Some biological uses of polyethylene glycol（PEG）：The use of PEG as a membrane fusogen was first reported in 1976with the creation of cell hybrids,formed by suspending two cell lines in a 50%w/w solution of PEG in w...Some biological uses of polyethylene glycol（PEG）：The use of PEG as a membrane fusogen was first reported in 1976with the creation of cell hybrids,formed by suspending two cell lines in a 50%w/w solution of PEG in water.展开更多
The oncoprotein MYC is a transcription factor that regulates arange of genes involved in various biological processes includingcell cycle arrest, cell proliferation, metabolism, protein synthesisand genomic instabilit...The oncoprotein MYC is a transcription factor that regulates arange of genes involved in various biological processes includingcell cycle arrest, cell proliferation, metabolism, protein synthesisand genomic instability. Recently, MYC has been shown playing arole in regulating cancer cell metastasis, while outcomes of thisregulation remain controversial. In some breast tumors, MYCaccelerates metastasis by elevating miR-9 miRNA expression [1].However, under certain circumstance, MYC activation may havean opposite function in suppressing cell motility and impairingcancer invasion [2-4]. Intriguingly, through direct suppressingexpressions of av and p3 integrin subunits, MYC impedes breastcancer cell metastasis [3]. Moreover, MYC blocks JNK signalingand consequently causes reduced tumor cell migration [5]. Therefore,the role of MYC in cell migration is largely unknown andneeds further investigation.展开更多
MPHPB was prepared from melamine,phenylphosphonic acid and boric acid,and its flame retardant effect in PE was investigated.Compared to the intermediate product(melamine phenyl hypophosphite(MPHP)),the residual char i...MPHPB was prepared from melamine,phenylphosphonic acid and boric acid,and its flame retardant effect in PE was investigated.Compared to the intermediate product(melamine phenyl hypophosphite(MPHP)),the residual char increased from 17.9% of MPHP to 41.2% of MPHPB at 800℃.The limiting oxygen index(LOI)of PE/20%MPHPB is 23.6%,which reaches V-0 rating.After the addition of 20%MPHPB,the total heat release(THR),peak heat release rate(pK-HRR),and average effective thermal combustion rates(av-EHC)of PE decreased.Additionally,characterizations including the pyrolysis gas chromatography-mass spectrometry(Py-GC-MS),scanning electron microscopy(SEM),raman spectroscopy test(LRS)and fourier transform infrared(FT-IR)were taken to investigate the flame retardant mechanism,and the results show that MPHPB plays roles in both gas and condensed phases.展开更多
To address the issues of short setting time and high bleeding rate of A component,which easily cause pipe plugging and poor grouting performance when a two-component grout is injected synchronously behind the Segmenta...To address the issues of short setting time and high bleeding rate of A component,which easily cause pipe plugging and poor grouting performance when a two-component grout is injected synchronously behind the Segmental Lining,the inorganic retarder sodium pyrophosphate(TSPP)and three organic retarders were added to the A component:sodium citrate(SC),sodium tartrate(ST)and glycerol(GLY).The effect law and microscopic mechanism of viscosity,bleeding rate,setting time,gelling time,compressive strength,and stone rate were investigated.The results revealed that the addition of retarders could enhance the stability and setting time of the A component and increase the gelling time,stone rate,and compressive strength of two-component grout.Among them,the performance of the grout with an SC dosage of 0.1% was superior.The bleeding rate of this grout was reduced to 3.5%,the stone rate of the two-component grout was more than 99%,and the early compressive strength and late compressive strength of this grout were increased by approximately 35% and 7%,respectively.The initial and final setting time of the A component with a TSPP dosage of 0.3% was the longest,which was prolonged to 17 and 26 h,respectively.Microscopic analysis revealed that the four retarders hindered the hydration process of cement through complexation and adsorption,and inhibited the hydration of C_(3)S and the crystallisation of CH.Moreover,they reduced the defects caused by the rapid reaction of water glass and CH on the solid phase structure,enabled the microstructure of the stone body to be denser,and subsequently,enhanced the compressive strength.展开更多
By combining the merits of radiative cooling(RC)and evaporation cooling(EC),radiative coupled evaporative cooling(REC)has attracted considerable attention for sub-ambient cooling purposes.However,for outdoor devices,t...By combining the merits of radiative cooling(RC)and evaporation cooling(EC),radiative coupled evaporative cooling(REC)has attracted considerable attention for sub-ambient cooling purposes.However,for outdoor devices,the interior heating power would increase the working temperature and fire risk,which would suppress their above-ambient heat dissipation capabilities and passive water cycle properties.In this work,we introduced a REC design based on an all-in-one photonic hydrogel for above-ambient heat dissipation and flame retardancy.Unlike conventional design RC film for heat dissipation with limited cooling power and fire risk,REC hydrogel can greatly improve the heat dissipation performance in the daytime with a high workload,indicating a 12.0℃lower temperature than the RC film under the same conditions in the outdoor experiment.In the nighttime with a low workload,RC-assisted adsorption can improve atmospheric water harvesting to ensure EC in the daytime.In addition,our REC hydrogel significantly enhanced flame retardancy by absorbing heat without a corresponding temperature rise,thus mitigating fire risks.Thus,our design shows a promising solution for the thermal management of outdoor devices,delivering outstanding performance in both heat dissipation and flame retardancy.展开更多
To improve the applicability of red mud in subgrade construction,we studied the effects of four traditional retarders,including borax,sodium hexametaphosphate,sodium gluconate,and sucrose,on the setting time,mechanica...To improve the applicability of red mud in subgrade construction,we studied the effects of four traditional retarders,including borax,sodium hexametaphosphate,sodium gluconate,and sucrose,on the setting time,mechanical properties and soil solidification of red mud-based subgrade engineered cementitious material(RCM).The mechanisms of the retarders on the hydration process of RCM were analyzed by hydration microcalorimeter,XRD,TG,and SEM-EDS.The experimental results show that four retarders have retarding effect on RCM,among which sodium gluconate and sucrose have significant retarding effect and do not have adverse effect on 28 d strength.Borax can slightly delay the setting time,and sodium hexametaphosphate has a better retarding effect,but they both reduce the 28 d strength.Microcosmic analysis shows that the retarders do not change the type of RCM hydration products,but mainly slow down the rate of hydration reaction through the adsorption and complexation or reaction of Ca^(2+)in the slurry.All the results show that the retarder has no weakening effect on the unconfined compressive strength,water stability and CBR properties of the stabilized subgrade soil based on RCM.展开更多
