and have excellent prospects for application in frontier military fields,such as protecting hot-end components of hypersonic aircraft.This research reviewed the latest research progress of platinum group metal coatings with hightemperature oxidation resistance,including coating preparation techniques,oxidation failure,and alloying modification.The leading preparation techniques of current platinum group metal coatings were discussed,as well as the advantages and disadvantages of various existing preparation techniques.Besides,the intrinsic properties,failure forms,and failure mechanisms of coatings of single platinum group metal in high-temperature oxygen-containing environments were analyzed.On this basis,the necessity,main methods,and main achievements of alloying modification of platinum group metals were summarized.Finally,the future development of platinum group coatings with high-temperature oxidation resistance was discussed and prospected.展开更多
In recent years,the research on superconductivity in one-dimensional(1D)materials has been attracting increasing attention due to its potential applications in low-dimensional nanodevices.However,the critical temperat...In recent years,the research on superconductivity in one-dimensional(1D)materials has been attracting increasing attention due to its potential applications in low-dimensional nanodevices.However,the critical temperature(T_(c))of 1D superconductors is low.In this work,we theoretically investigate the possible high T_(c) superconductivity of(5,5)carbon nanotube(CNT).The pristine(5,5)CNT is a Dirac semimetal and can be modulated into a semiconductor by full hydrogenation.Interestingly,by further hole doping,it can be regulated into a metallic state with the sp^(3)-hybridized σ electrons metalized,and a giant Kohn anomaly appears in the optical phonons.The two factors together enhance the electron–phonon coupling,and lead to high-T_(c) superconductivity.When the hole doping concentration of hydrogenated-(5,5)CNT is 2.5 hole/cell,the calculated T_(c) is 82.3 K,exceeding the boiling point of liquid nitrogen.Therefore,the predicted hole-doped hydrogenated-(5,5)CNT provides a new platform for 1D high-T_(c) superconductivity and may have potential applications in 1D nanodevices.展开更多
Spikelet filling characteristics in early-season rice in southern China may be distinctive due to its exposure to high temperatures during the ripening period.However,limited information is currently available on thes...Spikelet filling characteristics in early-season rice in southern China may be distinctive due to its exposure to high temperatures during the ripening period.However,limited information is currently available on these characteristics.This study aimed to characterize spikelet filling in early-season rice and identify the key factors contributing to its improvement.Field experiments were conducted over two years(2021 and 2022)to mainly investigate the proportions of fully-filled,partially-filled,and empty spikelets,along with the biomass-fertilized spikelet ratio and harvest index,in 11 early-season rice varieties.The results revealed significant varietal variation in spikelet filling,with the proportion of fully-filled spikelets ranging from 60.6%to 81.1%in 2021 and from 66.3%to 79.2%in 2022.Among the 11 varieties,Liangyou 42,Lingliangyou 942,and Liangyou 287 exhibited relatively superior performance in spikelet filling.Linear regression revealed that,although a significant negative relationship existed between the proportion of fully-filled spikelets and both partially-filled and empty spikelets,the relationship with partially-filled spikelets was stronger.Additionally,the proportion of fully-filled spikelets showed a significant positive relationship with the harvest index but not with the biomass-fertilized spikelet ratio.These findings indicate that increasing the harvest index and reducing the occurrence of partially-filled grains are essential strategies for improving spikelet filling in early-season rice.展开更多
Prolonged exposure to n-butanol, a common hazardous volatile organic compound(VOC) in the environment, can lead to a broad range of adverse health effects. Therefore, detecting n-butanol safely and efficiently at low ...Prolonged exposure to n-butanol, a common hazardous volatile organic compound(VOC) in the environment, can lead to a broad range of adverse health effects. Therefore, detecting n-butanol safely and efficiently at low concentrations becomes critical for both environmental monitoring and human health. In this study, a novel Eu/Ce-codoped MOF-ZnO gas sensor was developed for the sensitive detection of n-butanol gas under ultraviolet activation at ambient temperature. A series of Eu/Ce-ZnO nanomaterials were synthesized via a simple co-precipitation route, by carefully designing the varied mass ratios of Eu and Ce incorporated into pristine ZnO derived from MOF precursors. The gas testing results revealed that introducing an appropriate amount of Eu and Ce would enlarge the specific surface area and enrich the oxygen vacancy content compared to pristine MOF-ZnO. Upon UV irradiation, the 0.03 wt% Eu 0.04 wt% Ce-ZnO sensor achieved a superior response of 611 for100 ppm n-butanol at room temperature, 15.28 times higher than that of pristine MOF-ZnO(40). Furthermore, the sensor presented rapid response/recovery times(15 s/28 s) and excellent selectivity. The above contributions pave the way for the promising development of highly sensitive, ultraviolet-enhanced gas sensors for ambient temperature detection of VOCs.展开更多
When the operating temperature of a solid oxide electrolysis cell(SOEC)is lower than the outlet temperature of a nuclear reactor,the reactor can be directly coupled with the SOEC as a high-temperature heat source.Howe...When the operating temperature of a solid oxide electrolysis cell(SOEC)is lower than the outlet temperature of a nuclear reactor,the reactor can be directly coupled with the SOEC as a high-temperature heat source.However,the key to the efficiency and return on investment of this hybrid energy system lies in the expected lifetime of the SOEC.This study assessed Ni-YSZ|YSZ|GDC|LSC fuel electrode support cells’long-term stability during electrolysis at 650℃with a current density of−0.5Acm^(−2)over 1818 h.The average voltage degradation rate of 2.63%kh^(−1)unfolded in two phases:an initial rapid decay(90 to 1120 h at 3.58%kh^(−1))and a stable decay(1120 to 1818 h at 2.14%kh^(−1)),emphasizing SOECs’probability coupling with nuclear reactors at 650℃.Post-1818-hour electrolysis revealed nickel particle formation associated with Ni(OH)_(x)diffusion and re-deposition,alongside a strontium-containing layer causing interface cracking.Despite minimal strontium segregation in the EDS,XPS data indicated surface segregation of Sr.This study provides crucial insights into prolonged SOEC operation,highlighting both its potential and challenges.展开更多
