A full-sectional microstructure characterization method was developed to investigate the formation of coarse slag rims during the continuous casting of hypo-peritectic steel.The cross-sectional microstructural analysi...A full-sectional microstructure characterization method was developed to investigate the formation of coarse slag rims during the continuous casting of hypo-peritectic steel.The cross-sectional microstructural analysis of typical slag rims for two highly crystalline powders revealed that their formation was primarily driven by the solidification of the liquid slag.Distinct differences were observed in the microstructures of slag rims from the two powders.Powder A(characterized by a higher breaking temperature and viscosity)displayed alternating lamellar microstructures of coarse and fine phases,with the coarse phases composed of akermanite-gehlenite transition phases.In contrast,powder B(with a lower breaking temperature and viscosity)predominantly comprised regular akermanite-gehlenite crystals interspersed with a certain amount of glassy phases.Numerical simulations of a three-phase fluid flow coupled with heat transfer indicate that slag rim formation correlates with mold oscillation.Solidification of the liquid slag at the slag rim front predominantly occurs during the negative stroke of the mold oscillation.The average heating rate during the ascending stage of the mold reaches approximately 100 K·s^(−1),whereas the average cooling rate during the descending stage attains 400 K·s^(−1).This temperature variation leads to the formation of lamellar microstructures,whereas the ascending stage promotes the formation of coarse structures and thicker slag rims.Based on the powder properties,two distinct formation pathways exist for highly crystalline mold powders.For the powders with a higher breaking temperature,higher viscosity,and narrower solidification range(powder A),coarse microstructures and thicker slag rims were preferentially formed.For powders with lower breaking temperature and viscosity and wider solidification ranges(powder B),the liquid slag resisted rapid solidification,and the extended mushy zone allowed the partial liquid slag to persist at the slag rim front,promoting the formation of a thin slag rim.This study enhances the understanding of slag rim formation in highly crystalline mold powders and provides critical insights into the control of longitudinal surface cracks in hypo-peritectic steel.展开更多
The albite rim is present in most felsic gneisses of the Fuping Complex. The presence of the rim indicates the coexistence of plagioclase and K-feldspar in the rock. The rim is formed immediately after the myrmekite, ...The albite rim is present in most felsic gneisses of the Fuping Complex. The presence of the rim indicates the coexistence of plagioclase and K-feldspar in the rock. The rim is formed immediately after the myrmekite, and both textures were derived from the alteration of K-feldspar. The difference is that that there is no quartz present in the rim, and the rim is nearly albite and the anorthite content of the rim plagioclase is substantially lower than that of the myrmekite plagioclase. Formed at 400- 500~C the albite rim was derived from the K-feldspar composition adjustment in the late or post- magmatism stage. As the temperature decreased, the equilibrium between K-feldspar and plagioclase could be maintained, and reactions between the minerals occurred. The leucocratic veins in the complex show distinguished magma or migmatitic characteristics. The rim might form in the late magma or deuteric stage. The formation of the rim implies obvious granitic magmaor melt-injection activity. Typical metamorphic rocks cannot produce the rims. Anatexis after medium-high grade metamorphism might be subordinate. If present, the anatexis is water-present, but the rim texture cannot be taken as the symbol of anatexis.展开更多
Outlier detection is an important data screening type. RIM is a mechanism of outlier detection that identifies the contribution of data points in a regression model. A BIC-based RIM is essentially a technique develope...Outlier detection is an important data screening type. RIM is a mechanism of outlier detection that identifies the contribution of data points in a regression model. A BIC-based RIM is essentially a technique developed in this work to simultaneously detect influential data points and select optimal predictor variables. It is an addition to the body of existing literature in this area of study to both having an alternative to the AIC and Mallow’s Cp Statistic-based RIM as well as conditions of no influence, some sort of influence and perfectly single outlier data point in an entire data set which are proposed in this work. The method is implemented in R by an algorithm that iterates over all data points;deleting data points one at a time while computing BICs and selecting optimal predictors alongside RIMs. From the analyses done using evaporation data to compare the proposed method and the existing methods, the results show that the same data cases selected as having high influences by the two existing methods are also selected by the proposed method. The three methods show same performance;hence the relevance of the BIC-based RIM cannot be undermined.展开更多
