The Arabian-Nubian Shield(ANS)serves as a key geological archive,preserving the tectono-thermal evolution associated with the Rodinia breakup(∼900–800 Ma)and Gondwana formation(∼800–620 Ma).The Katherina Ring Comp...The Arabian-Nubian Shield(ANS)serves as a key geological archive,preserving the tectono-thermal evolution associated with the Rodinia breakup(∼900–800 Ma)and Gondwana formation(∼800–620 Ma).The Katherina Ring Complex(KRC),located in the Sinai Peninsula,Egypt(northern ANS),exemplifies continental growth through multistage magmatism and orogenesis,spanning the Tonian to Ediacaran periods(∼900–530 Ma).Despite its importance,debates persist regarding the nature,age,crustal characteristics,and magma source evolution of its constituent units.Situated in the northwestern part of the KRC,the Wadi Rofaiyed Cu deposit offers an exceptional natural laboratory for investigating continental crust formation during this interval,owing to its superb exposure and preservation.This study integrates detailed fieldwork,petrographic analyses,whole-rock geochemistry,Sr-Nd isotopes,and in situ zircon U-Pb-Lu-Hf isotopic data.It aims to(i)establish a robust chronological framework for the unmetamorphosed plutonic rocks of the KRC,(ii)advance the understanding of associated geodynamic processes,and(iii)elucidate the episodic magmatism events.The findings show that Wadi Rofaiyed juvenile crust developed in four main phases:(i)a subduction-accretionary phase(∼755 Ma)characterized by intense calc-alkaline magmatism,originating from the partial melting of mafic lower crust;(ii)a syn-collisional phase(∼630 Ma)occurred during the collision between the Saharan metacraton and the younger ANS crust,producing I-type granitoids formed through magma mixing and crustal anatexis;(iii)a post-collisional phase characterized by intermediate I-type(∼595 Ma)to felsic A-type alkaline magma(∼594 Ma),originated from the partial melting of the overthickened lower crust corresponding to lithospheric delamination;and(iv)an anorogenic phase(∼530 Ma)related to the final amalgamation of Greater Gondwana.Isotopic analyses across all four magmatic phases reveal low initial^(87)Sr/^(86)Sr(0.702648–0.703311)and positiveε_(Hf)(t)(+2.84 to+7.78)andε_(Nd)(t)(+2.61 to+5.21)values,consistent with lower crustal sources with depleted mantle-like signatures.The model ages(T_(DM2))for these magmatic rocks derived from zircon Hf(1.2–1.5 Ga)and whole-rock Nd isotopes(0.96–1.17 Ga)support a predominantly juvenile crustal origin.These findings underscore the multistage tectono-magmatic evolution of the northern ANS,advancing our understanding of obduction-accretion dynamics and crustal development during the Neoproterozoic.展开更多
1.Objective Nigeria lies between the West African Craton and the Congo Craton,south of the Tuareg Shield(Ogunmola JK et al.,2015).The Nasarawa pegmatite field mainly comprises of the Precambrian Basement Complex(inclu...1.Objective Nigeria lies between the West African Craton and the Congo Craton,south of the Tuareg Shield(Ogunmola JK et al.,2015).The Nasarawa pegmatite field mainly comprises of the Precambrian Basement Complex(including Archean-Proterozoic migmatite,gneiss,schists and Pan-African “Older Granites”),Mesozoic alkaline ring complexes(“Younger Granites”) and sedimentary basins(Yang QD et al.,2023;Fig.1a).“Older Granites” are part of the Pan-African mobile belt;“Younger Granites” has significant peralkaline characteristics.“Younger Granites” has a wide distribution in the north-central region of Nigeria,including areas such as Kano,Jos-Bauchi,Mada,and Nasarawa,and the emplacement age gradually decreases from north to south from 213 Ma(Dutse complex) to 141 Ma(Afu complex)(Amuda AK et al.,2021).展开更多
New fieldwork, mineralogical and geochemical data and interpretations are presented for the rare-metal bearing A-type granites of the Aja intrusive complex(AIC) in the northern segment of the Arabian Shield. This comp...New fieldwork, mineralogical and geochemical data and interpretations are presented for the rare-metal bearing A-type granites of the Aja intrusive complex(AIC) in the northern segment of the Arabian Shield. This complex is characterized by discontinuous ring-shaped outcrops cut by later faulting. The A-type rocks of the AIC are late Neoproterozoic post-collisional granites, including alkali feldspar granite, alkaline granite and peralkaline granite. They represent the outer zones of the AIC, surrounding a core of older rocks including monzogranite, syenogranite and granophyre granite. The sharp contacts between A-type granites of the outer zone and the different granitic rocks of the inner zone suggest that the AIC was emplaced as different phases over a time