Accurate and early evaluation of dental physiological characteristics is essential for effective disease detection and management.Polarization-sensitive optical coherence tomography(PS-OCT)is a noninvasive high-resolu...Accurate and early evaluation of dental physiological characteristics is essential for effective disease detection and management.Polarization-sensitive optical coherence tomography(PS-OCT)is a noninvasive high-resolution imaging technique that can obtain tooth structure and physiological features through intensity,retardation and degree of polarization uniformity(DOPU)images.In this study,we use the information provided by the PS-OCT system,especially the retardation information,to assess the physiological characteristics of teeth.In addition,we introduce a novel parameter—the rate of change of the retardation value(R)—to evaluate the magnitude of birefringence of enamel,which serves as an indicator of enamel health and mineralization.The results demonstrate that PS-OCT not only provides structural detail comparable to microcomputed tomography(microCT),but also yields additional physiological characteristics insights through polarization-based contrast.These findings highlight the strong potential of PS-OCT for early diagnosis,functional evaluation and personalized monitoring in dental care.展开更多
Bio-based 2,5-furandicarboxylic acid polyesters offer significant promise for reducing energy and environmental crises.However,their intrinsic flammability remains a critical limitation,and conventional flame-retardan...Bio-based 2,5-furandicarboxylic acid polyesters offer significant promise for reducing energy and environmental crises.However,their intrinsic flammability remains a critical limitation,and conventional flame-retardant strategies often compromise their mechanical properties,hindering their practical applications.Herein,a 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide(DOPO)-based comonomer(DDP)was used to synthesize flame-retardant poly(ethylene furandicarboxylate-co-phosphaphenanthrene)(PEFDn).The covalent integration of DDP confers intrinsic flame retardancy,avoiding the plasticization and migration issues associated with additive-type systems.Upon thermal decomposition,the DOPO-derived moieties release phosphoric acid and radical scavengers,promoting char formation and suppressing flame propagation.Furthermore,density functional theory(DFT)calculations combined with non-covalent interaction(NCI)analysis revealed that DOPO dimer molecules adopt a stable parallel-displaced π-π stacking configu ration,potentially facilitating microphase separation and enhancing the energy dissipation capability.PEFD_(10)achieves a UL-94 V-0 rating while simultaneously increasing impact toughness from 1.5 kJ/m^(2) to 14.7 kJ/m^(2).Im portantly,PEFDn maintained acceptable oxygen-barrier properties.PEFD10 also exhibited high transparency and UV-shielding performance.The combination of intrinsic flame safety,im pact-toughness resistance,UV shielding,and an oxygen barrier ensures reliable protection of electrical components and long-term operational stability.The integration of multiple critical properties within a single bio-based material represents a novel approach fo r enabling sustainable polymer solutions for high-pe rformance electrical applications.展开更多
Objective:To analyze the clinical effect of sensory integration training combined with cognitive training in the rehabilitation treatment of children with mental retardation.Methods:A total of 120 children with mental...Objective:To analyze the clinical effect of sensory integration training combined with cognitive training in the rehabilitation treatment of children with mental retardation.Methods:A total of 120 children with mental retardation who received rehabilitation intervention in our hospital from January 2022 to December 2025 were selected and divided into a control group and an experimental group,with 60 children in each group.The control group adopted a conventional rehabilitation training program;the experimental group adopted a combined sensory integration training and cognitive training program.The sensory integration ability,cognitive function,and daily living skills of children in the two groups were compared.Results:The sensory integration ability score of the experimental group(85.3±6.2)was significantly higher than that of the control group(72.1±7.5)(p<0.05);the cognitive function score(88.7±5.8)was significantly improved compared with that of the control group(76.4±6.9)(p<0.05);the daily living skills score(90.2±4.7)was significantly higher than that of the control group(80.5±5.3)(p<0.05).The social interaction ability of the experimental group reached 92.5%,which was significantly higher than that of the control group(81.3%)(p<0.05).Conclusion:Sensory integration training combined with cognitive training demonstrates favorable outcomes in the rehabilitation treatment of children with mental retardation,exhibiting a notable neurofunctional remodeling effect.It can optimize the multidimensional rehabilitation process,effectively enhance the comprehensive developmental potential of children,and hold significant clinical application value.展开更多
Although poly(urethane-urea)elastomers(PUEs)possess excellent mechanical properties and durability,their inherent flammability and inability to self-repair after damage significantly limits their applications in high-...Although poly(urethane-urea)elastomers(PUEs)possess excellent mechanical properties and durability,their inherent flammability and inability to self-repair after damage significantly limits their applications in high-end fields.To address this challenge,this study employs a supramolecular chemistry approach by simultaneously incorporating multiple hydrogen bonds as dynamic cross-linking points and a phosphorus-nitrogen synergistic flame-retardant structure into the poly(urethane-urea)network.The multiple hydrogen bonds endow the material with efficient intrinsic self-healing capability,while the phosphorus-nitrogen flame retardant ensures outstanding thermal stability and flame resistance,leading to the successful synthesis of a high-performance multifunctional poly(urethane-urea)elastomer.Experimental results demonstrated that when the content of the flame retardant diethyl(2-((2-aminoethyl)amino)ethyl)phosphoramidate(DEPTA)was 10 wt%,the resulting PUE/10%DEPTA achieved a V-0 rating in the vertical burning test,with a limiting oxygen index(LOI)of 30%.Concurrently,the elastomer maintained good toughness,exhibiting a tensile strength of 27.3 MPa,an elongation at break of 601%,and a self-healing efficiency of up to 94.46%.This breakthrough shows significant promise for advanced engineering applications that demand fire safety,structural durability,and extended service life through self-repair.展开更多
Adult-born oligodendrocytes are continuously produced in the brains of rodents.The functional role of these cells has been linked to the motor-related activities of healthy animals and is vital for acquiring new motor...Adult-born oligodendrocytes are continuously produced in the brains of rodents.The functional role of these cells has been linked to the motor-related activities of healthy animals and is vital for acquiring new motor skills.However,the relationship between these cells and the control of motor-related activities has not been investigated in pathological conditions.Therefore,the aim of this study is to investigate the role of oligodendrocytes in depression-related motor deficits and the effects of training.Psychomotor retardation is a key symptom of depression.Consistent with the impairments observed in rodent motor performance,the proliferation and activation of adult-born oligodendrocytes are altered in a corticosterone-induced stress paradigm.Therapeutic rotarod training can alleviate these symptoms by reversing the aforementioned changes.Notably,these alterations are particularly pronounced in layer I of the motor cortex.Thus,this study provides evidence of the potential functional involvement of adult-born oligodendrocytes in the motor impairments observed in the depressed animals.Additionally,it offers preliminary results for further investigation into layer I of the motor cortex in relation to these pathological conditions.展开更多