The development of collinear resonance ionization spectroscopy for studying the nuclear structure of nickel isotopes far from the stability line relies on high-efficiency two-color two-step photoionization pathways.We...The development of collinear resonance ionization spectroscopy for studying the nuclear structure of nickel isotopes far from the stability line relies on high-efficiency two-color two-step photoionization pathways.We systematically investigated the even-parity autoionization spectrum of atomic nickel through resonance ionization mass spectrometry(RIMS).Fifteen intense single-color photoionization lines and corresponding transitions in the 300-325 nm range were identified and excluded as potential interference peaks for subsequent two-color studies.Fifty-one even-parity autoionization states in the 64000-66800 cm^(-1)range were identified for the first time by scanning from five intermediate excited states of the3d^(8)(^(3)F)4s4p(^(3)P^(o))configuration.Forty-eight of these states were assigned unique total angular momentum quantum numbers(J)based on electric dipole transition selection rules.The autoionization state at 64437.77 cm^(-1)was identified as an optimal final state for enhancing photoionization efficiency in two-color two-step pathways.This study provides comprehensive datasets of even-parity autoionization states of nickel,supporting both the advancement of collinear resonance ionization spectroscopy for exotic nickel isotopes and theoretical modeling of autoionization states.The datasets are openly available at https://doi.org/10.57760/sciencedb.j00113.00280.展开更多
The intricate network of bilateral trade relationships among Pacific Rim countries(PRCs),along with the associated embodied carbon flows plays a pivotal role in shaping global carbon emission patterns and dynamics.Thi...The intricate network of bilateral trade relationships among Pacific Rim countries(PRCs),along with the associated embodied carbon flows plays a pivotal role in shaping global carbon emission patterns and dynamics.This study employs a multi-regional inputoutput analysis and a symbiotic degree model to explore the symbiotic effects of trade-embodied carbon flows between China and PRCs.We show that between 2009 and 2021,China's trade-embodied carbon exports to PRCs surged from 214.20 million tons to 614.80 million tons,driven largely by mechanical and electronic equipment.The share of the United States,Japan,and South Korea in China's total embodied carbon exports to PRCs has declined,whereas Southeast Asian countries have emerged as the primary source of China's embodied carbon imports.The degree of symbiosis in trade-embodied carbon between China and PRCs shifted from negative to positive,indicating a gradual trend toward positive asymmetric symbiosis.Moreover,China's role in regional trade-embodied carbon flows has transitioned from passive to active,with its influence particularly pronounced in countries such as Vietnam,Thailand,Japan,South Korea,and Russia.展开更多
The well deployment in the Ordovician Yingshan Formation in the Gucheng area of the Tarim Basin mainly focuses on the inner gentle slope in the western part of the study area,which results in a low drilling success ra...The well deployment in the Ordovician Yingshan Formation in the Gucheng area of the Tarim Basin mainly focuses on the inner gentle slope in the western part of the study area,which results in a low drilling success rate.To address this issue,this study focused on reconstructing sedimentary models and the adjustment strategies for oil and gas exploration.The carbonate sedimentary model of the Yingshan Formation was re-evaluated using the data of seismic interpretation,core observations,thin-section analyses,carbon isotopic composition,well logging,detrital zircon U-Pb dating,and carbonate mineral U-Pb dating.Then,the favorable sedimentary facies belts were delineated,and updated prospective exploration targets were proposed.The results demonstrate that the sedimentary model of the Yingshan Formation in the Gucheng area is characterized as a rimmed platform system,exhibiting an orderly west-to-east sedimentary sequence transition from restricted/open platform environments through the platform margin and slope settings,ultimately grading into basinal deposits.The platform margin,distinguished by thick successions of grain shoals overlain by interlayered karst zones,is the most favorable distribution area for large-scale reservoirs.Guided by this revised sedimentary model,Well Gutan-1 was successfully drilled within the outer platform margin,encountering over 90%high-energy grain shoal facies with well-developed porous and fractured-vuggy reservoirs,and achieving industrial oil and gas flow.It is confirmed that the platform margin is the priority area for oil and gas exploration in the Ordovician System of the Gucheng area,thereby effectively ending the prolonged exploration stagnation in the Yingshan Formation of the Gucheng area.展开更多