Following over 20 years of research,a direct measurement of the QGP temperature has been achieved at Relativistic Heavy-Ion Collider(RHIC),free from the blue-shift effect and contamination from strong interactions.Thi...Following over 20 years of research,a direct measurement of the QGP temperature has been achieved at Relativistic Heavy-Ion Collider(RHIC),free from the blue-shift effect and contamination from strong interactions.This viewpoint discusses a recent measurement of the QGP temperature at different stages at the Solenoidal Tracker at RHIC(STAR),which used e^(+)e^(-)pairs as penetrating probes.展开更多
This investigation utilizes non-equilibrium molecular dynamics(NEMD)simulations to explore shockinduced spallation in single-crystal tantalumacross shock velocities of 0.75–4 km/s and initial temperatures from300 to ...This investigation utilizes non-equilibrium molecular dynamics(NEMD)simulations to explore shockinduced spallation in single-crystal tantalumacross shock velocities of 0.75–4 km/s and initial temperatures from300 to 2000 K.Two spallation modes emerge:classical spallation for shock velocity below 1.5 km/s,with solid-state reversible Body-Centered Cubic(BCC)to Face-Centered Cubic(FCC)orHexagonal Close-Packed(HCP)phase transformations and discrete void nucleation-coalescence;micro-spallation for shock velocity above 3.0 km/s,featuring complete shock-induced melting and fragmentation,with a transitional regime(2.0-2.5 km/s)of partial melting.Spall strength decreases monotonically with temperature due to thermal softening.Elevated temperatures delay void nucleation but increase density,expanding spall regions and enhancing structural disorder with reduced BCC recovery.For microspallation,melting exacerbates damage,causing smaller voids and intensified atomic ejection,which increases with temperature.Free surface velocity profiles indicate damage:in classical spallation,first drop marks nucleation,and pullback signals spall layers.In micro-spallation,the first drop is irrelevant,but remains valid.Temperature delays pullback signals and weakens Hugoniot Elastic Limit.This study clarifies temperature-shock coupling in Ta spallation,aiding failure prediction in high-temperature shock environments.展开更多
Root-zone temperature(RZT)strongly affects plant growth,nutrient uptake and tolerance to environmental stress,making its regulation a key challenge in greenhouse cultivation in cold climates.This study aimed to assess...Root-zone temperature(RZT)strongly affects plant growth,nutrient uptake and tolerance to environmental stress,making its regulation a key challenge in greenhouse cultivation in cold climates.This study aimed to assess the potential of passive techniques,namely black polyethylene mulch and row covers,for modifying RZT dynamics in lettuce(Lactuca sativa L.)production and to evaluate the predictive performance of the eXtreme Gradient Boosting(XGBoost)algorithm.Experiments were conducted in Iğdır,Türkiye,over a 61-day period,with soil temperature continuously monitored at depths of 1-30 cm under mulched and non-mulched conditions,alongside measurements of greenhouse air temperature both with and without row covers.The application of row covers increased internal air temperature by 5.8℃,while mulching raised RZT by 0.6-1.3℃,with effects diminishing at deeper layers.XGBoost modeling achieved high predictive accuracy,with RMSE values of 0.150-0.189◦C and R^(2)values above 0.99,and feature-importance analysis indicated that neighboring soil depths were the strongest predictors of RZT.These findings show that integrating row covers and mulching can stabilize the root-zone microclimate without active heating.The XGBoost model provides a robust tool for forecasting soil temperature and supports sustainable greenhouse production in cold regions.展开更多
The glass transition temperature(T_(g))of styrene-butadiene rubber(SBR)is a key parameter determining its low-temperature flexibility and processing performance.Accurate prediction of T_(g)is crucial formaterial desig...The glass transition temperature(T_(g))of styrene-butadiene rubber(SBR)is a key parameter determining its low-temperature flexibility and processing performance.Accurate prediction of T_(g)is crucial formaterial design and application optimisation.Addressing the limitations of traditional experimental measurements and theoretical models in terms of efficiency,cost,and accuracy,this study proposes a machine learning prediction framework that integrates multi-model ensemble and Bayesian optimization by constructing a multi-component feature dataset and algorithm optimization strategy.Based on the constructed high-quality dataset containing 96 SBR samples,ninemachine learning models were employed to predict the T_(g)of SBR and compare their prediction performance.Ultimately,aGPR-XGBoost mixed model was constructed through model ensemble,achieving high-precision prediction with R^(2)values greater than 0.9 on both the training and test sets.Further feature attribution and local effect analysis were conducted using feature analysis methods such as SHAP and ALE,revealing the nonlinear influence patterns of various components on T_(g),providing a theoretical basis for SBR formulation design and T_(g)regulation.The machine learning prediction framework established in this study combines high-precision prediction with interpretability,significantly enhancing the prediction performance of the T_(g)of SBR.It offers an efficient tool for SBR molecular design and holds great potential for promotion and application.展开更多
