Photocatalytic hydrogen peroxide(H_(2)O_(2))production offers a sustainable route to convert water and oxygen into H_(2)O_(2)using solar energy.However,achieving long-term stability in photocatalysts remains a critica...Photocatalytic hydrogen peroxide(H_(2)O_(2))production offers a sustainable route to convert water and oxygen into H_(2)O_(2)using solar energy.However,achieving long-term stability in photocatalysts remains a critical challenge due to mismatched kinetics between oxygen reduction(ORR)and water oxidation(WOR),which leads to hole accumulation and oxidative degradation.Here,we report a redox-mediated strategy to address this bottleneck by designing a hydroquinone-embedded covalent organic framework(Tz-QH-COF)that enables reversible hole buffering and kinetic balance.The hydroquinone(QH)units act as dynamic hole reservoirs,capturing excess holes during ORR and converting to benzoquinone(Q),which is regenerated to QH via WOR,thereby preventing oxidative decomposition.This reversible QH/Q cycle,directly visualized through in situ attenuated total reflection surface-enhanced infrared absorption spectroscopy,ensures unmatched stability,achieving continuous H_(2)O_(2) production for 528 h(22 d)with an accumulated yield of 18.6 mmol L^(–1)—the highest reported duration for organic photocatalysts.Density functional theory calculations reveal that the QH units exhibit a strong oxygen adsorption energy and favorable two-electron ORR/WOR pathways with low energy barriers.The synergy between experimental and theoretical insights elucidates a redox-mediated charge-balance mechanism,advancing the design of robust photocatalysts for solar-driven H_(2)O_(2) synthesis.展开更多
基于闪存的固态硬盘(solid state driver,简称SSD)已经广泛应用于各种移动设备、PC机和服务器.与磁盘相比,尽管SSD具有数据存取速度高、抗震、低功耗等优良特性,但SSD自身也存在读写不对称、价格昂贵等不利因素,这使得SSD短期内不会完...基于闪存的固态硬盘(solid state driver,简称SSD)已经广泛应用于各种移动设备、PC机和服务器.与磁盘相比,尽管SSD具有数据存取速度高、抗震、低功耗等优良特性,但SSD自身也存在读写不对称、价格昂贵等不利因素,这使得SSD短期内不会完全取代磁盘.将SSD和磁盘组合构建混合系统,可以发挥不同的硬件特性,提升系统性能.基于MLC型SSD和SLC型SSD之间的特性差异,提出了一种闪存敏感的多级缓存管理策略——FAMC.FAMC将SSD用在内存和磁盘之间作扩展缓存,针对数据库系统、文件管理中数据访问的特点,有选择地将内存牺牲页缓存到不同类型的SSD.FAMC同时考虑写请求模式和负载类型对系统性能的影响,设计实现对SSD友好的数据管理策略.此外,FAMC基于不同的数据置换代价提出了适用于SSD的缓冲区管理算法.基于多级缓存存储系统对FAMC的性能进行了评测,实验结果表明,FAMC可以大幅度降低系统响应时间,减少磁盘I/O.展开更多
文摘Photocatalytic hydrogen peroxide(H_(2)O_(2))production offers a sustainable route to convert water and oxygen into H_(2)O_(2)using solar energy.However,achieving long-term stability in photocatalysts remains a critical challenge due to mismatched kinetics between oxygen reduction(ORR)and water oxidation(WOR),which leads to hole accumulation and oxidative degradation.Here,we report a redox-mediated strategy to address this bottleneck by designing a hydroquinone-embedded covalent organic framework(Tz-QH-COF)that enables reversible hole buffering and kinetic balance.The hydroquinone(QH)units act as dynamic hole reservoirs,capturing excess holes during ORR and converting to benzoquinone(Q),which is regenerated to QH via WOR,thereby preventing oxidative decomposition.This reversible QH/Q cycle,directly visualized through in situ attenuated total reflection surface-enhanced infrared absorption spectroscopy,ensures unmatched stability,achieving continuous H_(2)O_(2) production for 528 h(22 d)with an accumulated yield of 18.6 mmol L^(–1)—the highest reported duration for organic photocatalysts.Density functional theory calculations reveal that the QH units exhibit a strong oxygen adsorption energy and favorable two-electron ORR/WOR pathways with low energy barriers.The synergy between experimental and theoretical insights elucidates a redox-mediated charge-balance mechanism,advancing the design of robust photocatalysts for solar-driven H_(2)O_(2) synthesis.
文摘基于闪存的固态硬盘(solid state driver,简称SSD)已经广泛应用于各种移动设备、PC机和服务器.与磁盘相比,尽管SSD具有数据存取速度高、抗震、低功耗等优良特性,但SSD自身也存在读写不对称、价格昂贵等不利因素,这使得SSD短期内不会完全取代磁盘.将SSD和磁盘组合构建混合系统,可以发挥不同的硬件特性,提升系统性能.基于MLC型SSD和SLC型SSD之间的特性差异,提出了一种闪存敏感的多级缓存管理策略——FAMC.FAMC将SSD用在内存和磁盘之间作扩展缓存,针对数据库系统、文件管理中数据访问的特点,有选择地将内存牺牲页缓存到不同类型的SSD.FAMC同时考虑写请求模式和负载类型对系统性能的影响,设计实现对SSD友好的数据管理策略.此外,FAMC基于不同的数据置换代价提出了适用于SSD的缓冲区管理算法.基于多级缓存存储系统对FAMC的性能进行了评测,实验结果表明,FAMC可以大幅度降低系统响应时间,减少磁盘I/O.