The development of gas condensate reservoirs with a large gas cap,thin oil rim,strong bottom water,and natural barriers faces numerous challenges,including reservoir heterogeneity,coning effects,phase changes,and mult...The development of gas condensate reservoirs with a large gas cap,thin oil rim,strong bottom water,and natural barriers faces numerous challenges,including reservoir heterogeneity,coning effects,phase changes,and multiphase flow dynamics.The influx of gas and water may lead to a low recovery of the oil rim,while reservoir heterogeneity and natural barriers further exacerbate the uneven distribution of reservoir fluid,complicating development strategies.This paper aims to investigate innovative and effective development strategies for this type of reservoir.A detailed,proportionally scaled numerical simulation is performed based on the experimental results of an artificial sand-filled model,providing novel insights into the dynamic behavior of these reservoirs.By understanding the phase behavior and fluid flow characteristics of the reservoir,the study simulates various strategies for the rational and efficient development of the gas condensate reservoir.These strategies include well patterns and completions,the decision to develop the oil rim or gas cap,depletion rates,the bottom water control,and gas injection.The results show that horizontal wells or highly deviated wells are more suitable for the development of the oil rim,as they provide larger control ranges.The presence of strong bottom water is advantageous for displacement energy supply and pressure maintenance,but it intensifies water coning effects,leading to an earlier breakthrough and a sharp production decline.Therefore,it is preferable to apply highly deviated wells at the oil-gas contact,developing the oil rim at lower rates and smaller pressure gradients,followed by developing the gas cap.This approach can reduce water coning effects and improve recovery,with oil and gas recovery reaching 24.4%and 67.95%,respectively,which is an increase of 16.74%and 17.84%compared to direct depletion development of the gas cap.Due to the strong water bottom,continuous gas injection at the top of the reservoir becomes challenging.This study introduces gas assisted gravity drainage with water control technology,a novel and highly effective approach that addresses the impact of bottom water coning effects on the oil and gas zones and overcomes the limitations of gas flooding in reservoirs with strong bottom water.This method can significantly improve oil and gas recovery,achieving recovery of 39.74%and 84.50%,respectively.Compared to the conventional depletion strategy of sequential oil rim and gas cap development,this method achieves additional improvements of 15.33%and 16.55%in oil and gas recovery,respectively.展开更多
基金supported by the National Natural Science Foundation of China(No.52274318).
文摘A full-sectional microstructure characterization method was developed to investigate the formation of coarse slag rims during the continuous casting of hypo-peritectic steel.The cross-sectional microstructural analysis of typical slag rims for two highly crystalline powders revealed that their formation was primarily driven by the solidification of the liquid slag.Distinct differences were observed in the microstructures of slag rims from the two powders.Powder A(characterized by a higher breaking temperature and viscosity)displayed alternating lamellar microstructures of coarse and fine phases,with the coarse phases composed of akermanite-gehlenite transition phases.In contrast,powder B(with a lower breaking temperature and viscosity)predominantly comprised regular akermanite-gehlenite crystals interspersed with a certain amount of glassy phases.Numerical simulations of a three-phase fluid flow coupled with heat transfer indicate that slag rim formation correlates with mold oscillation.Solidification of the liquid slag at the slag rim front predominantly occurs during the negative stroke of the mold oscillation.The average heating rate during the ascending stage of the mold reaches approximately 100 K·s^(−1),whereas the average cooling rate during the descending stage attains 400 K·s^(−1).This temperature variation leads to the formation of lamellar microstructures,whereas the ascending stage promotes the formation of coarse structures and thicker slag rims.Based on the powder properties,two distinct formation pathways exist for highly crystalline mold powders.For the powders with a higher breaking temperature,higher viscosity,and narrower solidification range(powder A),coarse microstructures and thicker slag rims were preferentially formed.For powders with lower breaking temperature and viscosity and wider solidification ranges(powder B),the liquid slag resisted rapid solidification,and the extended mushy zone allowed the partial liquid slag to persist at the slag rim front,promoting the formation of a thin slag rim.This study enhances the understanding of slag rim formation in highly crystalline mold powders and provides critical insights into the control of longitudinal surface cracks in hypo-peritectic steel.