interval, following complete crystallization of earlier batches. The A-type granites represent the late intrusive phases of the AIC, which were emplaced during tectonic extension, as shown by the emplacement of dykes synchronous with the granite emplacement and the presence of cataclastic features. The A-type granites consist of K-feldspars, quartz, albite, amphiboles and sodic pyroxene with a wide variety of accessory minerals, including Fe-Ti oxides, zircon, allanite, fluorite, monazite, titanite, apatite, columbite, xenotime and epidote. They are highly evolved(71.3–75.8 wt% SiO2) and display the typical geochemical characteristics of post-collisional, within-plate granites. They are rare-metal granites enriched in total alkalis, Nb, Zr, Y, Ga, Ta, REE with low CaO, MgO, Ba, and Sr. Eu-negative anomalies(Eu/Eu* = 0.17–0.37) of the A-type granites reflect extreme magmatic fractionation and perhaps the effects of late fluid-rock interactions. The chemical characteristics indicate that the A-type granites of the AIC represent products of extreme fractional crystallization involving alkali feldspar, quartz and, to a lesser extent, ferromagnesian minerals. The parent magma was derived from the partial melting of a juvenile crustal protolith with a mantle contribution. Accumulation of residual volatile-rich melt and exsolved fluids in the late stage of the magma evolution produced pegmatite and quartz veins that cut the peripheries of the AIC. Post-magmatic alteration related to the final stages of the evolution of the A-type granitic magma, indicated by alterations of sodic amphibole and sodic pyroxene, hematitization and partial albitization.展开更多
The final quality of complex conical-section rings depends on co-design of multiple processes in forming process chain.In this study,for a complex aeroengine casing ring with a large slope and a flange on its end,a co...The final quality of complex conical-section rings depends on co-design of multiple processes in forming process chain.In this study,for a complex aeroengine casing ring with a large slope and a flange on its end,a co-design method of the forming process chain is put forward towards the objective of precision forming,which not only proposes a standard process route composed of multiple processes of upsetting,punching,rectangular ring rolling,loose tooling forging and profiled ring rolling,but also presents co-design methods of dies and blanks for all the processes.For profiled ring rolling,a design method of preformed blank that makes the blank and the target conical-section ring have the same axial volume distribution is proposed.By the method,the axial metal redistribution during the process can be alleviated greatly thus improving the forming stability and precision of the ring.Based on the geometric features of designed preformed blank,design methods of blanks and dies for loose tolling forging,rectangular ring rolling,punching and upsetting are proposed sequentially.In view of the key roles of loose tooling forging(manufacturing the preformed blank)and profiled ring rolling on the final quality of the conical ring parts,inherited FE simulations for these two processes are performed to verify the proposed design methods and determine appropriate design parameter.It is demonstrated that the proposed design method has significant advantages in improving forming precision.Besides,a suggestive value 1.5 of the rolling ratio for profiled ring rolling(a key design parameter)is given based on comprehensive consideration of multiple indicators such as ring roundness,deformation uniformity and forming load.The corresponding industrial experiments performed illustrate that a high forming precision of the conical-section aeroengine casing ring is achieved.展开更多
Photosynthesis in nature has been deemed as the most significant biochemical reaction,which maintains a relatively stable content of O_(2) and CO_(2) in the atmosphere.Herein,for a deeper comprehension of natural phot...Photosynthesis in nature has been deemed as the most significant biochemical reaction,which maintains a relatively stable content of O_(2) and CO_(2) in the atmosphere.Herein,for a deeper comprehension of natural photosynthesis,an artificial photosynthesis model reaction of photochemical CO_(2) to CO conversion(CO_(2)+2 H^(+)+2e^(-)→CO+H_(2)O)catalyzed by a homogeneous hexanuclear ring cobalt complex{K_(2)[CoO_(3)PCH_(2)N(CH_(2)CO_(2))_(2)]}_(6)(Co6 complex)is developed.Using the[Ru(bpy)_(3)]^(2+)as a photosensitizer and TEOA as a sacrificial electron donor,an optimal turnover frequency of 503.3 h^(‒1) and an apparent quantum efficiency of 0.81%are obtained.The good photocatalytic CO_(2) reduction performance is attributed to the efficient electron transfer between Co6 complex and[Ru(bpy)_(3)]^(2+),which boosts the photogenerated carriers separation of the photosensitizer.It is confirmed by the j‐V curves,light‐assisted UV‐vis curves,steady‐state photoluminescence spectra and real‐time laser flash photolysis experiments.In addition,the proposed catalytic mechanism for CO_(2) reduction reaction catalyzed by the Co6 complex is explored by the potassium thiocyanate poison experiment,Pourbaix diagram and density functional theory calculations.展开更多