This study presents a numerical investigation of the transient relaxation dynamics of a near-critical CO_(2)droplet immersed in a warmer supercritical environment composed of the same fluid.Three thermodynamic regimes...This study presents a numerical investigation of the transient relaxation dynamics of a near-critical CO_(2)droplet immersed in a warmer supercritical environment composed of the same fluid.Three thermodynamic regimes were analysed:quasi-critical(T_(r)=1.01,P_(r)=1.01),transitional(T_(r)=2.01,P_(r)=1.01),and deep supercritical(T_(r)=5.01,P_(r)=3.01).Theevolution of density,temperature,and velocity fieldswas examined to characterize the internal structure and stability of the interfacial transition layer.The evolution of density,temperature,and velocity fields highlights the competition between thermal diffusion,compressibility,andmass confinement in shaping the stability of the interfacial transition layer.Near the critical point,strong gradients and flux discontinuities emerge,consistent with known instabilities,whereas higher reduced conditions promote homogenization and stabilized transport.In the deep supercritical regime,smooth and nearly uniform fields indicate robust thermal stability.The model is validated against prior studies on droplet evaporation under supercritical and trans-critical conditions.Beyond theoretical insights,the results underline practical implications for advanced propulsion,heat transfer,and evaporation systems as well as for safe CO_(2)supercritical storage and extraction processes in energy,aerospace,pharmaceutical,and materials industries.展开更多
For red pear,the anthocyanin content is a crucial factor determining the fruit skin color,which affects consumer preferences.Low overnight temperatures promote anthocyanin accumulation,but the molecular mechanism resp...For red pear,the anthocyanin content is a crucial factor determining the fruit skin color,which affects consumer preferences.Low overnight temperatures promote anthocyanin accumulation,but the molecular mechanism responsible is unclear.In this study,‘Hongzaosu’pear(Pyrus pyrifolia×Pyrus communis)fruit were treated with a low nighttime temperature(LNT,16℃)or a warm nighttime temperature(WNT,26℃),with sampling conducted within two diurnal cycles.The results showed that LNT promoted anthocyanin accumulation in the fruit skin.The structural anthocyanin biosynthetic genes PpCHS,PpF3H,and PpUFGT exhibited a rhythmic increase in expression at night under LNT.To examine the underlying mechanism,RNA sequencing was conducted using pear calli exposed to LNT and WNT for different durations(24,48,72,or 96 h).Transcriptome analysis revealed 285 differentially expressed genes(DEGs)common to all pairwise comparisons of LNT-and WNT-treated calli of‘Clapp's Favorite’(P.communis)at the sampling time points.KEGG pathway and gene ontology enrichment analyses indicated that the common DEGs were enriched in secondary metabolic processes and phenylpropanoid metabolic processes,which are associated with anthocyanin biosynthesis.The transcription factor PpCDF5,which was responsive to LNT,was selected for further study.Dual-luciferase assays showed that PpCDF5 activated the transcription of anthocyanin biosynthetic genes PpMYB10,PpCHS,PpF3H,PpDFR,PpANS,and PpUFGT.The yeast one-hybrid and EMSA assays demonstrated that PpCDF5 directly binds to the PpF3H promoter,which contains an AAAG motif.Overexpression of PpCDF5 in pear calli and transient overexpression in pear fruit both increased anthocyanin accumulation.The results indicate that PpCDF5 is involved in LNT-induced anthocyanin biosynthesis in pear fruit and provide insights into the molecular regulation of commercial fruit coloration.展开更多
Temperature has a substantial impact on the emission of biogenic volatile organic compounds(BVOCs).Moder-ate warm temperatures,e.g.,30–40°C,could boost plant metabolism,increasing BVOC emissions.Against the back...Temperature has a substantial impact on the emission of biogenic volatile organic compounds(BVOCs).Moder-ate warm temperatures,e.g.,30–40°C,could boost plant metabolism,increasing BVOC emissions.Against the backdrop of global warming,plants emit more BVOCs to cope with thermal stress,leading to elevated concen-trations of tropospheric ozone(O_(3))and secondary organic aerosols(SOA).In recent years,a considerable body of research has explored the interaction between tree species and BVOCs under the influence of various environ-mental factors.Although many studies have examined explored the temperature dependence of BVOC emissions in the past,few studies have conducted a comprehensive and in-depth investigation into the impacts of tempera-ture.This review summarizes the relevant studies on BVOCs in the past decade,including the main biosynthetic pathways,emission observation techniques and emission inventories,as well as how temperature affects isoprene and monoterpene emission rates and the formation of O_(3) and SOA.Our work offers a theoretical foundation and guidance for future efforts to advance the comprehension of BVOC emission characteristics and develop strategies to mitigate secondary pollution.展开更多
The effect of real-time high temperature and thermal treatment on the mechanical characteristics and crack evolution of granite with different grain sizes(i.e.,0.5 mm,0.7 mm and 1.0 mm)is investigated by numerical sim...The effect of real-time high temperature and thermal treatment on the mechanical characteristics and crack evolution of granite with different grain sizes(i.e.,0.5 mm,0.7 mm and 1.0 mm)is investigated by numerical simulation employing a grain-based model,and the impact of initial cracks on thermal-induced strengthening is also examined by integrating random cracks within the model before tests.The results revealed that thermal stress,induced by the mismatch in thermal expansion coefficient between various minerals,is the primary distinction between rock specimens in real-time high temperature and thermal treatment.With increasing temperature,the thermal stress gradually accumulates in quartz minerals under real-time high temperature but releases after thermal treatment.The high local contact force significantly affects the peak stress and crack evolution.Uniaxial compression simulation results demonstrate that progressive accumulation of thermal stress induces degradation in macroscopic peak strength and increase of microcrack density.The grain size controls the ratio of intergranular contacts to intragranular contacts,and leads to an increase in strong contact number in the intragrain and a decrease in strong contact number in the intergrain.The strengthening of uniaxial compression strength in the experiment can be well simulated by controlling the number of pre-existing initial cracks in the numerical model.Our conclusions are beneficial to a better understanding of the underlying mechanisms of thermal damage and thermal strengthening of granite for deep geological engineering.展开更多