High-performance MXene-based polymer nanocomposites are well-suited for various industrial applications owing to their excellent mechanical,thermal,and other properties.However,the fabrication of flame-retardant polym...High-performance MXene-based polymer nanocomposites are well-suited for various industrial applications owing to their excellent mechanical,thermal,and other properties.However,the fabrication of flame-retardant polymer/MXene nanocom-posites remains challenging owing to the limited flame-retardant properties of MXene itself.This study prepared a novel MXene@Ag@PA hybrid material via radiation modification and complexation reaction.This material was used to further enhance the key properties of ethylene-vinyl acetate(EVA),such as its mechanical properties,thermal conductivity,flame retardancy,and electromagnetic shielding.The addition of two parts of this hybrid material increased the thermal conduc-tivity of EVA by 44.2%and reduced its peak exothermic rate during combustion by 30.1%compared with pure EVA.The material also significantly reduced smoke production and increased the residue content.In the X-band,the electromagnetic shielding effectiveness of the EVA composites reached 20 dB.Moreover,the MXene@Ag@PA hybrid material could be used to further enhance the mechanical properties of EVA composites under electron-beam irradiation.Thus,this study contributes to the development of MXene-based EVA advanced materials that are fire-safe,have high strength,and exhibit good electromagnetic shielding performance for various applications.展开更多
The microstructure design for thermal conduction pathways in polymeric electrical encapsulation materials is essential to meet the stringent requirements for efficient thermal management and thermal runaway safety in ...The microstructure design for thermal conduction pathways in polymeric electrical encapsulation materials is essential to meet the stringent requirements for efficient thermal management and thermal runaway safety in modern electronic devices.Hence,a composite with three-dimensional network(Ho/U-BNNS/WPU)is developed by simultaneously incorporating magnetically modified boron nitride nanosheets(M@BNNS)and non-magnetic organo-grafted BNNS(U-BNNS)into waterborne polyurethane(WPU)to synchronous molding under a horizontal magnetic field.The results indicate that the continuous in-plane pathways formed by M@BNNS aligned along the magnetic field direction,combined with the bridging structure established by U-BNNS,enable Ho/U-BNNS/WPU to exhibit exceptional in-plane(λ//)and through-plane thermal conductivities(λ_(⊥)).In particular,with the addition of 30 wt%M@BNNS and 5 wt%U-BNNS,theλ//andλ_(⊥)of composites reach 11.47 and 2.88 W m^(-1) K^(-1),respectively,which representing a 194.2%improvement inλ_(⊥)compared to the composites with a single orientation of M@BNNS.Meanwhile,Ho/U-BNNS/WPU exhibits distinguished thermal management capabilities as thermal interface materials for LED and chips.The composites also demonstrate excellent flame retardancy,with a peak heat release and total heat release reduced by 58.9%and 36.9%,respectively,compared to WPU.Thus,this work offers new insights into the thermally conductive structural design and efficient flame-retardant systems of polymer composites,presenting broad application potential in electronic packaging fields.展开更多
Depolarizing behavior is commonly observed in most natural samples.For this reason,optical tools measuring the differences in depolarization response among spatially separated structures are highly useful in a wide ra...Depolarizing behavior is commonly observed in most natural samples.For this reason,optical tools measuring the differences in depolarization response among spatially separated structures are highly useful in a wide range of imaging applications for enhanced visualization of structures,target identification,etc.One commonly used tool for depolarizing discrimination is the so-called depolarizing spaces.In this article,we exploit the combined use of two depolarizing spaces,the indices of polarization purity(IPP)and polarizance–reflection–transformation(PRT)spaces,to improve the capability of optical systems to identify polarization–anisotropy depolarizers.The potential of these spaces to discriminate among different depolarizers is first studied from a series of simulations by incoherently adding diattenuations or retarders,with some control parameters emulating samples in nature.The simulated results demonstrate that the proposed methods are capable of increasing differences among depolarizers beyond other well-known techniques.Experimentally,validation is provided by conducting diverse phantom experiments of easy interpretation and mimicking the stated simulations.As a useful application of our approach,we developed a model able to retrieve intrinsic microscopic information of samples from macroscopic polarimetric measurements.The proposed methods enable non-invasive,straightforward,macroscopic characterization of depolarizing samples,and may be of interest for enhanced visualization of samples in multiple imaging scenarios.展开更多
In recent decades,annual urban fire incidents,including those involving ancient wooden buildings burned,transportation,and solar panels,have increased,leading to significant loss of human life and property.Addressing ...In recent decades,annual urban fire incidents,including those involving ancient wooden buildings burned,transportation,and solar panels,have increased,leading to significant loss of human life and property.Addressing this issue without altering the surface morphology or interfering with optical behavior of flammable materials poses a substantial challenge.Herein,we present a transparent,low thickness,ceramifiable nanosystem coating composed of a highly adhesive base(poly(SSS1-co-HEMA1)),nanoscale layered double hydroxide sheets as ceramic precursors,and supramolecular melamine di-borate as an accelerator.We demonstrate that this hybrid coating can transform into a porous,fire-resistant protective layer with a highly thermostable vitreous phase upon exposure to flame/heat source.A nanosystem coating of just~100μm thickness can significantly increase the limiting oxygen index of wood(Pine)to 37.3%,dramatically reduce total heat release by 78.6%,and maintain low smoke toxicity(CIT_G=0.016).Detailed molecular force analysis,combined with a comprehensive examination of the underlying flame-retardant mechanisms,underscores the effectiveness of this coating.This work offers a strategy for creating efficient,environmentally friendly coatings with fire safety applications across various industries.展开更多
The rapid development of modern 5G technology has significantly increased the demand for multifunctional electromagnetic interference(EMI)shielding and wave-absorbing materials.Hence,a densification strategy was propo...The rapid development of modern 5G technology has significantly increased the demand for multifunctional electromagnetic interference(EMI)shielding and wave-absorbing materials.Hence,a densification strategy was proposed to fabricate multifunctional rigid polyimide(PI)composite foam.As a result,the composite PI foam exhibits excellent mechanical properties,with tensile and bending strengths of 4.7 and 21.1 MPa,respectively.Moreover,the composite PI foam achieves a promising EMI shielding performance with a high absorption coefficient(A)of 0.71,coupled with an X-band(8.2–12.4 GHz)EMI rating of 44 dB(2 mm)due to its high conductivity(20.29 ms/mm).Satisfyingly,the composite PI foam also has an optimal reflection loss(RL)of up to−46.4 dB and an effective absorption bandwidth(EAB)(RL<−10 dB)that covers the entire X-band.Meanwhile,the fabricated foam demonstrates a Joule heating performance of 89.2°C under supply voltages(3–9 V)and rapid response time(within 20 s)for stable and reproducible performance in long-term cycling.This work provides a versatile strategy for the development of lightweight and high-strength materials for EMI shielding and microwave absorption,demonstrating great potential for aerospace,microelectronics,and energy conversion applications.展开更多