In addition to syenite ring dykes and multiple alkaline granite stocks, the sub-volcanic Houshihushan alkaline ring complex near Shanhaiguan, Qinhuangdao City, contains cone-sheets of two types： a majority filled wit...In addition to syenite ring dykes and multiple alkaline granite stocks, the sub-volcanic Houshihushan alkaline ring complex near Shanhaiguan, Qinhuangdao City, contains cone-sheets of two types： a majority filled with granite porphyry and a minority filled with quartz syenite porphyry. Many cone sheets show evidence of multiple magma intrusion events. Some granite porphyry sheets＇ multiple chilled margins display magmatic roll structures indicating that turbulent magma flowed up the fractures. In one upward-closing cone-sheet K-feldspar phenocrysts floated up through fluid granite porphyry magma and became concentrated at the top providing direct evidence of shallow-level crystal fractionation, confirmed by published rock analyses. Accreted lapilli with K-feldspar crystal cores occur only in the inner parts of a minority of cone-sheets and field relationships indicate that they must have formed beneath the ground surface. Similar lapilli occur in erupted ignimbrites preserved in the collapsed caldera. Voids between lapilli in cone-sheets indicate the presence of volumes of gas below the surface that could have flowed upwards as fast-moving hot gas streams. We propose a mechanism of formation that began with subterranean magmatic rolls with K-feldspar crystal cores that formed on dyke walls, and became detached. Then they were caught up in rising gas streams and erupted at the surface. Thus accreted lapilli formed underground, were erupted along with blobs of fluid glass in escaping gases, and transported over the surface in nuées ardentes, to settle and cool as ignimbrite flows.展开更多
El-Kahfa complex locates at the intersection of Lat. 24°8′18″ N and Long. 34038′55″ E, South Eastern Desert of Egypt. It comprises an outer ring composed of alkaline syenites, ranging from barrento quartz-bea...El-Kahfa complex locates at the intersection of Lat. 24°8′18″ N and Long. 34038′55″ E, South Eastern Desert of Egypt. It comprises an outer ring composed of alkaline syenites, ranging from barrento quartz-bearing syenites, an inner ring which varies in composition from leucocratic to melanocratic syenites, and a central stock formed essentially of alkali gabbros. These alkali gabbros are cut by small bodies of alkaline syenites, which occasionally grade into nepheline syenites. The country rocks are represented mainly by metavolcanics and epidiorites. El-Kahfa syenites lack any primary hydrous mafic silicates indicating that their magma was anhydrous. Major and trace elements geochemistry of EI-Kahfa rocks reflects the crystallization of early plagioclase followed by Fe-Ti oxides. Salic members in the complex are co-magmatic and related to crystal liquid fractionation. The REE （rare earth elements）＇s tetrad is obvious on the primitive mantle normalized pattern of El-Kahfa rocks. The M-type tetrads clearly appear in the more evolved rocks. These tetrad effects are either a feature of magma-fluid system before crystallization or inherited from external fluid during or after the emplacement of the magma. Generally, El-Kahfa rocks parental magma was probably derived from Nb-enriched or at least under-plate mantle source within the continental East-Africa rift zone, where it may be subjected to minor contamination through their fractional crystallization.展开更多
The Jabal Hadb Ad Dayheen granitic complex in central Saudi Arabia is an alkaline granitic ring complex associated with a collapsed caldera. It mainly consists of monzogranite in the center, biotite-hornblende porphyr...The Jabal Hadb Ad Dayheen granitic complex in central Saudi Arabia is an alkaline granitic ring complex associated with a collapsed caldera. It mainly consists of monzogranite in the center, biotite-hornblende porphyritic granite, and biotite-aegirine-riebeckite granite, intruded by some felsic and mafic dikes. The petrological and geochemical characteristics show that the granitic suites consist of metalminous-peralkaline A-type granites. The secondary ion mass spectrometry(SIMS) zircon U-Pb