Thermal-mechanical damage and deformation at the interface between shotcrete linings and the surrounding rock of tunnels under high-temperature and variable-temperature conditions are critical to the safe construction...Thermal-mechanical damage and deformation at the interface between shotcrete linings and the surrounding rock of tunnels under high-temperature and variable-temperature conditions are critical to the safe construction and operation of tunnel engineering.This study investigated the thermo-mechanical damage behavior of the composite interface between alkali-resistant glass fiber-reinforced concrete(ARGFRC)and granite,focusing on a plateau railway tunnel.Laboratory triaxial tests,laser scanning,XRD analysis,numerical simulations,and theoretical analyses were employed to investigate how different initial curing temperatures and joint roughness coefficient(JRC)influence interfacial damage behavior.The results indicate that an increase in interface roughness exacerbates the structural damage at the interface.At a JRC of 19.9 and a temperature of 70℃,crack initiation in granite was notably restrained when the confining pressure rose from 7 MPa to 10 MPa.Roughness-induced stress distribution at the interface was notably altered,although this effect became less pronounced under high confining pressure conditions.Additionally,during high-temperature curing,thermal stress concentration at the tips of micro-convex protrusions on the granite surface induced microcracks in the adjacent ARGFRC matrix,followed by deformation.These findings provide practical guidelines for designing concrete support systems to ensure tunnel structural safety in high-altitude regions with harsh thermal environments.展开更多
Significant diurnal temperature variations in mountainous rack railways cause stiffness mismatches between the rack structure and simply supported bridges,leading to critical failures like bolt loosening and rack frac...Significant diurnal temperature variations in mountainous rack railways cause stiffness mismatches between the rack structure and simply supported bridges,leading to critical failures like bolt loosening and rack fractures.This study develops a dynamic model of the vehicle-rack-bridge system based on train-track-bridge interaction theory,integrating gear-rack meshing and wheel-rail contact mechanisms.The model analyzes the dynamic response of bridges with varying spans under combined thermal and dynamic loading.Numerical simulations,conducted using finite element analysis,reveal peak vibration accelerations of 1.3 m/s^(2)for the rack,3.0 m/s^(2)for the rail,1.2 m/s^(2)for the sleeper,and 0.1 m/s^(2)for the bridge,with maximum stresses of 3 MPa in the rack,8 MPa in the rail,and 25 MPa in connecting bolts.The results show significant span-dependent amplification of stress and strain in the rack system under thermo-mechanical loading,exceeding material strength limits at 60-meter spans.An innovative elastic connection method is proposed to mitigate stress concentrations effectively,en-hancing system durability.This study introduces a novel approach to modeling complex thermo-mechanical interactions in rack railway systems,validated through extensive simulations,and provides a practical solution for improving structural resilience,offering theoretical guidance for optimizing rack-bridge system design to ensure operational safety in extreme environmental conditions.展开更多
Curing temperature significantly affects the pozzolanic reaction kinetics of phosphorous slag(PS),thereby governing the early-age(7 d)hydration behavior of PS composite binders at 20,30,and 60℃.The Krstulovic-Dabic k...Curing temperature significantly affects the pozzolanic reaction kinetics of phosphorous slag(PS),thereby governing the early-age(7 d)hydration behavior of PS composite binders at 20,30,and 60℃.The Krstulovic-Dabic kinetic model was applied to identify three characteristic processes:nucleation and growth(NG),phase boundary interaction(I),and diffusion(D).Control mixtures containing inert quartz powder with comparable particle size distributions were prepared for comparison.Pore characteristics of hardened PS pastes at different temperatures were analyzed via mercury intrusion porosimetry,while hydration products were characterized using X-ray diffraction(XRD)and thermogravimetric analysis(TG-DTG).The experimental results indicate that the retarding effect of PS on early cement hydration outweighs its accelerating effect,attributed to the combined influence of nucleation and dilution,with retardation decreasing as temperature increases.PS exhibits early reactivity and continuously consumes calcium hydroxide through the pozzolanic reaction,as evidenced by stable phase assemblages accompanied by reduced CH content in XRD and TG-DTG analyses.At 20℃,increasing PS content maintains the NG→I→D mechanism but slows reaction rates across all stages.Elevated temperatures significantly accelerate the NG process,shifting the dominant mechanism from NG toward D.Simultaneously,enhanced PS reactivity contributes to a refined pore structure and improved compressive strength.展开更多
文摘This paper investigated the effects of root-zone (RZ) CO<sub>2</sub> concentration ([CO<sub>2</sub>]) on root morphology and growth, nitrate (NO<sub>3</sub>-</sup>) uptake and assimilation of lettuce plants at different root-zone temperatures (RZT). Elevated RZ [CO<sub>2</sub>] stimulated root development, root and shoot growth compared to ambient RZ [CO<sub>2</sub>]. The greatest increase in root growth was observed in plants grown under elevated RZ [CO<sub>2</sub>] of 50,000 ppm. However, RZ [CO<sub>2</sub>] of 10,000 ppm was sufficient to achieve the maximal leaf area and shoot productivity. Lettuce plants exhibited faster shoot and root growth at 20°C-RZT than at ambient (A)-RZT. However, under elevated RZ [CO<sub>2</sub>], the magnitude of increased growth was greater at A-RZT than at 20°C-RZT. Compared to RZ [CO<sub>2</sub>] of 360 ppm, elevated RZ [CO<sub>2</sub>] of 10,000 ppm increased NO<sub>3</sub>-</sup> accumulation and nitrate reductase activity (NRA) in both leaves and roots. NO<sub>3</sub>-</sup> concentrations of leaf and root were higher at 20°C-RZT than at A-RZT in all plants. NRA was higher in root than in leaf especially under A-RZT. The total reduced nitrogen (TRN) concentration was significantly higher in plants grown under elevated RZ [CO<sub>2</sub>] of 10,000 ppm than under ambient RZ [CO<sub>2</sub>] of 360 ppm with greater concentration in 20°C-RZT plants than in A-RZT plants. These results imply that elevated RZ [CO<sub>2</sub>] significantly affected root morphology, root and shoot growth and N metabolism of temperate lettuce with greater impacts at A-RZT than at 20°C-RZT. These findings have practical significance to vegetable production by growing the vegetable crops at cool-RZT with elevated RZ [CO<sub>2</sub>] to enhance its productivity.