Silicone rubber(SR)exhibits superior breathability and high-temperature resistance.However,SR is prone to degradation under extreme heat or combustion,limiting its effectiveness in mitigating secondary hazards.In this...Silicone rubber(SR)exhibits superior breathability and high-temperature resistance.However,SR is prone to degradation under extreme heat or combustion,limiting its effectiveness in mitigating secondary hazards.In this study,phosphate glass powder was used to calcinate zinc borate,lanthanum oxide,and cerium oxide.Methylphenyl polysiloxane was then grafted onto the surface of the glass powder,resulting in the modified pow-ders designated as Methylphenyl polysiloxane-grafted zinc borate-modified phosphate glass powder(GF-ZnBM),Methylphenyl polysiloxane-grafted lanthanum oxide-modified phosphate glass powder(GF-LaM),and Methylphenyl polysiloxane-grafted cerium oxide-modified phosphate glass powder(GF-CeM).The modified powders were sub-sequently incorporated into silicone rubber composites to enhance the ceramicization capability of silicone rubber at high temperatures.Specifically,GF-CeM and GF-LaM significantly increased the limiting oxygen index(LOI)to 33%and reduced the tendency for combustion propagation.Additionally,GF-CeM notably contributed to enhancing ceramicization strength.The presence of cerium oxide helps in the melting of the glass powder and enhances its adhesion to the silicone rubber matrix.SR/ZnB-GF exhibited the lowest activation energy among the tested composites,along with the best protective capability.The inclusion of modified glass powder has a minor impact on the rheological properties,indicating that the composite retains its ability to flow and deform under stress.This confirms that the material remains flexible under normal conditions and forms a ceramic structure when heated,thereby exhibiting self-supporting properties.This study provides a practical methodology for the targeted modification of glass powders,thereby further enhancing the fire safety of silicone-based composites.展开更多
The construction of hierarchical thermoplastic polyurethane(TPU)composites with superior flame retardant and electromagnetic shielding capabilities hold significant practical importance.In this work,TPU composites loa...The construction of hierarchical thermoplastic polyurethane(TPU)composites with superior flame retardant and electromagnetic shielding capabilities hold significant practical importance.In this work,TPU composites loaded with a multilayer core-shell flame retardant(APP@CoAl-LDH@Si)and a modified conductive nanofiller(MWCNT-NH_(2)-PA)were firstly prepared through the melt blending method,acting as surface layer.Additionally,multilayered MXene films functionalized by bacterial cellulose(BC)and dopamine hydrochloride(DA)were fabricated via a facile and efficient vacuum filtration approach.Finally,a PBM film was utilized as an intermediate layer to construct hierarchical TPU composites.The results indicated that the introduction of 10 wt%APP@CoAl-LDH@Si hybrid,the peak heat release rate,total heat release,peak smoke production rate,and total smoke release of the TPU composites were decreased by 83.0%,61.3%,48.5%and 66.9%,respectively,compared with those of pure TPU due to the free radicals capture effect of APP,and the flame-retardant functions of LDH and silane.Moreover,the hierarchical TPU/APP@CoAl-LDH@Si/CP1-PBM exhibited excellent electromagnetic shielding performance,achieving 43.6 dB in the X-band because of multiple reflection losses,interface polarization losses,and charge carrier movement-induced thermal dissipation.Extraordinarily,the A and R coefficients were reversed in the X and K bands.This phenomenon was attributed to the different degrees of confinement of the multilayer structure to electromagnetic waves with different wavelengths.This work presents a novel model for the design and preparation of high-performance polymer composites with multiple properties and regulation mechanism.展开更多
Machine picking in cotton is an emerging practice in India,to solve the problems of labour shortages and production costs increasing.Cotton production has been declining in recent years;however,the high density planti...Machine picking in cotton is an emerging practice in India,to solve the problems of labour shortages and production costs increasing.Cotton production has been declining in recent years;however,the high density planting system(HDPS)offers a viable method to enhance productivity by increasing plant populations per unit area,optimizing resource utilization,and facilitating machine picking.Cotton is an indeterminate plant that produce excessive vegeta-tive growth in favorable soil fertility and moisture conditions,which posing challenges for efficient machine picking.To address this issue,the application of plant growth retardants(PGRs)is essential for controlling canopy architecture.PGRs reduce internode elongation,promote regulated branching,and increase plant compactness,making cotton plants better suited for machine picking.PGRs application also optimizes photosynthates distribution between veg-etative and reproductive growth,resulting in higher yields and improved fibre quality.The integration of HDPS and PGRs applications results in an optimal plant architecture for improving machine picking efficiency.However,the success of this integration is determined by some factors,including cotton variety,environmental conditions,and geographical variations.These approaches not only address yield stagnation and labour shortages but also help to establish more effective and sustainable cotton farming practices,resulting in higher cotton productivity.展开更多
In-situ polymer electrolytes prepared by Li salt-initiated polymerization are promising electrolytes for solid-state Li metal batteries owing to their enhanced interface contact and facile and green preparation proces...In-situ polymer electrolytes prepared by Li salt-initiated polymerization are promising electrolytes for solid-state Li metal batteries owing to their enhanced interface contact and facile and green preparation process.However,conventional in-situ polymer electrolytes suffer from poor interface stability,low mechanical strength,low oxidation stability,and certain flammability.Herein,a silsesquioxane(POSS)-nanocage-crosslinked in-situ polymer electrolyte(POSS-DOL@PI-F)regulated by fluorinated plasticizer and enhanced by polyimide skeleton is fabricated by Li salt initiated in-situ polymerization.Polyimide skeleton and POSS-nanocage-crosslinked network significantly enhance the tensile strength(22.8 MPa)and thermal stability(200℃)of POSS-DOL@PI-F.Fluorinated plasticizer improves ionic conductivity(6.83×10^(-4)S cm^(-1)),flame retardance,and oxidation stability(5.0 V)of POSS-DOL@PI-F.The fluorinated plasticizer of POSS-DOL@PI-F constructs robust LiF-rich solid electrolyte interphases and cathode electrolyte interphases,thereby dramatically enhancing the interface stability of Li metal anodes and LiNi_(0.8)Mn_(0.1)Co_(0.1)O_(2)(NCM811)cathodes.POSS-DOL@PI-F enables stable,long-term(1200 h),and dendrite-free cycle of Li‖Li cells.POSS-DOL@PI-F significantly boosts the performance of Li‖NCM811cells,which display superior cycle stability under harsh conditions of high voltage(4.5 V),high temperature(60℃),low temperature(-20℃),and high areal capacity.This work provides a rational design strategy for safe and efficient polymer electrolytes.展开更多
基金supported by grants from the Lone Star Paralysis Foundationan NIH grant R01 NS081063 to GDB
文摘Some biological uses of polyethylene glycol（PEG）：The use of PEG as a membrane fusogen was first reported in 1976with the creation of cell hybrids,formed by suspending two cell lines in a 50%w/w solution of PEG in water.