analysis yielded ^(206)Pb/^(238)U ages of 613.3 ± 8.1 – 603.8 ± 3.8, 602.4 ± 3.8, 596 ± 5.6 Ma for biotitehornblende porphyritic granite, microgranite, and biotite-aegirine-riebeckite granite, respectively. The trace element characteristics and positive ε_(Hf)(t) values(3.2–12.2) indicate that the granitic rocks of the Dayheen Ring Complex are mainly derived from the juvenile crust with the involvement of mantlederived materials. Combined with the regional tectonic evolution, the formation of the Dayheen Ring Complex mainly covered four periods:(1) subduction initiation and formation of arc terranes(870–620 Ma)—volcanic craters formed during this period provided the channel for alkaline complex intrusion;(2) collision between East and West Gondwana continents and formation of the north East African Orogen(640–613 Ma)—monzogranite stock at the center of the ring complex emplaced during this period;(3) post-collision extension and collapse(613–602 Ma)—red metaluminous biotite-hornblende porphyritic granite and microgranite sheets in the rim of the Dayheen Ring Complex emplaced during this period;(4) within-plate extension(602 – 545 Ma) —white peralkaline biotite-aegirine-riebeckite granite and plenty of felsic and mafic dikes in the rim mainly formed during this period. The granitic rocks of the Dayheen Ring Complex mainly formed during the transitional stage of post-collison to within-plate extension after the collision between East and West Gondwana continents, and part of them formed during the early stage of the within-plate extension. U, Th, Zr, Nb, and rare earth element mineralization mainly formed during the early stage of the last period, having a close relationship with the intrusion of white peralkaline biotite-aegirine-riebeckite granite.展开更多
A concept of [GRAPHICS] diagonalization matrix over quaternion field is given, the necessary and sufficient conditions for determining whether a quaternion matrix is a [GRAPHICS] diagonalization one are discussed, and...A concept of [GRAPHICS] diagonalization matrix over quaternion field is given, the necessary and sufficient conditions for determining whether a quaternion matrix is a [GRAPHICS] diagonalization one are discussed, and a method of [GRAPHICS] diagonalization of matrices over quaternion field is given.展开更多
For a square-free integer d other than 0 and 1, let K = Q（√d）, where Q is the set of rational numbers. Then K is called a quadratic field and it has degree 2 over Q. For several quadratic fields K = Q（√d）, the r...For a square-free integer d other than 0 and 1, let K = Q（√d）, where Q is the set of rational numbers. Then K is called a quadratic field and it has degree 2 over Q. For several quadratic fields K = Q（√d）, the ring Rd of integers of K is not a unique-factorization domain. For d 〈 0, there exist only a finite number of complex quadratic fields, whose ring Rd of integers, called complex quadratic ring, is a unique-factorization domain, i.e., d = -1,-2,-3,-7,-11,-19,-43,-67,-163. Let Q denote a prime element of Rd, and let n be an arbitrary positive integer. The unit groups of Rd/（Q^n） was determined by Cross in 1983 for the case d = -1. This paper completely determined the unit groups of Rd/（Q^n） for the cases d = -2, -3.展开更多
Complexation of the planar multidentate ligand 3,5-bis-（2-hydroxyphenyl）pyrazole （H3L） with manganese chloride leads to the formation of the polynuclear complex [MnIHsL4Oa（MeO）a（MeOH）8] （1）. 1 has an octanuc...Complexation of the planar multidentate ligand 3,5-bis-（2-hydroxyphenyl）pyrazole （H3L） with manganese chloride leads to the formation of the polynuclear complex [MnIHsL4Oa（MeO）a（MeOH）8] （1）. 1 has an octanuclear macrocyclic core in which the MnnI ions are bridged by four L molecules to form a ring type structure. Antiferromagnetic interactions were shown to be op- erative between metal centers.展开更多
In this paper, for rings R, we introduce complex rings C（R）, quaternion rings H（R）, and octonion rings O（R）, which are extension rings of R; R C（R） H（R） O（R）. Our main purpose of this paper is to sho...In this paper, for rings R, we introduce complex rings C（R）, quaternion rings H（R）, and octonion rings O（R）, which are extension rings of R; R C（R） H（R） O（R）. Our main purpose of this paper is to show that if R is a Frobenius algebra, then these extension rings are Frobenius Mgebras and if R is a quasi-Frobenius ring, then C（R） and H（R） are quasi-Frobenius rings and, when Char（R）=2, O（R） is also a quasi-Frobenius ring.展开更多
基金supported by the National Natural Science Foundation of China(No.92162103)the Natural Science Foundation of Hunan Province(No.2022JJ30699,No.2023JJ10064)the Science and Technology Innovation Program of Hunan Province(No.2021RC4055,No.2022RC1182).