文摘Although tropical high ambient temperature and humidity severely reduced the productivity of temperate plants, temperate vegetable crops such as lettuce have been successfully grown in Singapore by only cooling its root-zone. In this paper, a cool Meditteranean vegetable, Eruca sativa, was studied to understand how different RZTs can impact its shoot productivity, photosynthesis and nutritional quality. All plants were cultivated using aeroponic systems in a tropical greenhouse under hot ambient conditions where roots were subjected to four different root-zone temperatures (RZTs) of 20°C-RZT, 25°C-RZT, 30°C-RZT and fluctuating ambient temperatures ranged from 25°C to 38°C [25°C/38°C (ambient)]-RZT. Parameters studied include shoot fresh weight (FW), photosynthetic gas exchange, midday chlorophyll (Chl) fluorescence F<sub>v</sub>/F<sub>m</sub> ratio, Chl fluorescence photochemical quenching (qP), non-photochemical quenching (qN) and electron transport rate (ETR), total phenolic compounds and mineral content such as potassium (K), calcium (Ca), magnesium (Mg) and iron (Fe). Among the 4 different RZT treatments, E. sativa plants grown under ambient-RZT (25/38°C-RZT) had the lowest shoot and root FW while those plants grown under 20°C-RZT had highest productivity of shoot and root. However, there were no significant differences in shoot and root FW in plants grown at 25°C- and 30°C-RZT. Compared to plants grown under 25°C/38°C (ambient-RZT), light-saturated photosynthetic CO<sub>2</sub> assimilation rate (A<sub>sat</sub>) and stomatal conductance (g<sub>ssat</sub>) were similarly higher in 20°C-, 25°C- and 30°C-RZT. All plants had midday Chl fluorescence F<sub>v</sub>/F<sub>m</sub> ratio lower than <0.8 ranged from 0.785 to 0.606 with the highest and lowest ratios recorded in 20°C-RZT and ambient-RZT plants, respectively. These results indicate that cooling the RZ of E. sativa plants protected their PS II from photoinactivation during midday in the greenhouse. There were no significant differences observed in photochemical quenching (qP), non-photochemical quenching (qN) and electron transport rate among plants grown under 20°C-, 25°C- and 30°C-RZT. However, plants grown under ambient-RZT had lower qP, qN and ETR compared to all other plants. E. sativa at 20°C-RZT with the best developed roots had the highest dietary mineral (K, Mg, Ca and Fe) contents but lower total phenolics content. In contrast, ambient-RZT, plants with poorly developed roots had the lowest mineral content but highest total phenolic content. The results of this study suggest that cooling of roots is a feasible method for the cultivation of E. sativa in the tropic, which enhances the content of dietary minerals in shoots.
文摘Soil temperature influences crop growth and quality under field and greenhouse conditions;however, precise investigation using controlled cultivation systems is largely lacking. We investigated effects of root-zone temperatures on growth and components of hydroponically grown red leaf lettuce (Lactuca sativa L. cv. Red Wave) under a controlled cultivation system at 20°C. Compared with ambient root-zone temperature exposure, a 7-day low temperature exposure reduced leaf area, stem size, fresh weight, and water content of lettuce. However, root-zone heating treatments produced no significant changes in growth parameters compared with ambient conditions. Leaves under low root-zone temperature contained higher anthocyanin, phenols, sugar, and nitrate concentrations than leaves under other temperatures. Root oxygen consumption declined with low temperature root exposure, but not with root heating. Leaves of plants under low rootzone temperature showed hydrogen peroxide production, accompanied by lipid peroxidation. Therefore, low temperature root treatment is suggested to induce oxidative stress responses in leaves, activating antioxidative secondary metabolic pathways.
文摘Air and soil temperatures strongly influence the growth and quality of crops. However, in root vegetables, such as carrot, few experiments aimed at regulating growth and quality by manipulating root-zone temperature have been reported. We investigated the effect of root-zone temperatures (20°C, 25°C, 29°C, and 33°C) on carrot growth and components using a hydroponic system. High root-zone temperatures for 14 days reduced shoot and rootgrowth and water content. In contrast, total phenolic compounds and soluble-solid content increased in tap roots under high-temperature treatment. Root oxygen consumption was upregulated after 7 days under high-temperature treatment. These results suggest that high root-zone temperatures induce drought-like stress responses that modulate carrot biomass and components. High root-zone temperature treatments administered to hydroponically grown crops may be a valuable tool for improving and increasing the quality and value of crops.
文摘Platinum group metals have high melting points,strong corrosion resistance,stable chemical properties,and low oxygen permeability in high-temperature oxygen-containing environments.As thermal protective coating materials,they have gained essential applications in the aerospace field and have excellent prospects for application in frontier military fields,such as protecting hot-end components of hypersonic aircraft.This research reviewed the latest research progress of platinum group metal coatings with hightemperature oxidation resistance,including coating preparation techniques,oxidation failure,and alloying modification.The leading preparation techniques of current platinum group metal coatings were discussed,as well as the advantages and disadvantages of various existing preparation techniques.Besides,the intrinsic properties,failure forms,and failure mechanisms of coatings of single platinum group metal in high-temperature oxygen-containing environments were analyzed.On this basis,the necessity,main methods,and main achievements of alloying modification of platinum group metals were summarized.Finally,the future development of platinum group coatings with high-temperature oxidation resistance was discussed and prospected.
基金supported by the National Natural Science Foundation of China (Grant Nos.12074213 and 11574108)the Major Basic Program of Natural Science Foundation of Shandong Province (Grant No.ZR2021ZD01)the Natural Science Foundation of Shandong Province (Grant No.ZR2023MA082)。
文摘In recent years,the research on superconductivity in one-dimensional(1D)materials has been attracting increasing attention due to its potential applications in low-dimensional nanodevices.However,the critical temperature(T_(c))of 1D superconductors is low.In this work,we theoretically investigate the possible high T_(c) superconductivity of(5,5)carbon nanotube(CNT).The pristine(5,5)CNT is a Dirac semimetal and can be modulated into a semiconductor by full hydrogenation.Interestingly,by further hole doping,it can be regulated into a metallic state with the sp^(3)-hybridized σ electrons metalized,and a giant Kohn anomaly appears in the optical phonons.The two factors together enhance the electron–phonon coupling,and lead to high-T_(c) superconductivity.When the hole doping concentration of hydrogenated-(5,5)CNT is 2.5 hole/cell,the calculated T_(c) is 82.3 K,exceeding the boiling point of liquid nitrogen.Therefore,the predicted hole-doped hydrogenated-(5,5)CNT provides a new platform for 1D high-T_(c) superconductivity and may have potential applications in 1D nanodevices.
基金funded by the Earmarked Fund for China Agriculture Research System,grant number CARS-01-33.
文摘Spikelet filling characteristics in early-season rice in southern China may be distinctive due to its exposure to high temperatures during the ripening period.However,limited information is currently available on these characteristics.This study aimed to characterize spikelet filling in early-season rice and identify the key factors contributing to its improvement.Field experiments were conducted over two years(2021 and 2022)to mainly investigate the proportions of fully-filled,partially-filled,and empty spikelets,along with the biomass-fertilized spikelet ratio and harvest index,in 11 early-season rice varieties.The results revealed significant varietal variation in spikelet filling,with the proportion of fully-filled spikelets ranging from 60.6%to 81.1%in 2021 and from 66.3%to 79.2%in 2022.Among the 11 varieties,Liangyou 42,Lingliangyou 942,and Liangyou 287 exhibited relatively superior performance in spikelet filling.Linear regression revealed that,although a significant negative relationship existed between the proportion of fully-filled spikelets and both partially-filled and empty spikelets,the relationship with partially-filled spikelets was stronger.Additionally,the proportion of fully-filled spikelets showed a significant positive relationship with the harvest index but not with the biomass-fertilized spikelet ratio.These findings indicate that increasing the harvest index and reducing the occurrence of partially-filled grains are essential strategies for improving spikelet filling in early-season rice.