基金supported by the National Natural Science Foundation of China(81672766 and 81788101 to W.D.),ChinaCAMS Innovation Fund for Medical Sciences(CIFMS)(2016-I2M-4-002to W.D.),China+1 种基金CAMS Basic Research Fund(2016ZX310186 and2016RC310038 to W.D.),ChinaState Key Laboratory Special Fund(2060204),China
文摘The oncoprotein MYC is a transcription factor that regulates arange of genes involved in various biological processes includingcell cycle arrest, cell proliferation, metabolism, protein synthesisand genomic instability. Recently, MYC has been shown playing arole in regulating cancer cell metastasis, while outcomes of thisregulation remain controversial. In some breast tumors, MYCaccelerates metastasis by elevating miR-9 miRNA expression [1].However, under certain circumstance, MYC activation may havean opposite function in suppressing cell motility and impairingcancer invasion [2-4]. Intriguingly, through direct suppressingexpressions of av and p3 integrin subunits, MYC impedes breastcancer cell metastasis [3]. Moreover, MYC blocks JNK signalingand consequently causes reduced tumor cell migration [5]. Therefore,the role of MYC in cell migration is largely unknown andneeds further investigation.
基金Funded by the Natural Science Foundation of Guangdong(Nos.2014A030313241,2014B090901068,and 2016A010103003)。
文摘MPHPB was prepared from melamine,phenylphosphonic acid and boric acid,and its flame retardant effect in PE was investigated.Compared to the intermediate product(melamine phenyl hypophosphite(MPHP)),the residual char increased from 17.9% of MPHP to 41.2% of MPHPB at 800℃.The limiting oxygen index(LOI)of PE/20%MPHPB is 23.6%,which reaches V-0 rating.After the addition of 20%MPHPB,the total heat release(THR),peak heat release rate(pK-HRR),and average effective thermal combustion rates(av-EHC)of PE decreased.Additionally,characterizations including the pyrolysis gas chromatography-mass spectrometry(Py-GC-MS),scanning electron microscopy(SEM),raman spectroscopy test(LRS)and fourier transform infrared(FT-IR)were taken to investigate the flame retardant mechanism,and the results show that MPHPB plays roles in both gas and condensed phases.
基金Funded by the National Natural Science Foundation of China(No.52378394)the Fundamental Research Funds for the Central Universities(No.B230201037)。
文摘To address the issues of short setting time and high bleeding rate of A component,which easily cause pipe plugging and poor grouting performance when a two-component grout is injected synchronously behind the Segmental Lining,the inorganic retarder sodium pyrophosphate(TSPP)and three organic retarders were added to the A component:sodium citrate(SC),sodium tartrate(ST)and glycerol(GLY).The effect law and microscopic mechanism of viscosity,bleeding rate,setting time,gelling time,compressive strength,and stone rate were investigated.The results revealed that the addition of retarders could enhance the stability and setting time of the A component and increase the gelling time,stone rate,and compressive strength of two-component grout.Among them,the performance of the grout with an SC dosage of 0.1% was superior.The bleeding rate of this grout was reduced to 3.5%,the stone rate of the two-component grout was more than 99%,and the early compressive strength and late compressive strength of this grout were increased by approximately 35% and 7%,respectively.The initial and final setting time of the A component with a TSPP dosage of 0.3% was the longest,which was prolonged to 17 and 26 h,respectively.Microscopic analysis revealed that the four retarders hindered the hydration process of cement through complexation and adsorption,and inhibited the hydration of C_(3)S and the crystallisation of CH.Moreover,they reduced the defects caused by the rapid reaction of water glass and CH on the solid phase structure,enabled the microstructure of the stone body to be denser,and subsequently,enhanced the compressive strength.
基金financially supported by the Science and Technology Innovation Program of Hunan Province(2024RC3003)the Central South University Innovation-Driven Research Programme(2023CXQD012)the Initiative for Sustainable Energy for its financial support。
文摘By combining the merits of radiative cooling(RC)and evaporation cooling(EC),radiative coupled evaporative cooling(REC)has attracted considerable attention for sub-ambient cooling purposes.However,for outdoor devices,the interior heating power would increase the working temperature and fire risk,which would suppress their above-ambient heat dissipation capabilities and passive water cycle properties.In this work,we introduced a REC design based on an all-in-one photonic hydrogel for above-ambient heat dissipation and flame retardancy.Unlike conventional design RC film for heat dissipation with limited cooling power and fire risk,REC hydrogel can greatly improve the heat dissipation performance in the daytime with a high workload,indicating a 12.0℃lower temperature than the RC film under the same conditions in the outdoor experiment.In the nighttime with a low workload,RC-assisted adsorption can improve atmospheric water harvesting to ensure EC in the daytime.In addition,our REC hydrogel significantly enhanced flame retardancy by absorbing heat without a corresponding temperature rise,thus mitigating fire risks.Thus,our design shows a promising solution for the thermal management of outdoor devices,delivering outstanding performance in both heat dissipation and flame retardancy.
基金Funded by the Shandong Province Key R&D Program(Major Technological Innovation Project(Nos.2023ZLGX01 and 2021CXGC010301)the Youth Project of National Natural Science Foundation(No.52309136)+1 种基金the Competitive Innovation Platform Project of Shandong Province(No.2023CXPT-080)the Postdoctoral Innovation Project(No.SDCX-ZG-202203037)。
文摘To improve the applicability of red mud in subgrade construction,we studied the effects of four traditional retarders,including borax,sodium hexametaphosphate,sodium gluconate,and sucrose,on the setting time,mechanical properties and soil solidification of red mud-based subgrade engineered cementitious material(RCM).The mechanisms of the retarders on the hydration process of RCM were analyzed by hydration microcalorimeter,XRD,TG,and SEM-EDS.The experimental results show that four retarders have retarding effect on RCM,among which sodium gluconate and sucrose have significant retarding effect and do not have adverse effect on 28 d strength.Borax can slightly delay the setting time,and sodium hexametaphosphate has a better retarding effect,but they both reduce the 28 d strength.Microcosmic analysis shows that the retarders do not change the type of RCM hydration products,but mainly slow down the rate of hydration reaction through the adsorption and complexation or reaction of Ca^(2+)in the slurry.All the results show that the retarder has no weakening effect on the unconfined compressive strength,water stability and CBR properties of the stabilized subgrade soil based on RCM.