文摘The Arabian-Nubian Shield(ANS)serves as a key geological archive,preserving the tectono-thermal evolution associated with the Rodinia breakup(∼900–800 Ma)and Gondwana formation(∼800–620 Ma).The Katherina Ring Complex(KRC),located in the Sinai Peninsula,Egypt(northern ANS),exemplifies continental growth through multistage magmatism and orogenesis,spanning the Tonian to Ediacaran periods(∼900–530 Ma).Despite its importance,debates persist regarding the nature,age,crustal characteristics,and magma source evolution of its constituent units.Situated in the northwestern part of the KRC,the Wadi Rofaiyed Cu deposit offers an exceptional natural laboratory for investigating continental crust formation during this interval,owing to its superb exposure and preservation.This study integrates detailed fieldwork,petrographic analyses,whole-rock geochemistry,Sr-Nd isotopes,and in situ zircon U-Pb-Lu-Hf isotopic data.It aims to(i)establish a robust chronological framework for the unmetamorphosed plutonic rocks of the KRC,(ii)advance the understanding of associated geodynamic processes,and(iii)elucidate the episodic magmatism events.The findings show that Wadi Rofaiyed juvenile crust developed in four main phases:(i)a subduction-accretionary phase(∼755 Ma)characterized by intense calc-alkaline magmatism,originating from the partial melting of mafic lower crust;(ii)a syn-collisional phase(∼630 Ma)occurred during the collision between the Saharan metacraton and the younger ANS crust,producing I-type granitoids formed through magma mixing and crustal anatexis;(iii)a post-collisional phase characterized by intermediate I-type(∼595 Ma)to felsic A-type alkaline magma(∼594 Ma),originated from the partial melting of the overthickened lower crust corresponding to lithospheric delamination;and(iv)an anorogenic phase(∼530 Ma)related to the final amalgamation of Greater Gondwana.Isotopic analyses across all four magmatic phases reveal low initial^(87)Sr/^(86)Sr(0.702648–0.703311)and positiveε_(Hf)(t)(+2.84 to+7.78)andε_(Nd)(t)(+2.61 to+5.21)values,consistent with lower crustal sources with depleted mantle-like signatures.The model ages(T_(DM2))for these magmatic rocks derived from zircon Hf(1.2–1.5 Ga)and whole-rock Nd isotopes(0.96–1.17 Ga)support a predominantly juvenile crustal origin.These findings underscore the multistage tectono-magmatic evolution of the northern ANS,advancing our understanding of obduction-accretion dynamics and crustal development during the Neoproterozoic.
基金funded by the projects of Tianjin North China Geological Exploration Bureau (HK2023–B01,HK2022–B08)China Geological Survey (DD20230576,DD20201152)。
文摘1.Objective Nigeria lies between the West African Craton and the Congo Craton,south of the Tuareg Shield(Ogunmola JK et al.,2015).The Nasarawa pegmatite field mainly comprises of the Precambrian Basement Complex(including Archean-Proterozoic migmatite,gneiss,schists and Pan-African “Older Granites”),Mesozoic alkaline ring complexes(“Younger Granites”) and sedimentary basins(Yang QD et al.,2023;Fig.1a).“Older Granites” are part of the Pan-African mobile belt;“Younger Granites” has significant peralkaline characteristics.“Younger Granites” has a wide distribution in the north-central region of Nigeria,including areas such as Kano,Jos-Bauchi,Mada,and Nasarawa,and the emplacement age gradually decreases from north to south from 213 Ma(Dutse complex) to 141 Ma(Afu complex)(Amuda AK et al.,2021).