基金supported by the National Natural Science Foundation of China (Grant No. 12304467)the China Postdoctoral Science Foundation (Grant No. 2023M732175)。
文摘Prolonged exposure to n-butanol, a common hazardous volatile organic compound(VOC) in the environment, can lead to a broad range of adverse health effects. Therefore, detecting n-butanol safely and efficiently at low concentrations becomes critical for both environmental monitoring and human health. In this study, a novel Eu/Ce-codoped MOF-ZnO gas sensor was developed for the sensitive detection of n-butanol gas under ultraviolet activation at ambient temperature. A series of Eu/Ce-ZnO nanomaterials were synthesized via a simple co-precipitation route, by carefully designing the varied mass ratios of Eu and Ce incorporated into pristine ZnO derived from MOF precursors. The gas testing results revealed that introducing an appropriate amount of Eu and Ce would enlarge the specific surface area and enrich the oxygen vacancy content compared to pristine MOF-ZnO. Upon UV irradiation, the 0.03 wt% Eu 0.04 wt% Ce-ZnO sensor achieved a superior response of 611 for100 ppm n-butanol at room temperature, 15.28 times higher than that of pristine MOF-ZnO(40). Furthermore, the sensor presented rapid response/recovery times(15 s/28 s) and excellent selectivity. The above contributions pave the way for the promising development of highly sensitive, ultraviolet-enhanced gas sensors for ambient temperature detection of VOCs.
基金supported by the Strategic Priority Research Program of the Chinese Academy of Sciences(No.XDA0400000)the Youth Innovation Promotion Association of the Chinese Academy of Sciences(No.2021253)+1 种基金the Major Science and Technology Projects of China National Offshore Oil Corporation Limited during the 14th Five Year Plan(No.KJGG-2022-12-CCUS-030500)the Photon Science Center for Carbon Neutrality of Chinese Academy of Science.
文摘When the operating temperature of a solid oxide electrolysis cell(SOEC)is lower than the outlet temperature of a nuclear reactor,the reactor can be directly coupled with the SOEC as a high-temperature heat source.However,the key to the efficiency and return on investment of this hybrid energy system lies in the expected lifetime of the SOEC.This study assessed Ni-YSZ|YSZ|GDC|LSC fuel electrode support cells’long-term stability during electrolysis at 650℃with a current density of−0.5Acm^(−2)over 1818 h.The average voltage degradation rate of 2.63%kh^(−1)unfolded in two phases:an initial rapid decay(90 to 1120 h at 3.58%kh^(−1))and a stable decay(1120 to 1818 h at 2.14%kh^(−1)),emphasizing SOECs’probability coupling with nuclear reactors at 650℃.Post-1818-hour electrolysis revealed nickel particle formation associated with Ni(OH)_(x)diffusion and re-deposition,alongside a strontium-containing layer causing interface cracking.Despite minimal strontium segregation in the EDS,XPS data indicated surface segregation of Sr.This study provides crucial insights into prolonged SOEC operation,highlighting both its potential and challenges.
文摘Following over 20 years of research,a direct measurement of the QGP temperature has been achieved at Relativistic Heavy-Ion Collider(RHIC),free from the blue-shift effect and contamination from strong interactions.This viewpoint discusses a recent measurement of the QGP temperature at different stages at the Solenoidal Tracker at RHIC(STAR),which used e^(+)e^(-)pairs as penetrating probes.
基金funded by the Changsha Municipal Natural Science Foundation(Grant No.kq2402024)Chengdu Polytechnic Scientific Research Platform(23KYPT01).
文摘This investigation utilizes non-equilibrium molecular dynamics(NEMD)simulations to explore shockinduced spallation in single-crystal tantalumacross shock velocities of 0.75–4 km/s and initial temperatures from300 to 2000 K.Two spallation modes emerge:classical spallation for shock velocity below 1.5 km/s,with solid-state reversible Body-Centered Cubic(BCC)to Face-Centered Cubic(FCC)orHexagonal Close-Packed(HCP)phase transformations and discrete void nucleation-coalescence;micro-spallation for shock velocity above 3.0 km/s,featuring complete shock-induced melting and fragmentation,with a transitional regime(2.0-2.5 km/s)of partial melting.Spall strength decreases monotonically with temperature due to thermal softening.Elevated temperatures delay void nucleation but increase density,expanding spall regions and enhancing structural disorder with reduced BCC recovery.For microspallation,melting exacerbates damage,causing smaller voids and intensified atomic ejection,which increases with temperature.Free surface velocity profiles indicate damage:in classical spallation,first drop marks nucleation,and pullback signals spall layers.In micro-spallation,the first drop is irrelevant,but remains valid.Temperature delays pullback signals and weakens Hugoniot Elastic Limit.This study clarifies temperature-shock coupling in Ta spallation,aiding failure prediction in high-temperature shock environments.
文摘Root-zone temperature(RZT)strongly affects plant growth,nutrient uptake and tolerance to environmental stress,making its regulation a key challenge in greenhouse cultivation in cold climates.This study aimed to assess the potential of passive techniques,namely black polyethylene mulch and row covers,for modifying RZT dynamics in lettuce(Lactuca sativa L.)production and to evaluate the predictive performance of the eXtreme Gradient Boosting(XGBoost)algorithm.Experiments were conducted in Iğdır,Türkiye,over a 61-day period,with soil temperature continuously monitored at depths of 1-30 cm under mulched and non-mulched conditions,alongside measurements of greenhouse air temperature both with and without row covers.The application of row covers increased internal air temperature by 5.8℃,while mulching raised RZT by 0.6-1.3℃,with effects diminishing at deeper layers.XGBoost modeling achieved high predictive accuracy,with RMSE values of 0.150-0.189◦C and R^(2)values above 0.99,and feature-importance analysis indicated that neighboring soil depths were the strongest predictors of RZT.These findings show that integrating row covers and mulching can stabilize the root-zone microclimate without active heating.The XGBoost model provides a robust tool for forecasting soil temperature and supports sustainable greenhouse production in cold regions.