基金supported by the China Geological Survey (nos. 1212011120129,1212010811033,and 1212011120152)the National Natural Science Foundation of China (no. 41072053)
文摘The albite rim is present in most felsic gneisses of the Fuping Complex. The presence of the rim indicates the coexistence of plagioclase and K-feldspar in the rock. The rim is formed immediately after the myrmekite, and both textures were derived from the alteration of K-feldspar. The difference is that that there is no quartz present in the rim, and the rim is nearly albite and the anorthite content of the rim plagioclase is substantially lower than that of the myrmekite plagioclase. Formed at 400- 500~C the albite rim was derived from the K-feldspar composition adjustment in the late or post- magmatism stage. As the temperature decreased, the equilibrium between K-feldspar and plagioclase could be maintained, and reactions between the minerals occurred. The leucocratic veins in the complex show distinguished magma or migmatitic characteristics. The rim might form in the late magma or deuteric stage. The formation of the rim implies obvious granitic magmaor melt-injection activity. Typical metamorphic rocks cannot produce the rims. Anatexis after medium-high grade metamorphism might be subordinate. If present, the anatexis is water-present, but the rim texture cannot be taken as the symbol of anatexis.
文摘Outlier detection is an important data screening type. RIM is a mechanism of outlier detection that identifies the contribution of data points in a regression model. A BIC-based RIM is essentially a technique developed in this work to simultaneously detect influential data points and select optimal predictor variables. It is an addition to the body of existing literature in this area of study to both having an alternative to the AIC and Mallow’s Cp Statistic-based RIM as well as conditions of no influence, some sort of influence and perfectly single outlier data point in an entire data set which are proposed in this work. The method is implemented in R by an algorithm that iterates over all data points;deleting data points one at a time while computing BICs and selecting optimal predictors alongside RIMs. From the analyses done using evaporation data to compare the proposed method and the existing methods, the results show that the same data cases selected as having high influences by the two existing methods are also selected by the proposed method. The three methods show same performance;hence the relevance of the BIC-based RIM cannot be undermined.
基金supported by the China National Nuclear Corporation Basic Research Project(Grant No.CNNC-JCYJ-202327)。
文摘The development of collinear resonance ionization spectroscopy for studying the nuclear structure of nickel isotopes far from the stability line relies on high-efficiency two-color two-step photoionization pathways.We systematically investigated the even-parity autoionization spectrum of atomic nickel through resonance ionization mass spectrometry(RIMS).Fifteen intense single-color photoionization lines and corresponding transitions in the 300-325 nm range were identified and excluded as potential interference peaks for subsequent two-color studies.Fifty-one even-parity autoionization states in the 64000-66800 cm^(-1)range were identified for the first time by scanning from five intermediate excited states of the3d^(8)(^(3)F)4s4p(^(3)P^(o))configuration.Forty-eight of these states were assigned unique total angular momentum quantum numbers(J)based on electric dipole transition selection rules.The autoionization state at 64437.77 cm^(-1)was identified as an optimal final state for enhancing photoionization efficiency in two-color two-step pathways.This study provides comprehensive datasets of even-parity autoionization states of nickel,supporting both the advancement of collinear resonance ionization spectroscopy for exotic nickel isotopes and theoretical modeling of autoionization states.The datasets are openly available at https://doi.org/10.57760/sciencedb.j00113.00280.
基金National Natural Science Foundation of China,No.42201258,No.42571214Ministry of Education Humanities and Social Sciences Research Youth Fund Project,No.22YJCZH057+2 种基金National Key Research and Development Program of China,No.2024YFE0214000The Project of Jinhua City’s Deepening of Local Cooperation between China and Africa in 2025,No.SXZF202548ZSpecial Major Project of National Influence Building Think Tank,No.ZKZD2024011。
文摘The intricate network of bilateral trade relationships among Pacific Rim countries(PRCs),along with the associated embodied carbon flows plays a pivotal role in shaping global carbon emission patterns and dynamics.This study employs a multi-regional inputoutput analysis and a symbiotic degree model to explore the symbiotic effects of trade-embodied carbon flows between China and PRCs.We show that between 2009 and 2021,China's trade-embodied carbon exports to PRCs surged from 214.20 million tons to 614.80 million tons,driven largely by mechanical and electronic equipment.The share of the United States,Japan,and South Korea in China's total embodied carbon exports to PRCs has declined,whereas Southeast Asian countries have emerged as the primary source of China's embodied carbon imports.The degree of symbiosis in trade-embodied carbon between China and PRCs shifted from negative to positive,indicating a gradual trend toward positive asymmetric symbiosis.Moreover,China's role in regional trade-embodied carbon flows has transitioned from passive to active,with its influence particularly pronounced in countries such as Vietnam,Thailand,Japan,South Korea,and Russia.