基金The authors extend their appreciation to the Deanship of Scientific ResearchHa’il Universityfor supporting this work through research project no.SCB-0150175
文摘New fieldwork, mineralogical and geochemical data and interpretations are presented for the rare-metal bearing A-type granites of the Aja intrusive complex(AIC) in the northern segment of the Arabian Shield. This complex is characterized by discontinuous ring-shaped outcrops cut by later faulting. The A-type rocks of the AIC are late Neoproterozoic post-collisional granites, including alkali feldspar granite, alkaline granite and peralkaline granite. They represent the outer zones of the AIC, surrounding a core of older rocks including monzogranite, syenogranite and granophyre granite. The sharp contacts between A-type granites of the outer zone and the different granitic rocks of the inner zone suggest that the AIC was emplaced as different phases over a time interval, following complete crystallization of earlier batches. The A-type granites represent the late intrusive phases of the AIC, which were emplaced during tectonic extension, as shown by the emplacement of dykes synchronous with the granite emplacement and the presence of cataclastic features. The A-type granites consist of K-feldspars, quartz, albite, amphiboles and sodic pyroxene with a wide variety of accessory minerals, including Fe-Ti oxides, zircon, allanite, fluorite, monazite, titanite, apatite, columbite, xenotime and epidote. They are highly evolved(71.3–75.8 wt% SiO2) and display the typical geochemical characteristics of post-collisional, within-plate granites. They are rare-metal granites enriched in total alkalis, Nb, Zr, Y, Ga, Ta, REE with low CaO, MgO, Ba, and Sr. Eu-negative anomalies(Eu/Eu* = 0.17–0.37) of the A-type granites reflect extreme magmatic fractionation and perhaps the effects of late fluid-rock interactions. The chemical characteristics indicate that the A-type granites of the AIC represent products of extreme fractional crystallization involving alkali feldspar, quartz and, to a lesser extent, ferromagnesian minerals. The parent magma was derived from the partial melting of a juvenile crustal protolith with a mantle contribution. Accumulation of residual volatile-rich melt and exsolved fluids in the late stage of the magma evolution produced pegmatite and quartz veins that cut the peripheries of the AIC. Post-magmatic alteration related to the final stages of the evolution of the A-type granitic magma, indicated by alterations of sodic amphibole and sodic pyroxene, hematitization and partial albitization.
基金the National Natural Science Foundation of China(52275378).
文摘The final quality of complex conical-section rings depends on co-design of multiple processes in forming process chain.In this study,for a complex aeroengine casing ring with a large slope and a flange on its end,a co-design method of the forming process chain is put forward towards the objective of precision forming,which not only proposes a standard process route composed of multiple processes of upsetting,punching,rectangular ring rolling,loose tooling forging and profiled ring rolling,but also presents co-design methods of dies and blanks for all the processes.For profiled ring rolling,a design method of preformed blank that makes the blank and the target conical-section ring have the same axial volume distribution is proposed.By the method,the axial metal redistribution during the process can be alleviated greatly thus improving the forming stability and precision of the ring.Based on the geometric features of designed preformed blank,design methods of blanks and dies for loose tolling forging,rectangular ring rolling,punching and upsetting are proposed sequentially.In view of the key roles of loose tooling forging(manufacturing the preformed blank)and profiled ring rolling on the final quality of the conical ring parts,inherited FE simulations for these two processes are performed to verify the proposed design methods and determine appropriate design parameter.It is demonstrated that the proposed design method has significant advantages in improving forming precision.Besides,a suggestive value 1.5 of the rolling ratio for profiled ring rolling(a key design parameter)is given based on comprehensive consideration of multiple indicators such as ring roundness,deformation uniformity and forming load.The corresponding industrial experiments performed illustrate that a high forming precision of the conical-section aeroengine casing ring is achieved.
