NbO-type MOFs constructed from dicopper paddlewheel secondary building units and diisophthalate ligands not only exhibit great promise for the separation of environment and energy-related gas pairs but also more impor...NbO-type MOFs constructed from dicopper paddlewheel secondary building units and diisophthalate ligands not only exhibit great promise for the separation of environment and energy-related gas pairs but also more importantly provide an excellent platform for the fundamental investigation of structure–property relationships.In this work,two NbO-type MOFs(ZJNU-91 and ZJNU-92)derived from linear and zigzag-shaped thieno[3,2-b]thiophene-functionalized diisophthalate ligands were solvothermally prepared and structurally characterized.展开更多
基金the Natural Science Foundation of China(No.21771162)the Natural Science Foundation of Zhejiang Province,China(LR16B010001)the Qianjiang Talents Project in Zhejiang Province(ZC304015017)for financial support.
文摘NbO-type MOFs constructed from dicopper paddlewheel secondary building units and diisophthalate ligands not only exhibit great promise for the separation of environment and energy-related gas pairs but also more importantly provide an excellent platform for the fundamental investigation of structure–property relationships.In this work,two NbO-type MOFs(ZJNU-91 and ZJNU-92)derived from linear and zigzag-shaped thieno[3,2-b]thiophene-functionalized diisophthalate ligands were solvothermally prepared and structurally characterized.