基金Supported by the National Natural Science Foundation of China General Program(42272181)CNPC-Southwest Petroleum University Innovation Consortium Program(2020CX010301).
文摘The well deployment in the Ordovician Yingshan Formation in the Gucheng area of the Tarim Basin mainly focuses on the inner gentle slope in the western part of the study area,which results in a low drilling success rate.To address this issue,this study focused on reconstructing sedimentary models and the adjustment strategies for oil and gas exploration.The carbonate sedimentary model of the Yingshan Formation was re-evaluated using the data of seismic interpretation,core observations,thin-section analyses,carbon isotopic composition,well logging,detrital zircon U-Pb dating,and carbonate mineral U-Pb dating.Then,the favorable sedimentary facies belts were delineated,and updated prospective exploration targets were proposed.The results demonstrate that the sedimentary model of the Yingshan Formation in the Gucheng area is characterized as a rimmed platform system,exhibiting an orderly west-to-east sedimentary sequence transition from restricted/open platform environments through the platform margin and slope settings,ultimately grading into basinal deposits.The platform margin,distinguished by thick successions of grain shoals overlain by interlayered karst zones,is the most favorable distribution area for large-scale reservoirs.Guided by this revised sedimentary model,Well Gutan-1 was successfully drilled within the outer platform margin,encountering over 90%high-energy grain shoal facies with well-developed porous and fractured-vuggy reservoirs,and achieving industrial oil and gas flow.It is confirmed that the platform margin is the priority area for oil and gas exploration in the Ordovician System of the Gucheng area,thereby effectively ending the prolonged exploration stagnation in the Yingshan Formation of the Gucheng area.
基金the support from the National Natural Science Foundation of China(NSFC Grant No.:52004032)。
文摘The development of gas condensate reservoirs with a large gas cap,thin oil rim,strong bottom water,and natural barriers faces numerous challenges,including reservoir heterogeneity,coning effects,phase changes,and multiphase flow dynamics.The influx of gas and water may lead to a low recovery of the oil rim,while reservoir heterogeneity and natural barriers further exacerbate the uneven distribution of reservoir fluid,complicating development strategies.This paper aims to investigate innovative and effective development strategies for this type of reservoir.A detailed,proportionally scaled numerical simulation is performed based on the experimental results of an artificial sand-filled model,providing novel insights into the dynamic behavior of these reservoirs.By understanding the phase behavior and fluid flow characteristics of the reservoir,the study simulates various strategies for the rational and efficient development of the gas condensate reservoir.These strategies include well patterns and completions,the decision to develop the oil rim or gas cap,depletion rates,the bottom water control,and gas injection.The results show that horizontal wells or highly deviated wells are more suitable for the development of the oil rim,as they provide larger control ranges.The presence of strong bottom water is advantageous for displacement energy supply and pressure maintenance,but it intensifies water coning effects,leading to an earlier breakthrough and a sharp production decline.Therefore,it is preferable to apply highly deviated wells at the oil-gas contact,developing the oil rim at lower rates and smaller pressure gradients,followed by developing the gas cap.This approach can reduce water coning effects and improve recovery,with oil and gas recovery reaching 24.4%and 67.95%,respectively,which is an increase of 16.74%and 17.84%compared to direct depletion development of the gas cap.Due to the strong water bottom,continuous gas injection at the top of the reservoir becomes challenging.This study introduces gas assisted gravity drainage with water control technology,a novel and highly effective approach that addresses the impact of bottom water coning effects on the oil and gas zones and overcomes the limitations of gas flooding in reservoirs with strong bottom water.This method can significantly improve oil and gas recovery,achieving recovery of 39.74%and 84.50%,respectively.Compared to the conventional depletion strategy of sequential oil rim and gas cap development,this method achieves additional improvements of 15.33%and 16.55%in oil and gas recovery,respectively.