文摘Photosynthesis in nature has been deemed as the most significant biochemical reaction,which maintains a relatively stable content of O_(2) and CO_(2) in the atmosphere.Herein,for a deeper comprehension of natural photosynthesis,an artificial photosynthesis model reaction of photochemical CO_(2) to CO conversion(CO_(2)+2 H^(+)+2e^(-)→CO+H_(2)O)catalyzed by a homogeneous hexanuclear ring cobalt complex{K_(2)[CoO_(3)PCH_(2)N(CH_(2)CO_(2))_(2)]}_(6)(Co6 complex)is developed.Using the[Ru(bpy)_(3)]^(2+)as a photosensitizer and TEOA as a sacrificial electron donor,an optimal turnover frequency of 503.3 h^(‒1) and an apparent quantum efficiency of 0.81%are obtained.The good photocatalytic CO_(2) reduction performance is attributed to the efficient electron transfer between Co6 complex and[Ru(bpy)_(3)]^(2+),which boosts the photogenerated carriers separation of the photosensitizer.It is confirmed by the j‐V curves,light‐assisted UV‐vis curves,steady‐state photoluminescence spectra and real‐time laser flash photolysis experiments.In addition,the proposed catalytic mechanism for CO_(2) reduction reaction catalyzed by the Co6 complex is explored by the potassium thiocyanate poison experiment,Pourbaix diagram and density functional theory calculations.
基金financially supported by the National Nature Science Foundation of China (No. 41272079)
文摘In addition to syenite ring dykes and multiple alkaline granite stocks, the sub-volcanic Houshihushan alkaline ring complex near Shanhaiguan, Qinhuangdao City, contains cone-sheets of two types： a majority filled with granite porphyry and a minority filled with quartz syenite porphyry. Many cone sheets show evidence of multiple magma intrusion events. Some granite porphyry sheets＇ multiple chilled margins display magmatic roll structures indicating that turbulent magma flowed up the fractures. In one upward-closing cone-sheet K-feldspar phenocrysts floated up through fluid granite porphyry magma and became concentrated at the top providing direct evidence of shallow-level crystal fractionation, confirmed by published rock analyses. Accreted lapilli with K-feldspar crystal cores occur only in the inner parts of a minority of cone-sheets and field relationships indicate that they must have formed beneath the ground surface. Similar lapilli occur in erupted ignimbrites preserved in the collapsed caldera. Voids between lapilli in cone-sheets indicate the presence of volumes of gas below the surface that could have flowed upwards as fast-moving hot gas streams. We propose a mechanism of formation that began with subterranean magmatic rolls with K-feldspar crystal cores that formed on dyke walls, and became detached. Then they were caught up in rising gas streams and erupted at the surface. Thus accreted lapilli formed underground, were erupted along with blobs of fluid glass in escaping gases, and transported over the surface in nuées ardentes, to settle and cool as ignimbrite flows.
文摘El-Kahfa complex locates at the intersection of Lat. 24°8′18″ N and Long. 34038′55″ E, South Eastern Desert of Egypt. It comprises an outer ring composed of alkaline syenites, ranging from barrento quartz-bearing syenites, an inner ring which varies in composition from leucocratic to melanocratic syenites, and a central stock formed essentially of alkali gabbros. These alkali gabbros are cut by small bodies of alkaline syenites, which occasionally grade into nepheline syenites. The country rocks are represented mainly by metavolcanics and epidiorites. El-Kahfa syenites lack any primary hydrous mafic silicates indicating that their magma was anhydrous. Major and trace elements geochemistry of EI-Kahfa rocks reflects the crystallization of early plagioclase followed by Fe-Ti oxides. Salic members in the complex are co-magmatic and related to crystal liquid fractionation. The REE （rare earth elements）＇s tetrad is obvious on the primitive mantle normalized pattern of El-Kahfa rocks. The M-type tetrads clearly appear in the more evolved rocks. These tetrad effects are either a feature of magma-fluid system before crystallization or inherited from external fluid during or after the emplacement of the magma. Generally, El-Kahfa rocks parental magma was probably derived from Nb-enriched or at least under-plate mantle source within the continental East-Africa rift zone, where it may be subjected to minor contamination through their fractional crystallization.