基金supported by the National Natural Science Foundation of China(Nos.62375144 and 12404345)"the Fundamental Research Funds for the Central Universities",Nankai University(No.63241331).
文摘Accurate and early evaluation of dental physiological characteristics is essential for effective disease detection and management.Polarization-sensitive optical coherence tomography(PS-OCT)is a noninvasive high-resolution imaging technique that can obtain tooth structure and physiological features through intensity,retardation and degree of polarization uniformity(DOPU)images.In this study,we use the information provided by the PS-OCT system,especially the retardation information,to assess the physiological characteristics of teeth.In addition,we introduce a novel parameter—the rate of change of the retardation value(R)—to evaluate the magnitude of birefringence of enamel,which serves as an indicator of enamel health and mineralization.The results demonstrate that PS-OCT not only provides structural detail comparable to microcomputed tomography(microCT),but also yields additional physiological characteristics insights through polarization-based contrast.These findings highlight the strong potential of PS-OCT for early diagnosis,functional evaluation and personalized monitoring in dental care.
基金financially supported by the National Key Research and Development Program of China(No.2021YFB3700300)the National Natural Science Foundation of China(Nos.52573017 and U21B2093)+1 种基金Key Research and Development Program of Ningbo(No.2022Z200)the Zhejiang Provincial Natural Science Foundation(No.LY23E030005)。
文摘Bio-based 2,5-furandicarboxylic acid polyesters offer significant promise for reducing energy and environmental crises.However,their intrinsic flammability remains a critical limitation,and conventional flame-retardant strategies often compromise their mechanical properties,hindering their practical applications.Herein,a 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide(DOPO)-based comonomer(DDP)was used to synthesize flame-retardant poly(ethylene furandicarboxylate-co-phosphaphenanthrene)(PEFDn).The covalent integration of DDP confers intrinsic flame retardancy,avoiding the plasticization and migration issues associated with additive-type systems.Upon thermal decomposition,the DOPO-derived moieties release phosphoric acid and radical scavengers,promoting char formation and suppressing flame propagation.Furthermore,density functional theory(DFT)calculations combined with non-covalent interaction(NCI)analysis revealed that DOPO dimer molecules adopt a stable parallel-displaced π-π stacking configu ration,potentially facilitating microphase separation and enhancing the energy dissipation capability.PEFD_(10)achieves a UL-94 V-0 rating while simultaneously increasing impact toughness from 1.5 kJ/m^(2) to 14.7 kJ/m^(2).Im portantly,PEFDn maintained acceptable oxygen-barrier properties.PEFD10 also exhibited high transparency and UV-shielding performance.The combination of intrinsic flame safety,im pact-toughness resistance,UV shielding,and an oxygen barrier ensures reliable protection of electrical components and long-term operational stability.The integration of multiple critical properties within a single bio-based material represents a novel approach fo r enabling sustainable polymer solutions for high-pe rformance electrical applications.
基金Baoding Science and Technology Plan Project(Project No.:2541ZF307)。
文摘Objective:To analyze the clinical effect of sensory integration training combined with cognitive training in the rehabilitation treatment of children with mental retardation.Methods:A total of 120 children with mental retardation who received rehabilitation intervention in our hospital from January 2022 to December 2025 were selected and divided into a control group and an experimental group,with 60 children in each group.The control group adopted a conventional rehabilitation training program;the experimental group adopted a combined sensory integration training and cognitive training program.The sensory integration ability,cognitive function,and daily living skills of children in the two groups were compared.Results:The sensory integration ability score of the experimental group(85.3±6.2)was significantly higher than that of the control group(72.1±7.5)(p<0.05);the cognitive function score(88.7±5.8)was significantly improved compared with that of the control group(76.4±6.9)(p<0.05);the daily living skills score(90.2±4.7)was significantly higher than that of the control group(80.5±5.3)(p<0.05).The social interaction ability of the experimental group reached 92.5%,which was significantly higher than that of the control group(81.3%)(p<0.05).Conclusion:Sensory integration training combined with cognitive training demonstrates favorable outcomes in the rehabilitation treatment of children with mental retardation,exhibiting a notable neurofunctional remodeling effect.It can optimize the multidimensional rehabilitation process,effectively enhance the comprehensive developmental potential of children,and hold significant clinical application value.
文摘Although poly(urethane-urea)elastomers(PUEs)possess excellent mechanical properties and durability,their inherent flammability and inability to self-repair after damage significantly limits their applications in high-end fields.To address this challenge,this study employs a supramolecular chemistry approach by simultaneously incorporating multiple hydrogen bonds as dynamic cross-linking points and a phosphorus-nitrogen synergistic flame-retardant structure into the poly(urethane-urea)network.The multiple hydrogen bonds endow the material with efficient intrinsic self-healing capability,while the phosphorus-nitrogen flame retardant ensures outstanding thermal stability and flame resistance,leading to the successful synthesis of a high-performance multifunctional poly(urethane-urea)elastomer.Experimental results demonstrated that when the content of the flame retardant diethyl(2-((2-aminoethyl)amino)ethyl)phosphoramidate(DEPTA)was 10 wt%,the resulting PUE/10%DEPTA achieved a V-0 rating in the vertical burning test,with a limiting oxygen index(LOI)of 30%.Concurrently,the elastomer maintained good toughness,exhibiting a tensile strength of 27.3 MPa,an elongation at break of 601%,and a self-healing efficiency of up to 94.46%.This breakthrough shows significant promise for advanced engineering applications that demand fire safety,structural durability,and extended service life through self-repair.
基金supported by Hong Kong Health and Medical Research Fund,No.02133206(to KFS).
文摘Adult-born oligodendrocytes are continuously produced in the brains of rodents.The functional role of these cells has been linked to the motor-related activities of healthy animals and is vital for acquiring new motor skills.However,the relationship between these cells and the control of motor-related activities has not been investigated in pathological conditions.Therefore,the aim of this study is to investigate the role of oligodendrocytes in depression-related motor deficits and the effects of training.Psychomotor retardation is a key symptom of depression.Consistent with the impairments observed in rodent motor performance,the proliferation and activation of adult-born oligodendrocytes are altered in a corticosterone-induced stress paradigm.Therapeutic rotarod training can alleviate these symptoms by reversing the aforementioned changes.Notably,these alterations are particularly pronounced in layer I of the motor cortex.Thus,this study provides evidence of the potential functional involvement of adult-born oligodendrocytes in the motor impairments observed in the depressed animals.Additionally,it offers preliminary results for further investigation into layer I of the motor cortex in relation to these pathological conditions.