基金supported by the National Natural Science Foundation of China(grant numbers 52250357 and 52203003).
文摘The glass transition temperature(T_(g))of styrene-butadiene rubber(SBR)is a key parameter determining its low-temperature flexibility and processing performance.Accurate prediction of T_(g)is crucial formaterial design and application optimisation.Addressing the limitations of traditional experimental measurements and theoretical models in terms of efficiency,cost,and accuracy,this study proposes a machine learning prediction framework that integrates multi-model ensemble and Bayesian optimization by constructing a multi-component feature dataset and algorithm optimization strategy.Based on the constructed high-quality dataset containing 96 SBR samples,ninemachine learning models were employed to predict the T_(g)of SBR and compare their prediction performance.Ultimately,aGPR-XGBoost mixed model was constructed through model ensemble,achieving high-precision prediction with R^(2)values greater than 0.9 on both the training and test sets.Further feature attribution and local effect analysis were conducted using feature analysis methods such as SHAP and ALE,revealing the nonlinear influence patterns of various components on T_(g),providing a theoretical basis for SBR formulation design and T_(g)regulation.The machine learning prediction framework established in this study combines high-precision prediction with interpretability,significantly enhancing the prediction performance of the T_(g)of SBR.It offers an efficient tool for SBR molecular design and holds great potential for promotion and application.
文摘This study presents a numerical investigation of the transient relaxation dynamics of a near-critical CO_(2)droplet immersed in a warmer supercritical environment composed of the same fluid.Three thermodynamic regimes were analysed:quasi-critical(T_(r)=1.01,P_(r)=1.01),transitional(T_(r)=2.01,P_(r)=1.01),and deep supercritical(T_(r)=5.01,P_(r)=3.01).Theevolution of density,temperature,and velocity fieldswas examined to characterize the internal structure and stability of the interfacial transition layer.The evolution of density,temperature,and velocity fields highlights the competition between thermal diffusion,compressibility,andmass confinement in shaping the stability of the interfacial transition layer.Near the critical point,strong gradients and flux discontinuities emerge,consistent with known instabilities,whereas higher reduced conditions promote homogenization and stabilized transport.In the deep supercritical regime,smooth and nearly uniform fields indicate robust thermal stability.The model is validated against prior studies on droplet evaporation under supercritical and trans-critical conditions.Beyond theoretical insights,the results underline practical implications for advanced propulsion,heat transfer,and evaporation systems as well as for safe CO_(2)supercritical storage and extraction processes in energy,aerospace,pharmaceutical,and materials industries.
基金supported by the National Natural Science Foundation of China(Grant Nos.32072545,32272639 and 32260745)Zhejiang Provincial Natural Science Foundation of China(Grant Nos.LTGN23C150009 and LY22C150003)Zhejiang University Experimental Technology Research Project(Grant No.SYBJS202217).
文摘For red pear,the anthocyanin content is a crucial factor determining the fruit skin color,which affects consumer preferences.Low overnight temperatures promote anthocyanin accumulation,but the molecular mechanism responsible is unclear.In this study,‘Hongzaosu’pear(Pyrus pyrifolia×Pyrus communis)fruit were treated with a low nighttime temperature(LNT,16℃)or a warm nighttime temperature(WNT,26℃),with sampling conducted within two diurnal cycles.The results showed that LNT promoted anthocyanin accumulation in the fruit skin.The structural anthocyanin biosynthetic genes PpCHS,PpF3H,and PpUFGT exhibited a rhythmic increase in expression at night under LNT.To examine the underlying mechanism,RNA sequencing was conducted using pear calli exposed to LNT and WNT for different durations(24,48,72,or 96 h).Transcriptome analysis revealed 285 differentially expressed genes(DEGs)common to all pairwise comparisons of LNT-and WNT-treated calli of‘Clapp's Favorite’(P.communis)at the sampling time points.KEGG pathway and gene ontology enrichment analyses indicated that the common DEGs were enriched in secondary metabolic processes and phenylpropanoid metabolic processes,which are associated with anthocyanin biosynthesis.The transcription factor PpCDF5,which was responsive to LNT,was selected for further study.Dual-luciferase assays showed that PpCDF5 activated the transcription of anthocyanin biosynthetic genes PpMYB10,PpCHS,PpF3H,PpDFR,PpANS,and PpUFGT.The yeast one-hybrid and EMSA assays demonstrated that PpCDF5 directly binds to the PpF3H promoter,which contains an AAAG motif.Overexpression of PpCDF5 in pear calli and transient overexpression in pear fruit both increased anthocyanin accumulation.The results indicate that PpCDF5 is involved in LNT-induced anthocyanin biosynthesis in pear fruit and provide insights into the molecular regulation of commercial fruit coloration.
基金supported by the National Key R&D Program of China(No.2024YFC3714200)Guangxi Key Research and Development Program,China(No.Guike AB24010074)+2 种基金the National Natural Science Foundation of China(Nos.22276099,U24A20515 and 22361162668)the Natural Science Foundation of Jiangsu Province(No.BK20240036)the Postgraduate Research&Practice Innovation Program of Jiangsu Province(No.KYCX24_1529).
文摘Temperature has a substantial impact on the emission of biogenic volatile organic compounds(BVOCs).Moder-ate warm temperatures,e.g.,30–40°C,could boost plant metabolism,increasing BVOC emissions.Against the backdrop of global warming,plants emit more BVOCs to cope with thermal stress,leading to elevated concen-trations of tropospheric ozone(O_(3))and secondary organic aerosols(SOA).In recent years,a considerable body of research has explored the interaction between tree species and BVOCs under the influence of various environ-mental factors.Although many studies have examined explored the temperature dependence of BVOC emissions in the past,few studies have conducted a comprehensive and in-depth investigation into the impacts of tempera-ture.This review summarizes the relevant studies on BVOCs in the past decade,including the main biosynthetic pathways,emission observation techniques and emission inventories,as well as how temperature affects isoprene and monoterpene emission rates and the formation of O_(3) and SOA.Our work offers a theoretical foundation and guidance for future efforts to advance the comprehension of BVOC emission characteristics and develop strategies to mitigate secondary pollution.