文摘The Jabal Hadb Ad Dayheen granitic complex in central Saudi Arabia is an alkaline granitic ring complex associated with a collapsed caldera. It mainly consists of monzogranite in the center, biotite-hornblende porphyritic granite, and biotite-aegirine-riebeckite granite, intruded by some felsic and mafic dikes. The petrological and geochemical characteristics show that the granitic suites consist of metalminous-peralkaline A-type granites. The secondary ion mass spectrometry(SIMS) zircon U-Pb analysis yielded ^(206)Pb/^(238)U ages of 613.3 ± 8.1 – 603.8 ± 3.8, 602.4 ± 3.8, 596 ± 5.6 Ma for biotitehornblende porphyritic granite, microgranite, and biotite-aegirine-riebeckite granite, respectively. The trace element characteristics and positive ε_(Hf)(t) values(3.2–12.2) indicate that the granitic rocks of the Dayheen Ring Complex are mainly derived from the juvenile crust with the involvement of mantlederived materials. Combined with the regional tectonic evolution, the formation of the Dayheen Ring Complex mainly covered four periods:(1) subduction initiation and formation of arc terranes(870–620 Ma)—volcanic craters formed during this period provided the channel for alkaline complex intrusion;(2) collision between East and West Gondwana continents and formation of the north East African Orogen(640–613 Ma)—monzogranite stock at the center of the ring complex emplaced during this period;(3) post-collision extension and collapse(613–602 Ma)—red metaluminous biotite-hornblende porphyritic granite and microgranite sheets in the rim of the Dayheen Ring Complex emplaced during this period;(4) within-plate extension(602 – 545 Ma) —white peralkaline biotite-aegirine-riebeckite granite and plenty of felsic and mafic dikes in the rim mainly formed during this period. The granitic rocks of the Dayheen Ring Complex mainly formed during the transitional stage of post-collison to within-plate extension after the collision between East and West Gondwana continents, and part of them formed during the early stage of the within-plate extension. U, Th, Zr, Nb, and rare earth element mineralization mainly formed during the early stage of the last period, having a close relationship with the intrusion of white peralkaline biotite-aegirine-riebeckite granite.
文摘A concept of [GRAPHICS] diagonalization matrix over quaternion field is given, the necessary and sufficient conditions for determining whether a quaternion matrix is a [GRAPHICS] diagonalization one are discussed, and a method of [GRAPHICS] diagonalization of matrices over quaternion field is given.
基金This work was supported by the National Natural Science Foundation of China （Grant Nos. 11461010, 11161006）, the Guangxi Natural Science Foundation （2014GXNSFAAll8005, 2015GXNSFAA139009）, the Guangxi Science Research and Technology Development Project （1599005-2-13）, and the Science Research Fund of Guangxi Education Department （KY2015ZD075）.
文摘For a square-free integer d other than 0 and 1, let K = Q（√d）, where Q is the set of rational numbers. Then K is called a quadratic field and it has degree 2 over Q. For several quadratic fields K = Q（√d）, the ring Rd of integers of K is not a unique-factorization domain. For d 〈 0, there exist only a finite number of complex quadratic fields, whose ring Rd of integers, called complex quadratic ring, is a unique-factorization domain, i.e., d = -1,-2,-3,-7,-11,-19,-43,-67,-163. Let Q denote a prime element of Rd, and let n be an arbitrary positive integer. The unit groups of Rd/（Q^n） was determined by Cross in 1983 for the case d = -1. This paper completely determined the unit groups of Rd/（Q^n） for the cases d = -2, -3.
基金a Grant-in-Aid for Scientific Research and for Priority Area "Coordination Programming" (area 2107) from MEXT,Japan
文摘Complexation of the planar multidentate ligand 3,5-bis-（2-hydroxyphenyl）pyrazole （H3L） with manganese chloride leads to the formation of the polynuclear complex [MnIHsL4Oa（MeO）a（MeOH）8] （1）. 1 has an octanuclear macrocyclic core in which the MnnI ions are bridged by four L molecules to form a ring type structure. Antiferromagnetic interactions were shown to be op- erative between metal centers.
文摘In this paper, for rings R, we introduce complex rings C（R）, quaternion rings H（R）, and octonion rings O（R）, which are extension rings of R; R C（R） H（R） O（R）. Our main purpose of this paper is to show that if R is a Frobenius algebra, then these extension rings are Frobenius Mgebras and if R is a quasi-Frobenius ring, then C（R） and H（R） are quasi-Frobenius rings and, when Char（R）=2, O（R） is also a quasi-Frobenius ring.