文摘High-performance MXene-based polymer nanocomposites are well-suited for various industrial applications owing to their excellent mechanical,thermal,and other properties.However,the fabrication of flame-retardant polymer/MXene nanocom-posites remains challenging owing to the limited flame-retardant properties of MXene itself.This study prepared a novel MXene@Ag@PA hybrid material via radiation modification and complexation reaction.This material was used to further enhance the key properties of ethylene-vinyl acetate(EVA),such as its mechanical properties,thermal conductivity,flame retardancy,and electromagnetic shielding.The addition of two parts of this hybrid material increased the thermal conduc-tivity of EVA by 44.2%and reduced its peak exothermic rate during combustion by 30.1%compared with pure EVA.The material also significantly reduced smoke production and increased the residue content.In the X-band,the electromagnetic shielding effectiveness of the EVA composites reached 20 dB.Moreover,the MXene@Ag@PA hybrid material could be used to further enhance the mechanical properties of EVA composites under electron-beam irradiation.Thus,this study contributes to the development of MXene-based EVA advanced materials that are fire-safe,have high strength,and exhibit good electromagnetic shielding performance for various applications.
基金support from the National Natural Science Foundation of China(22268025,52473083,and 22475176)Key Research and Development Program of Yunnan Province(202403AP140036)+2 种基金Natural Science Basic Research Program of Shaanxi(2024JC-TBZC-04)Applied Basic Research Program of Yunnan Province(202201AT070115 and 202201BE070001-031)supported by the Innovation Capability Support Program of Shaanxi(2024RS-CXTD-57).
文摘The microstructure design for thermal conduction pathways in polymeric electrical encapsulation materials is essential to meet the stringent requirements for efficient thermal management and thermal runaway safety in modern electronic devices.Hence,a composite with three-dimensional network(Ho/U-BNNS/WPU)is developed by simultaneously incorporating magnetically modified boron nitride nanosheets(M@BNNS)and non-magnetic organo-grafted BNNS(U-BNNS)into waterborne polyurethane(WPU)to synchronous molding under a horizontal magnetic field.The results indicate that the continuous in-plane pathways formed by M@BNNS aligned along the magnetic field direction,combined with the bridging structure established by U-BNNS,enable Ho/U-BNNS/WPU to exhibit exceptional in-plane(λ//)and through-plane thermal conductivities(λ_(⊥)).In particular,with the addition of 30 wt%M@BNNS and 5 wt%U-BNNS,theλ//andλ_(⊥)of composites reach 11.47 and 2.88 W m^(-1) K^(-1),respectively,which representing a 194.2%improvement inλ_(⊥)compared to the composites with a single orientation of M@BNNS.Meanwhile,Ho/U-BNNS/WPU exhibits distinguished thermal management capabilities as thermal interface materials for LED and chips.The composites also demonstrate excellent flame retardancy,with a peak heat release and total heat release reduced by 58.9%and 36.9%,respectively,compared to WPU.Thus,this work offers new insights into the thermally conductive structural design and efficient flame-retardant systems of polymer composites,presenting broad application potential in electronic packaging fields.
基金supported by the China Scholarship Council(Grant No.202306690024)the Ministerio de Ciencia e Innovación and Fondos FEDER(Grant Nos.PID2021-562126509OB-C21 and PDC2022-133332-C21)+1 种基金the Generalitat de Catalunya(Grant No.2021SGR00138)the Beatriu de Pinós Fellowship(Grant No.2021-BP-00206).
文摘Depolarizing behavior is commonly observed in most natural samples.For this reason,optical tools measuring the differences in depolarization response among spatially separated structures are highly useful in a wide range of imaging applications for enhanced visualization of structures,target identification,etc.One commonly used tool for depolarizing discrimination is the so-called depolarizing spaces.In this article,we exploit the combined use of two depolarizing spaces,the indices of polarization purity(IPP)and polarizance–reflection–transformation(PRT)spaces,to improve the capability of optical systems to identify polarization–anisotropy depolarizers.The potential of these spaces to discriminate among different depolarizers is first studied from a series of simulations by incoherently adding diattenuations or retarders,with some control parameters emulating samples in nature.The simulated results demonstrate that the proposed methods are capable of increasing differences among depolarizers beyond other well-known techniques.Experimentally,validation is provided by conducting diverse phantom experiments of easy interpretation and mimicking the stated simulations.As a useful application of our approach,we developed a model able to retrieve intrinsic microscopic information of samples from macroscopic polarimetric measurements.The proposed methods enable non-invasive,straightforward,macroscopic characterization of depolarizing samples,and may be of interest for enhanced visualization of samples in multiple imaging scenarios.
基金the financial support from the National Natural Science Foundation of China(524B2168,U22A20149,52173081,and 52273275)。
文摘In recent decades,annual urban fire incidents,including those involving ancient wooden buildings burned,transportation,and solar panels,have increased,leading to significant loss of human life and property.Addressing this issue without altering the surface morphology or interfering with optical behavior of flammable materials poses a substantial challenge.Herein,we present a transparent,low thickness,ceramifiable nanosystem coating composed of a highly adhesive base(poly(SSS1-co-HEMA1)),nanoscale layered double hydroxide sheets as ceramic precursors,and supramolecular melamine di-borate as an accelerator.We demonstrate that this hybrid coating can transform into a porous,fire-resistant protective layer with a highly thermostable vitreous phase upon exposure to flame/heat source.A nanosystem coating of just~100μm thickness can significantly increase the limiting oxygen index of wood(Pine)to 37.3%,dramatically reduce total heat release by 78.6%,and maintain low smoke toxicity(CIT_G=0.016).Detailed molecular force analysis,combined with a comprehensive examination of the underlying flame-retardant mechanisms,underscores the effectiveness of this coating.This work offers a strategy for creating efficient,environmentally friendly coatings with fire safety applications across various industries.
基金support from the Postgraduate Innovation Foundation of Xi'an Polytechnic University(No.chx2024034)the Natural Science Foundation of Shaanxi Province(No.2022JQ-362,2021JQ-677)the Scientific Research Program Funded by Shaanxi Provincial Education Department(No.21JK20180911).
文摘The rapid development of modern 5G technology has significantly increased the demand for multifunctional electromagnetic interference(EMI)shielding and wave-absorbing materials.Hence,a densification strategy was proposed to fabricate multifunctional rigid polyimide(PI)composite foam.As a result,the composite PI foam exhibits excellent mechanical properties,with tensile and bending strengths of 4.7 and 21.1 MPa,respectively.Moreover,the composite PI foam achieves a promising EMI shielding performance with a high absorption coefficient(A)of 0.71,coupled with an X-band(8.2–12.4 GHz)EMI rating of 44 dB(2 mm)due to its high conductivity(20.29 ms/mm).Satisfyingly,the composite PI foam also has an optimal reflection loss(RL)of up to−46.4 dB and an effective absorption bandwidth(EAB)(RL<−10 dB)that covers the entire X-band.Meanwhile,the fabricated foam demonstrates a Joule heating performance of 89.2°C under supply voltages(3–9 V)and rapid response time(within 20 s)for stable and reproducible performance in long-term cycling.This work provides a versatile strategy for the development of lightweight and high-strength materials for EMI shielding and microwave absorption,demonstrating great potential for aerospace,microelectronics,and energy conversion applications.