基金Project(51879135)supported by the Taishan Scholars Program,ChinaProject(52309130)supported by the National Natural Science Foundation of China+1 种基金Project(SKLGME023003)supported by the Open Research Fund of State Key Laboratory of Geomechanics and Geotechnical Engineering Safety,ChinaProject(2022AH051754)supported by the Natural Science Research Project of Anhui Universities,China。
文摘The effect of real-time high temperature and thermal treatment on the mechanical characteristics and crack evolution of granite with different grain sizes(i.e.,0.5 mm,0.7 mm and 1.0 mm)is investigated by numerical simulation employing a grain-based model,and the impact of initial cracks on thermal-induced strengthening is also examined by integrating random cracks within the model before tests.The results revealed that thermal stress,induced by the mismatch in thermal expansion coefficient between various minerals,is the primary distinction between rock specimens in real-time high temperature and thermal treatment.With increasing temperature,the thermal stress gradually accumulates in quartz minerals under real-time high temperature but releases after thermal treatment.The high local contact force significantly affects the peak stress and crack evolution.Uniaxial compression simulation results demonstrate that progressive accumulation of thermal stress induces degradation in macroscopic peak strength and increase of microcrack density.The grain size controls the ratio of intergranular contacts to intragranular contacts,and leads to an increase in strong contact number in the intragrain and a decrease in strong contact number in the intergrain.The strengthening of uniaxial compression strength in the experiment can be well simulated by controlling the number of pre-existing initial cracks in the numerical model.Our conclusions are beneficial to a better understanding of the underlying mechanisms of thermal damage and thermal strengthening of granite for deep geological engineering.
基金funded by the National Natural Science Foundation of China(Nos.52209130 and 52379100)Shandong Provincial Natural Science Foundation(No.ZR2024ME112).
文摘Thermal-mechanical damage and deformation at the interface between shotcrete linings and the surrounding rock of tunnels under high-temperature and variable-temperature conditions are critical to the safe construction and operation of tunnel engineering.This study investigated the thermo-mechanical damage behavior of the composite interface between alkali-resistant glass fiber-reinforced concrete(ARGFRC)and granite,focusing on a plateau railway tunnel.Laboratory triaxial tests,laser scanning,XRD analysis,numerical simulations,and theoretical analyses were employed to investigate how different initial curing temperatures and joint roughness coefficient(JRC)influence interfacial damage behavior.The results indicate that an increase in interface roughness exacerbates the structural damage at the interface.At a JRC of 19.9 and a temperature of 70℃,crack initiation in granite was notably restrained when the confining pressure rose from 7 MPa to 10 MPa.Roughness-induced stress distribution at the interface was notably altered,although this effect became less pronounced under high confining pressure conditions.Additionally,during high-temperature curing,thermal stress concentration at the tips of micro-convex protrusions on the granite surface induced microcracks in the adjacent ARGFRC matrix,followed by deformation.These findings provide practical guidelines for designing concrete support systems to ensure tunnel structural safety in high-altitude regions with harsh thermal environments.
基金Supported by the Sichuan Science and Technology Program(Grant Nos.2021YFD0211,2023ZDZX0011).
文摘Significant diurnal temperature variations in mountainous rack railways cause stiffness mismatches between the rack structure and simply supported bridges,leading to critical failures like bolt loosening and rack fractures.This study develops a dynamic model of the vehicle-rack-bridge system based on train-track-bridge interaction theory,integrating gear-rack meshing and wheel-rail contact mechanisms.The model analyzes the dynamic response of bridges with varying spans under combined thermal and dynamic loading.Numerical simulations,conducted using finite element analysis,reveal peak vibration accelerations of 1.3 m/s^(2)for the rack,3.0 m/s^(2)for the rail,1.2 m/s^(2)for the sleeper,and 0.1 m/s^(2)for the bridge,with maximum stresses of 3 MPa in the rack,8 MPa in the rail,and 25 MPa in connecting bolts.The results show significant span-dependent amplification of stress and strain in the rack system under thermo-mechanical loading,exceeding material strength limits at 60-meter spans.An innovative elastic connection method is proposed to mitigate stress concentrations effectively,en-hancing system durability.This study introduces a novel approach to modeling complex thermo-mechanical interactions in rack railway systems,validated through extensive simulations,and provides a practical solution for improving structural resilience,offering theoretical guidance for optimizing rack-bridge system design to ensure operational safety in extreme environmental conditions.
基金Funded by the Sichuan Province Science and Technology Support Program(No.2025YFNZH0022)the Chengdu Municipal Science and Technology Program(No.2025-YF11-00003-HZ)。
文摘Curing temperature significantly affects the pozzolanic reaction kinetics of phosphorous slag(PS),thereby governing the early-age(7 d)hydration behavior of PS composite binders at 20,30,and 60℃.The Krstulovic-Dabic kinetic model was applied to identify three characteristic processes:nucleation and growth(NG),phase boundary interaction(I),and diffusion(D).Control mixtures containing inert quartz powder with comparable particle size distributions were prepared for comparison.Pore characteristics of hardened PS pastes at different temperatures were analyzed via mercury intrusion porosimetry,while hydration products were characterized using X-ray diffraction(XRD)and thermogravimetric analysis(TG-DTG).The experimental results indicate that the retarding effect of PS on early cement hydration outweighs its accelerating effect,attributed to the combined influence of nucleation and dilution,with retardation decreasing as temperature increases.PS exhibits early reactivity and continuously consumes calcium hydroxide through the pozzolanic reaction,as evidenced by stable phase assemblages accompanied by reduced CH content in XRD and TG-DTG analyses.At 20℃,increasing PS content maintains the NG→I→D mechanism but slows reaction rates across all stages.Elevated temperatures significantly accelerate the NG process,shifting the dominant mechanism from NG toward D.Simultaneously,enhanced PS reactivity contributes to a refined pore structure and improved compressive strength.