基金supported by National Natural Science Foundation of China(51991352 and 51874266).
文摘Silicone rubber(SR)exhibits superior breathability and high-temperature resistance.However,SR is prone to degradation under extreme heat or combustion,limiting its effectiveness in mitigating secondary hazards.In this study,phosphate glass powder was used to calcinate zinc borate,lanthanum oxide,and cerium oxide.Methylphenyl polysiloxane was then grafted onto the surface of the glass powder,resulting in the modified pow-ders designated as Methylphenyl polysiloxane-grafted zinc borate-modified phosphate glass powder(GF-ZnBM),Methylphenyl polysiloxane-grafted lanthanum oxide-modified phosphate glass powder(GF-LaM),and Methylphenyl polysiloxane-grafted cerium oxide-modified phosphate glass powder(GF-CeM).The modified powders were sub-sequently incorporated into silicone rubber composites to enhance the ceramicization capability of silicone rubber at high temperatures.Specifically,GF-CeM and GF-LaM significantly increased the limiting oxygen index(LOI)to 33%and reduced the tendency for combustion propagation.Additionally,GF-CeM notably contributed to enhancing ceramicization strength.The presence of cerium oxide helps in the melting of the glass powder and enhances its adhesion to the silicone rubber matrix.SR/ZnB-GF exhibited the lowest activation energy among the tested composites,along with the best protective capability.The inclusion of modified glass powder has a minor impact on the rheological properties,indicating that the composite retains its ability to flow and deform under stress.This confirms that the material remains flexible under normal conditions and forms a ceramic structure when heated,thereby exhibiting self-supporting properties.This study provides a practical methodology for the targeted modification of glass powders,thereby further enhancing the fire safety of silicone-based composites.
基金financially supported by the National Natural Science Foundation of China(No.52173070)the Key research and development projects of Baoying County(No.BY202205).
文摘The construction of hierarchical thermoplastic polyurethane(TPU)composites with superior flame retardant and electromagnetic shielding capabilities hold significant practical importance.In this work,TPU composites loaded with a multilayer core-shell flame retardant(APP@CoAl-LDH@Si)and a modified conductive nanofiller(MWCNT-NH_(2)-PA)were firstly prepared through the melt blending method,acting as surface layer.Additionally,multilayered MXene films functionalized by bacterial cellulose(BC)and dopamine hydrochloride(DA)were fabricated via a facile and efficient vacuum filtration approach.Finally,a PBM film was utilized as an intermediate layer to construct hierarchical TPU composites.The results indicated that the introduction of 10 wt%APP@CoAl-LDH@Si hybrid,the peak heat release rate,total heat release,peak smoke production rate,and total smoke release of the TPU composites were decreased by 83.0%,61.3%,48.5%and 66.9%,respectively,compared with those of pure TPU due to the free radicals capture effect of APP,and the flame-retardant functions of LDH and silane.Moreover,the hierarchical TPU/APP@CoAl-LDH@Si/CP1-PBM exhibited excellent electromagnetic shielding performance,achieving 43.6 dB in the X-band because of multiple reflection losses,interface polarization losses,and charge carrier movement-induced thermal dissipation.Extraordinarily,the A and R coefficients were reversed in the X and K bands.This phenomenon was attributed to the different degrees of confinement of the multilayer structure to electromagnetic waves with different wavelengths.This work presents a novel model for the design and preparation of high-performance polymer composites with multiple properties and regulation mechanism.
文摘Machine picking in cotton is an emerging practice in India,to solve the problems of labour shortages and production costs increasing.Cotton production has been declining in recent years;however,the high density planting system(HDPS)offers a viable method to enhance productivity by increasing plant populations per unit area,optimizing resource utilization,and facilitating machine picking.Cotton is an indeterminate plant that produce excessive vegeta-tive growth in favorable soil fertility and moisture conditions,which posing challenges for efficient machine picking.To address this issue,the application of plant growth retardants(PGRs)is essential for controlling canopy architecture.PGRs reduce internode elongation,promote regulated branching,and increase plant compactness,making cotton plants better suited for machine picking.PGRs application also optimizes photosynthates distribution between veg-etative and reproductive growth,resulting in higher yields and improved fibre quality.The integration of HDPS and PGRs applications results in an optimal plant architecture for improving machine picking efficiency.However,the success of this integration is determined by some factors,including cotton variety,environmental conditions,and geographical variations.These approaches not only address yield stagnation and labour shortages but also help to establish more effective and sustainable cotton farming practices,resulting in higher cotton productivity.
基金supported by the National Natural Science Foundation of China(22375116,22001057)the Science Foundation of High-Level Talents of Wuyi University(2019AL017,2021AL002)Tianjin Lishen Battery Co.,Ltd。
文摘In-situ polymer electrolytes prepared by Li salt-initiated polymerization are promising electrolytes for solid-state Li metal batteries owing to their enhanced interface contact and facile and green preparation process.However,conventional in-situ polymer electrolytes suffer from poor interface stability,low mechanical strength,low oxidation stability,and certain flammability.Herein,a silsesquioxane(POSS)-nanocage-crosslinked in-situ polymer electrolyte(POSS-DOL@PI-F)regulated by fluorinated plasticizer and enhanced by polyimide skeleton is fabricated by Li salt initiated in-situ polymerization.Polyimide skeleton and POSS-nanocage-crosslinked network significantly enhance the tensile strength(22.8 MPa)and thermal stability(200℃)of POSS-DOL@PI-F.Fluorinated plasticizer improves ionic conductivity(6.83×10^(-4)S cm^(-1)),flame retardance,and oxidation stability(5.0 V)of POSS-DOL@PI-F.The fluorinated plasticizer of POSS-DOL@PI-F constructs robust LiF-rich solid electrolyte interphases and cathode electrolyte interphases,thereby dramatically enhancing the interface stability of Li metal anodes and LiNi_(0.8)Mn_(0.1)Co_(0.1)O_(2)(NCM811)cathodes.POSS-DOL@PI-F enables stable,long-term(1200 h),and dendrite-free cycle of Li‖Li cells.POSS-DOL@PI-F significantly boosts the performance of Li‖NCM811cells,which display superior cycle stability under harsh conditions of high voltage(4.5 V),high temperature(60℃),low temperature(-20℃),and high areal capacity.This work provides a rational design strategy for safe and efficient polymer electrolytes.
